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Stable isotopes of Carbon Monoxide (CO) and radiocarbon carbon dioxide were measured over three summers at Indianapolis, Indiana, US, and for 1 year at a site thought to be strongly influenced by CO from oxidized volatile organic compounds (VOCs) in South Carolina, US. The Indianapolis results were used to provide an estimate of the carbon and oxygen isotopic signatures of CO produced from oxidized VOCs. This updated estimate agrees well with the data from South Carolina during the summer.
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ACP | Articles | Volume 19, issue 13
Atmos. Chem. Phys., 19, 8547–8562, 2019
https://doi.org/10.5194/acp-19-8547-2019
Atmos. Chem. Phys., 19, 8547–8562, 2019
https://doi.org/10.5194/acp-19-8547-2019

Research article 05 Jul 2019

Research article | 05 Jul 2019

An improved estimate for the δ13C and δ18O signatures of carbon monoxide produced from atmospheric oxidation of volatile organic compounds

Isaac J. Vimont et al.

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Cited articles

Atkinson, R.: Atmospheric chemistry of VOCs and NOx, Atmos. Environ., 34, 2063–2101, https://doi.org/10.1016/s1352-2310(99)00460-4, 2000. 
Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review, Atmos. Environ., 37, 197–219, https://doi.org/10.1016/S1352-2310(03)00391-1, 2003a. 
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003b. 
Bergamaschi, P., Brenninkmeijer, C. A. M., Hahn, M., Röckmann, T., Scharffe, D. H., Crutzen, P. J., Elansky, N. F., Belikov, I. B., Trivett, N. B. A., and Worthy, D. E. J.: Isotope analysis based source identification for atmospheric CH4 and CO sampled across Russia using the Trans-Siberian railroad, J. Geophys. Res.-Atmos., 103, 8227–8235, https://doi.org/10.1029/97jd03738, 1998. 
Bergamaschi, P., Hein, R., Brenninkmeijer, C. A. M., and Crutzen, P. J.: Inverse modeling of the global CO cycle 2, Inversion of 13C/12C and 18O/16O isotope ratios, J. Geophys. Res., 105, 1929–1945, 2000. 
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Short summary
Stable isotopes of Carbon Monoxide (CO) and radiocarbon carbon dioxide were measured over three summers at Indianapolis, Indiana, US, and for 1 year at a site thought to be strongly influenced by CO from oxidized volatile organic compounds (VOCs) in South Carolina, US. The Indianapolis results were used to provide an estimate of the carbon and oxygen isotopic signatures of CO produced from oxidized VOCs. This updated estimate agrees well with the data from South Carolina during the summer.
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