Articles | Volume 18, issue 14
https://doi.org/10.5194/acp-18-10237-2018
https://doi.org/10.5194/acp-18-10237-2018
Research article
 | 
18 Jul 2018
Research article |  | 18 Jul 2018

High gas-phase mixing ratios of formic and acetic acid in the High Arctic

Emma L. Mungall, Jonathan P. D. Abbatt, Jeremy J. B. Wentzell, Gregory R. Wentworth, Jennifer G. Murphy, Daniel Kunkel, Ellen Gute, David W. Tarasick, Sangeeta Sharma, Christopher J. Cox, Taneil Uttal, and John Liggio

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Cited articles

Aliabadi, A., Staebler, R., de Grandpré, J., Zadra, A., and Vaillancourt, P.: Comparison of estimated atmospheric boundary layer mixing height in the Arctic and Southern Great Plains under statically stable conditions: Experimental and numerical aspects, Atmos.-Ocean, 54, 60–74, https://doi.org/10.1080/07055900.2015.1119100, 2016. a
Anderson, P. S. and Neff, W. D.: Boundary layer physics over snow and ice, Atmos. Chem. Phys., 8, 3563–3582, https://doi.org/10.5194/acp-8-3563-2008, 2008. a, b
Baboukas, E. D., Kanakidou, M., and Mihalopoulos, N.: Carboxylic acids in gas and particulate phase above the Atlantic Ocean, J. Geophys. Res.-Atmos., 105, 14459–14471, https://doi.org/10.1029/1999JD900977, 2000. a, b
Bannan, T. J., Bacak, A., Muller, J. B. A., Booth, A. M., Jones, B., Le Breton, M., Leather, K. E., Ghalaieny, M., Xiao, P., Shallcross, D. E., and Percival, C. J.: Importance of direct anthropogenic emissions of formic acid measured by a chemical ionisation mass spectrometer (CIMS) during the Winter ClearfLo Campaign in London, January 2012, Atmos. Environ., 83, 301–310, https://doi.org/10.1016/j.atmosenv.2013.10.029, 2014. a, b
Barrie, L. A. and Barrie, M. J.: Chemical components of lower tropospheric aerosols in the high Arctic: Six years of observations, J. Atmos. Chem, 11, 211–226, 1990. a
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We measured gas-phase formic and acetic acid at Alert, Nunavut. These acids play an important role in cloud water acidity in remote environments, yet they are not well represented in chemical transport models, particularly in the Arctic. We observed high levels of formic and acetic acid under both cold, wet, and cloudy and warm, sunny, and dry conditions, suggesting that multiple sources significantly contribute to gas-phase concentrations of these species in the summer Arctic.
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