Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

IF value: 5.414
IF5.414
IF 5-year value: 5.958
IF 5-year
5.958
CiteScore value: 9.7
CiteScore
9.7
SNIP value: 1.517
SNIP1.517
IPP value: 5.61
IPP5.61
SJR value: 2.601
SJR2.601
Scimago H <br class='widget-line-break'>index value: 191
Scimago H
index
191
h5-index value: 89
h5-index89
ACP | Articles | Volume 19, issue 7
Atmos. Chem. Phys., 19, 4419–4437, 2019
https://doi.org/10.5194/acp-19-4419-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 19, 4419–4437, 2019
https://doi.org/10.5194/acp-19-4419-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 04 Apr 2019

Research article | 04 Apr 2019

Solubility and solution-phase chemistry of isocyanic acid, methyl isocyanate, and cyanogen halides

James M. Roberts and Yong Liu

Related authors

The nitrogen budget of laboratory-simulated western US wildfires during the FIREX 2016 Fire Lab study
James M. Roberts, Chelsea E. Stockwell, Robert J. Yokelson, Joost de Gouw, Yong Liu, Vanessa Selimovic, Abigail R. Koss, Kanako Sekimoto, Matthew M. Coggon, Bin Yuan, Kyle J. Zarzana, Steven S. Brown, Cristina Santin, Stefan H. Doerr, and Carsten Warneke
Atmos. Chem. Phys., 20, 8807–8826, https://doi.org/10.5194/acp-20-8807-2020,https://doi.org/10.5194/acp-20-8807-2020, 2020
Short summary
Molecular composition and photochemical lifetimes of brown carbon chromophores in biomass burning organic aerosol
Lauren T. Fleming, Peng Lin, James M. Roberts, Vanessa Selimovic, Robert Yokelson, Julia Laskin, Alexander Laskin, and Sergey A. Nizkorodov
Atmos. Chem. Phys., 20, 1105–1129, https://doi.org/10.5194/acp-20-1105-2020,https://doi.org/10.5194/acp-20-1105-2020, 2020
Short summary
OH chemistry of non-methane organic gases (NMOGs) emitted from laboratory and ambient biomass burning smoke: evaluating the influence of furans and oxygenated aromatics on ozone and secondary NMOG formation
Matthew M. Coggon, Christopher Y. Lim, Abigail R. Koss, Kanako Sekimoto, Bin Yuan, Jessica B. Gilman, David H. Hagan, Vanessa Selimovic, Kyle J. Zarzana, Steven S. Brown, James M. Roberts, Markus Müller, Robert Yokelson, Armin Wisthaler, Jordan E. Krechmer, Jose L. Jimenez, Christopher Cappa, Jesse H. Kroll, Joost de Gouw, and Carsten Warneke
Atmos. Chem. Phys., 19, 14875–14899, https://doi.org/10.5194/acp-19-14875-2019,https://doi.org/10.5194/acp-19-14875-2019, 2019
Short summary
On the sources and sinks of atmospheric VOCs: an integrated analysis of recent aircraft campaigns over North America
Xin Chen, Dylan B. Millet, Hanwant B. Singh, Armin Wisthaler, Eric C. Apel, Elliot L. Atlas, Donald R. Blake, Ilann Bourgeois, Steven S. Brown, John D. Crounse, Joost A. de Gouw, Frank M. Flocke, Alan Fried, Brian G. Heikes, Rebecca S. Hornbrook, Tomas Mikoviny, Kyung-Eun Min, Markus Müller, J. Andrew Neuman, Daniel W. O'Sullivan, Jeff Peischl, Gabriele G. Pfister, Dirk Richter, James M. Roberts, Thomas B. Ryerson, Stephen R. Shertz, Chelsea R. Thompson, Victoria Treadaway, Patrick R. Veres, James Walega, Carsten Warneke, Rebecca A. Washenfelder, Petter Weibring, and Bin Yuan
Atmos. Chem. Phys., 19, 9097–9123, https://doi.org/10.5194/acp-19-9097-2019,https://doi.org/10.5194/acp-19-9097-2019, 2019
Short summary
Effects of gas–wall interactions on measurements of semivolatile compounds and small polar molecules
Xiaoxi Liu, Benjamin Deming, Demetrios Pagonis, Douglas A. Day, Brett B. Palm, Ranajit Talukdar, James M. Roberts, Patrick R. Veres, Jordan E. Krechmer, Joel A. Thornton, Joost A. de Gouw, Paul J. Ziemann, and Jose L. Jimenez
Atmos. Meas. Tech., 12, 3137–3149, https://doi.org/10.5194/amt-12-3137-2019,https://doi.org/10.5194/amt-12-3137-2019, 2019
Short summary

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Rate coefficients for reactions of OH with aromatic and aliphatic volatile organic compounds determined by the multivariate relative rate technique
Jacob T. Shaw, Andrew R. Rickard, Mike J. Newland, and Terry J. Dillon
Atmos. Chem. Phys., 20, 9725–9736, https://doi.org/10.5194/acp-20-9725-2020,https://doi.org/10.5194/acp-20-9725-2020, 2020
Short summary
Atmospheric fate of two relevant unsaturated ketoethers: kinetics, products and mechanisms for the reaction of hydroxyl radicals with (E)-4-methoxy-3-buten-2-one and (1E)-1-methoxy-2-methyl-1-penten-3-one
Rodrigo Gastón Gibilisco, Ian Barnes, Iustinian Gabriel Bejan, and Peter Wiesen
Atmos. Chem. Phys., 20, 8939–8951, https://doi.org/10.5194/acp-20-8939-2020,https://doi.org/10.5194/acp-20-8939-2020, 2020
Short summary
The nitrogen budget of laboratory-simulated western US wildfires during the FIREX 2016 Fire Lab study
James M. Roberts, Chelsea E. Stockwell, Robert J. Yokelson, Joost de Gouw, Yong Liu, Vanessa Selimovic, Abigail R. Koss, Kanako Sekimoto, Matthew M. Coggon, Bin Yuan, Kyle J. Zarzana, Steven S. Brown, Cristina Santin, Stefan H. Doerr, and Carsten Warneke
Atmos. Chem. Phys., 20, 8807–8826, https://doi.org/10.5194/acp-20-8807-2020,https://doi.org/10.5194/acp-20-8807-2020, 2020
Short summary
Determination of the absorption cross-sections of higher order iodine oxides at 355 nm and 532 nm
Thomas R. Lewis, Juan Carlos Gómez Martin, Mark A. Blitz, Carlos A. Cuevas, John M. C. Plane, and Alfonso Saiz-Lopez
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-456,https://doi.org/10.5194/acp-2020-456, 2020
Revised manuscript accepted for ACP
Short summary
Evolution of NO3 reactivity during the oxidation of isoprene
Patrick Dewald, Jonathan M. Liebmann, Nils Friedrich, Justin Shenolikar, Jan Schuladen, Franz Rohrer, David Reimer, Ralf Tillmann, Anna Novelli, Changmin Cho, Kangming Xu, Rupert Holzinger, François Bernard, Li Zhou, Wahid Mellouki, Steven S. Brown, Hendrik Fuchs, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-360,https://doi.org/10.5194/acp-2020-360, 2020
Revised manuscript accepted for ACP
Short summary

Cited articles

Afifi, M. Z. and Blatchley III, E. R.: Seasonal dynamics of water and air chemistry in an indoor chlorinated swimming pool, Water Res., 68, 771–783, 2015. 
Al-Rawi, H. and Williams, A.: Elimination-addition mechanisms of acyl group transfer: the hydrolysis and synthesis of carbamates, J. Am. Chem. Soc., 99, 2671–2678, 1977. 
Bailey, P. L. and Bishop, E.: Hydrolysis of cyanogen chloride, J. Chem. Soc., 912–916, https://doi.org/10.1039/dt9730000912, 1973. 
Barnes, I., Solignac, G., Mellouki, A., and Becker, K. H.: Aspects of the atmospheric chemistry of amides, Chem. Phys. Chem., 11, 3844–3857, 2010. 
Barth, M. C., Cochran, A. C., Fiddler, M. N., Roberts, J. M., and Bililign, S.: Numerical modeling of cloud chemistry effects on isocyanic acid (HNCO), J. Geophys. Res., 118, 8688–8701, 2013. 
Publications Copernicus
Download
Short summary
Condensed-phase reactions are important removal processes for reduced nitrogen species, isocyanic acid (HNCO), methyl isocyanate (CH3NCO), and cyanogen halides (XCN, X = Cl, Br, I). This chemistry is not well understood, so we measured aqueous-phase solubilities and reaction rates under a range of temperatures and conditions and in n-octanol, a proxy for non-polar media and biological membranes. The results were used to estimate atmospheric removal rates and fates of these nitrogen compounds.
Condensed-phase reactions are important removal processes for reduced nitrogen species,...
Citation
Altmetrics
Final-revised paper
Preprint