Articles | Volume 18, issue 20
https://doi.org/10.5194/acp-18-15419-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-15419-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
26 Oct 2018
Research article |
| 26 Oct 2018
| 26 Oct 2018
A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates
Azimeh Zare
Department of Chemistry, University of California Berkeley, Berkeley, CA,
USA
Paul S. Romer
Department of Chemistry, University of California Berkeley, Berkeley, CA,
USA
Tran Nguyen
College of Agricultural and Environmental Sciences, University of
California, Davis, CA, USA
Frank N. Keutsch
Department of Chemistry, University of Wisconsin-Madison, Madison, WI, USA
now at: School of Engineering and Applied Sciences and Department of
Chemistry & Chemical Biology, Harvard University, Cambridge, MA, USA
Kate Skog
Department of Chemistry, University of Wisconsin-Madison, Madison, WI, USA
now at: Department of Chemical & Environmental Engineering, Yale
University, New Haven, CT, USA
Department of Chemistry, University of California Berkeley, Berkeley, CA,
USA
Department of Earth and Planetary Sciences, University of California
Berkeley, Berkeley, CA, USA
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Cited
62 citations as recorded by crossref.
- The production and hydrolysis of organic nitrates from OH radical oxidation of <i>β</i>-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Evaluating the Impact of Chemical Complexity and Horizontal Resolution on Tropospheric Ozone Over the Conterminous US With a Global Variable Resolution Chemistry Model R. Schwantes et al. 10.1029/2021MS002889
- Metal-free catalysis on the reactions of nitric acid with aliphatic aldehydes: A new potential source of organic nitrates F. Bai et al. 10.1016/j.atmosenv.2023.119673
- Rapid hydrolysis of tertiary isoprene nitrate efficiently removes NO x from the atmosphere K. Vasquez et al. 10.1073/pnas.2017442117
- Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms A. Mayhew et al. 10.5194/acp-22-14783-2022
- Observation and modeling of organic nitrates on a suburban site in southwest China C. Li et al. 10.1016/j.scitotenv.2022.160287
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
- Evaluating the response of the Aerodyne aerosol mass spectrometer to monoterpene- and isoprene-derived organic nitrate standards M. Takeuchi et al. 10.1080/02786826.2024.2389183
- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.est.1c05310
- Leaf Stomatal Uptake of Alkyl Nitrates B. Place et al. 10.1021/acs.estlett.1c00793
- High atmospheric oxidation capacity drives wintertime nitrate pollution in the eastern Yangtze River Delta of China H. Zang et al. 10.5194/acp-22-4355-2022
- A systematic re-evaluation of methods for quantification of bulk particle-phase organic nitrates using real-time aerosol mass spectrometry D. Day et al. 10.5194/amt-15-459-2022
- Evaluation of version 3.0B of the BEHR OMI NO<sub>2</sub> product J. Laughner et al. 10.5194/amt-12-129-2019
- Photolysis of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.jpca.2c04307
- Formation processes of nitrogen-containing organic compounds from heterogeneous reactions of C3H6/NO2/O3 with α-Fe2O3 particles X. Xi et al. 10.1016/j.atmosenv.2022.119567
- Sensitivity of Tropospheric Ozone Over the Southeast USA to Dry Deposition C. Baublitz et al. 10.1029/2020GL087158
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- Reaction Mechanisms Underlying Unfunctionalized Alkyl Nitrate Hydrolysis in Aqueous Aerosols F. Keshavarz et al. 10.1021/acsearthspacechem.0c00253
- Enhanced formation of nitrogenous organic aerosols and brown carbon after aging in the planetary boundary layer Y. Wu et al. 10.1038/s41612-024-00726-x
- Contribution of Organic Nitrates to Organic Aerosol over South Korea during KORUS-AQ H. Kenagy et al. 10.1021/acs.est.1c05521
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
- Measurement of Henry's law constants of ethyl nitrate in deionized water, synthetic sea salt solutions, and n-octanol K. Easterbrook et al. 10.1016/j.chemosphere.2023.140482
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al. 10.5194/acp-21-14907-2021
- Length-Weight Relationship of Diamondback puffer Lagocephalus guentheri from the northeastern Mediterranean Sea S. Doğdu & C. Turan 10.35229/jaes.1477037
- Reactivity of a Carene-Derived Hydroxynitrate in Mixed Organic/Aqueous Matrices: Applying Synthetic Chemistry to Product Identification and Mechanistic Implications A. McAlister et al. 10.3390/atmos12121617
- Temperature-dependent emissions dominate aerosol and ozone formation in Los Angeles E. Pfannerstill et al. 10.1126/science.adg8204
- Lightning NO<sub>2</sub> simulation over the contiguous US and its effects on satellite NO<sub>2</sub> retrievals Q. Zhu et al. 10.5194/acp-19-13067-2019
- Particulate organic nitrates at Mount Tai in winter and spring: Variation characteristics and effects of mountain-valley breezes and elevated emission sources J. Chen et al. 10.1016/j.envres.2022.113182
- Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of <i>α</i>-pinene and <i>β</i>-pinene M. Takeuchi & N. Ng 10.5194/acp-19-12749-2019
- A better representation of volatile organic compound chemistry in WRF-Chem and its impact on ozone over Los Angeles Q. Zhu et al. 10.5194/acp-24-5265-2024
- Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO<sub>2</sub>, RO<sub>2</sub>NO<sub>2</sub>, and RONO<sub>2</sub> in the atmosphere C. Li et al. 10.5194/amt-14-4033-2021
- Urban and Remote cheMistry modELLing with the new chemical mechanism URMELL: part I gas-phase mechanism development M. Luttkus et al. 10.1039/D3EA00094J
- Assessment of PM2.5-bound nitrogen-containing organic compounds (NOCs) during winter at urban sites in China and Korea K. Jang et al. 10.1016/j.envpol.2020.114870
- Temperature-Dependent Composition of Summertime PM2.5 in Observations and Model Predictions across the Eastern U.S. P. Vannucci et al. 10.1021/acsearthspacechem.3c00333
- Reaction of Organic Matter with Nitronium Ion as a Source of Organic Nitrate Esters in Proxies for Organic Aerosols R. Hansen et al. 10.1021/acsearthspacechem.3c00111
- Combining Machine Learning and Satellite Observations to Predict Spatial and Temporal Variation of near Surface OH in North American Cities Q. Zhu et al. 10.1021/acs.est.1c05636
- Sensitivity of northeastern US surface ozone predictions to the representation of atmospheric chemistry in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMMv1.0) B. Place et al. 10.5194/acp-23-9173-2023
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
- Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area B. Nault et al. 10.5194/acp-24-9573-2024
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- A thermal-dissociation–cavity ring-down spectrometer (TD-CRDS) for the detection of organic nitrates in gas and particle phases N. Keehan et al. 10.5194/amt-13-6255-2020
- Incorporating Oxygen Isotopes of Oxidized Reactive Nitrogen in the Regional Atmospheric Chemistry Mechanism, version 2 (ICOIN-RACM2) W. Walters et al. 10.5194/gmd-17-4673-2024
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- Size Distribution and Secondary Formation of Particulate Organic Nitrates in Winter in a Coastal Area A. Shakoor et al. 10.3390/su152416776
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates Q. Zhao et al. 10.1038/s41612-023-00517-w
- Condensed Phase Kinetic Studies of Hydroxynitrates Derived from the Photooxidation of Carene, Limonene, trans-Carveol, and Perillic Alcohol J. Vesto et al. 10.3390/atmos13040592
- Development of a Solar-Induced Fluorescence─Canopy Conductance Model and Its Application to Stomatal Reactive Nitrogen Deposition E. Delaria et al. 10.1021/acsearthspacechem.1c00260
- Vertical Variations in Biogenic Organic Nitrates at Two Temperate Forest Sites D. Wei et al. 10.1021/acsestair.4c00123
- Volatile organic compound fluxes in the agricultural San Joaquin Valley – spatial distribution, source attribution, and inventory comparison E. Pfannerstill et al. 10.5194/acp-23-12753-2023
- Condition factor and meat yield of invasive zebra mussels (Dreissena polymorpha) in Lake Çıldır, Karakaya, and Keban Reservoirs in Turkey Ş. Atasaral & E. Çiloğlu 10.35229/jaes.1482693
- A large contribution of anthropogenic organo-nitrates to secondary organic aerosol in the Alberta oil sands A. Lee et al. 10.5194/acp-19-12209-2019
- Characterization of particulate organic nitrates in the Yangtze River Delta, East China, using the time-of-flight aerosol chemical speciation monitor D. Ge et al. 10.1016/j.atmosenv.2021.118927
- Modeling Volatility-Based Aerosol Phase State Predictions in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.1c00255
- Gas-Phase Photolysis and Photo-Oxidation of Isoprene-Derived Atmospherically Relevant Hydroxy Nitrates R. Verma et al. 10.1021/acsestair.4c00010
- Significant impacts of anthropogenic activities on monoterpene and oleic acid-derived particulate organic nitrates in the North China Plain J. Zhang et al. 10.1016/j.atmosres.2021.105585
- Modeling Secondary Organic Aerosols in China: State of the Art and Perspectives J. Li et al. 10.1007/s40726-022-00246-3
- Field Measurement of Alkyl Nitrates in the Atmosphere C. Li et al. 10.6023/A23100460
- The Berkeley High Resolution Tropospheric NO<sub>2</sub> product J. Laughner et al. 10.5194/essd-10-2069-2018
- Chemical characterization of sub-micron aerosols over the East Sea (Sea of Japan) A. Loh et al. 10.1016/j.scitotenv.2022.159173
62 citations as recorded by crossref.
- The production and hydrolysis of organic nitrates from OH radical oxidation of <i>β</i>-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Evaluating the Impact of Chemical Complexity and Horizontal Resolution on Tropospheric Ozone Over the Conterminous US With a Global Variable Resolution Chemistry Model R. Schwantes et al. 10.1029/2021MS002889
- Metal-free catalysis on the reactions of nitric acid with aliphatic aldehydes: A new potential source of organic nitrates F. Bai et al. 10.1016/j.atmosenv.2023.119673
- Rapid hydrolysis of tertiary isoprene nitrate efficiently removes NO x from the atmosphere K. Vasquez et al. 10.1073/pnas.2017442117
- Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms A. Mayhew et al. 10.5194/acp-22-14783-2022
- Observation and modeling of organic nitrates on a suburban site in southwest China C. Li et al. 10.1016/j.scitotenv.2022.160287
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
- Evaluating the response of the Aerodyne aerosol mass spectrometer to monoterpene- and isoprene-derived organic nitrate standards M. Takeuchi et al. 10.1080/02786826.2024.2389183
- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.est.1c05310
- Leaf Stomatal Uptake of Alkyl Nitrates B. Place et al. 10.1021/acs.estlett.1c00793
- High atmospheric oxidation capacity drives wintertime nitrate pollution in the eastern Yangtze River Delta of China H. Zang et al. 10.5194/acp-22-4355-2022
- A systematic re-evaluation of methods for quantification of bulk particle-phase organic nitrates using real-time aerosol mass spectrometry D. Day et al. 10.5194/amt-15-459-2022
- Evaluation of version 3.0B of the BEHR OMI NO<sub>2</sub> product J. Laughner et al. 10.5194/amt-12-129-2019
- Photolysis of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.jpca.2c04307
- Formation processes of nitrogen-containing organic compounds from heterogeneous reactions of C3H6/NO2/O3 with α-Fe2O3 particles X. Xi et al. 10.1016/j.atmosenv.2022.119567
- Sensitivity of Tropospheric Ozone Over the Southeast USA to Dry Deposition C. Baublitz et al. 10.1029/2020GL087158
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- Reaction Mechanisms Underlying Unfunctionalized Alkyl Nitrate Hydrolysis in Aqueous Aerosols F. Keshavarz et al. 10.1021/acsearthspacechem.0c00253
- Enhanced formation of nitrogenous organic aerosols and brown carbon after aging in the planetary boundary layer Y. Wu et al. 10.1038/s41612-024-00726-x
- Contribution of Organic Nitrates to Organic Aerosol over South Korea during KORUS-AQ H. Kenagy et al. 10.1021/acs.est.1c05521
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
- Measurement of Henry's law constants of ethyl nitrate in deionized water, synthetic sea salt solutions, and n-octanol K. Easterbrook et al. 10.1016/j.chemosphere.2023.140482
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al. 10.5194/acp-21-14907-2021
- Length-Weight Relationship of Diamondback puffer Lagocephalus guentheri from the northeastern Mediterranean Sea S. Doğdu & C. Turan 10.35229/jaes.1477037
- Reactivity of a Carene-Derived Hydroxynitrate in Mixed Organic/Aqueous Matrices: Applying Synthetic Chemistry to Product Identification and Mechanistic Implications A. McAlister et al. 10.3390/atmos12121617
- Temperature-dependent emissions dominate aerosol and ozone formation in Los Angeles E. Pfannerstill et al. 10.1126/science.adg8204
- Lightning NO<sub>2</sub> simulation over the contiguous US and its effects on satellite NO<sub>2</sub> retrievals Q. Zhu et al. 10.5194/acp-19-13067-2019
- Particulate organic nitrates at Mount Tai in winter and spring: Variation characteristics and effects of mountain-valley breezes and elevated emission sources J. Chen et al. 10.1016/j.envres.2022.113182
- Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of <i>α</i>-pinene and <i>β</i>-pinene M. Takeuchi & N. Ng 10.5194/acp-19-12749-2019
- A better representation of volatile organic compound chemistry in WRF-Chem and its impact on ozone over Los Angeles Q. Zhu et al. 10.5194/acp-24-5265-2024
- Thermal dissociation cavity-enhanced absorption spectrometer for measuring NO<sub>2</sub>, RO<sub>2</sub>NO<sub>2</sub>, and RONO<sub>2</sub> in the atmosphere C. Li et al. 10.5194/amt-14-4033-2021
- Urban and Remote cheMistry modELLing with the new chemical mechanism URMELL: part I gas-phase mechanism development M. Luttkus et al. 10.1039/D3EA00094J
- Assessment of PM2.5-bound nitrogen-containing organic compounds (NOCs) during winter at urban sites in China and Korea K. Jang et al. 10.1016/j.envpol.2020.114870
- Temperature-Dependent Composition of Summertime PM2.5 in Observations and Model Predictions across the Eastern U.S. P. Vannucci et al. 10.1021/acsearthspacechem.3c00333
- Reaction of Organic Matter with Nitronium Ion as a Source of Organic Nitrate Esters in Proxies for Organic Aerosols R. Hansen et al. 10.1021/acsearthspacechem.3c00111
- Combining Machine Learning and Satellite Observations to Predict Spatial and Temporal Variation of near Surface OH in North American Cities Q. Zhu et al. 10.1021/acs.est.1c05636
- Sensitivity of northeastern US surface ozone predictions to the representation of atmospheric chemistry in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMMv1.0) B. Place et al. 10.5194/acp-23-9173-2023
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
- Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area B. Nault et al. 10.5194/acp-24-9573-2024
- The changing role of organic nitrates in the removal and transport of NO<sub><i>x</i></sub> P. Romer Present et al. 10.5194/acp-20-267-2020
- A thermal-dissociation–cavity ring-down spectrometer (TD-CRDS) for the detection of organic nitrates in gas and particle phases N. Keehan et al. 10.5194/amt-13-6255-2020
- Incorporating Oxygen Isotopes of Oxidized Reactive Nitrogen in the Regional Atmospheric Chemistry Mechanism, version 2 (ICOIN-RACM2) W. Walters et al. 10.5194/gmd-17-4673-2024
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- Size Distribution and Secondary Formation of Particulate Organic Nitrates in Winter in a Coastal Area A. Shakoor et al. 10.3390/su152416776
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates Q. Zhao et al. 10.1038/s41612-023-00517-w
- Condensed Phase Kinetic Studies of Hydroxynitrates Derived from the Photooxidation of Carene, Limonene, trans-Carveol, and Perillic Alcohol J. Vesto et al. 10.3390/atmos13040592
- Development of a Solar-Induced Fluorescence─Canopy Conductance Model and Its Application to Stomatal Reactive Nitrogen Deposition E. Delaria et al. 10.1021/acsearthspacechem.1c00260
- Vertical Variations in Biogenic Organic Nitrates at Two Temperate Forest Sites D. Wei et al. 10.1021/acsestair.4c00123
- Volatile organic compound fluxes in the agricultural San Joaquin Valley – spatial distribution, source attribution, and inventory comparison E. Pfannerstill et al. 10.5194/acp-23-12753-2023
- Condition factor and meat yield of invasive zebra mussels (Dreissena polymorpha) in Lake Çıldır, Karakaya, and Keban Reservoirs in Turkey Ş. Atasaral & E. Çiloğlu 10.35229/jaes.1482693
- A large contribution of anthropogenic organo-nitrates to secondary organic aerosol in the Alberta oil sands A. Lee et al. 10.5194/acp-19-12209-2019
- Characterization of particulate organic nitrates in the Yangtze River Delta, East China, using the time-of-flight aerosol chemical speciation monitor D. Ge et al. 10.1016/j.atmosenv.2021.118927
- Modeling Volatility-Based Aerosol Phase State Predictions in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.1c00255
- Gas-Phase Photolysis and Photo-Oxidation of Isoprene-Derived Atmospherically Relevant Hydroxy Nitrates R. Verma et al. 10.1021/acsestair.4c00010
- Significant impacts of anthropogenic activities on monoterpene and oleic acid-derived particulate organic nitrates in the North China Plain J. Zhang et al. 10.1016/j.atmosres.2021.105585
- Modeling Secondary Organic Aerosols in China: State of the Art and Perspectives J. Li et al. 10.1007/s40726-022-00246-3
- Field Measurement of Alkyl Nitrates in the Atmosphere C. Li et al. 10.6023/A23100460
- The Berkeley High Resolution Tropospheric NO<sub>2</sub> product J. Laughner et al. 10.5194/essd-10-2069-2018
- Chemical characterization of sub-micron aerosols over the East Sea (Sea of Japan) A. Loh et al. 10.1016/j.scitotenv.2022.159173
Latest update: 30 Dec 2024
Short summary
Organic nitrates play an important role in concentrations and distribution of NOx, ozone and aerosol as the most important air pollutants. We develop a state-of-the-science detailed chemical mechanism representing individual organic nitrates, which is appropriate to use in air quality models and results in a more accurate simulation of atmospheric chemistry. Using this mechanism we explore production and removal processes of organic nitrates in a rural environment that are poorly constrained.
Organic nitrates play an important role in concentrations and distribution of NOx, ozone and...
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