Articles | Volume 20, issue 16
https://doi.org/10.5194/acp-20-10015-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-10015-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| Highlight paper
| 
27 Aug 2020
Research article | Highlight paper |
| 27 Aug 2020
| 27 Aug 2020
A semi-empirical potential energy surface and line list for H216O extending into the near-ultraviolet
Eamon K. Conway
CORRESPONDING AUTHOR
Center for Astrophysics, Harvard and Smithsonian, Atomic and Molecular Physics Division, Cambridge, MA 02138, USA
Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK
Iouli E. Gordon
Center for Astrophysics, Harvard and Smithsonian, Atomic and Molecular Physics Division, Cambridge, MA 02138, USA
Jonathan Tennyson
Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK
Oleg L. Polyansky
Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK
Sergei N. Yurchenko
Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK
Kelly Chance
Center for Astrophysics, Harvard and Smithsonian, Atomic and Molecular Physics Division, Cambridge, MA 02138, USA
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Juseon Bak, Kang-Hyeon Baek, Jae-Hwan Kim, Xiong Liu, Jhoon Kim, and Kelly Chance
Atmos. Meas. Tech., 12, 5201–5215, https://doi.org/10.5194/amt-12-5201-2019, https://doi.org/10.5194/amt-12-5201-2019, 2019
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Huiqun Wang, Amir Hossein Souri, Gonzalo González Abad, Xiong Liu, and Kelly Chance
Atmos. Meas. Tech., 12, 5183–5199, https://doi.org/10.5194/amt-12-5183-2019, https://doi.org/10.5194/amt-12-5183-2019, 2019
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Total column water vapor (TCWV) is retrieved from the spectra obtained by the Ozone Monitoring Instrument (OMI). Data filtering criteria are recommended. The OMI data generally compare well with reference datasets over both land and the oceans. The data are useful for a variety of applications spanning a range of spatial and temporal scales, such as atmospheric rivers, corn sweat and El Niño.
Juseon Bak, Xiong Liu, Kang Sun, Kelly Chance, and Jae-Hwan Kim
Atmos. Meas. Tech., 12, 3777–3788, https://doi.org/10.5194/amt-12-3777-2019, https://doi.org/10.5194/amt-12-3777-2019, 2019
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Hyeong-Ahn Kwon, Rokjin J. Park, Gonzalo González Abad, Kelly Chance, Thomas P. Kurosu, Jhoon Kim, Isabelle De Smedt, Michel Van Roozendael, Enno Peters, and John Burrows
Atmos. Meas. Tech., 12, 3551–3571, https://doi.org/10.5194/amt-12-3551-2019, https://doi.org/10.5194/amt-12-3551-2019, 2019
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Jin Liao, Thomas F. Hanisco, Glenn M. Wolfe, Jason St. Clair, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Alan Fried, Eloise A. Marais, Gonzalo Gonzalez Abad, Kelly Chance, Hiren T. Jethva, Thomas B. Ryerson, Carsten Warneke, and Armin Wisthaler
Atmos. Chem. Phys., 19, 2765–2785, https://doi.org/10.5194/acp-19-2765-2019, https://doi.org/10.5194/acp-19-2765-2019, 2019
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Kang Sun, Lei Zhu, Karen Cady-Pereira, Christopher Chan Miller, Kelly Chance, Lieven Clarisse, Pierre-François Coheur, Gonzalo González Abad, Guanyu Huang, Xiong Liu, Martin Van Damme, Kai Yang, and Mark Zondlo
Atmos. Meas. Tech., 11, 6679–6701, https://doi.org/10.5194/amt-11-6679-2018, https://doi.org/10.5194/amt-11-6679-2018, 2018
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Caroline R. Nowlan, Xiong Liu, Scott J. Janz, Matthew G. Kowalewski, Kelly Chance, Melanie B. Follette-Cook, Alan Fried, Gonzalo González Abad, Jay R. Herman, Laura M. Judd, Hyeong-Ahn Kwon, Christopher P. Loughner, Kenneth E. Pickering, Dirk Richter, Elena Spinei, James Walega, Petter Weibring, and Andrew J. Weinheimer
Atmos. Meas. Tech., 11, 5941–5964, https://doi.org/10.5194/amt-11-5941-2018, https://doi.org/10.5194/amt-11-5941-2018, 2018
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Hansen Cao, Tzung-May Fu, Lin Zhang, Daven K. Henze, Christopher Chan Miller, Christophe Lerot, Gonzalo González Abad, Isabelle De Smedt, Qiang Zhang, Michel van Roozendael, François Hendrick, Kelly Chance, Jie Li, Junyu Zheng, and Yuanhong Zhao
Atmos. Chem. Phys., 18, 15017–15046, https://doi.org/10.5194/acp-18-15017-2018, https://doi.org/10.5194/acp-18-15017-2018, 2018
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Our top-down estimates for annual total Chinese NMVOC emissions was 30.7 to 49.5 Tg y−1, including 16.4 to 23.6 Tg y−1 from anthropogenic sources, 12.2 to 22.8 Tg y−1 from biogenic sources, and 2.08 to 3.13 Tg y−1 from biomass burning. Our four inversions consistently showed that the emissions of Chinese anthropogenic NMVOC precursors of glyoxal were larger than the a priori estimates. The glyoxal and formaldehyde constraints helped distinguish the NMVOC species from different sources.
Pieternel F. Levelt, Joanna Joiner, Johanna Tamminen, J. Pepijn Veefkind, Pawan K. Bhartia, Deborah C. Stein Zweers, Bryan N. Duncan, David G. Streets, Henk Eskes, Ronald van der A, Chris McLinden, Vitali Fioletov, Simon Carn, Jos de Laat, Matthew DeLand, Sergey Marchenko, Richard McPeters, Jerald Ziemke, Dejian Fu, Xiong Liu, Kenneth Pickering, Arnoud Apituley, Gonzalo González Abad, Antti Arola, Folkert Boersma, Christopher Chan Miller, Kelly Chance, Martin de Graaf, Janne Hakkarainen, Seppo Hassinen, Iolanda Ialongo, Quintus Kleipool, Nickolay Krotkov, Can Li, Lok Lamsal, Paul Newman, Caroline Nowlan, Raid Suleiman, Lieuwe Gijsbert Tilstra, Omar Torres, Huiqun Wang, and Krzysztof Wargan
Atmos. Chem. Phys., 18, 5699–5745, https://doi.org/10.5194/acp-18-5699-2018, https://doi.org/10.5194/acp-18-5699-2018, 2018
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The aim of this paper is to highlight the many successes of the Ozone Monitoring Instrument (OMI) spanning more than 13 years. Data from OMI have been used in a wide range of applications. Due to its unprecedented spatial resolution, in combination with daily global coverage, OMI plays a unique role in measuring trace gases important for the ozone layer, air quality, and climate change. OMI data continue to be used for new research and applications.
Guanyu Huang, Xiong Liu, Kelly Chance, Kai Yang, and Zhaonan Cai
Atmos. Meas. Tech., 11, 17–32, https://doi.org/10.5194/amt-11-17-2018, https://doi.org/10.5194/amt-11-17-2018, 2018
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In this paper, we focus on the validation of OMI ozone (PROFOZ) product in the stratosphere using MLS ozone observations. This paper, with its companion paper focusing on the validation in the troposphere by using global ozonesonde observations, provides us with a comprehensive understanding of the data quality of OMI PROFOZ product and impacts of the “row anomaly”.
Juseon Bak, Xiong Liu, Jae-Hwan Kim, David P. Haffner, Kelly Chance, Kai Yang, and Kang Sun
Atmos. Meas. Tech., 10, 4373–4388, https://doi.org/10.5194/amt-10-4373-2017, https://doi.org/10.5194/amt-10-4373-2017, 2017
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This paper verifies and corrects the Ozone Mapping and Profiler Suite (OMPS) nadir mapper (NM) level 1B v2.0 measurements to retrieve reliable ozone profile and tropospheric ozone using an optimal estimation inversion with the fitting window of 302.5–340 nm. We apply "soft calibration" and "common mode correction" to OMPS radiances to eliminate systematic errors in the fitting residuals and derive random-noise measurement errors accounting for both OMPS radiances and forward model calculation.
Yang Wang, Steffen Beirle, Francois Hendrick, Andreas Hilboll, Junli Jin, Aleksandra A. Kyuberis, Johannes Lampel, Ang Li, Yuhan Luo, Lorenzo Lodi, Jianzhong Ma, Monica Navarro, Ivan Ortega, Enno Peters, Oleg L. Polyansky, Julia Remmers, Andreas Richter, Olga Puentedura, Michel Van Roozendael, André Seyler, Jonathan Tennyson, Rainer Volkamer, Pinhua Xie, Nikolai F. Zobov, and Thomas Wagner
Atmos. Meas. Tech., 10, 3719–3742, https://doi.org/10.5194/amt-10-3719-2017, https://doi.org/10.5194/amt-10-3719-2017, 2017
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Slant column densities of nitrous acid (HONO) derived from different MAX-DOAS instruments and retrieval software are systematically compared for the first time during the Multi Axis DOAS – Comparison campaign for Aerosols and Trace gases (MAD-CAT) campaign held at MPIC in Mainz, Germany, from June to October 2013. Through the inter-comparisons and sensitivity studies we quantified the uncertainties in the DOAS fits of HONO from different sources and concluded a recommended setting.
Kang Sun, Xiong Liu, Guanyu Huang, Gonzalo González Abad, Zhaonan Cai, Kelly Chance, and Kai Yang
Atmos. Meas. Tech., 10, 3677–3695, https://doi.org/10.5194/amt-10-3677-2017, https://doi.org/10.5194/amt-10-3677-2017, 2017
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This study derives on-orbit slit functions from the OMI irradiance spectra. The results differ from the widely used preflight slit functions. The on-orbit changes of OMI slit functions are insignificant over time after accounting for the solar activity. Applying the derived on-orbit slit functions to ozone-profile retrieval shows substantial improvements over the preflight slit functions based on comparisons with ozonesonde validations.
Christopher Chan Miller, Daniel J. Jacob, Eloise A. Marais, Karen Yu, Katherine R. Travis, Patrick S. Kim, Jenny A. Fisher, Lei Zhu, Glenn M. Wolfe, Thomas F. Hanisco, Frank N. Keutsch, Jennifer Kaiser, Kyung-Eun Min, Steven S. Brown, Rebecca A. Washenfelder, Gonzalo González Abad, and Kelly Chance
Atmos. Chem. Phys., 17, 8725–8738, https://doi.org/10.5194/acp-17-8725-2017, https://doi.org/10.5194/acp-17-8725-2017, 2017
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The use of satellite glyoxal observations for estimating isoprene emissions has been limited by knowledge of the glyoxal yield from isoprene. We use SENEX aircraft observations over the southeast US to evaluate glyoxal yields from isoprene in a 3-D atmospheric model. The SENEX observations support a pathway for glyoxal formation in pristine regions that we propose here, which may have implications for improving isoprene emissions estimates from upcoming high-resolution geostationary satellites.
Guanyu Huang, Xiong Liu, Kelly Chance, Kai Yang, Pawan K. Bhartia, Zhaonan Cai, Marc Allaart, Gérard Ancellet, Bertrand Calpini, Gerrie J. R. Coetzee, Emilio Cuevas-Agulló, Manuel Cupeiro, Hugo De Backer, Manvendra K. Dubey, Henry E. Fuelberg, Masatomo Fujiwara, Sophie Godin-Beekmann, Tristan J. Hall, Bryan Johnson, Everette Joseph, Rigel Kivi, Bogumil Kois, Ninong Komala, Gert König-Langlo, Giovanni Laneve, Thierry Leblanc, Marion Marchand, Kenneth R. Minschwaner, Gary Morris, Michael J. Newchurch, Shin-Ya Ogino, Nozomu Ohkawara, Ankie J. M. Piters, Françoise Posny, Richard Querel, Rinus Scheele, Frank J. Schmidlin, Russell C. Schnell, Otto Schrems, Henry Selkirk, Masato Shiotani, Pavla Skrivánková, René Stübi, Ghassan Taha, David W. Tarasick, Anne M. Thompson, Valérie Thouret, Matthew B. Tully, Roeland Van Malderen, Holger Vömel, Peter von der Gathen, Jacquelyn C. Witte, and Margarita Yela
Atmos. Meas. Tech., 10, 2455–2475, https://doi.org/10.5194/amt-10-2455-2017, https://doi.org/10.5194/amt-10-2455-2017, 2017
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It is essential to understand the data quality of +10-year OMI ozone product and impacts of the “row anomaly” (RA). We validate the OMI Ozone Profile (PROFOZ) product from Oct 2004 to Dec 2014 against ozonesonde observations globally. Generally, OMI has good agreement with ozonesondes. The spatiotemporal variation of retrieval performance suggests the need to improve OMI’s radiometric calibration especially during the post-RA period to maintain the long-term stability.
Hyeong-Ahn Kwon, Rokjin J. Park, Jaein I. Jeong, Seungun Lee, Gonzalo González Abad, Thomas P. Kurosu, Paul I. Palmer, and Kelly Chance
Atmos. Chem. Phys., 17, 4673–4686, https://doi.org/10.5194/acp-17-4673-2017, https://doi.org/10.5194/acp-17-4673-2017, 2017
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A geostationary satellite can measure daytime hourly HCHO columns. Atmospheric conditions such as synoptic meteorology and the presence of other gases and aerosols may affect HCHO measurements. We examine the effects of their temporal variation on the HCHO measurement of a geostationary satellite in East Asia. We find that the hourly variation of other species could be important. Especially the inclusion of hourly aerosol variation in the retrieval could lead to improving HCHO measurements.
Kang Sun, Xiong Liu, Caroline R. Nowlan, Zhaonan Cai, Kelly Chance, Christian Frankenberg, Richard A. M. Lee, Randy Pollock, Robert Rosenberg, and David Crisp
Atmos. Meas. Tech., 10, 939–953, https://doi.org/10.5194/amt-10-939-2017, https://doi.org/10.5194/amt-10-939-2017, 2017
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Accurately characterizing the instrument line shape (ILS) of the Orbiting Carbon Observatory-2 (OCO-2) is challenging and highly important due to its high spectral resolution and requirement for retrieval accuracy. Measured ILS during preflight experiments has been used in the OCO-2 CO2 retrieval. This study derives the on-orbit ILS of OCO-2 using its solar measurements and answers the questions whether on-orbit ILS has changed compared to preflight and whether it varies during the mission.
Johannes Lampel, Denis Pöhler, Oleg L. Polyansky, Aleksandra A. Kyuberis, Nikolai F. Zobov, Jonathan Tennyson, Lorenzo Lodi, Udo Frieß, Yang Wang, Steffen Beirle, Ulrich Platt, and Thomas Wagner
Atmos. Chem. Phys., 17, 1271–1295, https://doi.org/10.5194/acp-17-1271-2017, https://doi.org/10.5194/acp-17-1271-2017, 2017
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Water vapour is known to absorb radiation from the microwave region to the blue part of the visible spectrum.
Ab initio approaches to model individual absorption lines of the gaseous water molecule predict absorption lines
until its dissociation limit at 243 nm.
We present first evidence of water vapour absorption near 363 nm from field measurements using data
from multi-axis differential optical absorption spectroscopy (MAX-DOAS) and long-path (LP)-DOAS measurements.
Daniel J. Jacob, Alexander J. Turner, Joannes D. Maasakkers, Jianxiong Sheng, Kang Sun, Xiong Liu, Kelly Chance, Ilse Aben, Jason McKeever, and Christian Frankenberg
Atmos. Chem. Phys., 16, 14371–14396, https://doi.org/10.5194/acp-16-14371-2016, https://doi.org/10.5194/acp-16-14371-2016, 2016
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Methane is a greenhouse gas emitted by a range of natural and anthropogenic sources. Atmospheric methane has been measured continuously from space since 2003, and new instruments are planned to launch in the near future that will greatly expand the capabilities of space-based observations. We review the value of current, future, and proposed satellite observations to better quantify methane emissions from the global scale down to the scale of point sources.
Lei Zhu, Daniel J. Jacob, Patrick S. Kim, Jenny A. Fisher, Karen Yu, Katherine R. Travis, Loretta J. Mickley, Robert M. Yantosca, Melissa P. Sulprizio, Isabelle De Smedt, Gonzalo González Abad, Kelly Chance, Can Li, Richard Ferrare, Alan Fried, Johnathan W. Hair, Thomas F. Hanisco, Dirk Richter, Amy Jo Scarino, James Walega, Petter Weibring, and Glenn M. Wolfe
Atmos. Chem. Phys., 16, 13477–13490, https://doi.org/10.5194/acp-16-13477-2016, https://doi.org/10.5194/acp-16-13477-2016, 2016
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HCHO column data are widely used as a proxy for VOCs emissions, but validation of the data has been extremely limited. We use accurate aircraft observations to validate and intercompare 6 HCHO retrievals with GEOS-Chem as the intercomparison platform. Retrievals are interconsistent in spatial variability over the SE US and in daily variability, but are biased low by 20–51 %. Our work supports the use of HCHO column as a quantitative proxy for isoprene emission after correction of the low bias.
Huiqun Wang, Gonzalo Gonzalez Abad, Xiong Liu, and Kelly Chance
Atmos. Chem. Phys., 16, 11379–11393, https://doi.org/10.5194/acp-16-11379-2016, https://doi.org/10.5194/acp-16-11379-2016, 2016
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Water vapor is highly important. The OMI total column water vapor product retrieved using SAO's version 1.0 algorithm agrees well with other reference products over the land but has a low bias over the ocean. The updated OMI water vapor product retrieved using SAO's version 2.1 algorithm largely eliminates the low bias over the ocean, improving the land/ocean consistency and the overall data quality. This dataset can benefit a variety of scientific studies and practical applications.
Juseon Bak, Xiong Liu, Jae H. Kim, Matthew T. Deland, and Kelly Chance
Atmos. Meas. Tech., 9, 4521–4531, https://doi.org/10.5194/amt-9-4521-2016, https://doi.org/10.5194/amt-9-4521-2016, 2016
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The main focus of this paper is improving an error of OMI nadir ozone profile retrievals due to the presence of polar mesospheric clouds (PMCs), consisting of small light-scattering particles at an altitude of 80–85 km. This error is shown to be systematic bias from ~ −2 at 2 hPa to ~ −20 % at 0.5 hPa and significantly correlated with brightness of PMCs. We reduce this interference of PMCs on ozone retrievals by including the PMC optical depth in the forward-model calculation and retrieval.
Gonzalo González Abad, Alexander Vasilkov, Colin Seftor, Xiong Liu, and Kelly Chance
Atmos. Meas. Tech., 9, 2797–2812, https://doi.org/10.5194/amt-9-2797-2016, https://doi.org/10.5194/amt-9-2797-2016, 2016
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The multi-spectral possibilities of the OMPS Nadir Mapper instrument are exploited here to perform formaldehyde retrievals. Orbiting the Earth at 824 km, OMPS observes the atmosphere in a time frame similar to instruments belonging to NASA's A-Train constellation, 01:30. We show that OMPS is well suited to measure formaldehyde despite its spectral resolution of 1nm. The comparison of OMPS retrievals with OMI products show good temporal correlation.
Caroline R. Nowlan, Xiong Liu, James W. Leitch, Kelly Chance, Gonzalo González Abad, Cheng Liu, Peter Zoogman, Joshua Cole, Thomas Delker, William Good, Frank Murcray, Lyle Ruppert, Daniel Soo, Melanie B. Follette-Cook, Scott J. Janz, Matthew G. Kowalewski, Christopher P. Loughner, Kenneth E. Pickering, Jay R. Herman, Melinda R. Beaver, Russell W. Long, James J. Szykman, Laura M. Judd, Paul Kelley, Winston T. Luke, Xinrong Ren, and Jassim A. Al-Saadi
Atmos. Meas. Tech., 9, 2647–2668, https://doi.org/10.5194/amt-9-2647-2016, https://doi.org/10.5194/amt-9-2647-2016, 2016
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The Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) instrument is a remote sensing airborne instrument developed in support of future air quality satellite missions that will operate from geostationary orbit. GeoTASO flew in its first intensive field campaign during the DISCOVER-AQ 2013 Earth Venture Mission over Houston, Texas. This paper introduces the instrument and data analysis, and presents GeoTASO's first observations of NO2 at 250 m x 250 m spatial resolution.
Christopher Chan Miller, Daniel J. Jacob, Gonzalo González Abad, and Kelly Chance
Atmos. Chem. Phys., 16, 4631–4639, https://doi.org/10.5194/acp-16-4631-2016, https://doi.org/10.5194/acp-16-4631-2016, 2016
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Volatile organic compounds (VOCs) are important precursors for photochemical smog.
Glyoxal is an organic compound produced in the atmosphere from reactions of larger VOCs. OMI satellite observations of glyoxal show a large hotspot over the Pearl River delta. The hotspot can be explained by industrial paint and solvent emissions of aromatic VOCs. Our work shows OMI observations are consistent with current VOC emissions estimates, whereas previous work has suggested large underestimates.
U. Jeong, J. Kim, C. Ahn, O. Torres, X. Liu, P. K. Bhartia, R. J. D. Spurr, D. Haffner, K. Chance, and B. N. Holben
Atmos. Chem. Phys., 16, 177–193, https://doi.org/10.5194/acp-16-177-2016, https://doi.org/10.5194/acp-16-177-2016, 2016
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An aerosol retrieval and error analysis algorithm using OMI measurements based on an optimal-estimation method was developed in this study. The aerosol retrievals were validated using the DRAGON campaign products. The estimated errors of the retrievals represented the actual biases between retrieval and AERONET measurements well. The retrievals, with their estimated uncertainties, are expected to be valuable for relevant studies, such as trace gas retrieval and data assimilation.
J. Bak, X. Liu, J. H. Kim, M. T. Deland, and K. Chance
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-25907-2015, https://doi.org/10.5194/acpd-15-25907-2015, 2015
Revised manuscript not accepted
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This work demonstrated the interference of tenuous PMCs on OMI ozone profile retrievals above 6hPa. The presence of PMCs leads to the systematic biases of -2% at 2hPa and -20% at 0.5hPa in OMI retrievals, which are significantly correlated with brightness of PMCs. We perform simultaneous retrievals of PMC optical depth with ozone using optimal estimation technique, to reduce the interference on ozone profile retrievals. As a result, the negative OMI biases are reduced to within ±10%.
S. Hayashida, X. Liu, A. Ono, K. Yang, and K. Chance
Atmos. Chem. Phys., 15, 9865–9881, https://doi.org/10.5194/acp-15-9865-2015, https://doi.org/10.5194/acp-15-9865-2015, 2015
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The lower tropospheric ozone distribution maps were first obtained from the recent retrieval products of the Ozone Monitoring Instrument (OMI) onboard the Earth Observing System (EOS) Aura satellite. We found significant enhancement of ozone in the lower troposphere over central and eastern China (CEC), with Shandong Province as its center, and most notable in June in any given year. Similar seasonal variations were observed throughout the 9-year OMI measurement period of 2005 to 2013.
R. V. Kochanov, I. E. Gordon, L. S. Rothman, S. W. Sharpe, T. J. Johnson, and R. L. Sams
Clim. Past, 11, 1097–1105, https://doi.org/10.5194/cp-11-1097-2015, https://doi.org/10.5194/cp-11-1097-2015, 2015
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In the article Clim Past 10, 1779 (2014), the HITRAN2012 database was employed to evaluate the radiative forcing of 28 Archean gases. The authors claimed that for NO2, H2O2, C2H4, CH3OH, and CH3Br there are severe disagreements between cross sections generated from the HITRAN line-by-line data and those of the PNNL experimental database. In this work we show that the differences are not nearly at the scale suggested by the authors, and their conclusions about these gases and HO2 are not correct.
C. Liu, X. Liu, M. G. Kowalewski, S. J. Janz, G. González Abad, K. E. Pickering, K. Chance, and L. N. Lamsal
Atmos. Meas. Tech., 8, 751–759, https://doi.org/10.5194/amt-8-751-2015, https://doi.org/10.5194/amt-8-751-2015, 2015
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We characterize the wavelengths and slit functions of Airborne Compact Atmospheric Mapper (ACAM) measurements in ~304--500 nm through the cross-correlation technique. It is necessary to account for atmospheric gas absorption and the ring effect. The derived broadened Gaussian slit functions agree very well with laboratory measurements. Trace gas retrieval comparisons demonstrate that the cross-correlation technique can be reliably used to characterize slit functions.
J. Bak, X. Liu, J. H. Kim, K. Chance, and D. P. Haffner
Atmos. Chem. Phys., 15, 667–683, https://doi.org/10.5194/acp-15-667-2015, https://doi.org/10.5194/acp-15-667-2015, 2015
G. González Abad, X. Liu, K. Chance, H. Wang, T. P. Kurosu, and R. Suleiman
Atmos. Meas. Tech., 8, 19–32, https://doi.org/10.5194/amt-8-19-2015, https://doi.org/10.5194/amt-8-19-2015, 2015
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We present and discuss the Smithsonian Astrophysical Observatory (SAO) formaldehyde retrieval algorithm for the Ozone Monitoring Instrument (OMI), which is the operational retrieval for NASA OMI H2CO.
C. Chan Miller, G. Gonzalez Abad, H. Wang, X. Liu, T. Kurosu, D. J. Jacob, and K. Chance
Atmos. Meas. Tech., 7, 3891–3907, https://doi.org/10.5194/amt-7-3891-2014, https://doi.org/10.5194/amt-7-3891-2014, 2014
E. A. Marais, D. J. Jacob, A. Guenther, K. Chance, T. P. Kurosu, J. G. Murphy, C. E. Reeves, and H. O. T. Pye
Atmos. Chem. Phys., 14, 7693–7703, https://doi.org/10.5194/acp-14-7693-2014, https://doi.org/10.5194/acp-14-7693-2014, 2014
E. Hache, J.-L. Attié, C. Tourneur, P. Ricaud, L. Coret, W. A. Lahoz, L. El Amraoui, B. Josse, P. Hamer, J. Warner, X. Liu, K. Chance, M. Höpfner, R. Spurr, V. Natraj, S. Kulawik, A. Eldering, and J. Orphal
Atmos. Meas. Tech., 7, 2185–2201, https://doi.org/10.5194/amt-7-2185-2014, https://doi.org/10.5194/amt-7-2185-2014, 2014
C. E. Sioris, C. D. Boone, R. Nassar, K. J. Sutton, I. E. Gordon, K. A. Walker, and P. F. Bernath
Atmos. Meas. Tech., 7, 2243–2262, https://doi.org/10.5194/amt-7-2243-2014, https://doi.org/10.5194/amt-7-2243-2014, 2014
H. Wang, X. Liu, K. Chance, G. González Abad, and C. Chan Miller
Atmos. Meas. Tech., 7, 1901–1913, https://doi.org/10.5194/amt-7-1901-2014, https://doi.org/10.5194/amt-7-1901-2014, 2014
P. Zoogman, D. J. Jacob, K. Chance, X. Liu, M. Lin, A. Fiore, and K. Travis
Atmos. Chem. Phys., 14, 6261–6271, https://doi.org/10.5194/acp-14-6261-2014, https://doi.org/10.5194/acp-14-6261-2014, 2014
J. P. Parrella, K. Chance, R. J. Salawitch, T. Canty, M. Dorf, and K. Pfeilsticker
Atmos. Meas. Tech., 6, 2549–2561, https://doi.org/10.5194/amt-6-2549-2013, https://doi.org/10.5194/amt-6-2549-2013, 2013
J. Cuesta, M. Eremenko, X. Liu, G. Dufour, Z. Cai, M. Höpfner, T. von Clarmann, P. Sellitto, G. Foret, B. Gaubert, M. Beekmann, J. Orphal, K. Chance, R. Spurr, and J.-M. Flaud
Atmos. Chem. Phys., 13, 9675–9693, https://doi.org/10.5194/acp-13-9675-2013, https://doi.org/10.5194/acp-13-9675-2013, 2013
P. S. Kim, D. J. Jacob, X. Liu, J. X. Warner, K. Yang, K. Chance, V. Thouret, and P. Nedelec
Atmos. Chem. Phys., 13, 9321–9335, https://doi.org/10.5194/acp-13-9321-2013, https://doi.org/10.5194/acp-13-9321-2013, 2013
J. Bak, X. Liu, J. C. Wei, L. L. Pan, K. Chance, and J. H. Kim
Atmos. Meas. Tech., 6, 2239–2254, https://doi.org/10.5194/amt-6-2239-2013, https://doi.org/10.5194/amt-6-2239-2013, 2013
J. Bak, J. H. Kim, X. Liu, K. Chance, and J. Kim
Atmos. Meas. Tech., 6, 239–249, https://doi.org/10.5194/amt-6-239-2013, https://doi.org/10.5194/amt-6-239-2013, 2013
Related subject area
Subject: Radiation | Research Activity: Remote Sensing | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Understanding the trends in reflected solar radiation: a latitude- and month-based perspective
Evaluating the representation of Arctic cirrus solar radiative effects in the Integrated Forecasting System with airborne measurements
Uncertainty in simulated brightness temperature due to sensitivity to atmospheric gas spectroscopic parameters from the centimeter- to submillimeter-wave range
Direct observational evidence from space of the effect of CO2 increase on longwave spectral radiances: the unique role of high-spectral-resolution measurements
LIME: Lunar Irradiance Model of ESA, a new tool for absolute radiometric calibration using the Moon
Influence of cloud retrieval errors due to three-dimensional radiative effects on calculations of broadband shortwave cloud radiative effect
Estimation of 1 km downwelling shortwave radiation over the Tibetan Plateau under all-sky conditions
Record-breaking statistics detect islands of cooling in a sea of warming
Radiative closure and cloud effects on the radiation budget based on satellite and shipborne observations during the Arctic summer research cruise, PS106
Impacts of active satellite sensors' low-level cloud detection limitations on cloud radiative forcing in the Arctic
Longwave radiative effect of the cloud–aerosol transition zone based on CERES observations
Ice and mixed-phase cloud statistics on the Antarctic Plateau
Photovoltaic power potential in West Africa using long-term satellite data
Global distribution and 14-year changes in erythemal irradiance, UV atmospheric transmission, and total column ozone for2005–2018 estimated from OMI and EPIC observations
Biomass-burning-induced surface darkening and its impact on regional meteorology in eastern China
Air pollution slows down surface warming over the Tibetan Plateau
Estimation of hourly land surface heat fluxes over the Tibetan Plateau by the combined use of geostationary and polar-orbiting satellites
Estimations of global shortwave direct aerosol radiative effects above opaque water clouds using a combination of A-Train satellite sensors
Uncertainty of atmospheric microwave absorption model: impact on ground-based radiometer simulations and retrievals
Simulated and observed horizontal inhomogeneities of optical thickness of Arctic stratus
Net radiative effects of dust in the tropical North Atlantic based on integrated satellite observations and in situ measurements
Comparison of global observations and trends of total precipitable water derived from microwave radiometers and COSMIC radio occultation from 2006 to 2013
Characterizing energy budget variability at a Sahelian site: a test of NWP model behaviour
Scale dependence of cirrus horizontal heterogeneity effects on TOA measurements – Part I: MODIS brightness temperatures in the thermal infrared
Aerosol scattering effects on water vapor retrievals over the Los Angeles Basin
Directional, horizontal inhomogeneities of cloud optical thickness fields retrieved from ground-based and airbornespectral imaging
Airborne observations of far-infrared upwelling radiance in the Arctic
Retrieval of aerosol optical depth from surface solar radiation measurements using machine learning algorithms, non-linear regression and a radiative transfer-based look-up table
Microwave signatures of ice hydrometeors from ground-based observations above Summit, Greenland
Shortwave direct radiative effects of above-cloud aerosols over global oceans derived from 8 years of CALIOP and MODIS observations
Retrieving high-resolution surface solar radiation with cloud parameters derived by combining MODIS and MTSAT data
Instantaneous longwave radiative impact of ozone: an application on IASI/MetOp observations
A method to retrieve super-thin cloud optical depth over ocean background with polarized sunlight
Airborne observations and simulations of three-dimensional radiative interactions between Arctic boundary layer clouds and ice floes
Deriving polarization properties of desert-reflected solar spectra with PARASOL data
Using IASI to simulate the total spectrum of outgoing long-wave radiances
Investigation of the "elevated heat pump" hypothesis of the Asian monsoon using satellite observations
Improved retrieval of direct and diffuse downwelling surface shortwave flux in cloudless atmosphere using dynamic estimates of aerosol content and type: application to the LSA-SAF project
Surface-sensible and latent heat fluxes over the Tibetan Plateau from ground measurements, reanalysis, and satellite data
Influence of local surface albedo variability and ice crystal shape on passive remote sensing of thin cirrus
Combining MODIS, AVHRR and in situ data for evapotranspiration estimation over heterogeneous landscape of the Tibetan Plateau
Modeling polarized solar radiation from the ocean–atmosphere system for CLARREO inter-calibration applications
HIRS channel 12 brightness temperature dataset and its correlations with major climate indices
Performance of the Line-By-Line Radiative Transfer Model (LBLRTM) for temperature, water vapor, and trace gas retrievals: recent updates evaluated with IASI case studies
Multi-satellite aerosol observations in the vicinity of clouds
CLARA-SAL: a global 28 yr timeseries of Earth's black-sky surface albedo
Quantitative comparison of the variability in observed and simulated shortwave reflectance
Regional radiative impact of volcanic aerosol from the 2009 eruption of Mt. Redoubt
Airborne hyperspectral observations of surface and cloud directional reflectivity using a commercial digital camera
Direct and semi-direct radiative forcing of smoke aerosols over clouds
Ruixue Li, Bida Jian, Jiming Li, Deyu Wen, Lijie Zhang, Yang Wang, and Yuan Wang
Atmos. Chem. Phys., 24, 9777–9803, https://doi.org/10.5194/acp-24-9777-2024, https://doi.org/10.5194/acp-24-9777-2024, 2024
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Hemispheric or interannual averages of reflected solar radiation (RSR) can mask signals from seasonally active or region-specific mechanisms. We examine RSR characteristics from latitude and month perspectives, revealing decreased trends observed by CERES in both hemispheres driven by clear-sky atmospheric and cloud components at 30–50° N and cloud components at 0–50° S. AVHRR achieves symmetry criteria within uncertainty and is suitable for the long-term analysis of hemispheric RSR symmetry.
Johannes Röttenbacher, André Ehrlich, Hanno Müller, Florian Ewald, Anna E. Luebke, Benjamin Kirbus, Robin J. Hogan, and Manfred Wendisch
Atmos. Chem. Phys., 24, 8085–8104, https://doi.org/10.5194/acp-24-8085-2024, https://doi.org/10.5194/acp-24-8085-2024, 2024
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Weather prediction models simplify the physical processes related to light scattering by clouds consisting of complex ice crystals. Whether these simplifications are the cause for uncertainties in their prediction can be evaluated by comparing them with measurement data. Here we do this for Arctic ice clouds over sea ice using airborne measurements from two case studies. The model performs well for thick ice clouds but not so well for thin ones. This work can be used to improve the model.
Donatello Gallucci, Domenico Cimini, Emma Turner, Stuart Fox, Philip W. Rosenkranz, Mikhail Y. Tretyakov, Vinia Mattioli, Salvatore Larosa, and Filomena Romano
Atmos. Chem. Phys., 24, 7283–7308, https://doi.org/10.5194/acp-24-7283-2024, https://doi.org/10.5194/acp-24-7283-2024, 2024
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Nowadays, atmospheric radiative transfer models are widely used to simulate satellite and ground-based observations. A meaningful comparison between observations and simulations requires an estimate of the uncertainty associated with both. This work quantifies the uncertainty in atmospheric radiative transfer models in the microwave range, providing the uncertainty associated with simulations of new-generation satellite microwave sensors.
João Teixeira, R. Chris Wilson, and Heidar Th. Thrastarson
Atmos. Chem. Phys., 24, 6375–6383, https://doi.org/10.5194/acp-24-6375-2024, https://doi.org/10.5194/acp-24-6375-2024, 2024
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This paper presents direct evidence from space (solely based on observations) that CO2 increase leads to the theoretically expected effects on longwave spectral radiances. This is achieved by using a methodology that allows us to isolate the CO2 effects from the temperature and water vapor effects. By searching for ensembles of temperature and water vapor profiles that are similar to each other but have different values of CO2, it is possible to estimate the direct effects of CO2 on the spectra.
Carlos Toledano, Sarah Taylor, África Barreto, Stefan Adriaensen, Alberto Berjón, Agnieszka Bialek, Ramiro González, Emma Woolliams, and Marc Bouvet
Atmos. Chem. Phys., 24, 3649–3671, https://doi.org/10.5194/acp-24-3649-2024, https://doi.org/10.5194/acp-24-3649-2024, 2024
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The calibration of Earth observation sensors is key to ensuring the continuity of long-term and global climate records. Satellite sensors, calibrated prior to launch, are susceptible to degradation in space. The Moon provides a stable calibration reference; however, its illumination depends on the Sun–Earth–Moon geometry and must be modelled. A new lunar irradiance model is presented, built upon observations over 5 years at a high-altitude observatory and a rigorous calibration and validation.
Adeleke S. Ademakinwa, Zahid H. Tushar, Jianyu Zheng, Chenxi Wang, Sanjay Purushotham, Jianwu Wang, Kerry G. Meyer, Tamas Várnai, and Zhibo Zhang
Atmos. Chem. Phys., 24, 3093–3114, https://doi.org/10.5194/acp-24-3093-2024, https://doi.org/10.5194/acp-24-3093-2024, 2024
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Clouds play a critical role in our climate system. At present and in the near future, satellite-based remote sensing is the only means to obtain regional and global observations of cloud properties. The current satellite remote sensing algorithms are mostly based on the so-called 1D radiative transfer. This deviation from the 3D world reality can lead to large errors. In this study we investigate how this error affects our estimation of cloud radiative effects.
Peizhen Li, Lei Zhong, Yaoming Ma, Yunfei Fu, Meilin Cheng, Xian Wang, Yuting Qi, and Zixin Wang
Atmos. Chem. Phys., 23, 9265–9285, https://doi.org/10.5194/acp-23-9265-2023, https://doi.org/10.5194/acp-23-9265-2023, 2023
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In this paper, all-sky downwelling shortwave radiation (DSR) over the entire Tibetan Plateau (TP) at a spatial resolution of 1 km was estimated using an improved parameterization scheme. The influence of topography and different radiative attenuations were comprehensively taken into account. The derived DSR showed good agreement with in situ measurements. The accuracy was better than six other DSR products. The derived DSR also provided more reasonable and detailed spatial patterns.
Elisa T. Sena, Ilan Koren, Orit Altaratz, and Alexander B. Kostinski
Atmos. Chem. Phys., 22, 16111–16122, https://doi.org/10.5194/acp-22-16111-2022, https://doi.org/10.5194/acp-22-16111-2022, 2022
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We used record-breaking statistics together with spatial information to create record-breaking SST maps. The maps reveal warming patterns in the overwhelming majority of the ocean and coherent islands of cooling, where low records occur more frequently than high ones. Some of these cooling spots are well known; however, a surprising elliptical area in the Southern Ocean is observed as well. Similar analyses can be performed on other key climatological variables to explore their trend patterns.
Carola Barrientos-Velasco, Hartwig Deneke, Anja Hünerbein, Hannes J. Griesche, Patric Seifert, and Andreas Macke
Atmos. Chem. Phys., 22, 9313–9348, https://doi.org/10.5194/acp-22-9313-2022, https://doi.org/10.5194/acp-22-9313-2022, 2022
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This article describes an intercomparison of radiative fluxes and cloud properties from satellite, shipborne observations, and 1D radiative transfer simulations. The analysis focuses on research for PS106 expedition aboard the German research vessel, Polarstern. The results are presented in detailed case studies, time series for the PS106 cruise and extended to the central Arctic region. The findings illustrate the main periods of agreement and discrepancies of both points of view.
Yinghui Liu
Atmos. Chem. Phys., 22, 8151–8173, https://doi.org/10.5194/acp-22-8151-2022, https://doi.org/10.5194/acp-22-8151-2022, 2022
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Cloud detection from state-of-art satellite radar and lidar misses low-level clouds. Using in situ observations, this study confirms this cloud detection limitation over the Arctic Ocean. Impacts of this detection limitation from combined satellite radar and lidar on the monthly mean radiation flux estimations at the surface and at the top of the atmosphere in the Arctic are limited but larger from only satellite radar or satellite lidar in monthly mean and instantaneous values.
Babak Jahani, Hendrik Andersen, Josep Calbó, Josep-Abel González, and Jan Cermak
Atmos. Chem. Phys., 22, 1483–1494, https://doi.org/10.5194/acp-22-1483-2022, https://doi.org/10.5194/acp-22-1483-2022, 2022
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The change in the state of sky from cloudy to cloudless (or vice versa) comprises an additional phase called
transition zonewith characteristics laying between those of aerosols and clouds. This study presents an approach for the quantification of the broadband longwave radiative effects of the cloud–aerosol transition zone at the top of the atmosphere during daytime over the ocean based on satellite observations and radiative transfer simulations.
William Cossich, Tiziano Maestri, Davide Magurno, Michele Martinazzo, Gianluca Di Natale, Luca Palchetti, Giovanni Bianchini, and Massimo Del Guasta
Atmos. Chem. Phys., 21, 13811–13833, https://doi.org/10.5194/acp-21-13811-2021, https://doi.org/10.5194/acp-21-13811-2021, 2021
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The presence of clouds over Concordia, in the Antarctic Plateau, is investigated. Results are obtained by applying a machine learning algorithm to measurements of the infrared radiation emitted by the atmosphere toward the surface. The clear-sky, ice cloud, and mixed-phase cloud occurrence at different timescales is studied. A comparison with satellite measurements highlights the ability of the algorithm to identify multiple cloud conditions and study their variability at different timescales.
Ina Neher, Susanne Crewell, Stefanie Meilinger, Uwe Pfeifroth, and Jörg Trentmann
Atmos. Chem. Phys., 20, 12871–12888, https://doi.org/10.5194/acp-20-12871-2020, https://doi.org/10.5194/acp-20-12871-2020, 2020
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Photovoltaic power is one current option to meet the rising energy demand with low environmental impact. Global horizontal irradiance (GHI) is the fuel for photovoltaic power installations and needs to be evaluated to plan and dimension power plants. In this study, 35 years of satellite-based GHI data are analyzed over West Africa to determine their impact on photovoltaic power generation. The major challenges for the development of a solar-based power system in West Africa are then outlined.
Jay Herman, Alexander Cede, Liang Huang, Jerald Ziemke, Omar Torres, Nickolay Krotkov, Matthew Kowalewski, and Karin Blank
Atmos. Chem. Phys., 20, 8351–8380, https://doi.org/10.5194/acp-20-8351-2020, https://doi.org/10.5194/acp-20-8351-2020, 2020
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The amount of erythemal irradiance reaching the Earth's surface has been calculated from ozone, aerosol, and reflectivity data obtained from OMI and DSCOVR/EPIC satellite instruments showing areas with high levels of solar UV radiation. Changes in erythemal irradiance, cloud transmission, aerosol transmission, and ozone absorption have been estimated for 14 years 2005–2018 in units of percent per year for 191 locations, mostly large cities, and from EPIC for the entire illuminated Earth.
Rong Tang, Xin Huang, Derong Zhou, and Aijun Ding
Atmos. Chem. Phys., 20, 6177–6191, https://doi.org/10.5194/acp-20-6177-2020, https://doi.org/10.5194/acp-20-6177-2020, 2020
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Biomass-burning-induced large areas of dark char (i.e.
surface darkening) could influence the radiative energy balance. During the harvest season in eastern China, satellite retrieval shows that surface albedo was significantly decreased. Observational evidence of meteorological perturbations from the surface darkening is identified, which is further examined by model simulation. This work highlights the importance of burning-induced albedo change in weather forecast and regional climate.
Aolin Jia, Shunlin Liang, Dongdong Wang, Bo Jiang, and Xiaotong Zhang
Atmos. Chem. Phys., 20, 881–899, https://doi.org/10.5194/acp-20-881-2020, https://doi.org/10.5194/acp-20-881-2020, 2020
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The Tibetan Plateau (TP) plays a vital role in regional and global climate change due to its location and orography. After generating a long-term surface radiation (SR) dataset, we characterized the SR spatiotemporal variation along with temperature. Evidence from multiple data sources indicated that the TP dimming was primarily driven by increased aerosols from human activities, and the cooling effect of aerosol loading offsets TP surface warming, revealing the human impact on regional warming.
Lei Zhong, Yaoming Ma, Zeyong Hu, Yunfei Fu, Yuanyuan Hu, Xian Wang, Meilin Cheng, and Nan Ge
Atmos. Chem. Phys., 19, 5529–5541, https://doi.org/10.5194/acp-19-5529-2019, https://doi.org/10.5194/acp-19-5529-2019, 2019
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Fine-temporal-resolution turbulent heat fluxes at the plateau scale have significant importance for studying diurnal variation characteristics of atmospheric boundary and weather systems in the Tibetan Plateau (TP) and its surroundings. Time series of land surface heat fluxes with high temporal resolution over the entire TP were derived. The derived surface heat fluxes proved to be in good agreement with in situ measurements and were superior to GLDAS flux products.
Meloë S. Kacenelenbogen, Mark A. Vaughan, Jens Redemann, Stuart A. Young, Zhaoyan Liu, Yongxiang Hu, Ali H. Omar, Samuel LeBlanc, Yohei Shinozuka, John Livingston, Qin Zhang, and Kathleen A. Powell
Atmos. Chem. Phys., 19, 4933–4962, https://doi.org/10.5194/acp-19-4933-2019, https://doi.org/10.5194/acp-19-4933-2019, 2019
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Significant efforts are required to estimate the direct radiative effects of aerosols above clouds (DAREcloudy). We have used a combination of passive and active A-Train satellite sensors and derive mainly positive global and regional DAREcloudy values (e.g., global seasonal values between 0.13 and 0.26 W m-2). Despite differences in methods and sensors, the DAREcloudy values in this study are generally higher than previously reported. We discuss the primary reasons for these higher estimates.
Domenico Cimini, Philip W. Rosenkranz, Mikhail Y. Tretyakov, Maksim A. Koshelev, and Filomena Romano
Atmos. Chem. Phys., 18, 15231–15259, https://doi.org/10.5194/acp-18-15231-2018, https://doi.org/10.5194/acp-18-15231-2018, 2018
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The paper presents a general approach to quantify the uncertainty related to atmospheric absorption models. These models describe how the atmosphere interacts with radiation, and they have general implications for atmospheric sciences.
The presented approach contributes to a better understanding of the total uncertainty affecting atmospheric radiative properties, thus reducing the chances of systematic errors when observations are exploited for weather forecast or climate trend derivations.
Michael Schäfer, Katharina Loewe, André Ehrlich, Corinna Hoose, and Manfred Wendisch
Atmos. Chem. Phys., 18, 13115–13133, https://doi.org/10.5194/acp-18-13115-2018, https://doi.org/10.5194/acp-18-13115-2018, 2018
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Airborne observed horizontal fields of cloud optical thickness are compared with semi-idealized large eddy simulations of Arctic stratus. The comparison focuses on horizontal cloud inhomogeneities and directional features of the small-scale cloud structures. Using inhomogeneity parameters and autocorrelation analysis it is investigated, if the observed small-scale cloud inhomogeneities can be represented by the model. Forcings for cloud inhomogeneities are investigated in a sensitivity study.
Qianqian Song, Zhibo Zhang, Hongbin Yu, Seiji Kato, Ping Yang, Peter Colarco, Lorraine A. Remer, and Claire L. Ryder
Atmos. Chem. Phys., 18, 11303–11322, https://doi.org/10.5194/acp-18-11303-2018, https://doi.org/10.5194/acp-18-11303-2018, 2018
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Mineral dust is the most abundant atmospheric aerosol component in terms of dry mass. In this study, we integrate recent aircraft measurements of dust microphysical and optical properties with satellite retrievals of aerosol and radiative fluxes to quantify the dust direct radiative effects on the shortwave and longwave radiation at both the top of the atmosphere and the surface in the tropical North Atlantic during summer months.
Shu-Peng Ho, Liang Peng, Carl Mears, and Richard A. Anthes
Atmos. Chem. Phys., 18, 259–274, https://doi.org/10.5194/acp-18-259-2018, https://doi.org/10.5194/acp-18-259-2018, 2018
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In this study, we compare 7 years of atmospheric total precipitable water (TPW) derived from multiple microwave radiometers to collocated TPW estimates derived from COSMIC radio occultation under various atmospheric conditions over the oceans. Results show that these two TPW trends from independent observations are larger than previous estimates and are a strong indication of the positive water vapor–temperature feedback on a warming planet.
Anna Mackie, Paul I. Palmer, and Helen Brindley
Atmos. Chem. Phys., 17, 15095–15119, https://doi.org/10.5194/acp-17-15095-2017, https://doi.org/10.5194/acp-17-15095-2017, 2017
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We compare the balance of solar and thermal radiation at the surface and the top of the atmosphere from a forecasting model to observations at a site in Niamey, Niger, in the Sahel. To interpret the energy budgets we examine other factors, such as cloud properties, water vapour and aerosols, which we use to understand the differences between the observation and model. We find that some differences are linked to lack of ice in clouds, underestimated aerosol loading and surface temperatures.
Thomas Fauchez, Steven Platnick, Kerry Meyer, Céline Cornet, Frédéric Szczap, and Tamás Várnai
Atmos. Chem. Phys., 17, 8489–8508, https://doi.org/10.5194/acp-17-8489-2017, https://doi.org/10.5194/acp-17-8489-2017, 2017
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This study presents impact of cirrus cloud horizontal heterogeneity on simulated thermal infrared brightness temperatures at the top of the atmosphere for spatial resolutions ranging from 50 m to 10 km. The cirrus is generated by the 3DCLOUD code and the radiative transfer by the 3DMCPOL code. Brightness temperatures are mostly impacted by the horizontal transport effect and plane-parallel bias at high and coarse spatial resolutions, respectively, with a minimum around 100 m–250 m.
Zhao-Cheng Zeng, Qiong Zhang, Vijay Natraj, Jack S. Margolis, Run-Lie Shia, Sally Newman, Dejian Fu, Thomas J. Pongetti, Kam W. Wong, Stanley P. Sander, Paul O. Wennberg, and Yuk L. Yung
Atmos. Chem. Phys., 17, 2495–2508, https://doi.org/10.5194/acp-17-2495-2017, https://doi.org/10.5194/acp-17-2495-2017, 2017
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We propose a novel approach to describing the scattering effects of atmospheric aerosols using H2O retrievals in the near infrared. We found that the aerosol scattering effect is the primary contributor to the variations in the wavelength dependence of the H2O SCD retrievals and the scattering effects can be derived using H2O retrievals from multiple bands. This proposed method could potentially contribute towards reducing biases in greenhouse gas retrievals from space.
Michael Schäfer, Eike Bierwirth, André Ehrlich, Evelyn Jäkel, Frank Werner, and Manfred Wendisch
Atmos. Chem. Phys., 17, 2359–2372, https://doi.org/10.5194/acp-17-2359-2017, https://doi.org/10.5194/acp-17-2359-2017, 2017
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Cloud optical thickness fields, retrieved from solar spectral radiance measurements, are used to investigate the directional structure of horizontal cloud inhomogeneities with scalar one-dimensional inhomogeneity parameters, two-dimensional auto-correlation functions, and two-dimensional Fourier analysis. The investigations reveal that it is not sufficient to quantify horizontal cloud inhomogeneities by one-dimensional inhomogeneity parameters; two-dimensional parameters are necessary.
Quentin Libois, Liviu Ivanescu, Jean-Pierre Blanchet, Hannes Schulz, Heiko Bozem, W. Richard Leaitch, Julia Burkart, Jonathan P. D. Abbatt, Andreas B. Herber, Amir A. Aliabadi, and Éric Girard
Atmos. Chem. Phys., 16, 15689–15707, https://doi.org/10.5194/acp-16-15689-2016, https://doi.org/10.5194/acp-16-15689-2016, 2016
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The first airborne measurements performed with the FIRR are presented. Vertical profiles of upwelling spectral radiance in the far-infrared are measured in the Arctic atmosphere for the first time. They show the impact of the temperature inversion on the radiative budget of the atmosphere, especially in the far-infrared. The presence of ice clouds also significantly alters the far-infrared budget, highlighting the critical interplay between water vapour and clouds in this very dry region.
Jani Huttunen, Harri Kokkola, Tero Mielonen, Mika Esa Juhani Mononen, Antti Lipponen, Juha Reunanen, Anders Vilhelm Lindfors, Santtu Mikkonen, Kari Erkki Juhani Lehtinen, Natalia Kouremeti, Alkiviadis Bais, Harri Niska, and Antti Arola
Atmos. Chem. Phys., 16, 8181–8191, https://doi.org/10.5194/acp-16-8181-2016, https://doi.org/10.5194/acp-16-8181-2016, 2016
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For a good estimate of the current forcing by anthropogenic aerosols, knowledge in past is needed. One option to lengthen time series is to retrieve aerosol optical depth from solar radiation measurements. We have evaluated several methods for this task. Most of the methods produce aerosol optical depth estimates with a good accuracy. However, machine learning methods seem to be the most applicable not to produce any systematic biases, since they do not need constrain the aerosol properties.
Claire Pettersen, Ralf Bennartz, Mark S. Kulie, Aronne J. Merrelli, Matthew D. Shupe, and David D. Turner
Atmos. Chem. Phys., 16, 4743–4756, https://doi.org/10.5194/acp-16-4743-2016, https://doi.org/10.5194/acp-16-4743-2016, 2016
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We examined four summers of data from a ground-based atmospheric science instrument suite at Summit Station, Greenland, to isolate the signature of the ice precipitation. By using a combination of instruments with different specialities, we identified a passive microwave signature of the ice precipitation. This ice signature compares well to models using synthetic data characteristic of the site.
Zhibo Zhang, Kerry Meyer, Hongbin Yu, Steven Platnick, Peter Colarco, Zhaoyan Liu, and Lazaros Oreopoulos
Atmos. Chem. Phys., 16, 2877–2900, https://doi.org/10.5194/acp-16-2877-2016, https://doi.org/10.5194/acp-16-2877-2016, 2016
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The frequency of occurrence and shortwave direct radiative effects (DRE) of above-cloud aerosols (ACAs) over global oceans are investigated using 8 years of collocated CALIOP and MODIS observations. We estimated that ACAs have a global ocean annual mean diurnally averaged cloudy-sky DRE of 0.015 W m−2 (range of −0.03 to 0.06 W m−2) at TOA. The DREs at surface and within atmosphere are −0.15 W m−2 (range of −0.09 to −0.21 W m−2), and 0.17 W m−2 (range of 0.11 to 0.24 W m−2), respectively.
Wenjun Tang, Jun Qin, Kun Yang, Shaomin Liu, Ning Lu, and Xiaolei Niu
Atmos. Chem. Phys., 16, 2543–2557, https://doi.org/10.5194/acp-16-2543-2016, https://doi.org/10.5194/acp-16-2543-2016, 2016
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In this paper, we develop a new method to quickly retrieve high-resolution surface solar radiation (SSR) over China by combining MODIS and MTSAT data. The RMSEs of the retrieved SSR at hourly, daily, and monthly scales are about 98.5, 34.2, and 22.1 W m−2. The accuracy is comparable to or even higher than other two satellite radiation products. Finally, we derive an 8-year high-resolution SSR data set (hourly, 5 km) from 2007 to 2014, which would contribute to studies of land surface processes.
S. Doniki, D. Hurtmans, L. Clarisse, C. Clerbaux, H. M. Worden, K. W. Bowman, and P.-F. Coheur
Atmos. Chem. Phys., 15, 12971–12987, https://doi.org/10.5194/acp-15-12971-2015, https://doi.org/10.5194/acp-15-12971-2015, 2015
W. Sun, R. R. Baize, G. Videen, Y. Hu, and Q. Fu
Atmos. Chem. Phys., 15, 11909–11918, https://doi.org/10.5194/acp-15-11909-2015, https://doi.org/10.5194/acp-15-11909-2015, 2015
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A method is reported for retrieving super-thin cloud optical depth with polarized light. It is found that near-backscatter p-polarized light is sensitive to clouds, but not to ocean conditions. Near-backscatter p-polarized intensity linearly relates to super-thin cloud optical depth. Based on these findings, super-thin cloud optical depth can be retrieved with little effect from surface reflection.
M. Schäfer, E. Bierwirth, A. Ehrlich, E. Jäkel, and M. Wendisch
Atmos. Chem. Phys., 15, 8147–8163, https://doi.org/10.5194/acp-15-8147-2015, https://doi.org/10.5194/acp-15-8147-2015, 2015
W. Sun, R. R. Baize, C. Lukashin, and Y. Hu
Atmos. Chem. Phys., 15, 7725–7734, https://doi.org/10.5194/acp-15-7725-2015, https://doi.org/10.5194/acp-15-7725-2015, 2015
E. C. Turner, H.-T. Lee, and S. F. B. Tett
Atmos. Chem. Phys., 15, 6561–6575, https://doi.org/10.5194/acp-15-6561-2015, https://doi.org/10.5194/acp-15-6561-2015, 2015
M. M. Wonsick, R. T. Pinker, and Y. Ma
Atmos. Chem. Phys., 14, 8749–8761, https://doi.org/10.5194/acp-14-8749-2014, https://doi.org/10.5194/acp-14-8749-2014, 2014
X. Ceamanos, D. Carrer, and J.-L. Roujean
Atmos. Chem. Phys., 14, 8209–8232, https://doi.org/10.5194/acp-14-8209-2014, https://doi.org/10.5194/acp-14-8209-2014, 2014
Q. Shi and S. Liang
Atmos. Chem. Phys., 14, 5659–5677, https://doi.org/10.5194/acp-14-5659-2014, https://doi.org/10.5194/acp-14-5659-2014, 2014
C. Fricke, A. Ehrlich, E. Jäkel, B. Bohn, M. Wirth, and M. Wendisch
Atmos. Chem. Phys., 14, 1943–1958, https://doi.org/10.5194/acp-14-1943-2014, https://doi.org/10.5194/acp-14-1943-2014, 2014
Y. Ma, Z. Zhu, L. Zhong, B. Wang, C. Han, Z. Wang, Y. Wang, L. Lu, P. M. Amatya, W. Ma, and Z. Hu
Atmos. Chem. Phys., 14, 1507–1515, https://doi.org/10.5194/acp-14-1507-2014, https://doi.org/10.5194/acp-14-1507-2014, 2014
W. Sun and C. Lukashin
Atmos. Chem. Phys., 13, 10303–10324, https://doi.org/10.5194/acp-13-10303-2013, https://doi.org/10.5194/acp-13-10303-2013, 2013
L. Shi, C. J. Schreck III, and V. O. John
Atmos. Chem. Phys., 13, 6907–6920, https://doi.org/10.5194/acp-13-6907-2013, https://doi.org/10.5194/acp-13-6907-2013, 2013
M. J. Alvarado, V. H. Payne, E. J. Mlawer, G. Uymin, M. W. Shephard, K. E. Cady-Pereira, J. S. Delamere, and J.-L. Moncet
Atmos. Chem. Phys., 13, 6687–6711, https://doi.org/10.5194/acp-13-6687-2013, https://doi.org/10.5194/acp-13-6687-2013, 2013
T. Várnai, A. Marshak, and W. Yang
Atmos. Chem. Phys., 13, 3899–3908, https://doi.org/10.5194/acp-13-3899-2013, https://doi.org/10.5194/acp-13-3899-2013, 2013
A. Riihelä, T. Manninen, V. Laine, K. Andersson, and F. Kaspar
Atmos. Chem. Phys., 13, 3743–3762, https://doi.org/10.5194/acp-13-3743-2013, https://doi.org/10.5194/acp-13-3743-2013, 2013
Y. L. Roberts, P. Pilewskie, B. C. Kindel, D. R. Feldman, and W. D. Collins
Atmos. Chem. Phys., 13, 3133–3147, https://doi.org/10.5194/acp-13-3133-2013, https://doi.org/10.5194/acp-13-3133-2013, 2013
C. L. Young, I. N. Sokolik, and J. Dufek
Atmos. Chem. Phys., 12, 3699–3715, https://doi.org/10.5194/acp-12-3699-2012, https://doi.org/10.5194/acp-12-3699-2012, 2012
A. Ehrlich, E. Bierwirth, M. Wendisch, A. Herber, and J.-F. Gayet
Atmos. Chem. Phys., 12, 3493–3510, https://doi.org/10.5194/acp-12-3493-2012, https://doi.org/10.5194/acp-12-3493-2012, 2012
E. M. Wilcox
Atmos. Chem. Phys., 12, 139–149, https://doi.org/10.5194/acp-12-139-2012, https://doi.org/10.5194/acp-12-139-2012, 2012
Cited articles
Barber, R. J., Tennyson, J., Harris, G. J., and Tolchenov, R. N.: A high
accuracy computed water line list, Mon. Not. R. Astron. Soc., 368,
1087–1094, https://doi.org/10.1111/j.1365-2966.2006.10184.x, 2006. a
Borger, C., Beirle, S., Dörner, S., Sihler, H., and Wagner, T.: Total column water vapour retrieval from S-5P/TROPOMI in the visible blue spectral range, Atmos. Meas. Tech., 13, 2751–2783, https://doi.org/10.5194/amt-13-2751-2020, 2020. a
Boyarkin, O. V., Koshelev, M. A., Aseev, O., Maksyutenko, P., Rizzo, T. R.,
Zobov, N. F., Lodi, L., Tennyson, J., and Polyansky, O. L.: Accurate bond
dissociation energy of water determined by triple-resonance vibrational
spectroscopy and ab initio calculations, Chem. Phys. Lett., 568-569, 14–20,
https://doi.org/10.1016/j.cplett.2013.03.007, 2013. a
Bunker, P. R. and Moss, R. E.: Effect of the Breakdown of the Born-Oppenheimer
Approximation on the Rotation-Vibration Hamiltonian of a Triatomic Molecule,
J. Mol. Spectrosc., 80, 217–228, 1980. a
Cantrell, C. A., Davidson, J. A., McDaniel, A. H., Shetter, R. E., and Calvert, J. G.: Temperature-dependent formaldehyde cross sections in the
near-ultraviolet spectral region, J. Phys. Chem., 94, 3902–3908,
https://doi.org/10.1021/j100373a008, 1990. a
Cantrell, C. A., Zimmer, A., and Tyndall, G. S.: Correction to “Absorption
cross sections for water vapor from 183 to 193 nm”, Geophys. Res. Lett., 24, 2687–2687, https://doi.org/10.1029/97GL02803, 1997a. a
Cantrell, C. A., Zimmer, A., and Tyndall, G. S.: Absorption cross sections for water vapor from 183 to 193 nm, Geophys. Res. Lett., 24, 2195–2198,
https://doi.org/10.1029/97GL02100, 1997b. a
Chung, C.-Y., Chew, E. P., Bing-Ming Cheng, M. B., and Lee, Y.-P.: Temperature dependence of absorption cross-section of H2O, HOD, and D2O in the spectral region 140–193 nm, Nucl. Instrum. Meth. A, 467-468, 1572–1576,
https://doi.org/10.1016/S0168-9002(01)00762-8, 2001. a
Coles, P. A., Ovsyannikov, R. I., Polyansky, O. L., Yurchenko, S. N., and
Tennyson, J.: Improved potential energy surface and spectral assignments for
ammonia in the near-infrared region, J. Quant. Spectrosc. Ra.,
219, 199–212, https://doi.org/10.1016/j.jqsrt.2018.07.022, 2018. a
Coles, P. A., Yurchenko, S. N., Kovacich, R. P., Hobby, J., and Tennyson, J.:
A variationally computed room temperature line list for AsH3, Phys.
Chem. Chem. Phys., 21, 3264–3277, https://doi.org/10.1039/C8CP07110A, 2019. a
Conway, E. K., Kyuberis, A. A., Polyansky, O. L., Tennyson, J., and Zobov, N.: A highly accurate ab initio dipole moment surface for the ground electronic state of water vapour for spectra extending into the ultraviolet, J. Chem. Phys., 149, 084307, https://doi.org/10.1063/1.5043545, 2018. a, b, c, d, e, f, g
Conway, E. K., Gordon, I. E., Kyuberis, A. A., Polyansky, O. L., Tennyson, J., and Zobov, N. F.: Accurate line lists for H
Conway, E. K., Gordon, I. E., Polyansky, O. L., and Tennyson, J.: Use of the
complete basis set limit for computing highly accurate ab initio
dipole moments, J. Chem. Phys., 152, 024105, https://doi.org/10.1063/1.5135931,
2020b. a
Császár, A. G., Czakó, G., Furtenbacher, T., and Mátyus, E.: An
active database approach to complete rotational–vibrational spectra of small
molecules, Annu. Rep. Comput. Chem., 3, 155–176,
https://doi.org/10.1016/S1574-1400(07)03009-5, 2007. a
Delahaye, T., Nikitin, A., Rey, M., Szalay, P. G., and Tyuterev, V. G.: A new
accurate ground-state potential energy surface of ethylene and predictions
for rotational and vibrational energy levels, J. Chem. Phys., 141, 104301,
https://doi.org/10.1063/1.4894419, 2014. a
Dunning, T. H.: Gaussian basis sets for use in correlated molecular
calculations. I. The atoms boron through neon and hydrogen , J. Chem. Phys.,
90, 1007–1023, https://doi.org/10.1063/1.456153, 1989. a
Dupre, P., Germain, T., Zobov, N. F., Tolchenov, R. N., and Tennyson, J.:
Continuous Wave – Cavity ring down near ultraviolet rotation-vibration
spectrum of water, J. Chem. Phys., 123, 154307, https://doi.org/10.1063/1.2055247,
2005. a, b
Fleischmann, O. C., Hartmann, M., Burrows, J. P., and Orphal, J.: New
ultraviolet absorption cross-sections of BrO at atmospheric temperatures
measured by time-windowing Fourier transform spectroscopy, J.
Photoch. Photobio. A, 168, 117–132,
https://doi.org/10.1016/j.jphotochem.2004.03.026, 2004. a
Fleming, B. T., France, K. C., Nell, N., Kohnert, R. A., Pool, K., Egan, A.,
Fossati, L., Koskinen, T. T., Vidotto, A. A., Hoadley, K., Desert, J.-M.,
Beasley, M., and Petit, P. M.: Colorado Ultraviolet Transit Experiment: a
dedicated CubeSat mission to study exoplanetary mass loss and magnetic
fields, Journal of Astronomical Telescopes, Instruments, and Systems, 4, 1–10, https://doi.org/10.1117/1.JATIS.4.1.014004, 2018. a
Furtenbacher, T. and Császár, A. G.: MARVEL: measured active
rotational-vibrational energy levels. II. Algorithmic improvements, J.
Quant. Spectrosc. Ra., 113, 929–935,
https://doi.org/10.1016/j.jqsrt.2012.01.005, 2012. a
Furtenbacher, T., Császár, A. G., and Tennyson, J.: MARVEL: measured
active rotational-vibrational energy levels, J. Mol. Spectrosc., 245,
115–125, https://doi.org/10.1016/j.jms.2007.07.005, 2007. a
Furtenbacher, T., Tóbiás, R., Tennyson, J., Polyansky, O. L., and Császár,
A. G.: W2020: A Database of Validated Rovibrational Experimental Transitions
and Empirical Energy Levels of H216O, J. Phys. Chem.
Ref. Data, 49, 033101, https://doi.org/10.1063/5.0008253, 2020. a, b, c, d
Gonzalez Abad, G., Hossein Souri, A., Bak, J., Chance, K., Flynn, L. E., Krotkov, N. A., Lamsal, L., Li, C., Liu, X., Chan Miller, C., Nowlan, C. R., Suleiman, R., and Wang, H.: Five decades observing Earth's atmospheric
trace gases using ultraviolet and visible backscatter solar radiation from
space, J. Quant. Spectrosc. Ra., 238, 106478,
https://doi.org/10.1016/j.jqsrt.2019.04.030, 2019. a, b
Gordon, I. E., Rothman, L. S., Hill, C., Kochanov, R. V., Tan, Y., Bernath,
P. F., Birk, M., Boudon, V., Campargue, A., Chance, K. V., Drouin, B. J.,
Flaud, J.-M., Gamache, R. R., Hodges, J. T., Jacquemart, D., Perevalov,
V. I., Perrin, A., Shine, K. P., Smith, M.-A. H., Tennyson, J., Toon, G. C.,
Tran, H., Tyuterev, V. G., Barbe, A., Császár, A. G., Devi, V. M.,
Furtenbacher, T., Harrison, J. J., Hartmann, J.-M., Jolly, A., Johnson,
T. J., Karman, T., Kleiner, I., Kyuberis, A. A., Loos, J., Lyulin, O. M.,
Massie, S. T., Mikhailenko, S. N., Moazzen-Ahmadi, N., Müller, H. S. P.,
Naumenko, O. V., Nikitin, A. V., Polyansky, O. L., Rey, M., Rotger, M.,
Sharpe, S. W., Sung, K., Starikova, E., Tashkun, S. A., Vander Auwera, J.,
Wagner, G., Wilzewski, J., Wcisło, P., Yu, S., and Zak, E. J.: The
HITRAN 2016 molecular spectroscopic database, J. Quant. Spectrosc.
Ra., 203, 3–69, https://doi.org/10.1016/j.jqsrt.2017.06.038, 2017. a, b, c
Grechko, M., Boyarkin, O. V., Rizzo, T. R., Maksyutenko, P., Zobov, N. F.,
Shirin, S., Lodi, L., Tennyson, J., Császár, A. G., and Polyansky,
O. L.: State-selective spectroscopy of water up to its first dissociation
limit, J. Chem. Phys., 131, 221105, https://doi.org/10.1063/1.3273207, 2009. a
Grechko, M., Maksyutenko, P., Rizzo, T. R., and Boyarkin, O. V.:
Communication: Feshbach resonances in the water molecule revealed by
state-selective spectroscopy, J. Chem. Phys., 133, 081103,
https://doi.org/10.1063/1.3472312, 2010. a
Huang, X., Schwenke, D. W., Tashkun, S. A., and Lee, T. J.: An
isotopic-independent highly accurate potential energy surface for CO2
isotopologues and an initial 12C16O2 infrared line list, J.
Chem. Phys., 136, 124311, https://doi.org/10.1063/1.3697540, 2012. a
Kim, J., Jeong, U., Ahn, M.-H., Kim, J. H., Park, R. J., Lee, H., Song, C. H., Choi, Y.-S., Lee, K.-H., Yoo, J.-M., Jeong, M.-J., Park, S. K., Lee, K.-M., Song, C.-K., Kim, S.-W., Kim, Y., Kim, S.-W., Kim, M., Go, S., Liu, X., Chance, K., Chan Miller, C., Al-Saadi, J., Veihelmann, B., Bhartia, P. K., Torres, O., Abad, G. G., Haffner, D. P., Ko, D. H., Lee, S. H., Woo, J.-H., Chong, H., Park, S. S., Nicks, D., Choi, W. J., Moon, K.-J., Cho, A., Yoon, J., Kim, S.-k., Hong, H., Lee, K., Lee, H., Lee, S., Choi, M., Veefkind, P., Levelt, P., Edwards, D. P., Kang, M., Eo, M., Bak, J., Baek, K., Kwon, H.-A., Yang, J., Park, J., Han, K. M., Kim, B.-R., Shin, H.-W., Choi, H., Lee, E., Chong, J., Cha, Y., Koo, J.-H., Irie, H., Hayashida, S., Kasai, Y., Kanaya, Y., Liu, C., Lin, J., Crawford, J. H., Carmichael, G. R., Newchurch, M. J., Lefer, B. L., Herman, J. R., Swap, R. J., Lau, A. K. H., Kurosu, T. P., Jaross, G., Ahlers, B., Dobber, M., McElroy, C., and Choi, Y.: New Era of Air Quality Monitoring from Space: Geostationary Environment Monitoring Spectrometer (GEMS), B. Am. Meteorol. Soc., 101, E1–E22, https://doi.org/10.1175/bams-d-18-0013.1, 2020. a
Kochanov, R. V., Gordon, I. E., Rothman, L. S., Wcisło, P., Hill, C., and
Wilzewski, J. S.: HITRAN Application Programming Interface (HAPI): A
comprehensive approach to working with spectroscopic data, J. Quant.
Spectrosc. Ra., 177, 15–30, https://doi.org/10.1016/j.jqsrt.2016.03.005,
2016. a
Lampel, J., Pöhler, D., Tschritter, J., Frieß, U., and Platt, U.: On the relative absorption strengths of water vapour in the blue wavelength range, Atmos. Meas. Tech., 8, 4329–4346, https://doi.org/10.5194/amt-8-4329-2015, 2015. a
Lampel, J., Pöhler, D., Polyansky, O. L., Kyuberis, A. A., Zobov, N. F., Tennyson, J., Lodi, L., Frieß, U., Wang, Y., Beirle, S., Platt, U., and Wagner, T.: Detection of water vapour absorption around 363 nm in measured atmospheric absorption spectra and its effect on DOAS evaluations, Atmos. Chem. Phys., 17, 1271–1295, https://doi.org/10.5194/acp-17-1271-2017, 2017. a, b, c, d, e, f, g, h, i, j, k
Levelt, P. F., Joiner, J., Tamminen, J., Veefkind, J. P., Bhartia, P. K., Stein Zweers, D. C., Duncan, B. N., Streets, D. G., Eskes, H., van der A, R., McLinden, C., Fioletov, V., Carn, S., de Laat, J., DeLand, M., Marchenko, S., McPeters, R., Ziemke, J., Fu, D., Liu, X., Pickering, K., Apituley, A., González Abad, G., Arola, A., Boersma, F., Chan Miller, C., Chance, K., de Graaf, M., Hakkarainen, J., Hassinen, S., Ialongo, I., Kleipool, Q., Krotkov, N., Li, C., Lamsal, L., Newman, P., Nowlan, C., Suleiman, R., Tilstra, L. G., Torres, O., Wang, H., and Wargan, K.: The Ozone Monitoring Instrument: overview of 14 years in space, Atmos. Chem. Phys., 18, 5699–5745, https://doi.org/10.5194/acp-18-5699-2018, 2018. a, b, c
Lodi, L. and Tennyson, J.: Theoretical methods for small-molecule
ro-vibrational spectroscopy, J. Phys. B, 43, 133001, https://doi.org/10.1088/0953-4075/43/13/133001, 2010. a
Lodi, L. and Tennyson, J.: Line lists for H218O and H217O
based on empirically-adjusted line positions and ab initio intensities, J.
Quant. Spectrosc. Ra., 113, 850–858,
https://doi.org/10.1016/j.jqsrt.2012.02.023, 2012. a
Lodi, L., Tennyson, J., and Polyansky, O. L.: A global, high accuracy ab initio
dipole moment surface for the electronic ground state of the water molecule,
J. Chem. Phys., 135, 034113, https://doi.org/10.1063/1.3604934, 2011. a, b, c
Mant, B. P., Yachmenev, A., Tennyson, J., and Yurchenko, S. N.: ExoMol
molecular line lists – XXVII: spectra of C2H4, Mon. Not. R. Astron.
Soc., 478, 3220–3232, https://doi.org/10.1093/mnras/sty1239, 2018. a
McKemmish, L. K., Masseron, T., Hoeijmakers, J., Pérez-Mesa, V. V., Grimm,
S. L., Yurchenko, S. N., and Tennyson, J.: ExoMol Molecular line lists –
XXXIII. The spectrum of Titanium Oxide, Mon. Not. R. Astron. Soc., 488,
2836–2854, https://doi.org/10.1093/mnras/stz1818, 2019. a
Medvedev, E. S., Ushakov, V. G., Conway, E. K., Upadhyay, A., Gordon, I. E.,
and Tennyson, J.: Empirical normal intensity distribution for overtone
vibrational spectra of triatomic molecules, J. Quant. Spectrosc. Ra., 252, 107084, https://doi.org/10.1016/j.jqsrt.2020.107084,
2020. a
Mota, R., Parafita, R., Giuliani, A., Hubin-Franskin, M.-J., Lourenço, J.
M. C., Garcia, G., Hoffmann, S. V., Mason, N. J., Ribeiro, P. A., Raposo, M.,
and ao Vieira, P. L.: Water VUV electronic state spectroscopy by
synchrotron radiation, Chem. Phys. Lett., 416, 152–159,
https://doi.org/10.1016/j.cplett.2005.09.073, 2005. a
Noël, S., Buchwitz, M., and Burrows, J. P.: First retrieval of global water vapour column amounts from SCIAMACHY measurements, Atmos. Chem. Phys., 4, 111–125, https://doi.org/10.5194/acp-4-111-2004, 2004. a
Owens, A., Yachmenev, A., Tennyson, J., Thiel, W., and Yurchenko, S. N.:
ExoMol Molecular line lists XXIX: The rotation-vibration spectrum of methyl
chloride up to 1200 K, Mon. Not. R. Astron. Soc., 479, 3002–3010,
https://doi.org/10.1093/mnras/sty1542, 2018. a
Pei, L., Min, Q., Du, Y., Wang, Z., Yin, B., Yang, K., Disterhoft, P.,
Pongetti, T., and Zhu, L.: Water Vapor Near-UV Absorption: Laboratory
Spectrum, Field Evidence, and Atmospheric Impacts, J. Geophys. Res.-Atmos.,
124, 14310–14324, https://doi.org/10.1029/2019JD030724, 2020. a, b, c, d, e, f, g, h, i, j, k, l, m, n
Peterson, K. A. and Dunning, T. H.: Accurate correlation consistent basis sets for molecular core–valence correlation effects: The second row atoms Al–Ar, and the first row atoms B–Ne revisited, J. Chem. Phys., 117, 10548,
https://doi.org/10.1063/1.1520138, 2002. a
Polyansky, O. L., Ovsyannikov, R. I., Kyuberis, A. A., Lodi, L., Tennyson, J., and Zobov, N. F.: Calculation of rotation-vibration energy levels of the
water molecule with near-experimental accuracy based on an ab initio
potential energy surface, J. Phys. Chem. A, 117, 9633–9643,
https://doi.org/10.1021/jp312343z, 2013. a, b
Pyykkö, P., Dyall, K. G., Császár, A. G., Tarczay, G., Polyansky,
O. L., and Tennyson, J.: Lamb shift effects in rotation-vibration spectra of
water, Phys. Rev. A, 63, 024502, https://doi.org/10.1103/PhysRevA.63.024502, 2001. a
Quiney, H. M., Barletta, P., Tarczay, G., Császár, A. G., Polyansky,
O. L., and Tennyson, J.: Two-electron relativistic corrections to the
potential energy surface and vibration-rotation levels of water, Chem. Phys.
Lett., 344, 413–420, https://doi.org/10.1016/S0009-2614(01)00784-9, 2001. a
Ranjan, S., Schwieterman, E. W., Harman, C., Fateev, A., Sousa-Silva, C.,
Seager, S., and Hu, R.: Photochemistry of Anoxic Abiotic Habitable Planet
Atmospheres: Impact of New H2O Cross Sections, Astrophys.
J., 896, 148, https://doi.org/10.3847/1538-4357/ab9363, 2020. a
Rocha, C. and Varandas, A.: Energy-switching potential energy surface for
ground-state C3, Chem. Phys. Lett., 700, 36–43,
https://doi.org/10.1016/j.cplett.2018.04.005, 2018. a
Rothman, L., Gordon, I., Barber, R., Dothe, H., Gamache, R., Goldman, A.,
Perevalov, V., Tashkun, S., and Tennyson, J.: HITEMP, the high-temperature
molecular spectroscopic database, J. Quant. Spectrosc. Ra., 111,
2139–2150, https://doi.org/10.1016/j.jqsrt.2010.05.001, 2010. a, b
Schryber, J. H., Polyansky, O. L., Jensen, P., and Tennyson, J.: On the
spectroscopically determined the potential energy surfaces for the electronic
ground states of NO2 and H2O, J. Mol. Spectrosc., 185, 234–243,
https://doi.org/10.1006/jmsp.1997.7407, 1997. a
Schwenke, D. W.: Beyond the Potential Energy Surface: Ab initio Corrections to the Born-Oppenheimer Approximation for H2O, J. Phys. Chem. A, 105,
2352–2360, https://doi.org/10.1021/jp0032513, 2001. a, b, c
Shirin, S. V., Polyansky, O. L., Zobov, N. F., Barletta, P., and Tennyson, J.:Spectroscopically determined potential energy surface of H216O up to 25 000 cm−1, J. Chem. Phys., 118, 2124–2129, https://doi.org/10.1063/1.1532001, 2003. a
Stutz, J., Kim, E. S., Platt, U., Bruno, P., Perrino, C., and Febo, A.:
UV-visible absorption cross sections of nitrous acid, J. Geophys. Res.,
105, 14585–14592, https://doi.org/10.1029/2000JD900003, 2000. a
Tennyson, J., Kostin, M. A., Barletta, P., Harris, G. J., Polyansky, O. L.,
Ramanlal, J., and Zobov, N. F.: DVR3D: a program suite for the calculation of
rotation-vibration spectra of triatomic molecules, Comput. Phys. Commun.,
163, 85–116, https://doi.org/10.1016/j.cpc.2003.10.003, 2004. a, b
Tennyson, J., Bernath, P. F., Brown, L. R., Campargue, A., Carleer, M. R.,
Császár, A. G., Daumont, L., Gamache, R. R., Hodges, J. T., Naumenko,
O. V., Polyansky, O. L., Rothmam, L. S., Vandaele, A. C., Zobov, N. F., Al
Derzi, A. R., Fábri, C., Fazliev, A. Z., Furtenbacher, T., Gordon, I. E.,
Lodi, L., and Mizus, I. I.: IUPAC critical evaluation of the
rotational-vibrational spectra of water vapor. Part III. Energy levels and
transition wavenumbers for H216O, J. Quant. Spectrosc. Ra., 117, 29–80, https://doi.org/10.1016/j.jqsrt.2012.10.002, 2013. a
Tennyson, J., Bernath, P. F., Brown, L. R., Campargue, A., Császár, A. G., Daumont, L., Gamache, R. R., Hodges, J. T., Naumenko, O. V., Polyansky, O. L., Rothman, L. S., Vandaele, A. C., and Zobov, N. F.: A Database of
Water Transitions from Experiment and Theory (IUPAC Technical Report), Pure
Appl. Chem., 86, 71–83, https://doi.org/10.1515/pac-2014-5012, 2014. a
Tennyson, J., Yurchenko, S. N., Al-Refaie, A. F., Barton, E. J., Chubb, K. L., Coles, P. A., Diamantopoulou, S., Gorman, M. N., Hill, C., Lam, A. Z., Lodi, L., McKemmish, L. K., Na, Y., Owens, A., Polyansky, O. L., Rivlin, T.,
Sousa-Silva, C., Underwood, D. S., Yachmenev, A., and Zak, E.: The ExoMol
database: molecular line lists for exoplanet and other hot atmospheres, J.
Mol. Spectrosc., 327, 73–94, https://doi.org/10.1016/j.jms.2016.05.002, 2016. a
Tóbiás, R., Furtenbacher, T., Tennyson, J., and Császár, A. G.:
Accurate empirical rovibrational energies and transitions of H216O,
Phys. Chem. Chem. Phys., 21, 3473–3495, https://doi.org/10.1039/c8cp05169k, 2019. a
Varandas, A. J. C.: Energy switching approach to potential surfaces: An
accurate single-valued function for the water molecule, J. Chem. Phys., 105,
3524–3531, https://doi.org/10.1063/1.473005, 1996. a
Wagner, T., Heland, J., Zöger, M., and Platt, U.: A fast H2O total column density product from GOME – Validation with in-situ aircraft measurements, Atmos. Chem. Phys., 3, 651–663, https://doi.org/10.5194/acp-3-651-2003, 2003. a
Wagner, T., Beirle, S., Sihler, H., and Mies, K.: A feasibility study for the retrieval of the total column precipitable water vapour from satellite observations in the blue spectral range, Atmos. Meas. Tech., 6, 2593–2605, https://doi.org/10.5194/amt-6-2593-2013, 2013. a
Wang, H., Liu, X., Chance, K., González Abad, G., and Chan Miller, C.: Water vapor retrieval from OMI visible spectra, Atmos. Meas. Tech., 7, 1901–1913, https://doi.org/10.5194/amt-7-1901-2014, 2014. a, b
Wang, H., Souri, A. H., González Abad, G., Liu, X., and Chance, K.: Ozone Monitoring Instrument (OMI) Total Column Water Vapor version 4 validation and applications, Atmos. Meas. Tech., 12, 5183–5199, https://doi.org/10.5194/amt-12-5183-2019, 2019. a, b
Woon, D. E. and Dunning Jr., T. H.: Gaussian basis sets for use in
correlated molecular calculations. V. Core‐valence basis sets for boron
through neon, J. Chem. Phys., 103, 4572–4585, https://doi.org/10.1063/1.470645, 1995.
a
Yurchenko, S. N., Carvajal, M., Jensen, P., Herregodts, F., and Huet, T. R.:
Potential parameters of PH3 obtained by simultaneous fitting of ab
initio data and experimental vibrational band origins, Chem. Phys., 290,
59–67, https://doi.org/10.1016/S0301-0104(03)00098-3, 2003. a, b
Zobov, N. F., Polyansky, O. L., Le Sueur, C. R., and Tennyson, J.:
Vibration-rotation levels of water beyond the Born-Oppenheimer
approximation, Chem. Phys. Lett., 260, 381–387,
https://doi.org/10.1016/0009-2614(96)00872-X, 1996. a
Zoogman, P., Liu, X., Suleiman, R. M., Pennington, W. F., Flittner, D. E.,
Al-Saadi, J. A., Hilton, B. B., Nicks, D. K., Newchurch, M. J., Carr, J. L.,
Janz, S. J., Andraschko, M. R., Arola, A., Baker, B. D., Canova, B. P.,
Miller, C. C., Cohen, R. C., Davis, J. E., Dussault, M. E., Edwards, D. P.,
Fishman, J., Ghulam, A., Abad, G. G., Grutter, M., Herman, J. R., Houck, J.,
Jacob, D. J., Joiner, J., Kerridge, B. J., Kim, J., Krotkov, N. A., Lamsal,
L., Li, C., Lindfors, A., Martin, R. V., McElroy, C. T., McLinden, C.,
Natraj, V., Neil, D. O., Nowlan, C. R., O'Sullivan, E. J., Palmer, P. I.,
Pierce, R. B., Pippin, M. R., Saiz-Lopez, A., Spurr, R. J. D., Szykman,
J. J., Torres, O., Veefkind, J. P., Veihelmann, B., Wang, H., Wang, J., and
Chance, K.: Tropospheric emissions: Monitoring of pollution (TEMPO), J.
Quant. Spectrosc. Ra., 186, 17–39,
https://doi.org/10.1016/j.jqsrt.2016.05.008, 2017. a, b
Short summary
Water vapour has a complex spectrum and absorbs from the microwave to the near-UV where it dissociates. There is limited knowledge of the absorption features in the near-UV, and there is a large disagreement for the available models and experiments. We created a new ab initio model that is in good agreement with observation at 363 nm. At lower wavelengths, our calculations suggest that the latest experiments overestimate absorption. This has implications for trace gas retrievals in the near-UV.
Water vapour has a complex spectrum and absorbs from the microwave to the near-UV where it...
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