Articles | Volume 13, issue 11
Research article
12 Jun 2013
Research article |  | 12 Jun 2013

Newly observed peroxides and the water effect on the formation and removal of hydroxyalkyl hydroperoxides in the ozonolysis of isoprene

D. Huang, Z. M. Chen, Y. Zhao, and H. Liang

Related authors

Impacts of aerosols on the chemistry of atmospheric trace gases: a case study of peroxides and HO2 radicals
H. Liang, Z. M. Chen, D. Huang, Y. Zhao, and Z. Y. Li
Atmos. Chem. Phys., 13, 11259–11276,,, 2013

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Selective deuteration as a tool for resolving autoxidation mechanisms in α-pinene ozonolysis
Melissa Meder, Otso Peräkylä, Jonathan G. Varelas, Jingyi Luo, Runlong Cai, Yanjun Zhang, Theo Kurtén, Matthieu Riva, Matti Rissanen, Franz M. Geiger, Regan J. Thomson, and Mikael Ehn
Atmos. Chem. Phys., 23, 4373–4390,,, 2023
Short summary
Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation
Philip T. M. Carlsson, Luc Vereecken, Anna Novelli, François Bernard, Steven S. Brown, Bellamy Brownwood, Changmin Cho, John N. Crowley, Patrick Dewald, Peter M. Edwards, Nils Friedrich, Juliane L. Fry, Mattias Hallquist, Luisa Hantschke, Thorsten Hohaus, Sungah Kang, Jonathan Liebmann, Alfred W. Mayhew, Thomas Mentel, David Reimer, Franz Rohrer, Justin Shenolikar, Ralf Tillmann, Epameinondas Tsiligiannis, Rongrong Wu, Andreas Wahner, Astrid Kiendler-Scharr, and Hendrik Fuchs
Atmos. Chem. Phys., 23, 3147–3180,,, 2023
Short summary
Measurement of Henry's law and liquid-phase loss rate constants of peroxypropionic nitric anhydride (PPN) in deionized water and in n-octanol
Kevin D. Easterbrook, Mitchell A. Vona, Kiana Nayebi-Astaneh, Amanda M. Miller, and Hans D. Osthoff
Atmos. Chem. Phys., 23, 311–322,,, 2023
Short summary
Product distribution, kinetics, and aerosol formation from the OH oxidation of dimethyl sulfide under different RO2 regimes
Qing Ye, Matthew B. Goss, Jordan E. Krechmer, Francesca Majluf, Alexander Zaytsev, Yaowei Li, Joseph R. Roscioli, Manjula Canagaratna, Frank N. Keutsch, Colette L. Heald, and Jesse H. Kroll
Atmos. Chem. Phys., 22, 16003–16015,,, 2022
Short summary
Atmospheric breakdown chemistry of the new “green” solvent 2,2,5,5-tetramethyloxolane via gas-phase reactions with OH and Cl radicals
Caterina Mapelli, Juliette V. Schleicher, Alex Hawtin, Conor D. Rankine, Fiona C. Whiting, Fergal Byrne, C. Rob McElroy, Claudiu Roman, Cecilia Arsene, Romeo I. Olariu, Iustinian G. Bejan, and Terry J. Dillon
Atmos. Chem. Phys., 22, 14589–14602,,, 2022
Short summary

Cited articles

Aplincourt, P. and Anglada, J. M.: Theoretical studies of the isoprene ozonolysis under tropospheric conditions. 1. Reaction of substituted carbonyl oxides with water, J. Phys. Chem. A., 107, 5798–5811, 2003a.
Aplincourt, P. and Anglada, J. M.: Theoretical studies of the isoprene ozonolysis under tropospheric conditions. 2. Unimolecular and water-assisted decomposition of the α-hydroxy hydroperoxides, J. Phys. Chem. A., 107, 5812–5820, 2003b.
Ariya, P. A., Sander, R., and Crutzen, P. J.: Significance of HOx and peroxides production due to alkene ozonolysis during the fall and winter: A modeling study, J. Geophys. Res., 105, 17721–17738, 2000.
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103{,} 4605–4683, 2003.
Atkinson, R., Aschmann, S. M., Arey, J., and Shorees, B.: Formation of OH radicals in the gas-phase reactions of O3 with a series of terpenes, J. Geophys. Res., 97D, 6065–6073, 1992.
Final-revised paper