Articles | Volume 21, issue 10
https://doi.org/10.5194/acp-21-7773-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-7773-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Enhanced secondary organic aerosol formation from the photo-oxidation of mixed anthropogenic volatile organic compounds
Junling Li
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Hong Li
CORRESPONDING AUTHOR
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Yan Chen
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences, CAS
Research/Education Center for Excellence in Molecular Sciences, Institute of
Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Hao Zhang
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Xin Zhang
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Zhenhai Wu
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Yongchun Liu
Beijing Advanced Innovation Center for Soft Matter Science and
Engineering, Beijing University of Chemical Technology, Beijing 100029,
China
Xuezhong Wang
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Weigang Wang
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences, CAS
Research/Education Center for Excellence in Molecular Sciences, Institute of
Chemistry, Chinese Academy of Sciences, Beijing 100190, China
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences, CAS
Research/Education Center for Excellence in Molecular Sciences, Institute of
Chemistry, Chinese Academy of Sciences, Beijing 100190, China
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Ozone formation is enhanced by higher OH concentration and higher temperature but is influenced little by SO2. SO2 can largely enhance the particle formation. Organo-sulfates and organo-nitrates are detected in the formed particles, and the presence of SO2 can promote the formation of organo-sulfates. The results provide a scientific basis for systematically evaluating the effects of SO2, OH concentration, and temperature on the oxidation of mixed organic gases in the atmosphere.
Yishuo Guo, Chao Yan, Yuliang Liu, Xiaohui Qiao, Feixue Zheng, Ying Zhang, Ying Zhou, Chang Li, Xiaolong Fan, Zhuohui Lin, Zemin Feng, Yusheng Zhang, Penggang Zheng, Linhui Tian, Wei Nie, Zhe Wang, Dandan Huang, Kaspar R. Daellenbach, Lei Yao, Lubna Dada, Federico Bianchi, Jingkun Jiang, Yongchun Liu, Veli-Matti Kerminen, and Markku Kulmala
Atmos. Chem. Phys., 22, 10077–10097, https://doi.org/10.5194/acp-22-10077-2022, https://doi.org/10.5194/acp-22-10077-2022, 2022
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Gaseous oxygenated organic molecules (OOMs) are able to form atmospheric aerosols, which will impact on human health and climate change. Here, we find that OOMs in urban Beijing are dominated by anthropogenic sources, i.e. aromatic (29 %–41 %) and aliphatic (26 %–41 %) OOMs. They are also the main contributors to the condensational growth of secondary organic aerosols (SOAs). Therefore, the restriction on anthropogenic VOCs is crucial for the reduction of SOAs and haze formation.
Wei Ma, Zemin Feng, Junlei Zhan, Yongchun Liu, Pengfei Liu, Chengtang Liu, Qingxin Ma, Kang Yang, Yafei Wang, Hong He, Markku Kulmala, Yujing Mu, and Junfeng Liu
Atmos. Chem. Phys., 22, 4841–4851, https://doi.org/10.5194/acp-22-4841-2022, https://doi.org/10.5194/acp-22-4841-2022, 2022
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The influence of photochemical loss of volatile organic compounds (VOCS) on O3 formation is investigated using an observation-based model. The sensitivity regime of ozone formation might be misdiagnosed due to the photochemical loss of VOCs in the atmosphere. The contribution of local photochemistry is underestimated regarding O3 pollution when one does not consider the photochemical loss of VOCs.
Junlei Zhan, Yongchun Liu, Wei Ma, Xin Zhang, Xuezhong Wang, Fang Bi, Yujie Zhang, Zhenhai Wu, and Hong Li
Atmos. Meas. Tech., 15, 1511–1520, https://doi.org/10.5194/amt-15-1511-2022, https://doi.org/10.5194/amt-15-1511-2022, 2022
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Our study investigated the O3 formation sensitivity in Beijing using a random forest model coupled with the reactivity of volatile organic
compound (VOC) species. Results found that random forest accurately predicted O3 concentration when initial VOCs were considered, and relative importance correlated well with O3 formation potential. The O3 isopleth curves calculated by the random forest model were generally comparable with those calculated by the box model.
Jingwei Zhang, Chaofan Lian, Weigang Wang, Maofa Ge, Yitian Guo, Haiyan Ran, Yusheng Zhang, Feixue Zheng, Xiaolong Fan, Chao Yan, Kaspar R. Daellenbach, Yongchun Liu, Markku Kulmala, and Junling An
Atmos. Chem. Phys., 22, 3275–3302, https://doi.org/10.5194/acp-22-3275-2022, https://doi.org/10.5194/acp-22-3275-2022, 2022
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This study added six potential HONO sources to the WRF-Chem model, evaluated their impact on HONO and O3 concentrations, including surface and vertical concentrations. The simulations extend our knowledge on atmospheric HONO sources, especially for nitrate photolysis. The study also explains the HONO difference in O3 formation on clean and hazy days, and reveals key potential HONO sources to O3 enhancements in haze-aggravating processes with a co-occurrence of high PM2.5 and O3 concentrations.
Jing Cai, Cheng Wu, Jiandong Wang, Wei Du, Feixue Zheng, Simo Hakala, Xiaolong Fan, Biwu Chu, Lei Yao, Zemin Feng, Yongchun Liu, Yele Sun, Jun Zheng, Chao Yan, Federico Bianchi, Markku Kulmala, Claudia Mohr, and Kaspar R. Daellenbach
Atmos. Chem. Phys., 22, 1251–1269, https://doi.org/10.5194/acp-22-1251-2022, https://doi.org/10.5194/acp-22-1251-2022, 2022
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This study investigates the connection between organic aerosol (OA) molecular composition and particle absorptive properties in autumn in Beijing. We find that the molecular properties of OA compounds in different episodes influence particle light absorption properties differently: the light absorption enhancement of black carbon and light absorption coefficient of brown carbon were mostly related to more oxygenated OA (low C number and four O atoms) and aromatics/nitro-aromatics, respectively.
Ying Zhou, Simo Hakala, Chao Yan, Yang Gao, Xiaohong Yao, Biwu Chu, Tommy Chan, Juha Kangasluoma, Shahzad Gani, Jenni Kontkanen, Pauli Paasonen, Yongchun Liu, Tuukka Petäjä, Markku Kulmala, and Lubna Dada
Atmos. Chem. Phys., 21, 17885–17906, https://doi.org/10.5194/acp-21-17885-2021, https://doi.org/10.5194/acp-21-17885-2021, 2021
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We characterized the connection between new particle formation (NPF) events in terms of frequency, intensity and growth at a near-highway location in central Beijing and at a background mountain site 80 km away. Due to the substantial contribution of NPF to the global aerosol budget, identifying the conditions that promote the occurrence of regional NPF events could help understand their contribution on a large scale and would improve their implementation in global models.
Men Xia, Xiang Peng, Weihao Wang, Chuan Yu, Zhe Wang, Yee Jun Tham, Jianmin Chen, Hui Chen, Yujing Mu, Chenglong Zhang, Pengfei Liu, Likun Xue, Xinfeng Wang, Jian Gao, Hong Li, and Tao Wang
Atmos. Chem. Phys., 21, 15985–16000, https://doi.org/10.5194/acp-21-15985-2021, https://doi.org/10.5194/acp-21-15985-2021, 2021
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ClNO2 is an important precursor of chlorine radical that affects photochemistry. However, its production and impact are not well understood. Our study presents field observations of ClNO2 at three sites in northern China. These observations provide new insights into nighttime processes that produce ClNO2 and the significant impact of ClNO2 on secondary pollutions during daytime. The results improve the understanding of photochemical pollution in the lower part of the atmosphere.
Yongchun Liu, Zemin Feng, Feixue Zheng, Xiaolei Bao, Pengfei Liu, Yanli Ge, Yan Zhao, Tao Jiang, Yunwen Liao, Yusheng Zhang, Xiaolong Fan, Chao Yan, Biwu Chu, Yonghong Wang, Wei Du, Jing Cai, Federico Bianchi, Tuukka Petäjä, Yujing Mu, Hong He, and Markku Kulmala
Atmos. Chem. Phys., 21, 13269–13286, https://doi.org/10.5194/acp-21-13269-2021, https://doi.org/10.5194/acp-21-13269-2021, 2021
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The mechanisms and kinetics of particulate sulfate formation in the atmosphere are still open questions although they have been extensively discussed. We found that uptake of SO2 is the rate-determining step for the conversion of SO2 to particulate sulfate. NH4NO3 plays an important role in AWC, the phase state of aerosol particles, and subsequently the uptake kinetics of SO2 under high-RH conditions. This work is a good example of the feedback between aerosol physics and aerosol chemistry.
Zhuohui Lin, Yonghong Wang, Feixue Zheng, Ying Zhou, Yishuo Guo, Zemin Feng, Chang Li, Yusheng Zhang, Simo Hakala, Tommy Chan, Chao Yan, Kaspar R. Daellenbach, Biwu Chu, Lubna Dada, Juha Kangasluoma, Lei Yao, Xiaolong Fan, Wei Du, Jing Cai, Runlong Cai, Tom V. Kokkonen, Putian Zhou, Lili Wang, Tuukka Petäjä, Federico Bianchi, Veli-Matti Kerminen, Yongchun Liu, and Markku Kulmala
Atmos. Chem. Phys., 21, 12173–12187, https://doi.org/10.5194/acp-21-12173-2021, https://doi.org/10.5194/acp-21-12173-2021, 2021
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We find that ammonium nitrate and aerosol water content contributed most during low mixing layer height conditions; this may further trigger enhanced formation of sulfate and organic aerosol via heterogeneous reactions. The results of this study contribute towards a more detailed understanding of the aerosol–chemistry–radiation–boundary layer feedback that is likely to be responsible for explosive aerosol mass growth events in urban Beijing.
Xiaolong Fan, Jing Cai, Chao Yan, Jian Zhao, Yishuo Guo, Chang Li, Kaspar R. Dällenbach, Feixue Zheng, Zhuohui Lin, Biwu Chu, Yonghong Wang, Lubna Dada, Qiaozhi Zha, Wei Du, Jenni Kontkanen, Theo Kurtén, Siddhart Iyer, Joni T. Kujansuu, Tuukka Petäjä, Douglas R. Worsnop, Veli-Matti Kerminen, Yongchun Liu, Federico Bianchi, Yee Jun Tham, Lei Yao, and Markku Kulmala
Atmos. Chem. Phys., 21, 11437–11452, https://doi.org/10.5194/acp-21-11437-2021, https://doi.org/10.5194/acp-21-11437-2021, 2021
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We observed significant concentrations of gaseous HBr and HCl throughout the winter and springtime in urban Beijing, China. Our results indicate that gaseous HCl and HBr are most likely originated from anthropogenic emissions such as burning activities, and the gas–aerosol partitioning may play a crucial role in contributing to the gaseous HCl and HBr. These observations suggest that there is an important recycling pathway of halogen species in inland megacities.
Chao Peng, Patricia N. Razafindrambinina, Kotiba A. Malek, Lanxiadi Chen, Weigang Wang, Ru-Jin Huang, Yuqing Zhang, Xiang Ding, Maofa Ge, Xinming Wang, Akua A. Asa-Awuku, and Mingjin Tang
Atmos. Chem. Phys., 21, 7135–7148, https://doi.org/10.5194/acp-21-7135-2021, https://doi.org/10.5194/acp-21-7135-2021, 2021
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Organosulfates are important constituents in tropospheric aerosol particles, but their hygroscopic properties and cloud condensation nuclei activities are not well understood. In our work, three complementary techniques were employed to investigate the interactions of 11 organosulfates with water vapor under sub- and supersaturated conditions.
Yishuo Guo, Chao Yan, Chang Li, Wei Ma, Zemin Feng, Ying Zhou, Zhuohui Lin, Lubna Dada, Dominik Stolzenburg, Rujing Yin, Jenni Kontkanen, Kaspar R. Daellenbach, Juha Kangasluoma, Lei Yao, Biwu Chu, Yonghong Wang, Runlong Cai, Federico Bianchi, Yongchun Liu, and Markku Kulmala
Atmos. Chem. Phys., 21, 5499–5511, https://doi.org/10.5194/acp-21-5499-2021, https://doi.org/10.5194/acp-21-5499-2021, 2021
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Fog, cloud and haze are very common natural phenomena. Sulfuric acid (SA) is one of the key compounds forming those suspended particles, technically called aerosols, through gas-to-particle conversion. Therefore, the concentration level, source and sink of SA is very important. Our results show that ozonolysis of alkenes plays a major role in nighttime SA formation under unpolluted conditions in urban Beijing, and nighttime cluster mode particles are probably driven by SA in urban environments.
Runlong Cai, Chao Yan, Dongsen Yang, Rujing Yin, Yiqun Lu, Chenjuan Deng, Yueyun Fu, Jiaxin Ruan, Xiaoxiao Li, Jenni Kontkanen, Qiang Zhang, Juha Kangasluoma, Yan Ma, Jiming Hao, Douglas R. Worsnop, Federico Bianchi, Pauli Paasonen, Veli-Matti Kerminen, Yongchun Liu, Lin Wang, Jun Zheng, Markku Kulmala, and Jingkun Jiang
Atmos. Chem. Phys., 21, 2457–2468, https://doi.org/10.5194/acp-21-2457-2021, https://doi.org/10.5194/acp-21-2457-2021, 2021
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Based on long-term measurements, we discovered that the collision of H2SO4–amine clusters is the governing mechanism that initializes fast new particle formation in the polluted atmospheric environment of urban Beijing. The mechanism and the governing factors for H2SO4–amine nucleation in the polluted atmosphere are quantitatively investigated in this study.
Weigang Wang, Ting Lei, Andreas Zuend, Hang Su, Yafang Cheng, Yajun Shi, Maofa Ge, and Mingyuan Liu
Atmos. Chem. Phys., 21, 2179–2190, https://doi.org/10.5194/acp-21-2179-2021, https://doi.org/10.5194/acp-21-2179-2021, 2021
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Aerosol mixing state regulates the interactions between water molecules and particles and thus controls aerosol activation and hygroscopic growth, which thereby influences visibility degradation, cloud formation, and its radiative forcing. However, there are few studies attempting to investigate their interactions with water molecules. Here, we investigated the effect of organic coatings on the hygroscopic behavior of the inorganic core.
Tianzeng Chen, Jun Liu, Qingxin Ma, Biwu Chu, Peng Zhang, Jinzhu Ma, Yongchun Liu, Cheng Zhong, Pengfei Liu, Yafei Wang, Yujing Mu, and Hong He
Atmos. Chem. Phys., 21, 1341–1356, https://doi.org/10.5194/acp-21-1341-2021, https://doi.org/10.5194/acp-21-1341-2021, 2021
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Effects of photochemical aging on the formation and evolution of summertime secondary aerosol were systematically investigated in a suburb of Beijing. Higher PM1 concentration accompanied longer photochemical age (ta). Sulfate and more-oxidized OOA formation were significantly sensitive to the increase in ta, and their contributions were greatly enhanced at elevated ta levels. Our results suggested that photochemical aging process played a crucial role in PM1 and O3 pollution in summertime.
Jingsha Xu, Shaojie Song, Roy M. Harrison, Congbo Song, Lianfang Wei, Qiang Zhang, Yele Sun, Lu Lei, Chao Zhang, Xiaohong Yao, Dihui Chen, Weijun Li, Miaomiao Wu, Hezhong Tian, Lining Luo, Shengrui Tong, Weiran Li, Junling Wang, Guoliang Shi, Yanqi Huangfu, Yingze Tian, Baozhu Ge, Shaoli Su, Chao Peng, Yang Chen, Fumo Yang, Aleksandra Mihajlidi-Zelić, Dragana Đorđević, Stefan J. Swift, Imogen Andrews, Jacqueline F. Hamilton, Ye Sun, Agung Kramawijaya, Jinxiu Han, Supattarachai Saksakulkrai, Clarissa Baldo, Siqi Hou, Feixue Zheng, Kaspar R. Daellenbach, Chao Yan, Yongchun Liu, Markku Kulmala, Pingqing Fu, and Zongbo Shi
Atmos. Meas. Tech., 13, 6325–6341, https://doi.org/10.5194/amt-13-6325-2020, https://doi.org/10.5194/amt-13-6325-2020, 2020
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An interlaboratory comparison was conducted for the first time to examine differences in water-soluble inorganic ions (WSIIs) measured by 10 labs using ion chromatography (IC) and by two online aerosol chemical speciation monitor (ACSM) methods. Major ions including SO42−, NO3− and NH4+ agreed well in 10 IC labs and correlated well with ACSM data. WSII interlab variability strongly affected aerosol acidity results based on ion balance, but aerosol pH computed by ISORROPIA II was very similar.
Chao Peng, Yu Wang, Zhijun Wu, Lanxiadi Chen, Ru-Jin Huang, Weigang Wang, Zhe Wang, Weiwei Hu, Guohua Zhang, Maofa Ge, Min Hu, Xinming Wang, and Mingjin Tang
Atmos. Chem. Phys., 20, 13877–13903, https://doi.org/10.5194/acp-20-13877-2020, https://doi.org/10.5194/acp-20-13877-2020, 2020
Yongchun Liu, Yusheng Zhang, Chaofan Lian, Chao Yan, Zeming Feng, Feixue Zheng, Xiaolong Fan, Yan Chen, Weigang Wang, Biwu Chu, Yonghong Wang, Jing Cai, Wei Du, Kaspar R. Daellenbach, Juha Kangasluoma, Federico Bianchi, Joni Kujansuu, Tuukka Petäjä, Xuefei Wang, Bo Hu, Yuesi Wang, Maofa Ge, Hong He, and Markku Kulmala
Atmos. Chem. Phys., 20, 13023–13040, https://doi.org/10.5194/acp-20-13023-2020, https://doi.org/10.5194/acp-20-13023-2020, 2020
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Understanding of the chemical and physical processes leading to atmospheric aerosol particle formation is crucial to devising effective mitigation strategies to protect the public and reduce uncertainties in climate predictions. We found that the photolysis of nitrous acid could promote the formation of organic and nitrate aerosol and that traffic-related emission is a major contributor to ambient nitrous acid on haze days in wintertime in Beijing.
Jing Cai, Biwu Chu, Lei Yao, Chao Yan, Liine M. Heikkinen, Feixue Zheng, Chang Li, Xiaolong Fan, Shaojun Zhang, Daoyuan Yang, Yonghong Wang, Tom V. Kokkonen, Tommy Chan, Ying Zhou, Lubna Dada, Yongchun Liu, Hong He, Pauli Paasonen, Joni T. Kujansuu, Tuukka Petäjä, Claudia Mohr, Juha Kangasluoma, Federico Bianchi, Yele Sun, Philip L. Croteau, Douglas R. Worsnop, Veli-Matti Kerminen, Wei Du, Markku Kulmala, and Kaspar R. Daellenbach
Atmos. Chem. Phys., 20, 12721–12740, https://doi.org/10.5194/acp-20-12721-2020, https://doi.org/10.5194/acp-20-12721-2020, 2020
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By applying both OA PMF and size PMF at the same urban measurement site in Beijing, similar particle source types, including vehicular emissions, cooking emissions and secondary formation-related sources, were resolved by both frameworks and agreed well. It is also found that in the absence of new particle formation, vehicular and cooking emissions dominate the particle number concentration, while secondary particulate matter governed PM2.5 mass during spring and summer in Beijing.
Ting Lei, Nan Ma, Juan Hong, Thomas Tuch, Xin Wang, Zhibin Wang, Mira Pöhlker, Maofa Ge, Weigang Wang, Eugene Mikhailov, Thorsten Hoffmann, Ulrich Pöschl, Hang Su, Alfred Wiedensohler, and Yafang Cheng
Atmos. Meas. Tech., 13, 5551–5567, https://doi.org/10.5194/amt-13-5551-2020, https://doi.org/10.5194/amt-13-5551-2020, 2020
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We present the design of a nano-hygroscopicity tandem differential mobility analyzer (nano-HTDMA) apparatus that enables high accuracy and precision in hygroscopic growth measurements of aerosol nanoparticles with diameters less than 10 nm. We further introduce comprehensive methods for system calibration and validation of the performance of the system. We then study the size dependence of the deliquescence and the efflorescence of aerosol nanoparticles for sizes down to 6 nm.
Lubna Dada, Ilona Ylivinkka, Rima Baalbaki, Chang Li, Yishuo Guo, Chao Yan, Lei Yao, Nina Sarnela, Tuija Jokinen, Kaspar R. Daellenbach, Rujing Yin, Chenjuan Deng, Biwu Chu, Tuomo Nieminen, Yonghong Wang, Zhuohui Lin, Roseline C. Thakur, Jenni Kontkanen, Dominik Stolzenburg, Mikko Sipilä, Tareq Hussein, Pauli Paasonen, Federico Bianchi, Imre Salma, Tamás Weidinger, Michael Pikridas, Jean Sciare, Jingkun Jiang, Yongchun Liu, Tuukka Petäjä, Veli-Matti Kerminen, and Markku Kulmala
Atmos. Chem. Phys., 20, 11747–11766, https://doi.org/10.5194/acp-20-11747-2020, https://doi.org/10.5194/acp-20-11747-2020, 2020
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We rely on sulfuric acid measurements in four contrasting environments, Hyytiälä, Finland; Agia Marina, Cyprus; Budapest, Hungary; and Beijing, China, representing semi-pristine boreal forest, rural environment in the Mediterranean area, urban environment, and heavily polluted megacity, respectively, in order to define the sources and sinks of sulfuric acid in these environments and to derive a new sulfuric acid proxy to be utilized in locations and during periods when it is not measured.
Jenni Kontkanen, Chenjuan Deng, Yueyun Fu, Lubna Dada, Ying Zhou, Jing Cai, Kaspar R. Daellenbach, Simo Hakala, Tom V. Kokkonen, Zhuohui Lin, Yongchun Liu, Yonghong Wang, Chao Yan, Tuukka Petäjä, Jingkun Jiang, Markku Kulmala, and Pauli Paasonen
Atmos. Chem. Phys., 20, 11329–11348, https://doi.org/10.5194/acp-20-11329-2020, https://doi.org/10.5194/acp-20-11329-2020, 2020
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To estimate the impacts of atmospheric aerosol particles on air quality, knowledge of size distributions of particles emitted from anthropogenic sources is needed. We introduce a new method for determining size-resolved particle number emissions from measured particle size distributions. We apply our method to data measured in Beijing, China. We find that particle number emissions at our site are dominated by emissions of particles smaller than 30 nm, originating mainly from traffic.
Tommy Chan, Runlong Cai, Lauri R. Ahonen, Yiliang Liu, Ying Zhou, Joonas Vanhanen, Lubna Dada, Yan Chao, Yongchun Liu, Lin Wang, Markku Kulmala, and Juha Kangasluoma
Atmos. Meas. Tech., 13, 4885–4898, https://doi.org/10.5194/amt-13-4885-2020, https://doi.org/10.5194/amt-13-4885-2020, 2020
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Using a particle size magnifier (PSM; Airmodus, Finland), we determined the particle size distribution using four inversion methods and compared each method to the others to establish their strengths and weaknesses. Furthermore, we provided a step-by-step procedure on how to invert measured data using the PSM. Finally, we provided recommendations, code and data related to the data inversion. This is an important paper, as no operating procedure exists regarding how to process measured PSM data.
Cited articles
Aimanant, S. and Ziemann, P. J.: Chemical mechanisms of aging of aerosol
formed from the reaction of n-pentadecane with OH radicals in the presence
of NOx, Aerosol Sci. Tech., 47, 979–990, https://doi.org/10.1080/02786826.2013.804621, 2013.
Appel, K. W., Napelenok, S. L., Foley, K. M., Pye, H. O. T., Hogrefe, C., Luecken, D. J., Bash, J. O., Roselle, S. J., Pleim, J. E., Foroutan, H., Hutzell, W. T., Pouliot, G. A., Sarwar, G., Fahey, K. M., Gantt, B., Gilliam, R. C., Heath, N. K., Kang, D., Mathur, R., Schwede, D. B., Spero, T. L., Wong, D. C., and Young, J. O.: Description and evaluation of the Community Multiscale Air Quality (CMAQ) modeling system version 5.1, Geosci. Model Dev., 10, 1703–1732, https://doi.org/10.5194/gmd-10-1703-2017, 2017.
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic
compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I – gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Calvert, J. G., Atkinson, R., Becker, K. H., Kamens, R. M., Seinfeld, J. H.,
Wallington, T. J., and Yarwood, G.: The mechanisms of atmospheric oxidation
of aromatic hydrocarbons, Oxford University Press, New York, USA, 2002.
Cao, G. and Jang, M.: Effects of particle acidity and UV light on secondary
organic aerosol formation from oxidation of aromatics in the absence of NOx, Atmos. Environ., 41, 7603–7613, https://doi.org/10.1016/j.atmosenv.2007.05.034, 2007.
Carlton, A. G., Pinder, R. W., Bhave, P. V., and Pouliot, G. A.: To what
extent can biogenic SOA be controlled? Environ. Sci. Technol., 44,
3376–3380, 2010.
Charron, A., Polo-Rehn, L., Besombes, J.-L., Golly, B., Buisson, C., Chanut, H., Marchand, N., Guillaud, G., and Jaffrezo, J.-L.: Identification and quantification of particulate tracers of exhaust and non-exhaust vehicle emissions, Atmos. Chem. Phys., 19, 5187–5207, https://doi.org/10.5194/acp-19-5187-2019, 2019.
Chen, Q., Ikemori, F., and Mochida, M.: Light absorption and
excitation-emission fluorescence of urban organic aerosol components and
their relationship to chemical structure, Environ. Sci. Technol., 50,
10859–10868, https://doi.org/10.1021/acs.est.6b02541, 2016.
Chen, T., Liu, Y., Ma, Q., Chu, B., Zhang, P., Liu, C., Liu, J., and He, H.: Significant source of secondary aerosol: formation from gasoline evaporative emissions in the presence of SO2 and NH3, Atmos. Chem. Phys., 19, 8063–8081, https://doi.org/10.5194/acp-19-8063-2019, 2019.
Chen, T., Xue, L., Zheng, P., Zhang, Y., Liu, Y., Sun, J., Han, G., Li, H., Zhang, X., Li, Y., Li, H., Dong, C., Xu, F., Zhang, Q., and Wang, W.: Volatile organic compounds and ozone air pollution in an oil production region in northern China, Atmos. Chem. Phys., 20, 7069–7086, https://doi.org/10.5194/acp-20-7069-2020, 2020.
de Gouw, J. A., Middlebrook, A. M., Warneke, C., Goldan, P. D., Kuster, W.
C., Roberts, J. M., Fehsenfeld, F. C., Worsnop, D. R., Canagaratna, M. R.,
Pszenny, A. A. P., Keene, W. C., Marchewka, M., Bertman, S. B., and Bates,
T. S.: Budget of organic carbon in a polluted atmosphere: Results from the
New England Air Quality Study in 2002, J. Geophys. Res.-Atmos., 110, D16305, https://doi.org/10.1029/2004jd005623, 2005.
Fahnestock, K. A. S., Yee, L. D., Loza, C. L., Coggon, M. M., Schwantes, R.,
Zhang, X., Dalleska, N. F., and Seinfeld, J. H.: Secondary Organic Aerosol
Composition from C12 Alkanes, J. Phys. Chem. A, 119, 4281–4297, https://doi.org/10.1021/jp501779w, 2015.
Galloway, M. M., Loza, C. L., Chhabra, P. S., Chan, A. W. H., Yee, L. D.,
Seinfeld, J. H., and Keutsch, F. N.: Analysis of photochemical and dark
glyoxal uptake: Implications for SOA formation, Geophys. Res. Lett., 38, L17811, https://doi.org/10.1029/2011gl048514, 2011.
Garmash, O., Rissanen, M. P., Pullinen, I., Schmitt, S., Kausiala, O., Tillmann, R., Zhao, D., Percival, C., Bannan, T. J., Priestley, M., Hallquist, Å. M., Kleist, E., Kiendler-Scharr, A., Hallquist, M., Berndt, T., McFiggans, G., Wildt, J., Mentel, T. F., and Ehn, M.: Multi-generation OH oxidation as a source for highly oxygenated organic molecules from aromatics, Atmos. Chem. Phys., 20, 515–537, https://doi.org/10.5194/acp-20-515-2020, 2020.
Gentner, D. R., Isaacman, G., Worton, D. R., Chan, A. W. H., Dallmann, T.
R., Davis, L., Liu, S., Day, D. A., Russell, L. M., Wilson, K. R., Weber,
R., Guha, A., Harley, R. A., and Goldstein, A. H.: Elucidating secondary
organic aerosol from diesel and gasoline vehicles through detailed
characterization of organic carbon emissions, P. Natl. Acad. Sci. USA,
109, 18318–18323, https://doi.org/10.1073/pnas.1212272109, 2012.
Glasius, M., la Cour, A., and Lohse, C.: Fossil and nonfossil carbon in fine
particulate matter: A study of five European cities, J. Geophys. Res.-Atmos., 116, D11302, https://doi.org/10.1029/2011jd015646, 2011.
Grosjean, D.: ERT outdoor environmental chamber and dedicated analytical
facilities, Environ. Res. Technol. Inc., Westlake Village, California, USA, Report P-A704-050, 1981.
Heald, C. L., Jacob, D. J., Park, R. J., Russell, L. M., Huebert, B. J.,
Seinfeld, J. H., Liao, H., and Weber, R. J.: A large organic aerosol source
in the free troposphere missing from current models, Geophys. Res. Lett.,
32, L18809, https://doi.org/10.1029/2005gl023831, 2005.
Herrmann, H., Schaefer, T., Tilgner, A., Styler, S. A., Weller, C., Teich,
M., and Otto, T.: Tropospheric aqueous-phase chemistry: kinetics,
mechanisms, and its coupling to a changing gas phase, Chem. Rev., 115,
4259–4334, https://doi.org/10.1021/cr500447k, 2015.
Hodzic, A., Jimenez, J. L., Madronich, S., Canagaratna, M. R., DeCarlo, P. F., Kleinman, L., and Fast, J.: Modeling organic aerosols in a megacity: potential contribution of semi-volatile and intermediate volatility primary organic compounds to secondary organic aerosol formation, Atmos. Chem. Phys., 10, 5491–5514, https://doi.org/10.5194/acp-10-5491-2010, 2010.
Hoyle, C. R., Boy, M., Donahue, N. M., Fry, J. L., Glasius, M., Guenther, A., Hallar, A. G., Huff Hartz, K., Petters, M. D., Petäjä, T., Rosenoern, T., and Sullivan, A. P.: A review of the anthropogenic influence on biogenic secondary organic aerosol, Atmos. Chem. Phys., 11, 321–343, https://doi.org/10.5194/acp-11-321-2011, 2011.
Huang, J., McQueen, J., Wilczak, J., Djalalova, I., Stajner, I., Shafran,
P., Allured, D., Lee, P., Pan, L., Tong, D., Huang, H.-C., DiMego, G.,
Upadhayay, S., and Delle Monache, L.: Improving NOAA NAQFC PM2.5
Predictions with a Bias Correction Approach, Weather Forecast., 32,
407–421, https://doi.org/10.1175/waf-d-16-0118.1, 2017.
Huang, M., Lin, Y., Huang, X., Liu, X., Guo, X., Hu, C., Zhao, W., Gu, X.,
Fang, L., and Zhang, W.: Experimental study of particulate products for
aging of 1,3,5-trimethylbenzene secondary organic aerosol,
Atmos. Pollut. Res., 6, 209–219, https://doi.org/10.5094/apr.2015.025, 2015.
Huang, M., Hao, L., Cai, S., Gu, X., Zhang, W., Hu, C., Wang, Z., Fang, L.,
and Zhang, W.: Effects of inorganic seed aerosols on the particulate
products of aged 1,3,5-trimethylbenzene secondary organic aerosol, Atmos.
Environ., 152, 490–502, https://doi.org/10.1016/j.atmosenv.2017.01.010, 2017a.
Huang, M., Xu, J., Cai, S., Liu, X., Hu, C., Gu, X., Fang, L., and Zhang,
W.: Mass Spectral Analysis of the Aged 1,3,5-Trimethylbenzene Secondary
Organic Aerosol in the Presence of Ammonium Sulfate Seeds,
Pol. J. Environ. Stud., 26, 1531–1537, https://doi.org/10.15244/pjoes/66768, 2017b.
Huang, M., Xu, J., Cai, S., Liu, X., Hu, C., Gu, X., Zhao, W., Fang, L., and
Zhang, W.: Chemical analysis of particulate products of aged
1,3,5-trimethylbenzene secondary organic aerosol in the presence of ammonia,
Atmos. Pollut. Res., 9, 146–155, https://doi.org/10.1016/j.apr.2017.08.003, 2018.
Huang, X.-G., Shao, T.-J., Zhao, J.-B., Cao, J.-J., and Yue, D.-P.: Impact
of meteorological factors and precursors on spatial distribution of ozone
concentration in Eastern China, China Environ. Sci., 39, 2273–2282, https://doi.org/10.19674/j.cnki.issn1000-6923.2019.0270, 2019.
Jaffe, D. A. and Zhang, L.: Meteorological anomalies lead to elevated
O3 in the western U.S. in June 2015, Geophys. Res. Lett., 44,
1990–1997, https://doi.org/10.1002/2016gl072010, 2017.
Johnson, D., Jenkin, M. E., Wirtz, K., and Martin-Reviejo, M.: Simulating
the formation of secondary organic aerosol from the photooxidation of
toluene, Environ. Chem., 1, 150–165, https://doi.org/10.1071/en04069, 2004.
Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J., Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J., Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J., Moortgat, G. K., Winterhalter, R., Myhre, C. E. L., Tsigaridis, K., Vignati, E., Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate modelling: a review, Atmos. Chem. Phys., 5, 1053–1123, https://doi.org/10.5194/acp-5-1053-2005, 2005.
Kansal, A.: Sources and reactivity of NMHCs and VOCs in the atmosphere: a
review, J. Hazard. Mater., 166, 17–26, https://doi.org/10.1016/j.jhazmat.2008.11.048, 2009.
Kari, E., Hao, L., Ylisirniö, A., Buchholz, A., Leskinen, A., Yli-Pirilä, P., Nuutinen, I., Kuuspalo, K., Jokiniemi, J., Faiola, C. L., Schobesberger, S., and Virtanen, A.: Potential dual effect of anthropogenic emissions on the formation of biogenic secondary organic aerosol (BSOA), Atmos. Chem. Phys., 19, 15651–15671, https://doi.org/10.5194/acp-19-15651-2019, 2019.
Kelly, J. M., Doherty, R. M., O'Connor, F. M., and Mann, G. W.: The impact of biogenic, anthropogenic, and biomass burning volatile organic compound emissions on regional and seasonal variations in secondary organic aerosol, Atmos. Chem. Phys., 18, 7393–7422, https://doi.org/10.5194/acp-18-7393-2018, 2018.
Kim, H. and Paulson, S. E.: Real refractive indices and volatility of secondary organic aerosol generated from photooxidation and ozonolysis of limonene, α-pinene and toluene, Atmos. Chem. Phys., 13, 7711–7723, https://doi.org/10.5194/acp-13-7711-2013, 2013.
Kroll, J. H., Chan, A. W. H., Ng, N. L., Flagan, R. C., and Seinfeld, J. H.:
Reactions of semivolatile organics and their effects on secondary organic
aerosol formation, Environ. Sci. Technol., 41, 3545–3550, 2007.
Laskin, A., Laskin, J., and Nizkorodov, S. A.: Chemistry of atmospheric
brown carbon, Chem. Rev., 115, 4335–4382, https://doi.org/10.1021/cr5006167, 2015.
Lauraguais, A., Coeur-Tourneur, C., Cassez, A., and Seydi, A.: Rate constant
and secondary organic aerosol yields for the gas-phase reaction of hydroxyl
radicals with syringol (2,6-dimethoxyphenol), Atmos. Environ., 55, 43–48, https://doi.org/10.1016/j.atmosenv.2012.02.027, 2012.
Lauraguais, A., Coeur-Tourneur, C., Cassez, A., Deboudt, K., Fourmentin, M.,
and Choël, M.: Atmospheric reactivity of hydroxyl radicals with guaiacol
(2-methoxyphenol), a biomass burning emitted compound: Secondary organic
aerosol formation and gas-phase oxidation products, Atmos. Environ., 86,
155–163, https://doi.org/10.1016/j.atmosenv.2013.11.074, 2014.
Li, J., Li, K., Wang, W., Wang, J., Peng, C., and Ge, M.: Optical properties
of secondary organic aerosols derived from long-chain alkanes under various
NOx and seed conditions, Sci. Total Environ., 579, 1699–1705, https://doi.org/10.1016/j.scitotenv.2016.11.189, 2017.
Li, J., Wang, W., Li, K., Zhang, W., Peng, C., Zhou, L., Shi, B., Chen, Y., Liu, M., Li, H., and Ge, M.: Temperature effects on optical properties and chemical composition of secondary organic aerosol derived from n-dodecane, Atmos. Chem. Phys., 20, 8123–8137, https://doi.org/10.5194/acp-20-8123-2020, 2020.
Li, J., Li, H., Wang, X., Wang, W., Ge, M., Zhang, H., Zhang, X., Li, K.,
Chen, Y., Wu, Z., Chai, F., Meng, F., Mu, Y., Mellouki, A., Bi, F., Zhang,
Y., Wu, L., and Liu, Y.: A large-scale outdoor atmospheric simulation smog
chamber for studying atmospheric photochemical processes: Characterization
and preliminary application, J. Environ. Sci., 102, 185–197, 2021.
Li, K., Li, J., Liggio, J., Wang, W., Ge, M., Liu, Q., Guo, Y., Tong, S.,
Li, J., Peng, C., Jing, B., Wang, D., and Fu, P.: Enhanced light scattering
of secondary organic aerosols by multiphase reactions, Environ. Sci.
Technol., 51, 1285–1292, https://doi.org/10.1021/acs.est.6b03229, 2017a.
Li, K., Li, J., Wang, W., Tong, S., Liggio, J., and Ge, M.: Evaluating the
effectiveness of joint emission control policies on the reduction of ambient
VOCs: Implications from observation during the 2014 APEC summit in suburban
Beijing, Atmos. Environ., 164, 117–127, https://doi.org/10.1016/j.atmosenv.2017.05.050,
2017b.
Li, K., Li, J., Wang, W., Li, J., Peng, C., Wang, D., and Ge, M.: Effects of
gas-particle partitioning on refractive index and chemical composition of
m-xylene secondary organic aerosol, J. Phys. Chem. A, 122, 3250–3260, https://doi.org/10.1021/acs.jpca.7b12792, 2018.
Lim, Y. B. and Ziemann, P. J.: Products and mechanism of secondary organic
aerosol formation from reactions of n-alkanes with OH radicals in the
presence of NOx, Environ. Sci. Technol., 39, 9229–9236, https://doi.org/10.1021/es051447g, 2005.
Lim, Y. B. and Ziemann, P. J.: Effects of molecular structure on aerosol
yields from OH radical-initiated reactions of linear, branched, and cyclic
alkanes in the presence of NOx, Environ. Sci. Technol., 43, 2328–2334, https://doi.org/10.1021/es803389s, 2009.
Loza, C. L., Craven, J. S., Yee, L. D., Coggon, M. M., Schwantes, R. H., Shiraiwa, M., Zhang, X., Schilling, K. A., Ng, N. L., Canagaratna, M. R., Ziemann, P. J., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol yields of 12-carbon alkanes, Atmos. Chem. Phys., 14, 1423–1439, https://doi.org/10.5194/acp-14-1423-2014, 2014.
Luo, H., Jia, L., Wan, Q., An, T., and Wang, Y.: Role of liquid water in the
formation of O3 and SOA particles from 1,2,3-trimethylbenzene, Atmos. Environ., 217, 116955, https://doi.org/10.1016/j.atmosenv.2019.116955, 2019.
McFiggans, G., Mentel, T. F., Wildt, J., Pullinen, I., Kang, S., Kleist, E.,
Schmitt, S., Springer, M., Tillmann, R., Wu, C., Zhao, D., Hallquist, M.,
Faxon, C., Le Breton, M., Hallquist, A. M., Simpson, D., Bergstrom, R.,
Jenkin, M. E., Ehn, M., Thornton, J. A., Alfarra, M. R., Bannan, T. J.,
Percival, C. J., Priestley, M., Topping, D., and Kiendler-Scharr, A.:
Secondary organic aerosol reduced by mixture of atmospheric vapours, Nature,
565, 587–593, https://doi.org/10.1038/s41586-018-0871-y, 2019.
McMurry, P. H. and Grosjean, D.: Gas and aerosol wall losses in Teflon film
smog chambers, Environ. Sci. Technol., 19, 1176–1182, https://doi.org/10.1021/es00142a006, 1985.
Mellouki, A., Wallington, T. J., and Chen, J.: Atmospheric chemistry of
oxygenated volatile organic compounds: impacts on air quality and climate,
Chem. Rev., 115, 3984–4014, https://doi.org/10.1021/cr500549n, 2015.
Midey, A. J., Williams, S., Miller, T. M., and Viggiano, A. A.:
Reactions of O , NO+ and H3O+ with
methylcyclohexane (C7H14) and cyclooctane (C8H16) from
298 to 700 K, Int. J. Mass Spectrom., 222, 413–430, 2003.
Moise, T., Flores, J. M., and Rudich, Y.: Optical properties of secondary
organic aerosols and their changes by chemical processes, Chem. Rev., 115,
4400–4439, https://doi.org/10.1021/cr5005259, 2015.
Nakao, S., Tang, P., Tang, X., Clark, C. H., Qi, L., Seo, E., Asa-Awuku, A.,
and Cocker, D.: Density and elemental ratios of secondary organic aerosol:
Application of a density prediction method, Atmos. Environ., 68, 273–277, https://doi.org/10.1016/j.atmosenv.2012.11.006, 2013.
Ng, N. L., Chhabra, P. S., Chan, A. W. H., Surratt, J. D., Kroll, J. H., Kwan, A. J., McCabe, D. C., Wennberg, P. O., Sorooshian, A., Murphy, S. M., Dalleska, N. F., Flagan, R. C., and Seinfeld, J. H.: Effect of NOx level on secondary organic aerosol (SOA) formation from the photooxidation of terpenes, Atmos. Chem. Phys., 7, 5159–5174, https://doi.org/10.5194/acp-7-5159-2007, 2007a.
Ng, N. L., Kroll, J. H., Chan, A. W. H., Chhabra, P. S., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol formation from m-xylene, toluene, and benzene, Atmos. Chem. Phys., 7, 3909–3922, https://doi.org/10.5194/acp-7-3909-2007, 2007b.
Odum, J. R., Hoffmann, T., Bowman, F., Collins, D., Flagan, R. C., and
Seinfeld, J. H.: Gas/particle partitioning and secondary organic aerosol
yields, Environ. Sci. Technol., 30, 2580–2585, https://doi.org/10.1021/es950943+, 1996.
Paulsen, D., Dommen, J., Kalberer, M., Prevot, A. S. H., Richter, R., Sax,
M., Steinbacher, M., Weingartner, E., and Baltensperger, U.: Secondary
organic aerosol formation by irradiation of
1,3,5-trimethylbenzene-NOx-H2O in a new reaction chamber for
atmospheric chemistry and physics, Environ. Sci. Technol., 39, 2668–2678,
2005.
Phillips, S. M. and Smith, G. D.: Light absorption by charge transfer
complexes in brown carbon aerosols, Environ. Sci. Tech. Let., 1,
382–386, https://doi.org/10.1021/ez500263j, 2014.
Poschl, U.: Atmospheric aerosols: Composition, transformation, climate and
health effects, Angew. Chem. Int. Edit., 44, 7520–7540, https://doi.org/10.1002/anie.200501122, 2005.
Poschl, U. and Shiraiwa, M.: Multiphase chemistry at the
atmosphere-biosphere interface influencing climate and public health in the
anthropocene, Chem. Rev., 115, 4440–4475, https://doi.org/10.1021/cr500487s, 2015.
Ren, J., Zhang, F., Wang, Y., Collins, D., Fan, X., Jin, X., Xu, W., Sun, Y., Cribb, M., and Li, Z.: Using different assumptions of aerosol mixing state and chemical composition to predict CCN concentrations based on field measurements in urban Beijing, Atmos. Chem. Phys., 18, 6907–6921, https://doi.org/10.5194/acp-18-6907-2018, 2018.
Requia, W. J., Higgins, C. D., Adams, M. D., Mohamed, M., and Koutrakis, P.:
The health impacts of weekday traffic: A health risk assessment of PM2.5
emissions during congested periods, Environ. Int., 111, 164–176, https://doi.org/10.1016/j.envint.2017.11.025, 2018.
Robinson, A. L., Donahue, N. M., Shrivastava, M. K., Weitkamp, E. A., Sage,
A. M., Grieshop, A. P., Lane, T. E., Pierce, J. R., and Pandis, S. N.:
Rethinking organic aerosols: Semivolatile emissions and photochemical aging,
Science, 315, 1259–1262, https://doi.org/10.1126/science.1133061, 2007.
Saathoff, H., Naumann, K.-H., Möhler, O., Jonsson, Å. M., Hallquist, M., Kiendler-Scharr, A., Mentel, Th. F., Tillmann, R., and Schurath, U.: Temperature dependence of yields of secondary organic aerosols from the ozonolysis of α-pinene and limonene, Atmos. Chem. Phys., 9, 1551–1577, https://doi.org/10.5194/acp-9-1551-2009, 2009.
Sato, K., Fujitani, Y., Inomata, S., Morino, Y., Tanabe, K., Hikida, T., Shimono, A., Takami, A., Fushimi, A., Kondo, Y., Imamura, T., Tanimoto, H., and Sugata, S.: A study of volatility by composition, heating, and dilution measurements of secondary organic aerosol from 1,3,5-trimethylbenzene, Atmos. Chem. Phys., 19, 14901–14915, https://doi.org/10.5194/acp-19-14901-2019, 2019.
Schauer, J. J., Kleeman, M. J., Cass, G. R., and Simoneit, B. R. T.:
Measurement of emissions from air pollution sources, 5. C1−C32 organic
compounds from gasoline-powered motor vehicles, Environ. Sci. Technol., 36,
1169–1180, https://doi.org/10.1021/es0108077, 2002.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics: from air pollution to climate change, 3rd edn., John Wiley & Sons, Hoboken, 2016.
Shilling, J. E., Zaveri, R. A., Fast, J. D., Kleinman, L., Alexander, M. L., Canagaratna, M. R., Fortner, E., Hubbe, J. M., Jayne, J. T., Sedlacek, A., Setyan, A., Springston, S., Worsnop, D. R., and Zhang, Q.: Enhanced SOA formation from mixed anthropogenic and biogenic emissions during the CARES campaign, Atmos. Chem. Phys., 13, 2091–2113, https://doi.org/10.5194/acp-13-2091-2013, 2013.
Shiraiwa, M., Yee, L. D., Schilling, K. A., Loza, C. L., Craven, J. S.,
Zuend, A., Ziemann, P. J., and Seinfeld, J. H.: Size distribution dynamics
reveal particle-phase chemistry in organic aerosol formation, P. Natl. Acad. Sci. USA, 110, 11746–11750, https://doi.org/10.1073/pnas.1307501110, 2013.
Shrivastava, M., Cappa, C. D., Fan, J., Goldstein, A. H., Guenther, A. B.,
Jimenez, J. L., Kuang, C., Laskin, A., Martin, S. T., Ng, N. L., Petaja, T.,
Pierce, J. R., Rasch, P. J., Roldin, P., Seinfeld, J. H., Shilling, J.,
Smith, J. N., Thornton, J. A., Volkamer, R., Wang, J., Worsnop, D. R.,
Zaveri, R. A., Zelenyuk, A., and Zhang, Q.: Recent advances in understanding
secondary organic aerosol: Implications for global climate forcing, Rev.
Geophys., 55, 509–559, https://doi.org/10.1002/2016rg000540, 2017.
Slowik, J. G., Stroud, C., Bottenheim, J. W., Brickell, P. C., Chang, R. Y.-W., Liggio, J., Makar, P. A., Martin, R. V., Moran, M. D., Shantz, N. C., Sjostedt, S. J., van Donkelaar, A., Vlasenko, A., Wiebe, H. A., Xia, A. G., Zhang, J., Leaitch, W. R., and Abbatt, J. P. D.: Characterization of a large biogenic secondary organic aerosol event from eastern Canadian forests, Atmos. Chem. Phys., 10, 2825–2845, https://doi.org/10.5194/acp-10-2825-2010, 2010.
Spracklen, D. V., Jimenez, J. L., Carslaw, K. S., Worsnop, D. R., Evans, M. J., Mann, G. W., Zhang, Q., Canagaratna, M. R., Allan, J., Coe, H., McFiggans, G., Rap, A., and Forster, P.: Aerosol mass spectrometer constraint on the global secondary organic aerosol budget, Atmos. Chem. Phys., 11, 12109–12136, https://doi.org/10.5194/acp-11-12109-2011, 2011.
Tkacik, D. S., Presto, A. A., Donahue, N. M., and Robinson, A. L.: Secondary
Organic Aerosol Formation from Intermediate-Volatility Organic Compounds:
Cyclic, Linear, and Branched Alkanes, Environ. Sci. Technol., 46, 8773–8781, https://doi.org/10.1021/es301112c, 2012.
Trostl, J., Chuang, W. K., Gordon, H., Heinritzi, M., Yan, C., Molteni, U.,
Ahlm, L., Frege, C., Bianchi, F., Wagner, R., Simon, M., Lehtipalo, K.,
Williamson, C., Craven, J. S., Duplissy, J., Adamov, A., Almeida, J.,
Bernhammer, A. K., Breitenlechner, M., Brilke, S., Dias, A., Ehrhart, S.,
Flagan, R. C., Franchin, A., Fuchs, C., Guida, R., Gysel, M., Hansel, A.,
Hoyle, C. R., Jokinen, T., Junninen, H., Kangasluoma, J., Keskinen, H., Kim,
J., Krapf, M., Kurten, A., Laaksonen, A., Lawler, M., Leiminger, M., Mathot,
S., Mohler, O., Nieminen, T., Onnela, A., Petaja, T., Piel, F. M.,
Miettinen, P., Rissanen, M. P., Rondo, L., Sarnela, N., Schobesberger, S.,
Sengupta, K., Sipila, M., Smith, J. N., Steiner, G., Tome, A., Virtanen, A.,
Wagner, A. C., Weingartner, E., Wimmer, D., Winkler, P. M., Ye, P., Carslaw,
K. S., Curtius, J., Dommen, J., Kirkby, J., Kulmala, M., Riipinen, I.,
Worsnop, D. R., Donahue, N. M., and Baltensperger, U.: The role of
low-volatility organic compounds in initial particle growth in the
atmosphere, Nature, 533, 527–531, https://doi.org/10.1038/nature18271, 2016.
Tsiligiannis, E., Hammes, J., Salvador, C. M., Mentel, T. F., and Hallquist, M.: Effect of NOx on 1,3,5-trimethylbenzene (TMB) oxidation product distribution and particle formation, Atmos. Chem. Phys., 19, 15073–15086, https://doi.org/10.5194/acp-19-15073-2019, 2019.
Volkamer, R., Jimenez, J. L., San Martini, F., Dzepina, K., Zhang, Q.,
Salcedo, D., Molina, L. T., Worsnop, D. R., and Molina, M. J.: Secondary
organic aerosol formation from anthropogenic air pollution: Rapid and higher
than expected, Geophys. Res. Lett., 33, L17811, https://doi.org/10.1029/2006gl026899, 2006.
von Schneidemesser, E., Monks, P. S., Allan, J. D., Bruhwiler, L., Forster,
P., Fowler, D., Lauer, A., Morgan, W. T., Paasonen, P., Righi, M.,
Sindelarova, K., and Sutton, M. A.: Chemistry and the Linkages between Air
Quality and Climate Change, Chem. Rev., 115, 3856–3897, https://doi.org/10.1021/acs.chemrev.5b00089, 2015.
Wang, C., Yuan, B., Wu, C., Wang, S., Qi, J., Wang, B., Wang, Z., Hu, W., Chen, W., Ye, C., Wang, W., Sun, Y., Wang, C., Huang, S., Song, W., Wang, X., Yang, S., Zhang, S., Xu, W., Ma, N., Zhang, Z., Jiang, B., Su, H., Cheng, Y., Wang, X., and Shao, M.: Measurements of higher alkanes using NO+ chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China, Atmos. Chem. Phys., 20, 14123–14138, https://doi.org/10.5194/acp-20-14123-2020, 2020.
Wang, T., Xue, L., Brimblecombe, P., Lam, Y. F., Li, L., and Zhang, L.:
Ozone pollution in China: A review of concentrations, meteorological
influences, chemical precursors, and effects, Sci. Total Environ., 575,
1582–1596, https://doi.org/10.1016/j.scitotenv.2016.10.081, 2017.
Wirtz, K. and Martin-Reviejo, M.: Density of secondary organic aerosols, J.
Aerosol Sci., 34, 223–224, 2003.
Wu, R. and Xie, S.: Spatial Distribution of secondary organic aerosol
formation potential in China derived from speciated anthropogenic volatile
organic compound emissions, Environ. Sci. Technol., 52, 8146–8156, https://doi.org/10.1021/acs.est.8b01269, 2018.
Yang, J. C., Roth, P., Durbin, T. D., Johnson, K. C., Cocker III, D. R.,
Asa-Awuku, A., Brezny, R., Geller, M., and Karavalakis, G.: Gasoline
Particulate Filters as an Effective Tool to Reduce Particulate and
Polycyclic Aromatic Hydrocarbon Emissions from Gasoline Direct Injection
(GDI) Vehicles: A Case Study with Two GDI Vehicles, Environ. Sci. Technol., 52, 3275–3284, https://doi.org/10.1021/acs.est.7b05641, 2018.
Yee, L. D., Craven, J. S., Loza, C. L., Schilling, K. A., Ng, N. L.,
Canagaratna, M. R., Ziemann, P. J., Flagan, R. C., and Seinfeld, J. H.:
Secondary organic aerosol formation from low-NOx photooxidation of
dodecane: evolution of multigeneration gas-phase chemistry and aerosol
composition, J. Phys. Chem. A, 116, 6211–6230, https://doi.org/10.1021/jp211531h, 2012.
Yee, L. D., Craven, J. S., Loza, C. L., Schilling, K. A., Ng, N. L., Canagaratna, M. R., Ziemann, P. J., Flagan, R. C., and Seinfeld, J. H.: Effect of chemical structure on secondary organic aerosol formation from C12 alkanes, Atmos. Chem. Phys., 13, 11121–11140, https://doi.org/10.5194/acp-13-11121-2013, 2013.
Zhang, H., Wang, S., Hao, J., Wang, X., Wang, S., Chai, F., and Li, M.: Air
pollution and control action in Beijing, J. Clean. Prod., 112, 1519–1527, https://doi.org/10.1016/j.jclepro.2015.04.092, 2016.
Zhang, R., Wang, G., Guo, S., Zamora, M. L., Ying, Q., Lin, Y., Wang, W.,
Hu, M., and Wang, Y.: Formation of urban fine particulate matter, Chem.
Rev., 115, 3803–3855, https://doi.org/10.1021/acs.chemrev.5b00067, 2015.
Zhang, X., Cappa, C. D., Jathar, S. H., McVay, R. C., Ensberg, J. J.,
Kleeman, M. J., and Seinfeld, J. H.: Influence of vapor wall loss in
laboratory chambers on yields of secondary organic aerosol, P. Natl. Acad. Sci. USA, 111, 5802–5807, 2014.
Zhang, X., Schwantes, R. H., McVay, R. C., Lignell, H., Coggon, M. M., Flagan, R. C., and Seinfeld, J. H.: Vapor wall deposition in Teflon chambers, Atmos. Chem. Phys., 15, 4197–4214, https://doi.org/10.5194/acp-15-4197-2015, 2015.
Zhao, B., Wang, S., Donahue, N. M., Jathar, S. H., Huang, X., Wu, W., Hao,
J., and Robinson, A. L.: Quantifying the effect of organic aerosol aging and
intermediate-volatility emissions on regional-scale aerosol pollution in
China, Sci. Rep.-UK, 6, 28815, https://doi.org/10.1038/srep28815, 2016.
Zhao, Y., Nguyen, N. T., Presto, A. A., Hennigan, C. J., May, A. A., and
Robinson, A. L.: Intermediate volatility organic compound emissions from
on-road diesel vehicles: Chemical composition, emission factors, and
estimated secondary organic aerosol production, Environ. Sci. Technol., 49, 11516–11526, https://doi.org/10.1021/acs.est.5b02841, 2015.
Zhou, Y., Zhang, H., Parikh, H. M., Chen, E. H., Rattanavaraha, W., Rosen,
E. P., Wang, W., and Kamens, R. M.: Secondary organic aerosol formation from
xylenes and mixtures of toluene and xylenes in an atmospheric urban
hydrocarbon mixture: Water and particle seed effects (II), Atmos. Environ.,
45, 3882–3890, https://doi.org/10.1016/j.atmosenv.2010.12.048, 2011.
Short summary
SOA formation from the mixed anthropogenic volatile organic compounds was enhanced compared to the predicted SOA mass concentration based on the SOA yield of single species; interaction occurred between intermediate products from the two precursors. Interactions between the intermediate products from the mixtures and the effect on SOA formation give us a further understanding of the SOA formed in the atmosphere.
SOA formation from the mixed anthropogenic volatile organic compounds was enhanced compared to...
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