Articles | Volume 17, issue 17
Atmos. Chem. Phys., 17, 10405–10421, 2017
https://doi.org/10.5194/acp-17-10405-2017
Atmos. Chem. Phys., 17, 10405–10421, 2017
https://doi.org/10.5194/acp-17-10405-2017

Research article 06 Sep 2017

Research article | 06 Sep 2017

Characterizing source fingerprints and ageing processes in laboratory-generated secondary organic aerosols using proton-nuclear magnetic resonance (1H-NMR) analysis and HPLC HULIS determination

Nicola Zanca et al.

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Cited articles

Baduel, C., Voisin, D., and Jaffrezo, J. L.: Comparison of analytical methods for Humic Like Substances (HULIS) measurements in atmospheric particles, Atmos. Chem. Phys., 9, 5949–5962, https://doi.org/10.5194/acp-9-5949-2009, 2009.
Baltensperger, U., Dommen, J., Alfarra, M. R., Duplissy, J., Gaeggeler, K., Metzger, A., Facchini, M. C., Decesari, S., Finessi, E., Reinnig, C., Schott, M., Warnke, J., Hoffmann, T., Klatzer, B., Puxbaum, H., Geiser, M., Savi, M., Lang, D., Kalberer, M., and Geiser, T.: Combined determination of the chemical composition and of health effects of secondary organic aerosols: the POLYSOA project, J. Aerosol Med Pulm Drug Deliv., 21, 145–154, 2008.
Bessagnet, B., Menut, L., Curci, G., Hodzic, A., Guillaume, B., Liousse, C., Moukhtar, S., Pun, B., Seigneur, C., and Schulz, M.: Regional modeling of carbonaceous aerosols over Europe – focus on secondary organic aerosols, J. Atmos. Chem., 61, 175–202, 2008.
Betts, A. K., Fisch, G., von Randow, C., Silva Dias, M. A. F., Cohen, J. C. P., da Silva, R., and Fitzjarrald, D. R.: The Amazonian boundary layer and mesoscale circulations, in: Amazonia and Global Change, American Geophysical Union, ISBN: 9780875904764, 163–181, 2009.
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Short summary
Simulating the composition of organic aerosol particles formed by chemical reactions in the atmosphere (secondary organic aerosol, SOA) is challenged by the enormous complexity of molecular species and chemical processes involved. We report spectroscopic (NMR) and chromatographic data for SOA samples obtained using a flow reactor designed to simulate photochemical ageing. We show that the composition of aged biogenic (monoterpene) SOA particles closely resembles that of ambient aerosols.
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