Articles | Volume 19, issue 9
https://doi.org/10.5194/acp-19-6035-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-6035-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
08 May 2019
Research article |
| 08 May 2019
| 08 May 2019
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 2: Quartz and amorphous silica
Institute for Atmospheric and Climate Sciences, ETH Zurich, Zurich, 8092,
Switzerland
Claudia Marcolli
Institute for Atmospheric and Climate Sciences, ETH Zurich, Zurich, 8092,
Switzerland
Thomas Peter
Institute for Atmospheric and Climate Sciences, ETH Zurich, Zurich, 8092,
Switzerland
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Clare E. Singer, Benjamin W. Clouser, Sergey M. Khaykin, Martina Krämer, Francesco Cairo, Thomas Peter, Alexey Lykov, Christian Rolf, Nicole Spelten, Armin Afchine, Simone Brunamonti, and Elisabeth J. Moyer
Atmos. Meas. Tech., 15, 4767–4783, https://doi.org/10.5194/amt-15-4767-2022, https://doi.org/10.5194/amt-15-4767-2022, 2022
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In situ measurements of water vapor in the upper troposphere are necessary to study cloud formation and hydration of the stratosphere but challenging due to cold–dry conditions. We compare measurements from three water vapor instruments from the StratoClim campaign in 2017. In clear sky (clouds), point-by-point differences were <1.5±8 % (<1±8 %). This excellent agreement allows detection of fine-scale structures required to understand the impact of convection on stratospheric water vapor.
Yu Wang, Aristeidis Voliotis, Dawei Hu, Yunqi Shao, Mao Du, Ying Chen, Judith Kleinheins, Claudia Marcolli, M. Rami Alfarra, and Gordon McFiggans
Atmos. Chem. Phys., 22, 4149–4166, https://doi.org/10.5194/acp-22-4149-2022, https://doi.org/10.5194/acp-22-4149-2022, 2022
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Aerosol water uptake plays a key role in atmospheric physicochemical processes. We designed chamber experiments on aerosol water uptake of secondary organic aerosol (SOA) from mixed biogenic and anthropogenic precursors with inorganic seed. Our results highlight this chemical composition influences the reconciliation of the sub- and super-saturated water uptake, providing laboratory evidence for understanding the chemical controls of water uptake of the multi-component aerosol.
Kristian Klumpp, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 22, 3655–3673, https://doi.org/10.5194/acp-22-3655-2022, https://doi.org/10.5194/acp-22-3655-2022, 2022
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Debra K. Weisenstein, Daniele Visioni, Henning Franke, Ulrike Niemeier, Sandro Vattioni, Gabriel Chiodo, Thomas Peter, and David W. Keith
Atmos. Chem. Phys., 22, 2955–2973, https://doi.org/10.5194/acp-22-2955-2022, https://doi.org/10.5194/acp-22-2955-2022, 2022
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Arseniy Karagodin-Doyennel, Eugene Rozanov, Timofei Sukhodolov, Tatiana Egorova, Alfonso Saiz-Lopez, Carlos A. Cuevas, Rafael P. Fernandez, Tomás Sherwen, Rainer Volkamer, Theodore K. Koenig, Tanguy Giroud, and Thomas Peter
Geosci. Model Dev., 14, 6623–6645, https://doi.org/10.5194/gmd-14-6623-2021, https://doi.org/10.5194/gmd-14-6623-2021, 2021
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Here, we present the iodine chemistry module in the SOCOL-AERv2 model. The obtained iodine distribution demonstrated a good agreement when validated against other simulations and available observations. We also estimated the iodine influence on ozone in the case of present-day iodine emissions, the sensitivity of ozone to doubled iodine emissions, and when considering only organic or inorganic iodine sources. The new model can be used as a tool for further studies of iodine effects on ozone.
Bernd Kärcher and Claudia Marcolli
Atmos. Chem. Phys., 21, 15213–15220, https://doi.org/10.5194/acp-21-15213-2021, https://doi.org/10.5194/acp-21-15213-2021, 2021
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Aerosol–cloud interactions play an important role in climate change. Simulations of the competition between homogeneous solution droplet freezing and heterogeneous ice nucleation can be compromised by the misapplication of ice-active particle fractions frequently derived from laboratory measurements or parametrizations. Our study frames the problem and establishes a solution that is easy to implement in cloud models.
Soleil E. Worthy, Anand Kumar, Yu Xi, Jingwei Yun, Jessie Chen, Cuishan Xu, Victoria E. Irish, Pierre Amato, and Allan K. Bertram
Atmos. Chem. Phys., 21, 14631–14648, https://doi.org/10.5194/acp-21-14631-2021, https://doi.org/10.5194/acp-21-14631-2021, 2021
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We studied the effect of (NH4)2SO4 on the immersion freezing of non-mineral dust ice-nucleating substances (INSs) and mineral dusts. (NH4)2SO4 had no effect on the median freezing temperature of 9 of the 10 tested non-mineral dust INSs, slightly decreased that of the other, and increased that of all the mineral dusts. The difference in the response of mineral dust and non-mineral dust INSs to (NH4)2SO4 suggests that they nucleate ice and/or interact with (NH4)2SO4 via different mechanisms.
Timofei Sukhodolov, Tatiana Egorova, Andrea Stenke, William T. Ball, Christina Brodowsky, Gabriel Chiodo, Aryeh Feinberg, Marina Friedel, Arseniy Karagodin-Doyennel, Thomas Peter, Jan Sedlacek, Sandro Vattioni, and Eugene Rozanov
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This paper features the new atmosphere–ocean–aerosol–chemistry–climate model SOCOLv4.0 and its validation. The model performance is evaluated against reanalysis products and observations of atmospheric circulation and trace gas distribution, with a focus on stratospheric processes. Although we identified some problems to be addressed in further model upgrades, we demonstrated that SOCOLv4.0 is already well suited for studies related to chemistry–climate–aerosol interactions.
Claudia Marcolli, Fabian Mahrt, and Bernd Kärcher
Atmos. Chem. Phys., 21, 7791–7843, https://doi.org/10.5194/acp-21-7791-2021, https://doi.org/10.5194/acp-21-7791-2021, 2021
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Pores are aerosol particle features that trigger ice nucleation, as they take up water by capillary condensation below water saturation that freezes at low temperatures. The pore ice can then grow into macroscopic ice crystals making up cirrus clouds. Here, we investigate the pores in soot aggregates responsible for pore condensation and freezing (PCF). Moreover, we present a framework to parameterize soot PCF that is able to predict the ice nucleation activity based on soot properties.
Manuel Graf, Philipp Scheidegger, André Kupferschmid, Herbert Looser, Thomas Peter, Ruud Dirksen, Lukas Emmenegger, and Béla Tuzson
Atmos. Meas. Tech., 14, 1365–1378, https://doi.org/10.5194/amt-14-1365-2021, https://doi.org/10.5194/amt-14-1365-2021, 2021
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Water vapor is the most important natural greenhouse gas. The accurate and frequent measurement of its abundance, especially in the upper troposphere and lower stratosphere (UTLS), is technically challenging. We developed and characterized a mid-IR absorption spectrometer for highly accurate water vapor measurements in the UTLS. The instrument is sufficiently small and lightweight (3.9 kg) to be carried by meteorological balloons, which enables frequent and cost-effective soundings.
Michael Steiner, Beiping Luo, Thomas Peter, Michael C. Pitts, and Andrea Stenke
Geosci. Model Dev., 14, 935–959, https://doi.org/10.5194/gmd-14-935-2021, https://doi.org/10.5194/gmd-14-935-2021, 2021
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We evaluate polar stratospheric clouds (PSCs) as simulated by the chemistry–climate model (CCM) SOCOLv3.1 in comparison with measurements by the CALIPSO satellite. A cold bias results in an overestimated PSC area and mountain-wave ice is underestimated, but we find overall good temporal and spatial agreement of PSC occurrence and composition. This work confirms previous studies indicating that simplified PSC schemes may also achieve good approximations of the fundamental properties of PSCs.
Teresa Jorge, Simone Brunamonti, Yann Poltera, Frank G. Wienhold, Bei P. Luo, Peter Oelsner, Sreeharsha Hanumanthu, Bhupendra B. Singh, Susanne Körner, Ruud Dirksen, Manish Naja, Suvarna Fadnavis, and Thomas Peter
Atmos. Meas. Tech., 14, 239–268, https://doi.org/10.5194/amt-14-239-2021, https://doi.org/10.5194/amt-14-239-2021, 2021
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Balloon-borne frost point hygrometers are crucial for the monitoring of water vapour in the upper troposphere and lower stratosphere. We found that when traversing a mixed-phase cloud with big supercooled droplets, the intake tube of the instrument collects on its inner surface a high percentage of these droplets. The newly formed ice layer will sublimate at higher levels and contaminate the measurement. The balloon is also a source of contamination, but only at higher levels during the ascent.
Jing Dou, Peter A. Alpert, Pablo Corral Arroyo, Beiping Luo, Frederic Schneider, Jacinta Xto, Thomas Huthwelker, Camelia N. Borca, Katja D. Henzler, Jörg Raabe, Benjamin Watts, Hartmut Herrmann, Thomas Peter, Markus Ammann, and Ulrich K. Krieger
Atmos. Chem. Phys., 21, 315–338, https://doi.org/10.5194/acp-21-315-2021, https://doi.org/10.5194/acp-21-315-2021, 2021
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Photochemistry of iron(III) complexes plays an important role in aerosol aging, especially in the lower troposphere. Ensuing radical chemistry leads to decarboxylation, and the production of peroxides, and oxygenated volatile compounds, resulting in particle mass loss due to release of the volatile products to the gas phase. We investigated kinetic transport limitations due to high particle viscosity under low relative humidity conditions. For quantification a numerical model was developed.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Ales Kuchar, William Ball, Pavle Arsenovic, Ellis Remsberg, Patrick Jöckel, Markus Kunze, David A. Plummer, Andrea Stenke, Daniel Marsh, Doug Kinnison, and Thomas Peter
Atmos. Chem. Phys., 21, 201–216, https://doi.org/10.5194/acp-21-201-2021, https://doi.org/10.5194/acp-21-201-2021, 2021
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The solar signal in the mesospheric H2O and CO was extracted from the CCMI-1 model simulations and satellite observations using multiple linear regression (MLR) analysis. MLR analysis shows a pronounced and statistically robust solar signal in both H2O and CO. The model results show a general agreement with observations reproducing a negative/positive solar signal in H2O/CO. The pattern of the solar signal varies among the considered models, reflecting some differences in the model setup.
Sreeharsha Hanumanthu, Bärbel Vogel, Rolf Müller, Simone Brunamonti, Suvarna Fadnavis, Dan Li, Peter Ölsner, Manish Naja, Bhupendra Bahadur Singh, Kunchala Ravi Kumar, Sunil Sonbawne, Hannu Jauhiainen, Holger Vömel, Beiping Luo, Teresa Jorge, Frank G. Wienhold, Ruud Dirkson, and Thomas Peter
Atmos. Chem. Phys., 20, 14273–14302, https://doi.org/10.5194/acp-20-14273-2020, https://doi.org/10.5194/acp-20-14273-2020, 2020
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During boreal summer, anthropogenic sources yield the Asian Tropopause Aerosol Layer (ATAL), found in Asia between about 13 and 18 km altitude. Balloon-borne measurements of the ATAL conducted in northern India in 2016 show the strong variability of the ATAL. To explain its observed variability, model simulations are performed to deduce the origin of air masses on the Earth's surface, which is important to develop recommendations for regulations of anthropogenic surface emissions of the ATAL.
Robert O. David, Jonas Fahrni, Claudia Marcolli, Fabian Mahrt, Dominik Brühwiler, and Zamin A. Kanji
Atmos. Chem. Phys., 20, 9419–9440, https://doi.org/10.5194/acp-20-9419-2020, https://doi.org/10.5194/acp-20-9419-2020, 2020
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Ice crystal formation plays an important role in controlling the Earth's climate. However, the mechanisms responsible for ice formation in the atmosphere are still uncertain. Here we use surrogates for atmospherically relevant porous particles to determine the role of pore diameter and wettability on the ability of porous particles to nucleate ice in the atmosphere. Our results are consistent with the pore condensation and freeing mechanism.
Nir Bluvshtein, Ulrich K. Krieger, and Thomas Peter
Atmos. Meas. Tech., 13, 3191–3203, https://doi.org/10.5194/amt-13-3191-2020, https://doi.org/10.5194/amt-13-3191-2020, 2020
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Light-absorbing organic particles undergo transformations during their exposure in the atmosphere. The role these particles play in the global radiative balance is uncertain. This study describes high-sensitivity and high-precision measurements of light absorption by a single particle levitated in an electrodynamic balance. This high level of sensitivity enables future studies to explore the major processes responsible for changes to the particle's light absorptivity.
María Cascajo-Castresana, Robert O. David, Maiara A. Iriarte-Alonso, Alexander M. Bittner, and Claudia Marcolli
Atmos. Chem. Phys., 20, 3291–3315, https://doi.org/10.5194/acp-20-3291-2020, https://doi.org/10.5194/acp-20-3291-2020, 2020
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Atmospheric ice-nucleating particles are rare but relevant for cloud glaciation. A source of particles that nucleate ice above −15 °C is biological material including some proteins. Here we show that proteins of very diverse functions and structures can nucleate ice. Among these, the iron storage protein apoferritin stands out, with activity up to −4 °C. We show that its activity does not stem from correctly assembled proteins but from misfolded protein monomers or oligomers and aggregates.
Claudia Marcolli
Atmos. Chem. Phys., 20, 3209–3230, https://doi.org/10.5194/acp-20-3209-2020, https://doi.org/10.5194/acp-20-3209-2020, 2020
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Pore condensation and freezing (PCF) is an ice nucleation mechanism explaining ice formation at low ice supersaturation. It is assumed that liquid water condenses in pores of solid aerosol particles below water saturation followed by ice nucleation within the pores. This study discusses conditions of pore filling, homogeneous ice nucleation within the volume of porewater, and growth of ice out of the pores, taking the effect of negative pressure within pores below water saturation into account.
Aryeh Feinberg, Moustapha Maliki, Andrea Stenke, Bruno Sudret, Thomas Peter, and Lenny H. E. Winkel
Atmos. Chem. Phys., 20, 1363–1390, https://doi.org/10.5194/acp-20-1363-2020, https://doi.org/10.5194/acp-20-1363-2020, 2020
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The amount of the micronutrient selenium in food largely depends on the amount and form of selenium in soil. The atmosphere acts as a source of selenium to soils through deposition, yet little information is available about atmospheric selenium cycling. Therefore, we built the first global atmospheric selenium model. Through sensitivity and uncertainty analysis we determine that selenium can be transported thousands of kilometers and that measurements of selenium emissions should be prioritized.
Robert O. David, Maria Cascajo-Castresana, Killian P. Brennan, Michael Rösch, Nora Els, Julia Werz, Vera Weichlinger, Lin S. Boynton, Sophie Bogler, Nadine Borduas-Dedekind, Claudia Marcolli, and Zamin A. Kanji
Atmos. Meas. Tech., 12, 6865–6888, https://doi.org/10.5194/amt-12-6865-2019, https://doi.org/10.5194/amt-12-6865-2019, 2019
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Here we present the development and applicability of the DRoplet Ice Nuclei Counter Zurich (DRINCZ). DRINCZ allows for ice nuclei in the immersion mode to be quantified between 0 and -25 °C with an uncertainty of ±0.9 °C. Furthermore, we present a new method for assessing biases in drop-freezing apparatuses and cumulative ice-nucleating-particle concentrations from snow samples collected in the Austrian Alps at the Sonnblick Observatory.
William T. Ball, Justin Alsing, Johannes Staehelin, Sean M. Davis, Lucien Froidevaux, and Thomas Peter
Atmos. Chem. Phys., 19, 12731–12748, https://doi.org/10.5194/acp-19-12731-2019, https://doi.org/10.5194/acp-19-12731-2019, 2019
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We analyse long-term stratospheric ozone (60° S–60° N) trends over the 1985–2018 period. Previous work has suggested that lower stratosphere ozone declined over 1998–2016. We demonstrate that a large ozone upsurge in 2017 is likely related to QBO variability, but that lower stratospheric ozone trends likely remain lower in 2018 than in 1998. Tropical stratospheric ozone (30° S–30° N) shows highly probable decreases in both the lower stratosphere and in the integrated stratospheric ozone layer.
Aryeh Feinberg, Timofei Sukhodolov, Bei-Ping Luo, Eugene Rozanov, Lenny H. E. Winkel, Thomas Peter, and Andrea Stenke
Geosci. Model Dev., 12, 3863–3887, https://doi.org/10.5194/gmd-12-3863-2019, https://doi.org/10.5194/gmd-12-3863-2019, 2019
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We have improved several aspects of atmospheric sulfur cycling in SOCOL-AER, an aerosol–chemistry–climate model. The newly implemented features in SOCOL-AERv2 include interactive deposition schemes, improved sulfur mass conservation, and expanded tropospheric chemistry. SOCOL-AERv2 shows better agreement with stratospheric aerosol observations and sulfur deposition networks compared to SOCOL-AERv1. SOCOL-AERv2 can be used to study impacts of sulfate aerosol on climate, chemistry, and ecosystems.
Pavle Arsenovic, Alessandro Damiani, Eugene Rozanov, Bernd Funke, Andrea Stenke, and Thomas Peter
Atmos. Chem. Phys., 19, 9485–9494, https://doi.org/10.5194/acp-19-9485-2019, https://doi.org/10.5194/acp-19-9485-2019, 2019
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Low-energy electrons (LEE) are the dominant source of odd nitrogen, which destroys ozone, in the mesosphere and stratosphere in polar winter in the geomagnetically active periods. However, the observed stratospheric ozone anomalies can be reproduced only when accounting for both low- and middle-range energy electrons (MEE) in the chemistry-climate model. Ozone changes may induce further dynamical and thermal changes in the atmosphere. We recommend including both LEE and MEE in climate models.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6059–6084, https://doi.org/10.5194/acp-19-6059-2019, https://doi.org/10.5194/acp-19-6059-2019, 2019
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This paper not only interests the Atmospheric Science community but has a potential to cater to a broader audience. We discuss both long- and short-term effects of various
atmospherically relevantchemical species on fairly abundant mineral surfaces like feldspars and clays. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Sandro Vattioni, Debra Weisenstein, David Keith, Aryeh Feinberg, Thomas Peter, and Andrea Stenke
Atmos. Chem. Phys., 19, 4877–4897, https://doi.org/10.5194/acp-19-4877-2019, https://doi.org/10.5194/acp-19-4877-2019, 2019
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This study is among the first modeling studies on stratospheric sulfate geoengineering that interactively couple a size-resolved sectional aerosol module to well-described stratospheric chemistry and radiation schemes in a global 3-D chemistry–climate model. We found that compared with SO2 injection, the direct emission of aerosols results in more effective radiative forcing and that sensitivities to different injection strategies vary for different forms of injected sulfur.
Laura E. Revell, Andrea Stenke, Fiona Tummon, Aryeh Feinberg, Eugene Rozanov, Thomas Peter, N. Luke Abraham, Hideharu Akiyoshi, Alexander T. Archibald, Neal Butchart, Makoto Deushi, Patrick Jöckel, Douglas Kinnison, Martine Michou, Olaf Morgenstern, Fiona M. O'Connor, Luke D. Oman, Giovanni Pitari, David A. Plummer, Robyn Schofield, Kane Stone, Simone Tilmes, Daniele Visioni, Yousuke Yamashita, and Guang Zeng
Atmos. Chem. Phys., 18, 16155–16172, https://doi.org/10.5194/acp-18-16155-2018, https://doi.org/10.5194/acp-18-16155-2018, 2018
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Global models such as those participating in the Chemistry-Climate Model Initiative (CCMI) consistently simulate biases in tropospheric ozone compared with observations. We performed an advanced statistical analysis with one of the CCMI models to understand the cause of the bias. We found that emissions of ozone precursor gases are the dominant driver of the bias, implying either that the emissions are too large, or that the way in which the model handles emissions needs to be improved.
Simone Brunamonti, Teresa Jorge, Peter Oelsner, Sreeharsha Hanumanthu, Bhupendra B. Singh, K. Ravi Kumar, Sunil Sonbawne, Susanne Meier, Deepak Singh, Frank G. Wienhold, Bei Ping Luo, Maxi Boettcher, Yann Poltera, Hannu Jauhiainen, Rijan Kayastha, Jagadishwor Karmacharya, Ruud Dirksen, Manish Naja, Markus Rex, Suvarna Fadnavis, and Thomas Peter
Atmos. Chem. Phys., 18, 15937–15957, https://doi.org/10.5194/acp-18-15937-2018, https://doi.org/10.5194/acp-18-15937-2018, 2018
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Based on balloon-borne measurements performed in India and Nepal in 2016–2017, we infer the vertical distributions of water vapor, ozone and aerosols in the atmosphere, from the surface to 30 km altitude. Our measurements show that the atmospheric dynamics of the Asian summer monsoon system over the polluted Indian subcontinent lead to increased concentrations of water vapor and aerosols in the high atmosphere (approximately 14–20 km altitude), which can have an important effect on climate.
Mehrnoush M. Fard, Ulrich K. Krieger, and Thomas Peter
Atmos. Chem. Phys., 18, 13511–13530, https://doi.org/10.5194/acp-18-13511-2018, https://doi.org/10.5194/acp-18-13511-2018, 2018
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Atmospheric aerosol particles may undergo liquid–liquid phase separation (LLPS) when exposed to varying relative humidity, with an aqueous organic phase enclosing an aqueous inorganic phase below a threshold of relative humidity. Brown carbon (BrC) compounds will redistribute to the organic phase upon LLPS. We use numerical modeling to study the shortwave radiative impact of LLPS containing BrC and conclude that it is not significant for atmospheric aerosol.
Fabian Mahrt, Claudia Marcolli, Robert O. David, Philippe Grönquist, Eszter J. Barthazy Meier, Ulrike Lohmann, and Zamin A. Kanji
Atmos. Chem. Phys., 18, 13363–13392, https://doi.org/10.5194/acp-18-13363-2018, https://doi.org/10.5194/acp-18-13363-2018, 2018
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The ice nucleation ability of different soot particles in the cirrus and mixed-phase cloud temperature regime is presented. The impact of aerosol particle size, particle morphology, organic matter and hydrophilicity on ice nucleation is examined. We propose ice nucleation proceeds via a pore condensation freezing mechanism for soot particles with the necessary physicochemical properties that nucleated ice well below water saturation.
Timofei Sukhodolov, Jian-Xiong Sheng, Aryeh Feinberg, Bei-Ping Luo, Thomas Peter, Laura Revell, Andrea Stenke, Debra K. Weisenstein, and Eugene Rozanov
Geosci. Model Dev., 11, 2633–2647, https://doi.org/10.5194/gmd-11-2633-2018, https://doi.org/10.5194/gmd-11-2633-2018, 2018
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The Pinatubo eruption in 1991 is the strongest directly observed volcanic event. In a series of experiments, we simulate its influence on the stratospheric aerosol layer using a state-of-the-art aerosol–chemistry–climate model, SOCOL-AERv1.0, and compare our results to observations. We show that SOCOL-AER reproduces the most important atmospheric effects and can therefore be used to study the climate effects of future volcanic eruptions and geoengineering by artificial sulfate aerosol.
Anand Kumar, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 18, 7057–7079, https://doi.org/10.5194/acp-18-7057-2018, https://doi.org/10.5194/acp-18-7057-2018, 2018
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We have performed immersion freezing experiments with microcline (most active ice nucleation, IN, K-feldspar polymorph) and investigated the effect of ammonium and non-ammonium solutes on its IN efficiency. We report increased IN efficiency of microcline in dilute ammonia- or ammonium-containing solutions, which opens up a pathway for condensation freezing occurring at a warmer temperature than immersion freezing.
Fabian Schoenenberger, Stephan Henne, Matthias Hill, Martin K. Vollmer, Giorgos Kouvarakis, Nikolaos Mihalopoulos, Simon O'Doherty, Michela Maione, Lukas Emmenegger, Thomas Peter, and Stefan Reimann
Atmos. Chem. Phys., 18, 4069–4092, https://doi.org/10.5194/acp-18-4069-2018, https://doi.org/10.5194/acp-18-4069-2018, 2018
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Anthropogenic halocarbon emissions contribute to stratospheric ozone depletion and global warming. We measured atmospheric halocarbons for 6 months on Crete to extend the coverage of the existing observation network to the Eastern Mediterranean. The derived emission estimates showed a contribution of 16.8 % (13.6–23.3 %) and 53.2 % (38.1–84.2 %) of this region to the total HFC and HCFC emissions of the analyzed European domain and a reduction of the underlying uncertainties by 40–80 %.
Larry W. Thomason, Nicholas Ernest, Luis Millán, Landon Rieger, Adam Bourassa, Jean-Paul Vernier, Gloria Manney, Beiping Luo, Florian Arfeuille, and Thomas Peter
Earth Syst. Sci. Data, 10, 469–492, https://doi.org/10.5194/essd-10-469-2018, https://doi.org/10.5194/essd-10-469-2018, 2018
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We describe the construction of a continuous 38-year record of stratospheric aerosol optical properties. The Global Space-based Stratospheric Aerosol Climatology, or GloSSAC, provided the input data to the construction of the Climate Model Intercomparison Project stratospheric aerosol forcing data set (1979 to 2014) and is now extended through 2016. GloSSAC focuses on the the SAGE series of instruments through mid-2005 and on OSIRIS and CALIPSO after that time.
Pavle Arsenovic, Eugene Rozanov, Julien Anet, Andrea Stenke, Werner Schmutz, and Thomas Peter
Atmos. Chem. Phys., 18, 3469–3483, https://doi.org/10.5194/acp-18-3469-2018, https://doi.org/10.5194/acp-18-3469-2018, 2018
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Global warming will persist in the 21st century, even if the solar activity undergoes an unusually strong and long decline. Decreased ozone production caused by reduction of solar activity and change of atmospheric dynamics due to the global warming might result in further thinning of the tropical ozone layer. Globally, total ozone would not recover to the pre-ozone hole values as long as the decline of solar activity lasts. This may let more ultra-violet radiation reach the Earth's surface.
William T. Ball, Justin Alsing, Daniel J. Mortlock, Johannes Staehelin, Joanna D. Haigh, Thomas Peter, Fiona Tummon, Rene Stübi, Andrea Stenke, John Anderson, Adam Bourassa, Sean M. Davis, Doug Degenstein, Stacey Frith, Lucien Froidevaux, Chris Roth, Viktoria Sofieva, Ray Wang, Jeannette Wild, Pengfei Yu, Jerald R. Ziemke, and Eugene V. Rozanov
Atmos. Chem. Phys., 18, 1379–1394, https://doi.org/10.5194/acp-18-1379-2018, https://doi.org/10.5194/acp-18-1379-2018, 2018
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Using a robust analysis, with artefact-corrected ozone data, we confirm upper stratospheric ozone is recovering following the Montreal Protocol, but that lower stratospheric ozone (50° S–50° N) has continued to decrease since 1998, and the ozone layer as a whole (60° S–60° N) may be lower today than in 1998. No change in total column ozone may be due to increasing tropospheric ozone. State-of-the-art models do not reproduce lower stratospheric ozone decreases.
Ulrich K. Krieger, Franziska Siegrist, Claudia Marcolli, Eva U. Emanuelsson, Freya M. Gøbel, Merete Bilde, Aleksandra Marsh, Jonathan P. Reid, Andrew J. Huisman, Ilona Riipinen, Noora Hyttinen, Nanna Myllys, Theo Kurtén, Thomas Bannan, Carl J. Percival, and David Topping
Atmos. Meas. Tech., 11, 49–63, https://doi.org/10.5194/amt-11-49-2018, https://doi.org/10.5194/amt-11-49-2018, 2018
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Vapor pressures of low-volatility organic molecules at atmospheric temperatures reported in the literature often differ by several orders of magnitude between measurement techniques. These discrepancies exceed the stated uncertainty of each technique, which is generally reported to be smaller than a factor of 2. We determined saturation vapor pressures for the homologous series of polyethylene glycols ranging in vapor pressure at 298 K from 1E−7 Pa to 5E−2 Pa as a reference set.
Laura E. Revell, Andrea Stenke, Beiping Luo, Stefanie Kremser, Eugene Rozanov, Timofei Sukhodolov, and Thomas Peter
Atmos. Chem. Phys., 17, 13139–13150, https://doi.org/10.5194/acp-17-13139-2017, https://doi.org/10.5194/acp-17-13139-2017, 2017
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Compiling stratospheric aerosol data sets after a major volcanic eruption is difficult as the stratosphere becomes too optically opaque for satellite instruments to measure accurately. We performed ensemble chemistry–climate model simulations with two stratospheric aerosol data sets compiled for two international modelling activities and compared the simulated volcanic aerosol-induced effects from the 1991 Mt Pinatubo eruption on tropical stratospheric temperature and ozone with observations.
Sandra Bastelberger, Ulrich K. Krieger, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 17, 8453–8471, https://doi.org/10.5194/acp-17-8453-2017, https://doi.org/10.5194/acp-17-8453-2017, 2017
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We present quantitative condensed-phase diffusivity measurements of a volatile organic (tetraethylene glycol) in highly viscous single aerosol particles (aqueous sucrose). The condensed-phase diffusivity exhibits a strong temperature and humidity dependence. Our results suggest that diffusion limitations of volatile organics in highly viscous organic aerosol may severely impact gas–particle partitioning under cold and dry conditions.
Thomas Berkemeier, Markus Ammann, Ulrich K. Krieger, Thomas Peter, Peter Spichtinger, Ulrich Pöschl, Manabu Shiraiwa, and Andrew J. Huisman
Atmos. Chem. Phys., 17, 8021–8029, https://doi.org/10.5194/acp-17-8021-2017, https://doi.org/10.5194/acp-17-8021-2017, 2017
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Kinetic process models are efficient tools used to unravel the mechanisms governing chemical and physical transformation in multiphase atmospheric chemistry. However, determination of kinetic parameters such as reaction rate or diffusion coefficients from multiple data sets is often difficult or ambiguous. This study presents a novel optimization algorithm and framework to determine these parameters in an automated fashion and to gain information about parameter uncertainty and uniqueness.
Lisa Stirnweis, Claudia Marcolli, Josef Dommen, Peter Barmet, Carla Frege, Stephen M. Platt, Emily A. Bruns, Manuel Krapf, Jay G. Slowik, Robert Wolf, Andre S. H. Prévôt, Urs Baltensperger, and Imad El-Haddad
Atmos. Chem. Phys., 17, 5035–5061, https://doi.org/10.5194/acp-17-5035-2017, https://doi.org/10.5194/acp-17-5035-2017, 2017
Lukas Kaufmann, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 17, 3525–3552, https://doi.org/10.5194/acp-17-3525-2017, https://doi.org/10.5194/acp-17-3525-2017, 2017
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To improve the understanding of heterogeneous ice nucleation, we have subjected different ice nuclei to repeated freezing cycles and evaluated the freezing temperatures with different parameterizations of classical nucleation theory. It was found that two fit parameters were necessary to describe the temperature dependence of the nucleation rate.
Claudia Marcolli
Atmos. Chem. Phys., 17, 1595–1622, https://doi.org/10.5194/acp-17-1595-2017, https://doi.org/10.5194/acp-17-1595-2017, 2017
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Laboratory studies from the last century have shown that some types of particles are susceptible to pre-activation, i.e. they are able to develop macroscopic ice at warmer temperatures or lower relative humidities after they had been involved in an ice nucleation event before. This review analyses these works under the presumption that pre-activation occurs by ice preserved in pores, and it discusses atmospheric scenarios for which pre-activation might be important.
William T. Ball, Aleš Kuchař, Eugene V. Rozanov, Johannes Staehelin, Fiona Tummon, Anne K. Smith, Timofei Sukhodolov, Andrea Stenke, Laura Revell, Ancelin Coulon, Werner Schmutz, and Thomas Peter
Atmos. Chem. Phys., 16, 15485–15500, https://doi.org/10.5194/acp-16-15485-2016, https://doi.org/10.5194/acp-16-15485-2016, 2016
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We find monthly, mid-latitude temperature changes above 40 km are related to ozone and temperature variations throughout the middle atmosphere. We develop an index to represent this atmospheric variability. In statistical analysis, the index can account for up to 60 % of variability in tropical temperature and ozone above 27 km. The uncertainties can be reduced by up to 35 % and 20 % in temperature and ozone, respectively. This index is an important tool to quantify current and future ozone recovery.
Laura E. Revell, Andrea Stenke, Eugene Rozanov, William Ball, Stefan Lossow, and Thomas Peter
Atmos. Chem. Phys., 16, 13067–13080, https://doi.org/10.5194/acp-16-13067-2016, https://doi.org/10.5194/acp-16-13067-2016, 2016
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Water vapour in the stratosphere plays an important role in atmospheric chemistry and the Earth's radiative balance. We have analysed trends in stratospheric water vapour through the 21st century as simulated by a coupled chemistry–climate model following a range of greenhouse gas emission scenarios. We have also quantified the contribution that methane oxidation in the stratosphere makes to projected water vapour trends.
Lukas Kaufmann, Claudia Marcolli, Julian Hofer, Valeria Pinti, Christopher R. Hoyle, and Thomas Peter
Atmos. Chem. Phys., 16, 11177–11206, https://doi.org/10.5194/acp-16-11177-2016, https://doi.org/10.5194/acp-16-11177-2016, 2016
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We investigated dust samples from dust source regions all over the globe with respect to their ice nucleation activity and their mineralogical composition. Stones of reference minerals were milled and investigated the same way as the natural dust samples. We found that the mineralogical composition is a major determinant of ice nucleation ability. Natural samples consist of mixtures of minerals with remarkably similar ice nucleation ability.
Baban Nagare, Claudia Marcolli, André Welti, Olaf Stetzer, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8899–8914, https://doi.org/10.5194/acp-16-8899-2016, https://doi.org/10.5194/acp-16-8899-2016, 2016
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The relative importance of contact freezing and immersion freezing at mixed-phase cloud temperatures is the subject of debate. We performed experiments using continuous-flow diffusion chambers to compare the freezing efficiency of ice-nucleating particles for both these nucleation modes. Silver iodide, kaolinite and Arizona Test Dust were used as ice-nucleating particles. We could not confirm the dominance of contact freezing over immersion freezing for our experimental conditions.
Claudia Marcolli, Baban Nagare, André Welti, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8915–8937, https://doi.org/10.5194/acp-16-8915-2016, https://doi.org/10.5194/acp-16-8915-2016, 2016
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Silver iodide is one of the best-investigated ice nuclei. It has relevance for the atmosphere since it is used for glaciogenic cloud seeding. Nevertheless, many open questions remain. This paper gives an overview of silver iodide as an ice nucleus and tries to identify the factors that influence the ice nucleation ability of silver iodide.
Lindsay Renbaum-Wolff, Mijung Song, Claudia Marcolli, Yue Zhang, Pengfei F. Liu, James W. Grayson, Franz M. Geiger, Scot T. Martin, and Allan K. Bertram
Atmos. Chem. Phys., 16, 7969–7979, https://doi.org/10.5194/acp-16-7969-2016, https://doi.org/10.5194/acp-16-7969-2016, 2016
Erika Kienast-Sjögren, Christian Rolf, Patric Seifert, Ulrich K. Krieger, Bei P. Luo, Martina Krämer, and Thomas Peter
Atmos. Chem. Phys., 16, 7605–7621, https://doi.org/10.5194/acp-16-7605-2016, https://doi.org/10.5194/acp-16-7605-2016, 2016
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We present a climatology of mid-latitude cirrus cloud properties based on 13 000 hours of automatically analyzed lidar measurements at three different sites. Jungfraujoch,
situated at 3580 m a.s.l., is found to be ideal to measure high and optically thin
cirrus. We use our retrieved optical properties together with a radiation model and
estimate the radiative forcing by mid-latitude cirrus.
All cirrus clouds detected here have a positive net radiative effect.
B. Nagare, C. Marcolli, O. Stetzer, and U. Lohmann
Atmos. Chem. Phys., 15, 13759–13776, https://doi.org/10.5194/acp-15-13759-2015, https://doi.org/10.5194/acp-15-13759-2015, 2015
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We determined collision efficiencies of cloud droplets with aerosol particles experimentally and found that they were around 1 order of magnitude higher than theoretical formulations that include Brownian diffusion, impaction, interception, thermophoretic, diffusiophoretic and electric forces. This is most probably due to uncertainties and inaccuracies in the theoretical formulations of thermophoretic and diffusiophoretic processes.
D. M. Lienhard, A. J. Huisman, U. K. Krieger, Y. Rudich, C. Marcolli, B. P. Luo, D. L. Bones, J. P. Reid, A. T. Lambe, M. R. Canagaratna, P. Davidovits, T. B. Onasch, D. R. Worsnop, S. S. Steimer, T. Koop, and T. Peter
Atmos. Chem. Phys., 15, 13599–13613, https://doi.org/10.5194/acp-15-13599-2015, https://doi.org/10.5194/acp-15-13599-2015, 2015
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New data of water diffusivity in secondary organic aerosol (SOA) material and organic/inorganic model mixtures is presented over an extensive temperature range. Our data suggest that water diffusion in SOA is sufficiently fast so that it is unlikely to have significant consequences on the direct climatic effect under tropospheric conditions. Glass formation in SOA is unlikely to restrict homogeneous ice nucleation.
J.-X. Sheng, D. K. Weisenstein, B.-P. Luo, E. Rozanov, F. Arfeuille, and T. Peter
Atmos. Chem. Phys., 15, 11501–11512, https://doi.org/10.5194/acp-15-11501-2015, https://doi.org/10.5194/acp-15-11501-2015, 2015
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We have conducted a perturbed parameter model ensemble to investigate Mt.
Pinatubo's 1991 initial sulfur mass emission. Our results suggest that (a) the initial mass loading of the Pinatubo eruption is ~14 Mt of SO2; (b) the injection vertical distribution is strongly skewed towards the lower stratosphere, leading to a peak mass sulfur injection at 18-21 km; (c) the injection magnitude and height affect early southward transport of the volcanic cloud observed by SAGE II.
E. Hammer, N. Bukowiecki, B. P. Luo, U. Lohmann, C. Marcolli, E. Weingartner, U. Baltensperger, and C. R. Hoyle
Atmos. Chem. Phys., 15, 10309–10323, https://doi.org/10.5194/acp-15-10309-2015, https://doi.org/10.5194/acp-15-10309-2015, 2015
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An important quantity which determines aerosol activation and cloud formation is the effective peak supersaturation. The box model ZOMM was used to simulate the effective peak supersaturation experienced by an air parcel approaching a high-alpine research station in Switzerland. With the box model the sensitivity of the effective peak supersaturation to key aerosol and dynamical parameters was investigated.
E. Kienast-Sjögren, A. K. Miltenberger, B. P. Luo, and T. Peter
Atmos. Chem. Phys., 15, 7429–7447, https://doi.org/10.5194/acp-15-7429-2015, https://doi.org/10.5194/acp-15-7429-2015, 2015
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Sensitivities of Lagrangian cirrus modelling on input data uncertainties have been examined. We found a strong dependence on the temporal resolution of the trajectories and underlying numerical weather prediction (NWP) data as well as on the specific moisture content. Furthermore, we found a large day-to-day variability in the vertical wind spectrum, demonstrating the necessity to apply NWP models with high spatial and temporal resolution for Lagrangian cirrus modelling.
S. S. Steimer, U. K. Krieger, Y.-F. Te, D. M. Lienhard, A. J. Huisman, B. P. Luo, M. Ammann, and T. Peter
Atmos. Meas. Tech., 8, 2397–2408, https://doi.org/10.5194/amt-8-2397-2015, https://doi.org/10.5194/amt-8-2397-2015, 2015
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Atmospheric aerosol is often subject to supersaturated or supercooled conditions where bulk measurements are not possible. Here we demonstrate how measurements using single particle electrodynamic levitation combined with light scattering spectroscopy allow the retrieval of thermodynamic data, optical properties and water diffusivity of such metastable particles even when auxiliary bulk data are not available due to lack of sufficient amounts of sample.
L. E. Revell, F. Tummon, A. Stenke, T. Sukhodolov, A. Coulon, E. Rozanov, H. Garny, V. Grewe, and T. Peter
Atmos. Chem. Phys., 15, 5887–5902, https://doi.org/10.5194/acp-15-5887-2015, https://doi.org/10.5194/acp-15-5887-2015, 2015
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We have examined the effects of ozone precursor emissions and climate change on the tropospheric ozone budget. Under RCP 6.0, ozone in the future is governed primarily by changes in nitrogen oxides (NOx). Methane is also important, and induces an increase in tropospheric ozone that is approximately one-third of that caused by NOx. This study highlights the critical role that emission policies globally have to play in determining tropospheric ozone evolution through the 21st century.
G. Ganbavale, A. Zuend, C. Marcolli, and T. Peter
Atmos. Chem. Phys., 15, 447–493, https://doi.org/10.5194/acp-15-447-2015, https://doi.org/10.5194/acp-15-447-2015, 2015
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This study presents a new, improved parameterisation of the temperature dependence of activity coefficients implemented in the AIOMFAC group-contribution model. The AIOMFAC model with the improved parameterisation is applicable for a large variety of aqueous organic as well as water-free organic solutions of relevance for atmospheric aerosols. The new model parameters were determined based on published and new thermodynamic equilibrium data covering a temperature range from ~190 to 440 K.
T. Sukhodolov, E. Rozanov, A. I. Shapiro, J. Anet, C. Cagnazzo, T. Peter, and W. Schmutz
Geosci. Model Dev., 7, 2859–2866, https://doi.org/10.5194/gmd-7-2859-2014, https://doi.org/10.5194/gmd-7-2859-2014, 2014
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The performance of the main generations of the ECHAM shortwave radiation schemes is analysed in terms of the representation of the solar signal in the heating rates. The way to correct missing or underrepresented spectral intervals in the solar signal in the heating rates is suggested using the example of ECHAM6 and six-band ECHAM5 schemes. The suggested method is computationally fast and suitable for any other radiation scheme.
S. Pandey Deolal, S. Henne, L. Ries, S. Gilge, U. Weers, M. Steinbacher, J. Staehelin, and T. Peter
Atmos. Chem. Phys., 14, 12553–12571, https://doi.org/10.5194/acp-14-12553-2014, https://doi.org/10.5194/acp-14-12553-2014, 2014
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Mixing ratios of Peroxyacetyl nitrate (PAN) at Jungfraujoch (Switzerland) and Zugspitze (Germany) show a seasonal variation with maxima in spring, typical for remote sites in the lower atmosphere in northern mid-latitudes. The detailed analysis of PAN measurements of May 2008 indicates that PAN at these high mountain sites is dominated by photochemical formation in the relatively cold polluted European planetary boundary layer rather than formation in the free troposphere.
D. W. Fahey, R.-S. Gao, O. Möhler, H. Saathoff, C. Schiller, V. Ebert, M. Krämer, T. Peter, N. Amarouche, L. M. Avallone, R. Bauer, Z. Bozóki, L. E. Christensen, S. M. Davis, G. Durry, C. Dyroff, R. L. Herman, S. Hunsmann, S. M. Khaykin, P. Mackrodt, J. Meyer, J. B. Smith, N. Spelten, R. F. Troy, H. Vömel, S. Wagner, and F. G. Wienhold
Atmos. Meas. Tech., 7, 3177–3213, https://doi.org/10.5194/amt-7-3177-2014, https://doi.org/10.5194/amt-7-3177-2014, 2014
S. Muthers, J. G. Anet, A. Stenke, C. C. Raible, E. Rozanov, S. Brönnimann, T. Peter, F. X. Arfeuille, A. I. Shapiro, J. Beer, F. Steinhilber, Y. Brugnara, and W. Schmutz
Geosci. Model Dev., 7, 2157–2179, https://doi.org/10.5194/gmd-7-2157-2014, https://doi.org/10.5194/gmd-7-2157-2014, 2014
G. Ganbavale, C. Marcolli, U. K. Krieger, A. Zuend, G. Stratmann, and T. Peter
Atmos. Chem. Phys., 14, 9993–10012, https://doi.org/10.5194/acp-14-9993-2014, https://doi.org/10.5194/acp-14-9993-2014, 2014
A. Cirisan, B. P. Luo, I. Engel, F. G. Wienhold, M. Sprenger, U. K. Krieger, U. Weers, G. Romanens, G. Levrat, P. Jeannet, D. Ruffieux, R. Philipona, B. Calpini, P. Spichtinger, and T. Peter
Atmos. Chem. Phys., 14, 7341–7365, https://doi.org/10.5194/acp-14-7341-2014, https://doi.org/10.5194/acp-14-7341-2014, 2014
I. Suter, R. Zech, J. G. Anet, and T. Peter
Clim. Past, 10, 1183–1194, https://doi.org/10.5194/cp-10-1183-2014, https://doi.org/10.5194/cp-10-1183-2014, 2014
J. G. Anet, S. Muthers, E. V. Rozanov, C. C. Raible, A. Stenke, A. I. Shapiro, S. Brönnimann, F. Arfeuille, Y. Brugnara, J. Beer, F. Steinhilber, W. Schmutz, and T. Peter
Clim. Past, 10, 921–938, https://doi.org/10.5194/cp-10-921-2014, https://doi.org/10.5194/cp-10-921-2014, 2014
I. Engel, B. P. Luo, S. M. Khaykin, F. G. Wienhold, H. Vömel, R. Kivi, C. R. Hoyle, J.-U. Grooß, M. C. Pitts, and T. Peter
Atmos. Chem. Phys., 14, 3231–3246, https://doi.org/10.5194/acp-14-3231-2014, https://doi.org/10.5194/acp-14-3231-2014, 2014
C. Marcolli
Atmos. Chem. Phys., 14, 2071–2104, https://doi.org/10.5194/acp-14-2071-2014, https://doi.org/10.5194/acp-14-2071-2014, 2014
F. Arfeuille, D. Weisenstein, H. Mack, E. Rozanov, T. Peter, and S. Brönnimann
Clim. Past, 10, 359–375, https://doi.org/10.5194/cp-10-359-2014, https://doi.org/10.5194/cp-10-359-2014, 2014
J.-U. Grooß, I. Engel, S. Borrmann, W. Frey, G. Günther, C. R. Hoyle, R. Kivi, B. P. Luo, S. Molleker, T. Peter, M. C. Pitts, H. Schlager, G. Stiller, H. Vömel, K. A. Walker, and R. Müller
Atmos. Chem. Phys., 14, 1055–1073, https://doi.org/10.5194/acp-14-1055-2014, https://doi.org/10.5194/acp-14-1055-2014, 2014
J. Staufer, J. Staehelin, R. Stübi, T. Peter, F. Tummon, and V. Thouret
Atmos. Meas. Tech., 7, 241–266, https://doi.org/10.5194/amt-7-241-2014, https://doi.org/10.5194/amt-7-241-2014, 2014
J. Staufer, J. Staehelin, R. Stübi, T. Peter, F. Tummon, and V. Thouret
Atmos. Meas. Tech., 6, 3393–3406, https://doi.org/10.5194/amt-6-3393-2013, https://doi.org/10.5194/amt-6-3393-2013, 2013
S. M. Khaykin, I. Engel, H. Vömel, I. M. Formanyuk, R. Kivi, L. I. Korshunov, M. Krämer, A. D. Lykov, S. Meier, T. Naebert, M. C. Pitts, M. L. Santee, N. Spelten, F. G. Wienhold, V. A. Yushkov, and T. Peter
Atmos. Chem. Phys., 13, 11503–11517, https://doi.org/10.5194/acp-13-11503-2013, https://doi.org/10.5194/acp-13-11503-2013, 2013
F. Arfeuille, B. P. Luo, P. Heckendorn, D. Weisenstein, J. X. Sheng, E. Rozanov, M. Schraner, S. Brönnimann, L. W. Thomason, and T. Peter
Atmos. Chem. Phys., 13, 11221–11234, https://doi.org/10.5194/acp-13-11221-2013, https://doi.org/10.5194/acp-13-11221-2013, 2013
J. G. Anet, S. Muthers, E. Rozanov, C. C. Raible, T. Peter, A. Stenke, A. I. Shapiro, J. Beer, F. Steinhilber, S. Brönnimann, F. Arfeuille, Y. Brugnara, and W. Schmutz
Atmos. Chem. Phys., 13, 10951–10967, https://doi.org/10.5194/acp-13-10951-2013, https://doi.org/10.5194/acp-13-10951-2013, 2013
I. Engel, B. P. Luo, M. C. Pitts, L. R. Poole, C. R. Hoyle, J.-U. Grooß, A. Dörnbrack, and T. Peter
Atmos. Chem. Phys., 13, 10769–10785, https://doi.org/10.5194/acp-13-10769-2013, https://doi.org/10.5194/acp-13-10769-2013, 2013
A. Stenke, C. R. Hoyle, B. Luo, E. Rozanov, J. Gröbner, L. Maag, S. Brönnimann, and T. Peter
Atmos. Chem. Phys., 13, 9713–9729, https://doi.org/10.5194/acp-13-9713-2013, https://doi.org/10.5194/acp-13-9713-2013, 2013
C. R. Hoyle, I. Engel, B. P. Luo, M. C. Pitts, L. R. Poole, J.-U. Grooß, and T. Peter
Atmos. Chem. Phys., 13, 9577–9595, https://doi.org/10.5194/acp-13-9577-2013, https://doi.org/10.5194/acp-13-9577-2013, 2013
M. von Hobe, S. Bekki, S. Borrmann, F. Cairo, F. D'Amato, G. Di Donfrancesco, A. Dörnbrack, A. Ebersoldt, M. Ebert, C. Emde, I. Engel, M. Ern, W. Frey, S. Genco, S. Griessbach, J.-U. Grooß, T. Gulde, G. Günther, E. Hösen, L. Hoffmann, V. Homonnai, C. R. Hoyle, I. S. A. Isaksen, D. R. Jackson, I. M. Jánosi, R. L. Jones, K. Kandler, C. Kalicinsky, A. Keil, S. M. Khaykin, F. Khosrawi, R. Kivi, J. Kuttippurath, J. C. Laube, F. Lefèvre, R. Lehmann, S. Ludmann, B. P. Luo, M. Marchand, J. Meyer, V. Mitev, S. Molleker, R. Müller, H. Oelhaf, F. Olschewski, Y. Orsolini, T. Peter, K. Pfeilsticker, C. Piesch, M. C. Pitts, L. R. Poole, F. D. Pope, F. Ravegnani, M. Rex, M. Riese, T. Röckmann, B. Rognerud, A. Roiger, C. Rolf, M. L. Santee, M. Scheibe, C. Schiller, H. Schlager, M. Siciliani de Cumis, N. Sitnikov, O. A. Søvde, R. Spang, N. Spelten, F. Stordal, O. Sumińska-Ebersoldt, A. Ulanovski, J. Ungermann, S. Viciani, C. M. Volk, M. vom Scheidt, P. von der Gathen, K. Walker, T. Wegner, R. Weigel, S. Weinbruch, G. Wetzel, F. G. Wienhold, I. Wohltmann, W. Woiwode, I. A. K. Young, V. Yushkov, B. Zobrist, and F. Stroh
Atmos. Chem. Phys., 13, 9233–9268, https://doi.org/10.5194/acp-13-9233-2013, https://doi.org/10.5194/acp-13-9233-2013, 2013
A. Stenke, M. Schraner, E. Rozanov, T. Egorova, B. Luo, and T. Peter
Geosci. Model Dev., 6, 1407–1427, https://doi.org/10.5194/gmd-6-1407-2013, https://doi.org/10.5194/gmd-6-1407-2013, 2013
A. J. Huisman, U. K. Krieger, A. Zuend, C. Marcolli, and T. Peter
Atmos. Chem. Phys., 13, 6647–6662, https://doi.org/10.5194/acp-13-6647-2013, https://doi.org/10.5194/acp-13-6647-2013, 2013
F. Hasebe, Y. Inai, M. Shiotani, M. Fujiwara, H. Vömel, N. Nishi, S.-Y. Ogino, T. Shibata, S. Iwasaki, N. Komala, T. Peter, and S. J. Oltmans
Atmos. Chem. Phys., 13, 4393–4411, https://doi.org/10.5194/acp-13-4393-2013, https://doi.org/10.5194/acp-13-4393-2013, 2013
Related subject area
Subject: Clouds and Precipitation | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Retention of α-pinene oxidation products and nitro-aromatic compounds during riming
Direct formation of HONO through aqueous-phase photolysis of organic nitrates
On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal
Effects of pH and light exposure on the survival of bacteria and their ability to biodegrade organic compounds in clouds: implications for microbial activity in acidic cloud water
Towards a chemical mechanism of the oxidation of aqueous sulfur dioxide via isoprene hydroxyl hydroperoxides (ISOPOOH)
On the importance of atmospheric loss of organic nitrates by aqueous-phase ●OH oxidation
Lignin's ability to nucleate ice via immersion freezing and its stability towards physicochemical treatments and atmospheric processing
Biodegradation of phenol and catechol in cloud water: comparison to chemical oxidation in the atmospheric multiphase system
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 3: Aluminosilicates
Aqueous reactions of organic triplet excited states with atmospheric alkenes
The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 1: The K-feldspar microcline
Direct molecular-level characterization of different heterogeneous freezing modes on mica – Part 1
Chemistry of riming: the retention of organic and inorganic atmospheric trace constituents
Surface-charge-induced orientation of interfacial water suppresses heterogeneous ice nucleation on α-alumina (0001)
Screening of cloud microorganisms isolated at the Puy de Dôme (France) station for the production of biosurfactants
Comparing contact and immersion freezing from continuous flow diffusion chambers
A better understanding of hydroxyl radical photochemical sources in cloud waters collected at the puy de Dôme station – experimental versus modelled formation rates
Deposition and immersion-mode nucleation of ice by three distinct samples of volcanic ash
Organic matter matters for ice nuclei of agricultural soil origin
Effect of atmospheric organic complexation on iron-bearing dust solubility
Are sesquiterpenes a good source of secondary organic cloud condensation nuclei (CCN)? Revisiting β-caryophyllene CCN
Ice nucleation efficiency of clay minerals in the immersion mode
Atmospheric chemistry of carboxylic acids: microbial implication versus photochemistry
Yields of hydrogen peroxide from the reaction of hydroxyl radical with organic compounds in solution and ice
In-cloud processes of methacrolein under simulated conditions – Part 1: Aqueous phase photooxidation
In-cloud processes of methacrolein under simulated conditions – Part 2: Formation of secondary organic aerosol
Christine Borchers, Jackson Seymore, Martanda Gautam, Konstantin Dörholt, Yannik Müller, Andreas Arndt, Laura Gömmer, Florian Ungeheuer, Miklós Szakáll, Stephan Borrmann, Alexander Theis, Alexander Lucas Vogel, and Thorsten Hoffmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-1443, https://doi.org/10.5194/egusphere-2024-1443, 2024
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Riming, a crucial process in cloud dynamics, influences the vertical distribution of compounds in the atmosphere. Experiments in Mainz's wind tunnel investigated retention coefficients of organic compounds under varying conditions. Findings suggest a correlation between Henry's law constant and retention, applicable even to complex organic molecules.
Juan Miguel González-Sánchez, Miquel Huix-Rotllant, Nicolas Brun, Julien Morin, Carine Demelas, Amandine Durand, Sylvain Ravier, Jean-Louis Clément, and Anne Monod
Atmos. Chem. Phys., 23, 15135–15147, https://doi.org/10.5194/acp-23-15135-2023, https://doi.org/10.5194/acp-23-15135-2023, 2023
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Organic nitrates play a crucial role in air pollution, as they are nitrogen oxide (NOx) reservoirs. This work investigated the reaction products and mechanisms of their reactivity with light in the aqueous phase (cloud and fog conditions and wet aerosol). Our findings reveal that this chemistry leads to the formation of atmospheric nitrous acid (HONO).
Juan Miguel González-Sánchez, Nicolas Brun, Junteng Wu, Sylvain Ravier, Jean-Louis Clément, and Anne Monod
Atmos. Chem. Phys., 23, 5851–5866, https://doi.org/10.5194/acp-23-5851-2023, https://doi.org/10.5194/acp-23-5851-2023, 2023
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Organic nitrates play a crucial role in air pollution, as they are NOx reservoirs. This work investigated for the first time their reactivity with light in the aqueous phase (cloud and fog and wet aerosol), proving it slower than in the gas phase. Therefore, our findings reveal that partitioning of organic nitrates in the aqueous phase leads to longer atmospheric lifetimes of these compounds and thus a broader spatial distribution of their related pollution.
Yushuo Liu, Chee Kent Lim, Zhiyong Shen, Patrick K. H. Lee, and Theodora Nah
Atmos. Chem. Phys., 23, 1731–1747, https://doi.org/10.5194/acp-23-1731-2023, https://doi.org/10.5194/acp-23-1731-2023, 2023
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We investigated how cloud water pH and solar radiation impact the survival and energetic metabolism of two neutrophilic bacteria species and their biodegradation of organic acids. Experiments were performed using artificial cloud water that mimicked the pH and composition of cloud water in South China. We found that there is a minimum cloud water pH threshold at which neutrophilic bacteria will survive and biodegrade organic compounds in cloud water during the daytime and/or nighttime.
Eleni Dovrou, Kelvin H. Bates, Jean C. Rivera-Rios, Joshua L. Cox, Joshua D. Shutter, and Frank N. Keutsch
Atmos. Chem. Phys., 21, 8999–9008, https://doi.org/10.5194/acp-21-8999-2021, https://doi.org/10.5194/acp-21-8999-2021, 2021
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We examined the mechanism and products of oxidation of dissolved sulfur dioxide with the main isomers of isoprene hydroxyl hydroperoxides, via laboratory and model analysis. Two chemical mechanism pathways are proposed and the results provide an improved understanding of the broader atmospheric chemistry and role of multifunctional organic hydroperoxides, which should be the dominant VOC oxidation products under low-NO conditions, highlighting their significant contribution to sulfate formation.
Juan Miguel González-Sánchez, Nicolas Brun, Junteng Wu, Julien Morin, Brice Temime-Roussel, Sylvain Ravier, Camille Mouchel-Vallon, Jean-Louis Clément, and Anne Monod
Atmos. Chem. Phys., 21, 4915–4937, https://doi.org/10.5194/acp-21-4915-2021, https://doi.org/10.5194/acp-21-4915-2021, 2021
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Organic nitrates play a crucial role in air pollution as they are considered NOx reservoirs. This work lights up the importance of their reactions with OH radicals in the aqueous phase (cloud/fog, wet aerosol), which is slower than in the gas phase. For compounds that significantly partition in water such as polyfunctional biogenic nitrates, these aqueous-phase reactions should drive their atmospheric removal, leading to a broader spatial distribution of NOx than previously accounted for.
Sophie Bogler and Nadine Borduas-Dedekind
Atmos. Chem. Phys., 20, 14509–14522, https://doi.org/10.5194/acp-20-14509-2020, https://doi.org/10.5194/acp-20-14509-2020, 2020
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To study the role of organic matter in ice crystal formation, we investigated the ice nucleation ability of a subcomponent of organic aerosols, the biopolymer lignin, using a droplet-freezing technique. We found that lignin is an ice-active macromolecule with changing abilities based on dilutions. The effects of atmospheric processing and of physicochemical treatments on the ability of lignin solutions to freeze were negligible. Thus, lignin is a recalcitrant ice-nucleating macromolecule.
Saly Jaber, Audrey Lallement, Martine Sancelme, Martin Leremboure, Gilles Mailhot, Barbara Ervens, and Anne-Marie Delort
Atmos. Chem. Phys., 20, 4987–4997, https://doi.org/10.5194/acp-20-4987-2020, https://doi.org/10.5194/acp-20-4987-2020, 2020
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Current atmospheric multiphase models do not include biotransformations of organic compounds by bacteria, although many previous studies of our and other research groups have shown microbial activity in cloud water. The current lab/model study shows that for water-soluble aromatic compounds, biodegradation by bacteria may be as efficient as chemical reactions in cloud water.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6059–6084, https://doi.org/10.5194/acp-19-6059-2019, https://doi.org/10.5194/acp-19-6059-2019, 2019
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This paper not only interests the Atmospheric Science community but has a potential to cater to a broader audience. We discuss both long- and short-term effects of various
atmospherically relevantchemical species on fairly abundant mineral surfaces like feldspars and clays. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Richie Kaur, Brandi M. Hudson, Joseph Draper, Dean J. Tantillo, and Cort Anastasio
Atmos. Chem. Phys., 19, 5021–5032, https://doi.org/10.5194/acp-19-5021-2019, https://doi.org/10.5194/acp-19-5021-2019, 2019
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Organic triplets are an important class of aqueous photooxidants, but little is known about their reactions with most atmospheric organic compounds. We measured the reaction rate constants of a model triplet with 17 aliphatic alkenes; using their correlation with oxidation potential, we predicted rate constants for some atmospherically relevant alkenes. Depending on their reactivities, triplets can be minor to important sinks for isoprene- and limonene-derived alkenes in cloud or fog drops.
Julián Gelman Constantin, Melisa M. Gianetti, María P. Longinotti, and Horacio R. Corti
Atmos. Chem. Phys., 18, 14965–14978, https://doi.org/10.5194/acp-18-14965-2018, https://doi.org/10.5194/acp-18-14965-2018, 2018
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Numerous studies have shown that ice surface is actually coated by a thin layer of water even for temperatures below melting temperature. This quasi-liquid layer is relevant in the atmospheric chemistry of clouds, polar regions, glaciers, and other cold regions. We present new results of atomic force microscopy on pure ice, which suggests a thickness for this layer below 1 nm between -7 ºC and -2 ºC. We propose that in many cases previous authors have overestimated this thickness.
Anand Kumar, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 18, 7057–7079, https://doi.org/10.5194/acp-18-7057-2018, https://doi.org/10.5194/acp-18-7057-2018, 2018
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We have performed immersion freezing experiments with microcline (most active ice nucleation, IN, K-feldspar polymorph) and investigated the effect of ammonium and non-ammonium solutes on its IN efficiency. We report increased IN efficiency of microcline in dilute ammonia- or ammonium-containing solutions, which opens up a pathway for condensation freezing occurring at a warmer temperature than immersion freezing.
Ahmed Abdelmonem
Atmos. Chem. Phys., 17, 10733–10741, https://doi.org/10.5194/acp-17-10733-2017, https://doi.org/10.5194/acp-17-10733-2017, 2017
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On the basis of supercooled SHG spectroscopy, I report molecular-level evidence for the existence of one- and two-step deposition freezing depending on the surface type and the supersaturation conditions. In addition, immersion freezing shows a transient ice phase with a lifetime of c. 1 min. This study provides new insights into atmospheric processes and can impact various industrial and research branches, particularly climate change, weather modification, and tracing water in the hydrosphere.
Alexander Jost, Miklós Szakáll, Karoline Diehl, Subir K. Mitra, and Stephan Borrmann
Atmos. Chem. Phys., 17, 9717–9732, https://doi.org/10.5194/acp-17-9717-2017, https://doi.org/10.5194/acp-17-9717-2017, 2017
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During riming of graupel and hail, soluble chemical trace constituents contained in the liquid droplets could be retained while freezing onto the glaciated particle, or released back to the air potentially at other altitudes as retained. Quantification of retention constitutes a major uncertainty in numerical models for atmospheric chemistry and improvements hinge upon experimental determination of retention for carboxylic acids, aldehydes, SO2, H2O2, NH2, and others, as presented in this paper.
Ahmed Abdelmonem, Ellen H. G. Backus, Nadine Hoffmann, M. Alejandra Sánchez, Jenée D. Cyran, Alexei Kiselev, and Mischa Bonn
Atmos. Chem. Phys., 17, 7827–7837, https://doi.org/10.5194/acp-17-7827-2017, https://doi.org/10.5194/acp-17-7827-2017, 2017
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We report the effect of surface charge on heterogeneous immersion freezing for the atmospherically relevant sapphire surface. Combining linear and nonlinear optical techniques and investigating isolated drops, we find that charge-induced surface templating is detrimental for ice nucleation on α-alumina surface. This study provides new insights into atmospheric processes and can impact various industrial and research branches, particularly climate change and tracing of water in the hydrosphere.
Pascal Renard, Isabelle Canet, Martine Sancelme, Nolwenn Wirgot, Laurent Deguillaume, and Anne-Marie Delort
Atmos. Chem. Phys., 16, 12347–12358, https://doi.org/10.5194/acp-16-12347-2016, https://doi.org/10.5194/acp-16-12347-2016, 2016
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A total of 480 microorganisms collected from 39 clouds sampled in France were isolated and identified. This unique collection was screened for biosurfactant production by measuring the surface tension. 41 % of the tested strains were active producers. Pseudomonas, the most frequently detected genus in clouds, was the dominant group for the production of biosurfactants. Further, the potential impact of the production of biosurfactants by cloud microorganisms on atmospheric processes is discussed.
Baban Nagare, Claudia Marcolli, André Welti, Olaf Stetzer, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8899–8914, https://doi.org/10.5194/acp-16-8899-2016, https://doi.org/10.5194/acp-16-8899-2016, 2016
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Short summary
The relative importance of contact freezing and immersion freezing at mixed-phase cloud temperatures is the subject of debate. We performed experiments using continuous-flow diffusion chambers to compare the freezing efficiency of ice-nucleating particles for both these nucleation modes. Silver iodide, kaolinite and Arizona Test Dust were used as ice-nucleating particles. We could not confirm the dominance of contact freezing over immersion freezing for our experimental conditions.
A. Bianco, M. Passananti, H. Perroux, G. Voyard, C. Mouchel-Vallon, N. Chaumerliac, G. Mailhot, L. Deguillaume, and M. Brigante
Atmos. Chem. Phys., 15, 9191–9202, https://doi.org/10.5194/acp-15-9191-2015, https://doi.org/10.5194/acp-15-9191-2015, 2015
G. P. Schill, K. Genareau, and M. A. Tolbert
Atmos. Chem. Phys., 15, 7523–7536, https://doi.org/10.5194/acp-15-7523-2015, https://doi.org/10.5194/acp-15-7523-2015, 2015
Short summary
Short summary
Fine volcanic ash can influence cloud glaciation and, therefore, global climate. In this work we examined the heterogeneous ice nucleation properties of three distinct types of volcanic ash. We find that, in contrast to previous studies, these volcanic ash samples have different ice nucleation properties in the immersion mode. In the deposition mode, however, they nucleate ice with similar efficiency. We show that this behavior may be due to their mineralogy.
Y. Tobo, P. J. DeMott, T. C. J. Hill, A. J. Prenni, N. G. Swoboda-Colberg, G. D. Franc, and S. M. Kreidenweis
Atmos. Chem. Phys., 14, 8521–8531, https://doi.org/10.5194/acp-14-8521-2014, https://doi.org/10.5194/acp-14-8521-2014, 2014
R. Paris and K. V. Desboeufs
Atmos. Chem. Phys., 13, 4895–4905, https://doi.org/10.5194/acp-13-4895-2013, https://doi.org/10.5194/acp-13-4895-2013, 2013
X. Tang, D. R. Cocker III, and A. Asa-Awuku
Atmos. Chem. Phys., 12, 8377–8388, https://doi.org/10.5194/acp-12-8377-2012, https://doi.org/10.5194/acp-12-8377-2012, 2012
V. Pinti, C. Marcolli, B. Zobrist, C. R. Hoyle, and T. Peter
Atmos. Chem. Phys., 12, 5859–5878, https://doi.org/10.5194/acp-12-5859-2012, https://doi.org/10.5194/acp-12-5859-2012, 2012
M. Vaïtilingom, T. Charbouillot, L. Deguillaume, R. Maisonobe, M. Parazols, P. Amato, M. Sancelme, and A.-M. Delort
Atmos. Chem. Phys., 11, 8721–8733, https://doi.org/10.5194/acp-11-8721-2011, https://doi.org/10.5194/acp-11-8721-2011, 2011
T. Hullar and C. Anastasio
Atmos. Chem. Phys., 11, 7209–7222, https://doi.org/10.5194/acp-11-7209-2011, https://doi.org/10.5194/acp-11-7209-2011, 2011
Yao Liu, I. El Haddad, M. Scarfogliero, L. Nieto-Gligorovski, B. Temime-Roussel, E. Quivet, N. Marchand, B. Picquet-Varrault, and A. Monod
Atmos. Chem. Phys., 9, 5093–5105, https://doi.org/10.5194/acp-9-5093-2009, https://doi.org/10.5194/acp-9-5093-2009, 2009
I. El Haddad, Yao Liu, L. Nieto-Gligorovski, V. Michaud, B. Temime-Roussel, E. Quivet, N. Marchand, K. Sellegri, and A. Monod
Atmos. Chem. Phys., 9, 5107–5117, https://doi.org/10.5194/acp-9-5107-2009, https://doi.org/10.5194/acp-9-5107-2009, 2009
Cited articles
Abdelmonem, A., Backus, E. H. G., Hoffmann, N., Sánchez, M. A., Cyran, J.
D., Kiselev, A., and Bonn, M.: Surface-charge-induced orientation of
interfacial water suppresses heterogeneous ice nucleation on α-alumina (0001), Atmos. Chem. Phys., 17, 7827–7837,
https://doi.org/10.5194/acp-17-7827-2017, 2017.
Alastuey, A., Querol, X., Castillo, S., Escudero, M., Avila, A., Cuevas, E.,
Torres, C., Romero, P.-M., Exposito, F., García, O., Pedro Diaz, J.,
Dingenen, R. V., and Putaud, J. P.: Characterisation of TSP and PM2.5 at
Izaña and sta, Cruz de Tenerife (Canary Islands, Spain) during a Saharan
dust episode (July 2002), Atmos. Environ., 39, 4715–4728,
https://doi.org/10.1016/j.atmosenv.2005.04.018, 2005.
Alpert, P. A., Aller, J. Y., and Knopf, D. A.: Ice nucleation from aqueous
NaCl droplets with and without marine diatoms, Atmos. Chem. Phys., 11,
5539–5555, https://doi.org/10.5194/acp-11-5539-2011, 2011a.
Alpert, P. A., Aller, J. Y., and Knopf, D. A.: Initiation of the ice phase by
marine biogenic surfaces in supersaturated gas and supercooled aqueous
phases, Phys. Chem. Chem. Phys., 13, 19882–19894, https://doi.org/10.1039/C1CP21844A,
2011b.
Archuleta, C. M., DeMott, P. J., and Kreidenweis, S. M.: Ice nucleation by
surrogates for atmospheric mineral dust and mineral dust/sulfate particles at
cirrus temperatures, Atmos. Chem. Phys., 5, 2617–2634,
https://doi.org/10.5194/acp-5-2617-2005, 2005.
Atkinson, J. D., Murray, B. J., Woodhouse, M. T., Whale, T. F., Baustian, K.
J., Carslaw, K. S., Dobbie, S., O'Sullivan, D., and Malkin, T. L.: The
importance of feldspar for ice nucleation by mineral dust in mixed-phase
clouds, Nature, 498, 355–358, https://doi.org/10.1038/nature12278, 2013.
Augustin-Bauditz, S., Wex, H., Kanter, S., Ebert, M., Niedermeier, D., Stolz,
F., Prager, A., and Stratmann, F.: The immersion mode ice nucleation behavior
of mineral dusts: A comparison of different pure and surface modified dusts,
Geophys. Res. Lett., 41, 7375–7382, https://doi.org/10.1002/2014GL061317, 2014.
Avila, A., Queralt-Mitjans, I., and Alarcón, M.: Mineralogical
composition of African dust delivered by red rains over northeastern Spain,
J. Geophys. Res.-Atmos., 102, 21977–21996, https://doi.org/10.1029/97JD00485, 1997.
Baker, M. B.: Cloud microphysics and climate, Science, 276, 1072–1078,
https://doi.org/10.1126/science.276.5315.1072, 1997.
Baughman, R. J.: Quartz crystal growth, J. Cryst. Growth, 112, 753–757,
https://doi.org/10.1016/0022-0248(91)90132-O, 1991.
Belton, D. J., Deschaume, O., and Perry, C. C.: An overview of the
fundamentals of the chemistry of silica with relevance to biosilicification
and technological advances, FEBS J., 279, 1710–1720,
https://doi.org/10.1111/j.1742-4658.2012.08531.x, 2012.
Bennett, P. C., Melcer, M. E., Siegel, D. I., and Hassett, J. P.: The
dissolution of quartz in dilute aqueous solutions of organic acids at
25 ∘C, Geochim. Cosmochim. Ac., 52, 1521–1530,
https://doi.org/10.1016/0016-7037(88)90222-0, 1988.
Berger, G., Cadore, E., Schott, J., and Dove, P. M.: Dissolution rate of
quartz in lead and sodium electrolyte solutions between 25 and
300 ∘C: Effect of the nature of surface complexes and reaction
affinity, Geochim. Cosmochim. Ac., 58, 541–551,
https://doi.org/10.1016/0016-7037(94)90487-1, 1994.
Bickmore, B. R., Wheeler, J. C., Bates, B., Nagy, K. L., and Eggett, D. L.:
Reaction pathways for quartz dissolution determined by statistical and
graphical analysis of macroscopic experimental data, Geochim. Cosmochim. Ac.,
72, 4521–4536, https://doi.org/10.1016/j.gca.2008.07.002, 2008.
Blomfield, G. A. and Little, L. H.: Chemisorption of ammonia on silica, Can.
J. Chem., 51, 1771–1781, https://doi.org/10.1139/v73-265, 1973.
Bolis, V., Fubini, B., Coluccia, S., and Mostacci, E.: Surface hydration of
crystalline and amorphous silicas, J. Therm. Anal. Calorim., 30, 1283–1292,
https://doi.org/10.1007/bf01914297, 1985.
Bolis, V., Fubini, B., Marchese, L., Martra, G., and Costa, D.: Hydrophilic
and hydrophobic sites on dehydrated crystalline and amorphous silicas, J.
Chem. Soc., 87, 497–505, https://doi.org/10.1039/FT9918700497, 1991.
Boose, Y., Sierau, B., García, M. I., Rodríguez, S., Alastuey, A.,
Linke, C., Schnaiter, M., Kupiszewski, P., Kanji, Z. A., and Lohmann, U.: Ice
nucleating particles in the Saharan air layer, Atmos. Chem. Phys., 16,
9067–9087, https://doi.org/10.5194/acp-16-9067-2016, 2016a.
Boose, Y., Welti, A., Atkinson, J., Ramelli, F., Danielczok, A., Bingemer, H.
G., Plötze, M., Sierau, B., Kanji, Z. A., and Lohmann, U.: Heterogeneous
ice nucleation on dust particles sourced from nine deserts worldwide – Part
1: Immersion freezing, Atmos. Chem. Phys., 16, 15075–15095,
https://doi.org/10.5194/acp-16-15075-2016, 2016b.
Bowen, N. L.: The reaction principle in petrogenesis, J. Geol., 30, 177–198,
1922.
Bowen, N. L.: The evolution of igneous rocks, Princeton University Press,
Princeton, 1928.
Brady, P. V. and Walther, J. V.: Controls on silicate dissolution rates in
neutral and basic pH solutions at 25 ∘C, Geochim. Cosmochim. Ac.,
53, 2823–2830, https://doi.org/10.1016/0016-7037(89)90160-9, 1989.
Brady, P. V. and Walther, J. V.: Kinetics of quartz dissolution at low
temperatures, Chem. Geol., 82, 253–264, https://doi.org/10.1016/0009-2541(90)90084-K,
1990.
Brinker, C. J., Tallant, D. R., Roth, E. P., and Ashley, C. S.: Sol-gel
transition in simple silicates: III. Structural studies during densification,
J. Non-Cryst. Solids, 82, 117–126, https://doi.org/10.1016/0022-3093(86)90119-5, 1986.
Brinker, C. J., Kirkpatrick, R. J., Tallant, D. R., Bunker, B. C., and
Montez, B.: NMR confirmation of strained “defects” in amorphous silica, J.
Non-Cryst. Sol., 99, 418–428, https://doi.org/10.1016/0022-3093(88)90448-6, 1988.
Bunker, B. C.: Molecular mechanisms for corrosion of silica and silicate
glasses, J. Non-Cryst. Solids, 179, 300–308,
https://doi.org/10.1016/0022-3093(94)90708-0, 1994.
Burkert-Kohn, M., Wex, H., Welti, A., Hartmann, S., Grawe, S., Hellner, L.,
Herenz, P., Atkinson, J. D., Stratmann, F., and Kanji, Z. A.: Leipzig ice
nucleation chamber comparison (LINC): Intercomparison of four online ice
nucleation counters, Atmos. Chem. Phys., 17, 11683–11705,
https://doi.org/10.5194/acp-17-11683-2017, 2017.
Cant, N. W. and Little, L. H.: The infrared spectrum of ammonia adsorbed on
cabosil silica powder, Can. J. Chem., 43, 1252–1254, https://doi.org/10.1139/v65-170,
1965.
Cantrell, W. and Robinson, C.: Heterogeneous freezing of ammonium sulfate and
sodium chloride solutions by long chain alcohols, Geophys. Res. Lett., 33,
L07802, https://doi.org/10.1029/2005GL024945, 2006.
Caquineau, S., Gaudichet, A., Gomes, L., Magonthier, M.-C., and Chatenet, B.:
Saharan dust: Clay ratio as a relevant tracer to assess the origin of
soil-derived aerosols, Geophys. Res. Lett., 25, 983–986,
https://doi.org/10.1029/98GL00569, 1998.
Caquineau, S., Gaudichet, A., Gomes, L., and Legrand, M.: Mineralogy of
Saharan dust transported over northwestern tropical Atlantic ocean in
relation to source regions, J. Geophys. Res., 107, 4251,
https://doi.org/10.1029/2000JD000247, 2002.
Criscenti, L. J., Kubicki, J. D., and Brantley, S. L.: Silicate glass and
mineral dissolution:? Calculated reaction paths and activation energies for
hydrolysis of a Q3 Si by H3O+ using ab initio methods, J.
Phys. Chem. A, 110, 198–206, https://doi.org/10.1021/jp044360a, 2006.
Crundwell, F. K.: On the mechanism of the dissolution of quartz and silica in
aqueous solutions, ACS Omega, 2, 1116–1127, https://doi.org/10.1021/acsomega.7b00019,
2017.
DeMott, P. J., Cziczo, D. J., Prenni, A. J., Murphy, D. M., Kreidenweis, S.
M., Thomson, D. S., Borys, R., and Rogers, D. C.: Measurements of the
concentration and composition of nuclei for cirrus formation, P. Natl. Acad.
Sci. USA, 100, 14655, https://doi.org/10.1073/pnas.2532677100, 2003b.
DeMott, P. J., Prenni, A. J., Liu, X., Kreidenweis, S. M., Petters, M. D.,
Twohy, C. H., Richardson, M. S., Eidhammer, T., and Rogers, D. C.: Predicting
global atmospheric ice nuclei distributions and their impacts on climate, P.
Natl. Acad. Sci. USA, 107, 11217–11222, https://doi.org/10.1073/pnas.0910818107, 2010.
Döbelin, N. and Kleeberg, R.: Profex: A graphical user interface for the
rietveld refinement program BGMN, J. Appl. Crystallogr., 48, 1573–1580,
https://doi.org/10.1107/S1600576715014685, 2015.
Donaldson, K. E. N., and Borm, P. J. A.: The quartz hazard: A variable
entity, Ann. Occup. Hyg., 42, 287–294, https://doi.org/10.1093/annhyg/42.5.287, 1998.
Du, Q., Freysz, E., and Shen, Y. R.: Vibrational spectra of water molecules
at quartz/water interfaces, Phys. Rev. Lett., 72, 238–241, 1994.
Eischens, R. P. and Pliskin, W. A.: The infrared spectra of adsorbed
molecules, in: Advances in catalysis, edited by: Eley, D. D., Frankenburg, W.
G., Komarewsky, V. I., and Weisz, P. B., Academic Press, 1–56, 1958.
Field, P. R., Möhler, O., Connolly, P., Krämer, M., Cotton, R.,
Heymsfield, A. J., Saathoff, H., and Schnaiter, M.: Some ice nucleation
characteristics of Asian and Saharan desert dust, Atmos. Chem. Phys., 6,
2991–3006, https://doi.org/10.5194/acp-6-2991-2006, 2006.
Folman, M.: Infra-red studies of NH3 adsorption on chlorinated
porous vycor glass, Trans. Faraday Soc., 57, 2000–2006,
https://doi.org/10.1039/TF9615702000, 1961.
Fubini, B.: Surface chemistery and quartz hazard, Ann. Occup. Hyg., 42,
521–530, https://doi.org/10.1093/annhyg/42.8.521, 1998.
Fubini, B., Bolis, V., and Giamello, E.: The surface chemistry of crushed
quartz dust in relation to its pathogenicity, Inorg. Chim. Acta, 138,
193–197, https://doi.org/10.1016/S0020-1693(00)81222-0, 1987.
Fubini, B., Giamello, E., Pugliese, L., and Volante, M.: Mechanically induced
defects in quartz and their impact on pathogenicity, Solid State Ionics,
32/33, 334–343, https://doi.org/10.1016/0167-2738(89)90238-5, 1989.
Fubini, B., Bolis, V., Cavenago, A., and Ugliengo, P.: Ammonia and water as
probes for the surface reactivity of covalent solids: Cristobalite and
silicon carbide, J. Chem. Soc., 88, 277–289, https://doi.org/10.1039/FT9928800277, 1992.
Götze, J. and Möckel, R.: Quartz: Deposits, mineralogy and analytics,
Springer, Berlin, Heidelberg, 2014.
Harrison, A. D., Whale, T. F., Carpenter, M. A., Holden, M. A., Neve, L.,
O'Sullivan, D., Vergara Temprado, J., and Murray, B. J.: Not all feldspars
are equal: A survey of ice nucleating properties across the feldspar group of
minerals, Atmos. Chem. Phys., 16, 10927–10940,
https://doi.org/10.5194/acp-16-10927-2016, 2016.
Henderson, J. H., Syers, J. K., and Jackson, M. L.: Quartz dissolution as
influenced by pH and the presence of a disturbed surface layer, Isr. J.
Chem., 8, 357–372, https://doi.org/10.1002/ijch.197000042, 1970.
House, W. A. and Orr, D. R.: Investigation of the pH dependence of the
kinetics of quartz dissolution at 25 degree C, J. Chem. Soc., 88, 233–241,
https://doi.org/10.1039/FT9928800233, 1992.
Huneeus, N., Schulz, M., Balkanski, Y., Griesfeller, J., Prospero, J., Kinne,
S., Bauer, S., Boucher, O., Chin, M., Dentener, F., Diehl, T., Easter, R.,
Fillmore, D., Ghan, S., Ginoux, P., Grini, A., Horowitz, L., Koch, D., Krol,
M. C., Landing, W., Liu, X., Mahowald, N., Miller, R., Morcrette, J. J.,
Myhre, G., Penner, J., Perlwitz, J., Stier, P., Takemura, T., and Zender, C.
S.: Global dust model intercomparison in aerocom phase I, Atmos. Chem. Phys.,
11, 7781–7816, https://doi.org/10.5194/acp-11-7781-2011, 2011.
Isono, K. and Ikebe, Y.: On the ice-nucleating ability of rock-forming
minerals and soil particles, J. Meteorol. Soc. Japn. Ser. II, 38, 213–230,
https://doi.org/10.2151/jmsj1923.38.5_213, 1960.
Johari, G. P., Fleissner, G., Hallbrucker, A., and Mayer, E.: Thermodynamic
continuity between glassy and normal water, J. Phys. Chem., 98, 4719–4725,
https://doi.org/10.1021/j100068a038, 1994.
Kandler, K., Schutz, L., Deutscher, C., Ebert, M., Hofmann, H., Jackel, S.,
Jaenicke, R., Knippertz, P., Lieke, K., and Massling, A.: Size distribution,
mass concentration, chemical and mineralogical composition and derived
optical parameters of the boundary layer aerosol at Tinfou, Morocco, during
SAMUM 2006, Tellus B, 61, 32–50, 2009.
Kanji, Z. A., Sullivan, R. C., Niemand, M., DeMott, P. J., Prenni, A. J.,
Chou, C., Saathoff, H., and Möhler, O.: Heterogeneous ice nucleation
properties of natural desert dust particles coated with a surrogate of
secondary organic aerosol, Atmos. Chem. Phys., 19, 5091–5110,
https://doi.org/10.5194/acp-19-5091-2019, 2019.
Kaufmann, L., Marcolli, C., Hofer, J., Pinti, V., Hoyle, C. R., and Peter,
T.: Ice nucleation efficiency of natural dust samples in the immersion mode,
Atmos. Chem. Phys., 16, 11177–11206,
https://doi.org/10.5194/acp-16-11177-2016, 2016.
Kaufmann, L., Marcolli, C., Luo, B., and Peter, T.: Refreeze experiments with
water droplets containing different types of ice nuclei interpreted by
classical nucleation theory, Atmos. Chem. Phys., 17, 3525–3552,
https://doi.org/10.5194/acp-17-3525-2017, 2017.
Kline, W. E. and Fogler, H. S.: Dissolution kinetics: Catalysis by strong
acids, J. Colloid Interface Sci., 82, 93–102,
https://doi.org/10.1016/0021-9797(81)90127-2, 1981.
Knauss, K. G., and Wolery, T. J.: The dissolution kinetics of quartz as a
function of pH and time at 70 ∘C, Geochim. Cosmochim. Ac., 52,
43–53, https://doi.org/10.1016/0016-7037(88)90055-5, 1988.
Knopf, D. A. and Forrester, S. M.: Freezing of water and aqueous NaCl
droplets coated by organic monolayers as a function of surfactant properties
and water activity, J. Phys. Chem. A, 115, 5579–5591, https://doi.org/10.1021/jp2014644,
2011.
Knopf, D. A. and Alpert, P. A.: A water activity based model of heterogeneous
ice nucleation kinetics for freezing of water and aqueous solution droplets,
Farad. Discussions, 165, 513–534, https://doi.org/10.1039/C3FD00035D, 2013.
Kolb, C. E., Cox, R. A., Abbatt, J. P. D., Ammann, M., Davis, E. J.,
Donaldson, D. J., Garrett, B. C., George, C., Griffiths, P. T., Hanson, D.
R., Kulmala, M., McFiggans, G., Pöschl, U., Riipinen, I., Rossi, M. J.,
Rudich, Y., Wagner, P. E., Winkler, P. M., Worsnop, D. R., and O' Dowd, C.
D.: An overview of current issues in the uptake of atmospheric trace gases by
aerosols and clouds, Atmos. Chem. Phys., 10, 10561–10605,
https://doi.org/10.5194/acp-10-10561-2010, 2010.
Koop, T., Luo, B., Tsias, A., and Peter, T.: Water activity as the
determinant for homogeneous ice nucleation in aqueous solutions, Nature, 406,
611–614, 2000.
Kulkarni, G., Fan, J., Comstock, J. M., Liu, X., and Ovchinnikov, M.:
Laboratory measurements and model sensitivity studies of dust deposition ice
nucleation, Atmos. Chem. Phys., 12, 7295–7308,
https://doi.org/10.5194/acp-12-7295-2012, 2012.
Kumar, A., Marcolli, C., Luo, B., and Peter, T.: Ice nucleation activity of
silicates and aluminosilicates in pure water and aqueous solutions – Part 1:
The K-feldspar microcline, Atmos. Chem. Phys., 18, 7057–7079,
https://doi.org/10.5194/acp-18-7057-2018, 2018a.
Kumar, A., Marcolli, C., and Peter, T.: Research Data supporting “Ice
nucleation activity of silicates and aluminosilicates in pure water and
aqueous solutions, Part 2 – Quartz and amorphous silica”,
https://doi.org/10.3929/ethz-b-000286931, last access: 1 November 2018b.
Kumar, A., Marcolli, C., and Peter, T.: Ice nucleation activity of silicates and aluminosilicates in pure water
and aqueous solutions – Part 3: Aluminosilicates, Atmos. Chem. Phys., 19, 6059–6084,
https://doi.org/10.5194/acp-19-6059-2019, 2019.
Laurent, B., Marticorena, B., Bergametti, G., and Mei, F.: Modeling mineral
dust emissions from chinese and mongolian deserts, Glob. Planet. Change, 52,
121–141, https://doi.org/10.1016/j.gloplacha.2006.02.012, 2006.
Laurent, B., Marticorena, B., Bergametti, G., Léon, J. F., and Mahowald,
N. M.: Modeling mineral dust emissions from the sahara desert using new
surface properties and soil database, J. Geophys. Res.-Atmos., 113, D14218,
https://doi.org/10.1029/2007JD009484, 2008.
Li, C.-Z. and Nelson, P. F.: Interactions of quartz, zircon sand and
stainless steel with ammonia: Implications for the measurement of ammonia at
high temperatures, Fuel, 75, 525–526, https://doi.org/10.1016/0016-2361(95)00256-1,
1996.
Makoto, H. and Motoji, I.: Effects of UV exposure on e' centers formed in
crushed quartz grains, Jpn. J. Appl. Phys., 35, 4463–4467,
https://doi.org/10.1143/JJAP.35.4463, 1996.
Mapes, J. E. and Eischens, R. P.: The infrared spectra of ammonia chemisorbed
on cracking catalysts, J. Phys. Chem., 58, 1059–1062,
https://doi.org/10.1021/j150522a002, 1954.
Marcolli, C., Gedamke, S., Peter, T., and Zobrist, B.: Efficiency of
immersion mode ice nucleation on surrogates of mineral dust, Atmos. Chem.
Phys., 7, 5081–5091, https://doi.org/10.5194/acp-7-5081-2007, 2007.
Marcolli, C., Nagare, B., Welti, A., and Lohmann, U.: Ice nucleation
efficiency of AgI: Review and new insights, Atmos. Chem. Phys., 16,
8915–8937, https://doi.org/10.5194/acp-16-8915-2016, 2016.
Matsuki, A., Iwasaka, Y., Shi, G. Y., Zhang, D. Z., Trochkine, D., Yamada,
M., Kim, Y. S., Chen, B., Nagatani, T., and Miyazawa, T.: Morphological and
chemical modification of mineral dust: Observational insight into the
heterogeneous uptake of acidic gases, Geophys. Res. Lett., 32, L22806,
https://doi.org/10.1029/2005GL024176, 2005.
Morrow, B. A. and Cody, I. A.: Infrared studies of reactions on oxide
surfaces, 5. Lewis acid sites on dehydroxylated silica, J. Phys. Chem., 80,
1995–1998, https://doi.org/10.1021/j100559a009, 1976.
Morrow, B. A., Cody, I. A., and Lee, L. S. M.: Infrared studies of reactions
on oxide surfaces, 7. Mechanism of the adsorption of water and ammonia on
dehydroxylated silica, J. Phys. Chem., 80, 2761–2767,
https://doi.org/10.1021/j100566a009, 1976.
Murray, B. J., Broadley, S. L., Wilson, T. W., Atkinson, J. D., and Wills, R.
H.: Heterogeneous freezing of water droplets containing kaolinite particles,
Atmos. Chem. Phys., 11, 4191–4207, https://doi.org/10.5194/acp-11-4191-2011,
2011.
Murray, B. J., O'Sullivan, D., Atkinson, J. D., and Webb, M. E.: Ice
nucleation by particles immersed in supercooled cloud droplets, Chem. Soc.
Rev., 41, 6519–6554, https://doi.org/10.1039/C2CS35200A, 2012.
Musso, F., Sodupe, M., Corno, M., and Ugliengo, P.: H-Bond features of fully
hydroxylated surfaces of crystalline silica polymorphs: A periodic B3LYP
study, J. Phys. Chem. C, 113, 17876–17884, https://doi.org/10.1021/jp905325m, 2009.
Musso, F., Ugliengo, P., and Sodupe, M.: Do H-Bond features of silica
surfaces affect the H2O and NH3 adsorption? Insights from
periodic B3LYP calculations, J. Phys. Chem. A, 115, 11221–11228,
https://doi.org/10.1021/jp203988j, 2011.
Musso, F., Mignon, P., Ugliengo, P., and Sodupe, M.: Cooperative effects at
water-crystalline silica interfaces strengthen surface silanol hydrogen
bonding. An ab initio molecular dynamics study, Phys. Chem. Chem. Phys., 14,
10507–10514, https://doi.org/10.1039/C2CP40756F, 2012.
Muster, T. H., Prestidge, C. A., and Hayes, R. A.: Water adsorption kinetics
and contact angles of silica particles, Colloids Surf. Physicochem. Eng.
Aspects, 176, 253–266, https://doi.org/10.1016/S0927-7757(00)00600-2, 2001.
Niedermeier, D., Hartmann, S., Clauss, T., Wex, H., Kiselev, A., Sullivan, R.
C., DeMott, P. J., Petters, M. D., Reitz, P., Schneider, J., Mikhailov, E.,
Sierau, B., Stetzer, O., Reimann, B., Bundke, U., Shaw, R. A., Buchholz, A.,
Mentel, T. F., and Stratmann, F.: Experimental study of the role of
physicochemical surface processing on the in ability of mineral dust
particles, Atmos. Chem. Phys., 11, 11131–11144,
https://doi.org/10.5194/acp-11-11131-2011, 2011.
O'Sullivan, D., Murray, B. J., Malkin, T. L., Whale, T. F., Umo, N. S.,
Atkinson, J. D., Price, H. C., Baustian, K. J., Browse, J., and Webb, M. E.:
Ice nucleation by fertile soil dusts: relative importance of mineral and
biogenic components, Atmos. Chem. Phys., 14, 1853–1867,
https://doi.org/10.5194/acp-14-1853-2014, 2014.
Peckhaus, A., Kiselev, A., Hiron, T., Ebert, M., and Leisner, T.: A
comparative study of K-rich and Na ∕ Ca-rich feldspar ice-nucleating
particles in a nanoliter droplet freezing assay, Atmos. Chem. Phys., 16,
11477–11496, https://doi.org/10.5194/acp-16-11477-2016, 2016.
Pedevilla, P., Fitzner, M., and Michaelides, A.: What makes a good
descriptor for heterogeneous ice nucleation on OH-patterned surfaces, Phys.
Rev. B, 96, 115441, https://doi.org/10.1103/PhysRevB.96.115441, 2017.
Peri, J. B.: Infrared study of OH and NH2 groups on the surface of a
dry silica aerogel, J. Phys. Chem., 70, 2937–2945,
https://doi.org/10.1021/j100881a037, 1966.
Peri, J. B. and Hannan, R. B.: Surface hydroxyl groups on γ-alumina1,
J. Phys. Chem., 64, 1526–1530, https://doi.org/10.1021/j100839a044, 1960.
Perry, C. C.: Chemical studies of biogenic silica, in: Biomineralisation,
chemical and biological perspectives, edited by: Mann, S., Webb, J., and
Williams, R. J. P., VCH, Weinheim, 233–256, 1989.
Perry, C. C.: Silicification: The processes by which organisms capture and
mineralize silica, Rev. Mineral. Geochem., 54, 291–327, https://doi.org/10.2113/0540291,
2003.
Pinti, V., Marcolli, C., Zobrist, B., Hoyle, C. R., and Peter, T.: Ice
nucleation efficiency of clay minerals in the immersion mode, Atmos. Chem.
Phys., 12, 5859–5878, https://doi.org/10.5194/acp-12-5859-2012, 2012.
Poulsen, H. F., Neuefeind, J., Neumann, H. B., Schneider, J. R., and Zeidler,
M. D.: Amorphous silica studied by high energy X-ray diffraction, J.
Non-Cryst. Solids, 188, 63–74, https://doi.org/10.1016/0022-3093(95)00095-X, 1995.
Prospero, J. M.: Long-range transport of mineral dust in the global
atmosphere: Impact of African dust on the environment of the Southeastern
United States, P. Natl. Acad. Sci. USA, 96, 3396,
https://doi.org/10.1073/pnas.96.7.3396, 1999.
Pruppacher, H. R. and Sänger, R.: Mechanismus der vereisung
unterkühlter wassertropfen durch disperse keimsubstanzen, Z. Angew. Math.
Phys., 6, 407–416, https://doi.org/10.1007/bf01589767, 1955.
Pruppacher, H. R. and Klett, J. D.: Microphysics of clouds and precipitation,
Kluwer Academic Publishers, Dordrecht, the Netherlands, 1994.
Reitz, P., Spindler, C., Mentel, T. F., Poulain, L., Wex, H., Mildenberger,
K., Niedermeier, D., Hartmann, S., Clauss, T., Stratmann, F., Sullivan, R.
C., DeMott, P. J., Petters, M. D., Sierau, B., and Schneider, J.: Surface
modification of mineral dust particles by sulphuric acid processing:
Implications for ice nucleation abilities, Atmos. Chem. Phys., 11,
7839–7858, https://doi.org/10.5194/acp-11-7839-2011, 2011.
Richmond, G. L.: Molecular bonding and interactions at aqueous surfaces as
probed by vibrational sum frequency spectroscopy, Chem. Rev., 102,
2693–2724, https://doi.org/10.1021/cr0006876, 2002.
Rigg, Y. J., Alpert, P. A., and Knopf, D. A.: Immersion freezing of water and
aqueous ammonium sulfate droplets initiated by humic-like substances as a
function of water activity, Atmos. Chem. Phys., 13, 6603–6622,
https://doi.org/10.5194/acp-13-6603-2013, 2013.
Salam, A., Lohmann, U., and Lesins, G.: Ice nucleation of ammonia gas exposed
montmorillonite mineral dust particles, Atmos. Chem. Phys., 7, 3923–3931,
https://doi.org/10.5194/acp-7-3923-2007, 2007.
Salam, A., Lesins, G., and Lohmann, U.: Laboratory study of heterogeneous ice
nucleation in deposition mode of montmorillonite mineral dust particles aged
with ammonia, sulfur dioxide, and ozone at polluted atmospheric
concentrations, Air Qual. Atmos. Health, 1, 135–142,
https://doi.org/10.1007/s11869-008-0019-6, 2008.
Schepanski, K., Tegen, I., and Macke, A.: Saharan dust transport and
deposition towards the tropical northern Atlantic, Atmos. Chem. Phys., 9,
1173–1189, https://doi.org/10.5194/acp-9-1173-2009, 2009.
Schwartzentruber, J., Fürst, W., and Renon, H.: Dissolution of quartz
into dilute alkaline solutions at 90 ∘C: A kinetic study, Geochim.
Cosmochim. Ac., 51, 1867–1874, https://doi.org/10.1016/0016-7037(87)90177-3, 1987.
Speedy, R. J.: Thermodynamic properties of supercooled water at 1 atm, J.
Phys. Chem., 91, 3354–3358, https://doi.org/10.1021/j100296a049, 1987.
Storelvmo, T., Hoose, C., and Eriksson, P.: Global modeling of mixed-phase
clouds: The albedo and lifetime effects of aerosols, J. Geophys. Res.-Atmos.,
116, D05207, https://doi.org/10.1029/2010JD014724, 2011.
Sullivan, R. C., Miñambres, L., DeMott, P. J., Prenni, A. J., Carrico, C.
M., Levin, E. J. T., and Kreidenweis, S. M.: Chemical processing does not
always impair heterogeneous ice nucleation of mineral dust particles,
Geophys. Res. Lett., 37, L24805, https://doi.org/10.1029/2010GL045540, 2010a.
Sullivan, R. C., Petters, M. D., DeMott, P. J., Kreidenweis, S. M., Wex, H.,
Niedermeier, D., Hartmann, S., Clauss, T., Stratmann, F., Reitz, P.,
Schneider, J., and Sierau, B.: Irreversible loss of ice nucleation active
sites in mineral dust particles caused by sulphuric acid condensation, Atmos.
Chem. Phys., 10, 11471–11487, https://doi.org/10.5194/acp-10-11471-2010,
2010b.
Tamahrajah, J. and Brehm, A.: Preliminary kinetic data of silicic acid
species prior to the formation of exoskeletal structures, Mar. Chem., 181,
18–24, https://doi.org/10.1016/j.marchem.2016.03.001, 2016.
Tobo, Y., DeMott, P. J., Hill, T. C. J., Prenni, A. J., Swoboda-Colberg, N.
G., Franc, G. D., and Kreidenweis, S. M.: Organic matter matters for ice
nuclei of agricultural soil origin, Atmos. Chem. Phys., 14, 8521–8531,
https://doi.org/10.5194/acp-14-8521-2014, 2014.
Tribello, G. A., Slater, B., Zwijnenburg, M. A., and Bell, R. G.: Isomorphism
between ice and silica, Phys. Chem. Chem. Phys., 12, 8597–8606,
https://doi.org/10.1039/B916367K, 2010.
Tsyganenko, A. A., Pozdnyakov, D. V., and Filimonov, V. N.: Infrared study of
surface species arising from ammonia adsorption on oxide surfaces, J. Mol.
Struct., 29, 299–318, https://doi.org/10.1016/0022-2860(75)85038-1, 1975.
Turci, F., Pavan, C., Leinardi, R., Tomatis, M., Pastero, L., Garry, D.,
Anguissola, S., Lison, D., and Fubini, B.: Revisiting the paradigm of silica
pathogenicity with synthetic quartz crystals: The role of crystallinity and
surface disorder, Part. Fibre Toxicol., 13, https://doi.org/10.1186/s12989-016-0136-6,
2016.
Uno, I., Eguchi, K., Yumimoto, K., Takemura, T., Shimizu, A., Uematsu, M.,
Liu, Z., Wang, Z., Hara, Y., and Sugimoto, N.: Asian dust transported one
full circuit around the globe, Nat. Geosci., 2, 557–560,
https://doi.org/10.1038/ngeo583, 2009.
Usher, C. R., Michel, A. E., and Grassian, V. H.: Reactions on mineral dust,
Chem. Rev., 103, 4883–4940, https://doi.org/10.1021/cr020657y, 2003.
Vali, G.: Interpretation of freezing nucleation experiments: Singular and
stochastic; sites and surfaces, Atmos. Chem. Phys., 14, 5271–5294,
https://doi.org/10.5194/acp-14-5271-2014, 2014.
Vali, G., DeMott, P. J., Möhler, O., and Whale, T. F.: Technical note: A
proposal for ice nucleation terminology, Atmos. Chem. Phys., 15,
10263–10270, https://doi.org/10.5194/acp-15-10263-2015, 2015.
Vidyadhar, A. and Hanumantha Rao, K.: Adsorption mechanism of mixed
cationic/anionic collectors in feldspar-quartz flotation system, J. Colloid
Interface Sci., 306, 195–204, https://doi.org/10.1016/j.jcis.2006.10.047, 2007.
Walther, J. V. and Helgeson, H. C.: Calculation of the thermodynamic
properties of aqueous silica and the solubility of quartz and its polymorphs
at high pressures and temperatures, Am. J. Sci., 277, 1315–1351,
https://doi.org/10.2475/ajs.277.10.1315, 1977.
Wei, X., Miranda, P. B., Zhang, C., and Shen, Y. R.: Sum-frequency
spectroscopic studies of ice interfaces, Phys. Rev. B, 66, 085401,
https://doi.org/10.1103/PhysRevB.66.085401, 2002.
Wex, H., DeMott, P. J., Tobo, Y., Hartmann, S., Rösch, M., Clauss, T.,
Tomsche, L., Niedermeier, D., and Stratmann, F.: Kaolinite particles as ice
nuclei: learning from the use of different kaolinite samples and different
coatings, Atmos. Chem. Phys., 14, 5529–5546,
https://doi.org/10.5194/acp-14-5529-2014, 2014.
Whale, T. F., Holden, M. A., Kulak, A. N., Kim, Y.-Y., Meldrum, F. C.,
Christenson, H. K., and Murray, B. J.: The role of phase separation and
related topography in the exceptional ice-nucleating ability of alkali
feldspars, Phys. Chem. Chem. Phys., 19, 31186–31193, https://doi.org/10.1039/C7CP04898J,
2017.
Whale, T. F., Holden, M. A., Wilson, T. W., O'Sullivan, D., and Murray, B.
J.: The enhancement and suppression of immersion mode heterogeneous
ice-nucleation by solutes, Chem. Sci., 9, 4142–4151,
https://doi.org/10.1039/C7SC05421A, 2018.
Wright, L. B. and Walsh, T. R.: First-principles molecular dynamics
simulations of
Xiao, Y. and Lasaga, A. C.: Ab initio quantum mechanical studies of the
kinetics and mechanisms of silicate dissolution:
Zhdanov, S. P., Kosheleva, L. S., and Titova, T. I.: IR study of hydroxylated
silica, Langmuir, 3, 960–967, https://doi.org/10.1021/la00078a014, 1987.
Zhuravlev, L. T.: The surface chemistry of amorphous silica. Zhuravlev model,
Colloids Surf. Physicochem. Eng. Aspects, 173, 1–38,
https://doi.org/10.1016/S0927-7757(00)00556-2, 2000.
Zimmermann, F., Weinbruch, S., Schutz, L., Hofmann, H., Ebert, M., Kandler,
K., and Worringen, A.: Ice nucleation properties of the most abundant mineral
dust phases, J. Geophys. Res., 113, D23204, https://doi.org/10.1029/2008JD010655, 2008.
Zobrist, B., Marcolli, C., Koop, T., Luo, B. P., Murphy, D. M., Lohmann, U.,
Zardini, A. A., Krieger, U. K., Corti, T., Cziczo, D. J., Fueglistaler, S.,
Hudson, P. K., Thomson, D. S., and Peter, T.: Oxalic acid as a heterogeneous
ice nucleus in the upper troposphere and its indirect aerosol effect, Atmos.
Chem. Phys., 6, 3115–3129, https://doi.org/10.5194/acp-6-3115-2006, 2006.
Zobrist, B., Marcolli, C., Peter, T., and Koop, T.: Heterogeneous ice
nucleation in aqueous solutions:? The role of water activity, J. Phys. Chem.
A, 112, 3965–3975, https://doi.org/10.1021/jp7112208, 2008.
Zolles, T., Burkart, J., Häusler, T., Pummer, B., Hitzenberger, R., and
Grothe, H.: Identification of ice nucleation active sites on feldspar dust
particles, J. Phys. Chem. A, 119, 2692–2700, https://doi.org/10.1021/jp509839x, 2015.
Zuberi, B., Bertram, A. K., Cassa, C. A., Molina, L. T., and Molina, M. J.:
Heterogeneous nucleation of ice in (NH4)2SO4−H2O particles
with mineral dust immersions, Geophys. Res. Lett., 29,
https://doi.org/10.1029/2001GL014289,
2002.
Zuend, A., Marcolli, C., Luo, B. P., and Peter, T.: A thermodynamic model of
mixed organic-inorganic aerosols to predict activity coefficients, Atmos.
Chem. Phys., 8, 4559–4593, https://doi.org/10.5194/acp-8-4559-2008, 2008.
Zuend, A., Marcolli, C., Booth, A. M., Lienhard, D. M., Soonsin, V., Krieger,
U. K., Topping, D. O., McFiggans, G., Peter, T., and Seinfeld, J. H.: New and
extended parameterization of the thermodynamic model AIOMFAC: Calculation of
activity coefficients for organic-inorganic mixtures containing carboxyl,
hydroxyl, carbonyl, ether, ester, alkenyl, alkyl, and aromatic functional
groups, Atmos. Chem. Phys., 11, 9155–9206,
https://doi.org/10.5194/acp-11-9155-2011, 2011.
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Short summary
This paper not only interests the atmospheric science community but has a potential to cater to a broader audience. We discuss both long- and
short-term effects of various
atmospherically relevantchemical species on a fairly abundant mineral surface
Quartz. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
This paper not only interests the atmospheric science community but has a potential to cater to...
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