Articles | Volume 15, issue 14
https://doi.org/10.5194/acp-15-7913-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-7913-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
17 Jul 2015
Research article |
| 17 Jul 2015
The impact of parameterising light penetration into snow on the photochemical production of NOx and OH radicals in snow
H. G. Chan
CORRESPONDING AUTHOR
British Antarctic Survey, Natural Environment Research Council, Cambridge, CB3 0ET, UK
Department of Earth Sciences, Royal Holloway University of London, Egham, Surrey, TW20 0EX, UK
M. D. King
Department of Earth Sciences, Royal Holloway University of London, Egham, Surrey, TW20 0EX, UK
M. M. Frey
British Antarctic Survey, Natural Environment Research Council, Cambridge, CB3 0ET, UK
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Atmos. Chem. Phys., 18, 1507–1534, https://doi.org/10.5194/acp-18-1507-2018, https://doi.org/10.5194/acp-18-1507-2018, 2018
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Emissions of reactive nitrogen from snowpacks influence remote air quality. Two physical air–snow models for nitrate were developed. One assumes that below a threshold temperature the air–snow grain interface is pure ice and above it a disordered interface emerges. The other assumes an air–ice interface below melting and that any liquid present is concentrated in micropockets. Only the latter matches observations at two Antarctic lcoations covering a wide range of environmental conditions.
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In 2018, a new 120 m ice core was drilled in a region located under the Antarctic ozone hole. We present the first results including a 1300-year record of snow accumulation and aerosol chemistry. We investigate the aerosol and moisture source regions and atmospheric processes related to the ice core record and discuss what this means for developing a record of past ultraviolet-radiation and ozone depletion using the stable isotopic composition of nitrate measured in the same ice core.
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This is a comprehensive model–data comparison aiming to evaluate the proposed mechanism of sea salt aerosol (SSA) production from blowing snow on sea ice. Some key parameters such as snow salinity and blowing-snow size distribution were constrained by data collected in the Weddell Sea. The good agreement between modelled SSA and the cruise data strongly indicates that sea ice surface is a large SSA source in polar regions, a process which has not been considered in current climate models.
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Atmos. Chem. Phys., 18, 5235–5252, https://doi.org/10.5194/acp-18-5235-2018, https://doi.org/10.5194/acp-18-5235-2018, 2018
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The refractive index of atmospheric extracts sourced from urban (London), remote (Antarctica), and woodsmoke aerosol was determined by applying optical trapping simultaneously with Mie spectroscopy. In addition, owing to the absorbing nature of woodsmoke and an aqueous humic acid aerosol extract, the absorption Ångström exponent could be determined.The refractive index and absorption Ångström exponent were then applied in a top-of-the-atmosphere albedo radiation transfer model.
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Emissions of reactive nitrogen from snowpacks influence remote air quality. Two physical air–snow models for nitrate were developed. One assumes that below a threshold temperature the air–snow grain interface is pure ice and above it a disordered interface emerges. The other assumes an air–ice interface below melting and that any liquid present is concentrated in micropockets. Only the latter matches observations at two Antarctic lcoations covering a wide range of environmental conditions.
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Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
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Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
M. L. Lamare, J. Lee-Taylor, and M. D. King
Atmos. Chem. Phys., 16, 843–860, https://doi.org/10.5194/acp-16-843-2016, https://doi.org/10.5194/acp-16-843-2016, 2016
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The decrease in reflectivity (albedo) of sea ice and snow containing mineral dusts and volcanic ashes is calculated. The type of snow and sea ice, the thickness and the layering of mineral aerosol deposits are varied. The results show that the response of the albedo of snow and sea ice to mineral aerosol deposits is more sensitive to the type of snow or sea ice than to the properties of the mineral aerosol deposits themselves.
J. Erbland, J. Savarino, S. Morin, J. L. France, M. M. Frey, and M. D. King
Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, https://doi.org/10.5194/acp-15-12079-2015, 2015
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In this paper, we describe the development of a numerical model which aims at representing nitrate recycling at the air-snow interface on the East Antarctic Plateau. Stable isotopes are used as diagnostic and evaluation tools by comparing the model's results to recent field measurements of nitrate and key atmospheric species at Dome C, Antarctica. From sensitivity tests conducted with the model, we propose a framework for the interpretation of the nitrate isotope record in deep ice cores.
M. M. Frey, H. K. Roscoe, A. Kukui, J. Savarino, J. L. France, M. D. King, M. Legrand, and S. Preunkert
Atmos. Chem. Phys., 15, 7859–7875, https://doi.org/10.5194/acp-15-7859-2015, https://doi.org/10.5194/acp-15-7859-2015, 2015
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Surprisingly large concentrations and flux of atmospheric nitrogen oxides were measured at Dome C, East Antarctica. It was found that the surface snow holds a significant reservoir of photochemically produced NOx and is a sink of gas-phase ozone. Main drivers of NOx snow emissions were large snow nitrate concentrations, with contributions of increased UV from decreases in stratospheric ozone. Observed halogen and hydroxyl radical concentrations were too low to explain large NO2:NO ratios.
S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino, H. Gallée, M. King, B. Jourdain, W. Vicars, and D. Helmig
Atmos. Chem. Phys., 15, 6689–6705, https://doi.org/10.5194/acp-15-6689-2015, https://doi.org/10.5194/acp-15-6689-2015, 2015
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During two austral summers HCHO was investigated in air, snow, and interstitial air at the Concordia site located on the East Antarctic Plateau. Snow emission fluxes were estimated to be around 1 to 2 and 3 to 5 x 10^12 molecules m-2 s-1 at night and at noon, respectively. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible. The mean HCHO level of 130pptv observed at 1m above the surface is quite well reproduced by 1-D simulations.
H. Gallée, S. Preunkert, S. Argentini, M. M. Frey, C. Genthon, B. Jourdain, I. Pietroni, G. Casasanta, H. Barral, E. Vignon, C. Amory, and M. Legrand
Atmos. Chem. Phys., 15, 6225–6236, https://doi.org/10.5194/acp-15-6225-2015, https://doi.org/10.5194/acp-15-6225-2015, 2015
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Regional climate model MAR was run for the region of Dome C located on the East Antarctic plateau, during summer 2011–2012, with a high vertical resolution in the lower troposphere. MAR is generally in very good agreement with the observations and provides sufficiently reliable information about surface turbulent fluxes and vertical profiles of vertical diffusion coefficients when discussing the representativeness of chemical measurements made nearby the ground surface at Dome C.
A. Kukui, M. Legrand, S. Preunkert, M. M. Frey, R. Loisil, J. Gil Roca, B. Jourdain, M. D. King, J. L. France, and G. Ancellet
Atmos. Chem. Phys., 14, 12373–12392, https://doi.org/10.5194/acp-14-12373-2014, https://doi.org/10.5194/acp-14-12373-2014, 2014
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Concentrations of OH radicals and the sum of peroxy radicals, RO2, were measured in the boundary layer for the first time on the East Antarctic Plateau at the Concordia Station during the austral summer 2011/2012. The concentrations of radicals were comparable to those observed at the South Pole, confirming that the elevated oxidative capacity of the Antarctic atmospheric boundary layer found at the South Pole is not restricted to the South Pole but common over the high Antarctic plateau.
M. Legrand, S. Preunkert, M. Frey, Th. Bartels-Rausch, A. Kukui, M. D. King, J. Savarino, M. Kerbrat, and B. Jourdain
Atmos. Chem. Phys., 14, 9963–9976, https://doi.org/10.5194/acp-14-9963-2014, https://doi.org/10.5194/acp-14-9963-2014, 2014
A. A. Marks and M. D. King
The Cryosphere, 8, 1625–1638, https://doi.org/10.5194/tc-8-1625-2014, https://doi.org/10.5194/tc-8-1625-2014, 2014
Q. Libois, G. Picard, J. L. France, L. Arnaud, M. Dumont, C. M. Carmagnola, and M. D. King
The Cryosphere, 7, 1803–1818, https://doi.org/10.5194/tc-7-1803-2013, https://doi.org/10.5194/tc-7-1803-2013, 2013
S. Masclin, M. M. Frey, W. F. Rogge, and R. C. Bales
Atmos. Chem. Phys., 13, 8857–8877, https://doi.org/10.5194/acp-13-8857-2013, https://doi.org/10.5194/acp-13-8857-2013, 2013
A. A. Marks and M. D. King
The Cryosphere, 7, 1193–1204, https://doi.org/10.5194/tc-7-1193-2013, https://doi.org/10.5194/tc-7-1193-2013, 2013
J. Erbland, W. C. Vicars, J. Savarino, S. Morin, M. M. Frey, D. Frosini, E. Vince, and J. M. F. Martins
Atmos. Chem. Phys., 13, 6403–6419, https://doi.org/10.5194/acp-13-6403-2013, https://doi.org/10.5194/acp-13-6403-2013, 2013
M. M. Frey, N. Brough, J. L. France, P. S. Anderson, O. Traulle, M. D. King, A. E. Jones, E. W. Wolff, and J. Savarino
Atmos. Chem. Phys., 13, 3045–3062, https://doi.org/10.5194/acp-13-3045-2013, https://doi.org/10.5194/acp-13-3045-2013, 2013
Related subject area
Subject: Radiation | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
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Bjorn Stevens and Lukas Kluft
Atmos. Chem. Phys., 23, 14673–14689, https://doi.org/10.5194/acp-23-14673-2023, https://doi.org/10.5194/acp-23-14673-2023, 2023
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A simple model is introduced to account for the spectral diversity of radiant energy transfer. It provides an improved basis for assessing the different ways in which clouds influence Earth’s climate sensitivity, demonstrating how many cloud effects depend on the existing cloud climatology. Given existing assessments of changes in cloud albedo with warming, it is determined that clouds reduce Earth's climate sensitivity as compared to what it would be in a counterfactual world without clouds.
Kevin Wolf, Nicolas Bellouin, and Olivier Boucher
Atmos. Chem. Phys., 23, 14003–14037, https://doi.org/10.5194/acp-23-14003-2023, https://doi.org/10.5194/acp-23-14003-2023, 2023
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Cirrus and contrails considerably impact Earth's energy budget. Such ice clouds can have a positive (warming) or negative (cooling) net radiative effect (RE), which depends on cloud and ambient properties. The effect of eight parameters on the cloud RE is estimated. In total, 283 500 radiative transfer simulations have been performed, spanning the typical parameter ranges associated with cirrus and contrails. Specific cases are selected and discussed. The data set is publicly available.
Adam C. Varble, Po-Lun Ma, Matthew W. Christensen, Johannes Mülmenstädt, Shuaiqi Tang, and Jerome Fast
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We evaluate how clouds change in response to changing atmospheric particle (aerosol) concentrations in a climate model and find that the model-predicted cloud brightness increases too much as aerosols increase because the cloud drop number increases too much. Excessive drizzle in the model mutes this difference. Many differences between observational and model estimates are explained by varying assumptions of how much liquid has been lost in clouds, which impacts the estimated cloud drop number.
Olivia Linke, Johannes Quaas, Finja Baumer, Sebastian Becker, Jan Chylik, Sandro Dahlke, André Ehrlich, Dörthe Handorf, Christoph Jacobi, Heike Kalesse-Los, Luca Lelli, Sina Mehrdad, Roel A. J. Neggers, Johannes Riebold, Pablo Saavedra Garfias, Niklas Schnierstein, Matthew D. Shupe, Chris Smith, Gunnar Spreen, Baptiste Verneuil, Kameswara S. Vinjamuri, Marco Vountas, and Manfred Wendisch
Atmos. Chem. Phys., 23, 9963–9992, https://doi.org/10.5194/acp-23-9963-2023, https://doi.org/10.5194/acp-23-9963-2023, 2023
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Lapse rate feedback (LRF) is a major driver of the Arctic amplification (AA) of climate change. It arises because the warming is stronger at the surface than aloft. Several processes can affect the LRF in the Arctic, such as the omnipresent temperature inversion. Here, we compare multimodel climate simulations to Arctic-based observations from a large research consortium to broaden our understanding of these processes, find synergy among them, and constrain the Arctic LRF and AA.
Behrooz Keshtgar, Aiko Voigt, Bernhard Mayer, and Corinna Hoose
EGUsphere, https://doi.org/10.5194/egusphere-2023-1699, https://doi.org/10.5194/egusphere-2023-1699, 2023
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Cloud radiative heating and cooling (CRH) affects the dynamics and predictability of extratropical cyclones. However, CRH is uncertain in weather and climate models, and CRH uncertainties can affect the predictability of cyclones. In this study, we provide a systematic quantification of CRH uncertainties within a cyclone due to four factors. We show that the parameterization of the ice-optical properties contributes significantly to the uncertainty in the CRH within the cyclone.
Mark D. Zelinka, Christopher J. Smith, Yi Qin, and Karl E. Taylor
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The primary uncertainty in how strongly Earth's climate has been perturbed by human activities comes from the unknown radiative impact of aerosol changes. Accurately quantifying these forcings – and their sub-components – in climate models is crucial for understanding the past and future simulated climate. In this study we describe biases in previously published estimates of aerosol radiative forcing in climate models and provide corrected estimates along with code for users to compute them.
Ilias Fountoulakis, Alexandra Tsekeri, Stelios Kazadzis, Vassilis Amiridis, Angelos Nersesian, Maria Tsichla, Emmanouil Proestakis, Antonis Gkikas, Kyriakoula Papachristopoulou, Vasileios Barlakas, Claudia Emde, and Bernhard Mayer
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In our study we provide an assessment, through a sensitivity study, of the limitations of models to calculate the dust direct radiative effect (DRE) due to the underrepresentation of its size, refractive index (RI) and shape. Our results indicate the necessity of including more realistic sizes and RIs for dust particles in dust models, in order to derive better estimations of the dust direct radiative effects.
Tatiana Egorova, Jan Sedlacek, Timofei Sukhodolov, Arseniy Karagodin-Doyennel, Franziska Zilker, and Eugene Rozanov
Atmos. Chem. Phys., 23, 5135–5147, https://doi.org/10.5194/acp-23-5135-2023, https://doi.org/10.5194/acp-23-5135-2023, 2023
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This paper describes the climate and atmosphere benefits of the Montreal Protocol, simulated with the state-of-the-art Earth system model SOCOLv4.0. We have added to and confirmed the previous studies by showing that without the Montreal Protocol by the end of the 21st century there would be a dramatic reduction in the ozone layer as well as substantial perturbation of the essential climate variables in the troposphere caused by the warming from increasing ozone-depleting substances.
Daniele Visioni, Ben Kravitz, Alan Robock, Simone Tilmes, Jim Haywood, Olivier Boucher, Mark Lawrence, Peter Irvine, Ulrike Niemeier, Lili Xia, Gabriel Chiodo, Chris Lennard, Shingo Watanabe, John C. Moore, and Helene Muri
Atmos. Chem. Phys., 23, 5149–5176, https://doi.org/10.5194/acp-23-5149-2023, https://doi.org/10.5194/acp-23-5149-2023, 2023
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Geoengineering indicates methods aiming to reduce the temperature of the planet by means of reflecting back a part of the incoming radiation before it reaches the surface or allowing more of the planetary radiation to escape into space. It aims to produce modelling experiments that are easy to reproduce and compare with different climate models, in order to understand the potential impacts of these techniques. Here we assess its past successes and failures and talk about its future.
Yingfang Li, Zhili Wang, Yadong Lei, Huizheng Che, and Xiaoye Zhang
Atmos. Chem. Phys., 23, 2499–2523, https://doi.org/10.5194/acp-23-2499-2023, https://doi.org/10.5194/acp-23-2499-2023, 2023
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Since few studies have assessed the impacts of future combined reductions in aerosols, ozone, and their precursors on future climate change, we use models with an interactive representation of tropospheric aerosols and atmospheric chemistry schemes to quantify the impact of their reductions on the Asian climate. Our results suggest that their reductions will exacerbate the warming effect caused by greenhouse gases, increasing future climate extremes and associated population exposure risk.
Andreas Marsing, Ralf Meerkötter, Romy Heller, Stefan Kaufmann, Tina Jurkat-Witschas, Martina Krämer, Christian Rolf, and Christiane Voigt
Atmos. Chem. Phys., 23, 587–609, https://doi.org/10.5194/acp-23-587-2023, https://doi.org/10.5194/acp-23-587-2023, 2023
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We employ highly resolved aircraft measurements of profiles of the ice water content (IWC) in Arctic cirrus clouds in winter and spring, when solar irradiation is low. Using radiation transfer calculations, we assess the cloud radiative effect over different surfaces like snow or ocean. The variability in the IWC of the clouds affects their overall radiative effect and drives internal processes. This helps understand the role of cirrus in a rapidly changing Arctic environment.
John T. Fasullo and Jadwiga H. Richter
Atmos. Chem. Phys., 23, 163–182, https://doi.org/10.5194/acp-23-163-2023, https://doi.org/10.5194/acp-23-163-2023, 2023
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The continued high levels of anthropogenic greenhouse gas emissions increase the likelihood that key climate warming thresholds will be exceeded in the coming decades. Here we examine a recently proposed geoengineering approach using two recently produced climate model experiments. We find the associated latitudinal distribution of aerosol mass to exhibit substantial uncertainty, suggesting the need for significant flexibility in the location and amount of aerosol delivery, if implemented.
Youness El-Ouartassy, Irène Korsakissok, Matthieu Plu, Olivier Connan, Laurent Descamps, and Laure Raynaud
Atmos. Chem. Phys., 22, 15793–15816, https://doi.org/10.5194/acp-22-15793-2022, https://doi.org/10.5194/acp-22-15793-2022, 2022
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This work investigates the potential value of using fine-scale meteorological ensembles to represent the inherent meteorological uncertainties in atmospheric dispersion model outputs. Probabilistic scores were used to evaluate the probabilistic performance of dispersion ensembles, using an original dataset of new continuous 85Kr air concentration measurements and a well-known source term. The results show that the ensemble dispersion simulations perform better than deterministic ones.
Ilissa B. Ocko and Steven P. Hamburg
Atmos. Chem. Phys., 22, 9349–9368, https://doi.org/10.5194/acp-22-9349-2022, https://doi.org/10.5194/acp-22-9349-2022, 2022
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Hydrogen is considered a key strategy to decarbonize the global economy. However, hydrogen is also a short-lived indirect greenhouse gas that can easily leak into the atmosphere. Given that the climate impacts from hydrogen emissions are not well understood, especially in the near term, we assess impacts over all timescales for plausible emissions rates. We find that hydrogen leakage can cause more warming than widely perceived; thus, attention is needed to minimize emissions.
Dustin Francis Phillip Grogan, Cheng-Hsuan Lu, Shih-Wei Wei, and Sheng-Po Chen
Atmos. Chem. Phys., 22, 2385–2398, https://doi.org/10.5194/acp-22-2385-2022, https://doi.org/10.5194/acp-22-2385-2022, 2022
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This study shows that incorporating aerosols into satellite radiance calculations affects the representation of African easterly waves (AEWs), and their environment, over North Africa and the eastern Atlantic in a numerical weather model. These changes are driven by radiative effects of Saharan dust captured by the aerosol-affected radiances, which modify the initial fields and can improve the forecasting of AEWs.
Tao Tang, Drew Shindell, Yuqiang Zhang, Apostolos Voulgarakis, Jean-Francois Lamarque, Gunnar Myhre, Gregory Faluvegi, Bjørn H. Samset, Timothy Andrews, Dirk Olivié, Toshihiko Takemura, and Xuhui Lee
Atmos. Chem. Phys., 21, 13797–13809, https://doi.org/10.5194/acp-21-13797-2021, https://doi.org/10.5194/acp-21-13797-2021, 2021
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Previous studies showed that black carbon (BC) could warm the surface with decreased incoming radiation. With climate models, we found that the surface energy redistribution plays a more crucial role in surface temperature compared with other forcing agents. Though BC could reduce the surface heating, the energy dissipates less efficiently, which is manifested by reduced convective and evaporative cooling, thereby warming the surface.
Jiaojiao Liu and Xiangjun Shi
Atmos. Chem. Phys., 21, 10609–10624, https://doi.org/10.5194/acp-21-10609-2021, https://doi.org/10.5194/acp-21-10609-2021, 2021
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Cirrus thinning, which reduces the warming effect of cirrus clouds, has been investigated as a new geoengineering approach. In this study, a flexible seeding method is used to exploit the potential cooling effect of cirrus thinning. Simulation results show that the seeding method is essential for estimating the cooling effect. Cirrus thinning with the flexible seeding method could produce a considerable cooling effect, which is much stronger than the fixed seeding method.
Inés Sanz-Morère, Sebastian D. Eastham, Florian Allroggen, Raymond L. Speth, and Steven R. H. Barrett
Atmos. Chem. Phys., 21, 1649–1681, https://doi.org/10.5194/acp-21-1649-2021, https://doi.org/10.5194/acp-21-1649-2021, 2021
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Contrails cause ~50 % of aviation climate impacts, but this is highly uncertain. This is partly due to the effect of overlap between contrails and other cloud layers. We developed a model to quantify this effect, finding that overlap with natural clouds increased contrails' radiative forcing in 2015. This suggests that cloud avoidance may help in reducing aviation's climate impacts. We also find that contrail–contrail overlap reduces impacts by ~3 %, increasing non-linearly with optical depth.
Kine Onsum Moseid, Michael Schulz, Trude Storelvmo, Ingeborg Rian Julsrud, Dirk Olivié, Pierre Nabat, Martin Wild, Jason N. S. Cole, Toshihiko Takemura, Naga Oshima, Susanne E. Bauer, and Guillaume Gastineau
Atmos. Chem. Phys., 20, 16023–16040, https://doi.org/10.5194/acp-20-16023-2020, https://doi.org/10.5194/acp-20-16023-2020, 2020
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In this study we compare solar radiation at the surface from observations and Earth system models from 1961 to 2014. We find that the models do not reproduce the so-called
global dimmingas found in observations. Only model experiments with anthropogenic aerosol emissions display any dimming at all. The discrepancies between observations and models are largest in China, which we suggest is in part due to erroneous aerosol precursor emission inventories in the emission dataset used for CMIP6.
Richard J. Bantges, Helen E. Brindley, Jonathan E. Murray, Alan E. Last, Jacqueline E. Russell, Cathryn Fox, Stuart Fox, Chawn Harlow, Sebastian J. O'Shea, Keith N. Bower, Bryan A. Baum, Ping Yang, Hilke Oetjen, and Juliet C. Pickering
Atmos. Chem. Phys., 20, 12889–12903, https://doi.org/10.5194/acp-20-12889-2020, https://doi.org/10.5194/acp-20-12889-2020, 2020
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Understanding how ice clouds influence the Earth's energy balance remains a key challenge for predicting the future climate. These clouds are ubiquitous and are composed of ice crystals that have complex shapes that are incredibly difficult to model. This work exploits new measurements of the Earth's emitted thermal energy made from instruments flown on board an aircraft to test how well the latest ice cloud models can represent these clouds. Results indicate further developments are required.
Nina Črnivec and Bernhard Mayer
Atmos. Chem. Phys., 20, 10733–10755, https://doi.org/10.5194/acp-20-10733-2020, https://doi.org/10.5194/acp-20-10733-2020, 2020
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Unresolved interaction between clouds and atmospheric radiation is a source of uncertainty in weather and climate models. The present study highlights the potential of the state-of-the-art Tripleclouds radiative solver for shallow cumulus clouds, exposing the significance of properly representing subgrid cloud horizontal heterogeneity. The Tripleclouds concept was thereby incorporated in the widely employed δ-Eddington two-stream radiation scheme within the comprehensive libRadtran library.
Allison B. Marquardt Collow, Mark A. Miller, Lynne C. Trabachino, Michael P. Jensen, and Meng Wang
Atmos. Chem. Phys., 20, 10073–10090, https://doi.org/10.5194/acp-20-10073-2020, https://doi.org/10.5194/acp-20-10073-2020, 2020
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Uncertainties in marine boundary layer clouds arise in the presence of biomass burning aerosol, as is the case over the southeast Atlantic Ocean. Heating due to this aerosol has the potential to alter the thermodynamic profile as the aerosol is transported across the Atlantic Ocean. Radiation transfer experiments indicate local shortwave aerosol heating is ~2–8 K d−1; however uncertainties in this quantity exist due to the single-scattering albedo and back trajectories of the aerosol plume.
Christopher J. Smith, Ryan J. Kramer, Gunnar Myhre, Kari Alterskjær, William Collins, Adriana Sima, Olivier Boucher, Jean-Louis Dufresne, Pierre Nabat, Martine Michou, Seiji Yukimoto, Jason Cole, David Paynter, Hideo Shiogama, Fiona M. O'Connor, Eddy Robertson, Andy Wiltshire, Timothy Andrews, Cécile Hannay, Ron Miller, Larissa Nazarenko, Alf Kirkevåg, Dirk Olivié, Stephanie Fiedler, Anna Lewinschal, Chloe Mackallah, Martin Dix, Robert Pincus, and Piers M. Forster
Atmos. Chem. Phys., 20, 9591–9618, https://doi.org/10.5194/acp-20-9591-2020, https://doi.org/10.5194/acp-20-9591-2020, 2020
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The spread in effective radiative forcing for both CO2 and aerosols is narrower in the latest CMIP6 (Coupled Model Intercomparison Project) generation than in CMIP5. For the case of CO2 it is likely that model radiation parameterisations have improved. Tropospheric and stratospheric radiative adjustments to the forcing behave differently for different forcing agents, and there is still significant diversity in how clouds respond to forcings, particularly for total anthropogenic forcing.
Tao Tang, Drew Shindell, Yuqiang Zhang, Apostolos Voulgarakis, Jean-Francois Lamarque, Gunnar Myhre, Camilla W. Stjern, Gregory Faluvegi, and Bjørn H. Samset
Atmos. Chem. Phys., 20, 8251–8266, https://doi.org/10.5194/acp-20-8251-2020, https://doi.org/10.5194/acp-20-8251-2020, 2020
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By using climate simulations, we found that both CO2 and black carbon aerosols could reduce low-level cloud cover, which is mainly due to changes in relative humidity, cloud water, dynamics, and stability. Because the impact of cloud on solar radiation is in effect only during daytime, such cloud reduction could enhance solar heating, thereby raising the daily maximum temperature by 10–50 %, varying by region, which has great implications for extreme climate events and socioeconomic activity.
Tobias Donth, Evelyn Jäkel, André Ehrlich, Bernd Heinold, Jacob Schacht, Andreas Herber, Marco Zanatta, and Manfred Wendisch
Atmos. Chem. Phys., 20, 8139–8156, https://doi.org/10.5194/acp-20-8139-2020, https://doi.org/10.5194/acp-20-8139-2020, 2020
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Solar radiative effects of Arctic black carbon (BC) particles (suspended in the atmosphere and in the surface snowpack) were quantified under cloudless and cloudy conditions. An atmospheric and a snow radiative transfer model were coupled to account for radiative interactions between both compartments. It was found that (i) the warming effect of BC in the snowpack overcompensates for the atmospheric BC cooling effect, and (ii) clouds tend to reduce the atmospheric BC cooling and snow BC warming.
Paul Ockenfuß, Claudia Emde, Bernhard Mayer, and Germar Bernhard
Atmos. Chem. Phys., 20, 1961–1976, https://doi.org/10.5194/acp-20-1961-2020, https://doi.org/10.5194/acp-20-1961-2020, 2020
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We model solar radiation as it would be measured on the Earth's surface in the core shadow of a total solar eclipse. Subsequently, we compare our results to observations during the total eclipse 2017 for ultraviolet, visible and near-infrared wavelengths. Moreover, we analyze the effect of the surface reflectance, the ozone profile, aerosol and the topography and give a visualization of the prevailing photons paths in the atmosphere during the eclipse.
Nina Črnivec and Bernhard Mayer
Atmos. Chem. Phys., 19, 8083–8100, https://doi.org/10.5194/acp-19-8083-2019, https://doi.org/10.5194/acp-19-8083-2019, 2019
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The interaction between radiation and clouds represents a source of uncertainty in numerical weather prediction (NWP), due to both intrinsic problems of one-dimensional radiation schemes and poor representation of clouds. The underlying question addressed in this study is how large the bias is of radiative heating rates in NWP models for shallow cumulus clouds and how it scales with various parameters, such as solar zenith angle, surface albedo, cloud cover and liquid water path.
Ben Kravitz, Philip J. Rasch, Hailong Wang, Alan Robock, Corey Gabriel, Olivier Boucher, Jason N. S. Cole, Jim Haywood, Duoying Ji, Andy Jones, Andrew Lenton, John C. Moore, Helene Muri, Ulrike Niemeier, Steven Phipps, Hauke Schmidt, Shingo Watanabe, Shuting Yang, and Jin-Ho Yoon
Atmos. Chem. Phys., 18, 13097–13113, https://doi.org/10.5194/acp-18-13097-2018, https://doi.org/10.5194/acp-18-13097-2018, 2018
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Marine cloud brightening has been proposed as a means of geoengineering/climate intervention, or deliberately altering the climate system to offset anthropogenic climate change. In idealized simulations that highlight contrasts between land and ocean, we find that the globe warms, including the ocean due to transport of heat from land. This study reinforces that no net energy input into the Earth system does not mean that temperature will necessarily remain unchanged.
Rick D. Russotto and Thomas P. Ackerman
Atmos. Chem. Phys., 18, 11905–11925, https://doi.org/10.5194/acp-18-11905-2018, https://doi.org/10.5194/acp-18-11905-2018, 2018
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In simulations with different climate models in which the strength of the Sun is reduced to cancel the surface warming from a quadrupling of atmospheric carbon dioxide, low cloud cover decreases, high cloud cover increases, the upper troposphere and stratosphere cool, and water vapor concentration decreases. The stratospheric cooling and low cloud reduction result in more sunlight reduction being needed than originally thought.
Justyna Lisok, Anna Rozwadowska, Jesper G. Pedersen, Krzysztof M. Markowicz, Christoph Ritter, Jacek W. Kaminski, Joanna Struzewska, Mauro Mazzola, Roberto Udisti, Silvia Becagli, and Izabela Gorecka
Atmos. Chem. Phys., 18, 8829–8848, https://doi.org/10.5194/acp-18-8829-2018, https://doi.org/10.5194/acp-18-8829-2018, 2018
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The aim of the presented study was to investigate the impact on the radiation budget and atmospheric dynamics of a biomass-burning plume, transported from Alaska to the High Arctic region of Ny-Ålesund, Svalbard, in early July 2015. We found that the smoke plume may significantly alter radiative properties of the atmosphere. Furthermore, the simulations of atmospheric dynamics indicated a vertical positive displacement and broadening of the plume with time.
Simon Gruber, Simon Unterstrasser, Jan Bechtold, Heike Vogel, Martin Jung, Henry Pak, and Bernhard Vogel
Atmos. Chem. Phys., 18, 6393–6411, https://doi.org/10.5194/acp-18-6393-2018, https://doi.org/10.5194/acp-18-6393-2018, 2018
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A numerical model also used for operational weather forecast was applied to investigate the impact of contrails and contrail cirrus on the radiative fluxes at the earth's surface. Accounting for contrails produced by aircraft enables the model to simulate high clouds that are otherwise missing. In a case study, we find that the effect of these extra clouds is to reduce the incoming shortwave radiation at the surface as well as the production of photovoltaic power by up to 10 %.
Andrew E. Dessler, Thorsten Mauritsen, and Bjorn Stevens
Atmos. Chem. Phys., 18, 5147–5155, https://doi.org/10.5194/acp-18-5147-2018, https://doi.org/10.5194/acp-18-5147-2018, 2018
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One of the most important parameters in climate science is the equilibrium climate sensitivity (ECS). Estimates of this quantity based on 20th-century observations suggest low values of ECS (below 2 °C). We show that these calculations may be significantly in error. Together with other recent work on this problem, it seems probable that the ECS is larger than suggested by the 20th-century observations.
Jake J. Gristey, J. Christine Chiu, Robert J. Gurney, Cyril J. Morcrette, Peter G. Hill, Jacqueline E. Russell, and Helen E. Brindley
Atmos. Chem. Phys., 18, 5129–5145, https://doi.org/10.5194/acp-18-5129-2018, https://doi.org/10.5194/acp-18-5129-2018, 2018
Daniela Meloni, Alcide di Sarra, Gérard Brogniez, Cyrielle Denjean, Lorenzo De Silvestri, Tatiana Di Iorio, Paola Formenti, José L. Gómez-Amo, Julian Gröbner, Natalia Kouremeti, Giuliano Liuzzi, Marc Mallet, Giandomenico Pace, and Damiano M. Sferlazzo
Atmos. Chem. Phys., 18, 4377–4401, https://doi.org/10.5194/acp-18-4377-2018, https://doi.org/10.5194/acp-18-4377-2018, 2018
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This study examines how different aerosol optical properties determine the dust longwave radiative effects at the surface, in the atmosphere and at the top of the atmosphere, based on the combination of remote sensing and in situ observations from the ground, from airborne sensors, and from space, by means of radiative transfer modelling. The closure experiment is based on longwave irradiances and spectral brightness temperatures measured during the 2013 ChArMEx–ADRIMED campaign at Lampedusa.
Netsanet K. Alamirew, Martin C. Todd, Claire L. Ryder, John H. Marsham, and Yi Wang
Atmos. Chem. Phys., 18, 1241–1262, https://doi.org/10.5194/acp-18-1241-2018, https://doi.org/10.5194/acp-18-1241-2018, 2018
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This paper quantifies the radiative effects of dust and water vapour in the Saharan heat low. Dust has a warming effect at the top of the atmosphere while cooling the surface. Water vapour has a warming effect both at the top of atmosphere and the surface. We find dust and water vapour have similar effects in driving the variability in the top-of-atmosphere radiative budget, while dust has a stronger effect than water vapour in controlling day-to-day variability of the surface radiative budget.
Fabian Jakub and Bernhard Mayer
Atmos. Chem. Phys., 17, 13317–13327, https://doi.org/10.5194/acp-17-13317-2017, https://doi.org/10.5194/acp-17-13317-2017, 2017
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The formation of shallow cumulus cloud streets was historically attributed primarily to dynamics. Here, we focus on the interaction between radiatively induced surface heterogeneities and the resulting patterns in the flow. Our results suggest that solar radiative heating has the potential to organize clouds perpendicular to the sun's incidence angle.
Guadalupe Sanchez, Antonio Serrano, and María Luisa Cancillo
Atmos. Chem. Phys., 17, 12697–12708, https://doi.org/10.5194/acp-17-12697-2017, https://doi.org/10.5194/acp-17-12697-2017, 2017
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This study proposes models to estimate the UVER diffuse irradiance, which means, at least, 40 % of the ultraviolet solar radiation reaching the Earth's surface at mid-latitudes. These models are inspired by expressions originally used to estimate total diffuse fraction and rely on variables commonly available to favor their applicability. The best model in this paper performs better than previous approaches and no additional information about the cloud or aerosol layer is needed.
Päivi Haapanala, Petri Räisänen, Greg M. McFarquhar, Jussi Tiira, Andreas Macke, Michael Kahnert, John DeVore, and Timo Nousiainen
Atmos. Chem. Phys., 17, 6865–6882, https://doi.org/10.5194/acp-17-6865-2017, https://doi.org/10.5194/acp-17-6865-2017, 2017
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The dependence of solar-disk and circumsolar radiances on ice cloud
properties is studied with a Monte Carlo radiative transfer model. Ice
crystal roughness (or more generally, non-ideality) is found to be the
most important parameter influencing the circumsolar radiance, and ice
crystal sizes and shapes also play significant roles. When comparing
with radiances measured with the SAM instrument, rough ice crystals
reproduce the measurements better than idealized smooth ice crystals do.
Carolin Klinger, Bernhard Mayer, Fabian Jakub, Tobias Zinner, Seung-Bu Park, and Pierre Gentine
Atmos. Chem. Phys., 17, 5477–5500, https://doi.org/10.5194/acp-17-5477-2017, https://doi.org/10.5194/acp-17-5477-2017, 2017
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Radiation is driving weather and climate. Yet, the effect of radiation on clouds is not fully understood and often only poorly represented in models. Better understanding and better parameterizations of the radiation–cloud interaction are therefore essential. Using our newly developed fast
neighboring column approximationfor 3-D thermal heating and cooling rates, we show that thermal radiation changes cloud circulation and causes organization and a deepening of the clouds.
Nicolas Bellouin, Laura Baker, Øivind Hodnebrog, Dirk Olivié, Ribu Cherian, Claire Macintosh, Bjørn Samset, Anna Esteve, Borgar Aamaas, Johannes Quaas, and Gunnar Myhre
Atmos. Chem. Phys., 16, 13885–13910, https://doi.org/10.5194/acp-16-13885-2016, https://doi.org/10.5194/acp-16-13885-2016, 2016
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This study uses global climate models to quantify how strongly man-made emissions of selected pollutants modify the energy budget of the Earth. The pollutants studied interact directly and indirectly with sunlight and terrestrial radiation and remain a relatively short time in the atmosphere, leading to regional and seasonal variations in their impacts. This new data set is useful to compare the potential climate impacts of different pollutants in support of policies to reduce climate change.
Shi Song, K. Sebastian Schmidt, Peter Pilewskie, Michael D. King, Andrew K. Heidinger, Andi Walther, Hironobu Iwabuchi, Gala Wind, and Odele M. Coddington
Atmos. Chem. Phys., 16, 13791–13806, https://doi.org/10.5194/acp-16-13791-2016, https://doi.org/10.5194/acp-16-13791-2016, 2016
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The radiative effects of spatially complex cloud fields are notoriously difficult to estimate and are afflicted with errors up to ±50 % of the incident solar radiation. We find that horizontal photon transport, the leading cause for these three-dimensional effects, manifests itself through a spectral fingerprint – a new observable that holds promise for reducing the errors associated with spatial complexity by moving the problem to the spectral dimension.
Agnieszka E. Czerwińska, Janusz W. Krzyścin, Janusz Jarosławski, and Michał Posyniak
Atmos. Chem. Phys., 16, 13641–13651, https://doi.org/10.5194/acp-16-13641-2016, https://doi.org/10.5194/acp-16-13641-2016, 2016
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This article presents a comparison between the two surface-UV dose series, measured with Brewer spectrophotometers working simultaneously at two different sites in Poland: in a large city agglomeration and in the suburbs. We consider whether the city of Warsaw acts as a shield from ultraviolet overexposure. Our study proves that the UV level in Warsaw is slightly lower than that found in cleaner suburbs of the city.
Camilla Weum Stjern, Bjørn Hallvard Samset, Gunnar Myhre, Huisheng Bian, Mian Chin, Yanko Davila, Frank Dentener, Louisa Emmons, Johannes Flemming, Amund Søvde Haslerud, Daven Henze, Jan Eiof Jonson, Tom Kucsera, Marianne Tronstad Lund, Michael Schulz, Kengo Sudo, Toshihiko Takemura, and Simone Tilmes
Atmos. Chem. Phys., 16, 13579–13599, https://doi.org/10.5194/acp-16-13579-2016, https://doi.org/10.5194/acp-16-13579-2016, 2016
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Air pollution can reach distant regions through intercontinental transport. Here we first present results from the Hemispheric Transport of Air Pollution Phase 2 exercise, where many models performed the same set of coordinated emission-reduction experiments. We find that mitigations have considerable extra-regional effects, and show that this is particularly true for black carbon emissions, as long-range transport elevates aerosols to higher levels where their radiative influence is stronger.
Nataly Chubarova, Yekaterina Zhdanova, and Yelena Nezval
Atmos. Chem. Phys., 16, 11867–11881, https://doi.org/10.5194/acp-16-11867-2016, https://doi.org/10.5194/acp-16-11867-2016, 2016
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Biologically active ultraviolet (UV) radiation is an important environmental factor, which affect human health and nature. UV radiation has a significant increase with the altitude. We propose a new method for calculating the altitude UV dependence for different types of biologically active UV radiation. The proposed method was implemented in the on-line UV tool (http://momsu.ru/uv/) for Northern Eurasia. The possible UV effects on human health were considered over Alpine zone.
Alex Montornès, Bernat Codina, John W. Zack, and Yolanda Sola
Atmos. Chem. Phys., 16, 5949–5967, https://doi.org/10.5194/acp-16-5949-2016, https://doi.org/10.5194/acp-16-5949-2016, 2016
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This paper documents a new package for the Weather Research and Forecasting--Advanced Research WRF (WRF-ARW) model that can simulate any partial, total or hybrid solar eclipse for the period 1950–2050 and is also extensible to a longer period. First, a description of the implementation together with a validation for the period 1950–2050 of all solar eclipse trajectories is presented. Second, the model response is analyzed in four total solar eclipse episodes. Global horizontal irradiance (GHI) outcomes are validated with respect to ground-based measurements.
Bin Zhao, Kuo-Nan Liou, Yu Gu, Cenlin He, Wee-Liang Lee, Xing Chang, Qinbin Li, Shuxiao Wang, Hsien-Liang R. Tseng, Lai-Yung R. Leung, and Jiming Hao
Atmos. Chem. Phys., 16, 5841–5852, https://doi.org/10.5194/acp-16-5841-2016, https://doi.org/10.5194/acp-16-5841-2016, 2016
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We examine the impact of buildings on surface solar fluxes in Beijing by accounting for their 3-D structures. We find that inclusion of buildings changes surface solar fluxes by within ±1 W m−2, ±1–10 W m−2, and up to ±100 W m−2 at grid resolutions of 4 km, 800 m, and 90 m, respectively. We can resolve pairs of positive-negative flux deviations on different sides of buildings at ≤ 800 m resolutions. We should treat building-effect on solar fluxes differently in models with different resolutions.
Thomas Schmidt, John Kalisch, Elke Lorenz, and Detlev Heinemann
Atmos. Chem. Phys., 16, 3399–3412, https://doi.org/10.5194/acp-16-3399-2016, https://doi.org/10.5194/acp-16-3399-2016, 2016
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We performed an irradiance forecast experiment based on analysis of
hemispheric sky images and evaluated results on a large data set of 99
pyranometers distributed over 10 × 12 km. We developed a surface
irradiance retrieval from cloud information derived from the images.
Very high resolution forecasts were processed up to 25 min. A main
finding is that forecast skill is enhanced in complex cloud conditions
leading to high variability in surface irradiance.
G. Alexandri, A. K. Georgoulias, P. Zanis, E. Katragkou, A. Tsikerdekis, K. Kourtidis, and C. Meleti
Atmos. Chem. Phys., 15, 13195–13216, https://doi.org/10.5194/acp-15-13195-2015, https://doi.org/10.5194/acp-15-13195-2015, 2015
Short summary
Short summary
It is shown here that RegCM4 regional climate model adequately simulates surface solar radiation (SSR) over Europe but significantly over/underestimates several parameters that determine the transmission of solar radiation in the atmosphere. The agreement between RegCM4 and satellite-based SSR observations is actually a result of the conflicting effect of these parameters. We suggest that there should be a reassessment of the way these parameters are represented within this and other models.
M. E. Nicholls
Atmos. Chem. Phys., 15, 9003–9029, https://doi.org/10.5194/acp-15-9003-2015, https://doi.org/10.5194/acp-15-9003-2015, 2015
Cited articles
Anastasio, C. and Chuand, L.: Formation of hydroxyl radical from the photolysis of frozen hydrogen peroxide, J. Phys. Chem. A, 112, 2747–2748, https://doi.org/10.1021/jp800491n, 2008.
Bartels-Rausch, T., Jacobi, H.-W., Kahan, T. F., Thomas, J. L., Thomson, E. S., Abbatt, J. P. D., Ammann, M., Blackford, J. R., Bluhm, H., Boxe, C., Domine, F., Frey, M. M., Gladich, I., Guzmán, M. I., Heger, D., Huthwelker, Th., Klán, P., Kuhs, W. F., Kuo, M. H., Maus, S., Moussa, S. G., McNeill, V. F., Newberg, J. T., Pettersson, J. B. C., Roeselová, M., and Sodeau, J. R.: A review of air-ice chemical and physical interactions (AICI): liquids, quasi-liquids, and solids in snow, Atmos. Chem. Phys., 14, 1587–1633, https://doi.org/10.5194/acp-14-1587-2014, 2014.
Beaglehole, D., Ramanathan, B., and Rumberg, J.: The UV to IR transmittance of Antarctic snow, J. Geophys. Res.-Atmos., 103, 8849–8857, https://doi.org/10.1029/97JD03604, 1998.
Beine, H. J., Dominé, F., Simpson, W., Honrath, R. E., Sparapani, R., Zhou, X., and King, M.: Snow-pile and chamber experiments during the Polar Sunrise Experiment "Alert 2000": exploration of nitrogen chemistry, Atmos. Environ., 36, 2707–2719, https://doi.org/10.1016/S1352-2310(02)00120-6, 2002.
Beine, H. J., Amoroso, A., Dominé, F., King, M. D., Nardino, M., Ianniello, A., and France, J. L.: Surprisingly small HONO emissions from snow surfaces at Browning Pass, Antarctica, Atmos. Chem. Phys., 6, 2569–2580, https://doi.org/10.5194/acp-6-2569-2006, 2006.
Chen, G., Davis, D., Crawford, J., Hutterli, L., Huey, L., Slusher, D., Mauldin, L., Eisele, F., Tanner, D., Dibb, J., Buhr, M., McConnell, J., Lefer, B., Shetter, R., Blake, D., Song, C., Lombardi, K., and Arnoldy, J.: A reassessment of HOx South Pole chemistry based on observations recorded during ISCAT 2000, Atmos. Environ., 38, 5451–5461, 2004.
Chu, L. and Anastasio, C.: Quantum yields of hydroxyl radical and nitrogen dioxide from the photolysis of nitrate on ice, J. Phys. Chem. A, 107, 9594–9602, https://doi.org/10.1021/jp0349132, 2003.
Chu, L. and Anastasio, C.: Formation of hydroxyl radical from the photolysis of frozen hydrogen peroxide, J. Phys. Chem. A, 109, 6264–6271, https://doi.org/10.1021/jp051415f, 2005.
Chu, L., and Anastasio, C.: Temperature and wavelength dependence of nitrite photolysis in frozen and aqueous solutions, Environ. Sci. Technol., 41, 3626–3632, https://doi.org/10.1021/es062731q, 2007.
Cotter, E. S. N., Jones, A. E., Wolff, E. W., and Bauguitte, S. J.-B.: What controls photochemical NO and NO2 production from Antarctic snow? Laboratory investigation assessing the wavelength and temperature dependence, J. Geophys. Res.-Atmos., 108, 4147 , https://doi.org/10.1029/2002JD002602, 2003.
Davis, D., Chen, G., Buhr, M., Crawford, J., Lenschow, D., Lefer, B., Shetter, R., Eisele, F., Mauldin, L., and Hogan, A.: South Pole chemistry: an assessment of factors controlling variability and absolute levels, Atmos. Environ., 38, 5375–5388, 2004.
DeMore, W. B., C. J. Howard, D. M. G., Kolb, C. E., Hampson, R. F., and Molina, M. J.: Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling, JPL Publication 97–4, National Aeronautics and Space Administration, Jet Propulsion Laboratory, Pasadena, California, USA, 1997.
Dibb, J. E., Arsenault, M., Peterson, M. C., and Honrath, R. E.: Fast nitrogen oxide photochemistry in Summit, Greenland snow, Atmos. Environ., 36, 2501–2511, 2002.
Dubowski, Y., Colussi, A. J., and Hoffmann, M. R.: Nitrogen dioxide release in the 302 nm band photolysis of spray-frozen aqueous nitrate solutions. Atmospheric implications, J. Phys. Chem. A, 105, 4928–4932, https://doi.org/10.1021/jp0042009, 2001.
Dubowski, Y., Colussi, A. J., Boxe, C., and Hoffmann, M. R.: Monotonic increase of nitrite yields in the photolysis of nitrate in ice and water between 238 and 294 K, J. Phys. Chem. A, 106, 6967–6971, https://doi.org/10.1021/jp0142942, 2002.
Fisher, F. N., King, M. D., and Lee-Taylor, J.: Extinction of UV-visible radiation in wet midlatitude (maritime) snow: implications for increased NOx emission, J. Geophys. Res.-Atmos., 110, D21301, https://doi.org/10.1029/2005JD005963, 2005.
France, J. and King, M.: The effect of measurement geometry on recording solar radiation attenuation in snowpack (e-folding depth) using fibre-optic probes, J. Glaciol., 58, 417–418, https://doi.org/10.3189/2012JoG11J227, 2012.
France, J., King, M., and Lee-Taylor, J.: Hydroxyl (OH) radical production rates in snowpacks from photolysis of hydrogen peroxide (H2O2) and nitrate (NO3-), Atmos. Environ., 41, 5502–5509, https://doi.org/10.1016/j.atmosenv.2007.03.056, 2007.
France, J., King, M., and Lee-Taylor, J.: The importance of considering depth-resolved photochemistry in snow: a radiative-transfer study of NO2 and OH production in Ny-alesund (Svalbard) snowpacks, J. Glaciol., 56, 655–663, https://doi.org/10.3189/002214310793146250, 2010.
France, J. L., King, M. D., Frey, M. M., Erbland, J., Picard, G., Preunkert, S., MacArthur, A., and Savarino, J.: Snow optical properties at Dome C (Concordia), Antarctica; implications for snow emissions and snow chemistry of reactive nitrogen, Atmos. Chem. Phys., 11, 9787–9801, https://doi.org/10.5194/acp-11-9787-2011, 2011.
France, J. L., Reay, H. J., King, M. D., Voisin, D., Jacobi, H. W., Domine, F., Beine, H., Anastasio, C., MacArthur, A., and Lee-Taylor, J.: Hydroxyl radical and NOx production rates, black carbon concentrations and light-absorbing impurities in snow from field measurements of light penetration and nadir reflectivity of onshore and offshore coastal Alaskan snow, J. Geophys. Res.-Atmos., 117, D00R12, https://doi.org/10.1029/2011JD016639, 2012.
Frey, M. M., Savarino, J., Morin, S., Erbland, J., and Martins, J. M. F.: Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling, Atmos. Chem. Phys., 9, 8681–8696, https://doi.org/10.5194/acp-9-8681-2009, 2009.
Gardner, E. P., Sperry, P. D., and Calvert, J. G.: Primary quantum yields of NO2 photodissociation, J. Geophys. Res.-Atmos., 92, 6642–6652, https://doi.org/10.1029/JD092iD06p06642, 1987.
Grannas, A. M., Jones, A. E., Dibb, J., Ammann, M., Anastasio, C., Beine, H. J., Bergin, M., Bottenheim, J., Boxe, C. S., Carver, G., Chen, G., Crawford, J. H., Dominé, F., Frey, M. M., Guzmán, M. I., Heard, D. E., Helmig, D., Hoffmann, M. R., Honrath, R. E., Huey, L. G., Hutterli, M., Jacobi, H. W., Klán, P., Lefer, B., McConnell, J., Plane, J., Sander, R., Savarino, J., Shepson, P. B., Simpson, W. R., Sodeau, J. R., von Glasow, R., Weller, R., Wolff, E. W., and Zhu, T.: An overview of snow photochemistry: evidence, mechanisms and impacts, Atmos. Chem. Phys., 7, 4329–4373, https://doi.org/10.5194/acp-7-4329-2007, 2007.
Grenfell, T. C., Warren, S. G., and Mullen, P. C.: Reflection of solar radiation by the Antarctic snow surface at ultraviolet, visible, and near-infrared wavelengths, J. Geophys. Res.-Atmos., 99, 18669–18684, https://doi.org/10.1029/94JD01484, 1994.
Hoffer, A., Gelencsér, A., Guyon, P., Kiss, G., Schmid, O., Frank, G. P., Artaxo, P., and Andreae, M. O.: Optical properties of humic-like substances (HULIS) in biomass-burning aerosols, Atmos. Chem. Phys., 6, 3563–3570, https://doi.org/10.5194/acp-6-3563-2006, 2006.
Jacobi, H.-W., Bales, R. C., Honrath, R. E., Peterson, M. C., Dibb, J. E., Swanson, A. L., and Albert, M. R.: Reactive trace gases measured in the interstitial air of surface snow at Summit, Greenland, Atmos. Environ., 38, 1687–1697, https://doi.org/10.1016/j.atmosenv.2004.01.004,2004.
Jones, A. E., Weller, R., Wolff, E. W., and Jacobi, H. W.: Speciation and rate of photochemical NO and NO2 production in Antarctic snow, Geophys. Res. Lett., 27, 345–348, https://doi.org/10.1029/1999GL010885, 2000.
Khokanovsky, A. A.: Remote Sensing of the Cryosphere, Ch4 Remote sensing of snow albedo, grain size, and pollution from space, 48–72, John Wiley & Sons, Ltd, Chichester, UK, https://doi.org/10.1002/9781118368909.ch4, 2015.
King, M. D. and Simpson, W. R.: Extinction of UV radiation in Arctic snow at Alert, Canada (82° N), J. Geophys. Res.-Atmos., 106, 12499–12507, https://doi.org/10.1029/2001JD900006, 2001.
Kroon, M., Veefkind, J. P., Sneep, M., McPeters, R. D., Bhartia, P. K., and Levelt, P. F.: Comparing OMI-TOMS and OMI-DOAS total ozone column data, J. Geophys. Res.-Atmos., 113, D16S28, https://doi.org/10.1029/2007JD008798, 2008.
Kramarova, N. A., Nash, E. R., Newman, P. A., Bhartia, P. K., McPeters, R. D., Rault, D. F., Seftor, C. J., Xu, P. Q., and Labow, G. J.: Measuring the Antarctic ozone hole with the new Ozone Mapping and Profiler Suite (OMPS), Atmos. Chem. Phys., 14, 2353–2361, https://doi.org/10.5194/acp-14-2353-2014, 2014.
Lee-Taylor, J. and Madronich, S.: Calculation of actinic fluxes with a coupled atmosphere–snow radiative transfer model, J. Geophys. Res., 107, 4796, https://doi.org/10.1029/2002JD002084, 2002.
Libois, Q., Picard, G., France, J. L., Arnaud, L., Dumont, M., Carmagnola, C. M., and King, M. D.: Influence of grain shape on light penetration in snow, The Cryosphere, 7, 1803–1818, https://doi.org/10.5194/tc-7-1803-2013, 2013.
Libois, Q., Picard, G., Dumont, M., Arnaud, L., Sergent, C., Pougatch, E., Sudul, M., and Vial, D.: Experimental determination of the absorption enhancement parameter of snow, J. Glaciol., 60, 714–724, 2014.
Malinka, A. V.: Light scattering in porous materials: Geometrical optics and stereological approach, J. Quant. Spectrosc. Radiat. Transfer, 141, 14–23, https://doi.org/http://dx.doi.org/10.1016/j.jqsrt.2014.02.022, 2014.
Marks, A. A. and King, M. D.: The effect of snow/sea ice type on the response of albedo and light penetration depth (e-folding depth) to increasing black carbon, The Cryosphere, 8, 1625–1638, https://doi.org/10.5194/tc-8-1625-2014, 2014.
Mauldin, R. L., Eisele, F. L., Tanner, D. J., Kosciuch, E., Shetter, R., Lefer, B., Hall, S. R., Nowak, J. B., Buhr, M., Chen, G., Wang, P., and Davis, D.: Measurements of OH, H2SO4, and MSA at the South Pole during ISCAT, Geophys. Res. Lett., 28, 3629–3632, https://doi.org/10.1029/2000GL012711, 2001.
McNeill, V. F., Grannas, A. M., Abbatt, J. P. D., Ammann, M., Ariya, P., Bartels-Rausch, T., Domine, F., Donaldson, D. J., Guzman, M. I., Heger, D., Kahan, T. F., Klán, P., Masclin, S., Toubin, C., and Voisin, D.: Organics in environmental ices: sources, chemistry, and impacts, Atmos. Chem. Phys., 12, 9653–9678, https://doi.org/10.5194/acp-12-9653-2012, 2012.
Simpson, W. R., King, M. D., Beine, H. J., Honrath, R. E., and Zhou, X.: Radiation-transfer modeling of snow-pack photochemical processes during ALERT 2000, Atmos. Environ., 36, 2663–2670, https://doi.org/10.1016/S1352-2310(02)00124-3, 2002.
Sjostedt, S. J., Huey, L. G., Tanner, D. J., Peischl, J., Chen, G., Dibb, J. E., Lefer, B., Hutterli, M. A., Beyersdorf, A. J., Blake, N. J., and Blake, D. R.: Peroxy and hydroxyl radical measurements during the spring 2004 Summit Field Campaign, American Geophysical Union, Fall Meeting 2005, abstract #A24A-02, 2005AGUFM.A24A..02S, 5–9 December 2005, San Francisco, CA, USA, 2005.
Thomas, J. L., Stutz, J., Lefer, B., Huey, L. G., Toyota, K., Dibb, J. E., and von Glasow, R.: Modeling chemistry in and above snow at Summit, Greenland – Part 1: Model description and results, Atmos. Chem. Phys., 11, 4899–4914, https://doi.org/10.5194/acp-11-4899-2011, 2011.
Voisin, D., Jaffrezo, J.-L., Houdier, S., Barret, M., Cozic, J., King, M. D., France, J. L., Reay, H. J., Grannas, A., Kos, G., Ariya, P. A., Beine, H. J., and Domine, F.: Carbonaceous species and humic like substances (HULIS) in Arctic snowpack during OASIS field campaign in Barrow, J. Geophys. Res.-Atmos., 117, D00R19, https://doi.org/10.1029/2011JD016612, 2012.
Warneck, P. and Wurzinger, C.: Product quantum yields for the 305-nm photodecomposition of nitrate in aqueous solution, J. Phys. Chem., 92, 6278–6283, https://doi.org/10.1021/j100333a022, 1988.
Warren, S. G.: Optical properties of snow, Rev. Geophys., 20, 67–89, https://doi.org/10.1029/RG020i001p00067, 1982.
Warren, S. G. and Brandt, R. E.: Optical constants of ice from the ultraviolet to the microwave: a revised compilation, J. Geophys. Res.-Atmos., 113, D14220, https://doi.org/10.1029/2007JD009744, 2008.
Warren, S. G. and Wiscombe, W. J.: A model for the spectral albedo of snow. II: Snow containing atmospheric aerosols, J. Atmos. Sci., 37, 2734–2745, https://doi.org/10.1175/1520-0469(1980), 1980.
Warren, S. G., Brandt, R. E., and Grenfell, T. C.: Visible and near-ultraviolet absorption spectrum of ice from transmission of solar radiation into snow, Appl. Optics, 45, 5320–5334, https://doi.org/10.1364/AO.45.005320, 2006.
Wiscombe, W. J. and Warren, S. G.: A model for the spectral albedo of snow. I: Pure snow, J. Atmos. Sci., 37, 2712–2733, https://doi.org/10.1175/1520-0469(1980)037<2712:AMFTSA>2.0.CO;2, 1980.
Wolff, E. W. and Bales, R. C.: Chemical Exchange Between the Atmosphere and Polar Snow, NATO ASI Series, 43, Springer, Berlin, Heidelberg, Germany, 1996.
Zatko, M. C., Grenfell, T. C., Alexander, B., Doherty, S. J., Thomas, J. L., and Yang, X.: The influence of snow grain size and impurities on the vertical profiles of actinic flux and associated NOx emissions on the Antarctic and Greenland ice sheets, Atmos. Chem. Phys., 13, 3547–3567, https://doi.org/10.5194/acp-13-3547-2013, 2013.
Zege, E. P., Katsev, I. L., Malinka, A. V., Prikhach, A. S., Heygster, G., and Wiebe, H.: Algorithm for retrieval of the effective snow grain size and pollution amount from satellite measurements, Remote Sens. Environ., 115, 2674–2685, https://doi.org/10.1016/j.rse.2011.06.001, 2011.
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