Research article
31 Jul 2019
Research article
| 31 Jul 2019
A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol
Kelvin H. Bates and Daniel J. Jacob
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Cited
59 citations as recorded by crossref.
- Nocturnal survival of isoprene linked to formation of upper tropospheric organic aerosol P. Palmer et al. 10.1126/science.abg4506
- Atmospheric Autoxidation of Amines K. Møller et al. 10.1021/acs.est.0c03937
- Changes to simulated global atmospheric composition resulting from recent revisions to isoprene oxidation chemistry M. Khan et al. 10.1016/j.atmosenv.2020.117914
- Effects of heterogeneous reactions on tropospheric chemistry: a global simulation with the chemistry–climate model CHASER V4.0 P. Ha et al. 10.5194/gmd-14-3813-2021
- Next‐Generation Isoprene Measurements From Space: Detecting Daily Variability at High Resolution K. Wells et al. 10.1029/2021JD036181
- Influence of conducive weather on ozone in the presence of reduced NOx emissions: A case study in Chicago during the 2020 lockdowns P. Jing & D. Goldberg 10.1016/j.apr.2021.101313
- Tropospheric Ozone Assessment Report A. Archibald et al. 10.1525/elementa.2020.034
- Can Isoprene Oxidation Explain High Concentrations of Atmospheric Formic and Acetic Acid over Forests? M. Link et al. 10.1021/acsearthspacechem.0c00010
- Biogenic secondary organic aerosols: A review on formation mechanism, analytical challenges and environmental impacts M. Mahilang et al. 10.1016/j.chemosphere.2020.127771
- A machine-learning-guided adaptive algorithm to reduce the computational cost of integrating kinetics in global atmospheric chemistry models: application to GEOS-Chem versions 12.0.0 and 12.9.1 L. Shen et al. 10.5194/gmd-15-1677-2022
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) P. Dewald et al. 10.5194/amt-14-5501-2021
- Measurement report: Vertical distribution of biogenic and anthropogenic secondary organic aerosols in the urban boundary layer over Beijing during late summer H. Ren et al. 10.5194/acp-21-12949-2021
- Ground-Based Atmospheric Measurements of CO:CO2 Ratios in Eastern Highland Rim Using a CO Tracer Technique L. Gamage et al. 10.1021/acsearthspacechem.9b00322
- A perspective on the development of gas-phase chemical mechanisms for Eulerian air quality models W. Stockwell et al. 10.1080/10962247.2019.1694605
- Photochemical environment over Southeast Asia primed for hazardous ozone levels with influx of nitrogen oxides from seasonal biomass burning M. Marvin et al. 10.5194/acp-21-1917-2021
- Stereoselectivity in Atmospheric Autoxidation K. Møller et al. 10.1021/acs.jpclett.9b01972
- Observational Insights into Isoprene Secondary Organic Aerosol Formation through the Epoxide Pathway at Three Urban Sites from Northern to Southern China Y. Zhang et al. 10.1021/acs.est.1c06974
- A Near-Explicit Mechanistic Evaluation of Isoprene Photochemical Secondary Organic Aerosol Formation and Evolution: Simulations of Multiple Chamber Experiments with and without Added NOx J. Thornton et al. 10.1021/acsearthspacechem.0c00118
- Large contribution to secondary organic aerosol from isoprene cloud chemistry H. Lamkaddam et al. 10.1126/sciadv.abe2952
- The Multi-Scale Infrastructure for Chemistry and Aerosols (MUSICA) G. Pfister et al. 10.1175/BAMS-D-19-0331.1
- Recyclable MFe2O4 (M = Mn, Zn, Cu, Ni, Co) coupled micro–nano bubbles for simultaneous catalytic oxidation to remove NOx and SO2 in flue gas H. Sun & D. Li 10.1039/D0RA04392C
- Isoprene Reactivity on Water Surfaces from ab initio QM/MM Molecular Dynamics Simulations M. Martins‐Costa & M. Ruiz‐López 10.1002/cphc.202000652
- Description of the NASA GEOS Composition Forecast Modeling System GEOS‐CF v1.0 C. Keller et al. 10.1029/2020MS002413
- The fuel of atmospheric chemistry: Toward a complete description of reactive organic carbon C. Heald & J. Kroll 10.1126/sciadv.aay8967
- Total OH reactivity over the Amazon rainforest: variability with temperature, wind, rain, altitude, time of day, season, and an overall budget closure E. Pfannerstill et al. 10.5194/acp-21-6231-2021
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-20-3333-2020
- Field observational constraints on the controllers in glyoxal (CHOCHO) reactive uptake to aerosol D. Kim et al. 10.5194/acp-22-805-2022
- Aqueous Photochemistry of 2-Methyltetrol and Erythritol as Sources of Formic Acid and Acetic Acid in the Atmosphere J. Cope et al. 10.1021/acsearthspacechem.1c00107
- Emissions, chemistry or bidirectional surface transfer? Gas phase formic acid dynamics in the atmosphere Z. Gao et al. 10.1016/j.atmosenv.2022.118995
- Rapid hydrolysis of tertiary isoprene nitrate efficiently removes NO x from the atmosphere K. Vasquez et al. 10.1073/pnas.2017442117
- Improvements to the representation of BVOC chemistry–climate interactions in UKCA (v11.5) with the CRI-Strat 2 mechanism: incorporation and evaluation J. Weber et al. 10.5194/gmd-14-5239-2021
- Satellite isoprene retrievals constrain emissions and atmospheric oxidation K. Wells et al. 10.1038/s41586-020-2664-3
- Multifunctional Products of Isoprene Oxidation in Polluted Atmosphere and Their Contribution to SOA Z. Xu et al. 10.1029/2020GL089276
- Catalytic role of formaldehyde in particulate matter formation E. Dovrou et al. 10.1073/pnas.2113265119
- High productivity in hybrid-poplar plantations without isoprene emission to the atmosphere R. Monson et al. 10.1073/pnas.1912327117
- Biogenic volatile organic compound ambient mixing ratios and emission rates in the Alaskan Arctic tundra H. Angot et al. 10.5194/bg-17-6219-2020
- Global Atmospheric Budget of Acetone: Air‐Sea Exchange and the Contribution to Hydroxyl Radicals S. Wang et al. 10.1029/2020JD032553
- Chemical characterization and stable nitrogen isotope composition of nitrogenous component of ambient aerosols from Kanpur in the Indo-Gangetic Plains G. Singh et al. 10.1016/j.scitotenv.2020.143032
- The Global Budget of Atmospheric Methanol: New Constraints on Secondary, Oceanic, and Terrestrial Sources K. Bates et al. 10.1029/2020JD033439
- Spatio-temporal characterization of tropospheric ozone and its precursor pollutants NO2 and HCHO over South Asia U. Baruah et al. 10.1016/j.scitotenv.2021.151135
- Thermalized Epoxide Formation in the Atmosphere K. Møller et al. 10.1021/acs.jpca.9b09364
- The GFDL Global Atmospheric Chemistry‐Climate Model AM4.1: Model Description and Simulation Characteristics L. Horowitz et al. 10.1029/2019MS002032
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
- Atmospheric formaldehyde at El Teide and Pic du Midi remote high-altitude sites C. Prados-Roman et al. 10.1016/j.atmosenv.2020.117618
- A Graph Theoretical Intercomparison of Atmospheric Chemical Mechanisms S. Silva et al. 10.1029/2020GL090481
- Gas-Phase Oxidation Rates and Products of 1,2-Dihydroxy Isoprene K. Bates et al. 10.1021/acs.est.1c04177
- Tight Coupling of Surface and In-Plant Biochemistry and Convection Governs Key Fine Particulate Components over the Amazon Rainforest M. Shrivastava et al. 10.1021/acsearthspacechem.1c00356
- Chemical characterization of secondary organic aerosol at a rural site in the southeastern US: insights from simultaneous high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and FIGAERO chemical ionization mass spectrometer (CIMS) measurements Y. Chen et al. 10.5194/acp-20-8421-2020
- Second-Order Kinetic Rate Coefficients for the Aqueous-Phase Hydroxyl Radical (OH) Oxidation of Isoprene-Derived Secondary Organic Aerosol Compounds at 298 K K. Abellar et al. 10.1021/acs.est.1c04606
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- FORest Canopy Atmosphere Transfer (FORCAsT) 2.0: model updates and evaluation with observations at a mixed forest site D. Wei et al. 10.5194/gmd-14-6309-2021
- Low molecular weight dicarboxylic acids, oxocarboxylic acids and α-dicarbonyls as ozonolysis products of isoprene: Implication for the gaseous-phase formation of secondary organic aerosols S. Bikkina et al. 10.1016/j.scitotenv.2020.144472
- Direct retrieval of isoprene from satellite-based infrared measurements D. Fu et al. 10.1038/s41467-019-11835-0
- Chemistry of Simple Organic Peroxy Radicals under Atmospheric through Combustion Conditions: Role of Temperature, Pressure, and NOx Level M. Goldman et al. 10.1021/acs.jpca.1c07203
- Reconciling Observed and Predicted Tropical Rainforest OH Concentrations D. Jeong et al. 10.1029/2020JD032901
- The GFDL Earth System Model Version 4.1 (GFDL‐ESM 4.1): Overall Coupled Model Description and Simulation Characteristics J. Dunne et al. 10.1029/2019MS002015
- A simplified parameterization of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) for global chemistry and climate models: a case study with GEOS-Chem v11-02-rc D. Jo et al. 10.5194/gmd-12-2983-2019
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
57 citations as recorded by crossref.
- Nocturnal survival of isoprene linked to formation of upper tropospheric organic aerosol P. Palmer et al. 10.1126/science.abg4506
- Atmospheric Autoxidation of Amines K. Møller et al. 10.1021/acs.est.0c03937
- Changes to simulated global atmospheric composition resulting from recent revisions to isoprene oxidation chemistry M. Khan et al. 10.1016/j.atmosenv.2020.117914
- Effects of heterogeneous reactions on tropospheric chemistry: a global simulation with the chemistry–climate model CHASER V4.0 P. Ha et al. 10.5194/gmd-14-3813-2021
- Next‐Generation Isoprene Measurements From Space: Detecting Daily Variability at High Resolution K. Wells et al. 10.1029/2021JD036181
- Influence of conducive weather on ozone in the presence of reduced NOx emissions: A case study in Chicago during the 2020 lockdowns P. Jing & D. Goldberg 10.1016/j.apr.2021.101313
- Tropospheric Ozone Assessment Report A. Archibald et al. 10.1525/elementa.2020.034
- Can Isoprene Oxidation Explain High Concentrations of Atmospheric Formic and Acetic Acid over Forests? M. Link et al. 10.1021/acsearthspacechem.0c00010
- Biogenic secondary organic aerosols: A review on formation mechanism, analytical challenges and environmental impacts M. Mahilang et al. 10.1016/j.chemosphere.2020.127771
- A machine-learning-guided adaptive algorithm to reduce the computational cost of integrating kinetics in global atmospheric chemistry models: application to GEOS-Chem versions 12.0.0 and 12.9.1 L. Shen et al. 10.5194/gmd-15-1677-2022
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) P. Dewald et al. 10.5194/amt-14-5501-2021
- Measurement report: Vertical distribution of biogenic and anthropogenic secondary organic aerosols in the urban boundary layer over Beijing during late summer H. Ren et al. 10.5194/acp-21-12949-2021
- Ground-Based Atmospheric Measurements of CO:CO2 Ratios in Eastern Highland Rim Using a CO Tracer Technique L. Gamage et al. 10.1021/acsearthspacechem.9b00322
- A perspective on the development of gas-phase chemical mechanisms for Eulerian air quality models W. Stockwell et al. 10.1080/10962247.2019.1694605
- Photochemical environment over Southeast Asia primed for hazardous ozone levels with influx of nitrogen oxides from seasonal biomass burning M. Marvin et al. 10.5194/acp-21-1917-2021
- Stereoselectivity in Atmospheric Autoxidation K. Møller et al. 10.1021/acs.jpclett.9b01972
- Observational Insights into Isoprene Secondary Organic Aerosol Formation through the Epoxide Pathway at Three Urban Sites from Northern to Southern China Y. Zhang et al. 10.1021/acs.est.1c06974
- A Near-Explicit Mechanistic Evaluation of Isoprene Photochemical Secondary Organic Aerosol Formation and Evolution: Simulations of Multiple Chamber Experiments with and without Added NOx J. Thornton et al. 10.1021/acsearthspacechem.0c00118
- Large contribution to secondary organic aerosol from isoprene cloud chemistry H. Lamkaddam et al. 10.1126/sciadv.abe2952
- The Multi-Scale Infrastructure for Chemistry and Aerosols (MUSICA) G. Pfister et al. 10.1175/BAMS-D-19-0331.1
- Recyclable MFe2O4 (M = Mn, Zn, Cu, Ni, Co) coupled micro–nano bubbles for simultaneous catalytic oxidation to remove NOx and SO2 in flue gas H. Sun & D. Li 10.1039/D0RA04392C
- Isoprene Reactivity on Water Surfaces from ab initio QM/MM Molecular Dynamics Simulations M. Martins‐Costa & M. Ruiz‐López 10.1002/cphc.202000652
- Description of the NASA GEOS Composition Forecast Modeling System GEOS‐CF v1.0 C. Keller et al. 10.1029/2020MS002413
- The fuel of atmospheric chemistry: Toward a complete description of reactive organic carbon C. Heald & J. Kroll 10.1126/sciadv.aay8967
- Total OH reactivity over the Amazon rainforest: variability with temperature, wind, rain, altitude, time of day, season, and an overall budget closure E. Pfannerstill et al. 10.5194/acp-21-6231-2021
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-20-3333-2020
- Field observational constraints on the controllers in glyoxal (CHOCHO) reactive uptake to aerosol D. Kim et al. 10.5194/acp-22-805-2022
- Aqueous Photochemistry of 2-Methyltetrol and Erythritol as Sources of Formic Acid and Acetic Acid in the Atmosphere J. Cope et al. 10.1021/acsearthspacechem.1c00107
- Emissions, chemistry or bidirectional surface transfer? Gas phase formic acid dynamics in the atmosphere Z. Gao et al. 10.1016/j.atmosenv.2022.118995
- Rapid hydrolysis of tertiary isoprene nitrate efficiently removes NO x from the atmosphere K. Vasquez et al. 10.1073/pnas.2017442117
- Improvements to the representation of BVOC chemistry–climate interactions in UKCA (v11.5) with the CRI-Strat 2 mechanism: incorporation and evaluation J. Weber et al. 10.5194/gmd-14-5239-2021
- Satellite isoprene retrievals constrain emissions and atmospheric oxidation K. Wells et al. 10.1038/s41586-020-2664-3
- Multifunctional Products of Isoprene Oxidation in Polluted Atmosphere and Their Contribution to SOA Z. Xu et al. 10.1029/2020GL089276
- Catalytic role of formaldehyde in particulate matter formation E. Dovrou et al. 10.1073/pnas.2113265119
- High productivity in hybrid-poplar plantations without isoprene emission to the atmosphere R. Monson et al. 10.1073/pnas.1912327117
- Biogenic volatile organic compound ambient mixing ratios and emission rates in the Alaskan Arctic tundra H. Angot et al. 10.5194/bg-17-6219-2020
- Global Atmospheric Budget of Acetone: Air‐Sea Exchange and the Contribution to Hydroxyl Radicals S. Wang et al. 10.1029/2020JD032553
- Chemical characterization and stable nitrogen isotope composition of nitrogenous component of ambient aerosols from Kanpur in the Indo-Gangetic Plains G. Singh et al. 10.1016/j.scitotenv.2020.143032
- The Global Budget of Atmospheric Methanol: New Constraints on Secondary, Oceanic, and Terrestrial Sources K. Bates et al. 10.1029/2020JD033439
- Spatio-temporal characterization of tropospheric ozone and its precursor pollutants NO2 and HCHO over South Asia U. Baruah et al. 10.1016/j.scitotenv.2021.151135
- Thermalized Epoxide Formation in the Atmosphere K. Møller et al. 10.1021/acs.jpca.9b09364
- The GFDL Global Atmospheric Chemistry‐Climate Model AM4.1: Model Description and Simulation Characteristics L. Horowitz et al. 10.1029/2019MS002032
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
- Atmospheric formaldehyde at El Teide and Pic du Midi remote high-altitude sites C. Prados-Roman et al. 10.1016/j.atmosenv.2020.117618
- A Graph Theoretical Intercomparison of Atmospheric Chemical Mechanisms S. Silva et al. 10.1029/2020GL090481
- Gas-Phase Oxidation Rates and Products of 1,2-Dihydroxy Isoprene K. Bates et al. 10.1021/acs.est.1c04177
- Tight Coupling of Surface and In-Plant Biochemistry and Convection Governs Key Fine Particulate Components over the Amazon Rainforest M. Shrivastava et al. 10.1021/acsearthspacechem.1c00356
- Chemical characterization of secondary organic aerosol at a rural site in the southeastern US: insights from simultaneous high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and FIGAERO chemical ionization mass spectrometer (CIMS) measurements Y. Chen et al. 10.5194/acp-20-8421-2020
- Second-Order Kinetic Rate Coefficients for the Aqueous-Phase Hydroxyl Radical (OH) Oxidation of Isoprene-Derived Secondary Organic Aerosol Compounds at 298 K K. Abellar et al. 10.1021/acs.est.1c04606
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- FORest Canopy Atmosphere Transfer (FORCAsT) 2.0: model updates and evaluation with observations at a mixed forest site D. Wei et al. 10.5194/gmd-14-6309-2021
- Low molecular weight dicarboxylic acids, oxocarboxylic acids and α-dicarbonyls as ozonolysis products of isoprene: Implication for the gaseous-phase formation of secondary organic aerosols S. Bikkina et al. 10.1016/j.scitotenv.2020.144472
- Direct retrieval of isoprene from satellite-based infrared measurements D. Fu et al. 10.1038/s41467-019-11835-0
- Chemistry of Simple Organic Peroxy Radicals under Atmospheric through Combustion Conditions: Role of Temperature, Pressure, and NOx Level M. Goldman et al. 10.1021/acs.jpca.1c07203
- Reconciling Observed and Predicted Tropical Rainforest OH Concentrations D. Jeong et al. 10.1029/2020JD032901
- The GFDL Earth System Model Version 4.1 (GFDL‐ESM 4.1): Overall Coupled Model Description and Simulation Characteristics J. Dunne et al. 10.1029/2019MS002015
2 citations as recorded by crossref.
- A simplified parameterization of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) for global chemistry and climate models: a case study with GEOS-Chem v11-02-rc D. Jo et al. 10.5194/gmd-12-2983-2019
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
Latest update: 20 May 2022
Short summary
Isoprene is a highly reactive chemical released to the atmosphere by plants. Its gas-phase reactions and interactions with chemicals released by human activity have far-reaching atmospheric consequences, contributing to ozone and particulate pollution and prolonging the lifetime of methane, a potent greenhouse gas. We use global simulations with a new isoprene reaction scheme to quantify those effects and to show how recently discovered aspects of isoprene chemistry play out on a global scale.
Isoprene is a highly reactive chemical released to the atmosphere by plants. Its gas-phase...
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