Articles | Volume 21, issue 3
Atmos. Chem. Phys., 21, 1565–1580, 2021
https://doi.org/10.5194/acp-21-1565-2021
Atmos. Chem. Phys., 21, 1565–1580, 2021
https://doi.org/10.5194/acp-21-1565-2021

Research article 04 Feb 2021

Research article | 04 Feb 2021

Mass accommodation and gas–particle partitioning in secondary organic aerosols: dependence on diffusivity, volatility, particle-phase reactions, and penetration depth

Manabu Shiraiwa and Ulrich Pöschl

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Cited articles

Alpert, P. A., Corral Arroyo, P., Dou, J., Krieger, U. K., Steimer, S. S., Förster, J.-D., Ditas, F., Pöhlker, C., Rossignol, S., Passananti, M., Perrier, S., George, C., Shiraiwa, M., Berkemeier, T., Watts, B., and Ammann, M.: Visualizing reaction and diffusion in xanthan gum aerosol particles exposed to ozone, Phys. Chem. Chem. Phys., 21, 20613–20627, https://doi.org/10.1039/C9CP03731D, 2019. 
Anonymous Referee: Interactive comment on “Mass Accommodation and Gas-Particle Partitioning in Secondary Organic Aerosols: Dependence on Diffusivity, Volatility, Particle-phase Reactions, and Penetration Depth” by Manabu Shiraiwa and Ulrich Pöschl, Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-536-RC2, 2020. 
Aumont, B., Szopa, S., and Madronich, S.: Modelling the evolution of organic carbon during its gas-phase tropospheric oxidation: development of an explicit model based on a self generating approach, Atmos. Chem. Phys., 5, 2497–2517, https://doi.org/10.5194/acp-5-2497-2005, 2005. 
Badali, K. M., Zhou, S., Aljawhary, D., Antiñolo, M., Chen, W. J., Lok, A., Mungall, E., Wong, J. P. S., Zhao, R., and Abbatt, J. P. D.: Formation of hydroxyl radicals from photolysis of secondary organic aerosol material, Atmos. Chem. Phys., 15, 7831–7840, https://doi.org/10.5194/acp-15-7831-2015, 2015. 
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Mass accommodation is a crucial process in secondary organic aerosol partitioning that depends on volatility, diffusivity, reactivity, and particle penetration depth of the chemical species involved. For efficient kinetic modeling, we introduce an effective mass accommodation coefficient that accounts for the above influencing factors, can be applied in the common Fuchs–Sutugin approximation, and helps to resolve inconsistencies and shortcomings of earlier experimental and model investigations.
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