Articles | Volume 20, issue 9
https://doi.org/10.5194/acp-20-5425-2020
https://doi.org/10.5194/acp-20-5425-2020
Research article
 | 
08 May 2020
Research article |  | 08 May 2020

Origin and transformation of ambient volatile organic compounds during a dust-to-haze episode in northwest China

Yonggang Xue, Yu Huang, Steven Sai Hang Ho, Long Chen, Liqin Wang, Shuncheng Lee, and Junji Cao

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Cited articles

Atkinson, R. and Arey, J.: Atmospheric Degradation of Volatile Organic Compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003. 
Cadle, S. H., Mulawa, P. A., Hunsanger, E. C., Nelson, K., Ragazzi, R. A., and Barrett, R.: Composition of light-duty motor vehicle exhaust particulate matter in the Denver, Colorado area, Environ. Sci. Technol., 33, 2328–2339, https://doi.org/10.1021/es9810843, 1999. 
Cao, J. J., Wu, F., Chow, J. C., Lee, S. C., Li, Y., Chen, S. W., An, Z. S., Fung, K. K., Watson, J. G., Zhu, C. S., and Liu, S. X.: Characterization and source apportionment of atmospheric organic and elemental carbon during fall and winter of 2003 in Xi'an, China, Atmos. Chem. Phys., 5, 3127–3137, https://doi.org/10.5194/acp-5-3127-2005, 2005. 
Chen, H., Nanayakkara, C. E., and Grassian, V. H.: Titanium Dioxide Photocatalysis in Atmospheric Chemistry, Chem. Rev., 112, 5919–5948, https://doi.org/10.1021/cr3002092, 2012. 
Chow, J. C., Watson, J. G., Pritchett, L. C., Pierson, W. R., Frazier, C. A., and Purcell, R. G.: The dri thermal/optical reflectance carbon analysis system: description, evaluation and applications in U.S. Air quality studies, Atmos. Environ. A Gen., 27, 1185–1201, https://doi.org/10.1016/0960-1686(93)90245-T, 1993. 
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Particulate active metallic oxides in dust were proposed to influence the photochemical reactions of ambient volatile organic compounds (VOCs). A case study investigated the origin and transformation of VOCs during a windblown dust-to-haze pollution episode. In the dust event, a sharp decrease in VOC loading and aging of their components was observed. An increase in Ti and Fe and a fast decrease in trans-/cis-2-butene ratios demonstrated that dust can accelerate the oxidation of ambient VOCs.
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