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Volume 14, issue 18
Atmos. Chem. Phys., 14, 9963–9976, 2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.

Special issue: Oxidant Production over Antarctic Land and its Export...

Atmos. Chem. Phys., 14, 9963–9976, 2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 19 Sep 2014

Research article | 19 Sep 2014

Large mixing ratios of atmospheric nitrous acid (HONO) at Concordia (East Antarctic Plateau) in summer: a strong source from surface snow?

M. Legrand1,2, S. Preunkert1,2, M. Frey3, Th. Bartels-Rausch4, A. Kukui5,6, M. D. King7, J. Savarino1,2, M. Kerbrat1,2, and B. Jourdain1,2 M. Legrand et al.
  • 1CNRS, Laboratoire de Glaciologie et Géophysique d'Environnement (LGGE), 38041 Grenoble, France
  • 2Univ. Grenoble Alpes, LGGE, 38041 Grenoble, France
  • 3British Antarctic Survey (BAS), Natural Environment Research Council, Cambridge, UK
  • 4Laboratory of Radio and Environmental Chemistry, Paul Scherrer Institute (PSI), 5232 Villigen, Switzerland
  • 5Laboratoire des Atmosphères, Milieux, Observations Spatiales (LATMOS), Paris, France
  • 6Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E) UMR-CNRS, Orléans, France
  • 7Department of Earth Sciences, Royal Holloway University of London, Egham, Surrey, TW20 0EX, UK

Abstract. During the austral summer 2011/2012 atmospheric nitrous acid (HONO) was investigated for the second time at the Concordia site (75°06' S, 123°33' E), located on the East Antarctic Plateau, by deploying a long-path absorption photometer (LOPAP). Hourly mixing ratios of HONO measured in December 2011/January 2012 (35 ± 5.0 pptv) were similar to those measured in December 2010/January 2011 (30.4 ± 3.5 pptv). The large value of the HONO mixing ratio at the remote Concordia site suggests a local source of HONO in addition to weak production from oxidation of NO by the OH radical. Laboratory experiments demonstrate that surface snow removed from Concordia can produce gas-phase HONO at mixing ratios half that of the NOx mixing ratio produced in the same experiment at typical temperatures encountered at Concordia in summer. Using these lab data and the emission flux of NOx from snow estimated from the vertical gradient of atmospheric concentrations measured during the campaign, a mean diurnal HONO snow emission ranging between 0.5 and 0.8 × 109 molecules cm−2 s−1 is calculated. Model calculations indicate that, in addition to around 1.2 pptv of HONO produced by the NO oxidation, these HONO snow emissions can only explain 6.5 to 10.5 pptv of HONO in the atmosphere at Concordia. To explain the difference between observed and simulated HONO mixing ratios, tests were done both in the field and at lab to explore the possibility that the presence of HNO4 had biased the measurements of HONO.

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