Articles | Volume 17, issue 17
https://doi.org/10.5194/acp-17-10405-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-10405-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
06 Sep 2017
Research article |
| 06 Sep 2017
Characterizing source fingerprints and ageing processes in laboratory-generated secondary organic aerosols using proton-nuclear magnetic resonance (1H-NMR) analysis and HPLC HULIS determination
Nicola Zanca
CORRESPONDING AUTHOR
Institute of Atmospheric Sciences and Climate (ISAC) of the National
Research Council of Italy (CNR), Bologna, 40129, Italy
Proambiente S.c.r.l., Bologna, 40129, Italy
Andrew T. Lambe
Aerodyne Research Inc., Billerica, MA 01821, USA
Chemistry Department, Boston College, Chestnut Hill, MA 02467, USA
Paola Massoli
Aerodyne Research Inc., Billerica, MA 01821, USA
Marco Paglione
Institute of Atmospheric Sciences and Climate (ISAC) of the National
Research Council of Italy (CNR), Bologna, 40129, Italy
David R. Croasdale
Chemistry Department, Boston College, Chestnut Hill, MA 02467, USA
Yatish Parmar
Chemistry Department, Boston College, Chestnut Hill, MA 02467, USA
Emilio Tagliavini
Department of Chemistry “Giacomo Ciamician”, University of Bologna,
Bologna, 40126, Italy
Stefania Gilardoni
Institute of Atmospheric Sciences and Climate (ISAC) of the National
Research Council of Italy (CNR), Bologna, 40129, Italy
Stefano Decesari
Institute of Atmospheric Sciences and Climate (ISAC) of the National
Research Council of Italy (CNR), Bologna, 40129, Italy
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Cited
15 citations as recorded by crossref.
- Iron and Copper Alter the Oxidative Potential of Secondary Organic Aerosol: Insights from Online Measurements and Model Development S. Campbell et al. 10.1021/acs.est.3c01975
- NMR spectroscopic applications to atmospheric organic aerosol analysis – Part 2: A review of existing methodologies and perspectives E. Tagliavini et al. 10.1016/j.trac.2024.117595
- Green synthesis of spermine coated iron nanoparticles and its effect on biochemical properties of Rosmarinus officinalis M. Afrouz et al. 10.1038/s41598-023-27844-5
- Molecular composition and optical property of humic-like substances (HULIS) in winter-time PM2.5 in the rural area of North China Plain H. Sun et al. 10.1016/j.atmosenv.2021.118316
- Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. 10.3390/atmos13040507
- Pathogenic Mechanisms of Secondary Organic Aerosols T. Déméautis et al. 10.1021/acs.chemrestox.1c00353
- Reactive Uptake of Isoprene Epoxydiols Increases the Viscosity of the Core of Phase-Separated Aerosol Particles N. Olson et al. 10.1021/acsearthspacechem.9b00138
- pH-Dependent Chemical Transformations of Humic-Like Substances and Further Cognitions Revealed by Optical Methods J. Qin et al. 10.1021/acs.est.1c07729
- Mechanistic insight into the kinetic fragmentation of norpinonic acid in the gas phase: an experimental and density functional theory (DFT) study I. Kurzydym et al. 10.5194/acp-24-9309-2024
- Detection of naphthalene in sea-water by a label-free plasmonic optical fiber biosensor N. Cennamo et al. 10.1016/j.talanta.2018.10.051
- Exposure of Lung Epithelial Cells to Photochemically Aged Secondary Organic Aerosol Shows Increased Toxic Effects P. Chowdhury et al. 10.1021/acs.estlett.8b00256
- Comprehensive characterizations of HULIS in fresh and secondary emissions of crop straw burning Y. Huo et al. 10.1016/j.atmosenv.2021.118220
- Measurement report: Particle-size-dependent fluorescence properties of water-soluble organic compounds (WSOCs) and their atmospheric implications for the aging of WSOCs J. Qin et al. 10.5194/acp-22-465-2022
- Measurement report: Effects of transition metal ions on the optical properties of humic-like substances (HULIS) reveal a structural preference – a case study of PM2.5 in Beijing, China J. Qin et al. 10.5194/acp-24-7575-2024
- NMR spectroscopic applications to atmospheric organic aerosol analysis – Part 1: A critical review of data source and analysis, potentialities and limitations S. Decesari et al. 10.1016/j.trac.2023.117516
15 citations as recorded by crossref.
- Iron and Copper Alter the Oxidative Potential of Secondary Organic Aerosol: Insights from Online Measurements and Model Development S. Campbell et al. 10.1021/acs.est.3c01975
- NMR spectroscopic applications to atmospheric organic aerosol analysis – Part 2: A review of existing methodologies and perspectives E. Tagliavini et al. 10.1016/j.trac.2024.117595
- Green synthesis of spermine coated iron nanoparticles and its effect on biochemical properties of Rosmarinus officinalis M. Afrouz et al. 10.1038/s41598-023-27844-5
- Molecular composition and optical property of humic-like substances (HULIS) in winter-time PM2.5 in the rural area of North China Plain H. Sun et al. 10.1016/j.atmosenv.2021.118316
- Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. 10.3390/atmos13040507
- Pathogenic Mechanisms of Secondary Organic Aerosols T. Déméautis et al. 10.1021/acs.chemrestox.1c00353
- Reactive Uptake of Isoprene Epoxydiols Increases the Viscosity of the Core of Phase-Separated Aerosol Particles N. Olson et al. 10.1021/acsearthspacechem.9b00138
- pH-Dependent Chemical Transformations of Humic-Like Substances and Further Cognitions Revealed by Optical Methods J. Qin et al. 10.1021/acs.est.1c07729
- Mechanistic insight into the kinetic fragmentation of norpinonic acid in the gas phase: an experimental and density functional theory (DFT) study I. Kurzydym et al. 10.5194/acp-24-9309-2024
- Detection of naphthalene in sea-water by a label-free plasmonic optical fiber biosensor N. Cennamo et al. 10.1016/j.talanta.2018.10.051
- Exposure of Lung Epithelial Cells to Photochemically Aged Secondary Organic Aerosol Shows Increased Toxic Effects P. Chowdhury et al. 10.1021/acs.estlett.8b00256
- Comprehensive characterizations of HULIS in fresh and secondary emissions of crop straw burning Y. Huo et al. 10.1016/j.atmosenv.2021.118220
- Measurement report: Particle-size-dependent fluorescence properties of water-soluble organic compounds (WSOCs) and their atmospheric implications for the aging of WSOCs J. Qin et al. 10.5194/acp-22-465-2022
- Measurement report: Effects of transition metal ions on the optical properties of humic-like substances (HULIS) reveal a structural preference – a case study of PM2.5 in Beijing, China J. Qin et al. 10.5194/acp-24-7575-2024
- NMR spectroscopic applications to atmospheric organic aerosol analysis – Part 1: A critical review of data source and analysis, potentialities and limitations S. Decesari et al. 10.1016/j.trac.2023.117516
Latest update: 15 Nov 2024
Short summary
Simulating the composition of organic aerosol particles formed by chemical reactions in the atmosphere (secondary organic aerosol, SOA) is challenged by the enormous complexity of molecular species and chemical processes involved. We report spectroscopic (NMR) and chromatographic data for SOA samples obtained using a flow reactor designed to simulate photochemical ageing. We show that the composition of aged biogenic (monoterpene) SOA particles closely resembles that of ambient aerosols.
Simulating the composition of organic aerosol particles formed by chemical reactions in the...
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