Articles | Volume 18, issue 2
https://doi.org/10.5194/acp-18-979-2018
https://doi.org/10.5194/acp-18-979-2018
Research article
 | 
25 Jan 2018
Research article |  | 25 Jan 2018

Atmospheric histories and emissions of chlorofluorocarbons CFC-13 (CClF3), ΣCFC-114 (C2Cl2F4), and CFC-115 (C2ClF5)

Martin K. Vollmer, Dickon Young, Cathy M. Trudinger, Jens Mühle, Stephan Henne, Matthew Rigby, Sunyoung Park, Shanlan Li, Myriam Guillevic, Blagoj Mitrevski, Christina M. Harth, Benjamin R. Miller, Stefan Reimann, Bo Yao, L. Paul Steele, Simon A. Wyss, Chris R. Lunder, Jgor Arduini, Archie McCulloch, Songhao Wu, Tae Siek Rhee, Ray H. J. Wang, Peter K. Salameh, Ove Hermansen, Matthias Hill, Ray L. Langenfelds, Diane Ivy, Simon O'Doherty, Paul B. Krummel, Michela Maione, David M. Etheridge, Lingxi Zhou, Paul J. Fraser, Ronald G. Prinn, Ray F. Weiss, and Peter G. Simmonds

Related authors

Increasing emissions of HCFC-123 and HCFC-124 may be due to leakage during HFC-125 production
Luke M. Western, Stephen Bourguet, Molly Crotwell, Lei Hu, Paul B. Krummel, Hélène De Longueville, Alistair J. Mainning, Jens Mühle, Dominique Rust, Isaac Vimont, Martin K. Vollmer, Minde An, Jgor Arduini, Andreas Engel, Paul J. Fraser, Anita L. Ganesan, Christina M. Harth, Chris Lunder, Michela Maione, Stephen A. Montzka, David Nance, Simon O’Doherty, Sunyoung Park, Stefan Reimann, Peter K. Salameh, Roland Schmidt, Kieran M. Stanley, Thomas Wagenhäuser, Dickon Young, Matt Rigby, Ronald G. Prinn, and Ray F. Weiss
EGUsphere, https://doi.org/10.5194/egusphere-2025-3000,https://doi.org/10.5194/egusphere-2025-3000, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Trifluoroacetate (TFA) in Precipitation and Surface Waters in Switzerland: Trends, Source Attribution, and Budget
Stephan Henne, Florian R. Storck, Henry Wöhrnschimmel, Markus Leuenberger, Martin K. Vollmer, and Stefan Reimann
EGUsphere, https://doi.org/10.5194/egusphere-2025-2861,https://doi.org/10.5194/egusphere-2025-2861, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Global Emissions and Abundances of Chemically and Radiatively Important Trace Gases from the AGAGE Network
Luke M. Western, Matthew Rigby, Jens Mühle, Paul B. Krummel, Chris R. Lunder, Simon O'Doherty, Stefan Reimann, Martin K. Vollmer, Dickon Young, Ben Adam, Paul J. Fraser, Anita L. Ganesan, Christina M. Harth, Ove Hermansen, Jooil Kim, Ray L. Langenfelds, Zoë M. Loh, Blagoj Mitrevski, Joseph R. Pitt, Peter K. Salameh, Roland Schmidt, Kieran Stanley, Ann R. Stavert, Hsiang-Jui Wang, Ray F. Weiss, and Ronald G. Prinn
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-348,https://doi.org/10.5194/essd-2025-348, 2025
Preprint under review for ESSD
Short summary
Towards a high-quality in situ observation network for oxygenated volatile organic compounds (OVOCs) in Europe: transferring metrological traceability to the field
Maitane Iturrate-Garcia, Thérèse Salameh, Paul Schlauri, Annarita Baldan, Martin K. Vollmer, Evdokia Stratigou, Sebastien Dusanter, Jianrong Li, Stefan Persijn, Anja Claude, Rupert Holzinger, Christophe Sutour, Tatiana Macé, Yasin Elshorbany, Andreas Ackermann, Céline Pascale, and Stefan Reimann
Atmos. Meas. Tech., 18, 371–403, https://doi.org/10.5194/amt-18-371-2025,https://doi.org/10.5194/amt-18-371-2025, 2025
Short summary
Estimation of the atmospheric hydroxyl radical oxidative capacity using multiple hydrofluorocarbons (HFCs)
Rona L. Thompson, Stephen A. Montzka, Martin K. Vollmer, Jgor Arduini, Molly Crotwell, Paul B. Krummel, Chris Lunder, Jens Mühle, Simon O'Doherty, Ronald G. Prinn, Stefan Reimann, Isaac Vimont, Hsiang Wang, Ray F. Weiss, and Dickon Young
Atmos. Chem. Phys., 24, 1415–1427, https://doi.org/10.5194/acp-24-1415-2024,https://doi.org/10.5194/acp-24-1415-2024, 2024
Short summary

Related subject area

Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Volatile organic compound sources and impacts in an urban Mediterranean area (Marseille, France)
Marvin Dufresne, Thérèse Salameh, Thierry Leonardis, Grégory Gille, Alexandre Armengaud, and Stéphane Sauvage
Atmos. Chem. Phys., 25, 5977–5999, https://doi.org/10.5194/acp-25-5977-2025,https://doi.org/10.5194/acp-25-5977-2025, 2025
Short summary
Short-lived organic nitrates in a suburban temperate forest: an indication of efficient assimilation of reactive nitrogen by the biosphere?
Simone T. Andersen, Rolf Sander, Patrick Dewald, Laura Wüst, Tobias Seubert, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Chaoyang Xue, Abdelwahid Mellouki, Alexandre Kukui, Vincent Michoud, Manuela Cirtog, Mathieu Cazaunau, Astrid Bauville, Hichem Bouzidi, Paola Formenti, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Christopher Cantrell, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 25, 5893–5909, https://doi.org/10.5194/acp-25-5893-2025,https://doi.org/10.5194/acp-25-5893-2025, 2025
Short summary
Spatiotemporal variations in atmospheric CH4 concentrations and enhancements in northern China based on a comprehensive dataset: ground-based observations, TROPOMI data, inventory data, and inversions
Pengfei Han, Ning Zeng, Bo Yao, Wen Zhang, Weijun Quan, Pucai Wang, Ting Wang, Minqiang Zhou, Qixiang Cai, Yuzhong Zhang, Ruosi Liang, Wanqi Sun, and Shengxiang Liu
Atmos. Chem. Phys., 25, 4965–4988, https://doi.org/10.5194/acp-25-4965-2025,https://doi.org/10.5194/acp-25-4965-2025, 2025
Short summary
Marine emissions and trade winds control the atmospheric nitrous oxide in the Galapagos Islands
Timur Cinay, Dickon Young, Nazaret Narváez Jimenez, Cristina Vintimilla-Palacios, Ariel Pila Alonso, Paul B. Krummel, William Vizuete, and Andrew R. Babbin
Atmos. Chem. Phys., 25, 4703–4718, https://doi.org/10.5194/acp-25-4703-2025,https://doi.org/10.5194/acp-25-4703-2025, 2025
Short summary
Measurement report: A complex street-level air quality observation campaign in a heavy-traffic area utilizing the multivariate adaptive regression splines method for field calibration of low-cost sensors
Petra Bauerová, Josef Keder, Adriana Šindelářová, Ondřej Vlček, William Patiño, Pavel Krč, Jan Geletič, Hynek Řezníček, Martin Bureš, Kryštof Eben, Michal Belda, Jelena Radović, Vladimír Fuka, Radek Jareš, Igor Esau, and Jaroslav Resler
Atmos. Chem. Phys., 25, 4477–4504, https://doi.org/10.5194/acp-25-4477-2025,https://doi.org/10.5194/acp-25-4477-2025, 2025
Short summary

Cited articles

Azzali, D. and Basile, G.: Purification process of pentafluoroethane (HFC-125), EP Patent 1 153 907, available at: https://www.google.com/patents/EP1153907B1?cl=un (last access: 6 December 2017), 2004.
Baasandorj, M., Feierabend, K. J., and Burkholder, J. B.: Rate coefficients and ClO radical yields in the reaction of O(1D) with CClF2CCl2F, CCl3CF3, CClF2CClF2, and CCl2FCF3, Int. J. Chem. Kinet., 43, 393–401, https://doi.org/10.1002/kin.20561, 2011.
Baasandorj, M., Fleming, E. L., Jackman, C. H., and Burkholder, J. B.: O(1D) kinetic study of key ozone depleting substances and greenhouse gases, J. Phys. Chem. A, 117, 2434–2445, https://doi.org/10.1021/jp312781c, 2013.
Banks, R. E. and Sharratt, P. N.: Environmental Impacts of the Manufacture of HFC-134a, Tech. rep., Department of Chemistry and Department of Chemical Engineering, UMIST, Manchester, 1996.
Brandstater, S. M., Cohn, M., Hedrick, V. E., and Iikubo, Y.: Processes for purification and production of fluorocarbons, US Patent App. 10/075 560, available at: https://www.google.ch/patents/US20030164283 (last access: 6 December 2017), 2003.
Download
Short summary
We measured the three chlorofluorocarbons (CFCs) CFC-13, CFC-114, and CFC-115 in the atmosphere because they are important in stratospheric ozone depletion. These compounds should have decreased in the atmosphere because they are banned by the Montreal Protocol but we find the opposite. Emissions over the last decade have not declined on a global scale. We use inverse modeling and our observations to find that a large part of the emissions originate in the Asian region.
Share
Altmetrics
Final-revised paper
Preprint