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ACP | Articles | Volume 19, issue 7
Atmos. Chem. Phys., 19, 4419–4437, 2019
https://doi.org/10.5194/acp-19-4419-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 19, 4419–4437, 2019
https://doi.org/10.5194/acp-19-4419-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 04 Apr 2019

Research article | 04 Apr 2019

Solubility and solution-phase chemistry of isocyanic acid, methyl isocyanate, and cyanogen halides

James M. Roberts and Yong Liu

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AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
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AR: Author's response | RR: Referee report | ED: Editor decision
AR by James Roberts on behalf of the Authors (23 Feb 2019)  Author's response    Manuscript
ED: Publish subject to technical corrections (05 Mar 2019) by Sergey A. Nizkorodov
AR by James Roberts on behalf of the Authors (08 Mar 2019)  Author's response    Manuscript
Publications Copernicus
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Short summary
Condensed-phase reactions are important removal processes for reduced nitrogen species, isocyanic acid (HNCO), methyl isocyanate (CH3NCO), and cyanogen halides (XCN, X = Cl, Br, I). This chemistry is not well understood, so we measured aqueous-phase solubilities and reaction rates under a range of temperatures and conditions and in n-octanol, a proxy for non-polar media and biological membranes. The results were used to estimate atmospheric removal rates and fates of these nitrogen compounds.
Condensed-phase reactions are important removal processes for reduced nitrogen species,...
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