Articles | Volume 18, issue 20
https://doi.org/10.5194/acp-18-15419-2018
https://doi.org/10.5194/acp-18-15419-2018
Research article
 | 
26 Oct 2018
Research article |  | 26 Oct 2018

A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates

Azimeh Zare, Paul S. Romer, Tran Nguyen, Frank N. Keutsch, Kate Skog, and Ronald C. Cohen

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Cited articles

Ackermann, I. J., Hass, H., Memmesheimer, M., Ebel, A., Binkowski, F. S., and Shankar, U.: Modal Aerosol Dynamics model for Europe: Development and first applications, Atmos. Environ., 32, 2981–2999, https://doi.org/10.1016/S1352-2310(98)00006-5, 1998. 
Arey, J., Aschmann, S. M., Kwok, E. S. C., and Atkinson, R.: Alkyl Nitrate, Hydroxyalkyl Nitrate, and Hydroxycarbonyl Formation from the NOx-Air Photooxidations of C5-C8 n-Alkanes, J. Phys. Chem. A, 105, 1020–1027, https://doi.org/10.1021/jp003292z, 2001. 
Aschmann, S. M., Atkinson, R., and Arey, J.: Products of reaction of OH radicals with α-pinene, J. Geophys. Res.-Atmos., 107, 4191, https://doi.org/10.1029/2001JD001098, 2002. 
Bates, K. H., Nguyen, T. B., Teng, A. P., Crounse, J. D., Kjaergaard, H. G., Stoltz, B. M., Seinfeld, J. H., and Wennberg, P. O.: Production and Fate of C4 Dihydroxycarbonyl Compounds from Isoprene Oxidation, J. Phys. Chem. A, 120, 106–117, https://doi.org/10.1021/acs.jpca.5b10335, 2016. 
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Short summary
Organic nitrates play an important role in concentrations and distribution of NOx, ozone and aerosol as the most important air pollutants. We develop a state-of-the-science detailed chemical mechanism representing individual organic nitrates, which is appropriate to use in air quality models and results in a more accurate simulation of atmospheric chemistry. Using this mechanism we explore production and removal processes of organic nitrates in a rural environment that are poorly constrained.
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