Articles | Volume 21, issue 20
https://doi.org/10.5194/acp-21-15809-2021
https://doi.org/10.5194/acp-21-15809-2021
Research article
 | 
22 Oct 2021
Research article |  | 22 Oct 2021

Improving the representation of HONO chemistry in CMAQ and examining its impact on haze over China

Shuping Zhang, Golam Sarwar, Jia Xing, Biwu Chu, Chaoyang Xue, Arunachalam Sarav, Dian Ding, Haotian Zheng, Yujing Mu, Fengkui Duan, Tao Ma, and Hong He

Related authors

Predicted impacts of heterogeneous chemical pathways on particulate sulfur over Fairbanks (Alaska), the Northern Hemisphere, and the Contiguous United States
Sara L. Farrell, Havala O. T. Pye, Robert Gilliam, George Pouliot, Deanna Huff, Golam Sarwar, William Vizuete, Nicole Briggs, Fengkui Duan, Tao Ma, Shuping Zhang, and Kathleen Fahey
Atmos. Chem. Phys., 25, 3287–3312, https://doi.org/10.5194/acp-25-3287-2025,https://doi.org/10.5194/acp-25-3287-2025, 2025
Short summary

Cited articles

An, J., Li, Y., Chen, Y., Li, J., Qu, Y., and Tang, Y.: Enhancements of major aerosol components due to additional HONO sources in the North China Plain and implications for visibility and haze, Adv. Atmos. Sci., 30, 57–66, https://doi.org/10.1007/s00376-012-2016-9, 2012. 
Anttila, T., Kiendler-Scharr, A., Tillmann, R., and Mentel, T. F.: On the Reactive Uptake of Gaseous Compounds by Organic-Coated Aqueous Aerosols: Theoretical Analysis and Application to the Heterogeneous Hydrolysis of N2O5, J. Phys. Chem. A, 110, 10435–10443, https://doi.org/10.1021/jp062403c, 2006. 
Appel, W., Bhave, P., Gilliland, A., Sarwar, G., and Roselle, S.: Evaluation of the community multiscale air quality (CMAQ) model version 4.5: Sensitivities impacting model performance, Part II – particulate matter, Atmos. Environ., 42, 6057–6066, https://doi.org/10.1016/j.atmosenv.2008.03.036, 2008. 
Bao, F. X., Li, M., Zhang, Y., Chen, C. C., and Zhao, J. C.: Photochemical Aging of Beijing Urban PM2.5: HONO Production, Environ. Sci. Technol., 52, 6309–6316, https://doi.org/10.1021/acs.est.8b00538, 2018. 
Bernard, F., Cazaunau, M., Grosselin, B., Zhou, B., Zheng, J., Liang, P., Zhang, Y., Ye, X., Daële, V., Mu, Y., Zhang, R., Chen, J.-M., and Mellouki, A.: Measurements of nitrous acid (HONO) in urban area of Shanghai, China, Environ. Sci. Pollut. Res., 23, 5818–5829, https://doi.org/10.1007/s11356-015-5797-4, 2015.  
Download
Short summary
Six heterogeneous HONO chemistry updates in CMAQ significantly improve HONO concentration. HONO production is primarily controlled by the heterogeneous reactions on ground and aerosol surfaces during haze. Additional HONO chemistry updates increase OH and production of secondary aerosols: sulfate, nitrate, and SOA.
Share
Altmetrics
Final-revised paper
Preprint