Articles | Volume 14, issue 19
Atmos. Chem. Phys., 14, 10465–10482, 2014
https://doi.org/10.5194/acp-14-10465-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue: The Modular Earth Submodel System (MESSy) (ACP/GMD inter-journal...
Atmos. Chem. Phys., 14, 10465–10482, 2014
https://doi.org/10.5194/acp-14-10465-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article 01 Oct 2014
Research article | 01 Oct 2014
Model-simulated trend of surface carbon monoxide for the 2001–2010 decade
J. Yoon and A. Pozzer
Related authors
Narendra Ojha, Andrea Pozzer, Armin Rauthe-Schöch, Angela K. Baker, Jongmin Yoon, Carl A. M. Brenninkmeijer, and Jos Lelieveld
Atmos. Chem. Phys., 16, 3013–3032, https://doi.org/10.5194/acp-16-3013-2016, https://doi.org/10.5194/acp-16-3013-2016, 2016
Short summary
Short summary
We compare simulations of ozone and carbon monoxide using a regional chemistry transport model (WRF-Chem) with aircraft observations from CARIBIC program over India during monsoon period. Sensitivity simulations are conducted to assess the influences of regional emissions and long-range transport.
A. Pozzer, A. de Meij, J. Yoon, H. Tost, A. K. Georgoulias, and M. Astitha
Atmos. Chem. Phys., 15, 5521–5535, https://doi.org/10.5194/acp-15-5521-2015, https://doi.org/10.5194/acp-15-5521-2015, 2015
Short summary
Short summary
Thanks to numerical simulations and satellite observations, it is shown that aerosol optical depth (AOD) trends (2000--2010 period) over the US and Europe are due to emission decrease, while over the Sahara Desert and the Middle East they are due to meteorological changes. Over Southeast Asia, both meteorology and emission changes are important for the AOD trends.
It is shown that soluble components strongly influence AOD, as their contribution is enhanced by the aerosol water content.
J. Yoon, A. Pozzer, P. Hoor, D. Y. Chang, S. Beirle, T. Wagner, S. Schloegl, J. Lelieveld, and H. M. Worden
Atmos. Chem. Phys., 13, 11307–11316, https://doi.org/10.5194/acp-13-11307-2013, https://doi.org/10.5194/acp-13-11307-2013, 2013
Ovid Oktavian Krüger, Bruna A. Holanda, Sourangsu Chowdhury, Andrea Pozzer, David Walter, Christopher Pöhlker, Maria Dolores Andrés Hernández, John Phillip Burrows, Christiane Voigt, Jos Lelieveld, Johannes Quaas, Ulrich Pöschl, and Mira L. Pöhlker
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-1100, https://doi.org/10.5194/acp-2021-1100, 2022
Preprint under review for ACP
Short summary
Short summary
The abrupt reduction in human activities during the first COVID-19 lockdown created unprecedented atmospheric conditions. We took the opportunity to quantify changes in black carbon (BC) as a major anthropogenic air pollutant. Therefore, we measured BC onboard a research aircraft over Europe during the lockdown and compared the results to measurements from 2017. With model simulations we account for different weather conditions and find a lockdown-related decrease in BC of 40 %.
Guangjie Zheng, Hang Su, Siwen Wang, Andrea Pozzer, and Yafang Cheng
Atmos. Chem. Phys., 22, 47–63, https://doi.org/10.5194/acp-22-47-2022, https://doi.org/10.5194/acp-22-47-2022, 2022
Short summary
Short summary
The recently proposed multiphase buffer theory provides a framework to reconstruct long-term trends and spatial variations in aerosol pH, while non-ideality is a major limitation for its broad applications. Here we proposed a parameterization method to estimate the impact of non-ideality and validated it against long-term observations and global simulations. With this method, the multiphase buffer theory can reproduce well aerosol pH variations estimated by comprehensive thermodynamic models.
Dimitris Akritidis, Andrea Pozzer, Johannes Flemming, Antje Inness, Philippe Nédélec, and Prodromos Zanis
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-998, https://doi.org/10.5194/acp-2021-998, 2021
Preprint under review for ACP
Short summary
Short summary
We perform a process-oriented evaluation of Copernicus Atmosphere Monitoring Service (CAMS) reanalysis (CAMSRA) O3 over Europe, using WOUDC (World Ozone and Ultraviolet Radiation Data Centre) ozonesondes and IAGOS (In-service Aircraft for a Global Observing System) aircraft measurements. Chemical data assimilation assists CAMSRA to reproduce the observed O3 increases in the troposphere during the examined folding events, yet it mostly results in O3 overestimation in the upper troposphere.
Clara M. Nussbaumer, Andrea Pozzer, Ivan Tadic, Lenard Röder, Florian Obersteiner, Hartwig Harder, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-1028, https://doi.org/10.5194/acp-2021-1028, 2021
Preprint under review for ACP
Short summary
Short summary
The European COVID-19 lockdowns have significantly reduced the emission of primary pollutants such as NOx which impacts the tropospheric photochemical processes and the abundance of O3. In this study, we present how the lockdowns have affected tropospheric trace gases and ozone production based on in situ observations and modeling simulations. We additionally show that the chemical regime shifted from a transition point to a NOx limitation in the upper troposphere.
Simon Felix Reifenberg, Anna Martin, Matthias Kohl, Zaneta Hamryszczak, Ivan Tadic, Lenard Röder, Daniel J. Crowley, Horst Fischer, Katharina Kaiser, Johannes Schneider, Raphael Dörich, John N. Crowley, Laura Tomsche, Andreas Marsing, Christiane Voigt, Andreas Zahn, Christopher Pöhlker, Bruna Holanda, Ovid O. Krüger, Ulrich Pöschl, Mira Pöhlker, Patrick Jöckel, Marcel Dorf, Ulrich Schumann, Jonathan Williams, Joachim Curtius, Hardwig Harder, Hans Schlager, Jos Lelieveld, and Andrea Pozzer
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-1005, https://doi.org/10.5194/acp-2021-1005, 2021
Preprint under review for ACP
Short summary
Short summary
In this work we use a combination of observational data from an aircraft campaign and model results to investigate the effect of the European lockdown due to COVID-19 in spring 2020. Using model results, we show that the largest relative changes to the atmospheric composition caused by the reduced emissionsare located in the upper troposphere, around the aircraft cruise altitude, while largest absolute changes are present at the surface.
Vlassis A. Karydis, Alexandra P. Tsimpidi, Andrea Pozzer, and Jos Lelieveld
Atmos. Chem. Phys., 21, 14983–15001, https://doi.org/10.5194/acp-21-14983-2021, https://doi.org/10.5194/acp-21-14983-2021, 2021
Short summary
Short summary
Aerosol particle pH is well-buffered by alkaline compounds, notably NH3 and crustal elements. NH3 is found to supply remarkable buffering capacity on a global scale, from the polluted continents to the remote oceans. Potential future changes in agricultural NH3 must be accompanied by strong reductions of SO2 and NOx to avoid particles becoming highly acidic, with implications for human health (aerosol toxicity), ecosystems (acid deposition), clouds, and climate (aerosol hygroscopicity).
Andrea Pozzer
Geosci. Commun., 4, 453–460, https://doi.org/10.5194/gc-4-453-2021, https://doi.org/10.5194/gc-4-453-2021, 2021
Short summary
Short summary
In this paper we investigate the numbers of pages, references and references per page in open-access EGU journals. We showed that, while the number of references and number of pages have been constantly increasing in the period 2010–2020, the number of references per page did not change in the same period. Furthermore, all the journals showed a similar number of references per page, i.e. ~ 3.8 references per page.
Andrea Pozzer, Simon Reifenberg, Vinod Kumar, Bruno Franco, Domenico Taraborrelli, Sergy Gromov, Sebastian Ehrhart, Patrick Jöckel, Rolf Sander, Veronica Fall, Simon Rosanka, Vlassis Karydis, Dimitris Akritidis, Tamara Emmerichs, Monica Crippa, Diego Guizzardi, Johannes W. Kaiser, Lieven Clarisse, Astrid Kiendler-Scharr, Holger Tost, and Alexandra Tsimpidi
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2021-295, https://doi.org/10.5194/gmd-2021-295, 2021
Revised manuscript under review for GMD
Short summary
Short summary
A newly developed set-up of the chemistry general circulation model EMAC (ECHAM5/MESSy for Atmospheric Chemistry) is here evaluated; a comprehensive organic degradation mechanism is used and coupled with a volatility base model. The results show that the model is reproducing most of the tracer and aerosols satisfactorily, although with discrepancies for oxygenated organic gases and that this model configuration can be used for further research in atmospheric chemistry.
Philipp G. Eger, Luc Vereecken, Rolf Sander, Jan Schuladen, Nicolas Sobanski, Horst Fischer, Einar Karu, Jonathan Williams, Ville Vakkari, Tuukka Petäjä, Jos Lelieveld, Andrea Pozzer, and John N. Crowley
Atmos. Chem. Phys., 21, 14333–14349, https://doi.org/10.5194/acp-21-14333-2021, https://doi.org/10.5194/acp-21-14333-2021, 2021
Short summary
Short summary
We determine the impact of pyruvic acid photolysis on the formation of acetaldehyde and peroxy radicals during summer and autumn in the Finnish boreal forest using a data-constrained box model. Our results are dependent on the chosen scenario in which the overall quantum yield and the photolysis products are varied. We highlight that pyruvic acid photolysis can be an important contributor to acetaldehyde and peroxy radical formation in remote, forested regions.
Mengze Li, Andrea Pozzer, Jos Lelieveld, and Jonathan Williams
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2021-246, https://doi.org/10.5194/essd-2021-246, 2021
Preprint under review for ESSD
Short summary
Short summary
We present a global airborne measurement dataset of atmospheric ethane, propane and methane and temporal trends for the time period 2006-2016 in the UTLS. The Copernicus CAMS-GLOB ethane emission inventory coupled with atmospheric model EMAC was optimized by the observational data with 12 ethane sectoral emission sources distinguished. The global ethane emission budget is estimated to be 19.28 Tg/yr for 2006–2016.
Vinod Kumar, Julia Remmers, Steffen Beirle, Joachim Fallmann, Astrid Kerkweg, Jos Lelieveld, Mariano Mertens, Andrea Pozzer, Benedikt Steil, Marc Barra, Holger Tost, and Thomas Wagner
Atmos. Meas. Tech., 14, 5241–5269, https://doi.org/10.5194/amt-14-5241-2021, https://doi.org/10.5194/amt-14-5241-2021, 2021
Short summary
Short summary
We present high-resolution regional atmospheric chemistry model simulations focused around Germany. We highlight the importance of spatial resolution of the model itself as well as the input emissions inventory and short-scale temporal variability of emissions for simulations. We propose a consistent approach for evaluating the simulated vertical distribution of NO2 using MAX-DOAS measurements while also considering its spatial sensitivity volume and change in sensitivity within this volume.
Simon Rosanka, Bruno Franco, Lieven Clarisse, Pierre-François Coheur, Andrea Pozzer, Andreas Wahner, and Domenico Taraborrelli
Atmos. Chem. Phys., 21, 11257–11288, https://doi.org/10.5194/acp-21-11257-2021, https://doi.org/10.5194/acp-21-11257-2021, 2021
Short summary
Short summary
The strong El Niño in 2015 led to a particular dry season in Indonesia and favoured severe peatland fires. The smouldering conditions of these fires and the high carbon content of peat resulted in high volatile organic compound (VOC) emissions. By using a comprehensive atmospheric model, we show that these emissions have a significant impact on the tropospheric composition and oxidation capacity. These emissions are transported into to the lower stratosphere, resulting in a depletion of ozone.
Tamara Emmerichs, Bruno Franco, Catherine Wespes, Vinod Kumar, Andrea Pozzer, Simon Rosanka, and Domenico Taraborrelli
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-584, https://doi.org/10.5194/acp-2021-584, 2021
Revised manuscript not accepted
Short summary
Short summary
Near-surface ozone is a harmful air pollutant and it is strongly affected by radical reactions and surface-atmosphere exchanges which in turn are modulated, directly and indirectly, by weather. Understanding the impact of weather on ozone, and air quality, is thus important also in view of weather extremes. The inclusion of additional ozone-weather links in the global model yields a 2-fold reduction of the ozone bias towards satellite observations.
Ivan Tadic, Clara M. Nussbaumer, Birger Bohn, Hartwig Harder, Daniel Marno, Monica Martinez, Florian Obersteiner, Uwe Parchatka, Andrea Pozzer, Roland Rohloff, Martin Zöger, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 21, 8195–8211, https://doi.org/10.5194/acp-21-8195-2021, https://doi.org/10.5194/acp-21-8195-2021, 2021
Short summary
Short summary
Although mechanisms of tropospheric ozone (O3) formation are well understood, studies reporting on ozone formation derived from field measurements are challenging and remain sparse in number. We use airborne measurements to quantify nitric oxide (NO) and O3 distributions in the upper troposphere over the Atlantic Ocean and western Africa and compare our measurements to model simulations. Our results show that NO and ozone formation are greatest over the tropical areas of western Africa.
Jaydeep Singh, Narendra Singh, Narendra Ojha, Amit Sharma, Andrea Pozzer, Nadimpally Kiran Kumar, Kunjukrishnapillai Rajeev, Sachin S. Gunthe, and V. Rao Kotamarthi
Geosci. Model Dev., 14, 1427–1443, https://doi.org/10.5194/gmd-14-1427-2021, https://doi.org/10.5194/gmd-14-1427-2021, 2021
Short summary
Short summary
Atmospheric models often have limitations in simulating the geographically complex and climatically important central Himalayan region. In this direction, we have performed regional modeling at high resolutions to improve the simulation of meteorology and dynamics through a better representation of the topography. The study has implications for further model applications to investigate the effects of anthropogenic pressure over the Himalaya.
Chaim I. Garfinkel, Ohad Harari, Shlomi Ziskin Ziv, Jian Rao, Olaf Morgenstern, Guang Zeng, Simone Tilmes, Douglas Kinnison, Fiona M. O'Connor, Neal Butchart, Makoto Deushi, Patrick Jöckel, Andrea Pozzer, and Sean Davis
Atmos. Chem. Phys., 21, 3725–3740, https://doi.org/10.5194/acp-21-3725-2021, https://doi.org/10.5194/acp-21-3725-2021, 2021
Short summary
Short summary
Water vapor is the dominant greenhouse gas in the atmosphere, and El Niño is the dominant mode of variability in the ocean–atmosphere system. The connection between El Niño and water vapor above ~ 17 km is unclear, with single-model studies reaching a range of conclusions. This study examines this connection in 12 different models. While there are substantial differences among the models, all models appear to capture the fundamental physical processes correctly.
Domenico Taraborrelli, David Cabrera-Perez, Sara Bacer, Sergey Gromov, Jos Lelieveld, Rolf Sander, and Andrea Pozzer
Atmos. Chem. Phys., 21, 2615–2636, https://doi.org/10.5194/acp-21-2615-2021, https://doi.org/10.5194/acp-21-2615-2021, 2021
Short summary
Short summary
Atmospheric pollutants from anthropogenic activities and biomass burning are usually regarded as ozone precursors. Monocyclic aromatics are no exception. Calculations with a comprehensive atmospheric model are consistent with this view but only for air masses close to pollution source regions. However, the same model predicts that aromatics, when transported to remote areas, may effectively destroy ozone. This loss of tropospheric ozone rivals the one attributed to bromine.
Sara Bacer, Sylvia C. Sullivan, Odran Sourdeval, Holger Tost, Jos Lelieveld, and Andrea Pozzer
Atmos. Chem. Phys., 21, 1485–1505, https://doi.org/10.5194/acp-21-1485-2021, https://doi.org/10.5194/acp-21-1485-2021, 2021
Short summary
Short summary
We investigate the relative importance of the rates of both microphysical processes and unphysical correction terms that act as sources or sinks of ice crystals in cold clouds. By means of numerical simulations performed with a global chemistry–climate model, we assess the relevance of these rates at global and regional scales. This estimation is of fundamental importance to assign priority to the development of microphysics parameterizations and compare model output with observations.
Bettina Hottmann, Sascha Hafermann, Laura Tomsche, Daniel Marno, Monica Martinez, Hartwig Harder, Andrea Pozzer, Marco Neumaier, Andreas Zahn, Birger Bohn, Greta Stratmann, Helmut Ziereis, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 20, 12655–12673, https://doi.org/10.5194/acp-20-12655-2020, https://doi.org/10.5194/acp-20-12655-2020, 2020
Short summary
Short summary
During OMO we observed enhanced mixing ratios of hydroperoxides (ROOH) in the Asian monsoon anticyclone (AMA) relative to the background. The observed mixing ratios are higher than steady-state calculations and EMAC simulations, especially in the AMA, indicating atmospheric transport of ROOH. Uncertainties in the scavenging efficiencies likely cause deviations from EMAC. Longitudinal gradients indicate a pool of ROOH towards the center of the AMA associated with upwind convection over India.
Nijing Wang, Achim Edtbauer, Christof Stönner, Andrea Pozzer, Efstratios Bourtsoukidis, Lisa Ernle, Dirk Dienhart, Bettina Hottmann, Horst Fischer, Jan Schuladen, John N. Crowley, Jean-Daniel Paris, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 20, 10807–10829, https://doi.org/10.5194/acp-20-10807-2020, https://doi.org/10.5194/acp-20-10807-2020, 2020
Short summary
Short summary
Carbonyl compounds were measured on a ship travelling around the Arabian Peninsula in summer 2017, crossing both highly polluted and extremely clean regions of the marine boundary layer. We investigated the sources and sinks of carbonyls. The results from a global model showed a significant model underestimation for acetaldehyde, a molecule that can influence regional air chemistry. By adding a diurnal oceanic source, the model estimation was highly improved.
Ivan Tadic, John N. Crowley, Dirk Dienhart, Philipp Eger, Hartwig Harder, Bettina Hottmann, Monica Martinez, Uwe Parchatka, Jean-Daniel Paris, Andrea Pozzer, Roland Rohloff, Jan Schuladen, Justin Shenolikar, Sebastian Tauer, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 20, 6769–6787, https://doi.org/10.5194/acp-20-6769-2020, https://doi.org/10.5194/acp-20-6769-2020, 2020
Short summary
Short summary
We present shipborne observations of NO, NO2, O3, HCHO, OH, HO2, H2O and the actinic flux obtained in the marine boundary layer (MBL) around the Arabian Peninsula during the summer 2017 AQABA ship campaign. NOx (NO+NO2) and O3 observations clearly showed anthropogenic influence in the MBL around the Arabian Peninsula. The observations were also used to calculate net O3 production in the MBL around the Arabian Peninsula, which was greatest over the northern Red Sea, Oman Gulf and Arabian Gulf.
Peter H. Zimmermann, Carl A. M. Brenninkmeijer, Andrea Pozzer, Patrick Jöckel, Franziska Winterstein, Andreas Zahn, Sander Houweling, and Jos Lelieveld
Atmos. Chem. Phys., 20, 5787–5809, https://doi.org/10.5194/acp-20-5787-2020, https://doi.org/10.5194/acp-20-5787-2020, 2020
Short summary
Short summary
The atmospheric abundance of the greenhouse gas methane is determined by interacting emission sources and sinks in a dynamic global environment. In this study, its global budget from 1997 to 2016 is simulated with a general circulation model using emission estimates of 11 source categories. The model results are evaluated against 17 ground station and 320 intercontinental flight observation series. Deviations are used to re-scale the emission quantities with the aim of matching observations.
Damien Amedro, Matias Berasategui, Arne J. C. Bunkan, Andrea Pozzer, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 20, 3091–3105, https://doi.org/10.5194/acp-20-3091-2020, https://doi.org/10.5194/acp-20-3091-2020, 2020
Short summary
Short summary
Our laboratory experiments show that the rate coefficient for the termolecular reaction between OH and NO2 is enhanced in the presence of water vapour. Using a chemistry transport model we show that our new parameterization of the temperature, pressure, and bath-gas dependence of this reaction has a significant impact on, for example, NOx and the HNO2 / NO2 ratio when compared to present recommendations.
Julie M. Nicely, Bryan N. Duncan, Thomas F. Hanisco, Glenn M. Wolfe, Ross J. Salawitch, Makoto Deushi, Amund S. Haslerud, Patrick Jöckel, Béatrice Josse, Douglas E. Kinnison, Andrew Klekociuk, Michael E. Manyin, Virginie Marécal, Olaf Morgenstern, Lee T. Murray, Gunnar Myhre, Luke D. Oman, Giovanni Pitari, Andrea Pozzer, Ilaria Quaglia, Laura E. Revell, Eugene Rozanov, Andrea Stenke, Kane Stone, Susan Strahan, Simone Tilmes, Holger Tost, Daniel M. Westervelt, and Guang Zeng
Atmos. Chem. Phys., 20, 1341–1361, https://doi.org/10.5194/acp-20-1341-2020, https://doi.org/10.5194/acp-20-1341-2020, 2020
Short summary
Short summary
Differences in methane lifetime among global models are large and poorly understood. We use a neural network method and simulations from the Chemistry Climate Model Initiative to quantify the factors influencing methane lifetime spread among models and variations over time. UV photolysis, tropospheric ozone, and nitrogen oxides drive large model differences, while the same factors plus specific humidity contribute to a decreasing trend in methane lifetime between 1980 and 2015.
Ying Chen, Yafang Cheng, Nan Ma, Chao Wei, Liang Ran, Ralf Wolke, Johannes Größ, Qiaoqiao Wang, Andrea Pozzer, Hugo A. C. Denier van der Gon, Gerald Spindler, Jos Lelieveld, Ina Tegen, Hang Su, and Alfred Wiedensohler
Atmos. Chem. Phys., 20, 771–786, https://doi.org/10.5194/acp-20-771-2020, https://doi.org/10.5194/acp-20-771-2020, 2020
Short summary
Short summary
Particulate nitrate is one of the most important climate cooling agents. Our results show that interaction with sea-salt aerosol can shift nitrate to larger sized particles (redistribution effect), weakening its direct cooling effect. The modelling results indicate strong redistribution over coastal and offshore regions worldwide as well as continental Europe. Improving the consideration of the redistribution effect in global models fosters a better understanding of climate change.
Dimitris Akritidis, Andrea Pozzer, and Prodromos Zanis
Atmos. Chem. Phys., 19, 14387–14401, https://doi.org/10.5194/acp-19-14387-2019, https://doi.org/10.5194/acp-19-14387-2019, 2019
Short summary
Short summary
We investigate the impact of future climate change under the RCP6.0 scenario on tropopause folds and tropospheric ozone, using a transient EMAC simulation and a tropopause fold detection algorithm. A strengthening of ozone stratosphere-to-troposphere transport (STT) is projected for the future, resulting in an increase in upper- and middle-tropospheric ozone. The maxima of future ozone STT increases are mainly projected for regions where tropopause folds are expected to occur more frequently.
Horst Fischer, Raoul Axinte, Heiko Bozem, John N. Crowley, Cheryl Ernest, Stefan Gilge, Sascha Hafermann, Hartwig Harder, Korbinian Hens, Ruud H. H. Janssen, Rainer Königstedt, Dagmar Kubistin, Chinmay Mallik, Monica Martinez, Anna Novelli, Uwe Parchatka, Christian Plass-Dülmer, Andrea Pozzer, Eric Regelin, Andreas Reiffs, Torsten Schmidt, Jan Schuladen, and Jos Lelieveld
Atmos. Chem. Phys., 19, 11953–11968, https://doi.org/10.5194/acp-19-11953-2019, https://doi.org/10.5194/acp-19-11953-2019, 2019
Short summary
Short summary
We use in situ observations of H2O2 to study the interplay between photochemistry, transport and deposition processes. The data were obtained during five ground-based field campaigns across Europe. A budget calculation indicates that the photochemical production rate was much larger than photochemical loss and that dry deposition is the dominant loss process. To reproduce the change in H2O2 mixing ratios after sunrise, a variable contribution of entrainment from the residual layer is required.
Jianzhong Ma, Christoph Brühl, Qianshan He, Benedikt Steil, Vlassis A. Karydis, Klaus Klingmüller, Holger Tost, Bin Chen, Yufang Jin, Ningwei Liu, Xiangde Xu, Peng Yan, Xiuji Zhou, Kamal Abdelrahman, Andrea Pozzer, and Jos Lelieveld
Atmos. Chem. Phys., 19, 11587–11612, https://doi.org/10.5194/acp-19-11587-2019, https://doi.org/10.5194/acp-19-11587-2019, 2019
Short summary
Short summary
We find a pronounced maximum in aerosol extinction in the upper troposphere and lower stratosphere over the Tibetan Plateau during the Asian summer monsoon, caused mainly by mineral dust emitted from the northern Tibetan Plateau and slope area, lofted to and accumulating within the anticyclonic circulation. Mineral dust, water-soluble compounds, such as nitrate and sulfate, and associated liquid water dominate aerosol extinction around the tropopause within the Asian summer monsoon anticyclone.
Ohad Harari, Chaim I. Garfinkel, Shlomi Ziskin Ziv, Olaf Morgenstern, Guang Zeng, Simone Tilmes, Douglas Kinnison, Makoto Deushi, Patrick Jöckel, Andrea Pozzer, Fiona M. O'Connor, and Sean Davis
Atmos. Chem. Phys., 19, 9253–9268, https://doi.org/10.5194/acp-19-9253-2019, https://doi.org/10.5194/acp-19-9253-2019, 2019
Short summary
Short summary
Ozone depletion in the Antarctic has been shown to influence surface conditions, but the effects of ozone depletion in the Arctic on surface climate are unclear. We show that Arctic ozone does influence surface climate in both polar regions and tropical regions, though the proximate cause of these surface impacts is not yet clear.
Efstratios Bourtsoukidis, Lisa Ernle, John N. Crowley, Jos Lelieveld, Jean-Daniel Paris, Andrea Pozzer, David Walter, and Jonathan Williams
Atmos. Chem. Phys., 19, 7209–7232, https://doi.org/10.5194/acp-19-7209-2019, https://doi.org/10.5194/acp-19-7209-2019, 2019
Short summary
Short summary
We report on results that demonstrate the utility of non-methane hydrocarbons as source/sink identification tracers while providing their mixing ratios around the Arabian Peninsula. By introducing novel data-analysis approaches, we establish a new method for separating associated and non-associated (with liquids) gases. We formulate a relationship between hydrocarbon oxidative pairs that can be used to evaluate the relative abundance of the hydroxyl and chlorine radicals in the troposphere.
Vincent Huijnen, Andrea Pozzer, Joaquim Arteta, Guy Brasseur, Idir Bouarar, Simon Chabrillat, Yves Christophe, Thierno Doumbia, Johannes Flemming, Jonathan Guth, Béatrice Josse, Vlassis A. Karydis, Virginie Marécal, and Sophie Pelletier
Geosci. Model Dev., 12, 1725–1752, https://doi.org/10.5194/gmd-12-1725-2019, https://doi.org/10.5194/gmd-12-1725-2019, 2019
Short summary
Short summary
We report on an evaluation of tropospheric ozone and its precursor gases in three atmospheric chemistry versions as implemented in ECMWF’s Integrated Forecasting System (IFS), referred to as IFS(CB05BASCOE), IFS(MOZART) and IFS(MOCAGE). This configuration of having various chemistry versions within IFS provides a quantification of uncertainties in CAMS trace gas products that are induced by chemistry modelling.
Meryem Tanarhte, Sara Bacer, Susannah M. Burrows, J. Alex Huffman, Kyle M. Pierce, Andrea Pozzer, Roland Sarda-Estève, Nicole J. Savage, and Jos Lelieveld
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-251, https://doi.org/10.5194/acp-2019-251, 2019
Publication in ACP not foreseen
Short summary
Short summary
Bioaerosols have been an important topic in atmospheric science in the last two decades. This paper compares different emission parametrizations used in fungal spores modeling and compare their results to two sets of new observational datasets. It emphasises their uncertainties in order to improve their modeling in the future. This comparison is addressed primarily to the scientific community (publishing in ACP) interested in this type of modeling and the related experimental work in this field.
Rolf Sander, Andreas Baumgaertner, David Cabrera-Perez, Franziska Frank, Sergey Gromov, Jens-Uwe Grooß, Hartwig Harder, Vincent Huijnen, Patrick Jöckel, Vlassis A. Karydis, Kyle E. Niemeyer, Andrea Pozzer, Hella Riede, Martin G. Schultz, Domenico Taraborrelli, and Sebastian Tauer
Geosci. Model Dev., 12, 1365–1385, https://doi.org/10.5194/gmd-12-1365-2019, https://doi.org/10.5194/gmd-12-1365-2019, 2019
Short summary
Short summary
We present the atmospheric chemistry box model CAABA/MECCA which
now includes a number of new features: skeletal mechanism
reduction, the MOM chemical mechanism for volatile organic
compounds, an option to include reactions from the Master
Chemical Mechanism (MCM) and other chemical mechanisms, updated
isotope tagging, improved and new photolysis modules, and the new
feature of coexisting multiple chemistry mechanisms.
CAABA/MECCA is a community model published under the GPL.
Laura Tomsche, Andrea Pozzer, Narendra Ojha, Uwe Parchatka, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 19, 1915–1939, https://doi.org/10.5194/acp-19-1915-2019, https://doi.org/10.5194/acp-19-1915-2019, 2019
Short summary
Short summary
The Asian monsoon anticyclone (AMA) is an annual phenomenon in the northern hemispheric upper troposphere (UT) and lower stratosphere. We performed in situ measurements of carbon monoxide (CO) and methane (CH4) in the monsoon outflow region and in background air in the UT (Mediterranean, Arabian Peninsula, Arabian Sea) using airborne optical absorption spectroscopy during the Oxidation Mechanism Observations mission (summer 2015). The trace gases increased within the AMA, particularly CH4.
Yingying Yan, David Cabrera-Perez, Jintai Lin, Andrea Pozzer, Lu Hu, Dylan B. Millet, William C. Porter, and Jos Lelieveld
Geosci. Model Dev., 12, 111–130, https://doi.org/10.5194/gmd-12-111-2019, https://doi.org/10.5194/gmd-12-111-2019, 2019
Short summary
Short summary
The GEOS-Chem model has been updated with the SAPRC-11 aromatics chemical mechanism to evaluate global and regional effects of aromatics on tropospheric oxidation capacity. Our results reveal relatively slight changes in ozone, hydroxyl radical, and nitrogen oxides on a global mean basis (1–4 %), although remarkable regional differences (5–20 %) exist near the source regions. Improved representation of aromatics is important to simulate the tropospheric oxidation.
Sebastian Ehrhart, Eimear M. Dunne, Hanna E. Manninen, Tuomo Nieminen, Jos Lelieveld, and Andrea Pozzer
Geosci. Model Dev., 11, 4987–5001, https://doi.org/10.5194/gmd-11-4987-2018, https://doi.org/10.5194/gmd-11-4987-2018, 2018
Sara Bacer, Sylvia C. Sullivan, Vlassis A. Karydis, Donifan Barahona, Martina Krämer, Athanasios Nenes, Holger Tost, Alexandra P. Tsimpidi, Jos Lelieveld, and Andrea Pozzer
Geosci. Model Dev., 11, 4021–4041, https://doi.org/10.5194/gmd-11-4021-2018, https://doi.org/10.5194/gmd-11-4021-2018, 2018
Short summary
Short summary
The complexity of ice nucleation mechanisms and aerosol--ice interactions makes their representation still challenging in atmospheric models. We have implemented a comprehensive ice crystal formation parameterization in the global chemistry-climate model EMAC to improve the representation of ice crystal number concentrations. The newly implemented parameterization takes into account processes which were previously neglected by the standard version of the model.
Alexandra P. Tsimpidi, Vlassis A. Karydis, Andrea Pozzer, Spyros N. Pandis, and Jos Lelieveld
Geosci. Model Dev., 11, 3369–3389, https://doi.org/10.5194/gmd-11-3369-2018, https://doi.org/10.5194/gmd-11-3369-2018, 2018
Short summary
Short summary
A new module, ORACLE 2-D, that calculates the concentrations of surrogate organic species in two-dimensional space defined by volatility and oxygen-to-carbon ratio has been developed and evaluated. ORACLE 2-D uses a simple photochemical aging scheme that efficiently simulates the net effects of fragmentation and functionalization. ORACLE 2-D can be used to compute the ability of organic particles to act as cloud condensation nuclei and serves as a tool to quantify their climatic impact.
Maarten Krol, Marco de Bruine, Lars Killaars, Huug Ouwersloot, Andrea Pozzer, Yi Yin, Frederic Chevallier, Philippe Bousquet, Prabir Patra, Dmitry Belikov, Shamil Maksyutov, Sandip Dhomse, Wuhu Feng, and Martyn P. Chipperfield
Geosci. Model Dev., 11, 3109–3130, https://doi.org/10.5194/gmd-11-3109-2018, https://doi.org/10.5194/gmd-11-3109-2018, 2018
Short summary
Short summary
The TransCom inter-comparison project regularly carries out studies to quantify errors in simulated atmospheric transport. This paper presents the first results of an age of air (AoA) inter-comparison of six global transport models. Following a protocol, six models simulated five tracers from which atmospheric transport times can easily be deduced. Results highlight that inter-model differences associated with atmospheric transport are still large and require further analysis.
Chinmay Mallik, Laura Tomsche, Efstratios Bourtsoukidis, John N. Crowley, Bettina Derstroff, Horst Fischer, Sascha Hafermann, Imke Hüser, Umar Javed, Stephan Keßel, Jos Lelieveld, Monica Martinez, Hannah Meusel, Anna Novelli, Gavin J. Phillips, Andrea Pozzer, Andreas Reiffs, Rolf Sander, Domenico Taraborrelli, Carina Sauvage, Jan Schuladen, Hang Su, Jonathan Williams, and Hartwig Harder
Atmos. Chem. Phys., 18, 10825–10847, https://doi.org/10.5194/acp-18-10825-2018, https://doi.org/10.5194/acp-18-10825-2018, 2018
Short summary
Short summary
OH and HO2 control the transformation of air pollutants and O3 formation. Their implication for air quality over the climatically sensitive Mediterranean region was studied during a field campaign in Cyprus. Production of OH, HO2, and recycled OH was lower in aged marine air masses. Box model simulations of OH and HO2 agreed with measurements except at high terpene concentrations when model RO2 due to terpenes caused large HO2 loss. Autoxidation schemes for RO2 improved the agreement.
Meryem Tanarhte, Sara Bacer, Susannah M. Burrows, J. Alex Huffman, Kyle M. Pierce, Andrea Pozzer, Roland Sarda-Estève, Nicole J. Savage, and Jos Lelieveld
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-361, https://doi.org/10.5194/acp-2018-361, 2018
Revised manuscript not accepted
Yingying Yan, Andrea Pozzer, Narendra Ojha, Jintai Lin, and Jos Lelieveld
Atmos. Chem. Phys., 18, 5589–5605, https://doi.org/10.5194/acp-18-5589-2018, https://doi.org/10.5194/acp-18-5589-2018, 2018
Short summary
Short summary
Surface-based measurements from the EMEP network and EMAC model simulations are used to estimate the European surface ozone changes over 1995–2014. It shows a significantly decreasing trend in the 95th percentile ozone concentrations, while increasing in the 5th percentile ozone. Sensitivity simulations and statistical analysis show that a decrease in European anthropogenic emissions had contrasting effects on surface ozone trends between the 95th and 5th percentile levels.
Klaus Klingmüller, Swen Metzger, Mohamed Abdelkader, Vlassis A. Karydis, Georgiy L. Stenchikov, Andrea Pozzer, and Jos Lelieveld
Geosci. Model Dev., 11, 989–1008, https://doi.org/10.5194/gmd-11-989-2018, https://doi.org/10.5194/gmd-11-989-2018, 2018
Short summary
Short summary
More than 1 billion tons of mineral dust particles are raised into the atmosphere every year, which has a significant impact on climate, society and ecosystems. The location, time and amount of dust emissions depend on surface and wind conditions. In the atmospheric chemistry–climate model EMAC, we have updated the relevant surface data and equations. Our validation shows that the updates substantially improve the agreement of model results and observations.
Katrin Dulitz, Damien Amedro, Terry J. Dillon, Andrea Pozzer, and John N. Crowley
Atmos. Chem. Phys., 18, 2381–2394, https://doi.org/10.5194/acp-18-2381-2018, https://doi.org/10.5194/acp-18-2381-2018, 2018
Short summary
Short summary
The reaction between the OH radical and HNO3 represents an important route for the release of NOx (NO and NO2) from HNO3, the most important NOx reservoir in many parts of the atmosphere. In our laboratory study, we have generated an extensive, high-quality set of rate coefficients for this reaction at different temperatures and pressures and used these to derive a new parameterisation of the rate coefficient for atmospheric modelling.
Amit Sharma, Narendra Ojha, Andrea Pozzer, Kathleen A. Mar, Gufran Beig, Jos Lelieveld, and Sachin S. Gunthe
Atmos. Chem. Phys., 17, 14393–14413, https://doi.org/10.5194/acp-17-14393-2017, https://doi.org/10.5194/acp-17-14393-2017, 2017
Short summary
Short summary
We evaluate the numerical simulations of surface ozone during pre-monsoon season against a network of stations including clean, rural and polluted urban environments in the south Asian region. Significant effects of the employed emission inventory and chemical mechanism on the simulated ozone are found during the noon hours of intense photochemistry. The presented evaluation on the diurnal timescale would have implications for assessing ozone buildup and impacts on human health and crop yields.
Huisheng Bian, Mian Chin, Didier A. Hauglustaine, Michael Schulz, Gunnar Myhre, Susanne E. Bauer, Marianne T. Lund, Vlassis A. Karydis, Tom L. Kucsera, Xiaohua Pan, Andrea Pozzer, Ragnhild B. Skeie, Stephen D. Steenrod, Kengo Sudo, Kostas Tsigaridis, Alexandra P. Tsimpidi, and Svetlana G. Tsyro
Atmos. Chem. Phys., 17, 12911–12940, https://doi.org/10.5194/acp-17-12911-2017, https://doi.org/10.5194/acp-17-12911-2017, 2017
Short summary
Short summary
Atmospheric nitrate contributes notably to total aerosol mass in the present day and is likely to be more important over the next century, with a projected decline in SO2 and NOx emissions and increase in NH3 emissions. This paper investigates atmospheric nitrate using multiple global models and measurements. The study is part of the AeroCom phase III activity. The study is the first attempt to look at global atmospheric nitrate simulation at physical and chemical process levels.
Andrea Pozzer, Alexandra P. Tsimpidi, Vlassis A. Karydis, Alexander de Meij, and Jos Lelieveld
Atmos. Chem. Phys., 17, 12813–12826, https://doi.org/10.5194/acp-17-12813-2017, https://doi.org/10.5194/acp-17-12813-2017, 2017
Short summary
Short summary
This study shows that agricultural emissions are important for air quality and their reduction can effectively reduce the concentration of fine particles and their associated premature mortality. Therefore, emission control policies, especially in North America and Europe, should also involve strong ammonia emission decreases to optimally reduce fine-particle concentration.
David Cabrera-Perez, Domenico Taraborrelli, Jos Lelieveld, Thorsten Hoffmann, and Andrea Pozzer
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2017-928, https://doi.org/10.5194/acp-2017-928, 2017
Revised manuscript not accepted
Short summary
Short summary
Aromatic compounds are present in rural and urban atmospheres. The aim of this work is to disentangle the impacts of these compounds in different important atmospheric chemical species with the help of a numerical model. Aromatics have low impact OH, NOx and Ozone concentrations in the global scale (below 4 %). The impact however is larger in the regional scale (up to 10 %). The largest impact is in glyoxal and NO3 concentrations, with changes up to 10 % globally and 40 % regionally.
Heiko Bozem, Andrea Pozzer, Hartwig Harder, Monica Martinez, Jonathan Williams, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 17, 11835–11848, https://doi.org/10.5194/acp-17-11835-2017, https://doi.org/10.5194/acp-17-11835-2017, 2017
Short summary
Short summary
We present a case study of deep convection over Germany in July 2007 within the framework of the HOOVER II project. Airborne in situ measurements within the in- and outflow regions of an isolated thunderstorm provide a unique data set to study the influence of deep convection on the transport efficiency of soluble and insoluble trace gases. Despite their high solubility HCHO and H2O2 show enhanced concentrations in the outflow presumably due to degassing from cloud droplets during freezing.
Stephan Keßel, David Cabrera-Perez, Abraham Horowitz, Patrick R. Veres, Rolf Sander, Domenico Taraborrelli, Maria Tucceri, John N. Crowley, Andrea Pozzer, Christof Stönner, Luc Vereecken, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 17, 8789–8804, https://doi.org/10.5194/acp-17-8789-2017, https://doi.org/10.5194/acp-17-8789-2017, 2017
Short summary
Short summary
In this study we identify an often overlooked stable oxide of carbon, namely carbon suboxide (C3O2), in ambient air. We have made C3O2 and in the laboratory determined its absorption cross section data and the rate of reaction with two important atmospheric oxidants, OH and O3. By incorporating known sources and sinks in a global model we have generated a first global picture of the distribution of this species in the atmosphere.
Narendra Ojha, Andrea Pozzer, Dimitris Akritidis, and Jos Lelieveld
Atmos. Chem. Phys., 17, 6743–6757, https://doi.org/10.5194/acp-17-6743-2017, https://doi.org/10.5194/acp-17-6743-2017, 2017
Short summary
Short summary
We investigate the processes, frequency of occurrence and seasonality, and effects of strongly enhanced ozone layers in the middle–upper troposphere (SOPs) over the Himalayas using a global model (EMAC). Rapid transport of stratospheric air masses is found as a key underlying process. Model predicts more frequent SOP events during the pre-monsoon. SOPs are found to significantly enhance the tropospheric ozone column over the Himalayas.
Vlassis A. Karydis, Alexandra P. Tsimpidi, Sara Bacer, Andrea Pozzer, Athanasios Nenes, and Jos Lelieveld
Atmos. Chem. Phys., 17, 5601–5621, https://doi.org/10.5194/acp-17-5601-2017, https://doi.org/10.5194/acp-17-5601-2017, 2017
Short summary
Short summary
The importance of mineral dust for cloud droplet formation is studied by considering the adsorption activation of insoluble dust particles and the thermodynamic interactions between mineral cations and inorganic anions. This study demonstrates that a comprehensive treatment of the CCN activity of mineral dust and its chemical and thermodynamic interactions with inorganic species by chemistry climate models is important to realistically account for aerosol–chemistry–cloud–climate interaction.
Mohamed Abdelkader, Swen Metzger, Benedikt Steil, Klaus Klingmüller, Holger Tost, Andrea Pozzer, Georgiy Stenchikov, Leonard Barrie, and Jos Lelieveld
Atmos. Chem. Phys., 17, 3799–3821, https://doi.org/10.5194/acp-17-3799-2017, https://doi.org/10.5194/acp-17-3799-2017, 2017
Short summary
Short summary
We present a modeling study on the impacts of the key processes (dust emission flux, convection and dust aging parameterizations) that control the transatlantic dust transport using an advanced version of the EMAC atmospheric chemistry general circulation model. We define the
direct effect of dust agingas an increase in the AOD as a result of hygroscopic growth. We define the
indirect effectas a reduction in the dust AOD due to the higher removal of the aged dust particles.
Sinikka T. Lennartz, Christa A. Marandino, Marc von Hobe, Pau Cortes, Birgit Quack, Rafel Simo, Dennis Booge, Andrea Pozzer, Tobias Steinhoff, Damian L. Arevalo-Martinez, Corinna Kloss, Astrid Bracher, Rüdiger Röttgers, Elliot Atlas, and Kirstin Krüger
Atmos. Chem. Phys., 17, 385–402, https://doi.org/10.5194/acp-17-385-2017, https://doi.org/10.5194/acp-17-385-2017, 2017
Short summary
Short summary
We present new sea surface and marine boundary layer measurements of carbonyl sulfide, the most abundant sulfur gas in the atmosphere, and calculate an oceanic emission estimate. Our results imply that oceanic emissions are very unlikely to account for the missing source in the atmospheric budget that is currently discussed for OCS.
Imran A. Girach, Narendra Ojha, Prabha R. Nair, Andrea Pozzer, Yogesh K. Tiwari, K. Ravi Kumar, and Jos Lelieveld
Atmos. Chem. Phys., 17, 257–275, https://doi.org/10.5194/acp-17-257-2017, https://doi.org/10.5194/acp-17-257-2017, 2017
Short summary
Short summary
This study presents first ship-borne measurements of trace gases over the Bay of Bengal during summer monsoon. The observed variations in trace gases are shown to be due to dynamics/transport and en route photochemistry. Analysis of meteorological and chemical fields shows that significantly lower ozone during rainfall is associated with the downdrafts. A regional model reproduces the observed variations and revealed the rapid transport of ozone across the Bay of Bengal during an event.
Sara Bacer, Theodoros Christoudias, and Andrea Pozzer
Atmos. Chem. Phys., 16, 15581–15592, https://doi.org/10.5194/acp-16-15581-2016, https://doi.org/10.5194/acp-16-15581-2016, 2016
Short summary
Short summary
We investigate the influence of the North Atlantic Oscillation on atmospheric pollutant transport in the 21st century under a global climate-change scenario, using a coupled atmosphere–chemistry–ocean general circulation model. We find that, at the end of the century, the south-western Mediterranean and northern Africa will see higher pollutant concentrations during positive NAO phases with respect to the past, while a wider part of north Europe will see lower pollutant concentrations.
Dimitris Akritidis, Andrea Pozzer, Prodromos Zanis, Evangelos Tyrlis, Bojan Škerlak, Michael Sprenger, and Jos Lelieveld
Atmos. Chem. Phys., 16, 14025–14039, https://doi.org/10.5194/acp-16-14025-2016, https://doi.org/10.5194/acp-16-14025-2016, 2016
Short summary
Short summary
We investigate the contribution of tropopause folds in the summertime tropospheric ozone pool over the eastern Mediterranean and the Middle East. For this purpose we use the EMAC atmospheric chemistry–climate model and a fold identification algorithm. A clear increase of ozone is found in the middle troposphere due to fold activity. The interannual variability of near-surface ozone over the eastern Mediterranean is related to that of both tropopause folds and ozone in the free troposphere.
Kathleen A. Mar, Narendra Ojha, Andrea Pozzer, and Tim M. Butler
Geosci. Model Dev., 9, 3699–3728, https://doi.org/10.5194/gmd-9-3699-2016, https://doi.org/10.5194/gmd-9-3699-2016, 2016
Short summary
Short summary
Ground-level ozone is an air pollutant with adverse effects on human and ecosystem health and is also a climate forcer with a significant warming effect. This paper presents the setup and evaluation of a model for ozone air quality over Europe. Within the model evaluation, we compare the use of two commonly used photochemical schemes, and we conclude that uncertainties in the representation of chemistry are important to consider when using air quality models for policy applications.
Jos Lelieveld, Sergey Gromov, Andrea Pozzer, and Domenico Taraborrelli
Atmos. Chem. Phys., 16, 12477–12493, https://doi.org/10.5194/acp-16-12477-2016, https://doi.org/10.5194/acp-16-12477-2016, 2016
Short summary
Short summary
The self-cleaning capacity of the atmosphere is controlled by hydroxyl (OH) radicals in the troposphere. There are primary and secondary OH sources, the former through the photodissociation of ozone, the latter through OH recycling. We used a global model, showing that secondary sources are larger than assumed previously, which buffers OH. Complementary OH formation mechanisms in pristine and polluted environments, connected through transport of ozone, can maintain stable global OH levels.
Narendra Singh, Raman Solanki, Narendra Ojha, Ruud H. H. Janssen, Andrea Pozzer, and Surendra K. Dhaka
Atmos. Chem. Phys., 16, 10559–10572, https://doi.org/10.5194/acp-16-10559-2016, https://doi.org/10.5194/acp-16-10559-2016, 2016
Short summary
Short summary
Our study presents measurements and model simulations of boundary layer evolution over a mountain peak in the central Himalayas. The observations were made as a part of the Ganges Valley Aerosol Experiment. The implications of biases in model simulated boundary layer towards simulations of trace species is investigated.
Steffen Beirle, Christoph Hörmann, Patrick Jöckel, Song Liu, Marloes Penning de Vries, Andrea Pozzer, Holger Sihler, Pieter Valks, and Thomas Wagner
Atmos. Meas. Tech., 9, 2753–2779, https://doi.org/10.5194/amt-9-2753-2016, https://doi.org/10.5194/amt-9-2753-2016, 2016
David Cabrera-Perez, Domenico Taraborrelli, Rolf Sander, and Andrea Pozzer
Atmos. Chem. Phys., 16, 6931–6947, https://doi.org/10.5194/acp-16-6931-2016, https://doi.org/10.5194/acp-16-6931-2016, 2016
Short summary
Short summary
The global atmospheric budget and distribution of monocyclic aromatic compounds is estimated, using an atmospheric chemistry general circulation model. Simulation results are evaluated with observations with the goal of understanding emission, production and removal of these compounds. Anthropogenic and biomass burning are the main sources of aromatic compounds to the atmosphere. The main sink is photochemical decomposition and in lesser importance dry deposition.
Klaus Klingmüller, Andrea Pozzer, Swen Metzger, Georgiy L. Stenchikov, and Jos Lelieveld
Atmos. Chem. Phys., 16, 5063–5073, https://doi.org/10.5194/acp-16-5063-2016, https://doi.org/10.5194/acp-16-5063-2016, 2016
Short summary
Short summary
During the last decade, the Middle East experienced the strongest increase in atmospheric aerosol concentrations worldwide. Based on satellite observations, the present study corroborates this trend and reveals correlations with soil moisture and precipitation in and surrounding the Fertile Crescent. This suggests that the increasing drought conditions in this region have enhanced dust emissions, a tendency which is expected to be intensified by climate change.
Patrick Jöckel, Holger Tost, Andrea Pozzer, Markus Kunze, Oliver Kirner, Carl A. M. Brenninkmeijer, Sabine Brinkop, Duy S. Cai, Christoph Dyroff, Johannes Eckstein, Franziska Frank, Hella Garny, Klaus-Dirk Gottschaldt, Phoebe Graf, Volker Grewe, Astrid Kerkweg, Bastian Kern, Sigrun Matthes, Mariano Mertens, Stefanie Meul, Marco Neumaier, Matthias Nützel, Sophie Oberländer-Hayn, Roland Ruhnke, Theresa Runde, Rolf Sander, Dieter Scharffe, and Andreas Zahn
Geosci. Model Dev., 9, 1153–1200, https://doi.org/10.5194/gmd-9-1153-2016, https://doi.org/10.5194/gmd-9-1153-2016, 2016
Short summary
Short summary
With an advanced numerical global chemistry climate model (CCM) we performed several detailed
combined hind-cast and projection simulations of the period 1950 to 2100 to assess the
past, present, and potential future dynamical and chemical state of the Earth atmosphere.
The manuscript documents the model and the various applied model set-ups and provides
a first evaluation of the simulation results from a global perspective as a quality check of the data.
Narendra Ojha, Andrea Pozzer, Armin Rauthe-Schöch, Angela K. Baker, Jongmin Yoon, Carl A. M. Brenninkmeijer, and Jos Lelieveld
Atmos. Chem. Phys., 16, 3013–3032, https://doi.org/10.5194/acp-16-3013-2016, https://doi.org/10.5194/acp-16-3013-2016, 2016
Short summary
Short summary
We compare simulations of ozone and carbon monoxide using a regional chemistry transport model (WRF-Chem) with aircraft observations from CARIBIC program over India during monsoon period. Sensitivity simulations are conducted to assess the influences of regional emissions and long-range transport.
V. A. Karydis, A. P. Tsimpidi, A. Pozzer, M. Astitha, and J. Lelieveld
Atmos. Chem. Phys., 16, 1491–1509, https://doi.org/10.5194/acp-16-1491-2016, https://doi.org/10.5194/acp-16-1491-2016, 2016
Short summary
Short summary
We provide an assessment of the chemical composition and global aerosol load of aerosol nitrate and determine the effect of mineral dust on its formation due to thermodynamical interactions. For this purpose we used an explicit geographical representation of the emitted soil particle size distribution and chemical composition. We conclude mineral dust aerosol chemistry is important for nitrate aerosol formation and significantly affects its global distribution, especially in the coarse mode.
S. Bacer, T. Christoudias, and A. Pozzer
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-33049-2015, https://doi.org/10.5194/acpd-15-33049-2015, 2015
Preprint withdrawn
Short summary
Short summary
We investigate the temporal variability of the North Atlantic Oscillation (NAO) pattern and its relation to the atmospheric dispersion of pollutants in the near past and in the future.
We use a global climate circulation model in order to analyze the NAO signal and its correlation with pollutant concentrations. We find that the NAO is influenced by natural climate variability and that the NAO Indices may be used as indicators of (future) pollutant transport over Europe.
H. G. Ouwersloot, A. Pozzer, B. Steil, H. Tost, and J. Lelieveld
Geosci. Model Dev., 8, 2435–2445, https://doi.org/10.5194/gmd-8-2435-2015, https://doi.org/10.5194/gmd-8-2435-2015, 2015
H. Fischer, A. Pozzer, T. Schmitt, P. Jöckel, T. Klippel, D. Taraborrelli, and J. Lelieveld
Atmos. Chem. Phys., 15, 6971–6980, https://doi.org/10.5194/acp-15-6971-2015, https://doi.org/10.5194/acp-15-6971-2015, 2015
S. Zheng, A. Pozzer, C. X. Cao, and J. Lelieveld
Atmos. Chem. Phys., 15, 5715–5725, https://doi.org/10.5194/acp-15-5715-2015, https://doi.org/10.5194/acp-15-5715-2015, 2015
Short summary
Short summary
The present study uses aerosol optical depth as proxy to estimate 12 years of PM2.5 data for the Beijing central area and calculate the yearly premature mortality by different diseases attributable to PM2.5. The estimated average total mortality due to PM2.5 is about 5100 individuals/year for the period 2001--2012 in the Beijing central area, and the per capita mortality for all ages due to PM2.5 is around 15 per 10,000 person-years for the period 2010--2012.
A. Pozzer, A. de Meij, J. Yoon, H. Tost, A. K. Georgoulias, and M. Astitha
Atmos. Chem. Phys., 15, 5521–5535, https://doi.org/10.5194/acp-15-5521-2015, https://doi.org/10.5194/acp-15-5521-2015, 2015
Short summary
Short summary
Thanks to numerical simulations and satellite observations, it is shown that aerosol optical depth (AOD) trends (2000--2010 period) over the US and Europe are due to emission decrease, while over the Sahara Desert and the Middle East they are due to meteorological changes. Over Southeast Asia, both meteorology and emission changes are important for the AOD trends.
It is shown that soluble components strongly influence AOD, as their contribution is enhanced by the aerosol water content.
R. H. H. Janssen and A. Pozzer
Geosci. Model Dev., 8, 453–471, https://doi.org/10.5194/gmd-8-453-2015, https://doi.org/10.5194/gmd-8-453-2015, 2015
A. P. Tsimpidi, V. A. Karydis, A. Pozzer, S. N. Pandis, and J. Lelieveld
Geosci. Model Dev., 7, 3153–3172, https://doi.org/10.5194/gmd-7-3153-2014, https://doi.org/10.5194/gmd-7-3153-2014, 2014
Short summary
Short summary
A computationally efficient module for the description of OA composition and evolution in the atmosphere has been developed. This module subdivides OA into several compounds based on their source of origin and volatility, allowing the quantification of POA vs. SOA as well as biogenic vs. anthropogenic contributions to OA concentrations. Such fundamental information can shed light on long-term changes in OA abundance, and hence project the effects of OA on future air quality and climate.
R. Sander, P. Jöckel, O. Kirner, A. T. Kunert, J. Landgraf, and A. Pozzer
Geosci. Model Dev., 7, 2653–2662, https://doi.org/10.5194/gmd-7-2653-2014, https://doi.org/10.5194/gmd-7-2653-2014, 2014
C. Liu, S. Beirle, T. Butler, P. Hoor, C. Frankenberg, P. Jöckel, M. Penning de Vries, U. Platt, A. Pozzer, M. G. Lawrence, J. Lelieveld, H. Tost, and T. Wagner
Atmos. Chem. Phys., 14, 1717–1732, https://doi.org/10.5194/acp-14-1717-2014, https://doi.org/10.5194/acp-14-1717-2014, 2014
Y. F. Elshorbany, P. J. Crutzen, B. Steil, A. Pozzer, H. Tost, and J. Lelieveld
Atmos. Chem. Phys., 14, 1167–1184, https://doi.org/10.5194/acp-14-1167-2014, https://doi.org/10.5194/acp-14-1167-2014, 2014
D. Giannadaki, A. Pozzer, and J. Lelieveld
Atmos. Chem. Phys., 14, 957–968, https://doi.org/10.5194/acp-14-957-2014, https://doi.org/10.5194/acp-14-957-2014, 2014
P. Zanis, P. Hadjinicolaou, A. Pozzer, E. Tyrlis, S. Dafka, N. Mihalopoulos, and J. Lelieveld
Atmos. Chem. Phys., 14, 115–132, https://doi.org/10.5194/acp-14-115-2014, https://doi.org/10.5194/acp-14-115-2014, 2014
J. Yoon, A. Pozzer, P. Hoor, D. Y. Chang, S. Beirle, T. Wagner, S. Schloegl, J. Lelieveld, and H. M. Worden
Atmos. Chem. Phys., 13, 11307–11316, https://doi.org/10.5194/acp-13-11307-2013, https://doi.org/10.5194/acp-13-11307-2013, 2013
J. Lelieveld, C. Barlas, D. Giannadaki, and A. Pozzer
Atmos. Chem. Phys., 13, 7023–7037, https://doi.org/10.5194/acp-13-7023-2013, https://doi.org/10.5194/acp-13-7023-2013, 2013
Related subject area
Subject: Gases | Research Activity: Atmospheric Modelling | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Methane emissions in the United States, Canada, and Mexico: evaluation of national methane emission inventories and 2010–2017 sectoral trends by inverse analysis of in situ (GLOBALVIEWplus CH4 ObsPack) and satellite (GOSAT) atmospheric observations
Evaluation of SO2, SO42− and an updated SO2 dry deposition parameterization in the United Kingdom Earth System Model
Development and evaluation of a new compact mechanism for aromatic oxidation in atmospheric models
Ozone deposition impact assessments for forest canopies require accurate ozone flux partitioning on diurnal timescales
Unraveling pathways of elevated ozone induced by the 2020 lockdown in Europe by an observationally constrained regional model using TROPOMI
Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere: a case study over the west coast of Borneo
Improving predictability of high-ozone episodes through dynamic boundary conditions, emission refresh and chemical data assimilation during the Long Island Sound Tropospheric Ozone Study (LISTOS) field campaign
Pyruvic acid, an efficient catalyst in SO3 hydrolysis and effective clustering agent in sulfuric acid-based new particle formation
Atmospheric observations consistent with reported decline in the UK's methane emissions (2013–2020)
Influence of atmospheric in-cloud aqueous-phase chemistry on the global simulation of SO2 in CESM2
Technical note: Quality assessment of ozone reanalysis products and gap-filling over subarctic Europe for vegetation risk mapping
Evolution of OH reactivity in NO-free volatile organic compound photooxidation investigated by the fully explicit GECKO-A model
Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results
Evaluating consistency between total column CO2 retrievals from OCO-2 and the in situ network over North America: implications for carbon flux estimation
Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants
The role of emission reductions and the meteorological situation for air quality improvements during the COVID-19 lockdown period in central Europe
Heterogeneity and chemical reactivity of the remote troposphere defined by aircraft measurements
A mass-balance-based emission inventory of non-methane volatile organic compounds (NMVOCs) for solvent use in China
Opinion: The germicidal effect of ambient air (open-air factor) revisited
Impact of Athabasca oil sands operations on mercury levels in air and deposition
Study of different Carbon Bond 6 (CB6) mechanisms by using a concentration sensitivity analysis
Accelerating methane growth rate from 2010 to 2017: leading contributions from the tropics and East Asia
Observation and modelling of ozone-destructive halogen chemistry in a passively degassing volcanic plume
Tropospheric ozone changes and ozone sensitivity from present-day to future under shared socio-economic pathways
An integrated analysis of contemporary methane emissions and concentration trends over China using in situ, satellite observations, and model simulations
Modeling study of the impact of SO2 volcanic passive emissions on the tropospheric sulfur budget
The impact of organic pollutants from Indonesian peatland fires on the tropospheric and lower stratospheric composition
Comprehensive evaluations of diurnal NO2 measurements during DISCOVER-AQ 2011: effects of resolution-dependent representation of NOx emissions
Downscaling system for modeling of atmospheric composition on regional, urban and street scales
Satellite soil moisture data assimilation impacts on modeling weather variables and ozone in the southeastern US – Part 1: An overview
Development of ozone reactivity scales for volatile organic compounds in a Chinese megacity
Measured and modelled air quality trends in Italy over the period 2003–2010
Large and increasing methane emissions from eastern Amazonia derived from satellite data, 2010–2018
Contrasting chemical environments in summertime for atmospheric ozone across major Chinese industrial regions: the effectiveness of emission control strategies
Unexpected enhancement of ozone exposure and health risks during National Day in China
Role of oceanic ozone deposition in explaining temporal variability in surface ozone at High Arctic sites
Oxidation of low-molecular-weight organic compounds in cloud droplets: global impact on tropospheric oxidants
Bias-correcting carbon fluxes derived from land-surface satellite data for retrospective and near-real-time assimilation systems
Characterizing model errors in chemical transport modeling of methane: using GOSAT XCH4 data with weak-constraint four-dimensional variational data assimilation
Estimation of fire-induced carbon emissions from Equatorial Asia in 2015 using in situ aircraft and ship observations
Influence of weather situation on non-CO2 aviation climate effects: the REACT4C climate change functions
Photo-initiated ground state chemistry: How important is it in the atmosphere?
Impact of international shipping emissions on ozone and PM2.5 in East Asia during summer: the important role of HONO and ClNO2
Modelling the impacts of iodine chemistry on the northern Indian Ocean marine boundary layer
Time-dependent 3D simulations of tropospheric ozone depletion events in the Arctic spring using the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem)
Assessing and improving cloud-height-based parameterisations of global lightning flash rate, and their impact on lightning-produced NOx and tropospheric composition in a chemistry–climate model
Impact of regional Northern Hemisphere mid-latitude anthropogenic sulfur dioxide emissions on local and remote tropospheric oxidants
Impact of organic molecular structure on the estimation of atmospherically relevant physicochemical parameters
Spatial and temporal variability in the hydroxyl (OH) radical: understanding the role of large-scale climate features and their influence on OH through its dynamical and photochemical drivers
Analysis of atmospheric ammonia over South and East Asia based on the MOZART-4 model and its comparison with satellite and surface observations
Xiao Lu, Daniel J. Jacob, Haolin Wang, Joannes D. Maasakkers, Yuzhong Zhang, Tia R. Scarpelli, Lu Shen, Zhen Qu, Melissa P. Sulprizio, Hannah Nesser, A. Anthony Bloom, Shuang Ma, John R. Worden, Shaojia Fan, Robert J. Parker, Hartmut Boesch, Ritesh Gautam, Deborah Gordon, Michael D. Moran, Frances Reuland, Claudia A. Octaviano Villasana, and Arlyn Andrews
Atmos. Chem. Phys., 22, 395–418, https://doi.org/10.5194/acp-22-395-2022, https://doi.org/10.5194/acp-22-395-2022, 2022
Short summary
Short summary
We evaluate methane emissions and trends for 2010–2017 in the gridded national emission inventories for the United States, Canada, and Mexico by inversion of in situ and satellite methane observations. We find that anthropogenic methane emissions for all three countries are underestimated in the national inventories, largely driven by oil emissions. Anthropogenic methane emissions in the US peak in 2014, in contrast to the report of a steadily decreasing trend over 2010–2017 from the US EPA.
Catherine Hardacre, Jane P. Mulcahy, Richard J. Pope, Colin G. Jones, Steven T. Rumbold, Can Li, Colin Johnson, and Steven T. Turnock
Atmos. Chem. Phys., 21, 18465–18497, https://doi.org/10.5194/acp-21-18465-2021, https://doi.org/10.5194/acp-21-18465-2021, 2021
Short summary
Short summary
We investigate UKESM1's ability to represent the sulfur (S) cycle in the recent historical period. The S cycle is a key driver of historical radiative forcing. Earth system models such as UKESM1 should represent the S cycle well so that we can have confidence in their projections of future climate. We compare UKESM1 to observations of sulfur compounds, finding that the model generally performs well. We also identify areas for UKESM1’s development, focussing on how SO2 is removed from the air.
Kelvin H. Bates, Daniel J. Jacob, Ke Li, Peter D. Ivatt, Mat J. Evans, Yingying Yan, and Jintai Lin
Atmos. Chem. Phys., 21, 18351–18374, https://doi.org/10.5194/acp-21-18351-2021, https://doi.org/10.5194/acp-21-18351-2021, 2021
Short summary
Short summary
Simple aromatic compounds (benzene, toluene, xylene) have complex gas-phase chemistry that is inconsistently represented in atmospheric models. We compile recent experimental and theoretical insights to develop a new mechanism for gas-phase aromatic oxidation that is sufficiently compact for use in multiscale models. We compare our new mechanism to chamber experiments and other mechanisms, and implement it in a global model to quantify the impacts of aromatic oxidation on tropospheric chemistry.
Auke J. Visser, Laurens N. Ganzeveld, Ignacio Goded, Maarten C. Krol, Ivan Mammarella, Giovanni Manca, and K. Folkert Boersma
Atmos. Chem. Phys., 21, 18393–18411, https://doi.org/10.5194/acp-21-18393-2021, https://doi.org/10.5194/acp-21-18393-2021, 2021
Short summary
Short summary
Dry deposition is an important sink for tropospheric ozone that affects ecosystem carbon uptake, but process understanding remains incomplete. We apply a common deposition representation in atmospheric chemistry models and a multi-layer canopy model to multi-year ozone deposition observations. The multi-layer canopy model performs better on diurnal timescales compared to the common approach, leading to a substantially improved simulation of ozone deposition and vegetation ozone impact metrics.
Amir H. Souri, Kelly Chance, Juseon Bak, Caroline R. Nowlan, Gonzalo González Abad, Yeonjin Jung, David C. Wong, Jingqiu Mao, and Xiong Liu
Atmos. Chem. Phys., 21, 18227–18245, https://doi.org/10.5194/acp-21-18227-2021, https://doi.org/10.5194/acp-21-18227-2021, 2021
Short summary
Short summary
The global pandemic is believed to have an impact on emissions of air pollutants such as nitrogen dioxide (NO2) and formaldehyde (HCHO). This study quantifies the changes in the amount of NOx and VOC emissions via state-of-the-art inverse modeling technique using satellite observations during the lockdown 2020 with respect to a baseline over Europe, which in turn, it permits unraveling atmospheric processes being responsible for ozone formation in a less cloudy month.
Paul D. Hamer, Virginie Marécal, Ryan Hossaini, Michel Pirre, Gisèle Krysztofiak, Franziska Ziska, Andreas Engel, Stephan Sala, Timo Keber, Harald Bönisch, Elliot Atlas, Kirstin Krüger, Martyn Chipperfield, Valery Catoire, Azizan A. Samah, Marcel Dorf, Phang Siew Moi, Hans Schlager, and Klaus Pfeilsticker
Atmos. Chem. Phys., 21, 16955–16984, https://doi.org/10.5194/acp-21-16955-2021, https://doi.org/10.5194/acp-21-16955-2021, 2021
Short summary
Short summary
Bromoform is a stratospheric ozone-depleting gas released by seaweed and plankton transported to the stratosphere via convection in the tropics. We study the chemical interactions of bromoform and its derivatives within convective clouds using a cloud-scale model and observations. Our findings are that soluble bromine gases are efficiently washed out and removed within the convective clouds and that most bromine is transported vertically to the upper troposphere in the form of bromoform.
Siqi Ma, Daniel Tong, Lok Lamsal, Julian Wang, Xuelei Zhang, Youhua Tang, Rick Saylor, Tianfeng Chai, Pius Lee, Patrick Campbell, Barry Baker, Shobha Kondragunta, Laura Judd, Timothy A. Berkoff, Scott J. Janz, and Ivanka Stajner
Atmos. Chem. Phys., 21, 16531–16553, https://doi.org/10.5194/acp-21-16531-2021, https://doi.org/10.5194/acp-21-16531-2021, 2021
Short summary
Short summary
Predicting high ozone gets more challenging as urban emissions decrease. How can different techniques be used to foretell the quality of air to better protect human health? We tested four techniques with the CMAQ model against observations during a field campaign over New York City. The new system proves to better predict the magnitude and timing of high ozone. These approaches can be extended to other regions to improve the predictability of high-O3 episodes in contemporary urban environments.
Narcisse Tsona Tchinda, Lin Du, Ling Liu, and Xiuhui Zhang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-784, https://doi.org/10.5194/acp-2021-784, 2021
Revised manuscript accepted for ACP
Short summary
Short summary
This study explores the effect of pyruvic acid (PA) both in the SO3 hydrolysis and in sulfuric acid-based aerosol formation. Results show that in dry and polluted areas, PA-catalyzed SO3 hydrolysis is about two orders of magnitude more efficient to form sulfuric acid than the water-catalyzed reaction. Moreover, PA can effectively enhance the ternary SA-PA-NH3 particle formation rate by up to 4.7 × 102 relative to the binary SA-NH3 particle formation rate at cold temperatures.
Mark F. Lunt, Alistair J. Manning, Grant Allen, Tim Arnold, Stéphane J.-B. Bauguitte, Hartmut Boesch, Anita L. Ganesan, Aoife Grant, Carole Helfter, Eiko Nemitz, Simon J. O'Doherty, Paul I. Palmer, Joseph R. Pitt, Chris Rennick, Daniel Say, Kieran M. Stanley, Ann R. Stavert, Dickon Young, and Matt Rigby
Atmos. Chem. Phys., 21, 16257–16276, https://doi.org/10.5194/acp-21-16257-2021, https://doi.org/10.5194/acp-21-16257-2021, 2021
Short summary
Short summary
We present an evaluation of the UK's methane emissions between 2013 and 2020 using a network of tall tower measurement sites. We find emissions that are consistent in both magnitude and trend with the UK's reported emissions, with a declining trend driven by a decrease in emissions from England. The impact of various components of the modelling set-up on these findings are explored through a number of sensitivity studies.
Wendong Ge, Junfeng Liu, Kan Yi, Jiayu Xu, Yizhou Zhang, Xiurong Hu, Jianmin Ma, Xuejun Wang, Yi Wan, Jianying Hu, Zhaobin Zhang, Xilong Wang, and Shu Tao
Atmos. Chem. Phys., 21, 16093–16120, https://doi.org/10.5194/acp-21-16093-2021, https://doi.org/10.5194/acp-21-16093-2021, 2021
Short summary
Short summary
Compared with the observations, the results incorporating detailed cloud aqueous-phase chemistry greatly reduced SO2 overestimation. The biases in annual simulated SO2 concentrations (or mixing ratios) decreased by 46 %, 41 %, and 22 % in Europe, the USA, and China, respectively. Fe chemistry and HOx chemistry contributed more to SO2 oxidation than N chemistry. Higher concentrations of soluble Fe and higher pH values could further enhance the oxidation capacity.
Stefanie Falk, Ane V. Vollsnes, Aud B. Eriksen, Frode Stordal, and Terje Koren Berntsen
Atmos. Chem. Phys., 21, 15647–15661, https://doi.org/10.5194/acp-21-15647-2021, https://doi.org/10.5194/acp-21-15647-2021, 2021
Short summary
Short summary
We evaluate regional and global models for ozone modeling and damage risk mapping of vegetation over subarctic Europe. Our analysis suggests that low-resolution global models do not reproduce the observed ozone seasonal cycle at ground level, underestimating ozone by 30–50 %. High-resolution regional models capture the seasonal cycle well, still underestimating ozone by up to 20 %. Our proposed gap-filling method for site observations shows a 76 % accuracy compared to the regional model (80 %).
Zhe Peng, Julia Lee-Taylor, Harald Stark, John J. Orlando, Bernard Aumont, and Jose L. Jimenez
Atmos. Chem. Phys., 21, 14649–14669, https://doi.org/10.5194/acp-21-14649-2021, https://doi.org/10.5194/acp-21-14649-2021, 2021
Short summary
Short summary
We use the fully explicit GECKO-A model to study the OH reactivity (OHR) evolution in the NO-free photooxidation of several volatile organic compounds. Oxidation progressively produces more saturated and functionalized species, then breaks them into small species. OHR per C atom evolution is similar for different precursors once saturated multifunctional species are formed. We also find that partitioning of these species to chamber walls leads to large deviations in chambers from the atmosphere.
Philipp G. Eger, Luc Vereecken, Rolf Sander, Jan Schuladen, Nicolas Sobanski, Horst Fischer, Einar Karu, Jonathan Williams, Ville Vakkari, Tuukka Petäjä, Jos Lelieveld, Andrea Pozzer, and John N. Crowley
Atmos. Chem. Phys., 21, 14333–14349, https://doi.org/10.5194/acp-21-14333-2021, https://doi.org/10.5194/acp-21-14333-2021, 2021
Short summary
Short summary
We determine the impact of pyruvic acid photolysis on the formation of acetaldehyde and peroxy radicals during summer and autumn in the Finnish boreal forest using a data-constrained box model. Our results are dependent on the chosen scenario in which the overall quantum yield and the photolysis products are varied. We highlight that pyruvic acid photolysis can be an important contributor to acetaldehyde and peroxy radical formation in remote, forested regions.
Bharat Rastogi, John B. Miller, Micheal Trudeau, Arlyn E. Andrews, Lei Hu, Marikate Mountain, Thomas Nehrkorn, Bianca Baier, Kathryn McKain, John Mund, Kaiyu Guan, and Caroline B. Alden
Atmos. Chem. Phys., 21, 14385–14401, https://doi.org/10.5194/acp-21-14385-2021, https://doi.org/10.5194/acp-21-14385-2021, 2021
Short summary
Short summary
Predicting Earth's climate is difficult, partly due to uncertainty in forecasting how much CO2 can be removed by oceans and plants, because we cannot measure these exchanges directly on large scales. Satellites such as NASA's OCO-2 can provide part of the needed information, but data need to be highly precise and accurate. We evaluate these data and find small biases in certain months that are similar to the signals of interest. We argue that continued improvement of these data is necessary.
Xuan Wang, Daniel J. Jacob, William Downs, Shuting Zhai, Lei Zhu, Viral Shah, Christopher D. Holmes, Tomás Sherwen, Becky Alexander, Mathew J. Evans, Sebastian D. Eastham, J. Andrew Neuman, Patrick R. Veres, Theodore K. Koenig, Rainer Volkamer, L. Gregory Huey, Thomas J. Bannan, Carl J. Percival, Ben H. Lee, and Joel A. Thornton
Atmos. Chem. Phys., 21, 13973–13996, https://doi.org/10.5194/acp-21-13973-2021, https://doi.org/10.5194/acp-21-13973-2021, 2021
Short summary
Short summary
Halogen radicals have a broad range of implications for tropospheric chemistry, air quality, and climate. We present a new mechanistic description and comprehensive simulation of tropospheric halogens in a global 3-D model and compare the model results with surface and aircraft measurements. We find that halogen chemistry decreases the global tropospheric burden of ozone by 11 %, NOx by 6 %, and OH by 4 %.
Volker Matthias, Markus Quante, Jan A. Arndt, Ronny Badeke, Lea Fink, Ronny Petrik, Josefine Feldner, Daniel Schwarzkopf, Eliza-Maria Link, Martin O. P. Ramacher, and Ralf Wedemann
Atmos. Chem. Phys., 21, 13931–13971, https://doi.org/10.5194/acp-21-13931-2021, https://doi.org/10.5194/acp-21-13931-2021, 2021
Short summary
Short summary
COVID-19 lockdown measures in spring 2020 led to cleaner air in central Europe. Densely populated areas benefitted mainly from largely reduced NO2 concentrations, while rural areas experienced lower reductions in NO2 but also lower ozone concentrations. Very low particulate matter (PM) concentrations in parts of Europe were not an effect of lockdown measures. Model simulations show that modified weather conditions are more significant for ozone and PM than severe traffic emission reductions.
Hao Guo, Clare M. Flynn, Michael J. Prather, Sarah A. Strode, Stephen D. Steenrod, Louisa Emmons, Forrest Lacey, Jean-Francois Lamarque, Arlene M. Fiore, Gus Correa, Lee T. Murray, Glenn M. Wolfe, Jason M. St. Clair, Michelle Kim, John Crounse, Glenn Diskin, Joshua DiGangi, Bruce C. Daube, Roisin Commane, Kathryn McKain, Jeff Peischl, Thomas B. Ryerson, Chelsea Thompson, Thomas F. Hanisco, Donald Blake, Nicola J. Blake, Eric C. Apel, Rebecca S. Hornbrook, James W. Elkins, Eric J. Hintsa, Fred L. Moore, and Steven Wofsy
Atmos. Chem. Phys., 21, 13729–13746, https://doi.org/10.5194/acp-21-13729-2021, https://doi.org/10.5194/acp-21-13729-2021, 2021
Short summary
Short summary
The NASA Atmospheric Tomography (ATom) mission built a climatology of the chemical composition of tropospheric air parcels throughout the middle of the Pacific and Atlantic oceans. The level of detail allows us to reconstruct the photochemical budgets of O3 and CH4 over these vast, remote regions. We find that most of the chemical heterogeneity is captured at the resolution used in current global chemistry models and that the majority of reactivity occurs in the
hottest20 % of parcels.
Ziwei Mo, Ru Cui, Bin Yuan, Huihua Cai, Brian C. McDonald, Meng Li, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 21, 13655–13666, https://doi.org/10.5194/acp-21-13655-2021, https://doi.org/10.5194/acp-21-13655-2021, 2021
Short summary
Short summary
There is a lack of detailed understanding of NMVOC emissions from the use of volatile chemical products (VCPs) in China. This study used a mass balance method to compile a long-term emission inventory for solvent use (including coatings, adhesives, inks, pesticides, cleaners and personal care products) in China during 2000–2017. The striking growth and recent trend of solvent use NMVOC emissions can give important implications for air quality modeling and NMVOC control strategies in China.
R. Anthony Cox, Markus Ammann, John N. Crowley, Paul T. Griffiths, Hartmut Herrmann, Erik H. Hoffmann, Michael E. Jenkin, V. Faye McNeill, Abdelwahid Mellouki, Christopher J. Penkett, Andreas Tilgner, and Timothy J. Wallington
Atmos. Chem. Phys., 21, 13011–13018, https://doi.org/10.5194/acp-21-13011-2021, https://doi.org/10.5194/acp-21-13011-2021, 2021
Short summary
Short summary
The term open-air factor was coined in the 1960s, establishing that rural air had powerful germicidal properties possibly resulting from immediate products of the reaction of ozone with alkenes, unsaturated compounds ubiquitously present in natural and polluted environments. We have re-evaluated those early experiments, applying the recently substantially improved knowledge, and put them into the context of the lifetime of aerosol-borne pathogens that are so important in the Covid-19 pandemic.
Ashu Dastoor, Andrei Ryjkov, Gregor Kos, Junhua Zhang, Jane Kirk, Matthew Parsons, and Alexandra Steffen
Atmos. Chem. Phys., 21, 12783–12807, https://doi.org/10.5194/acp-21-12783-2021, https://doi.org/10.5194/acp-21-12783-2021, 2021
Short summary
Short summary
An assessment of mercury levels in air and deposition in the Athabasca oil sands region (AOSR) in Northern Alberta, Canada, was conducted to investigate the contribution of Hg emitted from oil sands activities to the surrounding landscape using a 3D process-based Hg model in 2012–2015. Oil sands Hg emissions are found to be important sources of Hg contamination to the local landscape in proximity to the processing activities, particularly in wintertime.
Le Cao, Simeng Li, and Luhang Sun
Atmos. Chem. Phys., 21, 12687–12714, https://doi.org/10.5194/acp-21-12687-2021, https://doi.org/10.5194/acp-21-12687-2021, 2021
Short summary
Short summary
Gas-phase chemical reaction mechanisms, e.g., CB6 mechanism, are essential parts of the atmospheric transport model. In order to better understand the changes caused by the updates between different versions of the CB6 mechanism, in this study, the behavior of three different CB6 mechanisms in simulating ozone, nitrogen oxides and formaldehyde under two different emission conditions was analyzed using a concentration sensitivity analysis, and the reasons causing the deviations were figured out.
Yi Yin, Frederic Chevallier, Philippe Ciais, Philippe Bousquet, Marielle Saunois, Bo Zheng, John Worden, A. Anthony Bloom, Robert J. Parker, Daniel J. Jacob, Edward J. Dlugokencky, and Christian Frankenberg
Atmos. Chem. Phys., 21, 12631–12647, https://doi.org/10.5194/acp-21-12631-2021, https://doi.org/10.5194/acp-21-12631-2021, 2021
Short summary
Short summary
The growth of methane, the second-most important anthropogenic greenhouse gas after carbon dioxide, has been accelerating in recent years. Using an ensemble of multi-tracer atmospheric inversions constrained by surface or satellite observations, we show that global methane emissions increased by nearly 1 % per year from 2010–2017, with leading contributions from the tropics and East Asia.
Luke Surl, Tjarda Roberts, and Slimane Bekki
Atmos. Chem. Phys., 21, 12413–12441, https://doi.org/10.5194/acp-21-12413-2021, https://doi.org/10.5194/acp-21-12413-2021, 2021
Short summary
Short summary
Many different chemical reactions happen when the gases from a volcano mix with air, but what effects do they have? We present aircraft measurements which show that there is less ozone within the plume of Etna than outside it. We have also made a computer model of this chemistry. This model can reproduce the effects seen when halogens (bromine and chlorine) are included in the volcanic emissions.
We look closely at the simulation to discover how complicated halogen reactions cause ozone loss.
Zhenze Liu, Ruth M. Doherty, Oliver Wild, Fiona M. O’Connor, and Steven T. Turnock
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-689, https://doi.org/10.5194/acp-2021-689, 2021
Revised manuscript accepted for ACP
Short summary
Short summary
Tropospheric ozone is important to future air quality and climate, and changing emissions and climate influence ozone. We investigate the evolution of ozone and ozone sensitivity in the present day (2004–2014) and in the near future (2045–2055) , and explore the main drivers of ozone changes from globe and regional perspectives. This helps guide the suitable emission control strategies to mitigate ozone pollution.
Haiyue Tan, Lin Zhang, Xiao Lu, Yuanhong Zhao, Bo Yao, Robert J. Parker, and Hartmut Boech
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-464, https://doi.org/10.5194/acp-2021-464, 2021
Revised manuscript accepted for ACP
Short summary
Short summary
Methane is the second most important anthropogenic greenhouse gas. Understand methane emissions and concentration growth over China in the recent decade is important to support its mitigation. This study analyzes the contributions of methane emissions from different regions and sources over the globe to methane changes over China in 2007–2018. Our results show strong international transport influences, and emphasize the need of intensive methane measurements covering eastern China.
Claire Lamotte, Jonathan Guth, Virginie Marécal, Martin Cussac, Paul David Hamer, Nicolas Theys, and Philipp Schneider
Atmos. Chem. Phys., 21, 11379–11404, https://doi.org/10.5194/acp-21-11379-2021, https://doi.org/10.5194/acp-21-11379-2021, 2021
Short summary
Short summary
Improvements are made in a global chemical transfer model by considering a new volcanic SO2 emissions inventory, with more volcanoes referenced and more information on the altitude of injection. Better constraining volcanic emissions with this inventory improves the global, but mostly local, tropospheric sulfur composition. The tropospheric sulfur budget shows a nonlinearity to the volcanic contribution, especially to the sulfate aerosol burden and sulfur wet deposition.
Simon Rosanka, Bruno Franco, Lieven Clarisse, Pierre-François Coheur, Andrea Pozzer, Andreas Wahner, and Domenico Taraborrelli
Atmos. Chem. Phys., 21, 11257–11288, https://doi.org/10.5194/acp-21-11257-2021, https://doi.org/10.5194/acp-21-11257-2021, 2021
Short summary
Short summary
The strong El Niño in 2015 led to a particular dry season in Indonesia and favoured severe peatland fires. The smouldering conditions of these fires and the high carbon content of peat resulted in high volatile organic compound (VOC) emissions. By using a comprehensive atmospheric model, we show that these emissions have a significant impact on the tropospheric composition and oxidation capacity. These emissions are transported into to the lower stratosphere, resulting in a depletion of ozone.
Jianfeng Li, Yuhang Wang, Ruixiong Zhang, Charles Smeltzer, Andrew Weinheimer, Jay Herman, K. Folkert Boersma, Edward A. Celarier, Russell W. Long, James J. Szykman, Ruben Delgado, Anne M. Thompson, Travis N. Knepp, Lok N. Lamsal, Scott J. Janz, Matthew G. Kowalewski, Xiong Liu, and Caroline R. Nowlan
Atmos. Chem. Phys., 21, 11133–11160, https://doi.org/10.5194/acp-21-11133-2021, https://doi.org/10.5194/acp-21-11133-2021, 2021
Short summary
Short summary
Comprehensive evaluations of simulated diurnal cycles of NO2 and NOy concentrations, vertical profiles, and tropospheric vertical column densities at two different resolutions with various measurements during the DISCOVER-AQ 2011 campaign show potential distribution biases of NOx emissions in the National Emissions Inventory 2011 at both 36 and 4 km resolutions, providing another possible explanation for the overestimation of model results.
Roman Nuterman, Alexander Mahura, Alexander Baklanov, Bjarne Amstrup, and Ashraf Zakey
Atmos. Chem. Phys., 21, 11099–11112, https://doi.org/10.5194/acp-21-11099-2021, https://doi.org/10.5194/acp-21-11099-2021, 2021
Short summary
Short summary
The street air pollution is usually higher than the pollution at regional and urban scales. It mostly associated with both local emission sources and urban weather conditions. We present the downscaling system for regional, subregional-urban and street scales and evaluate it for acute air-pollution episode. Its evaluation showed a good prediction score across various spatiotemporal scales as well as feasibility of deterministic modelling approach for the operational street scale forecasting.
Min Huang, James H. Crawford, Joshua P. DiGangi, Gregory R. Carmichael, Kevin W. Bowman, Sujay V. Kumar, and Xiwu Zhan
Atmos. Chem. Phys., 21, 11013–11040, https://doi.org/10.5194/acp-21-11013-2021, https://doi.org/10.5194/acp-21-11013-2021, 2021
Short summary
Short summary
This study evaluates the impact of satellite soil moisture data assimilation on modeled weather and ozone fields at various altitudes above the southeastern US during the summer. It emphasizes the importance of soil moisture in the understanding of surface ozone pollution and upper tropospheric chemistry, as well as air pollutants’ source–receptor relationships between the US and its downwind areas.
Yingnan Zhang, Likun Xue, William P. L. Carter, Chenglei Pei, Tianshu Chen, Jiangshan Mu, Yujun Wang, Qingzhu Zhang, and Wenxing Wang
Atmos. Chem. Phys., 21, 11053–11068, https://doi.org/10.5194/acp-21-11053-2021, https://doi.org/10.5194/acp-21-11053-2021, 2021
Short summary
Short summary
We developed the localized incremental reactivity (IR) for VOCs in a Chinese megacity and elucidated their applications in calculating the ozone formation potential (OFP). The IR scales showed a strong dependence on chemical mechanisms. Both emission- and observation-based inputs are suitable for the MIR calculation but not the case under mixed-limited or NOx-limited O3 formation regimes. We provide suggestions for the application of IR and OFP scales to aid in VOC control in China.
Ilaria D'Elia, Gino Briganti, Lina Vitali, Antonio Piersanti, Gaia Righini, Massimo D'Isidoro, Andrea Cappelletti, Mihaela Mircea, Mario Adani, Gabriele Zanini, and Luisella Ciancarella
Atmos. Chem. Phys., 21, 10825–10849, https://doi.org/10.5194/acp-21-10825-2021, https://doi.org/10.5194/acp-21-10825-2021, 2021
Short summary
Short summary
We present an analysis of modelled trends of PM10, NO2, and O3 airborne concentrations over the Italian territory in 2003–2010. Our analysis shows a general downward simulated trend for all pollutants, with good agreement between observed and modelled values and the model widening both coverage and significance of air concentration trends. Due to the complex atmospheric dynamics, emission reductions do not always result in decreasing concentrations, especially for secondary pollutants.
Chris Wilson, Martyn P. Chipperfield, Manuel Gloor, Robert J. Parker, Hartmut Boesch, Joey McNorton, Luciana V. Gatti, John B. Miller, Luana S. Basso, and Sarah A. Monks
Atmos. Chem. Phys., 21, 10643–10669, https://doi.org/10.5194/acp-21-10643-2021, https://doi.org/10.5194/acp-21-10643-2021, 2021
Short summary
Short summary
Methane (CH4) is an important greenhouse gas emitted from wetlands like those found in the basin of the Amazon River. Using an atmospheric model and observations from GOSAT, we quantified CH4 emissions from Amazonia during the previous decade. We found that the largest emissions came from a region in the eastern basin and that emissions there were rising faster than in other areas of South America. This finding was supported by CH4 observations made on aircraft within the basin.
Zhenze Liu, Ruth M. Doherty, Oliver Wild, Michael Hollaway, and Fiona M. O’Connor
Atmos. Chem. Phys., 21, 10689–10706, https://doi.org/10.5194/acp-21-10689-2021, https://doi.org/10.5194/acp-21-10689-2021, 2021
Short summary
Short summary
Surface ozone (O3) has become the main cause of atmospheric pollution in the summertime in China since 2013. We find that 70 % reductions in NOx emissions are required to reduce O3 pollution in most of industrial regions of China, and controls in VOC emissions are very important. The new chemical scheme developed for a global chemistry–climate model not only captures the regional air pollution but also benefits the future studies of regional air-quality–climate interactions.
Peng Wang, Juanyong Shen, Men Xia, Shida Sun, Yanli Zhang, Hongliang Zhang, and Xinming Wang
Atmos. Chem. Phys., 21, 10347–10356, https://doi.org/10.5194/acp-21-10347-2021, https://doi.org/10.5194/acp-21-10347-2021, 2021
Short summary
Short summary
Ozone (O3) pollution has received extensive attention due to worsening air quality and rising health risks. The Chinese National Day holiday (CNDH), which is associated with intensive commercial and tourist activities, serves as a valuable experiment to evaluate the O3 response during the holiday. We find sharply increasing trends of observed O3 concentrations throughout China during the CNDH, leading to 33 % additional total daily deaths.
Johannes G. M. Barten, Laurens N. Ganzeveld, Gert-Jan Steeneveld, and Maarten C. Krol
Atmos. Chem. Phys., 21, 10229–10248, https://doi.org/10.5194/acp-21-10229-2021, https://doi.org/10.5194/acp-21-10229-2021, 2021
Short summary
Short summary
We present an evaluation of ocean and snow/ice O3 deposition in explaining observed hourly surface O3 at 25 pan-Arctic sites using an atmospheric meteorology/chemistry model. The model includes a mechanistic representation of ocean O3 deposition as a function of ocean biogeochemical and mixing conditions. The mechanistic representation agrees better with O3 observations in terms of magnitude and temporal variability especially in the High Arctic (> 70° N).
Simon Rosanka, Rolf Sander, Bruno Franco, Catherine Wespes, Andreas Wahner, and Domenico Taraborrelli
Atmos. Chem. Phys., 21, 9909–9930, https://doi.org/10.5194/acp-21-9909-2021, https://doi.org/10.5194/acp-21-9909-2021, 2021
Short summary
Short summary
In-cloud destruction of ozone depends on hydroperoxyl radicals in cloud droplets, where they are produced by oxygenated volatile organic compound (OVOC) oxygenation. Only rudimentary representations of these processes, if any, are currently available in global atmospheric models. By using a comprehensive atmospheric model that includes a complex in-cloud OVOC oxidation scheme, we show that atmospheric oxidants are reduced and models ignoring this process will underpredict clouds as ozone sinks.
Brad Weir, Lesley E. Ott, George J. Collatz, Stephan R. Kawa, Benjamin Poulter, Abhishek Chatterjee, Tomohiro Oda, and Steven Pawson
Atmos. Chem. Phys., 21, 9609–9628, https://doi.org/10.5194/acp-21-9609-2021, https://doi.org/10.5194/acp-21-9609-2021, 2021
Short summary
Short summary
We present a collection of carbon surface fluxes, the Low-order Flux Inversion (LoFI), derived from satellite observations of the Earth's surface and calibrated to match long-term inventories and atmospheric and oceanic records. Simulations using LoFI reproduce background atmospheric carbon dioxide measurements with comparable skill to the leading surface flux products. Available both retrospectively and as a forecast, LoFI enables the study of the carbon cycle as it occurs.
Ilya Stanevich, Dylan B. A. Jones, Kimberly Strong, Martin Keller, Daven K. Henze, Robert J. Parker, Hartmut Boesch, Debra Wunch, Justus Notholt, Christof Petri, Thorsten Warneke, Ralf Sussmann, Matthias Schneider, Frank Hase, Rigel Kivi, Nicholas M. Deutscher, Voltaire A. Velazco, Kaley A. Walker, and Feng Deng
Atmos. Chem. Phys., 21, 9545–9572, https://doi.org/10.5194/acp-21-9545-2021, https://doi.org/10.5194/acp-21-9545-2021, 2021
Short summary
Short summary
We explore the utility of a weak-constraint (WC) four-dimensional variational (4D-Var) data assimilation scheme for mitigating systematic errors in methane simulation in the GEOS-Chem model. We use data from the Greenhouse Gases Observing Satellite (GOSAT) and show that, compared to the traditional 4D-Var approach, the WC scheme improves the agreement between the model and independent observations. We find that the WC corrections to the model provide insight into the source of the errors.
Yosuke Niwa, Yousuke Sawa, Hideki Nara, Toshinobu Machida, Hidekazu Matsueda, Taku Umezawa, Akihiko Ito, Shin-Ichiro Nakaoka, Hiroshi Tanimoto, and Yasunori Tohjima
Atmos. Chem. Phys., 21, 9455–9473, https://doi.org/10.5194/acp-21-9455-2021, https://doi.org/10.5194/acp-21-9455-2021, 2021
Short summary
Short summary
Fires in Equatorial Asia release a large amount of carbon into the atmosphere. Extensively using high-precision atmospheric carbon dioxide (CO2) data from a commercial aircraft observation project, we estimated fire carbon emissions in Equatorial Asia induced by the big El Niño event in 2015. Additional shipboard measurement data elucidated the validity of the analysis and the best estimate indicated 273 Tg C for fire emissions during September–October 2015.
Christine Frömming, Volker Grewe, Sabine Brinkop, Patrick Jöckel, Amund S. Haslerud, Simon Rosanka, Jesper van Manen, and Sigrun Matthes
Atmos. Chem. Phys., 21, 9151–9172, https://doi.org/10.5194/acp-21-9151-2021, https://doi.org/10.5194/acp-21-9151-2021, 2021
Short summary
Short summary
The influence of weather situations on non-CO2 aviation climate impact is investigated to identify systematic weather-related sensitivities. If aircraft avoid the most sensitive areas, climate impact might be reduced. Enhanced significance is found for emission in relation to high-pressure systems, jet stream, polar night, and tropopause altitude. The results represent a comprehensive data set for studies aiming at weather-dependent flight trajectory optimization to reduce total climate impact.
Keiran Nicholas Rowell, Scott Henderson Kable, and Meredith Jane Trevenar Jordan
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-424, https://doi.org/10.5194/acp-2021-424, 2021
Revised manuscript accepted for ACP
Short summary
Short summary
Sunlight drives chemical reactions in the atmosphere by breaking chemical bonds. Motivated by the knowledge that, if we can better understand the fundamental chemistry, we will be better able to predict atmospheric composition and model any future changes, we use quantum chemistry to investigate new classes of atmospheric reactions. We identify several potentially important reaction classes that will have implications to the atmospheric production of organic acids and molecular hydrogen.
Jianing Dai and Tao Wang
Atmos. Chem. Phys., 21, 8747–8759, https://doi.org/10.5194/acp-21-8747-2021, https://doi.org/10.5194/acp-21-8747-2021, 2021
Short summary
Short summary
We used the WRF–Chem model with the latest HONO and ClNO2 processes to investigate their effects on the concentrations of ROx radicals, O3, and PM2.5 in Asia during summer. The results show that the ship-derived HONO and ClNO2 increased the ROx radical concentration by 2–3 times and subsequently increased the O3 and PM2.5 concentrations in marine areas. These findings indicate the importance of these nitrogen processes in the evaluation of the impact of ship emissions on air quality.
Anoop S. Mahajan, Qinyi Li, Swaleha Inamdar, Kirpa Ram, Alba Badia, and Alfonso Saiz-Lopez
Atmos. Chem. Phys., 21, 8437–8454, https://doi.org/10.5194/acp-21-8437-2021, https://doi.org/10.5194/acp-21-8437-2021, 2021
Short summary
Short summary
Using a regional model, we show that iodine-catalysed reactions cause large regional changes in the chemical composition in the northern Indian Ocean, with peak changes of up to 25 % in O3, 50 % in nitrogen oxides (NO and NO2), 15 % in hydroxyl radicals (OH), 25 % in hydroperoxyl radicals (HO2), and up to a 50 % change in the nitrate radical (NO3). These results show the importance of including iodine chemistry in modelling the atmosphere in this region.
Maximilian Herrmann, Holger Sihler, Udo Frieß, Thomas Wagner, Ulrich Platt, and Eva Gutheil
Atmos. Chem. Phys., 21, 7611–7638, https://doi.org/10.5194/acp-21-7611-2021, https://doi.org/10.5194/acp-21-7611-2021, 2021
Short summary
Short summary
Time-dependent 3D numerical simulations of tropospheric bromine release and ozone depletion events (ODEs) in the Arctic polar spring of 2009 are compared to observations. Simulation results agree well with the observations at both Utqiaġvik, Alaska, and at Summit, Greenland. In a parameter study, different settings for the bromine release mechanism are evaluated. An enhancement of the bromine release mechanism improves the agreement regarding the occurrence of ODEs with the observations.
Ashok K. Luhar, Ian E. Galbally, Matthew T. Woodhouse, and Nathan Luke Abraham
Atmos. Chem. Phys., 21, 7053–7082, https://doi.org/10.5194/acp-21-7053-2021, https://doi.org/10.5194/acp-21-7053-2021, 2021
Short summary
Short summary
Lightning-generated nitrogen oxides (LNOx) greatly influence tropospheric photochemistry. The most common parameterisation of lightning flash rate used to calculate LNOx in global composition models underestimates measurements over the ocean by a factor of 20–25. We formulate and validate an alternative parameterisation to remedy this problem. The new scheme causes an increase in the ozone burden by 8.5 % and the hydroxyl radical by 13 %, and these have implications for climate and air quality.
Daniel M. Westervelt, Arlene M. Fiore, Colleen B. Baublitz, and Gustavo Correa
Atmos. Chem. Phys., 21, 6799–6810, https://doi.org/10.5194/acp-21-6799-2021, https://doi.org/10.5194/acp-21-6799-2021, 2021
Short summary
Short summary
Particulate air pollution in the atmosphere can impact the availability of gas-phase chemical constituents, which can then have feedbacks on gas-phase air pollutants. We use a chemistry–climate computer model to simulate the impact of particulate pollution from three major world regions on gas-phase chemical constituents. We find that surface-level ozone air pollution decreases by up to 5 ppbv over China in response to Chinese particulate air pollution, which has implications for policy.
Gabriel Isaacman-VanWertz and Bernard Aumont
Atmos. Chem. Phys., 21, 6541–6563, https://doi.org/10.5194/acp-21-6541-2021, https://doi.org/10.5194/acp-21-6541-2021, 2021
Short summary
Short summary
There are tens of thousands of different chemical compounds in the atmosphere. To tackle this complexity, there are a wide range of different methods to estimate their physical and chemical properties. We use these methods to understand how much the detailed structure of a molecule impacts its properties, and the extent to which properties can be estimated without knowing this level of detail. We find that structure matters, but methods lacking that level of detail still perform reasonably well.
Daniel C. Anderson, Bryan N. Duncan, Arlene M. Fiore, Colleen B. Baublitz, Melanie B. Follette-Cook, Julie M. Nicely, and Glenn M. Wolfe
Atmos. Chem. Phys., 21, 6481–6508, https://doi.org/10.5194/acp-21-6481-2021, https://doi.org/10.5194/acp-21-6481-2021, 2021
Short summary
Short summary
We demonstrate that large-scale climate features are the primary driver of year-to-year variability in simulated values of the hydroxyl radical, the primary atmospheric oxidant, over 1980–2018. The El Niño–Southern Oscillation is the dominant mode of hydroxyl variability, resulting in large-scale global decreases in OH during El Niño events. Other climate modes, such as the Australian monsoon and the North Atlantic Oscillation, have impacts of similar magnitude but on on more localized scales.
Pooja V. Pawar, Sachin D. Ghude, Chinmay Jena, Andrea Móring, Mark A. Sutton, Santosh Kulkarni, Deen Mani Lal, Divya Surendran, Martin Van Damme, Lieven Clarisse, Pierre-François Coheur, Xuejun Liu, Gaurav Govardhan, Wen Xu, Jize Jiang, and Tapan Kumar Adhya
Atmos. Chem. Phys., 21, 6389–6409, https://doi.org/10.5194/acp-21-6389-2021, https://doi.org/10.5194/acp-21-6389-2021, 2021
Short summary
Short summary
In this study, simulations of atmospheric ammonia (NH3) with MOZART-4 and HTAP-v2 are compared with satellite (IASI) and ground-based measurements to understand the spatial and temporal variability of NH3 over two emission hotspot regions of Asia, the IGP and the NCP. Our simulations indicate that the formation of ammonium aerosols is quicker over the NCP than the IGP, leading to smaller NH3 columns over the higher NH3-emitting NCP compared to the IGP region for comparable emissions.
Cited articles
Ahlm, L., Nilsson, E. D., Krejci, R., Mårtensson, E. M., Vogt, M., and Artaxo, P.: Aerosol number fluxes over the Amazon rain forest during the wet season, Atmos. Chem. Phys., 9, 9381–9400, https://doi.org/10.5194/acp-9-9381-2009, 2009.
Andreae, M. O. and Merlet, P.: Emission of trace gases and aerosols from biomass burning, Global Biogeochem. Cy., 15, 955–966, https://doi.org/10.1029/2000GB001382, 2001.
Angelbratt, J., Mellqvist, J., Simpson, D., Jonson, J. E., Blumenstock, T., Borsdorff, T., Duchatelet, P., Forster, F., Hase, F., Mahieu, E., De Mazière, M., Notholt, J., Petersen, A. K., Raffalski, U., Servais, C., Sussmann, R., Warneke, T., and Vigouroux, C.: Carbon monoxide (CO) and ethane (C2H6) trends from ground-based solar FTIR measurements at six European stations, comparison and sensitivity analysis with the EMEP model, Atmos. Chem. Phys., 11, 9253–9269, https://doi.org/10.5194/acp-11-9253-2011, 2011.
Bekki, S., Law, K. S., and Pyle, J. A.: Effect of ozone depletion on atmospheric methane and CO concentrations, Nature, 371, 595–597, https://doi.org/10.1038/371595a0, 1994.
Bergamaschi, P., Hein, R., Heimann, M., and Crutzen, P. J.: Inverse modeling of the global CO cycle: 1. Inversion of CO mixing ratios, J. Geophys. Res.-Atmos., 105, 1909–1927, https://doi.org/10.1029/1999JD900818, 2000.
Bovensmann, H., Burrows, J. P., Buchwitz, M., Frerick, J., Noël, S., Rozanov, V. V., Chance, K. V., and Goede, A. P. H.: SCIAMACHY – Mission Objectives and Measurement Modes. J. Atmos. Sci., 56, 127–150, https://doi.org/10.1175/1520-0469(1999)056<0127:SMOAMM>2.0.CO;2, 1999.
Buchwitz, M., de Beek, R., Bramstedt, K., Noël, S., Bovensmann, H., and Burrows, J. P.: Global carbon monoxide as retrieved from SCIAMACHY by WFM-DOAS, Atmos. Chem. Phys., 4, 1945–1960, https://doi.org/10.5194/acp-4-1945-2004, 2004.
Buchwitz, M., de Beek, R., Noël, S., Burrows, J. P., Bovensmann, H., Bremer, H., Bergamaschi, P., Körner, S., and Heimann, M.: Carbon monoxide, methane and carbon dioxide columns retrieved from SCIAMACHY by WFM-DOAS: year 2003 initial data set, Atmos. Chem. Phys., 5, 3313–3329, https://doi.org/10.5194/acp-5-3313-2005, 2005.
Buchwitz, M., Khlystova, I., Bovensmann, H., and Burrows, J. P.: Three years of global carbon monoxide from SCIAMACHY: comparison with MOPITT and first results related to the detection of enhanced CO over cities, Atmos. Chem. Phys., 7, 2399–2411, https://doi.org/10.5194/acp-7-2399-2007, 2007.
Burrows, J. P., Hölzle, E., Goede, A. P. H., Visser, H., and Fricke, W.: SCIAMACHY – Scanning Imaging Absorption Spectrometer for Atmospheric Chartography, Acta Astronaut., 35, 445–451, 1995.
Burrows, J. P., Goede, A. P. H., Muller, C., and Bovensmann, H.: SCIAMACHY – The Need for Atmospheric Research from Space, in: SCIAMACHY – Exploring the Changing Earth's Atmosphere, edited by: Gottwald, M. and Bovensmann, H., Springer Science + Business Media B.V., Dordrecht, the Netherlands, 1–17, https://doi.org/10.1007/978-90-481-9896-2_1, 2011.
Butler, T. M., Stock, Z. S., Russo, M. R., Denier van der Gon, H. A. C., and Lawrence, M. G.: Megacity ozone air quality under four alternative future scenarios, Atmos. Chem. Phys., 12, 4413–4428, https://doi.org/10.5194/acp-12-4413-2012, 2012.
Chandra, S., Ziemke, J. R., Duncan, B. N., Diehl, T. L., Livesey, N. J., and Froidevaux, L.: Effects of the 2006 El Niño on tropospheric ozone and carbon monoxide: implications for dynamics and biomass burning, Atmos. Chem. Phys., 9, 4239–4249, https://doi.org/10.5194/acp-9-4239-2009, 2009.
Clerbaux, C., Hadji-Lazaro, J., Payan, S., Camy-Peyret, C., and Mégie, G.: Retrieval of CO columns from IMG/ADEOS spectra, IEEE T. Geosci. Remote, 37, 1657–1661, 1999.
Clerbaux, C., Boynard, A., Clarisse, L., George, M., Hadji-Lazaro, J., Herbin, H., Hurtmans, D., Pommier, M., Razavi, A., Turquety, S., Wespes, C., and Coheur, P.-F.: Monitoring of atmospheric composition using the thermal infrared IASI/MetOp sounder, Atmos. Chem. Phys., 9, 6041–6054, https://doi.org/10.5194/acp-9-6041-2009, 2009.
Crutzen, P. J.: Photochemical reactions initiated by and influencing ozone in unpolluted tropospheric air, Tellus, 26, 47–57, 1974.
Crutzen, P. J. and Gidel, L. T.: A two-dimensional photochemical model of the atmosphere. 2: The tropospheric budgets of anthropogenic chlorocarbons CO, CH4, CH3Cl and the effect of various. NOx sources on tropospheric ozone, J. Geophys. Res., 88, 6641–6661, 1983.
Davidson, E. A. and Artaxo, P.: Globally significant changes in biological processes of the Amazon Basin: Results of the Large-scale Biosphere-Atmosphere Experiment, Global Change Biol., 10, 1–11, https://doi.org/10.1111/j.1529-8817.2003.00779.x, 2004.
Deeter, M. N., Emmons, L. K., Francis, G. L., Edwards, D. P., Gille, J. C., Warner, J. X., Khattatov, B., Ziskin, D., Lamarque, J.-F., Ho, S.-P., Yudin, V., Attié, J.-L., Packman, D., Chen, J., Mao, D., and Drummond, J. R.: Operational carbon monoxide retrieval algorithm and selected results for the MOPITT instrument, J. Geophys. Res., 108, 4399, https://doi.org/10.1029/2002JD003186, 2003.
Deeter, M. N., Edwards, D. P., Gille, J. C., and Drummond, J. R.: Sensitivity of MOPITT observations to carbon monoxide in the lower troposphere. J. Geophys. Res., 112, 24306, https://doi.org/10.1029/2007JD008929, 2007.
Deeter, M. N., Edwards, D. P., Gille, J. C., Emmons, L. K., Francis, G., Ho, S.-P., Mao, D., Masters, D., Worden, H., Drummond, J. R., and Novelli, P. C.: The MOPITT version 4 CO product: Algorithm enhancements, validation, and long-term stability, J. Geophys. Res., 115, D07306, https://doi.org/10.1029/2009JD013005, 2010.
Deeter, M. N., Worden, H. M., Gille, J. C., Edwards, D. P., Mao, D., and Drummond, J. R.: MOPITT multispectral CO retrievals: Origins and effects of geophysical radiance errors, J. Geophys. Res., 116, D15303, https://doi.org/10.1029/2011JD015703, 2011.
Deeter, M. N., Worden, H. M., Edwards, D. P., Gille, J. C., and Andrews, A. E.: Evaluation of MOPITT Retrievals of Lowertropospheric Carbon Monoxide over the United States, J. Geophys. Res., 117, D13306, https://doi.org/10.1029/2012JD017553, 2012.
Deeter, M. N., Martínez-Alonso, S., Edwards, D. P., Emmons, L. K., Gille, J. C., Worden, H. M., Pittman, J. V., Daube, B. C., and Wofsy, S. C.: Validation of MOPITT Version 5 thermal-infrared, near-infrared, and multispectral carbon monoxide profile retrievals for 2000–2011, J. Geophys. Res., 118, 1–16, https://doi.org/10.1002/jgrd.50272, 2013.
de Laat, A. T. J., Gloudemans, A. M. S., Aben, I., Krol, M., Meirink, J. F., van der Werf, G. R., and Schrijver, H.: Scanning Imaging Absorption Spectrometer for Atmospheric Chartography carbon monoxide total columns: Statistical evaluation and comparison with chemistry transport model results, J. Geophys. Res., 112, D12310, https://doi.org/10.1029/2006JD008256, 2007.
de Meij, A., Pozzer, A., and Lelieveld, J.: Trend analysis in aerosol optical depths and pollutant emission estimates between 2000 and 2009, Atmos. Environ., 51, 75–85, https://doi.org/10.1016/j.atmosenv.2012.01.059, 2012.
Dlugokencky, E. J., Dutton, E. G., Novelli, P. C., Tans, P. P., Masarie, K. A., Lantz, K. O., and Madronich, S.: Changes in methane and CO growth rates after the eruption of Mt. Pinatubo and their link with changes in tropical tropospheric UV flux, Geophys. Res. Lett., 23, 2761–2764, https://doi.org/10.1029/96GL02638, 1996.
Drummond, J. R. and Mand, G. S.: The measurements of pollution in the troposphere (MOPITT) instrument: Overall performance and calibration requirements, J. Atmos. Ocean Tech., 13, 314–320, 1996.
Duncan, B. N. and Logan, J. A.: Model analysis of the factors regulating the trends and variability of carbon monoxide between 1988 and 1997, Atmos. Chem. Phys., 8, 7389–7403, https://doi.org/10.5194/acp-8-7389-2008, 2008.
Duncan, B. N., Logan, J. A., Megretskaia, I. A., Yantosca, R. M., Novelli, P. C., Jones, N. B., and Rinsland, C. P.: The global budget of CO, 1988–1997: source estimates and validation with a global model, J. Geophys. Res.-Atmos., 112, D22301, https://doi.org/10.1029/2007JD008459, 2007.
Ehhalt, D., Prather, M., Dentener, F., Derwent, R., Dlugokencky, E., Holland, E., Isaksen, I., Katima, J., Kirchhoff, V., Matson, P., Midgley, P., and Wang, M.: Atmospheric chemistry and greenhouse gases, in: Climate Change 2001: The Scientific Basis, Contribution of Working Group I to the Third Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Houghton, J. T., Ding, Y., Griggs, D. J., Noguer, M., van der Linden, P. J., Dai, X., Maskell, K., and Johnson, C. A., Cambridge University Press, Cambridge, UK, 257–259, 2001.
Emmons, L. K., Deeter, M. N., Gille, J. C., Edwards, D. P., Attié, J.-L., Warner, J., Ziskin, D., Francis, G. , Khattatov, B., Yudin, V., Lamarque, J.-F., Ho, S.-P., Mao, D., Chen, J. S., Drummond, J., Novelli, P., Sachse, G., Coffey, M. T., Hannigan, J. W., Gerbig, C. , Kawakami, S., Kondo, Y., Takegawa, N., Schlager, H., Baehr, J., and Ziereis, H.: Validation of Measurements of Pollution in the Troposphere (MOPITT) CO retrievals with aircraft in situ profiles, J. Geophys. Res., 109, D03309, https://doi.org/10.1029/2003JD004101, 2004.
Eskes, H. J. and Boersma, K. F.: Averaging kernels for DOAS total-column satellite retrievals, Atmos. Chem. Phys., 3, 1285–1291, https://doi.org/10.5194/acp-3-1285-2003, 2003.
Facchini, M. C., Decesari, S., Mircea, M., Fuzzi, S., and Loglio, G.: Surface tension of atmospheric wet aerosol and cloud/fog droplets in relation to their organic carbon econtent and chemical composition, Atmos. Environ., 33, 4853–4857, 2000.
Fishman, J. and Crutzen, P. J.: the origin of ozone in the troposphere, Nature, 274, 855–858, 1978.
Forster, P., Ramaswamy, V., Artaxo, P., Berntsen, T., Betts, R., Fahey, D. W., Haywood, J., Lean, J., Lowe, D. C., Myhre, G., Nganga, J., Prinn, R., Raga, G., Schulz, M., and Van Dorland, R.: Changes in Atmospheric Constituents and in Radiative Forcing. In: Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Solomon, S., Qin, D., Manning, M., Chen, Z., Marquis, M., Averyt, K. B., Tignor, M., and Miller, H. L., Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 129–234, 2007.
George, M., Clerbaux, C., Hurtmans, D., Turquety, S., Coheur, P.-F., Pommier, M., Hadji-Lazaro, J., Edwards, D. P., Worden, H., Luo, M., Rinsland, C., and McMillan, W.: Carbon monoxide distributions from the IASI/METOP mission: evaluation with other space-borne remote sensors, Atmos. Chem. Phys., 9, 8317–8330, https://doi.org/10.5194/acp-9-8317-2009, 2009.
Giglio, L., Randerson, J. T., van der Werf, G. R., Kasibhatla, P. S., Collatz, G. J., Morton, D. C., and DeFries, R. S.: Assessing variability and long-term trends in burned area by merging multiple satellite fire products, Biogeosciences, 7, 1171–1186, https://doi.org/10.5194/bg-7-1171-2010, 2010.
Gomez-Pelaez, A. J., Ramos, R., Gomez-Trueba, V., Novelli, P. C., and Campo-Hernandez, R.: A statistical approach to quantify uncertainty in carbon monoxide measurements at the Izaña global GAW station: 2008–2011, Atmos. Meas. Tech., 6, 787–799, https://doi.org/10.5194/amt-6-787-2013, 2013.
Graniera, C., Müller, J. F., Pétron, G., and Brasseur, G.: A three-dimensional study of the global CO budget, Chemosphere, 1, 255–261, https://doi.org/10.1016/S1465-9972(99)00007-0, 1999.
Granier, C., Bessagnet, B., Bond, T., D'Angiola, A., van der Gon, H. D., Frost, G. J., Heil, A., Kaiser, J. W., Kinne, S., Klimont, Z., Kloster, S., Lamarque, J.-F., Liousse, C., Masui, T., Meleux, F., Mieville, A., Ohara, T., Raut, J.-C., Riahi, K., Schultz, M. G., Smith, S. J., Thompson, A., van Aardenne, J., van der Werf, G. R., and van Vuuren, D. P.: Evolution of anthropogenic and biomass burning emissions of air pollutants at global and regional scales during the 1980-2010 period, Clim. Change, 109, 163–190, https://doi.org/10.1007/s10584-011-0154-1, 2011.
Haas-Laursea, D. and Hartley, D.: Consistent sampling methods for comparing models to CO2 flask data, J. Geophys. Res., 102, 19059–19071, https://doi.org/10.1029/97JD00795, 1997.
Hauglustaine, D. A., Brasseur, G. P., Walters, S., Rasch, P. J., Müller, J.-F., Emmons, L. K., and Carroll, M. A.: MOZART, a global chemical transport model for ozone and related chemical tracers: 2. Model results and evaluation, J. Geophys. Res., 103, 28291–28335, https://doi.org/10.1029/98JD02398, 1998.
Held, I. M., Delworth, T. L., Lu, J., Findell, K. L., and Knutson, T. R.: Simulation of Sahel drought in the 20th and 21st centuries, P. Natl. Acad. Sci. USA, 102, 17891–17896, https://doi.org/10.1073/pnas.0509057102, 2005.
Hilboll, A., Richter, A., and Burrows, J. P.: Long-term changes of tropospheric NO2 over megacities derived from multiple satellite instruments, Atmos. Chem. Phys., 13, 4145–4169, https://doi.org/10.5194/acp-13-4145-2013, 2013.
Ho, S.-P., Edwards, D. P., Gille, J. C., Luo, M., Osterman, G. B., Kulawik, S. S., and Worden, H.: A global comparison of carbon monoxide profiles and column amounts from Tropospheric Emission Spectrometer (TES) and Measurements of Pollution in the Troposphere (MOPITT), J. Geophys. Res., 114, D21307, https://doi.org/10.1029/2009JD012242, 2009.
Hogrefe, C., Lynn, B., Civerolo, K., Ku, J., Rosenthal, J., Rosenzweig, C., Goldberg, R., Gaffin, S., Knowlton, K., and Kinney, P.: Simulating changes in regional air pollution over the eastern United States due to changes in global and regional climate and emissions, J. Geophys. Res, 109, D22301, https://doi.org/10.1029/2004JD004690, 2004.
Holloway, T., Levy II, H., and Kasibhatla, P.: Global distribution of carbon monoxide, J. Geophys. Res., 105, 12123–12147, https://doi.org/10.1029/1999JD901173, 2000.
Hooghiemstra, P. B., Krol, M. C., Meirink, J. F., Bergamaschi, P., van der Werf, G. R., Novelli, P. C., Aben, I., and Röckmann, T.: Optimizing global CO emission estimates using a four-dimensional variational data assimilation system and surface network observations, Atmos. Chem. Phys., 11, 4705–4723, https://doi.org/10.5194/acp-11-4705-2011, 2011.
Hsu, N. C., Gautam, R., Sayer, A. M., Bettenhausen, C., Li, C., Jeong, M. J., Tsay, S.-C., and Holben, B. N.: Global and regional trends of aerosol optical depth over land and ocean using SeaWiFS measurements from 1997 to 2010, Atmos. Chem. Phys., 12, 8037–8053, https://doi.org/10.5194/acp-12-8037-2012, 2012.
Intergovernmental Panel on Climate Change (IPCC): Climate Change 1995, University Press, Cambridge, UK, 1996.
Jacobson, M. and Streets, D.: Influence of future anthropogenic emissions on climate, natural emissions, and air quality, J. Geophys. Res., 114, D08118, https://doi.org/10.1029/2008JD011476, 2009.
Jeuken, A. B. M., Siegmund, P. C., Heijboer, L. C., Feichter, J., and Bengtsson, L.: On the potential of assimilating meteorological analyses in a global climate model for the purpose of model validation, J. Geophys. Res., 101, 16939–16950, https://doi.org/10.1029/96JD01218, 1996.
Jöckel, P., Tost, H., Pozzer, A., Brühl, C., Buchholz, J., Ganzeveld, L., Hoor, P., Kerkweg, A., Lawrence, M. G., Sander, R., Steil, B., Stiller, G., Tanarhte, M., Taraborrelli, D., van Aardenne, J., and Lelieveld, J.: The atmospheric chemistry general circulation model ECHAM5/MESSy1: consistent simulation of ozone from the surface to the mesosphere, Atmos. Chem. Phys., 6, 5067–5104, https://doi.org/10.5194/acp-6-5067-2006, 2006.
Jöckel, P., Kerkweg, A., Pozzer, A., Sander, R., Tost, H., Riede, H., Baumgaertner, A., Gromov, S., and Kern, B.: Development cycle 2 of the Modular Earth Submodel System (MESSy2), Geosci. Model Dev., 3, 717–752, https://doi.org/10.5194/gmd-3-717-2010, 2010.
Johnson, B. T., Osborne, S. R., Haywood, J. M., and Harrison, M. A. J.: Aircraft measurements of biomass burning aerosol over West Africa during DABEX, J. Geophys. Res., 113, D00C06, https://doi.org/10.1029/2007JD009451, 2008.
Khalil, M. A. K. and Rasmussen, R. A.: Carbon monoxide in the Earth's atmosphere: indications of a global increase, Nature, 332, 242–245, https://doi.org/10.1038/332242a0, 1988.
Khalil, M. A. K. and Rasmussen, R. A.: The global cycle of carbon monoxide: trends and mass balance, Chemosphere, 20, 227–242, 1990.
Kirby, K. R., Laurance, W. F., Albernaz, A. K., Schroth, G., Fearnside, P. M., Bergen, S., Venticinque, E. M., and da Costa, C.: The future of deforestation in the Brazilian Amazon, Futures, 38, 432–453, https://doi.org/10.1016/j.futures.2005.07.011, 2006.
Klonecki, A., Pommier, M., Clerbaux, C., Ancellet, G., Cammas, J.-P., Coheur, P.-F., Cozic, A., Diskin, G. S., Hadji-Lazaro, J., Hauglustaine, D. A., Hurtmans, D., Khattatov, B., Lamarque, J.-F., Law, K. S., Nedelec, P., Paris, J.-D., Podolske, J. R., Prunet, P., Schlager, H., Szopa, S., and Turquety, S.: Assimilation of IASI satellite CO fields into a global chemistry transport model for validation against aircraft measurements, Atmos. Chem. Phys., 12, 4493–4512, https://doi.org/10.5194/acp-12-4493-2012, 2012.
Kopacz, M., Jacob, D. J., Fisher, J. A., Logan, J. A., Zhang, L., Megretskaia, I. A., Yantosca, R. M., Singh, K., Henze, D. K., Burrows, J. P., Buchwitz, M., Khlystova, I., McMillan, W. W., Gille, J. C., Edwards, D. P., Eldering, A., Thouret, V., and Nedelec, P.: Global estimates of CO sources with high resolution by adjoint inversion of multiple satellite datasets (MOPITT, AIRS, SCIAMACHY, TES), Atmos. Chem. Phys., 10, 855–876, https://doi.org/10.5194/acp-10-855-2010, 2010.
Latif, M. and Keenlyside, N. S.: El Niño/Southern Oscillation response to global warming, P. Natl. Acad. Sci. USA, 106, 20578–20583, https://doi.org/10.1073/pnas.0710860105, 2009.
Law, K. S.: Theoretical studies of carbon monoxide distributions, budgets and trends, Chemosphere – Global Change Science, 1, 19–31, https://doi.org/10.1016/S1465-9972(99)00020-3, 1999.
Lawrence, M. G., Jöckel, P., and von Kuhlmann, R.: What does the global mean OH concentration tell us?, Atmos. Chem. Phys., 1, 37–49, https://doi.org/10.5194/acp-1-37-2001, 2001.
Leggett, J., Pepper, W. J., and Swart, R. J.: Emissions scenarios for the IPCC: an update, in: Climate Change 1992: The Supplementary Report to the IPCC Scientific Assessment, prepared by: IPCC Working Group I, edited by: Houghton, J. T., Callander, B. A., and Varney, S. K. and WMO/UNEP, Cambridge University Press, Cambridge, UK, and New York, NY, USA, 1992.
Lelieveld, J., Peters, W., Dentener, F. J., and Krol, M. C.: Stability of tropospheric hydroxyl chemistry, J. Geophys. Res., 107, ACH 17-1–ACH 17-11, https://doi.org/10.1029/2002JD002272, 2002.
Lelieveld, J., Dentener, F. J., Peters, W., and Krol, M. C.: On the role of hydroxyl radicals in the self-cleansing capacity of the troposphere, Atmos. Chem. Phys., 4, 2337–2344, https://doi.org/10.5194/acp-4-2337-2004, 2004.
Lelieveld, J., Barlas, C., Giannadaki, D., and Pozzer, A.: Model calculated global, regional and megacity premature mortality due to air pollution, Atmos. Chem. Phys., 13, 7023–7037, https://doi.org/10.5194/acp-13-7023-2013, 2013.
Levy, H.: Normal atmosphere: large radical and formaldehyde concentrations predicted, Science, 173, 141–143, https://doi.org/10.1126/science.173.3992.141, 1971.
Junhua Liu, Logan, J. A., Jones, D. B. A., Livesey, N. J., Megretskaia, I., Carouge, C., and Nedelec, P.: Analysis of CO in the tropical troposphere using Aura satellite data and the GEOS-Chem model: insights into transport characteristics of the GEOS meteorological products, Atmos. Chem. Phys., 10, 12207–12232, https://doi.org/10.5194/acp-10-12207-2010, 2010.
Logan, J. A., Prather, M. J., Wofsy, S. C., and McElroy, M. B.: Tropospheric chemistry: A global perspective, J. Geophys. Res., 86, 7210–7254, https://doi.org/10.1029/JC086iC08p07210, 1981.
Lu, Z., Streets, D. G., Zhang, Q., Wang, S., Carmichael, G. R., Cheng, Y. F., Wei, C., Chin, M., Diehl, T., and Tan, Q.: Sulfur dioxide emissions in China and sulfur trends in East Asia since 2000, Atmos. Chem. Phys., 10, 6311–6331, https://doi.org/10.5194/acp-10-6311-2010, 2010.
Luo, M., Rinsland, C. P., Rodgers, C. D., Logan, J. A., Worden, H., Kulawik, S., Eldering, A., Goldman, A., Shephard, M. W., Gunson, M., and Lampel, M.: TES carbon monoxide validation with DACOM aircraft measurements during INTEX-B 2006, J. Geophys. Res., 112, D24S48, https://doi.org/10.1029/2007JD008803, 2007a.
Luo, M., Rinsland, C. P., Rodgers, C. D., Logan, J. A., Worden, H., Kulawik, S., Eldering, A., Goldman, A., Shephard, M. W., Gunson, M., and Lampel, M.: Comparison of carbon monoxide measurements by TES and MOPITT: Influence of a priori data and instrument characteristics on nadir atmospheric species retrievals, J. Geophys. Res., 112, D09303, https://doi.org/10.1029/2006JD007663, 2007b.
McFiggans, G., Alfarra, M., Allan, J., Bower, K., and Coe, H.: Simplification of the representation of the organic component of atmospheric particulates, Faraday Discuss., 130, 341–362, https://doi.org/10.1039/b419435g, 2005.
Meehl, G. A., Covey, C., Delworth, T., Latif, M., McAvaney, B., Mitchell, J. F. B., Stouffer, R. J., and Taylor, K. E.: The WCRP CMIP3 multimodel dataset: A new era in climate change research, B. Am. Meteorol. Soc., 88, 1383–1394, https://doi.org/10.1175/BAMS-88-9-1383, 2007.
Meinshausen, M., Smith, S. J., Calvin, K., Daniel, J. S., Kainuma, M. L. T., Lamarque, J.-F., Matsumoto, K., Montzka, S. A., Raper, S. C. B., Riahi, K., Thomson, A., Velders, G. J. M., and van Vuuren, D. P. P.: The RCP greenhouse gas concentrations and their extensions from 1765 to 2300, Clim. Change, 109, 213–241, https://doi.org/10.1007/s10584-011-0156-z, 2011.
Nakicenovic, N., Alcamo, J., Davis, G., De Vries, B., Fenhann, J., Gaffin, S., Gregory, K., Grübler, A., Jung, T. Y., Kram, T., Lebre La Rovere, E., Michaelis, L., Mori, S., Morita, T., Pepper, W., Pitcher, H., Price, L., Riahi, K., Roehrl, A., Rogner, H. H., Sankovski, A., Schlesinger, M., Priyadarshi Shukla, P., Smith, S., Swart, R., Van Rooijen, S., Victor, N., and Dadi, Z.: Special Report on Emissions Scenarios, Intergovernmental Panel on Climate Change, 599 pp., Cambridge University press, Cambridge, United Kingdom and New York, USA, 2000.
Novelli, P. C., Steele, L. P., and Tans, P. P.: Mixing ratios of carbon monoxide in the troposphere, J. Geophys. Res., 97, 20731–20750, https://doi.org/10.1029/92JD02010, 1992.
Novelli, P. C., Masarie, K. A., Tans, P. P., and Lang, P. M.: Recent Changes in Atmospheric Carbon Monoxide, Science, 263, 1587–1590, https://doi.org/10.1126/science.263.5153.1587, 1994.
Novelli, P. C., Masarie, K. A., Lang, P. M., Hall, B. D., Myers, R. C., and Elkins, J. W.: Reanalysis of tropospheric CO trends: Effects of the 1997–1998 wildfires, J. Geophys. Res., 108, 4464, https://doi.org/10.1029/2002JD003031, 2003.
Ohara, T., Akimoto, H., Kurokawa, J., Horii, N., Yamaji, K., Yan, X., and Hayasaka, T.: An Asian emission inventory of anthropogenic emission sources for the period 1980–2020, Atmos. Chem. Phys., 7, 4419–4444, https://doi.org/10.5194/acp-7-4419-2007, 2007.
Pan, L., Edwards, D. P., Gille, J. C., Smith, M. W., and Drummond, J. R.: Satellite remote sensing of tropospheric CO and CH4: forward model studies of the MOPITT instrument, Appl. Optics, 34, 6976–6988, https://doi.org/10.1364/AO.34.006976, 1995.
Pan, L., Gille, J. C., Edwards, D. P., Bailey, P. L., and Rodgers, C. D.: Retrieval of tropospheric carbon monoxide for the MOPITT experiment, J. Geophys. Res., 103, 32277–32290, https://doi.org/10.1029/98JD01828, 1998.
Pozzer, A., Jöckel, P., Tost, H., Sander, R., Ganzeveld, L., Kerkweg, A., and Lelieveld, J.: Simulating organic species with the global atmospheric chemistry general circulation model ECHAM5/MESSy1: a comparison of model results with observations, Atmos. Chem. Phys., 7, 2527–2550, https://doi.org/10.5194/acp-7-2527-2007, 2007.
Pozzer, A., Jöckel, P., and Van Aardenne, J.: The influence of the vertical distribution of emissions on tropospheric chemistry, Atmos. Chem. Phys., 9, 9417–9432, https://doi.org/10.5194/acp-9-9417-2009, 2009.
Pozzer, A., de Meij, A., Pringle, K. J., Tost, H., Doering, U. M., van Aardenne, J., and Lelieveld, J.: Distributions and regional budgets of aerosols and their precursors simulated with the EMAC chemistry-climate model, Atmos. Chem. Phys., 12, 961–987, https://doi.org/10.5194/acp-12-961-2012, 2012a.
Pozzer, A., Zimmermann, P., Doering, U. M., van Aardenne, J., Tost, H., Dentener, F., Janssens-Maenhout, G., and Lelieveld, J.: Effects of business-as-usual anthropogenic emissions on air quality, Atmos. Chem. Phys., 12, 6915–6937, https://doi.org/10.5194/acp-12-6915-2012, 2012b.
Rasmusson, E. M. and Carpenter, T. H.: Variations in Tropical Sea Surface Temperature and Surface Wind Fields Associated with the Southern Oscillation/El Niño, Mon. Weather Rev., 110, 354–384, https://doi.org/10.1175/1520-0493(1982)110<0354:VITSST>2.0.CO;2, 1982.
Reeves, C. E., Formenti, P., Afif, C., Ancellet, G., Attié, J.-L., Bechara, J., Borbon, A., Cairo, F., Coe, H., Crumeyrolle, S., Fierli, F., Flamant, C., Gomes, L., Hamburger, T., Jambert, C., Law, K. S., Mari, C., Jones, R. L., Matsuki, A., Mead, M. I., Methven, J., Mills, G. P., Minikin, A., Murphy, J. G., Nielsen, J. K., Oram, D. E., Parker, D. J., Richter, A., Schlager, H., Schwarzenboeck, A., and Thouret, V.: Chemical and aerosol characterisation of the troposphere over West Africa during the monsoon period as part of AMMA, Atmos. Chem. Phys., 10, 7575–7601, https://doi.org/10.5194/acp-10-7575-2010, 2010.
Riahi, K., Gruebler, A., and Nakicenovic, N.: Scenarios of long-term socio-economic and environmental development under climate stabilization, Technol. Forecast. Soc., 74, 887–935, https://doi.org/10.1016/j.techfore.2006.05.026, 2007.
Richter, A., Burrows, J. P., Nüß, H., Granier, C., and Niemeier, U.: Increase in tropospheric nitrogen dioxide over China observed from space, Nature Letters, 437, 129–132, https://doi.org/10.1038/nature04092, 2005.
Rieder, H. E., Frossard, L., Ribatet, M., Staehelin, J., Maeder, J. A., Di Rocco, S., Davison, A. C., Peter, T., Weihs, P., and Holawe, F.: On the relationship between total ozone and atmospheric dynamics and chemistry at mid-latitudes – Part 2: The effects of the El Niño/Southern Oscillation, volcanic eruptions and contributions of atmospheric dynamics and chemistry to long-term total ozone changes, Atmos. Chem. Phys., 13, 165–179, https://doi.org/10.5194/acp-13-165-2013, 2013.
Rodgers, C. D.: Inverse methods for atmospheric sounding – theory and practice, Series on Atmospheric, Oceanic and Planetary Physics, World Scientific Publishing, Singapore, 2000.
Rodgers, C. D. and Connor, B. J.: Intercomparison of Remote Sounding Instruments, J. Geophys. Res., 108, 4116, https://doi.org/10.1029/2002JD002299, 2003.
Roeckner, E., Brokopf, R., Esch, M., Giorgetta, M., Hagemann, S., Kornblueh, L., Manzini, E., Schlese, U., and Schulzweida, U.: Sensitivity of simulated climate to horizontal and vertical resolution in the ECHAM5 atmosphere model, J. Climate, 19, 3771–3791, https://doi.org/10.1175/JCLI3824.1, 2006.
Smith, S. J., Pitcher, H., and Wigley, T. M. L.: Global and regional anthropogenic sulfur dioxide emissions, Global Planet. Change, 29, 99–119, https://doi.org/10.1016/S0921-8181(00)00057-6, 2001.
Streets, D. G., Bond, T. C., Carmichael, G. R., Fernandes, S. D., Fu, Q., He, D., Klimont, Z., Nelson, S. M., Tsai, N. Y., Wang, M. Q., Woo, J. -H., and Yarber, K. F.: An inventory of gaseous and primary aerosol emissions in Asia in the year 2000, J. Geophys. Res., 108, 8809, https://doi.org/10.1029/2002JD003093, 2003.
Streets, D. G., Wu, Y., and Chin, M.: Two-decadal aerosol trends as a likely explanation of the global dimming/brightening transition, Geophys. Res. Lett., 33, L15806, https://doi.org/10.1029/2006GL026471, 2006.
Taylor, K. E.: Summarizing multiple aspects of model performance in a single diagram, J. Geophys. Res., 106, 7183–7192, https://doi.org/10.1029/2000JD900719, 2001.
Thompson, A. M.: The oxidizing capacity of the Earth's atmosphere-Probable past and future changes, Science, 256, 1157–1165, https://doi.org/10.1126/science.256.5060.1157, 1992.
Thompson, A. M. and Cicerone, R. J.: Possible perturbations to atmospheric CO, CH4, and OH, J. Geophys. Res., 91, 10853–10864, https://doi.org/10.1029/JD091iD10p10853, 1986.
Tiao, G. C., Reinsel, G. C., Xu, D., Pedrick, J. H., Zhu, X., Miller, A. J., DeLuisi, J. J., Mateer, C. L., and Wuebbles, D. J.: Effects of autocorrelation and temporal sampling schemes on estimates of trend and spatial correlation, J. Geophys. Res., 95, 20507–20517, https://doi.org/10.1029/JD095iD12p20507, 1990.
Tohjima, Y., Kubo, M., Minejima, C., Mukai, H., Tanimoto, H., Ganshin, A., Maksyutov, S., Katsumata, K., Machida, T., and Kita, K.: Temporal changes in the emissions of CH4 and CO from China estimated from CH4 / CO2 and CO / CO2 correlations observed at Hateruma Island, Atmos. Chem. Phys., 14, 1663–1677, https://doi.org/10.5194/acp-14-1663-2014, 2014.
Trenberth, K. E., Caron, J. M., Stepaniak, D. P., and Worley, S.: Evolution of El Niño-Southern Oscillation and global atmospheric surface temperatures, J. Geophys. Res., 107, 4065, https://doi.org/10.1029/2000JD000298, 2002.
University of Toronto and NCAR MOPITT Team: MOPITT (Measurement of Pollution in the Troposphere) Level 1 Algorithm Theoretical Basis Documents, ATBD-MOP-01, University of Toronto and NCAR MOPITT Team, http://eospso.gsfc.nasa.gov/sites/default/files/atbd/atbd-mop-01.pdf (last access: 19 September 2014), 1–45, August, 1996.
van der Werf, G. R., Randerson, J. T., Giglio, L., Collatz, G. J., Mu, M., Kasibhatla, P. S., Morton, D. C., DeFries, R. S., Jin, Y., and van Leeuwen, T. T.: Global fire emissions and the contribution of deforestation, savanna, forest, agricultural, and peat fires (1997–2009), Atmos. Chem. Phys., 10, 11707–11735, https://doi.org/10.5194/acp-10-11707-2010, 2010.
van Vuuren, D. P., Eickhout, B., Lucas, P. L., and den Elzen M. G. J.: Long-Term Multi-Gas Scenarios to Stabilise Radiative Forcing – Exploring Costs and Benefits Within an Integrated Assessment Framework, The Energy Journal, Special issue #3, 201–234, https://doi.org/10.5547/ISSN0195-6574-EJ-VolSI2006-NoSI3-10, 2006.
van Vuuren, D. P., den Elzen, M. G. J., Lucas, P. L., Eickhout, B., Strengers, B. J., van Ruijven, B., Wonink, S., and van Houdt, R.: Stabilizing greenhouse gas concentrations at low levels: an assessment of reduction strategies and costs, Clim. Change, 81, 119–159, https://doi.org/10.1007/s10584-006-9172-9, 2007.
van Vuuren, D. P., Edmonds, J. A., Kainuma, M., Riahi, K., Thomson, A. M., Hibbard, K., Hurtt, G. C., Kram, T., Krey, V., Lamarque, J.-F., Masui, T., Nakicenovic, M. M. N., Smith, S. J., and Rose, S.: The representative concentration pathways: an overview, Clim. Change, 109, 5–31, https://doi.org/10.1007/s10584-011-0148-z, 2011.
Wallace, J. M., and Hobbs, P. V.: Atmospheric Chemistry, in: Atmospheric Science, Second Edition: An Introductory Survey, edited by: Dmowska, R., Hartmann, D., and Rossby, H. T., Elsevier, MA, USA, California, USA, and London, UK, 153–207, 2006.
Weatherhead, E. C., Reinsel, G. C., Tiao, G. C., Meng, X.-L., Choi, D., Cheang, W.-K., Keller, T., DeLuisi, J., Wuebbles, D. J., Kerr, J. B., Miller, A. J., Oltmans, S. J., and Frederick, J. E.: Factors affecting the detection of trends: Statistical considerations and applications to environmental data, J. Geophys. Res., 103, 17149–17161, https://doi.org/10.1029/98JD00995, 1998.
Weatherhead, E. C., Stevermer, A. J., and Schwartz, B. E.: Detecting environmental changes and trends, Physics and Chemistry of the Earth, 27, 399–403, https://doi.org/10.1016/S1474-7065(02)00019-0, 2002.
WMO: Scientific Assessment of Ozone Depletion: 1998. Global Ozone Research and Monitoring Project – Report No. 44, World Meteorological Organization, Geneva, Switzerland, 732 pp., 1999.
WMO: Revision of the World Data Centre for Greenhouse Gases Data Submission and Dissemination Guide, GAW Report No. 188, WMO TD No.1507, World Meteorological Organization, Geneva, Switzerland, 49 pp., 2009.
Worden, H. M., Deeter, M. N., Edwards, D. P., Gille, J. C., Drummond, J. R., and Nédélec, P. P.: Observations of near-surface carbon monoxide from space using MOPITT multispectral retrievals, J. Geophys. Res., 115, D18314, https://doi.org/10.1029/2010JD014242, 2010.
Worden, H. M., Deeter, M. N., Frankenberg, C., George, M., Nichitiu, F., Worden, J., Aben, I., Bowman, K. W., Clerbaux, C., Coheur, P. F., de Laat, A. T. J., Detweiler, R., Drummond, J. R., Edwards, D. P., Gille, J. C., Hurtmans, D., Luo, M., Martínez-Alonso, S., Massie, S., Pfister, G., and Warner, J. X.: Decadal record of satellite carbon monoxide observations, Atmos. Chem. Phys., 13, 837–850, https://doi.org/10.5194/acp-13-837-2013, 2013.
Xu, X., Lin, W., Wang, T., Yan, P., Tang, J., Meng, Z., and Wang, Y.: Long-term trend of surface ozone at a regional background station in eastern China 1991–2006: enhanced variability, Atmos. Chem. Phys., 8, 2595–2607, https://doi.org/10.5194/acp-8-2595-2008, 2008.
Yoon, J., von Hoyningen-Huene, W., Vountas, M., and Burrows, J. P.: Analysis of linear long-term trend of aerosol optical thickness derived from SeaWiFS using BAER over Europe and South China, Atmos. Chem. Phys., 11, 12149–12167, https://doi.org/10.5194/acp-11-12149-2011, 2011.
Yoon, J., von Hoyningen-Huene, W., Kokhanovsky, A. A., Vountas, M., and Burrows, J. P.: Trend analysis of aerosol optical thickness and Ångström exponent derived from the global AERONET spectral observations, Atmos. Meas. Tech., 5, 1271–1299, https://doi.org/10.5194/amt-5-1271-2012, 2012.
Yoon, J., Pozzer, A., Hoor, P., Chang, D. Y., Beirle, S., Wagner, T., Schloegl, S., Lelieveld, J., and Worden, H. M.: Technical Note: Temporal change in averaging kernels as a source of uncertainty in trend estimates of carbon monoxide retrieved from MOPITT, Atmos. Chem. Phys., 13, 11307–11316, https://doi.org/10.5194/acp-13-11307-2013, 2013.
Yoon, J., Burrows, J. P., Vountas, M., von Hoyningen-Huene, W., Chang, D. Y., Richter, A., and Hilboll, A.: Changes in atmospheric aerosol loading retrieved from space-based measurements during the past decade, Atmos. Chem. Phys., 14, 6881–6902, https://doi.org/10.5194/acp-14-6881-2014, 2014.
Zhang, Y., Yu, H., Eck, T. F., Smirnov, A., Chin, M., Remer, L. A., Bian, H., Tan, Q., Levy, R., Holben, B. N., and Piazzolla, S.: Aerosol Daytime Variations over North and South America Derived from Multiyear AERONET Measurements, J. Geophys. Res., 117, D05211, https://doi.org/10.1029/2011JD017242, 2012.
Zhao, T. X.-P., Laszlo, I., Guo, W., Heidinger, A., Cao, C., Jelenak, A., Tarpley, D., and Sullivan, J.: Study of long-term trend in aerosol optical thickness observed from operational AVHRR satellite instrument, J. Geophys. Res., 113, D07201, https://doi.org/10.1029/2007JD009061, 2008.
Altmetrics
Final-revised paper
Preprint