Articles | Volume 23, issue 21
https://doi.org/10.5194/acp-23-13585-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-13585-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
01 Nov 2023
Research article |
| 01 Nov 2023
| 01 Nov 2023
Molecular fingerprints and health risks of smoke from home-use incense burning
Kai Song
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Nanjing University of Information Science & Technology, Nanjing 210044, China
School of Energy and Environment, City University of Hong Kong, Kowloon 999077, Hong Kong SAR, China
Shenzhen Research Institute, City University of Hong Kong, Shenzhen 518057, China
Jingshun Zhang
Department of Investigation, Shanghai Police College, Shanghai 200137, China
Zichao Wan
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
Yuan Zhang
School of Earth Science and Engineering, Hebei University of Engineering, Handan 056038, China
Kun Hu
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
Yuanzheng Gong
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
Daqi Lv
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
Sihua Lu
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
Yu Tan
School of Chemical Engineering and Technology, Sun-Yat-Sen University, Zhuhai 519000, China
Ruifeng Zhang
School of Energy and Environment, City University of Hong Kong, Kowloon 999077, Hong Kong SAR, China
Shenzhen Research Institute, City University of Hong Kong, Shenzhen 518057, China
Ang Li
China Automotive Technology and Research Center (CATARC), Beijing 100176, China
Shuyuan Yan
China Automotive Technology and Research Center (CATARC), Beijing 100176, China
Shichao Yan
China Automotive Technology and Research Center (CATARC), Beijing 100176, China
Baoming Fan
TECHSHIP (Beijing) Technology Co., LTD, Beijing 100039, China
Wenfei Zhu
School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
Chak K. Chan
School of Energy and Environment, City University of Hong Kong, Kowloon 999077, Hong Kong SAR, China
Shenzhen Research Institute, City University of Hong Kong, Shenzhen 518057, China
Maosheng Yao
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Nanjing University of Information Science & Technology, Nanjing 210044, China
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Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-838, https://doi.org/10.5194/acp-2022-838, 2022
Preprint withdrawn
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Atmos. Meas. Tech., 15, 6807–6817, https://doi.org/10.5194/amt-15-6807-2022, https://doi.org/10.5194/amt-15-6807-2022, 2022
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Gang Zhao, Tianyi Tan, Shuya Hu, Zhuofei Du, Dongjie Shang, Zhijun Wu, Song Guo, Jing Zheng, Wenfei Zhu, Mengren Li, Limin Zeng, and Min Hu
Atmos. Chem. Phys., 22, 10861–10873, https://doi.org/10.5194/acp-22-10861-2022, https://doi.org/10.5194/acp-22-10861-2022, 2022
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Black carbon is the second strongest absorbing component in the atmosphere that exerts warming effects on climate. One critical challenge in quantifying the ambient black carbon's radiative effects is addressing the BC microphysical properties. In this study, the microphysical properties of the aged and fresh BC particles are synthetically analyzed under different atmospheres. The measurement results can be further used in models to help constrain the uncertainties of the BC radiative effects.
Kai Song, Song Guo, Yuanzheng Gong, Daqi Lv, Yuan Zhang, Zichao Wan, Tianyu Li, Wenfei Zhu, Hui Wang, Ying Yu, Rui Tan, Ruizhe Shen, Sihua Lu, Shuangde Li, Yunfa Chen, and Min Hu
Atmos. Chem. Phys., 22, 9827–9841, https://doi.org/10.5194/acp-22-9827-2022, https://doi.org/10.5194/acp-22-9827-2022, 2022
Short summary
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Emissions from four typical Chinese domestic cooking and fried chicken using four kinds of oils were investigated to illustrate the impact of cooking style and oil. Of the estimated SOA, 10.2 %–32.0 % could be explained by S/IVOC oxidation. Multiway principal component analysis (MPCA) emphasizes the importance of the unsaturated fatty acid-alkadienal volatile product mechanism (oil autoxidation) accelerated by the cooking and heating procedure.
Cuiqi Zhang, Zhijun Wu, Jingchuan Chen, Jie Chen, Lizi Tang, Wenfei Zhu, Xiangyu Pei, Shiyi Chen, Ping Tian, Song Guo, Limin Zeng, Min Hu, and Zamin A. Kanji
Atmos. Chem. Phys., 22, 7539–7556, https://doi.org/10.5194/acp-22-7539-2022, https://doi.org/10.5194/acp-22-7539-2022, 2022
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The immersion ice nucleation effectiveness of aerosols from multiple sources in the urban environment remains elusive. In this study, we demonstrate that the immersion ice-nucleating particle (INP) concentration increased dramatically during a dust event in an urban atmosphere. Pollutant aerosols, including inorganic salts formed through secondary transformation (SIA) and black carbon (BC), might not act as effective INPs under mixed-phase cloud conditions.
Yuanzheng Gong, Kai Song, Song Guo, Daqi Lv, Yuan Zhang, Zichao Wan, Wenfei Zhu, Hui Wang, Ying Yu, Rui Tan, Ruizhe Shen, Sihua Lu, Shuangde Li, and Yunfa Chen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-326, https://doi.org/10.5194/acp-2022-326, 2022
Preprint withdrawn
Short summary
Short summary
Herein we applied thermal desorption comprehensive two-dimensional gas chromatography-mass spectrometer (TD-GCxGC-MS) for synchronous analysis of gaseous and particulate organics emitted from cooking fumes. With a systematic 4-step qualitative procedure and precise quantitative and semi-quantitative method, 170 and 352 compounds from C2 (acetic acids) – C30 (squalene) occupying 95 % and 90 % of the total ion current for gaseous and particulate samples were identified and quantified.
Haoran Zhang, Nan Li, Keqin Tang, Hong Liao, Chong Shi, Cheng Huang, Hongli Wang, Song Guo, Min Hu, Xinlei Ge, Mindong Chen, Zhenxin Liu, Huan Yu, and Jianlin Hu
Atmos. Chem. Phys., 22, 5495–5514, https://doi.org/10.5194/acp-22-5495-2022, https://doi.org/10.5194/acp-22-5495-2022, 2022
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We developed a new algorithm with low economic/technique costs to identify primary and secondary components of PM2.5. Our model was shown to be reliable by comparison with different observation datasets. We systematically explored the patterns and changes in the secondary PM2.5 pollution in China at large spatial and time scales. We believe that this method is a promising tool for efficiently estimating primary and secondary PM2.5, and has huge potential for future PM mitigation.
Yun Lin, Yuan Wang, Bowen Pan, Jiaxi Hu, Song Guo, Misti Levy Zamora, Pengfei Tian, Qiong Su, Yuemeng Ji, Jiayun Zhao, Mario Gomez-Hernandez, Min Hu, and Renyi Zhang
Atmos. Chem. Phys., 22, 4951–4967, https://doi.org/10.5194/acp-22-4951-2022, https://doi.org/10.5194/acp-22-4951-2022, 2022
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Severe regional haze events, which are characterized by exceedingly high levels of fine particulate matter (PM), occur frequently in many developing countries (such as China and India), with profound implications for human health, weather, and climate. Our work establishes a synthetic view for the dominant regional features during severe haze events, unraveling rapid in situ PM production and inefficient transport, both of which are amplified by atmospheric stagnation.
Zhancong Liang, Yangxi Chu, Masao Gen, and Chak K. Chan
Atmos. Chem. Phys., 22, 3017–3044, https://doi.org/10.5194/acp-22-3017-2022, https://doi.org/10.5194/acp-22-3017-2022, 2022
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The properties and fate of individual airborne particles can be significantly different, leading to distinct environmental impacts (e.g., climate and human health). While many instruments only analyze an ensemble of these particles, single-particle Raman spectroscopy enables unambiguous characterization of individual particles. This paper comprehensively reviews the applications of such a technique in studying atmospheric particles, especially for their physicochemical processing.
Shang Gao, Mona Kurppa, Chak K. Chan, and Keith Ngan
Atmos. Chem. Phys., 22, 2703–2726, https://doi.org/10.5194/acp-22-2703-2022, https://doi.org/10.5194/acp-22-2703-2022, 2022
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The contribution of cooking emissions to organic aerosols may exceed that of motor vehicles. However, little is known about how cooking-generated aerosols evolve in the outdoor environment. In this paper, we present a numerical study of the dispersion of cooking emissions. For plausible choices of the emission strength, cooking can yield much higher concentrations than traffic. This has important implications for public health and city planning.
Brix Raphael Go, Yan Lyu, Yan Ji, Yong Jie Li, Dan Dan Huang, Xue Li, Theodora Nah, Chun Ho Lam, and Chak K. Chan
Atmos. Chem. Phys., 22, 273–293, https://doi.org/10.5194/acp-22-273-2022, https://doi.org/10.5194/acp-22-273-2022, 2022
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Biomass burning (BB) is a global phenomenon that releases large quantities of pollutants such as phenols and aromatic carbonyls into the atmosphere. These compounds can form secondary organic aerosols (SOAs) which play an important role in the Earth’s energy budget. In this work, we demonstrated that the direct irradiation of vanillin (VL) could generate aqueous SOA (aqSOA) such as oligomers. In the presence of nitrate, VL photo-oxidation can also form nitrated compounds.
Zirui Zhang, Wenfei Zhu, Min Hu, Kefan Liu, Hui Wang, Rongzhi Tang, Ruizhe Shen, Ying Yu, Rui Tan, Kai Song, Yuanju Li, Wenbin Zhang, Zhou Zhang, Hongming Xu, Shijin Shuai, Shuangde Li, Yunfa Chen, Jiayun Li, Yuesi Wang, and Song Guo
Atmos. Chem. Phys., 21, 15221–15237, https://doi.org/10.5194/acp-21-15221-2021, https://doi.org/10.5194/acp-21-15221-2021, 2021
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We comprehensively investigated the mass growth potential, oxidation degree, formation pathway, and mass spectra features of typical urban-lifestyle secondary organic aerosols (SOAs) including vehicle SOAs and cooking SOAs. The mass spectra we acquired could provide necessary references to estimate the mass fractions of vehicle and cooking SOAs in the atmosphere, which would greatly decrease the uncertainty in air quality evaluation and health risk assessment in urban areas.
Wenfei Zhu, Song Guo, Zirui Zhang, Hui Wang, Ying Yu, Zheng Chen, Ruizhe Shen, Rui Tan, Kai Song, Kefan Liu, Rongzhi Tang, Yi Liu, Shengrong Lou, Yuanju Li, Wenbin Zhang, Zhou Zhang, Shijin Shuai, Hongming Xu, Shuangde Li, Yunfa Chen, Min Hu, Francesco Canonaco, and Andre S. H. Prévôt
Atmos. Chem. Phys., 21, 15065–15079, https://doi.org/10.5194/acp-21-15065-2021, https://doi.org/10.5194/acp-21-15065-2021, 2021
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The experiments of primary emissions and secondary organic aerosol (SOA) formation from urban lifestyle sources (cooking and vehicles) were conducted. The mass spectral features of primary organic aerosol (POA) and SOA were characterized by using a high-resolution time-of-flight aerosol mass spectrometer. This work, for the first time, establishes the vehicle and cooking SOA source profiles and can be further used as source constraints in the OA source apportionment in the ambient atmosphere.
Haijie Tong, Fobang Liu, Alexander Filippi, Jake Wilson, Andrea M. Arangio, Yun Zhang, Siyao Yue, Steven Lelieveld, Fangxia Shen, Helmi-Marja K. Keskinen, Jing Li, Haoxuan Chen, Ting Zhang, Thorsten Hoffmann, Pingqing Fu, William H. Brune, Tuukka Petäjä, Markku Kulmala, Maosheng Yao, Thomas Berkemeier, Manabu Shiraiwa, and Ulrich Pöschl
Atmos. Chem. Phys., 21, 10439–10455, https://doi.org/10.5194/acp-21-10439-2021, https://doi.org/10.5194/acp-21-10439-2021, 2021
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We measured radical yields of aqueous PM2.5 extracts and found lower yields at higher concentrations of PM2.5. Abundances of water-soluble transition metals and aromatics in PM2.5 were positively correlated with the relative fraction of •OH but negatively correlated with the relative fraction of C-centered radicals among detected radicals. Composition-dependent reactive species yields may explain differences in the reactivity and health effects of PM2.5 in clean versus polluted air.
Tianyi Tan, Min Hu, Zhuofei Du, Gang Zhao, Dongjie Shang, Jing Zheng, Yanhong Qin, Mengren Li, Yusheng Wu, Limin Zeng, Song Guo, and Zhijun Wu
Atmos. Chem. Phys., 21, 8499–8510, https://doi.org/10.5194/acp-21-8499-2021, https://doi.org/10.5194/acp-21-8499-2021, 2021
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Every year in the pre-monsoon season, the black carbon (BC) aerosols originated from biomass burning in southern Asia are easily transported to the Tibetan Plateau (TP) by the convenience of westerly wind. This study reveals that the BC aerosols in the aged biomass burning plumes strongly enhance the total light absorption over the TP, and the aging process during the long-range transport will further strengthen the radiative heating of those BC aerosols.
Kai Song, Song Guo, Haichao Wang, Ying Yu, Hui Wang, Rongzhi Tang, Shiyong Xia, Yuanzheng Gong, Zichao Wan, Daqi Lv, Rui Tan, Wenfei Zhu, Ruizhe Shen, Xin Li, Xuena Yu, Shiyi Chen, Liming Zeng, and Xiaofeng Huang
Atmos. Chem. Phys., 21, 7917–7932, https://doi.org/10.5194/acp-21-7917-2021, https://doi.org/10.5194/acp-21-7917-2021, 2021
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Nitrated phenols (NPs) are crucial components of brown carbon. To comprehend the constitutes and sources of NPs in winter of Beijing, their concentrations were measured by a CI-LToF-MS. The secondary formation process was simulated by a box model. NPs were mainly influenced by primary emissions and regional transport. Primary emitted phenol rather than benzene oxidation was crucial in the heavy pollution episode in Beijing. This provides more insight into pollution control strategies of NPs.
Yao Wang, Yue Zhao, Yuchen Wang, Jian-Zhen Yu, Jingyuan Shao, Ping Liu, Wenfei Zhu, Zhen Cheng, Ziyue Li, Naiqiang Yan, and Huayun Xiao
Atmos. Chem. Phys., 21, 2959–2980, https://doi.org/10.5194/acp-21-2959-2021, https://doi.org/10.5194/acp-21-2959-2021, 2021
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Organosulfates (OSs) are important constituents and tracers of secondary organic aerosols (SOAs) in the atmosphere. Here we characterized the OS species in ambient aerosols in Shanghai, China. We find that the contributions of OSs and SOAs to organic aerosols have increased in recent years and that OS production was largely controlled by the oxidant level (Ox), particularly in summer. We infer that mitigation of Ox pollution can effectively reduce the production of OSs and SOAs in eastern China.
Rongzhi Tang, Quanyang Lu, Song Guo, Hui Wang, Kai Song, Ying Yu, Rui Tan, Kefan Liu, Ruizhe Shen, Shiyi Chen, Limin Zeng, Spiro D. Jorga, Zhou Zhang, Wenbin Zhang, Shijin Shuai, and Allen L. Robinson
Atmos. Chem. Phys., 21, 2569–2583, https://doi.org/10.5194/acp-21-2569-2021, https://doi.org/10.5194/acp-21-2569-2021, 2021
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We performed chassis dynamometer experiments to investigate the emissions and secondary organic aerosol (SOA) formation potential of intermediate volatility organic compounds (IVOCs) from an on-road Chinese gasoline vehicle. High IVOC emission factors (EFs) and distinct volatility distribution were recognized. Our results indicate that vehicular IVOCs contribute significantly to SOA, implying the importance of reducing IVOCs when making air pollution control policies in urban areas of China.
Christian Mark Garcia Salvador, Rongzhi Tang, Michael Priestley, Linjie Li, Epameinondas Tsiligiannis, Michael Le Breton, Wenfei Zhu, Limin Zeng, Hui Wang, Ying Yu, Min Hu, Song Guo, and Mattias Hallquist
Atmos. Chem. Phys., 21, 1389–1406, https://doi.org/10.5194/acp-21-1389-2021, https://doi.org/10.5194/acp-21-1389-2021, 2021
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High-frequency online measurement of gas- and particle-phase nitro-aromatic compounds (NACs) at a rural site in China, heavily influenced by biomass burning events, enabled the analysis of the production pathway of NACs, including an explanation of strong persistence in the daytime. The contribution of secondary processes was significant, even during the dominant wintertime influence of primary emissions, suggesting the important role of regional secondary chemistry, i.e. photochemical smog.
Wenjie Wang, David D. Parrish, Xin Li, Min Shao, Ying Liu, Ziwei Mo, Sihua Lu, Min Hu, Xin Fang, Yusheng Wu, Limin Zeng, and Yuanhang Zhang
Atmos. Chem. Phys., 20, 15617–15633, https://doi.org/10.5194/acp-20-15617-2020, https://doi.org/10.5194/acp-20-15617-2020, 2020
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During the past decade, China has devoted very substantial resources to improving the environment. These efforts have improved atmospheric particulate matter loading, but ambient ozone levels have continued to increase. In this paper we investigate the causes of the increasing ozone concentrations through analysis of a data set that is, to our knowledge, unique: a 12-year data set including ground-level O3, NOx, and VOC precursors collected at an urban site in Beijing.
Sarah E. Benish, Hao He, Xinrong Ren, Sandra J. Roberts, Ross J. Salawitch, Zhanqing Li, Fei Wang, Yuying Wang, Fang Zhang, Min Shao, Sihua Lu, and Russell R. Dickerson
Atmos. Chem. Phys., 20, 14523–14545, https://doi.org/10.5194/acp-20-14523-2020, https://doi.org/10.5194/acp-20-14523-2020, 2020
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Airborne observations of ozone and related pollutants show smog was pervasive in spring 2016 over Hebei Province, China. We find high amounts of ozone precursors throughout and even above the PBL, continuing to generate ozone at high rates to be potentially transported downwind. Concentrations even in the rural areas of this highly industrialized province promote widespread ozone production, and we show that to improve air quality over Hebei both NOx and VOCs should be targeted.
Cited articles
Ahmad, T., Kenne, L., Olsson, K., and Theander, O.: The formation of 2-furaldehyde and formic acid from pentoses in slightly acidic deuterium oxide studied by 1H NMR spectroscopy, Carbohyd. Res., 276, 309–320, https://doi.org/10.1016/0008-6215(95)00176-T, 1995.
Alam, M. S., Zeraati-Rezaei, S., Liang, Z., Stark, C., Xu, H., MacKenzie, A. R., and Harrison, R. M.: Mapping and quantifying isomer sets of hydrocarbons (≥ C12) in diesel exhaust, lubricating oil and diesel fuel samples using GC × GC-ToF-MS, Atmos. Meas. Tech., 11, 3047–3058, https://doi.org/10.5194/amt-11-3047-2018, 2018.
Algrim, L. B. and Ziemann, P. J.: Effect of the Keto Group on Yields and Composition of Organic Aerosol Formed from OH Radical-Initiated Reactions of Ketones in the Presence of NOx, J. Phys. Chem. A, 120, 6978–6989, https://doi.org/10.1021/acs.jpca.6b05839, 2016.
Algrim, L. B. and Ziemann, P. J.: Effect of the Hydroxyl Group on Yields and Composition of Organic Aerosol Formed from OH Radical-Initiated Reactions of Alcohols in the Presence of NOx, ACS Earth Space Chem, 3, 413–423, https://doi.org/10.1021/acsearthspacechem.9b00015, 2019.
Apte, K. and Salvi, S.: Household air pollution and its effects on health, F1000Research, 5, 2593, https://doi.org/10.12688/f1000research.7552.1, 2016.
Bonner, W. A. and Roth, M. R.: The Conversion of D-Xylose-l-C14 into 2-Furaldehyde-α-C14, J. Am. Chem. Soc., 81, 5454–5456, https://doi.org/10.1021/ja01529a051, 1959.
Chan, A. W. H., Kautzman, K. E., Chhabra, P. S., Surratt, J. D., Chan, M. N., Crounse, J. D., Kürten, A., Wennberg, P. O., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol formation from photooxidation of naphthalene and alkylnaphthalenes: implications for oxidation of intermediate volatility organic compounds (IVOCs), Atmos. Chem. Phys., 9, 3049–3060, https://doi.org/10.5194/acp-9-3049-2009, 2009.
Chan, A. W. H., Chan, M. N., Surratt, J. D., Chhabra, P. S., Loza, C. L., Crounse, J. D., Yee, L. D., Flagan, R. C., Wennberg, P. O., and Seinfeld, J. H.: Role of aldehyde chemistry and NOx concentrations in secondary organic aerosol formation, Atmos. Chem. Phys., 10, 7169–7188, https://doi.org/10.5194/acp-10-7169-2010, 2010.
Charan, S. M., Buenconsejo, R. S., and Seinfeld, J. H.: Secondary organic aerosol yields from the oxidation of benzyl alcohol, Atmos. Chem. Phys., 20, 13167–13190, https://doi.org/10.5194/acp-20-13167-2020, 2020.
Chen, K. S. F., Tsai, Y. P., Lai, C. H., Xiang, Y. K., Chuang, K. Y., and Zhu, Z. H.: Human health-risk assessment based on chronic exposure to the carbonyl compounds and metals emitted by burning incense at temples, Environ. Sci. Pollut. R., 28, 40640–40652, https://doi.org/10.1007/s11356-020-10313-1, 2021.
Depoorter, A., Kalalian, C., Emmelin, C., Lorentz, C., and George, C.: Indoor heterogeneous photochemistry of furfural drives emissions of nitrous acid, Indoor Air, 31, 682–692, https://doi.org/10.1111/INA.12758, 2021.
Drozd, G. T., Zhao, Y., Saliba, G., Frodin, B., Maddox, C., Oliver Chang, M. C., Maldonado, H., Sardar, S., Weber, R. J., Robinson, A. L., Goldstein, A. H., Chang, M. C. O., Maldonado, H., Sarder, S., Weber, R. J., Robinson, A. L., Goldstein, A. H., Oliver Chang, M. C., Maldonado, H., Sardar, S., Weber, R. J., Robinson, A. L., and Goldstein, A. H.: Detailed Speciation of Intermediate Volatility and Semivolatile Organic Compound Emissions from Gasoline Vehicles: Effects of Cold-Starts and Implications for Secondary Organic Aerosol Formation, Environ. Sci. Technol., 53, 1706–1714, https://doi.org/10.1021/acs.est.8b05600, 2019.
Guo, S., Hu, M., Zamora, M. L., Peng, J., Shang, D., Zheng, J., Du, Z., Wu, Z., Shao, M., Zeng, L., Molina, M. J., and Zhang, R.: Elucidating severe urban haze formation in China, P. Natl. Acad. Sci. USA, 111, 17373–17378, https://doi.org/10.1073/pnas.1419604111, 2014.
Guo, S., Hu, M., Peng, J., Wu, Z., Zamora, M. L., Shang, D., Du, Z., Zheng, J., Fang, X., Tang, R., Wu, Y., Zeng, L., Shuai, S., Zhang, W., Wang, Y., Ji, Y., Li, Y., Zhang, A. L., Wang, W., Zhang, F., Zhao, J., Gong, X., Wang, C., Molina, M. J., and Zhang, R.: Remarkable nucleation and growth of ultrafine particles from vehicular exhaust, P. Natl. Acad. Sci. USA, 117, 3427–3432, https://doi.org/10.1073/pnas.1916366117, 2020.
Harvey, R. M. and Petrucci, G. A.: Control of ozonolysis kinetics and aerosol yield by nuances in the molecular structure of volatile organic compounds, Atmos. Environ., 122, 188–195, https://doi.org/10.1016/j.atmosenv.2015.09.038, 2015.
He, X., Zheng, X., You, Y., Zhang, S., Zhao, B., Wang, X., Huang, G., Chen, T., Cao, Y., He, L., Chang, X., Wang, S., and Wu, Y.: Comprehensive chemical characterization of gaseous I/SVOC emissions from heavy-duty diesel vehicles using two-dimensional gas chromatography time-of-flight mass spectrometry, Environ. Pollut., 305, 119284, https://doi.org/10.1016/j.envpol.2022.119284, 2022.
Ho, S. S. H. and Yu, J. Z.: Concentrations of formaldehyde and other carbonyls in environments affected by incense burning, J. Environ. Monitor., 4, 728–733, https://doi.org/10.1039/b200998f, 2002.
Huo, Y., Guo, Z., Liu, Y., Wu, D., Ding, X., Zhao, Z., Wu, M., Wang, L., Feng, Y., Chen, Y., Wang, S., Li, Q., and Chen, J.: Addressing Unresolved Complex Mixture of I/SVOCs Emitted From Incomplete Combustion of Solid Fuels by Nontarget Analysis, J. Geophys. Res.-Atmos., 126, e2021JD035835, https://doi.org/10.1029/2021JD035835, 2021.
Jetter, J. J., Guo, Z., McBrian, J. A., and Flynn, M. R.: Characterization of emissions from burning incense, Sci. Total Environ., 295, 51–67, https://doi.org/10.1016/S0048-9697(02)00043-8, 2002.
Lee, S. C. and Wang, B.: Characteristics of emissions of air pollutants from burning of incense in a large environmental chamber, Atmos. Environ., 38, 941–951, https://doi.org/10.1016/j.atmosenv.2003.11.002, 2004.
Li, L., Tang, P., Nakao, S., and Cocker III, D. R.: Impact of molecular structure on secondary organic aerosol formation from aromatic hydrocarbon photooxidation under low-NOx conditions, Atmos. Chem. Phys., 16, 10793–10808, https://doi.org/10.5194/acp-16-10793-2016, 2016.
Liu, T., Wang, Z., Huang, D. D., Wang, X., and Chan, C. K.: Significant Production of Secondary Organic Aerosol from Emissions of Heated Cooking Oils, Environ. Sci. Tech. Let., 5, 32–37, https://doi.org/10.1021/acs.estlett.7b00530, 2018.
Loza, C. L., Craven, J. S., Yee, L. D., Coggon, M. M., Schwantes, R. H., Shiraiwa, M., Zhang, X., Schilling, K. A., Ng, N. L., Canagaratna, M. R., Ziemann, P. J., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol yields of 12-carbon alkanes, Atmos. Chem. Phys., 14, 1423–1439, https://doi.org/10.5194/acp-14-1423-2014, 2014.
Lu, F., Li, S., Shen, B., Zhang, J., Liu, L., Shen, X., and Zhao, R.: The emission characteristic of VOCs and the toxicity of BTEX from different mosquito-repellent incenses, J. Hazard. Mater., 384, 121428, https://doi.org/10.1016/j.jhazmat.2019.121428, 2020.
Lu, Q., Zhao, Y., and Robinson, A. L.: Comprehensive organic emission profiles for gasoline, diesel, and gas-turbine engines including intermediate and semi-volatile organic compound emissions, Atmos. Chem. Phys., 18, 17637–17654, https://doi.org/10.5194/acp-18-17637-2018, 2018.
Manoukian, A., Quivet, E., Temime-Roussel, B., Nicolas, M., Maupetit, F., and Wortham, H.: Emission characteristics of air pollutants from incense and candle burning in indoor atmospheres, Environ. Sci. Pollut. R., 20, 4659–4670, https://doi.org/10.1007/s11356-012-1394-y, 2013.
Manoukian, A., Buiron, D., Temime-Roussel, B., Wortham, H., and Quivet, E.: Measurements of VOC/SVOC emission factors from burning incenses in an environmental test chamber: influence of temperature, relative humidity, and air exchange rate, Environ. Sci. Pollut. R., 23, 6300–6311, https://doi.org/10.1007/s11356-015-5819-2, 2016.
Matsunaga, A., Docherty, K. S., Lim, Y. B., and Ziemann, P. J.: Composition and yields of secondary organic aerosol formed from OH radical-initiated reactions of linear alkenes in the presence of NOx: Modeling and measurements, Atmos. Environ., 43, 1349–1357, https://doi.org/10.1016/j.atmosenv.2008.12.004, 2009.
McDonald, B. C., De Gouw, J. A., Gilman, J. B., Jathar, S. H., Akherati, A., Cappa, C. D., Jimenez, J. L., Lee-Taylor, J., Hayes, P. L., McKeen, S. A., Cui, Y. Y., Kim, S. W., Gentner, D. R., Isaacman-VanWertz, G., Goldstein, A. H., Harley, R. A., Frost, G. J., Roberts, J. M., Ryerson, T. B., and Trainer, M.: Volatile chemical products emerging as largest petrochemical source of urban organic emissions, Science, 359, 760–764, https://doi.org/10.1126/science.aaq0524, 2018.
Nabi, D., Gros, J., Dimitriou-Christidis, P., and Arey, J. S.: Mapping environmental partitioning properties of nonpolar complex mixtures by use of GC × GC, Environ. Sci. Technol., 48, 6814–6826, https://doi.org/10.1021/es501674p, 2014.
Nimlos, M. R., Qian, X., Davis, M., Himmel, M. E., and Johnson, D. K.: Energetics of xylose decomposition as determined using quantum mechanics modeling, J. Phys. Chem. A, 110, 11824–11838, https://doi.org/10.1021/jp0626770, 2006.
Shah, R. U., Coggon, M. M., Gkatzelis, G. I., McDonald, B. C., Tasoglou, A., Huber, H., Gilman, J., Warneke, C., Robinson, A. L., and Presto, A. A.: Urban Oxidation Flow Reactor Measurements Reveal Significant Secondary Organic Aerosol Contributions from Volatile Emissions of Emerging Importance, Environ. Sci. Technol., 54, 714–725, https://doi.org/10.1021/acs.est.9b06531, 2020.
Shang, X., Pan, H., Li, M., Miao, X., and Ding, H.: Lonicera japonica Thunb.: Ethnopharmacology, phytochemistry and pharmacology of an important traditional Chinese medicine, J. Ethnopharmacol., 138, 1–21, https://doi.org/10.1016/j.jep.2011.08.016, 2011.
Silva, G. V., Martins, A. O., and Martins, S. D. S.: Indoor air quality: Assessment of dangerous substances in incense products, Int. J. Env. Res. Pub. He., 18, 8086, https://doi.org/10.3390/ijerph18158086, 2021.
Song, K., Guo, S., Gong, Y., Lv, D., Zhang, Y., Wan, Z., Li, T., Zhu, W., Wang, H., Yu, Y., Tan, R., Shen, R., Lu, S., Li, S., Chen, Y., and Hu, M.: Impact of cooking style and oil on semi-volatile and intermediate volatility organic compound emissions from Chinese domestic cooking, Atmos. Chem. Phys., 22, 9827–9841, https://doi.org/0.5194/acp-22-9827-2022, 2022a.
Song, K., Gong, Y., Guo, S., Lv, D., Wang, H., Wan, Z., Yu, Y., Tang, R., Li, T., Tan, R., Zhu, W., Shen, R., and Lu, S.: Investigation of partition coefficients and fingerprints of atmospheric gas- and particle-phase intermediate volatility and semi-volatile organic compounds using pixel-based approaches, J. Chromatogr. A, 1665, 462808, https://doi.org/10.1016/j.chroma.2022.462808, 2022b.
Song, K., Guo, S., Gong, Y., Lv, D., Wan, Z., Zhang, Y., Fu, Z., Hu, K., and Lu, S.: Non-target scanning of organics from cooking emissions using comprehensive two-dimensional gas chromatography-mass spectrometer (GC × GC-MS), Appl. Geochem., 151, 105601, https://doi.org/10.1016/j.apgeochem.2023.105601, 2023.
Staub, P. O., Schiestl, F. P., Leonti, M., and Weckerle, C. S.: Chemical analysis of incense smokes used in Shaxi, Southwest China: A novel methodological approach in ethnobotany, J. Ethnopharmacol., 138, 212–218, https://doi.org/10.1016/j.jep.2011.08.078, 2011.
Stewart, G. J., Nelson, B. S., Acton, W. J. F., Vaughan, A. R., Hopkins, J. R., Yunus, S. S. M., Hewitt, C. N., Nemitz, E., Mandal, T. K., Gadi, R., Sahu, Lokesh. K., Rickard, A. R., Lee, J. D., and Hamilton, J. F.: Comprehensive organic emission profiles, secondary organic aerosol production potential, and OH reactivity of domestic fuel combustion in Delhi, India, Environmental Science: Atmospheres, 1, 104–117, https://doi.org/10.1039/d0ea00009d, 2021.
Suzuki, S., Kiuchi, S., Kinoshita, K., Takeda, Y., Sakaida, S., Konno, M., Tanaka, K., and Oguma, M.: Formation of polycyclic aromatic hydrocarbons, benzofuran, and dibenzofuran in fuel-rich oxidation of toluene using a flow reactor, Phys. Chem. Chem. Phys., 23, 6509–6525, https://doi.org/10.1039/d0cp06615j, 2021.
Tang, R., Lu, Q., Guo, S., Wang, H., Song, K., Yu, Y., Tan, R., Liu, K., Shen, R., Chen, S., Zeng, L., Jorga, S. D., Zhang, Z., Zhang, W., Shuai, S., and Robinson, A. L.: Measurement report: Distinct emissions and volatility distribution of intermediate-volatility organic compounds from on-road Chinese gasoline vehicles: implication of high secondary organic aerosol formation potential, Atmos. Chem. Phys., 21, 2569–2583, https://doi.org/10.5194/acp-21-2569-2021, 2021.
Tkacik, D. S., Presto, A. A., Donahue, N. M., and Robinson, A. L.: Secondary organic aerosol formation from intermediate-volatility organic compounds: Cyclic, linear, and branched alkanes, Environ. Sci. Technol., 46, 8773–8781, https://doi.org/10.1021/es301112c, 2012.
Tran, T. C. and Marriott, P. J.: Characterization of incense smoke by solid phase microextraction-Comprehensive two-dimensional gas chromatography (GC × GC), Atmos Environ, 41, 5756–5768, https://doi.org/10.1016/j.atmosenv.2007.02.030, 2007.
Uhde, E. and Salthammer, T.: Impact of reaction products from building materials and furnishings on indoor air quality-A review of recent advances in indoor chemistry, Atmos. Environ., 41, 3111–3128, https://doi.org/10.1016/j.atmosenv.2006.05.082, 2007.
Wang, J., Jin, L., Gao, J., Shi, J., Zhao, Y., Liu, S., Jin, T., Bai, Z., and Wu, C. Y.: Investigation of speciated VOC in gasoline vehicular exhaust under ECE and EUDC test cycles, Sci. Total Environ., 445–446, 110–116, https://doi.org/10.1016/j.scitotenv.2012.12.044, 2013.
Wang, Y. and Qian, H.: Phthalates and their impacts on human health, Healthcare, 9, 603, https://doi.org/10.3390/healthcare9050603, 2021.
Wong, A., Lou, W., Ho, K.-f., Yiu, B. K.-f., Lin, S., Chu, W. C.-w., Abrigo, J., Lee, D., Lam, B. Y.-k., Au, L. W.-c., Soo, Y. O.-y., Lau, A. Y.-l., Kwok, T. C.-y., Leung, T. W.-h., Lam, L. C.-w., Ho, K., and Mok, V. C.-t.: Indoor incense burning impacts cognitive functions and brain functional connectivity in community older adults, Scientific Reports, 10, 7090, https://doi.org/10.1038/s41598-020-63568-6, 2020.
Wu, W., Zhao, B., Wang, S., and Hao, J.: Ozone and secondary organic aerosol formation potential from anthropogenic volatile organic compounds emissions in China, J. Environ. Sci., 53, 224–237, https://doi.org/10.1016/j.jes.2016.03.025, 2017.
Yadav, V. K., Malik, P., Tirth, V., Khan, S. H., Yadav, K. K., Islam, S., Choudhary, N., Inwati, G. K., Arabi, A., Kim, D. H., and Jeon, B. H.: Health and Environmental Risks of Incense Smoke: Mechanistic Insights and Cumulative Evidence, J. Inflamm. Res., 15, 2665–2693, https://doi.org/10.2147/JIR.S347489, 2022.
Yang, T. T., Lin, T. S., and Chang, M.: Characteristics of emissions of volatile organic compounds from smoldering incense, B. Environ. Contam. Tox., 78, 308–313, https://doi.org/10.1007/s00128-007-9184-9, 2007.
Yang, T. T., Ho, S. C., Chuang, L. te, Chuang, H. C., Li, Y. T., and Wu, J. J.: Characterization of particulate-phase polycyclic aromatic hydrocarbons emitted from incense burning and their bioreactivity in RAW264.7 macrophage, Environ. Pollut., 220, 1190–1198, https://doi.org/10.1016/j.envpol.2016.11.016, 2017.
Yu, Y., Guo, S., Wang, H., Shen, R., Zhu, W., Tan, R., Song, K., Zhang, Z., Li, S., Chen, Y., and Hu, M.: Importance of Semivolatile/Intermediate-Volatility Organic Compounds to Secondary Organic Aerosol Formation from Chinese Domestic Cooking Emissions, Environ. Sci. Tech. Let., 9, 507–512, https://doi.org/10.1021/acs.estlett.2c00207, 2022.
Yue, T., Yue, X., Chai, F., Hu, J., Lai, Y., He, L., and Zhu, R.: Characteristics of volatile organic compounds (VOCs) from the evaporative emissions of modern passenger cars, Atmos. Environ., 151, 62–69, https://doi.org/10.1016/j.atmosenv.2016.12.008, 2017.
Zhao, Y., Hu, M., Slanina, S., and Zhang, Y.: Chemical compositions of fine particulate organic matter emitted from Chinese cooking, Environ. Sci. Technol., 41, 99–105, https://doi.org/10.1021/es0614518, 2007.
Zhao, Y., Hennigan, C. J., May, A. A., Tkacik, D. S., de Gouw, J. A., Gilman, J. B., Kuster, W. C., Borbon, A., and Robinson, A. L.: Intermediate-volatility organic compounds: A large source of secondary organic aerosol, Environ. Sci. Technol., 48, 13743–13750, https://doi.org/10.1021/es5035188, 2014.
Zhao, Y., Nguyen, N. T., Presto, A. A., Hennigan, C. J., May, A. A., and Robinson, A. L.: Intermediate Volatility Organic Compound Emissions from On-Road Diesel Vehicles: Chemical Composition, Emission Factors, and Estimated Secondary Organic Aerosol Production, Environ. Sci. Technol., 49, 11516–11526, https://doi.org/10.1021/acs.est.5b02841, 2015.
Zhao, Y., Saleh, R., Saliba, G., Presto, A. A., Gordon, T. D., Drozd, G. T., Goldstein, A. H., Donahue, N. M., and Robinson, A. L.: Reducing secondary organic aerosol formation from gasoline vehicle exhaust, P. Natl. Acad. Sci. USA, 114, 6984–6989, https://doi.org/10.1073/pnas.1620911114, 2017.
Zhu, X., Han, Y., Feng, Y., Cheng, P., Peng, Y., Wang, J., Cai, J., and Chen, Y.: Formation and emission characteristics of intermediate volatile organic compounds (IVOCs) from the combustion of biomass and their cellulose, hemicellulose, and lignin, Atmos. Environ., 286, 119217, https://doi.org/10.1016/j.atmosenv.2022.119217, 2022.
Zushi, Y., Yamatori, Y., Nagata, J., and Nabi, D.: Comprehensive two-dimensional gas-chromatography-based property estimation to assess the fate and behavior of complex mixtures: A case study of vehicle engine oil, Sci. Total Environ., 669, 739–745, https://doi.org/10.1016/j.scitotenv.2019.03.157, 2019.
Short summary
Incense burning is common in Asia, posing threats to human health and air quality. However, less is known about its emissions and health risks. Full-volatility organic species from incense-burning smoke are detected and quantified. Intermediate-volatility volatile organic compounds (IVOCs) are crucial organics accounting for 19.2 % of the total emission factors (EFs) and 40.0 % of the secondary organic aerosol (SOA) estimation, highlighting the importance of incorporating IVOCs into SOA models.
Incense burning is common in Asia, posing threats to human health and air quality. However, less...
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