Articles | Volume 19, issue 14
Atmos. Chem. Phys., 19, 9613–9640, 2019
https://doi.org/10.5194/acp-19-9613-2019
Atmos. Chem. Phys., 19, 9613–9640, 2019
https://doi.org/10.5194/acp-19-9613-2019
Research article
31 Jul 2019
Research article | 31 Jul 2019

A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol

Kelvin H. Bates and Daniel J. Jacob

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Cited articles

Aiken, A. C., DeCarlo, P. F., Kroll, J. H., Worsnop, D. R., Huffman, J. A., Docherty, K. S., Ulbrich, I. M., Mohr, C., Kimmel, J. R., Sueper, D., Sun, Y., Zhang, Q., Trimborn, A., Northway, M., Ziemann, P. J., Canagaratna, M. R., Onasch, T. B., Alfarra, M. R., Prevot, A. S. H., Dommen, J., Duplissy, J., Metzger, A., Baltensperger, U., and Jimenez, J. L.: O/C and OM/OC ratios of primary, secondary, and ambient organic aerosols with high-resolution time-of-flight aerosol mass spectrometry, Environ. Sci. Technol., 42, 4478–4485, https://doi.org/10.1021/es703009q, 2008. a
Allen, H. M., Crounse, J. D., Bates, K. H., Teng, A. P., Krawiec-Thayer, M. P., Rivera-Rios, J. C., Keutsch, F. N., St. Clair, J. M., Hanisco, T. F., Möller, K. H., Kjaergaard, H. G., and Wennberg, P. O.: Kinetics and product yields of the OH initiated oxidation of hydroxymethyl hydroperoxide, J. Phys. Chem. A, 122, 6292–6302, https://doi.org/10.1021/acs.jpca.8b04577, 2018. a
Alvarado, L. M. A., Richter, A., Vrekoussis, M., Wittrock, F., Hilboll, A., Schreier, S. F., and Burrows, J. P.: An improved glyoxal retrieval from OMI measurements, Atmos. Meas. Tech., 7, 4133–4150, https://doi.org/10.5194/amt-7-4133-2014, 2014. a
Archibald, A. T., Cooke, M. C., Utembe, S. R., Shallcross, D. E., Derwent, R. G., and Jenkin, M. E.: Impacts of mechanistic changes on HOx formation and recycling in the oxidation of isoprene, Atmos. Chem. Phys., 10, 8097–8118, https://doi.org/10.5194/acp-10-8097-2010, 2010. a, b
Atkinson, R., Aschmann, S. M., Tuazon, E. C., Arey, J., and Zielinska, B.: Formation of 3-Methylfuran from the gas-phase reaction of OH radicals with isoprene and the rate constant for its reaction with the OH radical, Int. J. Chem. Kinet., 21, 593–604, https://doi.org/10.1002/kin.550210709, 1989. a
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Short summary
Isoprene is a highly reactive chemical released to the atmosphere by plants. Its gas-phase reactions and interactions with chemicals released by human activity have far-reaching atmospheric consequences, contributing to ozone and particulate pollution and prolonging the lifetime of methane, a potent greenhouse gas. We use global simulations with a new isoprene reaction scheme to quantify those effects and to show how recently discovered aspects of isoprene chemistry play out on a global scale.
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