Articles | Volume 18, issue 12
https://doi.org/10.5194/acp-18-8621-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-8621-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Jun 2018
Research article |
| 20 Jun 2018
| 20 Jun 2018
BAERLIN2014 – stationary measurements and source apportionment at an urban background station in Berlin, Germany
Erika von Schneidemesser
CORRESPONDING AUTHOR
Institute for Advanced Sustainability Studies (IASS), 14467 Potsdam,
Germany
Boris Bonn
Institute for Advanced Sustainability Studies (IASS), 14467 Potsdam,
Germany
now at: Institute of Forest Sciences,
Albert-Ludwig Universität, 79110 Freiburg, Germany
Tim M. Butler
Institute for Advanced Sustainability Studies (IASS), 14467 Potsdam,
Germany
Christian Ehlers
IEK-8, Research Centre Jülich, 52425 Jülich, Germany
now at: Fachbereich 42: Kontinuierliches
Luftqualitätsmessnetz, Landesamt für Natur, Umwelt und
Verbraucherschutz NRW, 45133 Essen, Germany
Holger Gerwig
Division Environmental Health and Protection of Ecosystems, German
Environment Agency, 06844 Dessau-Roßlau, Germany
Hannele Hakola
Finnish Meteorological Institute, 00560 Helsinki, Finland
Heidi Hellén
Finnish Meteorological Institute, 00560 Helsinki, Finland
Andreas Kerschbaumer
Senate Department for the Environment, Transport and Climate
Protection, 10179 Berlin, Germany
Dieter Klemp
IEK-8, Research Centre Jülich, 52425 Jülich, Germany
Claudia Kofahl
IEK-8, Research Centre Jülich, 52425 Jülich, Germany
now at: Institut für Physikalische Chemie,
Georg-August-Universität, 37077 Göttingen, Germany
Jürgen Kura
Division Environmental Health and Protection of Ecosystems, German
Environment Agency, 06844 Dessau-Roßlau, Germany
Anja Lüdecke
Division Environmental Health and Protection of Ecosystems, German
Environment Agency, 06844 Dessau-Roßlau, Germany
Rainer Nothard
Senate Department for the Environment, Transport and Climate
Protection, 10179 Berlin, Germany
Axel Pietsch
Division Environmental Health and Protection of Ecosystems, German
Environment Agency, 06844 Dessau-Roßlau, Germany
Jörn Quedenau
Institute for Advanced Sustainability Studies (IASS), 14467 Potsdam,
Germany
Klaus Schäfer
Institute of Meteorology and Climate Research, Atmospheric
Environmental Research (IMK-IFU), Karlsruhe Institute of Technology (KIT),
82467 Garmisch-Partenkirchen, Germany
James J. Schauer
Environmental Chemistry and Technology Program, University of
Wisconsin-Madison, Madison 53705, WI, USA
Ashish Singh
Institute for Advanced Sustainability Studies (IASS), 14467 Potsdam,
Germany
Ana-Maria Villalobos
Environmental Chemistry and Technology Program, University of
Wisconsin-Madison, Madison 53705, WI, USA
Matthias Wiegner
Meteorological Institute, Ludwig-Maximilians-Universität, 80333
Munich, Germany
Mark G. Lawrence
Institute for Advanced Sustainability Studies (IASS), 14467 Potsdam,
Germany
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Aurelia Lupaşcu, Noelia Otero, Andrea Minkos, and Tim Butler
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Ground-level ozone is an important air pollutant that affects human health, ecosystems, and climate. Ozone is not emitted directly but rather formed in the atmosphere through chemical reactions involving two distinct precursors. Our results provide detailed information about the origin of ozone in Germany during two peak ozone events that took place in 2015 and 2018, thus improving our understanding of ground-level ozone.
Hannele Hakola, Ditte Taipale, Arnaud Praplan, Simon Schallhart, Steven Thomas, Toni Tykkä, Aku Helin, Jaana Bäck, and Heidi Hellén
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-478, https://doi.org/10.5194/acp-2022-478, 2022
Revised manuscript not accepted
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Norway spruce is one of the main tree species growing in the boreal area. We show that volatile organic compound emission potentials and compound composition vary a lot. We have investigated if e.g. growing location or age of a tree could explain the variations. Recognizing this observed large variability in spruce BVOC emissions (precursors for new particle formation processes), we also tested the consequences of this variability in simulations of aerosol formation.
Ajit Ahlawat, Kay Weinhold, Jesus Marval, Paolo Tronville, Ari Leskinen, Mika Komppula, Holger Gerwig, Lars Gerling, Stephan Weber, Rikke Bramming Jørgensen, Thomas Nørregaard Jensen, Marouane Merizak, Ulrich Vogt, Carla Ribalta, Mar Viana, Andre Schmitz, Maria Chiesa, Giacomo Gerosa, Lothar Keck, Markus Pesch, Gerhard Steiner, Thomas Krinke, Torsten Tritscher, Wolfram Birmili, and Alfred Wiedensohler
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2022-155, https://doi.org/10.5194/amt-2022-155, 2022
Revised manuscript not accepted
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Measurements of ultrafine particles must be done with quality-assured instruments. The performance of portable instruments such as NanoScan SMPS, and GRIMM Mini WRAS spectrometer measuring the particle number size distribution in the range from 10 to 200 nm were investigated. The influence of different aerosol types and maintenance activities on these instruments were explored. The results show that these portable instruments are suitable for mobile UFP measurements for source identification.
Ranjeet S. Sokhi, Nicolas Moussiopoulos, Alexander Baklanov, John Bartzis, Isabelle Coll, Sandro Finardi, Rainer Friedrich, Camilla Geels, Tiia Grönholm, Tomas Halenka, Matthias Ketzel, Androniki Maragkidou, Volker Matthias, Jana Moldanova, Leonidas Ntziachristos, Klaus Schäfer, Peter Suppan, George Tsegas, Greg Carmichael, Vicente Franco, Steve Hanna, Jukka-Pekka Jalkanen, Guus J. M. Velders, and Jaakko Kukkonen
Atmos. Chem. Phys., 22, 4615–4703, https://doi.org/10.5194/acp-22-4615-2022, https://doi.org/10.5194/acp-22-4615-2022, 2022
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This review of air quality research focuses on developments over the past decade. The article considers current and future challenges that are important from air quality research and policy perspectives and highlights emerging prominent gaps of knowledge. The review also examines how air pollution management needs to adapt to new challenges and makes recommendations to guide the direction for future air quality research within the wider community and to provide support for policy.
Huiming Lin, Yindong Tong, Chenghao Yu, Long Chen, Xiufeng Yin, Qianggong Zhang, Shichang Kang, Lun Luo, James Schauer, Benjamin de Foy, and Xuejun Wang
Atmos. Chem. Phys., 22, 2651–2668, https://doi.org/10.5194/acp-22-2651-2022, https://doi.org/10.5194/acp-22-2651-2022, 2022
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The Tibetan Plateau is known as
The Third Poleand is generally considered to be a clean area owing to its high altitude. However, it may receive be impacted by air pollutants transported from the Indian subcontinent. Pollutants generally enter the Tibetan Plateau in several ways. Among them is the Yarlung Zangbu–Brahmaputra Grand Canyon. In this study, we identified the influence of the Indian summer monsoon on the origin, transport, and behavior of mercury in this area.
Noelia Otero, Oscar E. Jurado, Tim Butler, and Henning W. Rust
Atmos. Chem. Phys., 22, 1905–1919, https://doi.org/10.5194/acp-22-1905-2022, https://doi.org/10.5194/acp-22-1905-2022, 2022
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Surface ozone and temperature are strongly dependent and their extremes might be exacerbated by underlying climatological drivers, such as atmospheric blocking. Using an observational data set, we measure the dependence structure between ozone and temperature under the influence of atmospheric blocking. Blocks enhanced the probability of occurrence of compound ozone and temperature extremes over northwestern and central Europe, leading to greater health risks.
Seán Schmitz, Sherry Towers, Guillermo Villena, Alexandre Caseiro, Robert Wegener, Dieter Klemp, Ines Langer, Fred Meier, and Erika von Schneidemesser
Atmos. Meas. Tech., 14, 7221–7241, https://doi.org/10.5194/amt-14-7221-2021, https://doi.org/10.5194/amt-14-7221-2021, 2021
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The last 2 decades have seen substantial technological advances in the development of low-cost air pollution instruments. This study introduces a seven-step methodology for the field calibration of low-cost sensors with user-friendly guidelines, open-access code, and a discussion of common barriers. Our goal with this work is to push for standardized reporting of methods, make critical data processing steps clear for users, and encourage responsible use in the scientific community and beyond.
Stefano Galmarini, Paul Makar, Olivia E. Clifton, Christian Hogrefe, Jesse O. Bash, Roberto Bellasio, Roberto Bianconi, Johannes Bieser, Tim Butler, Jason Ducker, Johannes Flemming, Alma Hodzic, Christopher D. Holmes, Ioannis Kioutsioukis, Richard Kranenburg, Aurelia Lupascu, Juan Luis Perez-Camanyo, Jonathan Pleim, Young-Hee Ryu, Roberto San Jose, Donna Schwede, Sam Silva, and Ralf Wolke
Atmos. Chem. Phys., 21, 15663–15697, https://doi.org/10.5194/acp-21-15663-2021, https://doi.org/10.5194/acp-21-15663-2021, 2021
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This technical note presents the research protocols for phase 4 of the Air Quality Model Evaluation International Initiative (AQMEII4). This initiative has three goals: (i) to define the state of wet and dry deposition in regional models, (ii) to evaluate how dry deposition influences air concentration and flux predictions, and (iii) to identify the causes for prediction differences. The evaluation compares LULC-specific dry deposition and effective conductances and fluxes.
Yang Liu, Simon Schallhart, Ditte Taipale, Toni Tykkä, Matti Räsänen, Lutz Merbold, Heidi Hellén, and Petri Pellikka
Atmos. Chem. Phys., 21, 14761–14787, https://doi.org/10.5194/acp-21-14761-2021, https://doi.org/10.5194/acp-21-14761-2021, 2021
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We studied the mixing ratio of biogenic volatile organic compounds (BVOCs) in a humid highland and dry lowland African ecosystem in Kenya. The mixing ratio of monoterpenoids was similar to that measured in the relevant ecosystems in western and southern Africa, while that of isoprene was lower. Modeling the emission factors (EFs) for BVOCs from the lowlands, the EFs for isoprene and β-pinene agreed well with what is assumed in the MEGAN, while those of α-pinene and limonene were higher.
Paul S. Monks, A. R. Ravishankara, Erika von Schneidemesser, and Roberto Sommariva
Atmos. Chem. Phys., 21, 12909–12948, https://doi.org/10.5194/acp-21-12909-2021, https://doi.org/10.5194/acp-21-12909-2021, 2021
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Which published papers have transformed our understanding of the chemical processes in the troposphere and shaped the field of atmospheric chemistry? We explore how these papers have shaped the development of the field of atmospheric chemistry and identify the major landmarks in the field of atmospheric chemistry through the lens of those papers' impact on science, legislation and environmental events.
Edward C. Chan and Timothy M. Butler
Geosci. Model Dev., 14, 4555–4572, https://doi.org/10.5194/gmd-14-4555-2021, https://doi.org/10.5194/gmd-14-4555-2021, 2021
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A large-eddy simulation based chemical transport model is implemented for an idealized street canyon. The dynamics of the model are evaluated using stationary measurements. A transient model run is also conducted over a 24 h period, where variations of pollutant concentrations indicate dependence on emissions, background concentrations, and solar state. Comparison stationary model runs show changes in flow structure concentrations.
Heidi Hellén, Arnaud P. Praplan, Toni Tykkä, Aku Helin, Simon Schallhart, Piia P. Schiestl-Aalto, Jaana Bäck, and Hannele Hakola
Atmos. Chem. Phys., 21, 8045–8066, https://doi.org/10.5194/acp-21-8045-2021, https://doi.org/10.5194/acp-21-8045-2021, 2021
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Even though terpene emissions of boreal needle trees have been studied quite intensively, there is less knowledge of the emissions of broadleaved deciduous trees and emissions of larger terpenes and oxygenated volatile organic compounds. Here we studied downy birch (Betula pubescens) emissions, and especially sesquiterpene and oxygenated sesquiterpene emissions were found to be high. These emissions may have significant effects on secondary organic aerosol formation in boreal areas.
Elena Macdonald, Noelia Otero, and Tim Butler
Atmos. Chem. Phys., 21, 4007–4023, https://doi.org/10.5194/acp-21-4007-2021, https://doi.org/10.5194/acp-21-4007-2021, 2021
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NO2 limit values are still regularly exceeded in many European cities despite decreasing emissions. Measurements of NOx concentrations from stations across Europe were systematically analysed to assess long-term changes observed in urban areas. We compared trends in concentration increments to trends in total and traffic emissions to find potential discrepancies. The results can help in evaluating inaccuracies in emission inventories and in improving spatial imbalances in data availability.
Jan-Lukas Tirpitz, Udo Frieß, François Hendrick, Carlos Alberti, Marc Allaart, Arnoud Apituley, Alkis Bais, Steffen Beirle, Stijn Berkhout, Kristof Bognar, Tim Bösch, Ilya Bruchkouski, Alexander Cede, Ka Lok Chan, Mirjam den Hoed, Sebastian Donner, Theano Drosoglou, Caroline Fayt, Martina M. Friedrich, Arnoud Frumau, Lou Gast, Clio Gielen, Laura Gomez-Martín, Nan Hao, Arjan Hensen, Bas Henzing, Christian Hermans, Junli Jin, Karin Kreher, Jonas Kuhn, Johannes Lampel, Ang Li, Cheng Liu, Haoran Liu, Jianzhong Ma, Alexis Merlaud, Enno Peters, Gaia Pinardi, Ankie Piters, Ulrich Platt, Olga Puentedura, Andreas Richter, Stefan Schmitt, Elena Spinei, Deborah Stein Zweers, Kimberly Strong, Daan Swart, Frederik Tack, Martin Tiefengraber, René van der Hoff, Michel van Roozendael, Tim Vlemmix, Jan Vonk, Thomas Wagner, Yang Wang, Zhuoru Wang, Mark Wenig, Matthias Wiegner, Folkard Wittrock, Pinhua Xie, Chengzhi Xing, Jin Xu, Margarita Yela, Chengxin Zhang, and Xiaoyi Zhao
Atmos. Meas. Tech., 14, 1–35, https://doi.org/10.5194/amt-14-1-2021, https://doi.org/10.5194/amt-14-1-2021, 2021
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Multi-axis differential optical absorption spectroscopy (MAX-DOAS) is a ground-based remote sensing measurement technique that derives atmospheric aerosol and trace gas vertical profiles from skylight spectra. In this study, consistency and reliability of MAX-DOAS profiles are assessed by applying nine different evaluation algorithms to spectral data recorded during an intercomparison campaign in the Netherlands and by comparing the results to colocated supporting observations.
Arnaud P. Praplan, Toni Tykkä, Simon Schallhart, Virpi Tarvainen, Jaana Bäck, and Heidi Hellén
Biogeosciences, 17, 4681–4705, https://doi.org/10.5194/bg-17-4681-2020, https://doi.org/10.5194/bg-17-4681-2020, 2020
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In this paper, we study emissions of volatile organic compounds (VOCs) from three boreal tree species. Individual compounds are quantified with on-line separation analytical techniques, while the total reactivity of the emissions is measured using a custom-built instrument. On some occasions, in particular when the trees suffer from stress, the total reactivity measured is higher than the sum of the reactivity of individual compounds. This indicates that the threes emit VOCs that remain unknown.
Tim Butler, Aurelia Lupascu, and Aditya Nalam
Atmos. Chem. Phys., 20, 10707–10731, https://doi.org/10.5194/acp-20-10707-2020, https://doi.org/10.5194/acp-20-10707-2020, 2020
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Ground-level ozone (O3) is not directly emitted; it is formed chemically in the atmosphere. Some ground-level O3 is transported from the stratosphere, but most O3 is produced from reactive precursors that are emitted by both natural and anthropogenic sources. We present the results of a novel source apportionment method for ground-level O3. Our results are consistent with previous work and also provide new insights. In particular, we highlight the roles of methane and international shipping.
Ka Lok Chan, Matthias Wiegner, Jos van Geffen, Isabelle De Smedt, Carlos Alberti, Zhibin Cheng, Sheng Ye, and Mark Wenig
Atmos. Meas. Tech., 13, 4499–4520, https://doi.org/10.5194/amt-13-4499-2020, https://doi.org/10.5194/amt-13-4499-2020, 2020
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The paper presents 2D MAX-DOAS observations of vertical distributions of aerosol extinction, NO2 and HCHO in Munich. The measured surface aerosol extinction coefficients and NO2 mixing ratios are compared to in situ monitoring data. The NO2 and HCHO data are subsequently used to validate satellite measurements. The MAX-DOAS measurements are also used to investigate the spatiotemporal characteristic of NO2 and HCHO in Munich.
Noelia Otero, Henning W. Rust, and Tim Butler
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-691, https://doi.org/10.5194/acp-2020-691, 2020
Revised manuscript not accepted
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Surface ozone concentrations are strongly correlated with temperature in summertime. Using long-term measurements, we investigate changes in the observed relationship between ozone and temperature over Germany. We propose a new statistical approach based on Generalized Additive Models (GAMs) to describe ozone production rates as a function of nitrogen oxides (NOx) and temperature. Our results suggest that NOx reductions alone can not explain the changes in the temperature dependence of ozone.
Aku Helin, Hannele Hakola, and Heidi Hellén
Atmos. Meas. Tech., 13, 3543–3560, https://doi.org/10.5194/amt-13-3543-2020, https://doi.org/10.5194/amt-13-3543-2020, 2020
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A thermal desorption–gas chromatography–mass spectrometry method following sorbent tube sampling was developed for the determination of terpenes in gas-phase samples. The main focus was on the analysis of diterpenes, which have been limited in study in gas-phase samples. The analytical figures of merit were fit for purpose (e.g. quantitation limits <10 pptv and reproducibility <10 % for terpenes). Diterpenes could be detected and identified in emissions from spruce and pine samples.
Jia Sun, Wolfram Birmili, Markus Hermann, Thomas Tuch, Kay Weinhold, Maik Merkel, Fabian Rasch, Thomas Müller, Alexander Schladitz, Susanne Bastian, Gunter Löschau, Josef Cyrys, Jianwei Gu, Harald Flentje, Björn Briel, Christoph Asbach, Heinz Kaminski, Ludwig Ries, Ralf Sohmer, Holger Gerwig, Klaus Wirtz, Frank Meinhardt, Andreas Schwerin, Olaf Bath, Nan Ma, and Alfred Wiedensohler
Atmos. Chem. Phys., 20, 7049–7068, https://doi.org/10.5194/acp-20-7049-2020, https://doi.org/10.5194/acp-20-7049-2020, 2020
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To evaluate the effectiveness of emission mitigation policies, we evaluated the trends of the size-resolved particle number concentrations and equivalent black carbon mass concentration at 16 observational sites for various environments in Germany (2009–2018). Overall, significant decrease trends are found for most of the parameters and sites. This study suggests that a combination of emission mitigation policies can effectively improve the air quality on large spatial scales such as in Germany.
Heidi Hellén, Simon Schallhart, Arnaud P. Praplan, Toni Tykkä, Mika Aurela, Annalea Lohila, and Hannele Hakola
Atmos. Chem. Phys., 20, 7021–7034, https://doi.org/10.5194/acp-20-7021-2020, https://doi.org/10.5194/acp-20-7021-2020, 2020
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We studied biogenic volatile organic compound emissions and their ambient concentrations in a sub-Arctic wetland. Although isoprene was the main terpenoid emitted, sesquiterpene emissions were also highly significant, especially in early summer. Sesquiterpenes have much higher potential to form secondary organic aerosol than isoprenes. High sesquiterpene emissions during early summer suggested that melting snow and thawing soil could be an important source of these compounds.
Matthias Wiegner, Alexander Geiß, Ina Mattis, Fred Meier, and Thomas Ruhtz
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-332, https://doi.org/10.5194/acp-2020-332, 2020
Publication in ACP not foreseen
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We investigated ceilometer signals from 2 testbeds in Munich and Berlin, Germany, with respect to their representativeness. For each testbed data of 24 months from 6 ceilometers were available. Two parameters were discussed: the mixing layer height (MLH) as an indicator for the vertical distribution and the integrated backscatter as a proxy for the amount of aerosols in the mixing layer. We found that only the MLH determined from a single ceilometer is applicable for a whole metropolitan area.
Jaakko Kukkonen, Susana López-Aparicio, David Segersson, Camilla Geels, Leena Kangas, Mari Kauhaniemi, Androniki Maragkidou, Anne Jensen, Timo Assmuth, Ari Karppinen, Mikhail Sofiev, Heidi Hellén, Kari Riikonen, Juha Nikmo, Anu Kousa, Jarkko V. Niemi, Niko Karvosenoja, Gabriela Sousa Santos, Ingrid Sundvor, Ulas Im, Jesper H. Christensen, Ole-Kenneth Nielsen, Marlene S. Plejdrup, Jacob Klenø Nøjgaard, Gunnar Omstedt, Camilla Andersson, Bertil Forsberg, and Jørgen Brandt
Atmos. Chem. Phys., 20, 4333–4365, https://doi.org/10.5194/acp-20-4333-2020, https://doi.org/10.5194/acp-20-4333-2020, 2020
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Residential wood combustion can cause substantial emissions of fine particulate matter and adverse health effects. This study has, for the first time, evaluated the impacts of residential wood combustion in a harmonised manner in four Nordic cities. Wood combustion caused major shares of fine particle concentrations in Oslo (up to 60 %) and Umeå (up to 30 %) and also notable shares in Copenhagen (up to 20 %) and Helsinki (up to 15 %).
Zhuoru Wang, Ka Lok Chan, Klaus-Peter Heue, Adrian Doicu, Thomas Wagner, Robert Holla, and Matthias Wiegner
Atmos. Meas. Tech., 13, 1835–1866, https://doi.org/10.5194/amt-13-1835-2020, https://doi.org/10.5194/amt-13-1835-2020, 2020
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We present a new aerosol profile retrieval algorithm for MAX-DOAS measurements at high-altitude sites and applied to the MAX-DOAS measurements at UFS. The retrieval algorithm is based on a O4 DSCD lookup table which is dedicated to high-altitude MAX-DOAS measurements. The comparison of retrieved aerosol optical depths (AODs) to sun photometer observations shows good agreement with a correlation coefficient (R) of 0.733 and 0.798 at 360 and 477 nm, respectively.
Hans Grob, Claudia Emde, Matthias Wiegner, Meinhard Seefeldner, Linda Forster, and Bernhard Mayer
Atmos. Meas. Tech., 13, 239–258, https://doi.org/10.5194/amt-13-239-2020, https://doi.org/10.5194/amt-13-239-2020, 2020
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Polarimetry has been established as an enhancement to classical photometry in aerosol remote sensing over the past years. We propose a fast and exact radiometric and polarimetric calibration method for polarized photometers. Additionally, a technique for correcting an alt-azimuthal mount is introduced.
These methods are applied to measurements obtained with our SSARA instrument during the A-LIFE field campaign. For 2 d, the data are subjected to an inversion of aerosol optical properties.
Marja Hemmilä, Ulla Makkonen, Aki Virkkula, Georgia Panagiotopoulou, Juho Aalto, Markku Kulmala, Tuukka Petäjä, Hannele Hakola, and Heidi Hellén
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-1157, https://doi.org/10.5194/acp-2019-1157, 2020
Publication in ACP not foreseen
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Amines are atmospheric bases, which can affect to nucleation of aerosols. Lately, a computational study showed that guanidine could be even more effective to stabilize sulphuric acid clusters. In this paper we used a a dynamic flow-through chamber with an online ion chromatograph MARGA coupled with a mass spectrometer (MARGA-MS). We studied amine and guanidine emission from a boreal forest floor in Finland, and find out, that the boreal forest floor is a source of amines and guanidine.
Boris Bonn, Ruth-Kristina Magh, Joseph Rombach, and Jürgen Kreuzwieser
Biogeosciences, 16, 4627–4645, https://doi.org/10.5194/bg-16-4627-2019, https://doi.org/10.5194/bg-16-4627-2019, 2019
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The effect of soil water availability (SWA) on emissions of isoprenoids by trees was studied by setting up a parameterization from published data. SWA impact on isoprene emissions can be described by a growth type curve, while monoterpene emissions display a pattern reflecting plants’ stomata opening. Sesquiterpene fluxes tend to increase at the start of severe drought until resources decline. Feedbacks on atmospheric processes such as ozone and aerosol particles are further studied.
Aurelia Lupaşcu and Tim Butler
Atmos. Chem. Phys., 19, 14535–14558, https://doi.org/10.5194/acp-19-14535-2019, https://doi.org/10.5194/acp-19-14535-2019, 2019
Carlos Toledano, Benjamín Torres, Cristian Velasco-Merino, Dietrich Althausen, Silke Groß, Matthias Wiegner, Bernadett Weinzierl, Josef Gasteiger, Albert Ansmann, Ramiro González, David Mateos, David Farrel, Thomas Müller, Moritz Haarig, and Victoria E. Cachorro
Atmos. Chem. Phys., 19, 14571–14583, https://doi.org/10.5194/acp-19-14571-2019, https://doi.org/10.5194/acp-19-14571-2019, 2019
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Ground-based sun photometers have been used to analyze the properties of long-range transported Saharan dust over Barbados. The measurements were carried out as part of the Saharan Aerosol Long-Range Transport and Aerosol–Cloud-Interaction Experiment (SALTRACE), carried out in the Caribbean in 2013. A variety of instruments, ground-based and airborne, were used in this research. In this paper, the sun photometer data are presented and related to data collected from other co-located instruments.
Arnaud P. Praplan, Toni Tykkä, Dean Chen, Michael Boy, Ditte Taipale, Ville Vakkari, Putian Zhou, Tuukka Petäjä, and Heidi Hellén
Atmos. Chem. Phys., 19, 14431–14453, https://doi.org/10.5194/acp-19-14431-2019, https://doi.org/10.5194/acp-19-14431-2019, 2019
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Our study shows that, despite our best efforts and recent progress, our knowledge of the chemical composition of the air under the canopy of a boreal forest still cannot be fully characterized. The discrepancy between the measured total reactivity of the air and the reactivity derived from the known chemical composition highlights the need to better understand the emissions from vegetation, but also other sources, such as the forest soil.
Pankaj Sadavarte, Maheswar Rupakheti, Prakash Bhave, Kiran Shakya, and Mark Lawrence
Atmos. Chem. Phys., 19, 12953–12973, https://doi.org/10.5194/acp-19-12953-2019, https://doi.org/10.5194/acp-19-12953-2019, 2019
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Emission inventory studies are an important regulatory tool for quantifying the amount of pollutants released in the atmosphere using the fuel consumption and emission rates for different fuels. This study developed an emission inventory over Nepal for 2001–2016 that reveals the changing fuel consumption and subsequently the pollution across different sectors of industrial, transport, agricultural, commercial and residential uses with the use of spatial distribution of anthropogenic activities.
Lukas Kohl, Markku Koskinen, Kaisa Rissanen, Iikka Haikarainen, Tatu Polvinen, Heidi Hellén, and Mari Pihlatie
Biogeosciences, 16, 3319–3332, https://doi.org/10.5194/bg-16-3319-2019, https://doi.org/10.5194/bg-16-3319-2019, 2019
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Plants emit small amounts of methane and large amounts of volatile organic compounds (VOCs). Measurements of plant methane emissions therefore require analysers that can provide accurate measurements of CH4 concentrations in the presence of changing amounts of VOCs. We therefore quantified to which degree various VOCs bias methane concentration measurements on different analysers. Our results show that some analysers are more sensitive to the presence of VOCs than others.
Jonathan Liebmann, Nicolas Sobanski, Jan Schuladen, Einar Karu, Heidi Hellén, Hannele Hakola, Qiaozhi Zha, Mikael Ehn, Matthieu Riva, Liine Heikkinen, Jonathan Williams, Horst Fischer, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 19, 10391–10403, https://doi.org/10.5194/acp-19-10391-2019, https://doi.org/10.5194/acp-19-10391-2019, 2019
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The formation of alkyl nitrates in the boreal forest was dominated by reactions of the NO3 radical with terpenes, both during the day and the night, with fewer contributions from OH and ozone. The alkyl nitrates formed had lifetimes on the order of 2 h, reflecting efficient loss via uptake to aerosol and deposition.
Xin Wan, Shichang Kang, Maheswar Rupakheti, Qianggong Zhang, Lekhendra Tripathee, Junming Guo, Pengfei Chen, Dipesh Rupakheti, Arnico K. Panday, Mark G. Lawrence, Kimitaka Kawamura, and Zhiyuan Cong
Atmos. Chem. Phys., 19, 2725–2747, https://doi.org/10.5194/acp-19-2725-2019, https://doi.org/10.5194/acp-19-2725-2019, 2019
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The sources of primary and secondary aerosols in the Hindu Kush–Himalayan–Tibetan Plateau region are not well known. Organic molecular tracers are useful for aerosol source apportionment. The characterization of molecular tracers were first systemically investigated and the contribution from primary and secondary sources to carbonaceous aerosols was estimated in the Kathmandu Valley. Our results demonstrate that biomass burning contributed a significant fraction to OC in the Kathmandu Valley.
Matthias Wiegner, Ina Mattis, Margit Pattantyús-Ábrahám, Juan Antonio Bravo-Aranda, Yann Poltera, Alexander Haefele, Maxime Hervo, Ulrich Görsdorf, Ronny Leinweber, Josef Gasteiger, Martial Haeffelin, Frank Wagner, Jan Cermak, Katerina Komínková, Mike Brettle, Christoph Münkel, and Kornelia Pönitz
Atmos. Meas. Tech., 12, 471–490, https://doi.org/10.5194/amt-12-471-2019, https://doi.org/10.5194/amt-12-471-2019, 2019
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Many ceilometers are influenced by water vapor absorption in the spectral range around 910 nm. Thus, a correction is required to retrieve aerosol optical properties. Validation of this correction scheme was performed in the framework of CeiLinEx2015 for several ceilometers with good agreement for Vaisala's CL51 ceilometer. For future applications we recommend monitoring the emitted wavelength and providing
darkmeasurements on a regular basis to be able to correct for signal artifacts.
Ashish Singh, Khadak S. Mahata, Maheswar Rupakheti, Wolfgang Junkermann, Arnico K. Panday, and Mark G. Lawrence
Atmos. Chem. Phys., 19, 245–258, https://doi.org/10.5194/acp-19-245-2019, https://doi.org/10.5194/acp-19-245-2019, 2019
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This paper reports the first airborne measurement campaign in the central Himalayan foothill region, one of the polluted but relatively poorly sampled regions of the world. The measurement campaign quantifies the vertical distribution of aerosols over a polluted mountain valley in the Himalayan foothills and investigates the extent of regional emission transport.
Nikolaos Papagiannopoulos, Lucia Mona, Aldo Amodeo, Giuseppe D'Amico, Pilar Gumà Claramunt, Gelsomina Pappalardo, Lucas Alados-Arboledas, Juan Luís Guerrero-Rascado, Vassilis Amiridis, Panagiotis Kokkalis, Arnoud Apituley, Holger Baars, Anja Schwarz, Ulla Wandinger, Ioannis Binietoglou, Doina Nicolae, Daniele Bortoli, Adolfo Comerón, Alejandro Rodríguez-Gómez, Michaël Sicard, Alex Papayannis, and Matthias Wiegner
Atmos. Chem. Phys., 18, 15879–15901, https://doi.org/10.5194/acp-18-15879-2018, https://doi.org/10.5194/acp-18-15879-2018, 2018
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A stand-alone automatic method for typing observations of the European Aerosol Research Lidar Network (EARLINET) is presented. The method compares the observations to model distributions that were constructed using EARLINET pre-classified data. The algorithm’s versatility and adaptability makes it suitable for network-wide typing studies.
Khadak Singh Mahata, Maheswar Rupakheti, Arnico Kumar Panday, Piyush Bhardwaj, Manish Naja, Ashish Singh, Andrea Mues, Paolo Cristofanelli, Deepak Pudasainee, Paolo Bonasoni, and Mark G. Lawrence
Atmos. Chem. Phys., 18, 14113–14132, https://doi.org/10.5194/acp-18-14113-2018, https://doi.org/10.5194/acp-18-14113-2018, 2018
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This paper presents the first-time simultaneous measurement of CO and O3 at multiple sites in the Kathmandu Valley bottom, its mountain rim and a river outlet, providing their spatial, temporal and seasonal–diurnal variations. Our study reveals that high O3, especially during premonsoon, in observed sites is of high concern for human health and ecosystems in the region. We also estimated CO emission flux to be 2–14 times higher than widely used emission databases (EDGAR HTAP, REAS and INTEX-B).
Heidi Hellén, Arnaud P. Praplan, Toni Tykkä, Ilona Ylivinkka, Ville Vakkari, Jaana Bäck, Tuukka Petäjä, Markku Kulmala, and Hannele Hakola
Atmos. Chem. Phys., 18, 13839–13863, https://doi.org/10.5194/acp-18-13839-2018, https://doi.org/10.5194/acp-18-13839-2018, 2018
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Exceptionally large ambient air concentration datasets of VOCs were measured in a boreal forest. For the first time concentration of the main sesquiterpene (β-caryophyllene) emitted by the local trees was also measured. Sesquiterpenes were found to have a major impact on local atmospheric chemistry, even though their concentrations were 30 times lower than the monoterpene concentrations. In addition, sesquiterpenes are expected to have a high impact on local secondary organic aerosol production.
Ka Lok Chan, Matthias Wiegner, Harald Flentje, Ina Mattis, Frank Wagner, Josef Gasteiger, and Alexander Geiß
Geosci. Model Dev., 11, 3807–3831, https://doi.org/10.5194/gmd-11-3807-2018, https://doi.org/10.5194/gmd-11-3807-2018, 2018
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The paper presents the comparison of ECMWF-IFS model simulation of aerosol backscatter profiles to long-term measurements of an extended ceilometer network. A significant influence of the numerical description of the hygroscopic growth of sea salt aerosols on the agreement between model and observations was found. Consideration of the nonsphericity of dust particles in the model reduced the attenuated backscatter of dust by ~&thinp;30 % and improved the agreement between model and observations.
Noelia Otero, Jana Sillmann, Kathleen A. Mar, Henning W. Rust, Sverre Solberg, Camilla Andersson, Magnuz Engardt, Robert Bergström, Bertrand Bessagnet, Augustin Colette, Florian Couvidat, Cournelius Cuvelier, Svetlana Tsyro, Hilde Fagerli, Martijn Schaap, Astrid Manders, Mihaela Mircea, Gino Briganti, Andrea Cappelletti, Mario Adani, Massimo D'Isidoro, María-Teresa Pay, Mark Theobald, Marta G. Vivanco, Peter Wind, Narendra Ojha, Valentin Raffort, and Tim Butler
Atmos. Chem. Phys., 18, 12269–12288, https://doi.org/10.5194/acp-18-12269-2018, https://doi.org/10.5194/acp-18-12269-2018, 2018
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This paper evaluates the capability of air-quality models to capture the observed relationship between surface ozone concentrations and meteorology over Europe. The air-quality models tended to overestimate the influence of maximum temperature and surface solar radiation. None of the air-quality models captured the strength of the observed relationship between ozone and relative humidity appropriately, underestimating the effect of relative humidity, a key factor in the ozone removal processes.
Anni Vanhatalo, Andrea Ghirardo, Eija Juurola, Jörg-Peter Schnitzler, Ina Zimmer, Heidi Hellén, Hannele Hakola, and Jaana Bäck
Biogeosciences, 15, 5047–5060, https://doi.org/10.5194/bg-15-5047-2018, https://doi.org/10.5194/bg-15-5047-2018, 2018
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We analysed the relationships between Scots pine needle monoterpene synthase activities, monoterpene storage pools and emissions of needles. The results showed changes in the monoterpene synthase activity of needles, linked to seasonality and needle ontogenesis, while the pool did not change considerably as a function of needle aging. Monoterpene emissions did not correlate with synthase activity or storage pool size. Additionally, we observed notably high plant-to-plant variation.
Piyush Bhardwaj, Manish Naja, Maheswar Rupakheti, Aurelia Lupascu, Andrea Mues, Arnico Kumar Panday, Rajesh Kumar, Khadak Singh Mahata, Shyam Lal, Harish C. Chandola, and Mark G. Lawrence
Atmos. Chem. Phys., 18, 11949–11971, https://doi.org/10.5194/acp-18-11949-2018, https://doi.org/10.5194/acp-18-11949-2018, 2018
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This study provides information about the regional variabilities in some of the pollutants using observations in Nepal and India. It is shown that agricultural crop residue burning leads to a significant enhancement in ozone and CO over a wider region. Further, the wintertime higher ozone levels are shown to be largely due to local emissions, while regional transport could be important in spring and hence shows the role of regional sources versus local sources in the Kathmandu Valley.
Tim Butler, Aurelia Lupascu, Jane Coates, and Shuai Zhu
Geosci. Model Dev., 11, 2825–2840, https://doi.org/10.5194/gmd-11-2825-2018, https://doi.org/10.5194/gmd-11-2825-2018, 2018
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This paper describes a method for determining origin of tropospheric ozone simulated in a global chemistry–climate model. This technique can show which precursor compounds were responsible for simulated ozone, and where they were emitted. In this paper we describe our technique, compare and contrast it with several other similar techniques, and use it to calculate the contribution of several different NOx and VOC precursor categories to the tropospheric ozone burden.
Josef Gasteiger and Matthias Wiegner
Geosci. Model Dev., 11, 2739–2762, https://doi.org/10.5194/gmd-11-2739-2018, https://doi.org/10.5194/gmd-11-2739-2018, 2018
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A software package has been developed to model optical properties of atmospheric aerosol ensembles based on a pre-calculated single particle data set. Spherical particles, spheroids, and a small set of irregular shapes are covered. A flexible and intuitive web interface is provided for online calculations of user-defined ensembles. The paper describes the package and outlines several applications, e.g., optical properties for aerosol size bins of an aerosol transport model.
Friderike Kuik, Andreas Kerschbaumer, Axel Lauer, Aurelia Lupascu, Erika von Schneidemesser, and Tim M. Butler
Atmos. Chem. Phys., 18, 8203–8225, https://doi.org/10.5194/acp-18-8203-2018, https://doi.org/10.5194/acp-18-8203-2018, 2018
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Modelled NOx concentrations are often underestimated compared to observations, and measurement studies show that reported NOx emissions in urban areas are often too low when the contribution from traffic is largest. This modelling study quantifies the underestimation of traffic NOx emissions in the Berlin–Brandenburg and finds that they are underestimated by ca. 50 % in the core urban area. More research is needed in order to more accurately understand real-world NOx emissions from traffic.
Andrea Mues, Axel Lauer, Aurelia Lupascu, Maheswar Rupakheti, Friderike Kuik, and Mark G. Lawrence
Geosci. Model Dev., 11, 2067–2091, https://doi.org/10.5194/gmd-11-2067-2018, https://doi.org/10.5194/gmd-11-2067-2018, 2018
Marja Hemmilä, Heidi Hellén, Aki Virkkula, Ulla Makkonen, Arnaud P. Praplan, Jenni Kontkanen, Lauri Ahonen, Markku Kulmala, and Hannele Hakola
Atmos. Chem. Phys., 18, 6367–6380, https://doi.org/10.5194/acp-18-6367-2018, https://doi.org/10.5194/acp-18-6367-2018, 2018
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We measured gas- and particle-phase amine and ammonia concentrations in a boreal forest site in 2015 with online ion chromatography coupled with mass spectrometry. We wanted to know how much and which kinds of amines there are, and how they behave and could affect nucleation. We observed seasonal and diurnal variations for different amines. Amines turned out to be a heterogeneous group of compounds. To our best knowledge, our amine measurements are the longest time series that has been made.
Xiaowan Zhu, Guiqian Tang, Jianping Guo, Bo Hu, Tao Song, Lili Wang, Jinyuan Xin, Wenkang Gao, Christoph Münkel, Klaus Schäfer, Xin Li, and Yuesi Wang
Atmos. Chem. Phys., 18, 4897–4910, https://doi.org/10.5194/acp-18-4897-2018, https://doi.org/10.5194/acp-18-4897-2018, 2018
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Our study first conducted a long-term observation of mixing layer height (MLH) with high resolution on the North China Plain (NCP), analyzed the spatiotemporal variations of regional MLH, investigated the reasons for MLH differences in the NCP and revealed the meteorological reasons for heavy haze pollution in southern Hebei. The study results provide scientific suggestions for regional industrial structure readjustment and have great importance for achieving the integrated development goals.
Jonathan Liebmann, Einar Karu, Nicolas Sobanski, Jan Schuladen, Mikael Ehn, Simon Schallhart, Lauriane Quéléver, Heidi Hellen, Hannele Hakola, Thorsten Hoffmann, Jonathan Williams, Horst Fischer, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 18, 3799–3815, https://doi.org/10.5194/acp-18-3799-2018, https://doi.org/10.5194/acp-18-3799-2018, 2018
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Using a newly developed experimental setup, we have made the first direct measurements (during autumn 2016) of NO3 reactivity in the Finnish boreal forest. The NO3 reactivity was generally very high (maximum value of 0.94/s) so that daytime reaction with organics was a substantial fraction of the NO3 loss. Observations of biogenic hydrocarbons (BVOCs) suggested a dominant role for monoterpenes in determining the NO3 reactivity, which displayed a strong vertical gradient between 8.5 and 25 m.
Christopher S. Malley, Erika von Schneidemesser, Sarah Moller, Christine F. Braban, W. Kevin Hicks, and Mathew R. Heal
Atmos. Chem. Phys., 18, 3563–3587, https://doi.org/10.5194/acp-18-3563-2018, https://doi.org/10.5194/acp-18-3563-2018, 2018
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This study quantifies the contribution of hourly nitrogen dioxide (NO2) variation to annual NO2 concentrations at > 2500 sites across Europe. Sites with distinct monthly, hour of day, and hourly NO2 contributions to annual NO2 were not grouped into specific European regions. Within relatively small areas there were sites with similar annual NO2 but with differences in these contributions. Therefore, measures implemented to reduce annual NO2 in one location may not be as effective in others.
Ana María Yáñez-Serrano, Anke Christine Nölscher, Efstratios Bourtsoukidis, Eliane Gomes Alves, Laurens Ganzeveld, Boris Bonn, Stefan Wolff, Marta Sa, Marcia Yamasoe, Jonathan Williams, Meinrat O. Andreae, and Jürgen Kesselmeier
Atmos. Chem. Phys., 18, 3403–3418, https://doi.org/10.5194/acp-18-3403-2018, https://doi.org/10.5194/acp-18-3403-2018, 2018
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This study shows the measurements of concentration of different monoterpene species in terms of height, time of day and season. Speciation seems similar during the dry seasons but changes with season. Furthermore, reactivity with the different oxidants demonstrated that a higher abundance of a monoterpene species does not automatically imply higher reactivity and that the most abundant monoterpene may not be the most atmospheric chemically relevant compound.
Mari Mäki, Hermanni Aaltonen, Jussi Heinonsalo, Heidi Hellén, Jukka Pumpanen, and Jaana Bäck
Biogeosciences Discuss., https://doi.org/10.5194/bg-2018-22, https://doi.org/10.5194/bg-2018-22, 2018
Preprint withdrawn
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Vegetation emissions of volatile organic compounds (VOCs) are intensively studied world-wide, but remains largely unknown how effectively belowground VOCs are produced and released into the atmosphere. We demonstrate that boreal forest soil is a diverse source and storage of VOCs, because more than 50 VOCs were detected in the soil air. Our results give evidence that VOC production processes and storages partly differ from those VOCs that are simultaneously emitted from the soil surface.
Khadak Singh Mahata, Arnico Kumar Panday, Maheswar Rupakheti, Ashish Singh, Manish Naja, and Mark G. Lawrence
Atmos. Chem. Phys., 17, 12573–12596, https://doi.org/10.5194/acp-17-12573-2017, https://doi.org/10.5194/acp-17-12573-2017, 2017
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The paper provides an overview of CH4, CO2, and CO mixing ratios, including diurnal and seasonal variation, and discusses the association of potential sources and meteorology with the observed temporal variation in the Kathmandu Valley. The study will provide an important dataset for a poorly studied region and will be useful for validating estimates from emission inventories, regional models, and satellite observations and assisting in the design of mitigation measures in the region.
Dipesh Rupakheti, Bhupesh Adhikary, Puppala Siva Praveen, Maheswar Rupakheti, Shichang Kang, Khadak Singh Mahata, Manish Naja, Qianggong Zhang, Arnico Kumar Panday, and Mark G. Lawrence
Atmos. Chem. Phys., 17, 11041–11063, https://doi.org/10.5194/acp-17-11041-2017, https://doi.org/10.5194/acp-17-11041-2017, 2017
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For the first time, atmospheric composition was monitored during pre-monsoon season of 2013 at Lumbini (UNESCO world heritage site as birthplace of the Buddha). PM and O3 frequently exceeded WHO guidelines. Pollution concentration, diurnal characteristics and influence of open burning on air quality in Lumbini were investigated. Potential source regions were also identified. Results show that air pollution at this site is of a great concern, requiring prompt attention for mitigation.
Heiko Bozem, Tim M. Butler, Mark G. Lawrence, Hartwig Harder, Monica Martinez, Dagmar Kubistin, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 17, 10565–10582, https://doi.org/10.5194/acp-17-10565-2017, https://doi.org/10.5194/acp-17-10565-2017, 2017
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We present airborne measurements and model simulations in the tropics and mid-latitudes during GABRIEL and HOOVER, respectively. Based only on in situ data net ozone formation/destruction tendencies (NOPR) are calculated and compared to a 3-D chemistry transport model. The NOPR is positive in the continental boundary layer and the upper troposphere above 6 km. In the marine boundary layer and the middle troposphere ozone destruction prevails. Fresh convection shows strong net ozone formation.
Augustin Colette, Camilla Andersson, Astrid Manders, Kathleen Mar, Mihaela Mircea, Maria-Teresa Pay, Valentin Raffort, Svetlana Tsyro, Cornelius Cuvelier, Mario Adani, Bertrand Bessagnet, Robert Bergström, Gino Briganti, Tim Butler, Andrea Cappelletti, Florian Couvidat, Massimo D'Isidoro, Thierno Doumbia, Hilde Fagerli, Claire Granier, Chris Heyes, Zig Klimont, Narendra Ojha, Noelia Otero, Martijn Schaap, Katarina Sindelarova, Annemiek I. Stegehuis, Yelva Roustan, Robert Vautard, Erik van Meijgaard, Marta Garcia Vivanco, and Peter Wind
Geosci. Model Dev., 10, 3255–3276, https://doi.org/10.5194/gmd-10-3255-2017, https://doi.org/10.5194/gmd-10-3255-2017, 2017
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The EURODELTA-Trends numerical experiment has been designed to assess the capability of chemistry-transport models to capture the evolution of surface air quality over the 1990–2010 period in Europe. It also includes sensitivity experiments in order to analyse the relative contribution of (i) emission changes, (ii) meteorological variability, and (iii) boundary conditions to air quality trends. The article is a detailed presentation of the experiment design and participating models.
Francisco Barraza, Fabrice Lambert, Héctor Jorquera, Ana María Villalobos, and Laura Gallardo
Atmos. Chem. Phys., 17, 10093–10107, https://doi.org/10.5194/acp-17-10093-2017, https://doi.org/10.5194/acp-17-10093-2017, 2017
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We quantify the main sources that have contributed to fine particulate matter (PM2.5) between 1998 and 2012 in Santiago's downtown. We calculate the long-term trend as well as abrupt changes in the time series and show how these relate to particular government policies implemented to improve air quality in specific years. We thus identify which measures successfully reduced individual sources and which sources need measures to avoid episodes when PM2.5 concentrations surpass Chilean standards.
Alexander Geiß, Matthias Wiegner, Boris Bonn, Klaus Schäfer, Renate Forkel, Erika von Schneidemesser, Christoph Münkel, Ka Lok Chan, and Rainer Nothard
Atmos. Meas. Tech., 10, 2969–2988, https://doi.org/10.5194/amt-10-2969-2017, https://doi.org/10.5194/amt-10-2969-2017, 2017
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Based on measurements with a ceilometer and from an air quality network, the relationship between the mixing layer height (MLH) and near surface concentrations of pollutants was investigated for summer 2014 in Berlin. It was found that the heterogeneity of the concentrations exceeds the differences due to different MLH retrievals. In particular for PM10 it seems to be unrealistic to find correlations between MLH and concentrations representative for an entire metropolitan area in flat terrain.
Caroline Brosy, Karina Krampf, Matthias Zeeman, Benjamin Wolf, Wolfgang Junkermann, Klaus Schäfer, Stefan Emeis, and Harald Kunstmann
Atmos. Meas. Tech., 10, 2773–2784, https://doi.org/10.5194/amt-10-2773-2017, https://doi.org/10.5194/amt-10-2773-2017, 2017
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Vertical and horizontal sounding of the planetary boundary layer can be complemented by unmanned aerial vehicles (UAV). Utilizing a multicopter-type UAV spatial sampling of air and simultaneously sensing of meteorological variables is possible for the study of surface exchange processes. During stable atmospheric conditions, vertical methane gradients of about 300 ppb were found. This approach extended the vertical profile height of existing tower-based infrastructure by a factor of five.
Linda Forster, Meinhard Seefeldner, Matthias Wiegner, and Bernhard Mayer
Atmos. Meas. Tech., 10, 2499–2516, https://doi.org/10.5194/amt-10-2499-2017, https://doi.org/10.5194/amt-10-2499-2017, 2017
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Halo displays are produced by scattering of sunlight by smooth, hexagonal ice crystals. Consequently, the presence of a halo should contain information on particle shape. This study presents HaloCam, a novel sun-tracking camera system, and an automated detection algorithm to collect and evaluate long-term halo observations. Two-year HaloCam observations revealed that about 25 % of the detected cirrus clouds occurred together with a 22° halo indicating the presence of smooth, hexagonal crystals.
Andrea Mues, Maheswar Rupakheti, Christoph Münkel, Axel Lauer, Heiko Bozem, Peter Hoor, Tim Butler, and Mark G. Lawrence
Atmos. Chem. Phys., 17, 8157–8176, https://doi.org/10.5194/acp-17-8157-2017, https://doi.org/10.5194/acp-17-8157-2017, 2017
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Ceilometer measurements taken in the Kathmandu Valley, Nepal, were used to study the temporal and spatial evolution of the mixing layer height in the valley. This provides important information on the vertical structure of the atmosphere and can thus also help to understand the mixing of air pollutants (e.g. black carbon) in the valley. The seasonal and diurnal cycles of the mixing layer were found to be highly dependent on meteorology and mainly anticorrelated to black carbon concentrations.
Chinmoy Sarkar, Vinayak Sinha, Baerbel Sinha, Arnico K. Panday, Maheswar Rupakheti, and Mark G. Lawrence
Atmos. Chem. Phys., 17, 8129–8156, https://doi.org/10.5194/acp-17-8129-2017, https://doi.org/10.5194/acp-17-8129-2017, 2017
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This study provides quantitative information regarding the source contributions of the major non-methane volatile organic compound sources in the Kathmandu Valley. Combining high-resolution in situ NMVOC data and model analyses, we show that REAS v2.1 and EDGAR v4.2 emission inventories underestimate the contribution of traffic and do not take the contribution of brick kilns into account. Furthermore, REAS v2.1 overestimates the contribution of residential biofuel use and industries.
Kabindra M. Shakya, Maheswar Rupakheti, Anima Shahi, Rejina Maskey, Bidya Pradhan, Arnico Panday, Siva P. Puppala, Mark Lawrence, and Richard E. Peltier
Atmos. Chem. Phys., 17, 6503–6516, https://doi.org/10.5194/acp-17-6503-2017, https://doi.org/10.5194/acp-17-6503-2017, 2017
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Particulate matter levels were monitored at six major roadway intersections in the Kathmandu Valley during two seasons in 2014. The study documented distinct seasonal (dry season versus wet season) and diel variations in particulate matter levels. This study suggests traffic-related emissions, and soil–dust–construction materials were found to be a major source of particulate matter at these locations.
Heidi Hellén, Leena Kangas, Anu Kousa, Mika Vestenius, Kimmo Teinilä, Ari Karppinen, Jaakko Kukkonen, and Jarkko V. Niemi
Atmos. Chem. Phys., 17, 3475–3487, https://doi.org/10.5194/acp-17-3475-2017, https://doi.org/10.5194/acp-17-3475-2017, 2017
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Estimating impacts of wood combustion on ambient levels of PAHs is challenging. In this study effect of residential wood combustion on the benzo[a]pyrene concentrations in the air of Helsinki metropolitan area was studied, using ambient air measurements, emission estimates and dispersion modeling. Combining all this information enabled a quantitative characterization of the influence of residential wood combustion, which was found to be the main local source and more important than for PM2.5.
Mari Mäki, Jussi Heinonsalo, Heidi Hellén, and Jaana Bäck
Biogeosciences, 14, 1055–1073, https://doi.org/10.5194/bg-14-1055-2017, https://doi.org/10.5194/bg-14-1055-2017, 2017
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The paper demonstrates which different biological factors and physico-chemical processes are important regulators of soil isoprenoid emissions at different times of the year. With the obtained knowledge on soil VOC sources, it will be possible to add soil VOC production into air chemistry models and thus improve the understanding on climatic feedback mechanisms between secondary organic aerosol formation, clouds, and radiative forcing.
Hannele Hakola, Virpi Tarvainen, Arnaud P. Praplan, Kerneels Jaars, Marja Hemmilä, Markku Kulmala, Jaana Bäck, and Heidi Hellén
Atmos. Chem. Phys., 17, 3357–3370, https://doi.org/10.5194/acp-17-3357-2017, https://doi.org/10.5194/acp-17-3357-2017, 2017
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We present spring and summer VOC emission rate measurements from Norway spruce using an in situ gas chromatograph. Monoterpene and C4–C10 aldehyde emission rates reached maxima in July. SQT emissions increased at the end of July and in August SQT were the most abundant group. The MT emission pattern varied a lot from tree to tree and therefore emission fluxes on canopy level should be conducted for more representative measurements. However, leaf level measurements produce more reliable SQT data.
Heidi Hellén, Simon Schallhart, Arnaud P. Praplan, Tuukka Petäjä, and Hannele Hakola
Atmos. Meas. Tech., 10, 281–289, https://doi.org/10.5194/amt-10-281-2017, https://doi.org/10.5194/amt-10-281-2017, 2017
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There is a lack of knowledge of volatile organic acids (VOAs), other than formic and acetic acids in gas phase, and this is at least partly due to the lack of sensitive enough measurement methods. In the present study we developed an in situ GC–MS measurement method for measuring C2–C7 monocarboxylic VOAs at ambient air concentration levels, which we used to measure ambient air concentrations in a boreal forest site. In addition, found mixing ratios were compared with PTR-TOFMS data.
Kerneels Jaars, Pieter G. van Zyl, Johan P. Beukes, Heidi Hellén, Ville Vakkari, Micky Josipovic, Andrew D. Venter, Matti Räsänen, Leandra Knoetze, Dirk P. Cilliers, Stefan J. Siebert, Markku Kulmala, Janne Rinne, Alex Guenther, Lauri Laakso, and Hannele Hakola
Atmos. Chem. Phys., 16, 15665–15688, https://doi.org/10.5194/acp-16-15665-2016, https://doi.org/10.5194/acp-16-15665-2016, 2016
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Biogenic volatile organic compounds (BVOCs) – important in tropospheric ozone and secondary organic aerosol formation – were measured at a savannah grassland in South Africa. Results presented are the most extensive for this type of landscape. Compared to other parts of the world, monoterpene levels were similar, while very low isoprene levels led to significantly lower total BVOC levels. BVOC levels were an order of magnitude lower compared to anthropogenic VOC levels measured at Welgegund.
Friderike Kuik, Axel Lauer, Galina Churkina, Hugo A. C. Denier van der Gon, Daniel Fenner, Kathleen A. Mar, and Tim M. Butler
Geosci. Model Dev., 9, 4339–4363, https://doi.org/10.5194/gmd-9-4339-2016, https://doi.org/10.5194/gmd-9-4339-2016, 2016
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The study evaluates the performance of a setup of the Weather Research and Forecasting model with chemistry and aerosols (WRF–Chem) for the Berlin–Brandenburg region of Germany. Its sensitivity to updating urban input parameters based on structural data for Berlin is tested, specifying land use classes on a sub-grid scale, downscaling the original emissions to a resolution of ca. 1 km by 1 km for Berlin based on proxy data and model resolution.
Carolina Cavazos Guerra, Axel Lauer, Andreas B. Herber, Tim M. Butler, Annette Rinke, and Klaus Dethloff
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2016-942, https://doi.org/10.5194/acp-2016-942, 2016
Revised manuscript has not been submitted
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Accurate description of the Arctic atmosphere is a challenge for the modelling comunity. We evaluate the performance of the Weather Research and Forecast model (WRF) in the Eurasian Arctic and analyse the implications of data to initialise the model and a land surface scheme. The results show that biases can be related to the quality of data used and in the case of black carbon concentrations, to emission data. More long term measurements are need for model Validation in the area.
Kathleen A. Mar, Narendra Ojha, Andrea Pozzer, and Tim M. Butler
Geosci. Model Dev., 9, 3699–3728, https://doi.org/10.5194/gmd-9-3699-2016, https://doi.org/10.5194/gmd-9-3699-2016, 2016
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Ground-level ozone is an air pollutant with adverse effects on human and ecosystem health and is also a climate forcer with a significant warming effect. This paper presents the setup and evaluation of a model for ozone air quality over Europe. Within the model evaluation, we compare the use of two commonly used photochemical schemes, and we conclude that uncertainties in the representation of chemistry are important to consider when using air quality models for policy applications.
Jane Coates, Kathleen A. Mar, Narendra Ojha, and Tim M. Butler
Atmos. Chem. Phys., 16, 11601–11615, https://doi.org/10.5194/acp-16-11601-2016, https://doi.org/10.5194/acp-16-11601-2016, 2016
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This modelling study reproduced the non-linear relationship of ozone, NOx and temperature using various chemical mechanisms previously determined from observational studies. Under urban conditions, faster reaction rates rather than increased isoprene emissions led to a slightly greater increase of ozone with temperature using different NOx conditions. This study also shows that the increase of ozone with temperature is more sensitive to atmospheric mixing than the choice of chemical mechanism.
Johanna Joensuu, Nuria Altimir, Hannele Hakola, Michael Rostás, Maarit Raivonen, Mika Vestenius, Hermanni Aaltonen, Markus Riederer, and Jaana Bäck
Atmos. Chem. Phys., 16, 7813–7823, https://doi.org/10.5194/acp-16-7813-2016, https://doi.org/10.5194/acp-16-7813-2016, 2016
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Plants produce volatile compounds (BVOCs) that have a major role in atmospheric chemistry. Our aim was to see if terpenes, a key group of BVOCs, can be found on surfaces of pine needles and, if so, how they compare with the emissions of the same tree. Both emissions and wax extracts were clearly dominated by monoterpenes, but there were also differences in the emission and wax spectra. The results support the existence of BVOCs on needle surfaces, with possible implications for air chemistry.
Boris Bonn, Erika von Schneidemesser, Dorota Andrich, Jörn Quedenau, Holger Gerwig, Anja Lüdecke, Jürgen Kura, Axel Pietsch, Christian Ehlers, Dieter Klemp, Claudia Kofahl, Rainer Nothard, Andreas Kerschbaumer, Wolfgang Junkermann, Rüdiger Grote, Tobias Pohl, Konradin Weber, Birgit Lode, Philipp Schönberger, Galina Churkina, Tim M. Butler, and Mark G. Lawrence
Atmos. Chem. Phys., 16, 7785–7811, https://doi.org/10.5194/acp-16-7785-2016, https://doi.org/10.5194/acp-16-7785-2016, 2016
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The distribution of air pollutants (gases and particles) have been investigated in different environments in Potsdam, Germany. Remarkable variations of the pollutants have been observed for distances of tens of meters by bicycles, vans and aircraft. Vegetated areas caused reductions depending on the pollutants, the vegetation type and dimensions. Our measurements show the pollutants to be of predominantly local origin, resulting in a huge challenge for common models to resolve.
Marje Prank, Mikhail Sofiev, Svetlana Tsyro, Carlijn Hendriks, Valiyaveetil Semeena, Xavier Vazhappilly Francis, Tim Butler, Hugo Denier van der Gon, Rainer Friedrich, Johannes Hendricks, Xin Kong, Mark Lawrence, Mattia Righi, Zissis Samaras, Robert Sausen, Jaakko Kukkonen, and Ranjeet Sokhi
Atmos. Chem. Phys., 16, 6041–6070, https://doi.org/10.5194/acp-16-6041-2016, https://doi.org/10.5194/acp-16-6041-2016, 2016
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Aerosol composition in Europe was simulated by four chemistry transport models and compared to observations to identify the most prominent areas for model improvement. Notable differences were found between the models' predictions, attributable to different treatment or omission of aerosol sources and processes. All models underestimated the observed concentrations by 10–60 %, mostly due to under-predicting the carbonaceous and mineral particles and omitting the aerosol-bound water.
Chinmoy Sarkar, Vinayak Sinha, Vinod Kumar, Maheswar Rupakheti, Arnico Panday, Khadak S. Mahata, Dipesh Rupakheti, Bhogendra Kathayat, and Mark G. Lawrence
Atmos. Chem. Phys., 16, 3979–4003, https://doi.org/10.5194/acp-16-3979-2016, https://doi.org/10.5194/acp-16-3979-2016, 2016
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First deployment of PTR-TOF-MS in South Asia. High acetaldehyde and biogenic isoprene concentrations detected even in winter in the Kathmandu Valley. Isocyanic acid, formamide, acetamide, naphthalene and nitromethane were detected for the first time in South Asian air. Oxygenated VOCs and isoprene-dominated OH reactivity and ozone production potentials (> 68 % OPP). Regulation of emissions from biomass co-fired brick kilns' by cleaner technology would improve air quality of the valley.
Guiqian Tang, Jinqiang Zhang, Xiaowan Zhu, Tao Song, Christoph Münkel, Bo Hu, Klaus Schäfer, Zirui Liu, Junke Zhang, Lili Wang, Jinyuan Xin, Peter Suppan, and Yuesi Wang
Atmos. Chem. Phys., 16, 2459–2475, https://doi.org/10.5194/acp-16-2459-2016, https://doi.org/10.5194/acp-16-2459-2016, 2016
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This is the first paper to validate and characterize mixing layer height and discuss its relationship with air pollution, using a ceilometer in Beijing. The novelty, originality, and importance of this paper are as follows: (1) the applicable conditions of the ceilometer; (2) the variations of mixing layer height; (3) thermal/dynamic structure inside mixing layers with different degrees of pollution; and (4) critical meteorological conditions for the formation of heavy air pollution.
J. Patokoski, T. M. Ruuskanen, M. K. Kajos, R. Taipale, P. Rantala, J. Aalto, T. Ryyppö, T. Nieminen, H. Hakola, and J. Rinne
Atmos. Chem. Phys., 15, 13413–13432, https://doi.org/10.5194/acp-15-13413-2015, https://doi.org/10.5194/acp-15-13413-2015, 2015
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In this study, main source areas for long-lived VOCs at the boreal forest in SMEAR II were determined. Air masses arriving from eastern and western directions were more polluted than those arriving from the northern direction. The biogenic and anthropogenic influences of three different source profiles were determined. The elevated trace gas concentrations from forest fire episodes were observed clearly in the trajectory analysis.
B. Kravitz, A. Robock, S. Tilmes, O. Boucher, J. M. English, P. J. Irvine, A. Jones, M. G. Lawrence, M. MacCracken, H. Muri, J. C. Moore, U. Niemeier, S. J. Phipps, J. Sillmann, T. Storelvmo, H. Wang, and S. Watanabe
Geosci. Model Dev., 8, 3379–3392, https://doi.org/10.5194/gmd-8-3379-2015, https://doi.org/10.5194/gmd-8-3379-2015, 2015
M. K. Kajos, P. Rantala, M. Hill, H. Hellén, J. Aalto, J. Patokoski, R. Taipale, C. C. Hoerger, S. Reimann, T. M. Ruuskanen, J. Rinne, and T. Petäjä
Atmos. Meas. Tech., 8, 4453–4473, https://doi.org/10.5194/amt-8-4453-2015, https://doi.org/10.5194/amt-8-4453-2015, 2015
M. Wiegner and J. Gasteiger
Atmos. Meas. Tech., 8, 3971–3984, https://doi.org/10.5194/amt-8-3971-2015, https://doi.org/10.5194/amt-8-3971-2015, 2015
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For the past few years a large number of autonomous continuously operating single-wavelength backscatter lidars, so called ceilometers, have been installed. Currently the assessment of their potential for aerosol remote sensing is a major research topic. This paper focusses on the need to consider water vapor
absorption if ceilometers emitting at wavelengths in the 905 to 910 nm range are used and proposes a correction scheme to improve the retrieval of the aerosol backscatter coefficient.
M. Beekmann, A. S. H. Prévôt, F. Drewnick, J. Sciare, S. N. Pandis, H. A. C. Denier van der Gon, M. Crippa, F. Freutel, L. Poulain, V. Ghersi, E. Rodriguez, S. Beirle, P. Zotter, S.-L. von der Weiden-Reinmüller, M. Bressi, C. Fountoukis, H. Petetin, S. Szidat, J. Schneider, A. Rosso, I. El Haddad, A. Megaritis, Q. J. Zhang, V. Michoud, J. G. Slowik, S. Moukhtar, P. Kolmonen, A. Stohl, S. Eckhardt, A. Borbon, V. Gros, N. Marchand, J. L. Jaffrezo, A. Schwarzenboeck, A. Colomb, A. Wiedensohler, S. Borrmann, M. Lawrence, A. Baklanov, and U. Baltensperger
Atmos. Chem. Phys., 15, 9577–9591, https://doi.org/10.5194/acp-15-9577-2015, https://doi.org/10.5194/acp-15-9577-2015, 2015
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A detailed characterization of air quality in the Paris (France) agglomeration, a megacity, during two summer and winter intensive campaigns and from additional 1-year observations, revealed that about 70% of the fine particulate matter (PM) at urban background is transported into the megacity from upwind regions. Unexpectedly, a major part of organic PM is of modern origin (woodburning and cooking activities, secondary formation from biogenic VOC).
P. S. Monks, A. T. Archibald, A. Colette, O. Cooper, M. Coyle, R. Derwent, D. Fowler, C. Granier, K. S. Law, G. E. Mills, D. S. Stevenson, O. Tarasova, V. Thouret, E. von Schneidemesser, R. Sommariva, O. Wild, and M. L. Williams
Atmos. Chem. Phys., 15, 8889–8973, https://doi.org/10.5194/acp-15-8889-2015, https://doi.org/10.5194/acp-15-8889-2015, 2015
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Ozone holds a certain fascination in atmospheric science. It is ubiquitous in the atmosphere, central to tropospheric oxidation chemistry, and yet harmful to human and ecosystem health as well as being an important greenhouse gas. It is not emitted into the atmosphere but is a byproduct of the very oxidation chemistry it largely initiates. This review examines current understanding of the processes regulating tropospheric ozone at global to local scales from both measurements and models.
J. Coates and T. M. Butler
Atmos. Chem. Phys., 15, 8795–8808, https://doi.org/10.5194/acp-15-8795-2015, https://doi.org/10.5194/acp-15-8795-2015, 2015
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We show that simplified chemical mechanisms break down VOC into smaller sized degradation products on the first day faster than the near-explicit MCM chemical mechanism which would lead to an underprediction of ozone levels downwind of VOC emissions, and an underestimation of the VOC contribution to tropospheric background ozone when using simplified chemical mechanisms in regional or global modelling studies.
F. Hase, M. Frey, T. Blumenstock, J. Groß, M. Kiel, R. Kohlhepp, G. Mengistu Tsidu, K. Schäfer, M. K. Sha, and J. Orphal
Atmos. Meas. Tech., 8, 3059–3068, https://doi.org/10.5194/amt-8-3059-2015, https://doi.org/10.5194/amt-8-3059-2015, 2015
M. Frey, F. Hase, T. Blumenstock, J. Groß, M. Kiel, G. Mengistu Tsidu, K. Schäfer, M. K. Sha, and J. Orphal
Atmos. Meas. Tech., 8, 3047–3057, https://doi.org/10.5194/amt-8-3047-2015, https://doi.org/10.5194/amt-8-3047-2015, 2015
C. C. Hoerger, A. Claude, C. Plass-Duelmer, S. Reimann, E. Eckart, R. Steinbrecher, J. Aalto, J. Arduini, N. Bonnaire, J. N. Cape, A. Colomb, R. Connolly, J. Diskova, P. Dumitrean, C. Ehlers, V. Gros, H. Hakola, M. Hill, J. R. Hopkins, J. Jäger, R. Junek, M. K. Kajos, D. Klemp, M. Leuchner, A. C. Lewis, N. Locoge, M. Maione, D. Martin, K. Michl, E. Nemitz, S. O'Doherty, P. Pérez Ballesta, T. M. Ruuskanen, S. Sauvage, N. Schmidbauer, T. G. Spain, E. Straube, M. Vana, M. K. Vollmer, R. Wegener, and A. Wenger
Atmos. Meas. Tech., 8, 2715–2736, https://doi.org/10.5194/amt-8-2715-2015, https://doi.org/10.5194/amt-8-2715-2015, 2015
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The performance of 20 European laboratories involved in long-term non-methane hydrocarbon (NMHC) measurements was assessed with respect to ACTRIS and GAW data quality objectives. The participants were asked to measure both a 30-component NMHC mixture in nitrogen and whole air. The NMHCs were analysed either by GC-FID or GC-MS. Most systems performed well for the NMHC in nitrogen, whereas in air more scatter was observed. Reasons for this are explained in the paper.
S. Kulkarni, N. Sobhani, J. P. Miller-Schulze, M. M. Shafer, J. J. Schauer, P. A. Solomon, P. E. Saide, S. N. Spak, Y. F. Cheng, H. A. C. Denier van der Gon, Z. Lu, D. G. Streets, G. Janssens-Maenhout, C. Wiedinmyer, J. Lantz, M. Artamonova, B. Chen, S. Imashev, L. Sverdlik, J. T. Deminter, B. Adhikary, A. D'Allura, C. Wei, and G. R. Carmichael
Atmos. Chem. Phys., 15, 1683–1705, https://doi.org/10.5194/acp-15-1683-2015, https://doi.org/10.5194/acp-15-1683-2015, 2015
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This study presents a regional-scale modeling analysis of aerosols in the Central Asia region including detailed characterization of seasonal source region and sector contributions along with the predicted changes in distribution of aerosols using 2030 future emission scenarios. The influence of long transport and impact of varied emission sources including dust, biomass burning, and anthropogenic sources on the regional aerosol distributions and the associated transport pathways are discussed.
B. Bonn, E. Bourtsoukidis, T. S. Sun, H. Bingemer, L. Rondo, U. Javed, J. Li, R. Axinte, X. Li, T. Brauers, H. Sonderfeld, R. Koppmann, A. Sogachev, S. Jacobi, and D. V. Spracklen
Atmos. Chem. Phys., 14, 10823–10843, https://doi.org/10.5194/acp-14-10823-2014, https://doi.org/10.5194/acp-14-10823-2014, 2014
M. Vestenius, H. Hellén, J. Levula, P. Kuronen, K.J. Helminen, T. Nieminen, M. Kulmala, and H. Hakola
Atmos. Chem. Phys., 14, 7883–7893, https://doi.org/10.5194/acp-14-7883-2014, https://doi.org/10.5194/acp-14-7883-2014, 2014
G. Pappalardo, A. Amodeo, A. Apituley, A. Comeron, V. Freudenthaler, H. Linné, A. Ansmann, J. Bösenberg, G. D'Amico, I. Mattis, L. Mona, U. Wandinger, V. Amiridis, L. Alados-Arboledas, D. Nicolae, and M. Wiegner
Atmos. Meas. Tech., 7, 2389–2409, https://doi.org/10.5194/amt-7-2389-2014, https://doi.org/10.5194/amt-7-2389-2014, 2014
K. Jaars, J. P. Beukes, P. G. van Zyl, A. D. Venter, M. Josipovic, J. J. Pienaar, V. Vakkari, H. Aaltonen, H. Laakso, M. Kulmala, P. Tiitta, A. Guenther, H. Hellén, L. Laakso, and H. Hakola
Atmos. Chem. Phys., 14, 7075–7089, https://doi.org/10.5194/acp-14-7075-2014, https://doi.org/10.5194/acp-14-7075-2014, 2014
M. Wiegner, F. Madonna, I. Binietoglou, R. Forkel, J. Gasteiger, A. Geiß, G. Pappalardo, K. Schäfer, and W. Thomas
Atmos. Meas. Tech., 7, 1979–1997, https://doi.org/10.5194/amt-7-1979-2014, https://doi.org/10.5194/amt-7-1979-2014, 2014
E. Bourtsoukidis, J. Williams, J. Kesselmeier, S. Jacobi, and B. Bonn
Atmos. Chem. Phys., 14, 6495–6510, https://doi.org/10.5194/acp-14-6495-2014, https://doi.org/10.5194/acp-14-6495-2014, 2014
C. Liu, S. Beirle, T. Butler, P. Hoor, C. Frankenberg, P. Jöckel, M. Penning de Vries, U. Platt, A. Pozzer, M. G. Lawrence, J. Lelieveld, H. Tost, and T. Wagner
Atmos. Chem. Phys., 14, 1717–1732, https://doi.org/10.5194/acp-14-1717-2014, https://doi.org/10.5194/acp-14-1717-2014, 2014
K. Schäfer, M. Elsasser, J. M. Arteaga-Salas, J. Gu, M. Pitz, J. Schnelle-Kreis, J. Cyrys, S. Emeis, A. S. H. Prevot, and R. Zimmermann
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-2235-2014, https://doi.org/10.5194/acpd-14-2235-2014, 2014
Revised manuscript not accepted
E. von Schneidemesser, M. Vieno, and P. S. Monks
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-1287-2014, https://doi.org/10.5194/acpd-14-1287-2014, 2014
Revised manuscript not accepted
Z. S. Stock, M. R. Russo, T. M. Butler, A. T. Archibald, M. G. Lawrence, P. J. Telford, N. L. Abraham, and J. A. Pyle
Atmos. Chem. Phys., 13, 12215–12231, https://doi.org/10.5194/acp-13-12215-2013, https://doi.org/10.5194/acp-13-12215-2013, 2013
B. Bonn, S. Sun, W. Haunold, R. Sitals, E. van Beesel, L. dos Santos, B. Nillius, and S. Jacobi
Atmos. Meas. Tech., 6, 3407–3423, https://doi.org/10.5194/amt-6-3407-2013, https://doi.org/10.5194/amt-6-3407-2013, 2013
S. Guo, M. Hu, Q. Guo, X. Zhang, J. J. Schauer, and R. Zhang
Atmos. Chem. Phys., 13, 8303–8314, https://doi.org/10.5194/acp-13-8303-2013, https://doi.org/10.5194/acp-13-8303-2013, 2013
M. K. Kajos, H. Hakola, T. Holst, T. Nieminen, V. Tarvainen, T. Maximov, T. Petäjä, A. Arneth, and J. Rinne
Biogeosciences, 10, 4705–4719, https://doi.org/10.5194/bg-10-4705-2013, https://doi.org/10.5194/bg-10-4705-2013, 2013
E. Z. Nordin, A. C. Eriksson, P. Roldin, P. T. Nilsson, J. E. Carlsson, M. K. Kajos, H. Hellén, C. Wittbom, J. Rissler, J. Löndahl, E. Swietlicki, B. Svenningsson, M. Bohgard, M. Kulmala, M. Hallquist, and J. H. Pagels
Atmos. Chem. Phys., 13, 6101–6116, https://doi.org/10.5194/acp-13-6101-2013, https://doi.org/10.5194/acp-13-6101-2013, 2013
A.C. Nölscher, E. Bourtsoukidis, B. Bonn, J. Kesselmeier, J. Lelieveld, and J. Williams
Biogeosciences, 10, 4241–4257, https://doi.org/10.5194/bg-10-4241-2013, https://doi.org/10.5194/bg-10-4241-2013, 2013
S. M. Burrows, P. J. Rayner, T. Butler, and M. G. Lawrence
Atmos. Chem. Phys., 13, 5473–5488, https://doi.org/10.5194/acp-13-5473-2013, https://doi.org/10.5194/acp-13-5473-2013, 2013
G. Pappalardo, L. Mona, G. D'Amico, U. Wandinger, M. Adam, A. Amodeo, A. Ansmann, A. Apituley, L. Alados Arboledas, D. Balis, A. Boselli, J. A. Bravo-Aranda, A. Chaikovsky, A. Comeron, J. Cuesta, F. De Tomasi, V. Freudenthaler, M. Gausa, E. Giannakaki, H. Giehl, A. Giunta, I. Grigorov, S. Groß, M. Haeffelin, A. Hiebsch, M. Iarlori, D. Lange, H. Linné, F. Madonna, I. Mattis, R.-E. Mamouri, M. A. P. McAuliffe, V. Mitev, F. Molero, F. Navas-Guzman, D. Nicolae, A. Papayannis, M. R. Perrone, C. Pietras, A. Pietruczuk, G. Pisani, J. Preißler, M. Pujadas, V. Rizi, A. A. Ruth, J. Schmidt, F. Schnell, P. Seifert, I. Serikov, M. Sicard, V. Simeonov, N. Spinelli, K. Stebel, M. Tesche, T. Trickl, X. Wang, F. Wagner, M. Wiegner, and K. M. Wilson
Atmos. Chem. Phys., 13, 4429–4450, https://doi.org/10.5194/acp-13-4429-2013, https://doi.org/10.5194/acp-13-4429-2013, 2013
D. Kunkel, H. Tost, and M. G. Lawrence
Atmos. Chem. Phys., 13, 4203–4222, https://doi.org/10.5194/acp-13-4203-2013, https://doi.org/10.5194/acp-13-4203-2013, 2013
S. Metzger, W. Junkermann, M. Mauder, K. Butterbach-Bahl, B. Trancón y Widemann, F. Neidl, K. Schäfer, S. Wieneke, X. H. Zheng, H. P. Schmid, and T. Foken
Biogeosciences, 10, 2193–2217, https://doi.org/10.5194/bg-10-2193-2013, https://doi.org/10.5194/bg-10-2193-2013, 2013
G. J. Phillips, U. Makkonen, G. Schuster, N. Sobanski, H. Hakola, and J. N. Crowley
Atmos. Meas. Tech., 6, 231–237, https://doi.org/10.5194/amt-6-231-2013, https://doi.org/10.5194/amt-6-231-2013, 2013
J. Lelieveld, M. G. Lawrence, and D. Kunkel
Atmos. Chem. Phys., 13, 31–34, https://doi.org/10.5194/acp-13-31-2013, https://doi.org/10.5194/acp-13-31-2013, 2013
H. Hakola, H. Hellén, M. Hemmilä, J. Rinne, and M. Kulmala
Atmos. Chem. Phys., 12, 11665–11678, https://doi.org/10.5194/acp-12-11665-2012, https://doi.org/10.5194/acp-12-11665-2012, 2012
Related subject area
Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Molecular and seasonal characteristics of organic vapors in urban Beijing: insights from Vocus-PTR measurements
The variations in volatile organic compounds based on the policy change for Omicron in the traffic hub of Zhengzhou
On the dynamics of ozone depletion events at Villum Research Station in the High Arctic
Measurement report: Long-term measurements of surface ozone and trends in semi-natural sub-Saharan African ecosystems
Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant
Reactive chlorine-, sulfur-, and nitrogen-containing volatile organic compounds impact atmospheric chemistry in the megacity of Delhi during both clean and extremely polluted seasons
Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
Ozone deposition measurements over wheat fields in the North China Plain: variability and related factors of deposition flux and velocity
Consistency evaluation of tropospheric ozone from ozonesonde and IAGOS (In-service Aircraft for a Global Observing System) observations: vertical distribution, ozonesonde types, and station–airport distance
CO2 and CO temporal variability over Mexico City from ground-based total column and surface measurements
Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization
Measurement report: In-flight and ground-based measurements of nitrogen oxide emissions from latest-generation jet engines and 100 % sustainable aviation fuel
Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night
Measurement report: Urban ammonia and amines in Houston, Texas
Biomass-burning sources control ambient particulate matter, but traffic and industrial sources control volatile organic compound (VOC) emissions and secondary-pollutant formation during extreme pollution events in Delhi
Multi-year observations of variable incomplete combustion in the New York megacity
Observations of the vertical distributions of summertime atmospheric pollutants in Nam Co: OH production and source analysis
Understanding summertime peroxyacetyl nitrate (PAN) formation and its relation to aerosol pollution: Insights from high-resolution measurements and modeling
Measurement report: Elevated atmospheric ammonia may promote particle pH and HONO formation – insights from the COVID-19 pandemic
Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China
Elevated oxidized mercury in the free troposphere: analytical advances and application at a remote continental mountaintop site
Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area
Real-world emission characteristics of VOCs from typical cargo ships and their potential contributions to secondary organic aerosol and O3 under low-sulfur fuel policies
NO3 reactivity during a summer period in a temperate forest below and above the canopy
The role of oceanic ventilation and terrestrial outflow in atmospheric non-methane hydrocarbons over the Chinese marginal seas
Concentration and source changes of nitrous acid (HONO) during the COVID-19 lockdown in Beijing
Characteristics and sources of nonmethane volatile organic compounds (NMVOCs) and O3–NOx–NMVOC relationships in Zhengzhou, China
Seasonal Air Concentration Variability, Gas/Particle Partitioning, Precipitation Scavenging, and Air-Water Equilibrium of Organophosphate Esters in Southern Canada
Exploring the variations in ambient BTEX in urban Europe and its environmental health implications
Measurement report: Surface exchange fluxes of HONO during the growth process of paddy fields in the Huaihe River Basin, China
Cloud processing of DMS oxidation products limits SO2 and OCS production in the Eastern North Atlantic marine boundary layer
Deciphering anthropogenic and biogenic contributions to selected non-methane volatile organic compound emissions in an urban area
Emission characteristics of reactive organic gases (ROGs) from industrial volatile chemical products (VCPs) in the Pearl River Delta (PRD), China
Measurement report: Enhanced photochemical formation of formic and isocyanic acids in urban regions aloft – insights from tower-based online gradient measurements
Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany
Exploring the Crucial Role of Atmospheric Carbonyl Compounds in Regional Ozone heavy Pollution: Insights from Intensive Field Observations and Observation-based modelling in the Chengdu Plain Urban Agglomeration, China
Surface snow bromide and nitrate at Eureka, Canada, in early spring and implications for polar boundary layer chemistry
Opinion: Strengthening research in the Global South – atmospheric science opportunities in South America and Africa
Shipping and algae emissions have a major impact on ambient air mixing ratios of non-methane hydrocarbons (NMHCs) and methanethiol on Utö Island in the Baltic Sea
Contribution of cooking emissions to the urban volatile organic compounds in Las Vegas, NV
Reanalysis of NOAA H2 observations: implications for the H2 budget
A large role of missing volatile organic compound reactivity from anthropogenic emissions in ozone pollution regulation
Diurnal, seasonal, and interannual variations in δ(18O) of atmospheric O2 and its application to evaluate changes in oxygen, carbon, and water cycles
Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion)
Production of oxygenated volatile organic compounds from the ozonolysis of coastal seawater
Comment on “Transport of substantial stratospheric ozone to the surface by a dying typhoon and shallow convection” by Chen et al. (2022)
Observations of cyanogen bromide (BrCN) in the global troposphere and their relation to polar surface O3 destruction
Individual coal mine methane emissions constrained by eddy covariance measurements: low bias and missing sources
Measurement report: Observations of ground-level ozone concentration gradients perpendicular to the Lake Ontario shoreline
Measurement report: The Palau Atmospheric Observatory and its ozonesonde record – continuous monitoring of tropospheric composition and dynamics in the tropical western Pacific
Zhaojin An, Rujing Yin, Xinyan Zhao, Xiaoxiao Li, Yuyang Li, Yi Yuan, Junchen Guo, Yiqi Zhao, Xue Li, Dandan Li, Yaowei Li, Dongbin Wang, Chao Yan, Kebin He, Douglas R. Worsnop, Frank N. Keutsch, and Jingkun Jiang
Atmos. Chem. Phys., 24, 13793–13810, https://doi.org/10.5194/acp-24-13793-2024, https://doi.org/10.5194/acp-24-13793-2024, 2024
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Online Vocus-PTR measurements show the compositions and seasonal variations in organic vapors in urban Beijing. With enhanced sensitivity and mass resolution, various species at a level of sub-parts per trillion (ppt) and organics with multiple oxygens (≥ 3) were observed. The fast photooxidation process in summer leads to an increase in both concentration and proportion of organics with multiple oxygens, while, in other seasons, the variations in them could be influenced by mixed sources.
Bowen Zhang, Dong Zhang, Zhe Dong, Xinshuai Song, Ruiqin Zhang, and Xiao Li
Atmos. Chem. Phys., 24, 13587–13601, https://doi.org/10.5194/acp-24-13587-2024, https://doi.org/10.5194/acp-24-13587-2024, 2024
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To gain insight into the impact of changes due to epidemic control policies, we undertook continuous online monitoring of volatile organic compounds (VOCs) at an urban site in Zhengzhou over a 2-month period. This study examines the characteristics of VOCs, their sources, and their temporal evolution. It also assesses the impact of the policy change on VOC pollution during the monitoring period, thus providing a basis for further research on VOC pollution and source control.
Jakob Boyd Pernov, Jens Liengaard Hjorth, Lise Lotte Sørensen, and Henrik Skov
Atmos. Chem. Phys., 24, 13603–13631, https://doi.org/10.5194/acp-24-13603-2024, https://doi.org/10.5194/acp-24-13603-2024, 2024
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Arctic ozone depletion events (ODEs) occur every spring and have vast implications for the oxidizing capacity, radiative balance, and mercury oxidation. In this study, we analyze ozone, ODEs, and their connection to meteorological and air mass history variables through statistical analyses, back trajectories, and machine learning (ML) at Villum Research Station. ODEs are favorable under sunny, calm conditions with air masses arriving from northerly wind directions with sea ice contact.
Hagninou Elagnon Venance Donnou, Aristide Barthélémy Akpo, Money Ossohou, Claire Delon, Véronique Yoboué, Dungall Laouali, Marie Ouafo-Leumbe, Pieter Gideon Van Zyl, Ousmane Ndiaye, Eric Gardrat, Maria Dias-Alves, and Corinne Galy-Lacaux
Atmos. Chem. Phys., 24, 13151–13182, https://doi.org/10.5194/acp-24-13151-2024, https://doi.org/10.5194/acp-24-13151-2024, 2024
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Ozone is a secondary air pollutant that is detrimental to human and plant health. A better understanding of its chemical evolution is a challenge for Africa, where it is still undersampled. Out of 14 sites examined (1995–2020), high levels of O3 are reported in southern Africa. The dominant chemical processes leading to O3 formation are identified. A decrease in O3 is observed at Katibougou (Mali) and Banizoumbou (Niger), and an increase is found at Zoétélé (Cameroon) and Skukuza (South Africa).
Junwei Song, Georgios I. Gkatzelis, Ralf Tillmann, Nicolas Brüggemann, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 24, 13199–13217, https://doi.org/10.5194/acp-24-13199-2024, https://doi.org/10.5194/acp-24-13199-2024, 2024
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Biogenic volatile organic compounds (BVOCs) and organic aerosol (OA) particles were measured online in a stressed spruce-dominated forest. OA was mainly attributed to the monoterpene oxidation products. The mixing ratios of BVOCs were higher than the values previously measured in other temperate forests. The results demonstrate that BVOCs are influenced not only by meteorology and biogenic emissions but also by local anthropogenic emissions and subsequent chemical transformation processes.
Sachin Mishra, Vinayak Sinha, Haseeb Hakkim, Arpit Awasthi, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Baerbel Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 13129–13150, https://doi.org/10.5194/acp-24-13129-2024, https://doi.org/10.5194/acp-24-13129-2024, 2024
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We quantified 111 gases using mass spectrometry to understand how seasonal and emission changes lead from clean air in the monsoon season to extremely polluted air in the post-monsoon season in Delhi. Averaged total mass concentrations (260 µg m-3) were > 4 times in polluted periods, driven by biomass burning emissions and reduced atmospheric ventilation. Reactive gaseous nitrogen, chlorine, and sulfur compounds hitherto unreported from such a polluted environment were discovered.
Gérard Ancellet, Camille Viatte, Anne Boynard, François Ravetta, Jacques Pelon, Cristelle Cailteau-Fischbach, Pascal Genau, Julie Capo, Axel Roy, and Philippe Nédélec
Atmos. Chem. Phys., 24, 12963–12983, https://doi.org/10.5194/acp-24-12963-2024, https://doi.org/10.5194/acp-24-12963-2024, 2024
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Characterization of ozone pollution in urban areas benefited from a measurement campaign in summer 2022 in the Paris region. The analysis is based on 21 d of lidar and aircraft observations. The main objective is an analysis of the sensitivity of ozone pollution to the micrometeorological processes in the urban atmospheric boundary layer and the transport of regional pollution. The paper also discusses to what extent satellite observations can track observed ozone plumes.
Xiaoyi Zhang, Wanyun Xu, Weili Lin, Gen Zhang, Jinjian Geng, Li Zhou, Huarong Zhao, Sanxue Ren, Guangsheng Zhou, Jianmin Chen, and Xiaobin Xu
Atmos. Chem. Phys., 24, 12323–12340, https://doi.org/10.5194/acp-24-12323-2024, https://doi.org/10.5194/acp-24-12323-2024, 2024
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Ozone (O3) deposition is a key process that removes surface O3, affecting air quality, ecosystems and climate change. We conducted O3 deposition measurement over a wheat canopy using a newly relaxed eddy accumulation flux system. Large variabilities in O3 deposition were detected, mainly determined by crop growth and modulated by various environmental factors. More O3 deposition observations over different surfaces are needed for exploring deposition mechanisms and model optimization.
Honglei Wang, David W. Tarasick, Jane Liu, Herman G. J. Smit, Roeland Van Malderen, Lijuan Shen, Romain Blot, and Tianliang Zhao
Atmos. Chem. Phys., 24, 11927–11942, https://doi.org/10.5194/acp-24-11927-2024, https://doi.org/10.5194/acp-24-11927-2024, 2024
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In this study, we identify 23 suitable pairs of sites from World Ozone and Ultraviolet Radiation Data Centre (WOUDC) and In-service Aircraft for a Global Observing System (IAGOS) datasets (1995 to 2021), compare the average vertical distributions of tropospheric O3 from ozonesonde and aircraft measurements, and analyze the differences based on ozonesonde type and station–airport distance.
Noémie Taquet, Wolfgang Stremme, María Eugenia González del Castillo, Victor Almanza, Alejandro Bezanilla, Olivier Laurent, Carlos Alberti, Frank Hase, Michel Ramonet, Thomas Lauvaux, Ke Che, and Michel Grutter
Atmos. Chem. Phys., 24, 11823–11848, https://doi.org/10.5194/acp-24-11823-2024, https://doi.org/10.5194/acp-24-11823-2024, 2024
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We characterize the variability in CO and CO2 emissions over Mexico City from long-term time-resolved Fourier transform infrared spectroscopy solar absorption and surface measurements from 2013 to 2021. Using the average intraday CO growth rate from total columns, the average CO / CO2 ratio and TROPOMI data, we estimate the interannual variability in the CO and CO2 anthropogenic emissions of Mexico City, highlighting the effect of an unprecedented drop in activity due to the COVID-19 lockdown.
Akima Ringsdorf, Achim Edtbauer, Bruna Holanda, Christopher Poehlker, Marta O. Sá, Alessandro Araújo, Jürgen Kesselmeier, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 24, 11883–11910, https://doi.org/10.5194/acp-24-11883-2024, https://doi.org/10.5194/acp-24-11883-2024, 2024
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We show the average height distribution of separately observed aldehydes and ketones over a day and discuss their rainforest-specific sources and sinks as well as their seasonal changes above the Amazon. Ketones have much longer atmospheric lifetimes than aldehydes and thus different implications for atmospheric chemistry. However, they are commonly observed together, which we overcome by measuring with a NO+ chemical ionization mass spectrometer for the first time in the Amazon rainforest.
Theresa Harlass, Rebecca Dischl, Stefan Kaufmann, Raphael Märkl, Daniel Sauer, Monika Scheibe, Paul Stock, Tiziana Bräuer, Andreas Dörnbrack, Anke Roiger, Hans Schlager, Ulrich Schumann, Magdalena Pühl, Tobias Schripp, Tobias Grein, Linda Bondorf, Charles Renard, Maxime Gauthier, Mark Johnson, Darren Luff, Paul Madden, Peter Swann, Denise Ahrens, Reetu Sallinen, and Christiane Voigt
Atmos. Chem. Phys., 24, 11807–11822, https://doi.org/10.5194/acp-24-11807-2024, https://doi.org/10.5194/acp-24-11807-2024, 2024
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Emissions from aircraft have a direct impact on our climate. Here, we present airborne and ground-based measurement data of nitrogen oxides that were collected in the exhaust of an Airbus aircraft. We study the impact of burning fossil and sustainable aviation fuel on nitrogen oxide emissions at different engine settings related to combustor temperature, pressure and fuel flow. Further, we compare observations with engine emission models.
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024, https://doi.org/10.5194/acp-24-11603-2024, 2024
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Using measurements of various trace gases in a suburban forest near Paris in the summer of 2022, we were able to gain insight into the sources and sinks of NOx (NO+NO2) with a special focus on their nighttime chemical and physical loss processes. NO was observed as a result of nighttime soil emissions when O3 levels were strongly depleted by deposition. NO oxidation products were not observed at night, indicating that soil and/or foliar surfaces are an efficient sink of reactive N.
Lee Tiszenkel, James H. Flynn, and Shan-Hu Lee
Atmos. Chem. Phys., 24, 11351–11363, https://doi.org/10.5194/acp-24-11351-2024, https://doi.org/10.5194/acp-24-11351-2024, 2024
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Ammonia and amines are important ingredients for aerosol formation in urban environments, but the measurements of these compounds are extremely challenging. Our observations show that urban ammonia and amines in Houston are emitted from urban sources, and diurnal variations in their concentrations are likely governed by gas-to-particle conversion and emissions.
Arpit Awasthi, Baerbel Sinha, Haseeb Hakkim, Sachin Mishra, Varkrishna Mummidivarapu, Gurmanjot Singh, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Vinayak Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 10279–10304, https://doi.org/10.5194/acp-24-10279-2024, https://doi.org/10.5194/acp-24-10279-2024, 2024
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We use 111 volatile organic compounds (VOCs), PM10, and PM2.5 in a positive matrix factorization (PMF) model to resolve 11 pollution sources validated with chemical fingerprints. Crop residue burning and heating account for ~ 50 % of the PM, while traffic and industrial emissions dominate the gas-phase VOC burden and formation potential of secondary organic aerosols (> 60 %). Non-tailpipe emissions from compressed-natural-gas-fuelled commercial vehicles dominate the transport sector's PM burden.
Luke D. Schiferl, Cong Cao, Bronte Dalton, Andrew Hallward-Driemeier, Ricardo Toledo-Crow, and Róisín Commane
Atmos. Chem. Phys., 24, 10129–10142, https://doi.org/10.5194/acp-24-10129-2024, https://doi.org/10.5194/acp-24-10129-2024, 2024
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Carbon monoxide (CO) is an air pollutant and an important indicator of the incomplete combustion of fossil fuels in cities. Using 4 years of winter and spring observations in New York City, we found that both the magnitude and variability of CO from the metropolitan area are greater than expected. Transportation emissions cannot explain the missing and variable CO, which points to energy from buildings as a likely underappreciated source of urban air pollution and greenhouse gas emissions.
Chengzhi Xing, Cheng Liu, Chunxiang Ye, Jingkai Xue, Hongyu Wu, Xiangguang Ji, Jinping Ou, and Qihou Hu
Atmos. Chem. Phys., 24, 10093–10112, https://doi.org/10.5194/acp-24-10093-2024, https://doi.org/10.5194/acp-24-10093-2024, 2024
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We identified the contributions of ozone (O3) and nitrous acid (HONO) to the production rates of hydroxide (OH) in vertical space on the Tibetan Plateau (TP). A new insight was offered: the contributions of HONO and O3 to the production rates of OH on the TP are even greater than in lower-altitudes areas. This study enriches the understanding of vertical distribution of atmospheric components and explains the strong atmospheric oxidation capacity (AOC) on the TP.
Baoye Hu, Naihua Chen, Rui Li, Mingqiang Huang, Jinsheng Chen, Youwei Hong, Lingling Xu, Xiaolong Fan, Mengren Li, Lei Tong, Qiuping Zheng, and Yuxiang Yang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2631, https://doi.org/10.5194/egusphere-2024-2631, 2024
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Box modeling with the master chemical mechanism (MCM) was used to address the puzzle of summertime PAN formation and its association with aerosol pollution under high ozone conditions. The MCM model proves to be an ideal tool for investigating PAN photochemical formation (IOA=0.75). The model performed better during the clean period than during the haze period. Through the machine learning method of XGBoost, we found that the top three factors leading to simulation bias were NH3, NO3, and PM2.5.
Xinyuan Zhang, Lingling Wang, Nan Wang, Shuangliang Ma, Shenbo Wang, Ruiqin Zhang, Dong Zhang, Mingkai Wang, and Hongyu Zhang
Atmos. Chem. Phys., 24, 9885–9898, https://doi.org/10.5194/acp-24-9885-2024, https://doi.org/10.5194/acp-24-9885-2024, 2024
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This study highlights the importance of the redox reaction of NO2 with SO2 based on actual atmospheric observations. The particle pH in future China is expected to rise steadily. Consequently, this reaction could become a significant source of HONO in China. Therefore, it is crucial to coordinate the control of SO2, NOx, and NH3 emissions to avoid a rapid increase in the particle pH.
Jun Zhou, Chunsheng Zhang, Aiming Liu, Bin Yuan, Yan Wang, Wenjie Wang, Jie-Ping Zhou, Yixin Hao, Xiao-Bing Li, Xianjun He, Xin Song, Yubin Chen, Suxia Yang, Shuchun Yang, Yanfeng Wu, Bin Jiang, Shan Huang, Junwen Liu, Yuwen Peng, Jipeng Qi, Minhui Deng, Bowen Zhong, Yibo Huangfu, and Min Shao
Atmos. Chem. Phys., 24, 9805–9826, https://doi.org/10.5194/acp-24-9805-2024, https://doi.org/10.5194/acp-24-9805-2024, 2024
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In-depth understanding of the near-ground vertical variability in photochemical ozone (O3) formation is crucial for mitigating O3 pollution. Utilizing a self-built vertical observation system, a direct net photochemical O3 production rate detection system, and an observation-based model, we diagnosed the vertical distributions and formation mechanism of net photochemical O3 production rates and sensitivity in the Pearl River Delta region, one of the most O3-polluted areas in China.
Eleanor J. Derry, Tyler R. Elgiar, Taylor Y. Wilmot, Nicholas W. Hoch, Noah S. Hirshorn, Peter Weiss-Penzias, Christopher F. Lee, John C. Lin, A. Gannet Hallar, Rainer Volkamer, Seth N. Lyman, and Lynne E. Gratz
Atmos. Chem. Phys., 24, 9615–9643, https://doi.org/10.5194/acp-24-9615-2024, https://doi.org/10.5194/acp-24-9615-2024, 2024
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Mercury (Hg) is a globally distributed neurotoxic pollutant. Atmospheric deposition is the main source of Hg in ecosystems. However, measurement biases hinder understanding of the origins and abundance of the more bioavailable oxidized form. We used an improved, calibrated measurement system to study air mass composition and transport of atmospheric Hg at a remote mountaintop site in the central US. Oxidized Hg originated upwind in the low to middle free troposphere under clean, dry conditions.
Benjamin A. Nault, Katherine R. Travis, James H. Crawford, Donald R. Blake, Pedro Campuzano-Jost, Ronald C. Cohen, Joshua P. DiGangi, Glenn S. Diskin, Samuel R. Hall, L. Gregory Huey, Jose L. Jimenez, Kyung-Eun Min, Young Ro Lee, Isobel J. Simpson, Kirk Ullmann, and Armin Wisthaler
Atmos. Chem. Phys., 24, 9573–9595, https://doi.org/10.5194/acp-24-9573-2024, https://doi.org/10.5194/acp-24-9573-2024, 2024
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Ozone (O3) is a pollutant formed from the reactions of gases emitted from various sources. In urban areas, the density of human activities can increase the O3 formation rate (P(O3)), thus impacting air quality and health. Observations collected over Seoul, South Korea, are used to constrain P(O3). A high local P(O3) was found; however, local P(O3) was partly reduced due to compounds typically ignored. These observations also provide constraints for unmeasured compounds that will impact P(O3).
Fan Zhang, Binyu Xiao, Zeyu Liu, Yan Zhang, Chongguo Tian, Rui Li, Can Wu, Yali Lei, Si Zhang, Xinyi Wan, Yubao Chen, Yong Han, Min Cui, Cheng Huang, Hongli Wang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 24, 8999–9017, https://doi.org/10.5194/acp-24-8999-2024, https://doi.org/10.5194/acp-24-8999-2024, 2024
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Mandatory use of low-sulfur fuel due to global sulfur limit regulations means large uncertainties in volatile organic compound (VOC) emissions. On-board tests of VOCs from nine cargo ships in China were carried out. Results showed that switching from heavy-fuel oil to diesel increased emission factor VOCs by 48 % on average, enhancing O3 and the secondary organic aerosol formation potential. Thus, implementing a global ultra-low-sulfur oil policy needs to be optimized in the near future.
Patrick Dewald, Tobias Seubert, Simone T. Andersen, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Chaoyang Xue, Abdelwahid Mellouki, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 8983–8997, https://doi.org/10.5194/acp-24-8983-2024, https://doi.org/10.5194/acp-24-8983-2024, 2024
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In the scope of a field campaign in a suburban forest near Paris in the summer of 2022, we measured the reactivity of the nitrate radical NO3 towards biogenic volatile organic compounds (BVOCs; e.g. monoterpenes) mainly below but also above the canopy. NO3 reactivity was the highest during nights with strong temperature inversions and decreased strongly with height. Reactions with BVOCs were the main removal process of NO3 throughout the diel cycle below the canopy.
Jian Wang, Lei Xue, Qianyao Ma, Feng Xu, Gaobin Xu, Shibo Yan, Jiawei Zhang, Jianlong Li, Honghai Zhang, Guiling Zhang, and Zhaohui Chen
Atmos. Chem. Phys., 24, 8721–8736, https://doi.org/10.5194/acp-24-8721-2024, https://doi.org/10.5194/acp-24-8721-2024, 2024
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This study investigated the distribution and sources of non-methane hydrocarbons (NMHCs) in the lower atmosphere over the marginal seas of China. NMHCs, a subset of volatile organic compounds (VOCs), play a crucial role in atmospheric chemistry. Derived from systematic atmospheric sampling in coastal cities and marginal sea regions, this study offers valuable insights into the interaction between land and sea in shaping offshore atmospheric NMHCs.
Yusheng Zhang, Feixue Zheng, Zemin Feng, Chaofan Lian, Weigang Wang, Xiaolong Fan, Wei Ma, Zhuohui Lin, Chang Li, Gen Zhang, Chao Yan, Ying Zhang, Veli-Matti Kerminen, Federico Bianch, Tuukka Petäjä, Juha Kangasluoma, Markku Kulmala, and Yongchun Liu
Atmos. Chem. Phys., 24, 8569–8587, https://doi.org/10.5194/acp-24-8569-2024, https://doi.org/10.5194/acp-24-8569-2024, 2024
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The nitrous acid (HONO) budget was validated during a COVID-19 lockdown event. The main conclusions are (1) HONO concentrations showed a significant decrease from 0.97 to 0.53 ppb during lockdown; (2) vehicle emissions accounted for 53 % of nighttime sources, with the heterogeneous conversion of NO2 on ground surfaces more important than aerosol; and (3) the dominant daytime source shifted from the homogenous reaction between NO and OH (51 %) to nitrate photolysis (53 %) during lockdown.
Dong Zhang, Xiao Li, Minghao Yuan, Yifei Xu, Qixiang Xu, Fangcheng Su, Shenbo Wang, and Ruiqin Zhang
Atmos. Chem. Phys., 24, 8549–8567, https://doi.org/10.5194/acp-24-8549-2024, https://doi.org/10.5194/acp-24-8549-2024, 2024
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The increasing concentration of O3 precursors and unfavorable meteorological conditions are key factors in the formation of O3 pollution in Zhengzhou. Vehicular exhausts (28 %), solvent usage (27 %), and industrial production (22 %) are identified as the main sources of NMVOCs. Moreover, O3 formation in Zhengzhou is found to be in an anthropogenic volatile organic compound (AVOC)-limited regime. Thus, to reduce O3 formation, a minimum AVOCs / NOx reduction ratio ≥ 3 : 1 is recommended.
Yuening Li, Faqiang Zhan, Chubashini Shunthirasingham, Ying Duan Lei, Jenny Oh, Amina Ben Chaaben, Zhe Lu, Kelsey Lee, Frank A. P. C. Gobas, Hayley Hung, and Frank Wania
EGUsphere, https://doi.org/10.5194/egusphere-2024-1883, https://doi.org/10.5194/egusphere-2024-1883, 2024
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Organophosphate esters are important man-made trace contaminants. Measuring them in the atmospheric gas phase, particles, precipitation and surface water from Canada, we explore seasonal concentration variability, gas/particle partitioning, precipitation scavenging, and air-water equilibrium. Whereas higher concentrations in summer and efficient precipitation scavenging conform with expectations, the lack of a relationship between compound volatility and gas-particle partitioning is puzzling.
Xiansheng Liu, Xun Zhang, Marvin Dufresne, Tao Wang, Lijie Wu, Rosa Lara, Roger Seco , Marta Monge, Ana Maria Yáñez-Serrano, Marie Gohy, Paul Petit, Audrey Chevalier, Marie-Pierre Vagnot, Yann Fortier, Alexia Baudic, Véronique Ghersi, Grégory Gille, Ludovic Lanzi, Valérie Gros, Leïla Simon, Heidi Hellen, Stefan Reimann, Zoé Le Bras, Michelle Jessy Müller, David Beddows, Siqi Hou, Zongbo Shi, Roy M. Harrison, William Bloss, James Dernie, Stéphane Sauvage, Philip K. Hopke, Xiaoli Duan, Taicheng An, Alastair Lewis, Jim Hopkins, Eleni Liakakou, Nikolaos Mihalopoulos, Xiaohu Zhang, Andrés Alastuey, Xavier Querol, and Thérèse Salameh
EGUsphere, https://doi.org/10.5194/egusphere-2024-2309, https://doi.org/10.5194/egusphere-2024-2309, 2024
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This study examines BTEX (benzene, toluene, ethylbenzene, xylenes) pollution in urban areas across 7 European countries. Analyzing data from 22 monitoring sites, we found traffic and industrial activities significantly impact BTEX levels, with peaks during rush hours. Despite improvements, the risk from BTEX exposure remains moderate, especially in high-traffic and industrial zones. It highlights the need for targeted air quality management to protect public health and improve urban air quality.
Fanhao Meng, Baobin Han, Min Qin, Wu Fang, Ke Tang, Dou Shao, Zhitang Liao, Jun Duan, Yan Feng, Yong Huang, Ting Ni, and Pinhua Xie
EGUsphere, https://doi.org/10.5194/egusphere-2024-2127, https://doi.org/10.5194/egusphere-2024-2127, 2024
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Comprehensive observations of HONO and NOx fluxes were first performed over paddy fields in the Huaihe River Basin. The consecutive peaks in HONO flux and NO flux demonstrated a potentially enhanced release of HONO and NO due to soil tillage, whereas higher WFPS (~80 %) inhibited microbial processes following irrigation. Notably, the biological processes and light-driven NO2 reactions on the surface could both be sources of HONO and influence the local HONO budget during rotary tillage.
Delaney B. Kilgour, Christopher M. Jernigan, Olga Garmash, Sneha Aggarwal, Claudia Mohr, Matt E. Salter, Joel A. Thornton, Jian Wang, Paul Zieger, and Timothy H. Bertram
EGUsphere, https://doi.org/10.5194/egusphere-2024-1975, https://doi.org/10.5194/egusphere-2024-1975, 2024
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We report simultaneous measurements of dimethyl sulfide (DMS) and hydroperoxymethyl thioformate (HPMTF) in the Eastern North Atlantic. We use an observationally constrained box model to show cloud loss is the dominant sink of HPMTF in this region over six weeks, resulting in large reductions in DMS-derived products that contribute to aerosol formation and growth. Our findings indicate that fast cloud processing of HPMTF must be included in global models to accurately capture the sulfur cycle.
Arianna Peron, Martin Graus, Marcus Striednig, Christian Lamprecht, Georg Wohlfahrt, and Thomas Karl
Atmos. Chem. Phys., 24, 7063–7083, https://doi.org/10.5194/acp-24-7063-2024, https://doi.org/10.5194/acp-24-7063-2024, 2024
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The anthropogenic fraction of non-methane volatile organic compound (NMVOC) emissions associated with biogenic sources (e.g., terpenes) is investigated based on eddy covariance observations. The anthropogenic fraction of terpene emissions is strongly dependent on season. When analyzing volatile chemical product (VCP) emissions in urban environments, we caution that observations from short-term campaigns might over-/underestimate their significance depending on local and seasonal circumstances.
Sihang Wang, Bin Yuan, Xianjun He, Ru Cui, Xin Song, Yubin Chen, Caihong Wu, Chaomin Wang, Yibo Huangfu, Xiao-Bing Li, Boguang Wang, and Min Shao
Atmos. Chem. Phys., 24, 7101–7121, https://doi.org/10.5194/acp-24-7101-2024, https://doi.org/10.5194/acp-24-7101-2024, 2024
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Emissions of reactive organic gases from industrial volatile chemical product sources are measured. There are large differences among these industrial sources. We show that oxygenated species account for significant contributions to reactive organic gas emissions, especially for industrial sources utilizing water-borne chemicals.
Qing Yang, Xiao-Bing Li, Bin Yuan, Xiaoxiao Zhang, Yibo Huangfu, Lei Yang, Xianjun He, Jipeng Qi, and Min Shao
Atmos. Chem. Phys., 24, 6865–6882, https://doi.org/10.5194/acp-24-6865-2024, https://doi.org/10.5194/acp-24-6865-2024, 2024
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Online vertical gradient measurements of formic and isocyanic acids were made based on a 320 m tower in a megacity. Vertical variations and sources of the two acids were analyzed in this study. We find that formic and isocyanic acids exhibited positive vertical gradients and were mainly contributed by photochemical formations. The formation of formic and isocyanic acids was also significantly enhanced in urban regions aloft.
Junwei Song, Harald Saathoff, Feng Jiang, Linyu Gao, Hengheng Zhang, and Thomas Leisner
Atmos. Chem. Phys., 24, 6699–6717, https://doi.org/10.5194/acp-24-6699-2024, https://doi.org/10.5194/acp-24-6699-2024, 2024
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This study presents concurrent online measurements of organic gas and particles (VOCs and OA) at a forested site in summer. Both VOCs and OA were largely contributed by oxygenated organic compounds. Semi-volatile oxygenated OA and organic nitrate formed from monoterpenes and sesquiterpenes contributed significantly to nighttime particle growth. The results help us to understand the causes of nighttime particle growth regularly observed in summer in central European rural forested environments.
Jiemeng Bao, Xin Zhang, Zhenhai Wu, Li Zhou, Jun Qian, Qinwen Tan, Fumo Yang, Junhui Chen, Yunfeng Li, Hefan Liu, Liqun Deng, and Hong Li
EGUsphere, https://doi.org/10.5194/egusphere-2024-1204, https://doi.org/10.5194/egusphere-2024-1204, 2024
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Our research in the Chengdu Plain Urban Agglomeration (CPUA), China, reveals significant correlations between carbonyl compounds and ozone pollution, particularly in Chengdu. Formaldehyde, acetone, and acetaldehyde are key contributors to ozone formation. Urgent collaborative actions among cities are needed to mitigate carbonyl-related ozone pollution, stressing the control of NOx and VOCs emissions. Our study offers crucial insights for crafting effective regional pollution control strategies.
Xin Yang, Kimberly Strong, Alison S. Criscitiello, Marta Santos-Garcia, Kristof Bognar, Xiaoyi Zhao, Pierre Fogal, Kaley A. Walker, Sara M. Morris, and Peter Effertz
Atmos. Chem. Phys., 24, 5863–5886, https://doi.org/10.5194/acp-24-5863-2024, https://doi.org/10.5194/acp-24-5863-2024, 2024
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This study uses snow samples collected from a Canadian high Arctic site, Eureka, to demonstrate that surface snow in early spring is a net sink of atmospheric bromine and nitrogen. Surface snow bromide and nitrate are significantly correlated, indicating the oxidation of reactive nitrogen is accelerated by reactive bromine. In addition, we show evidence that snow photochemical release of reactive bromine is very weak, and its emission flux is much smaller than the deposition flux of bromide.
Rebecca M. Garland, Katye E. Altieri, Laura Dawidowski, Laura Gallardo, Aderiana Mbandi, Nestor Y. Rojas, and N'datchoh E. Touré
Atmos. Chem. Phys., 24, 5757–5764, https://doi.org/10.5194/acp-24-5757-2024, https://doi.org/10.5194/acp-24-5757-2024, 2024
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This opinion piece focuses on two geographical areas in the Global South where the authors are based that are underrepresented in atmospheric science. This opinion provides context on common challenges and constraints, with suggestions on how the community can address these. The focus is on the strengths of atmospheric science research in these regions. It is these strengths, we believe, that highlight the critical role of Global South researchers in the future of atmospheric science research.
Heidi Hellén, Rostislav Kouznetsov, Kaisa Kraft, Jukka Seppälä, Mika Vestenius, Jukka-Pekka Jalkanen, Lauri Laakso, and Hannele Hakola
Atmos. Chem. Phys., 24, 4717–4731, https://doi.org/10.5194/acp-24-4717-2024, https://doi.org/10.5194/acp-24-4717-2024, 2024
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Mixing ratios of C2-C5 NMHCs and methanethiol were measured on an island in the Baltic Sea using an in situ gas chromatograph. Shipping emissions were found to be an important source of ethene, ethyne, propene, and benzene. High summertime mixing ratios of methanethiol and dependence of mixing ratios on seawater temperature and height indicated the biogenic origin to possibly be phytoplankton or macroalgae. These emissions may have a strong impact on SO2 production and new particle formation.
Matthew M. Coggon, Chelsea E. Stockwell, Lu Xu, Jeff Peischl, Jessica B. Gilman, Aaron Lamplugh, Henry J. Bowman, Kenneth Aikin, Colin Harkins, Qindan Zhu, Rebecca H. Schwantes, Jian He, Meng Li, Karl Seltzer, Brian McDonald, and Carsten Warneke
Atmos. Chem. Phys., 24, 4289–4304, https://doi.org/10.5194/acp-24-4289-2024, https://doi.org/10.5194/acp-24-4289-2024, 2024
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Residential and commercial cooking emits pollutants that degrade air quality. Here, ambient observations show that cooking is an important contributor to anthropogenic volatile organic compounds (VOCs) emitted in Las Vegas, NV. These emissions are not fully presented in air quality models, and more work may be needed to quantify emissions from important sources, such as commercial restaurants.
Fabien Paulot, Gabrielle Pétron, Andrew M. Crotwell, and Matteo B. Bertagni
Atmos. Chem. Phys., 24, 4217–4229, https://doi.org/10.5194/acp-24-4217-2024, https://doi.org/10.5194/acp-24-4217-2024, 2024
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New data from the National Oceanic and Atmospheric Administration show that hydrogen (H2) concentrations increased from 2010 to 2019, which is consistent with the simulated increase in H2 photochemical production (mainly from methane). But this cannot be reconciled with the expected decrease (increase) in H2 anthropogenic emissions (soil deposition) in the same period. This shows gaps in our knowledge of the H2 biogeochemical cycle that must be resolved to quantify the impact of higher H2 usage.
Wenjie Wang, Bin Yuan, Hang Su, Yafang Cheng, Jipeng Qi, Sihang Wang, Wei Song, Xinming Wang, Chaoyang Xue, Chaoqun Ma, Fengxia Bao, Hongli Wang, Shengrong Lou, and Min Shao
Atmos. Chem. Phys., 24, 4017–4027, https://doi.org/10.5194/acp-24-4017-2024, https://doi.org/10.5194/acp-24-4017-2024, 2024
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This study investigates the important role of unmeasured volatile organic compounds (VOCs) in ozone formation. Based on results in a megacity of China, we show that unmeasured VOCs can contribute significantly to ozone fomation and also influence the determination of ozone control strategy. Our results show that these unmeasured VOCs are mainly from human sources.
Shigeyuki Ishidoya, Satoshi Sugawara, and Atsushi Okazaki
EGUsphere, https://doi.org/10.5194/egusphere-2024-654, https://doi.org/10.5194/egusphere-2024-654, 2024
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Diurnal, seasonal, and interannual variations of the present-day stable isotopic ratio of atmospheric O2, in other words slight variations in the Dole-Morita effect, have been detected firstly. A box model that incorporated biological and water processes associated with the Dole-Morita effect reproduced the general characteristics of the observational results. Based on the findings, we proposed some applications to evaluate oxygen, carbon, and water cycles.
Romain Salignat, Matti Rissanen, Siddharth Iyer, Jean-Luc Baray, Pierre Tulet, Jean-Marc Metzger, Jérôme Brioude, Karine Sellegri, and Clémence Rose
Atmos. Chem. Phys., 24, 3785–3812, https://doi.org/10.5194/acp-24-3785-2024, https://doi.org/10.5194/acp-24-3785-2024, 2024
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Using mass spectrometry data collected at the Maïdo Observatory (2160 m a.s.l., Réunion), we provide the first detailed analysis of molecular cluster chemical composition specifically in the marine free troposphere. The abundance of the identified species is related both to in situ meteorological parameters and air mass history, which also provide insight into their origin. Our work makes an important contribution to documenting the chemistry and physics of the marine free troposphere.
Delaney B. Kilgour, Gordon A. Novak, Megan S. Claflin, Brian M. Lerner, and Timothy H. Bertram
Atmos. Chem. Phys., 24, 3729–3742, https://doi.org/10.5194/acp-24-3729-2024, https://doi.org/10.5194/acp-24-3729-2024, 2024
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Laboratory experiments with seawater mimics suggest ozone deposition to the surface ocean can be a source of reactive carbon to the marine atmosphere. We conduct both field and laboratory measurements to assess abiotic VOC composition and yields from ozonolysis of real surface seawater. We show that C5–C11 aldehydes contribute to the observed VOC emission flux. We estimate that VOCs generated by the ozonolysis of surface seawater are competitive with biological VOC production and emission.
Xiangdong Zheng, Wen Yang, Yuting Sun, Chunmei Geng, Yingying Liu, and Xiaobin Xu
Atmos. Chem. Phys., 24, 3759–3768, https://doi.org/10.5194/acp-24-3759-2024, https://doi.org/10.5194/acp-24-3759-2024, 2024
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Chen et al. (2022) attributed the nocturnal ozone enhancement (NOE) during the night of 31 July 2021 in the North China Plain (NCP) to "the direct stratospheric intrusion to reach the surface". We analyzed in situ data from the NCP. Our results do not suggest that there was a significant impact from the stratosphere on surface ozone during the NOE. We argue that the NOE was not caused by stratospheric intrusion but originated from fresh photochemical production in the lower troposphere.
James M. Roberts, Siyuan Wang, Patrick R. Veres, J. Andrew Neuman, Michael A. Robinson, Ilann Bourgeois, Jeff Peischl, Thomas B. Ryerson, Chelsea R. Thompson, Hannah M. Allen, John D. Crounse, Paul O. Wennberg, Samuel R. Hall, Kirk Ullmann, Simone Meinardi, Isobel J. Simpson, and Donald Blake
Atmos. Chem. Phys., 24, 3421–3443, https://doi.org/10.5194/acp-24-3421-2024, https://doi.org/10.5194/acp-24-3421-2024, 2024
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We measured cyanogen bromide (BrCN) in the troposphere for the first time. BrCN is a product of the same active bromine chemistry that destroys ozone and removes mercury in polar surface environments and is a previously unrecognized sink for active Br compounds. BrCN has an apparent lifetime against heterogeneous loss in the range 1–10 d, so it serves as a cumulative marker of Br-radical chemistry. Accounting for BrCN chemistry is an important part of understanding polar Br cycling.
Kai Qin, Wei Hu, Qin He, Fan Lu, and Jason Blake Cohen
Atmos. Chem. Phys., 24, 3009–3028, https://doi.org/10.5194/acp-24-3009-2024, https://doi.org/10.5194/acp-24-3009-2024, 2024
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We compute CH4 emissions and uncertainty on a mine-by-mine basis, including underground, overground, and abandoned mines. Mine-by-mine gas and flux data and 30 min observations from a flux tower located next to a mine shaft are integrated. The observed variability and bias correction are propagated over the emissions dataset, demonstrating that daily observations may not cover the range of variability. Comparisons show both an emissions magnitude and spatial mismatch with current inventories.
Yao Yan Huang and D. James Donaldson
Atmos. Chem. Phys., 24, 2387–2398, https://doi.org/10.5194/acp-24-2387-2024, https://doi.org/10.5194/acp-24-2387-2024, 2024
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Ground-level ozone interacts at the lake–land boundary; this is important to our understanding and modelling of atmospheric chemistry and air pollution in the lower atmosphere. We show that a steep ozone gradient occurs year-round moving inland up to 1 km from the lake and that this gradient is influenced by seasonal factors on the local land environment, where more rural areas are more greatly affected seasonally.
Katrin Müller, Jordis S. Tradowsky, Peter von der Gathen, Christoph Ritter, Sharon Patris, Justus Notholt, and Markus Rex
Atmos. Chem. Phys., 24, 2169–2193, https://doi.org/10.5194/acp-24-2169-2024, https://doi.org/10.5194/acp-24-2169-2024, 2024
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The Palau Atmospheric Observatory is introduced as an ideal site to detect changes in atmospheric composition and dynamics above the remote tropical western Pacific. We focus on the ozone sounding program from 2016–2021, including El Niño 2016. The year-round high convective activity is reflected in dominant low tropospheric ozone and high relative humidity. Their seasonal distributions are unique compared to other tropical sites and are modulated by the Intertropical Convergence Zone.
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Short summary
This paper provides an overview of the measurements done at an urban background site in Berlin from June-August of 2014. Results show that natural source contributions to ozone and particulate matter (PM) air pollutants are substantial. Large contributions of secondary aerosols formed in the atmosphere to PM10 concentrations were quantified. An analysis of the sources also identified contributions to PM from plant-based sources, vehicles, and a small contribution from wood burning.
This paper provides an overview of the measurements done at an urban background site in Berlin...
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