Articles | Volume 16, issue 18
Atmos. Chem. Phys., 16, 12205–12217, 2016
https://doi.org/10.5194/acp-16-12205-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue: Biogeochemical processes, tropospheric chemistry and interactions...
Atmos. Chem. Phys., 16, 12205–12217, 2016
https://doi.org/10.5194/acp-16-12205-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
29 Sep 2016
Research article
| 29 Sep 2016
Meteorological constraints on oceanic halocarbons above the Peruvian upwelling
Steffen Fuhlbrügge et al.
Related authors
Alina Fiehn, Birgit Quack, Helmke Hepach, Steffen Fuhlbrügge, Susann Tegtmeier, Matthew Toohey, Elliot Atlas, and Kirstin Krüger
Atmos. Chem. Phys., 17, 6723–6741, https://doi.org/10.5194/acp-17-6723-2017, https://doi.org/10.5194/acp-17-6723-2017, 2017
Short summary
Short summary
Halogenated very short-lived substances (VSLSs) are naturally produced in the ocean and emitted to the atmosphere. In the stratosphere, these compounds can have a significant influence on the ozone layer and climate. During a research cruise in the west Indian Ocean, we found an important source region of halogenated VSLSs during the Asian summer monsoon. Modeling the transport from the ocean to the stratosphere we found two main pathways, one over the Indian Ocean and one over northern India.
Helmke Hepach, Birgit Quack, Susann Tegtmeier, Anja Engel, Astrid Bracher, Steffen Fuhlbrügge, Luisa Galgani, Elliot L. Atlas, Johannes Lampel, Udo Frieß, and Kirstin Krüger
Atmos. Chem. Phys., 16, 12219–12237, https://doi.org/10.5194/acp-16-12219-2016, https://doi.org/10.5194/acp-16-12219-2016, 2016
Short summary
Short summary
We present surface seawater measurements of bromo- and iodocarbons, which are involved in numerous atmospheric processes such as tropospheric and stratospheric ozone chemistry, from the highly productive Peruvian upwelling. By combining trace gas measurements, characterization of organic matter and phytoplankton species, and tropospheric modelling, we show that large amounts of iodocarbons produced from the pool of organic matter may contribute strongly to local tropospheric iodine loading.
R. Hossaini, P. K. Patra, A. A. Leeson, G. Krysztofiak, N. L. Abraham, S. J. Andrews, A. T. Archibald, J. Aschmann, E. L. Atlas, D. A. Belikov, H. Bönisch, L. J. Carpenter, S. Dhomse, M. Dorf, A. Engel, W. Feng, S. Fuhlbrügge, P. T. Griffiths, N. R. P. Harris, R. Hommel, T. Keber, K. Krüger, S. T. Lennartz, S. Maksyutov, H. Mantle, G. P. Mills, B. Miller, S. A. Montzka, F. Moore, M. A. Navarro, D. E. Oram, K. Pfeilsticker, J. A. Pyle, B. Quack, A. D. Robinson, E. Saikawa, A. Saiz-Lopez, S. Sala, B.-M. Sinnhuber, S. Taguchi, S. Tegtmeier, R. T. Lidster, C. Wilson, and F. Ziska
Atmos. Chem. Phys., 16, 9163–9187, https://doi.org/10.5194/acp-16-9163-2016, https://doi.org/10.5194/acp-16-9163-2016, 2016
Steffen Fuhlbrügge, Birgit Quack, Susann Tegtmeier, Elliot Atlas, Helmke Hepach, Qiang Shi, Stefan Raimund, and Kirstin Krüger
Atmos. Chem. Phys., 16, 7569–7585, https://doi.org/10.5194/acp-16-7569-2016, https://doi.org/10.5194/acp-16-7569-2016, 2016
Short summary
Short summary
This study presents a novel estimate for the contribution of oceanic VSLS emissions to the atmospheric boundary layer and free troposphere during the SHIVA-Sonne cruise in the South China and Sulu seas in 2011. While oceanic emissions of CHBr3 and CH3I showed a significant contribution to their atmospheric abundances, atmospheric CH2Br2 appeared to be largely advected. Convective activity in the region can furthermore lead to low VSLS boundary layer mixing ratios despite high oceanic emissions.
H. Hepach, B. Quack, F. Ziska, S. Fuhlbrügge, E. L. Atlas, K. Krüger, I. Peeken, and D. W. R. Wallace
Atmos. Chem. Phys., 14, 1255–1275, https://doi.org/10.5194/acp-14-1255-2014, https://doi.org/10.5194/acp-14-1255-2014, 2014
S. Fuhlbrügge, K. Krüger, B. Quack, E. Atlas, H. Hepach, and F. Ziska
Atmos. Chem. Phys., 13, 6345–6357, https://doi.org/10.5194/acp-13-6345-2013, https://doi.org/10.5194/acp-13-6345-2013, 2013
Markus Jesswein, Rafael P. Fernandez, Lucas Berná, Alfonso Saiz-Lopez, Jens-Uwe Grooß, Ryan Hossaini, Eric C. Apel, Rebecca S. Hornbrook, Elliot L. Atlas, Donald R. Blake, Stephen Montzka, Timo Keber, Tanja Schuck, Thomas Wagenhäuser, and Andreas Engel
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-472, https://doi.org/10.5194/acp-2022-472, 2022
Preprint under review for ACP
Short summary
Short summary
This study presents the global and seasonal distribution of the two major brominated short-lived substances CH2Br2 and CHBr3 in the upper troposphere and lower stratosphere based on observations from several aircraft campaigns. They show similar seasonality for both hemispheres, except in the respective hemispheric autumn lower stratosphere. A comparison with the TOMCAT and CAM-Chem models shows good agreement in the annual mean, but larger differences in the seasonal consideration.
Yue Jia, Birgit Quack, Robert D. Kinley, Ignacio Pisso, and Susann Tegtmeier
Atmos. Chem. Phys., 22, 7631–7646, https://doi.org/10.5194/acp-22-7631-2022, https://doi.org/10.5194/acp-22-7631-2022, 2022
Short summary
Short summary
In this study, we assessed the potential risks of bromoform released from Asparagopsis farming near Australia for the stratospheric ozone layer by analyzing different cultivation scenarios. We conclude that the intended operation of Asparagopsis seaweed cultivation farms with an annual yield to meet the needs of 50 % of feedlots and cattle in either open-ocean or terrestrial cultures in Australia will not impact the ozone layer under normal operating conditions.
Susann Tegtmeier, Christa Marandino, Yue Jia, Birgit Quack, and Anoop S. Mahajan
Atmos. Chem. Phys., 22, 6625–6676, https://doi.org/10.5194/acp-22-6625-2022, https://doi.org/10.5194/acp-22-6625-2022, 2022
Short summary
Short summary
In the atmosphere over the Indian Ocean, intense anthropogenic pollution from Southeast Asia mixes with pristine oceanic air. During the winter monsoon, high pollution levels are regularly observed over the entire northern Indian Ocean, while during the summer monsoon, clean air dominates. Here, we review current progress in detecting and understanding atmospheric gas-phase composition over the Indian Ocean and its impacts on the upper atmosphere, oceanic biogeochemistry, and marine ecosystems.
Eric A. Ray, Elliot L. Atlas, Sue Schauffler, Sofia Chelpon, Laura Pan, Harald Bönisch, and Karen H. Rosenlof
Atmos. Chem. Phys., 22, 6539–6558, https://doi.org/10.5194/acp-22-6539-2022, https://doi.org/10.5194/acp-22-6539-2022, 2022
Short summary
Short summary
The movement of air masses and the trace gases they contain from the Earth’s surface into the upper troposphere and lower stratosphere (UTLS) can have important implications for the radiative and chemical balance of the atmosphere. In this study we build on recent techniques and use new ones to estimate a range of transport diagnostics based on simultaneously measured trace gases in the UTLS during the monsoon season in North America.
Amy Foulds, Grant Allen, Jacob T. Shaw, Prudence Bateson, Patrick A. Barker, Langwen Huang, Joseph R. Pitt, James D. Lee, Shona E. Wilde, Pamela Dominutti, Ruth M. Purvis, David Lowry, James L. France, Rebecca E. Fisher, Alina Fiehn, Magdalena Pühl, Stéphane J. B. Bauguitte, Stephen A. Conley, Mackenzie L. Smith, Tom Lachlan-Cope, Ignacio Pisso, and Stefan Schwietzke
Atmos. Chem. Phys., 22, 4303–4322, https://doi.org/10.5194/acp-22-4303-2022, https://doi.org/10.5194/acp-22-4303-2022, 2022
Short summary
Short summary
We measured CH4 emissions from 21 offshore oil and gas facilities in the Norwegian Sea in 2019. Measurements compared well with operator-reported emissions but were greatly underestimated when compared with a 2016 global fossil fuel inventory. This study demonstrates the need for up-to-date and accurate inventories for use in research and policy and the important benefits of best-practice reporting methods by operators. Airborne measurements are an effective tool to validate such inventories.
Yanan Zhao, Dennis Booge, Christa A. Marandino, Cathleen Schlundt, Astrid Bracher, Elliot L. Atlas, Jonathan Williams, and Hermann W. Bange
Biogeosciences, 19, 701–714, https://doi.org/10.5194/bg-19-701-2022, https://doi.org/10.5194/bg-19-701-2022, 2022
Short summary
Short summary
We present here, for the first time, simultaneously measured dimethylsulfide (DMS) seawater concentrations and DMS atmospheric mole fractions from the Peruvian upwelling region during two cruises in December 2012 and October 2015. Our results indicate low oceanic DMS concentrations and atmospheric DMS molar fractions in surface waters and the atmosphere, respectively. In addition, the Peruvian upwelling region was identified as an insignificant source of DMS emissions during both periods.
Sven Krautwurst, Konstantin Gerilowski, Jakob Borchardt, Norman Wildmann, Michał Gałkowski, Justyna Swolkień, Julia Marshall, Alina Fiehn, Anke Roiger, Thomas Ruhtz, Christoph Gerbig, Jaroslaw Necki, John P. Burrows, Andreas Fix, and Heinrich Bovensmann
Atmos. Chem. Phys., 21, 17345–17371, https://doi.org/10.5194/acp-21-17345-2021, https://doi.org/10.5194/acp-21-17345-2021, 2021
Short summary
Short summary
Quantification of anthropogenic CH4 emissions remains challenging, but it is essential for near-term climate mitigation strategies. We use airborne remote sensing observations to assess bottom-up estimates of coal mining emissions from one of Europe's largest CH4 emission hot spots located in Poland. The analysis reveals that emissions from small groups of shafts can be disentangled, but caution is advised when comparing observations to commonly reported annual emissions.
Paul D. Hamer, Virginie Marécal, Ryan Hossaini, Michel Pirre, Gisèle Krysztofiak, Franziska Ziska, Andreas Engel, Stephan Sala, Timo Keber, Harald Bönisch, Elliot Atlas, Kirstin Krüger, Martyn Chipperfield, Valery Catoire, Azizan A. Samah, Marcel Dorf, Phang Siew Moi, Hans Schlager, and Klaus Pfeilsticker
Atmos. Chem. Phys., 21, 16955–16984, https://doi.org/10.5194/acp-21-16955-2021, https://doi.org/10.5194/acp-21-16955-2021, 2021
Short summary
Short summary
Bromoform is a stratospheric ozone-depleting gas released by seaweed and plankton transported to the stratosphere via convection in the tropics. We study the chemical interactions of bromoform and its derivatives within convective clouds using a cloud-scale model and observations. Our findings are that soluble bromine gases are efficiently washed out and removed within the convective clouds and that most bromine is transported vertically to the upper troposphere in the form of bromoform.
Julian Kostinek, Anke Roiger, Maximilian Eckl, Alina Fiehn, Andreas Luther, Norman Wildmann, Theresa Klausner, Andreas Fix, Christoph Knote, Andreas Stohl, and André Butz
Atmos. Chem. Phys., 21, 8791–8807, https://doi.org/10.5194/acp-21-8791-2021, https://doi.org/10.5194/acp-21-8791-2021, 2021
Short summary
Short summary
Abundant mining and industrial activities in the Upper Silesian Coal Basin lead to large emissions of the potent greenhouse gas methane. This study quantifies these emissions with continuous, high-precision airborne measurements and dispersion modeling. Our emission estimates are in line with values reported in the European Pollutant Release and Transfer Register (E-PRTR 2017) but significantly lower than values reported in the Emissions Database for Global Atmospheric Research (EDGAR v4.3.2).
Josefine Maas, Susann Tegtmeier, Yue Jia, Birgit Quack, Jonathan V. Durgadoo, and Arne Biastoch
Atmos. Chem. Phys., 21, 4103–4121, https://doi.org/10.5194/acp-21-4103-2021, https://doi.org/10.5194/acp-21-4103-2021, 2021
Short summary
Short summary
Cooling-water disinfection at coastal power plants is a known source of atmospheric bromoform. A large source of anthropogenic bromoform is the industrial regions in East Asia. In current bottom-up flux estimates, these anthropogenic emissions are missing, underestimating the global air–sea flux of bromoform. With transport simulations, we show that by including anthropogenic bromoform from cooling-water treatment, the bottom-up flux estimates significantly improve in East and Southeast Asia.
Jin Ma, Linda M. J. Kooijmans, Ara Cho, Stephen A. Montzka, Norbert Glatthor, John R. Worden, Le Kuai, Elliot L. Atlas, and Maarten C. Krol
Atmos. Chem. Phys., 21, 3507–3529, https://doi.org/10.5194/acp-21-3507-2021, https://doi.org/10.5194/acp-21-3507-2021, 2021
Short summary
Short summary
Carbonyl sulfide is an important trace gas in the atmosphere and useful to estimating gross primary productivity in ecosystems, but its sources and sinks remain highly uncertain. Therefore, we applied inverse model system TM5-4DVAR to better constrain the global budget. Our finding is in line with earlier studies, pointing to missing sources in the tropics and more uptake in high latitudes. We also stress the necessity of more ground-based observations and satellite data assimilation in future.
Alina Fiehn, Julian Kostinek, Maximilian Eckl, Theresa Klausner, Michał Gałkowski, Jinxuan Chen, Christoph Gerbig, Thomas Röckmann, Hossein Maazallahi, Martina Schmidt, Piotr Korbeń, Jarosław Neçki, Pawel Jagoda, Norman Wildmann, Christian Mallaun, Rostyslav Bun, Anna-Leah Nickl, Patrick Jöckel, Andreas Fix, and Anke Roiger
Atmos. Chem. Phys., 20, 12675–12695, https://doi.org/10.5194/acp-20-12675-2020, https://doi.org/10.5194/acp-20-12675-2020, 2020
Short summary
Short summary
A severe reduction of greenhouse gas emissions is necessary to fulfill the Paris Agreement. We use aircraft- and ground-based in situ observations of trace gases and wind speed from two flights over the Upper Silesian Coal Basin, Poland, for independent emission estimation. The derived methane emission estimates are within the range of emission inventories, carbon dioxide estimates are in the lower range and carbon monoxide emission estimates are slightly higher than emission inventory values.
Hirofumi Ohyama, Isamu Morino, Voltaire A. Velazco, Theresa Klausner, Gerry Bagtasa, Matthäus Kiel, Matthias Frey, Akihiro Hori, Osamu Uchino, Tsuneo Matsunaga, Nicholas M. Deutscher, Joshua P. DiGangi, Yonghoon Choi, Glenn S. Diskin, Sally E. Pusede, Alina Fiehn, Anke Roiger, Michael Lichtenstern, Hans Schlager, Pao K. Wang, Charles C.-K. Chou, Maria Dolores Andrés-Hernández, and John P. Burrows
Atmos. Meas. Tech., 13, 5149–5163, https://doi.org/10.5194/amt-13-5149-2020, https://doi.org/10.5194/amt-13-5149-2020, 2020
Short summary
Short summary
Column-averaged dry-air mole fractions of CO2 and CH4 measured by a solar viewing portable Fourier transform spectrometer (EM27/SUN) were validated with in situ profile data obtained during the transfer flights of two aircraft campaigns. Atmospheric dynamical properties based on ERA5 and WRF-Chem were used as criteria for selecting the best aircraft profiles for the validation. The resulting air-mass-independent correction factors for the EM27/SUN data were 0.9878 for CO2 and 0.9829 for CH4.
Susann Tegtmeier, Elliot Atlas, Birgit Quack, Franziska Ziska, and Kirstin Krüger
Atmos. Chem. Phys., 20, 7103–7123, https://doi.org/10.5194/acp-20-7103-2020, https://doi.org/10.5194/acp-20-7103-2020, 2020
Short summary
Short summary
We investigate emissions of brominated gases from the ocean and their contribution to stratospheric ozone depletion. Once in the atmosphere, these gases usually break down in less than 6 months. Their impact on the ozone layer depends on the prevailing atmospheric circulation, since transport to the stratosphere requires uplift. We combine aircraft and ship observations with atmospheric modelling to analyse how, where, and when these gases are transported from the ocean into the stratosphere.
Helmke Hepach, Claire Hughes, Karen Hogg, Susannah Collings, and Rosie Chance
Biogeosciences, 17, 2453–2471, https://doi.org/10.5194/bg-17-2453-2020, https://doi.org/10.5194/bg-17-2453-2020, 2020
Short summary
Short summary
Tropospheric iodine takes part in numerous atmospheric chemical cycles, including tropospheric ozone destruction and aerosol formation. Due to its significance for atmospheric processes, it is crucial to constrain its sources and sinks. This paper aims at investigating and understanding features of biogenic iodate-to-iodide reduction in microalgal monocultures. We find that phytoplankton senescence may play a crucial role in the release of iodide to the marine environment.
Anna-Leah Nickl, Mariano Mertens, Anke Roiger, Andreas Fix, Axel Amediek, Alina Fiehn, Christoph Gerbig, Michal Galkowski, Astrid Kerkweg, Theresa Klausner, Maximilian Eckl, and Patrick Jöckel
Geosci. Model Dev., 13, 1925–1943, https://doi.org/10.5194/gmd-13-1925-2020, https://doi.org/10.5194/gmd-13-1925-2020, 2020
Short summary
Short summary
Based on the global and regional chemistry–climate model system MECO(n), we implemented a forecast system to support the planning of measurement campaign research flights with chemical weather forecasts. We applied this system for the first time to provide 6 d forecasts in support of the CoMet 1.0
campaign targeting methane emitted from coal mining ventilation shafts in the Upper Silesian Coal Basin in Poland. We describe the new forecast system and evaluate its forecast skill.
Sinikka T. Lennartz, Christa A. Marandino, Marc von Hobe, Meinrat O. Andreae, Kazushi Aranami, Elliot Atlas, Max Berkelhammer, Heinz Bingemer, Dennis Booge, Gregory Cutter, Pau Cortes, Stefanie Kremser, Cliff S. Law, Andrew Marriner, Rafel Simó, Birgit Quack, Günther Uher, Huixiang Xie, and Xiaobin Xu
Earth Syst. Sci. Data, 12, 591–609, https://doi.org/10.5194/essd-12-591-2020, https://doi.org/10.5194/essd-12-591-2020, 2020
Short summary
Short summary
Sulfur-containing trace gases in the atmosphere influence atmospheric chemistry and the energy budget of the Earth by forming aerosols. The ocean is an important source of the most abundant sulfur gas in the atmosphere, carbonyl sulfide (OCS) and its most important precursor carbon disulfide (CS2). In order to assess global variability of the sea surface concentrations of both gases to calculate their oceanic emissions, we have compiled a database of existing shipborne measurements.
Elizabeth Asher, Rebecca S. Hornbrook, Britton B. Stephens, Doug Kinnison, Eric J. Morgan, Ralph F. Keeling, Elliot L. Atlas, Sue M. Schauffler, Simone Tilmes, Eric A. Kort, Martin S. Hoecker-Martínez, Matt C. Long, Jean-François Lamarque, Alfonso Saiz-Lopez, Kathryn McKain, Colm Sweeney, Alan J. Hills, and Eric C. Apel
Atmos. Chem. Phys., 19, 14071–14090, https://doi.org/10.5194/acp-19-14071-2019, https://doi.org/10.5194/acp-19-14071-2019, 2019
Short summary
Short summary
Halogenated organic trace gases, which are a source of reactive halogens to the atmosphere, exert a disproportionately large influence on atmospheric chemistry and climate. This paper reports novel aircraft observations of halogenated compounds over the Southern Ocean in summer and evaluates hypothesized regional sources and emissions of these trace gases through their relationships to additional aircraft observations.
Yue Jia, Susann Tegtmeier, Elliot Atlas, and Birgit Quack
Atmos. Chem. Phys., 19, 11089–11103, https://doi.org/10.5194/acp-19-11089-2019, https://doi.org/10.5194/acp-19-11089-2019, 2019
Sinikka T. Lennartz, Marc von Hobe, Dennis Booge, Henry C. Bittig, Tim Fischer, Rafael Gonçalves-Araujo, Kerstin B. Ksionzek, Boris P. Koch, Astrid Bracher, Rüdiger Röttgers, Birgit Quack, and Christa A. Marandino
Ocean Sci., 15, 1071–1090, https://doi.org/10.5194/os-15-1071-2019, https://doi.org/10.5194/os-15-1071-2019, 2019
Short summary
Short summary
The ocean emits the gases carbonyl sulfide (OCS) and carbon disulfide (CS2), which affect our climate. The goal of this study was to quantify the rates at which both gases are produced in the eastern tropical South Pacific (ETSP), one of the most productive oceanic regions worldwide. Both gases are produced by reactions triggered by sunlight, but we found that the amount produced depends on different factors. Our results improve numerical models to predict oceanic concentrations of both gases.
Xin Chen, Dylan B. Millet, Hanwant B. Singh, Armin Wisthaler, Eric C. Apel, Elliot L. Atlas, Donald R. Blake, Ilann Bourgeois, Steven S. Brown, John D. Crounse, Joost A. de Gouw, Frank M. Flocke, Alan Fried, Brian G. Heikes, Rebecca S. Hornbrook, Tomas Mikoviny, Kyung-Eun Min, Markus Müller, J. Andrew Neuman, Daniel W. O'Sullivan, Jeff Peischl, Gabriele G. Pfister, Dirk Richter, James M. Roberts, Thomas B. Ryerson, Stephen R. Shertz, Chelsea R. Thompson, Victoria Treadaway, Patrick R. Veres, James Walega, Carsten Warneke, Rebecca A. Washenfelder, Petter Weibring, and Bin Yuan
Atmos. Chem. Phys., 19, 9097–9123, https://doi.org/10.5194/acp-19-9097-2019, https://doi.org/10.5194/acp-19-9097-2019, 2019
Short summary
Short summary
Volatile organic compounds (VOCs) affect air quality and modify the lifetimes of other pollutants. We combine a high-resolution 3-D atmospheric model with an ensemble of aircraft observations to perform an integrated analysis of the VOC budget over North America. We find that biogenic emissions provide the main source of VOC reactivity even in most major cities. Our findings point to key gaps in current models related to oxygenated VOCs and to the distribution of VOCs in the free troposphere.
Josefine Maas, Susann Tegtmeier, Birgit Quack, Arne Biastoch, Jonathan V. Durgadoo, Siren Rühs, Stephan Gollasch, and Matej David
Ocean Sci., 15, 891–904, https://doi.org/10.5194/os-15-891-2019, https://doi.org/10.5194/os-15-891-2019, 2019
Short summary
Short summary
In a large-scale analysis, the spread of disinfection by-products from oxidative ballast water treatment is investigated, with a focus on Southeast Asia where major ports are located. Halogenated compounds such as bromoform (CHBr3) are produced in the ballast water and, once emitted into the environment, can participate in ozone depletion. Anthropogenic bromoform is rapidly emitted into the atmosphere and can locally double around large ports. A large-scale impact cannot be found.
Robyn Butler, Paul I. Palmer, Liang Feng, Stephen J. Andrews, Elliot L. Atlas, Lucy J. Carpenter, Valeria Donets, Neil R. P. Harris, Stephen A. Montzka, Laura L. Pan, Ross J. Salawitch, and Sue M. Schauffler
Atmos. Chem. Phys., 18, 13135–13153, https://doi.org/10.5194/acp-18-13135-2018, https://doi.org/10.5194/acp-18-13135-2018, 2018
Short summary
Short summary
Natural sources of short-lived bromoform and dibromomethane are important for determining the inorganic bromine budget in the stratosphere that drives ozone loss. Two new modelling techniques describe how different geographical source regions influence their atmospheric variability over the western Pacific. We find that it is driven primarily by open ocean sources, and we use atmospheric observations to help estimate their contributions to the upper tropospheric inorganic bromine budget.
Alina Fiehn, Birgit Quack, Irene Stemmler, Franziska Ziska, and Kirstin Krüger
Atmos. Chem. Phys., 18, 11973–11990, https://doi.org/10.5194/acp-18-11973-2018, https://doi.org/10.5194/acp-18-11973-2018, 2018
Short summary
Short summary
Oceanic very short-lived substances, VSLS, contribute to stratospheric halogen loading and ozone depletion. We created bromoform emission inventories with monthly resolution for the tropical Indian Ocean and west Pacific and modeled the atmospheric transport of bromoform with the particle dispersion model FLEXPART/ERA-Interim. Results underline that the seasonal and regional stratospheric bromine entrainment critically depends on the seasonality and spatial distribution of the VSLS emissions.
Richard Newton, Geraint Vaughan, Eric Hintsa, Michal T. Filus, Laura L. Pan, Shawn Honomichl, Elliot Atlas, Stephen J. Andrews, and Lucy J. Carpenter
Atmos. Chem. Phys., 18, 5157–5171, https://doi.org/10.5194/acp-18-5157-2018, https://doi.org/10.5194/acp-18-5157-2018, 2018
Short summary
Short summary
We consider the ozone measurements from aircraft during the CAST/CONTRAST/ATTREX campaigns of 2014. Low concentrations of ozone were found in the layer of 10–15 km altitude, which is indicative of uplift of ozone-poor air from near the sea surface to 10–15 km altitude. Chemicals that have origins in the sea were found in greater abundance when ozone concentrations were low compared to when ozone concentrations were high. The lowest ozone concentrations were found in the Southern Hemisphere.
Theodore K. Koenig, Rainer Volkamer, Sunil Baidar, Barbara Dix, Siyuan Wang, Daniel C. Anderson, Ross J. Salawitch, Pamela A. Wales, Carlos A. Cuevas, Rafael P. Fernandez, Alfonso Saiz-Lopez, Mathew J. Evans, Tomás Sherwen, Daniel J. Jacob, Johan Schmidt, Douglas Kinnison, Jean-François Lamarque, Eric C. Apel, James C. Bresch, Teresa Campos, Frank M. Flocke, Samuel R. Hall, Shawn B. Honomichl, Rebecca Hornbrook, Jørgen B. Jensen, Richard Lueb, Denise D. Montzka, Laura L. Pan, J. Michael Reeves, Sue M. Schauffler, Kirk Ullmann, Andrew J. Weinheimer, Elliot L. Atlas, Valeria Donets, Maria A. Navarro, Daniel Riemer, Nicola J. Blake, Dexian Chen, L. Gregory Huey, David J. Tanner, Thomas F. Hanisco, and Glenn M. Wolfe
Atmos. Chem. Phys., 17, 15245–15270, https://doi.org/10.5194/acp-17-15245-2017, https://doi.org/10.5194/acp-17-15245-2017, 2017
Short summary
Short summary
Tropospheric inorganic bromine (BrO and Bry) shows a C-shaped profile over the tropical western Pacific Ocean, and supports previous speculation that marine convection is a source for inorganic bromine from sea salt to the upper troposphere. The Bry profile in the tropical tropopause layer (TTL) is complex, suggesting that the total Bry budget in the TTL is not closed without considering aerosol bromide. The implications for atmospheric composition and bromine sources are discussed.
Cathleen Schlundt, Susann Tegtmeier, Sinikka T. Lennartz, Astrid Bracher, Wee Cheah, Kirstin Krüger, Birgit Quack, and Christa A. Marandino
Atmos. Chem. Phys., 17, 10837–10854, https://doi.org/10.5194/acp-17-10837-2017, https://doi.org/10.5194/acp-17-10837-2017, 2017
Short summary
Short summary
For the first time, oxygenated volatile organic carbon (OVOC) in the ocean and overlaying atmosphere in the western Pacific Ocean has been measured. OVOCs are important for atmospheric chemistry. They are involved in ozone production in the upper troposphere (UT), and they have a climate cooling effect. We showed that phytoplankton was an important source for OVOCs in the surface ocean, and when OVOCs are emitted into the atmosphere, they could reach the UT and might influence ozone formation.
Maria A. Navarro, Alfonso Saiz-Lopez, Carlos A. Cuevas, Rafael P. Fernandez, Elliot Atlas, Xavier Rodriguez-Lloveras, Douglas Kinnison, Jean-Francois Lamarque, Simone Tilmes, Troy Thornberry, Andrew Rollins, James W. Elkins, Eric J. Hintsa, and Fred L. Moore
Atmos. Chem. Phys., 17, 9917–9930, https://doi.org/10.5194/acp-17-9917-2017, https://doi.org/10.5194/acp-17-9917-2017, 2017
Short summary
Short summary
Inorganic bromine (Bry) plays an important role in ozone layer depletion. Based on aircraft observations of organic bromine species and chemistry simulations, we model the Bry abundances over the Pacific tropical tropopause. Our results show BrO and Br as the dominant species during daytime hours, and BrCl and BrONO2 as the nighttime dominant species over the western and eastern Pacific, respectively. The difference in the partitioning is due to changes in the abundance of O3, NO2, and Cly.
Alina Fiehn, Birgit Quack, Helmke Hepach, Steffen Fuhlbrügge, Susann Tegtmeier, Matthew Toohey, Elliot Atlas, and Kirstin Krüger
Atmos. Chem. Phys., 17, 6723–6741, https://doi.org/10.5194/acp-17-6723-2017, https://doi.org/10.5194/acp-17-6723-2017, 2017
Short summary
Short summary
Halogenated very short-lived substances (VSLSs) are naturally produced in the ocean and emitted to the atmosphere. In the stratosphere, these compounds can have a significant influence on the ozone layer and climate. During a research cruise in the west Indian Ocean, we found an important source region of halogenated VSLSs during the Asian summer monsoon. Modeling the transport from the ocean to the stratosphere we found two main pathways, one over the Indian Ocean and one over northern India.
Nga Lee Ng, Steven S. Brown, Alexander T. Archibald, Elliot Atlas, Ronald C. Cohen, John N. Crowley, Douglas A. Day, Neil M. Donahue, Juliane L. Fry, Hendrik Fuchs, Robert J. Griffin, Marcelo I. Guzman, Hartmut Herrmann, Alma Hodzic, Yoshiteru Iinuma, José L. Jimenez, Astrid Kiendler-Scharr, Ben H. Lee, Deborah J. Luecken, Jingqiu Mao, Robert McLaren, Anke Mutzel, Hans D. Osthoff, Bin Ouyang, Benedicte Picquet-Varrault, Ulrich Platt, Havala O. T. Pye, Yinon Rudich, Rebecca H. Schwantes, Manabu Shiraiwa, Jochen Stutz, Joel A. Thornton, Andreas Tilgner, Brent J. Williams, and Rahul A. Zaveri
Atmos. Chem. Phys., 17, 2103–2162, https://doi.org/10.5194/acp-17-2103-2017, https://doi.org/10.5194/acp-17-2103-2017, 2017
Short summary
Short summary
Oxidation of biogenic volatile organic compounds by NO3 is an important interaction between anthropogenic
and natural emissions. This review results from a June 2015 workshop and includes the recent literature
on kinetics, mechanisms, organic aerosol yields, and heterogeneous chemistry; advances in analytical
instrumentation; the current state NO3-BVOC chemistry in atmospheric models; and critical needs for
future research in modeling, field observations, and laboratory studies.
Brian M. Lerner, Jessica B. Gilman, Kenneth C. Aikin, Elliot L. Atlas, Paul D. Goldan, Martin Graus, Roger Hendershot, Gabriel A. Isaacman-VanWertz, Abigail Koss, William C. Kuster, Richard A. Lueb, Richard J. McLaughlin, Jeff Peischl, Donna Sueper, Thomas B. Ryerson, Travis W. Tokarek, Carsten Warneke, Bin Yuan, and Joost A. de Gouw
Atmos. Meas. Tech., 10, 291–313, https://doi.org/10.5194/amt-10-291-2017, https://doi.org/10.5194/amt-10-291-2017, 2017
Short summary
Short summary
Whole air sampling followed by analysis by gas chromatography is a common technique for characterization of trace volatile organic compounds in the atmosphere. We describe a new automated gas chromatograph–mass spectrograph which uses a Stirling cooler for sample preconcentration at −165 °C without the need for a cryogen such as liquid nitrogen. We also discuss potential sources of artifacts from our electropolished stainless steel sampling system and present results from two field campaigns.
Bodo Werner, Jochen Stutz, Max Spolaor, Lisa Scalone, Rasmus Raecke, James Festa, Santo Fedele Colosimo, Ross Cheung, Catalina Tsai, Ryan Hossaini, Martyn P. Chipperfield, Giorgio S. Taverna, Wuhu Feng, James W. Elkins, David W. Fahey, Ru-Shan Gao, Erik J. Hintsa, Troy D. Thornberry, Free Lee Moore, Maria A. Navarro, Elliot Atlas, Bruce C. Daube, Jasna Pittman, Steve Wofsy, and Klaus Pfeilsticker
Atmos. Chem. Phys., 17, 1161–1186, https://doi.org/10.5194/acp-17-1161-2017, https://doi.org/10.5194/acp-17-1161-2017, 2017
Short summary
Short summary
The paper reports on inorganic and organic bromine measured in the tropical tropopause layer (TTL) over the eastern Pacific in early 2013. Bryinorg is found to increase from a mean of 2.63 ± 1.04 ppt for θ in the range of 350–360 K to 5.11 ± 1.57 ppt for θ=390 ± 400 K, whereas in the subtropical lower stratosphere, it reaches 7.66 ± 2.95 ppt for θ in the range of 390–400 K. Within the TTL, total bromine is found to range from 20.3 ppt to 22.3 ppt.
Sinikka T. Lennartz, Christa A. Marandino, Marc von Hobe, Pau Cortes, Birgit Quack, Rafel Simo, Dennis Booge, Andrea Pozzer, Tobias Steinhoff, Damian L. Arevalo-Martinez, Corinna Kloss, Astrid Bracher, Rüdiger Röttgers, Elliot Atlas, and Kirstin Krüger
Atmos. Chem. Phys., 17, 385–402, https://doi.org/10.5194/acp-17-385-2017, https://doi.org/10.5194/acp-17-385-2017, 2017
Short summary
Short summary
We present new sea surface and marine boundary layer measurements of carbonyl sulfide, the most abundant sulfur gas in the atmosphere, and calculate an oceanic emission estimate. Our results imply that oceanic emissions are very unlikely to account for the missing source in the atmospheric budget that is currently discussed for OCS.
Martyn P. Chipperfield, Qing Liang, Matthew Rigby, Ryan Hossaini, Stephen A. Montzka, Sandip Dhomse, Wuhu Feng, Ronald G. Prinn, Ray F. Weiss, Christina M. Harth, Peter K. Salameh, Jens Mühle, Simon O'Doherty, Dickon Young, Peter G. Simmonds, Paul B. Krummel, Paul J. Fraser, L. Paul Steele, James D. Happell, Robert C. Rhew, James Butler, Shari A. Yvon-Lewis, Bradley Hall, David Nance, Fred Moore, Ben R. Miller, James W. Elkins, Jeremy J. Harrison, Chris D. Boone, Elliot L. Atlas, and Emmanuel Mahieu
Atmos. Chem. Phys., 16, 15741–15754, https://doi.org/10.5194/acp-16-15741-2016, https://doi.org/10.5194/acp-16-15741-2016, 2016
Short summary
Short summary
Carbon tetrachloride (CCl4) is a compound which, when released into the atmosphere, can cause depletion of the stratospheric ozone layer. Its emissions are controlled under the Montreal Protocol, and its atmospheric abundance is slowly decreasing. However, this decrease is not as fast as expected based on estimates of its emissions and its atmospheric lifetime. We have used an atmospheric model to look at the uncertainties in the CCl4 lifetime and to examine the impact on its atmospheric decay.
Stephen J. Andrews, Lucy J. Carpenter, Eric C. Apel, Elliot Atlas, Valeria Donets, James R. Hopkins, Rebecca S. Hornbrook, Alastair C. Lewis, Richard T. Lidster, Richard Lueb, Jamie Minaeian, Maria Navarro, Shalini Punjabi, Daniel Riemer, and Sue Schauffler
Atmos. Meas. Tech., 9, 5213–5225, https://doi.org/10.5194/amt-9-5213-2016, https://doi.org/10.5194/amt-9-5213-2016, 2016
Short summary
Short summary
We present a comparison of aircraft measurements of important trace gases from a co-ordinated campaign in Jan–Feb 2014 in the tropical west Pacific involving the NASA Global Hawk, NCAR GV and FAAM BAe-146 aircraft.
The paper studies the comparability of separate measurements across platforms and demonstrates that aircraft measurements are relevant for characterising the vertical uplift of important gases, such as those with ozone-depleting potential, to the upper troposphere–lower stratosphere.
Helmke Hepach, Birgit Quack, Susann Tegtmeier, Anja Engel, Astrid Bracher, Steffen Fuhlbrügge, Luisa Galgani, Elliot L. Atlas, Johannes Lampel, Udo Frieß, and Kirstin Krüger
Atmos. Chem. Phys., 16, 12219–12237, https://doi.org/10.5194/acp-16-12219-2016, https://doi.org/10.5194/acp-16-12219-2016, 2016
Short summary
Short summary
We present surface seawater measurements of bromo- and iodocarbons, which are involved in numerous atmospheric processes such as tropospheric and stratospheric ozone chemistry, from the highly productive Peruvian upwelling. By combining trace gas measurements, characterization of organic matter and phytoplankton species, and tropospheric modelling, we show that large amounts of iodocarbons produced from the pool of organic matter may contribute strongly to local tropospheric iodine loading.
Dennis Booge, Christa A. Marandino, Cathleen Schlundt, Paul I. Palmer, Michael Schlundt, Elliot L. Atlas, Astrid Bracher, Eric S. Saltzman, and Douglas W. R. Wallace
Atmos. Chem. Phys., 16, 11807–11821, https://doi.org/10.5194/acp-16-11807-2016, https://doi.org/10.5194/acp-16-11807-2016, 2016
Short summary
Short summary
Isoprene, a biogenic trace gas, is an important precursor of secondary organic aerosol/cloud condensation nuclei. Here, we use isoprene and related field measurements from three different ocean data sets together with remotely sensed satellite data to model global marine isoprene emissions. Our findings suggest that there is at least one missing oceanic source of isoprene and possibly other unknown factors in the ocean or atmosphere influencing the atmospheric values.
R. Hossaini, P. K. Patra, A. A. Leeson, G. Krysztofiak, N. L. Abraham, S. J. Andrews, A. T. Archibald, J. Aschmann, E. L. Atlas, D. A. Belikov, H. Bönisch, L. J. Carpenter, S. Dhomse, M. Dorf, A. Engel, W. Feng, S. Fuhlbrügge, P. T. Griffiths, N. R. P. Harris, R. Hommel, T. Keber, K. Krüger, S. T. Lennartz, S. Maksyutov, H. Mantle, G. P. Mills, B. Miller, S. A. Montzka, F. Moore, M. A. Navarro, D. E. Oram, K. Pfeilsticker, J. A. Pyle, B. Quack, A. D. Robinson, E. Saikawa, A. Saiz-Lopez, S. Sala, B.-M. Sinnhuber, S. Taguchi, S. Tegtmeier, R. T. Lidster, C. Wilson, and F. Ziska
Atmos. Chem. Phys., 16, 9163–9187, https://doi.org/10.5194/acp-16-9163-2016, https://doi.org/10.5194/acp-16-9163-2016, 2016
Steffen Fuhlbrügge, Birgit Quack, Susann Tegtmeier, Elliot Atlas, Helmke Hepach, Qiang Shi, Stefan Raimund, and Kirstin Krüger
Atmos. Chem. Phys., 16, 7569–7585, https://doi.org/10.5194/acp-16-7569-2016, https://doi.org/10.5194/acp-16-7569-2016, 2016
Short summary
Short summary
This study presents a novel estimate for the contribution of oceanic VSLS emissions to the atmospheric boundary layer and free troposphere during the SHIVA-Sonne cruise in the South China and Sulu seas in 2011. While oceanic emissions of CHBr3 and CH3I showed a significant contribution to their atmospheric abundances, atmospheric CH2Br2 appeared to be largely advected. Convective activity in the region can furthermore lead to low VSLS boundary layer mixing ratios despite high oceanic emissions.
S. Tegtmeier, F. Ziska, I. Pisso, B. Quack, G. J. M. Velders, X. Yang, and K. Krüger
Atmos. Chem. Phys., 15, 13647–13663, https://doi.org/10.5194/acp-15-13647-2015, https://doi.org/10.5194/acp-15-13647-2015, 2015
Short summary
Short summary
At present, man-made halogens and natural oceanic substances both contribute to the observed ozone depletion. Emissions of the anthropogenic halogens have been reduced, whereas emissions of the natural substances are expected to increase in future climate due to anthropogenic activities affecting oceanic processes. We assess the impact of these oceanic substances on ozone by weighting their emissions with their potential to destroy ozone for current conditions and future projections.
H. Hepach, B. Quack, S. Raimund, T. Fischer, E. L. Atlas, and A. Bracher
Biogeosciences, 12, 6369–6387, https://doi.org/10.5194/bg-12-6369-2015, https://doi.org/10.5194/bg-12-6369-2015, 2015
Short summary
Short summary
This manuscript covers the first measurements of CHBr3, CH2Br2 and CH3I from the equatorial Atlantic during the Cold Tongue season, identifying this region and season as a source for these compounds. For the first time, we calculated diapycnal fluxes, and showed that the fluxes from below the mixed layer to the surface are not sufficient to balance the mixed layer budget. Hence, we conclude that mixed layer production has to take place despite a pronounced sub-mixed-layer-maximum.
S. T. Lennartz, G. Krysztofiak, C. A. Marandino, B.-M. Sinnhuber, S. Tegtmeier, F. Ziska, R. Hossaini, K. Krüger, S. A. Montzka, E. Atlas, D. E. Oram, T. Keber, H. Bönisch, and B. Quack
Atmos. Chem. Phys., 15, 11753–11772, https://doi.org/10.5194/acp-15-11753-2015, https://doi.org/10.5194/acp-15-11753-2015, 2015
Short summary
Short summary
Marine-produced short-lived trace gases such as halocarbons and DMS significantly impact atmospheric chemistry. To assess this impact on ozone depletion and the radiative budget, it is critical that their marine emissions in atmospheric chemistry models are quantified as accurately as possible. We show that calculating emissions online with an interactive atmosphere improves the agreement with current observations and should be employed regularly in models where marine sources are important.
Fuqing Zhang, Junhong Wei, Meng Zhang, K. P. Bowman, L. L. Pan, E. Atlas, and S. C. Wofsy
Atmos. Chem. Phys., 15, 7667–7684, https://doi.org/10.5194/acp-15-7667-2015, https://doi.org/10.5194/acp-15-7667-2015, 2015
Short summary
Short summary
Based on spectral and wavelet analyses, along with a diagnosis of the polarization relations, this study analyzes in situ airborne measurements from the 2008 Stratosphere-Troposphere Analyses of Regional Transport (START08) experiment to characterize gravity waves in the extratropical upper troposphere and lower stratosphere (ExUTLS) region. The focus is on the second research flight (RF02), which was dedicated to probing gravity waves associated with strong upper-tropospheric jet-front systems.
I. Stemmler, I. Hense, and B. Quack
Biogeosciences, 12, 1967–1981, https://doi.org/10.5194/bg-12-1967-2015, https://doi.org/10.5194/bg-12-1967-2015, 2015
I. Stemmler, I. Hense, B. Quack, and E. Maier-Reimer
Biogeosciences, 11, 4459–4476, https://doi.org/10.5194/bg-11-4459-2014, https://doi.org/10.5194/bg-11-4459-2014, 2014
Q. Liang, E. Atlas, D. Blake, M. Dorf, K. Pfeilsticker, and S. Schauffler
Atmos. Chem. Phys., 14, 5781–5792, https://doi.org/10.5194/acp-14-5781-2014, https://doi.org/10.5194/acp-14-5781-2014, 2014
D. R. Gentner, T. B. Ford, A. Guha, K. Boulanger, J. Brioude, W. M. Angevine, J. A. de Gouw, C. Warneke, J. B. Gilman, T. B. Ryerson, J. Peischl, S. Meinardi, D. R. Blake, E. Atlas, W. A. Lonneman, T. E. Kleindienst, M. R. Beaver, J. M. St. Clair, P. O. Wennberg, T. C. VandenBoer, M. Z. Markovic, J. G. Murphy, R. A. Harley, and A. H. Goldstein
Atmos. Chem. Phys., 14, 4955–4978, https://doi.org/10.5194/acp-14-4955-2014, https://doi.org/10.5194/acp-14-4955-2014, 2014
C. J. Young, R. A. Washenfelder, P. M. Edwards, D. D. Parrish, J. B. Gilman, W. C. Kuster, L. H. Mielke, H. D. Osthoff, C. Tsai, O. Pikelnaya, J. Stutz, P. R. Veres, J. M. Roberts, S. Griffith, S. Dusanter, P. S. Stevens, J. Flynn, N. Grossberg, B. Lefer, J. S. Holloway, J. Peischl, T. B. Ryerson, E. L. Atlas, D. R. Blake, and S. S. Brown
Atmos. Chem. Phys., 14, 3427–3440, https://doi.org/10.5194/acp-14-3427-2014, https://doi.org/10.5194/acp-14-3427-2014, 2014
B. D. Hall, A. Engel, J. Mühle, J. W. Elkins, F. Artuso, E. Atlas, M. Aydin, D. Blake, E.-G. Brunke, S. Chiavarini, P. J. Fraser, J. Happell, P. B. Krummel, I. Levin, M. Loewenstein, M. Maione, S. A. Montzka, S. O'Doherty, S. Reimann, G. Rhoderick, E. S. Saltzman, H. E. Scheel, L. P. Steele, M. K. Vollmer, R. F. Weiss, D. Worthy, and Y. Yokouchi
Atmos. Meas. Tech., 7, 469–490, https://doi.org/10.5194/amt-7-469-2014, https://doi.org/10.5194/amt-7-469-2014, 2014
H. Hepach, B. Quack, F. Ziska, S. Fuhlbrügge, E. L. Atlas, K. Krüger, I. Peeken, and D. W. R. Wallace
Atmos. Chem. Phys., 14, 1255–1275, https://doi.org/10.5194/acp-14-1255-2014, https://doi.org/10.5194/acp-14-1255-2014, 2014
S. Tegtmeier, K. Krüger, B. Quack, E. Atlas, D. R. Blake, H. Boenisch, A. Engel, H. Hepach, R. Hossaini, M. A. Navarro, S. Raimund, S. Sala, Q. Shi, and F. Ziska
Atmos. Chem. Phys., 13, 11869–11886, https://doi.org/10.5194/acp-13-11869-2013, https://doi.org/10.5194/acp-13-11869-2013, 2013
R. Hossaini, H. Mantle, M. P. Chipperfield, S. A. Montzka, P. Hamer, F. Ziska, B. Quack, K. Krüger, S. Tegtmeier, E. Atlas, S. Sala, A. Engel, H. Bönisch, T. Keber, D. Oram, G. Mills, C. Ordóñez, A. Saiz-Lopez, N. Warwick, Q. Liang, W. Feng, F. Moore, B. R. Miller, V. Marécal, N. A. D. Richards, M. Dorf, and K. Pfeilsticker
Atmos. Chem. Phys., 13, 11819–11838, https://doi.org/10.5194/acp-13-11819-2013, https://doi.org/10.5194/acp-13-11819-2013, 2013
S. S. Brown, W. P. Dubé, R. Bahreini, A. M. Middlebrook, C. A. Brock, C. Warneke, J. A. de Gouw, R. A. Washenfelder, E. Atlas, J. Peischl, T. B. Ryerson, J. S. Holloway, J. P. Schwarz, R. Spackman, M. Trainer, D. D. Parrish, F. C. Fehshenfeld, and A. R. Ravishankara
Atmos. Chem. Phys., 13, 11317–11337, https://doi.org/10.5194/acp-13-11317-2013, https://doi.org/10.5194/acp-13-11317-2013, 2013
F. Ziska, B. Quack, K. Abrahamsson, S. D. Archer, E. Atlas, T. Bell, J. H. Butler, L. J. Carpenter, C. E. Jones, N. R. P. Harris, H. Hepach, K. G. Heumann, C. Hughes, J. Kuss, K. Krüger, P. Liss, R. M. Moore, A. Orlikowska, S. Raimund, C. E. Reeves, W. Reifenhäuser, A. D. Robinson, C. Schall, T. Tanhua, S. Tegtmeier, S. Turner, L. Wang, D. Wallace, J. Williams, H. Yamamoto, S. Yvon-Lewis, and Y. Yokouchi
Atmos. Chem. Phys., 13, 8915–8934, https://doi.org/10.5194/acp-13-8915-2013, https://doi.org/10.5194/acp-13-8915-2013, 2013
C. A. Marandino, S. Tegtmeier, K. Krüger, C. Zindler, E. L. Atlas, F. Moore, and H. W. Bange
Atmos. Chem. Phys., 13, 8427–8437, https://doi.org/10.5194/acp-13-8427-2013, https://doi.org/10.5194/acp-13-8427-2013, 2013
P. D. Hamer, V. Marécal, R. Hossaini, M. Pirre, N. Warwick, M. Chipperfield, A. A. Samah, N. Harris, A. Robinson, B. Quack, A. Engel, K. Krüger, E. Atlas, K. Subramaniam, D. Oram, E. Leedham, G. Mills, K. Pfeilsticker, S. Sala, T. Keber, H. Bönisch, L. K. Peng, M. S. M. Nadzir, P. T. Lim, A. Mujahid, A. Anton, H. Schlager, V. Catoire, G. Krysztofiak, S. Fühlbrügge, M. Dorf, and W. T. Sturges
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-20611-2013, https://doi.org/10.5194/acpd-13-20611-2013, 2013
Revised manuscript not accepted
W. Cheah, B. B. Taylor, S. Wiegmann, S. Raimund, G. Krahmann, B. Quack, and A. Bracher
Biogeosciences Discuss., https://doi.org/10.5194/bgd-10-12115-2013, https://doi.org/10.5194/bgd-10-12115-2013, 2013
Revised manuscript not accepted
S. Fuhlbrügge, K. Krüger, B. Quack, E. Atlas, H. Hepach, and F. Ziska
Atmos. Chem. Phys., 13, 6345–6357, https://doi.org/10.5194/acp-13-6345-2013, https://doi.org/10.5194/acp-13-6345-2013, 2013
K. Großmann, U. Frieß, E. Peters, F. Wittrock, J. Lampel, S. Yilmaz, J. Tschritter, R. Sommariva, R. von Glasow, B. Quack, K. Krüger, K. Pfeilsticker, and U. Platt
Atmos. Chem. Phys., 13, 3363–3378, https://doi.org/10.5194/acp-13-3363-2013, https://doi.org/10.5194/acp-13-3363-2013, 2013
Related subject area
Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Springtime nitrogen oxides and tropospheric ozone in Svalbard: results from the measurement station network
Measurement report: Observations of long-lived volatile organic compounds from the 2019–2020 Australian wildfires during the COALA campaign
Composition and reactivity of volatile organic compounds in the South Coast Air Basin and San Joaquin Valley of California
Analysis of regional CO2 contributions at the high Alpine observatory Jungfraujoch by means of atmospheric transport simulations and δ13C
Variations and sources of volatile organic compounds (VOCs) in urban region: insights from measurements on a tall tower
Tropical peat fire emissions: 2019 field measurements in Sumatra and Borneo and synthesis with previous studies
Sulfuric acid in the Amazon basin: measurements and evaluation of existing sulfuric acid proxies
Seasonal variation in oxygenated organic molecules in urban Beijing and their contribution to secondary organic aerosol
Oxygenated volatile organic compounds (VOCs) as significant but varied contributors to VOC emissions from vehicles
The impacts of wildfires on ozone production and boundary layer dynamics in California's Central Valley
Distribution of hydrogen peroxide over Europe during the BLUESKY aircraft campaign
Eddy covariance measurements highlight sources of nitrogen oxide emissions missing from inventories for central London
Budget of nitrous acid (HONO) at an urban site in the fall season of Guangzhou, China
Long-term trend of ozone pollution in China during 2014–2020: distinct seasonal and spatial characteristics and ozone sensitivity
Investigation of new particle formation mechanisms and aerosol processes at Marambio Station, Antarctic Peninsula
Atmospheric biogenic volatile organic compounds in the Alaskan Arctic tundra: constraints from measurements at Toolik Field Station
Measurement report: Variations in surface SO2 and NOx mixing ratios from 2004 to 2016 at a background site in the North China Plain
Fate of the nitrate radical at the summit of a semi-rural mountain site in Germany assessed with direct reactivity measurements
Spatiotemporal variations of the δ(O2 ∕ N2), CO2 and δ(APO) in the troposphere over the western North Pacific
OH and HO2 radical chemistry at a suburban site during the EXPLORE-YRD campaign in 2018
Towards reconstructing the Arctic atmospheric methane history over the 20th century: measurement and modelling results for the North Greenland Ice Core Project firn
Atmospheric gas-phase composition over the Indian Ocean
Joint occurrence of heatwaves and ozone pollution and increased health risks in Beijing, China: role of synoptic weather pattern and urbanization
Using atmospheric trace gas vertical profiles to evaluate model fluxes: a case study of Arctic-CAP observations and GEOS simulations for the ABoVE domain
An evaluation of new particle formation events in Helsinki during a Baltic Sea cyanobacterial summer bloom
Oceanic emissions of dimethyl sulfide and methanethiol and their contribution to sulfur dioxide production in the marine atmosphere
An investigation into the chemistry of HONO in the marine boundary layer at Tudor Hill Marine Atmospheric Observatory in Bermuda
Tropospheric ozone production and chemical regime analysis during the COVID-19 lockdown over Europe
Overview: On the transport and transformation of pollutants in the outflow of major population centres – observational data from the EMeRGe European intensive operational period in summer 2017
Interannual variability of terpenoid emissions in an alpine city
Observations and modelling of glyoxal in the tropical Atlantic marine boundary layer
Mass spectrometric measurements of ambient ions and estimation of gaseous sulfuric acid in the free troposphere and lowermost stratosphere during the CAFE-EU/BLUESKY campaign
Top-down and bottom-up estimates of anthropogenic methyl bromide emissions from eastern China
Direct measurements of ozone response to emissions perturbations in California
Reconciling the total carbon budget for boreal forest wildfire emissions using airborne observations
Ground-based investigation of HOx and ozone chemistry in biomass burning plumes in rural Idaho
Insights into the significant increase in ozone during COVID-19 in a typical urban city of China
Quantification and assessment of methane emissions from offshore oil and gas facilities on the Norwegian continental shelf
Full latitudinal marine atmospheric measurements of iodine monoxide
Direct observations indicate photodegradable oxygenated volatile organic compounds (OVOCs) as larger contributors to radicals and ozone production in the atmosphere
Assessing vehicle fuel efficiency using a dense network of CO2 observations
Odds and ends of atmospheric mercury in Europe and over the North Atlantic Ocean: temporal trends of 25 years of measurements
Interpretation of NO3–N2O5 observation via steady state in high-aerosol air mass: the impact of equilibrium coefficient in ambient conditions
Global emissions of perfluorocyclobutane (PFC-318, c-C4F8) resulting from the use of hydrochlorofluorocarbon-22 (HCFC-22) feedstock to produce polytetrafluoroethylene (PTFE) and related fluorochemicals
Atmospheric measurements at Mt. Tai – Part I: HONO formation and its role in the oxidizing capacity of the upper boundary layer
Urban inland wintertime N2O5 and ClNO2 influenced by snow-covered ground, air turbulence, and precipitation
First observation of mercury species on an important water vapor channel in the southeastern Tibetan Plateau
Swiss halocarbon emissions for 2019 to 2020 assessed from regional atmospheric observations
Radical chemistry in the Pearl River Delta: observations and modeling of OH and HO2 radicals in Shenzhen 2018
Measurement report: Long-term measurements of aerosol precursor concentrations in the Finnish subarctic boreal forest
Alena Dekhtyareva, Mark Hermanson, Anna Nikulina, Ove Hermansen, Tove Svendby, Kim Holmén, and Rune Grand Graversen
Atmos. Chem. Phys., 22, 11631–11656, https://doi.org/10.5194/acp-22-11631-2022, https://doi.org/10.5194/acp-22-11631-2022, 2022
Short summary
Short summary
Despite decades of industrial activity in Svalbard, there is no continuous air pollution monitoring in the region’s settlements except Ny-Ålesund. The NOx and O3 observations from the three-station network have been compared for the first time in this study. It has been shown how the large-scale weather regimes control the synoptic meteorological conditions and determine the atmospheric long-range transport pathways and efficiency of local air pollution dispersion.
Asher P. Mouat, Clare Paton-Walsh, Jack B. Simmons, Jhonathan Ramirez-Gamboa, David W. T. Griffith, and Jennifer Kaiser
Atmos. Chem. Phys., 22, 11033–11047, https://doi.org/10.5194/acp-22-11033-2022, https://doi.org/10.5194/acp-22-11033-2022, 2022
Short summary
Short summary
We examine emissions of volatile organic compounds from 2020 wildfires in forested regions of Australia (AU). We find that biomass burning in temperate regions of the US and AU emit similar species in similar proportion, both in natural and lab settings. This suggests studies of wildfires in one region may be used to help improve air quality models in other parts of the world. We observe time series of ozone and nitrogen dioxide. Last, we look at which compounds contribute most to OH reactivity.
Shang Liu, Barbara Barletta, Rebecca S. Hornbrook, Alan Fried, Jeff Peischl, Simone Meinardi, Matthew Coggon, Aaron Lamplugh, Jessica B. Gilman, Georgios I. Gkatzelis, Carsten Warneke, Eric C. Apel, Alan J. Hills, Ilann Bourgeois, James Walega, Petter Weibring, Dirk Richter, Toshihiro Kuwayama, Michael FitzGibbon, and Donald Blake
Atmos. Chem. Phys., 22, 10937–10954, https://doi.org/10.5194/acp-22-10937-2022, https://doi.org/10.5194/acp-22-10937-2022, 2022
Short summary
Short summary
California’s ozone persistently exceeds the air quality standards. We studied the spatial distribution of volatile organic compounds (VOCs) that produce ozone over the most polluted regions in California using aircraft measurements. We find that the oxygenated VOCs have the highest ozone formation potential. Spatially, biogenic VOCs are important during high ozone episodes in the South Coast Air Basin, while dairy emissions may be critical for ozone production in San Joaquin Valley.
Simone M. Pieber, Béla Tuzson, Stephan Henne, Ute Karstens, Christoph Gerbig, Frank-Thomas Koch, Dominik Brunner, Martin Steinbacher, and Lukas Emmenegger
Atmos. Chem. Phys., 22, 10721–10749, https://doi.org/10.5194/acp-22-10721-2022, https://doi.org/10.5194/acp-22-10721-2022, 2022
Short summary
Short summary
Understanding regional greenhouse gas emissions into the atmosphere is a prerequisite to mitigate climate change. In this study, we investigated the regional contributions of carbon dioxide (CO2) at the location of the high Alpine observatory Jungfraujoch (JFJ, Switzerland, 3580 m a.s.l.). To this purpose, we combined receptor-oriented atmospheric transport simulations for CO2 concentration in the period 2009–2017 with stable carbon isotope (δ13C–CO2) information.
Xiao-Bing Li, Bin Yuan, Sihang Wang, Chunlin Wang, Jing Lan, Zhijie Liu, Yongxin Song, Xianjun He, Yibo Huangfu, Chenglei Pei, Peng Cheng, Suxia Yang, Jipeng Qi, Caihong Wu, Shan Huang, Yingchang You, Ming Chang, Huadan Zheng, Wenda Yang, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 22, 10567–10587, https://doi.org/10.5194/acp-22-10567-2022, https://doi.org/10.5194/acp-22-10567-2022, 2022
Short summary
Short summary
High-time-resolution measurements of volatile organic compounds (VOCs) were made using an online mass spectrometer at a 600 m tall tower in urban region. Compositions, temporal variations, and sources of VOCs were quantitatively investigated in this study. We find that VOC measurements in urban regions aloft could better characterize source characteristics of anthropogenic emissions. Our results could provide important implications in making future strategies for control of VOCs.
Robert J. Yokelson, Bambang H. Saharjo, Chelsea E. Stockwell, Erianto I. Putra, Thilina Jayarathne, Acep Akbar, Israr Albar, Donald R. Blake, Laura L. B. Graham, Agus Kurniawan, Simone Meinardi, Diah Ningrum, Ati D. Nurhayati, Asmadi Saad, Niken Sakuntaladewi, Eko Setianto, Isobel J. Simpson, Elizabeth A. Stone, Sigit Sutikno, Andri Thomas, Kevin C. Ryan, and Mark A. Cochrane
Atmos. Chem. Phys., 22, 10173–10194, https://doi.org/10.5194/acp-22-10173-2022, https://doi.org/10.5194/acp-22-10173-2022, 2022
Short summary
Short summary
Fire plus non-fire GHG emissions associated with draining peatlands are the largest per area of any land use change considered by the IPCC. To characterize average and variability for tropical peat fire emissions, highly mobile smoke sampling teams were deployed across four Indonesian provinces to explore an extended interannual, climatic, and spatial range. Large adjustments to IPCC-recommended emissions are suggested. Lab data bolster an extensive emissions database for tropical peat fires.
Deanna C. Myers, Saewung Kim, Steven Sjostedt, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
Atmos. Chem. Phys., 22, 10061–10076, https://doi.org/10.5194/acp-22-10061-2022, https://doi.org/10.5194/acp-22-10061-2022, 2022
Short summary
Short summary
We present the first measurements of gas-phase sulfuric acid from the Amazon basin and evaluate the efficacy of existing sulfuric acid parameterizations in this understudied region. Sulfuric acid is produced during the daytime and nighttime, though current proxies underestimate nighttime production. These results illustrate the need for better parameterizations of sulfuric acid and its precursors that are informed by measurements across a broad range of locations.
Yishuo Guo, Chao Yan, Yuliang Liu, Xiaohui Qiao, Feixue Zheng, Ying Zhang, Ying Zhou, Chang Li, Xiaolong Fan, Zhuohui Lin, Zemin Feng, Yusheng Zhang, Penggang Zheng, Linhui Tian, Wei Nie, Zhe Wang, Dandan Huang, Kaspar R. Daellenbach, Lei Yao, Lubna Dada, Federico Bianchi, Jingkun Jiang, Yongchun Liu, Veli-Matti Kerminen, and Markku Kulmala
Atmos. Chem. Phys., 22, 10077–10097, https://doi.org/10.5194/acp-22-10077-2022, https://doi.org/10.5194/acp-22-10077-2022, 2022
Short summary
Short summary
Gaseous oxygenated organic molecules (OOMs) are able to form atmospheric aerosols, which will impact on human health and climate change. Here, we find that OOMs in urban Beijing are dominated by anthropogenic sources, i.e. aromatic (29 %–41 %) and aliphatic (26 %–41 %) OOMs. They are also the main contributors to the condensational growth of secondary organic aerosols (SOAs). Therefore, the restriction on anthropogenic VOCs is crucial for the reduction of SOAs and haze formation.
Sihang Wang, Bin Yuan, Caihong Wu, Chaomin Wang, Tiange Li, Xianjun He, Yibo Huangfu, Jipeng Qi, Xiao-Bing Li, Qing'e Sha, Manni Zhu, Shengrong Lou, Hongli Wang, Thomas Karl, Martin Graus, Zibing Yuan, and Min Shao
Atmos. Chem. Phys., 22, 9703–9720, https://doi.org/10.5194/acp-22-9703-2022, https://doi.org/10.5194/acp-22-9703-2022, 2022
Short summary
Short summary
Volatile organic compound (VOC) emissions from vehicles are measured using online mass spectrometers. Differences between gasoline and diesel vehicles are observed with higher emission factors of most oxygenated VOCs (OVOCs) and heavier aromatics from diesel vehicles. A higher aromatics / toluene ratio could provide good indicators to distinguish emissions from both vehicle types. We show that OVOCs account for significant contributions to VOC emissions from vehicles, especially diesel vehicles.
Keming Pan and Ian C. Faloona
Atmos. Chem. Phys., 22, 9681–9702, https://doi.org/10.5194/acp-22-9681-2022, https://doi.org/10.5194/acp-22-9681-2022, 2022
Short summary
Short summary
This work represents a unique analysis of 10 existing air quality network sites and meteorological sites, two AmeriFlux sites, and a radio acoustic sounding system in the Central Valley of California during five consecutive fire seasons, June through September, from 2016 to 2020. We find that the ozone production rate increases by ~ 50 % during wildfire influenced periods. Wildfire smoke also decreases the heat flux by 30 % and results in 12 % lower mixed-layer height.
Zaneta T. Hamryszczak, Andrea Pozzer, Florian Obersteiner, Birger Bohn, Benedikt Steil, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 22, 9483–9497, https://doi.org/10.5194/acp-22-9483-2022, https://doi.org/10.5194/acp-22-9483-2022, 2022
Short summary
Short summary
Hydrogen peroxide plays a pivotal role in the chemistry of the atmosphere. Together with organic hydroperoxides, it forms a reservoir for peroxy radicals, which are known to be the key contributors to the self-cleaning processes of the atmosphere. Hydroperoxides were measured over Europe during the BLUESKY campaign in May–June 2020. The paper gives an overview of the distribution of the species in the troposphere and investigates the impact of wet scavenging and deposition on the budget of H2O2.
Will S. Drysdale, Adam R. Vaughan, Freya A. Squires, Sam J. Cliff, Stefan Metzger, David Durden, Natchaya Pingintha-Durden, Carole Helfter, Eiko Nemitz, C. Sue B. Grimmond, Janet Barlow, Sean Beevers, Gregor Stewart, David Dajnak, Ruth M. Purvis, and James D. Lee
Atmos. Chem. Phys., 22, 9413–9433, https://doi.org/10.5194/acp-22-9413-2022, https://doi.org/10.5194/acp-22-9413-2022, 2022
Short summary
Short summary
Measurements of NOx emissions are important for a good understanding of air quality. While there are many direct measurements of NOx concentration, there are very few measurements of its emission. Measurements of emissions provide constraints on emissions inventories and air quality models. This article presents measurements of NOx emission from the BT Tower in central London in 2017 and compares them with inventories, finding that they underestimate by a factor of ∼1.48.
Yihang Yu, Peng Cheng, Huirong Li, Wenda Yang, Baobin Han, Wei Song, Weiwei Hu, Xinming Wang, Bin Yuan, Min Shao, Zhijiong Huang, Zhen Li, Junyu Zheng, Haichao Wang, and Xiaofang Yu
Atmos. Chem. Phys., 22, 8951–8971, https://doi.org/10.5194/acp-22-8951-2022, https://doi.org/10.5194/acp-22-8951-2022, 2022
Short summary
Short summary
We have investigated the budget of HONO at an urban site in Guangzhou. Budget and comprehensive uncertainty analysis suggest that at such locations as ours, HONO direct emissions and NO + OH can become comparable or even surpass other HONO sources that typically receive greater attention and interest, such as the NO2 heterogeneous source and the unknown daytime photolytic source. Our findings emphasize the need to reduce the uncertainties of both conventional and novel HONO sources and sinks.
Wenjie Wang, David D. Parrish, Siwen Wang, Fengxia Bao, Ruijing Ni, Xin Li, Suding Yang, Hongli Wang, Yafang Cheng, and Hang Su
Atmos. Chem. Phys., 22, 8935–8949, https://doi.org/10.5194/acp-22-8935-2022, https://doi.org/10.5194/acp-22-8935-2022, 2022
Short summary
Short summary
Tropospheric ozone is an air pollutant that is detrimental to human health, vegetation and ecosystem productivity. A comprehensive characterisation of the spatial and temporal distribution of tropospheric ozone is critical to our understanding of these issues. Here we summarise this distribution over China from the available observational records to the extent possible. This study provides insights into efficient future ozone control strategies in China.
Lauriane L. J. Quéléver, Lubna Dada, Eija Asmi, Janne Lampilahti, Tommy Chan, Jonathan E. Ferrara, Gustavo E. Copes, German Pérez-Fogwill, Luis Barreira, Minna Aurela, Douglas R. Worsnop, Tuija Jokinen, and Mikko Sipilä
Atmos. Chem. Phys., 22, 8417–8437, https://doi.org/10.5194/acp-22-8417-2022, https://doi.org/10.5194/acp-22-8417-2022, 2022
Short summary
Short summary
Understanding how aerosols form is crucial for correctly modeling the climate and improving future predictions. This work provides extensive analysis of aerosol particles and their precursors at Marambio Station, Antarctic Peninsula. We show that sulfuric acid, ammonia, and dimethylamine are key contributors to the frequent new particle formation events observed at the site. We discuss nucleation mechanisms and highlight the need for targeted measurement to fully understand these processes.
Vanessa Selimovic, Damien Ketcherside, Sreelekha Chaliyakunnel, Catie Wielgasz, Wade Permar, Hélène Angot, Dylan B. Millet, Alan Fried, Detlev Helmig, and Lu Hu
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-396, https://doi.org/10.5194/acp-2022-396, 2022
Revised manuscript accepted for ACP
Short summary
Short summary
Arctic warming has led to an increase in plants that emit gases in response to stress, but how these gases affect regional chemistry is largely unknown due to lack of observational data. Here we present the most comprehensive gas phase measurements for this area to date and compare them to predictions from a global transport model. We report 78 gas phase species and investigate their importance to atmospheric chemistry in the area, with broader implications for similar plant types.
Xueli Liu, Liang Ran, Weili Lin, Xiaobin Xu, Zhiqiang Ma, Fan Dong, Di He, Liyan Zhou, Qingfeng Shi, and Yao Wang
Atmos. Chem. Phys., 22, 7071–7085, https://doi.org/10.5194/acp-22-7071-2022, https://doi.org/10.5194/acp-22-7071-2022, 2022
Short summary
Short summary
Significant decreases in annual mean NOx from 2011 to 2016 and SO2 from 2008 to 2016 confirm the effectiveness of relevant control measures on the reduction in NOx and SO2 emissions in the North China Plain (NCP). NOx at SDZ had a weaker influence than SO2 on the emission reduction in Beijing and other areas in the NCP. An increase in the number of motor vehicles and weak traffic restrictions have caused vehicle emissions of NOx, which indicates that NOx emission control should be strengthened.
Patrick Dewald, Clara M. Nussbaumer, Jan Schuladen, Akima Ringsdorf, Achim Edtbauer, Horst Fischer, Jonathan Williams, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 22, 7051–7069, https://doi.org/10.5194/acp-22-7051-2022, https://doi.org/10.5194/acp-22-7051-2022, 2022
Short summary
Short summary
We measured the gas-phase reactivity of the NO3 radical on the summit (825 m a.s.l.) of a semi-rural mountain in southwestern Germany in July 2021. The impact of VOC-induced NO3 losses (mostly monoterpenes) competing with a loss by reaction with NO and photolysis throughout the diel cycle was estimated. Besides chemistry, boundary layer dynamics and plant-physiological processes presumably have a great impact on our observations, which were compared to previous NO3 measurements at the same site.
Shigeyuki Ishidoya, Kazuhiro Tsuboi, Yosuke Niwa, Hidekazu Matsueda, Shohei Murayama, Kentaro Ishijima, and Kazuyuki Saito
Atmos. Chem. Phys., 22, 6953–6970, https://doi.org/10.5194/acp-22-6953-2022, https://doi.org/10.5194/acp-22-6953-2022, 2022
Short summary
Short summary
The atmospheric O2 / N2 ratio and CO2 concentration over the western North Pacific are presented. We found significant modification of the seasonal APO cycle in the middle troposphere due to the interhemispheric mixing of air. APO driven by the net marine biological activities indicated annual sea–air O2 flux during El Niño. Terrestrial biospheric and oceanic CO2 uptakes during 2012–2019 were estimated to be 1.8 and 2.8 Pg C a−1, respectively.
Xuefei Ma, Zhaofeng Tan, Keding Lu, Xinping Yang, Xiaorui Chen, Haichao Wang, Shiyi Chen, Xin Fang, Shule Li, Xin Li, Jingwei Liu, Ying Liu, Shengrong Lou, Wanyi Qiu, Hongli Wang, Limin Zeng, and Yuanhang Zhang
Atmos. Chem. Phys., 22, 7005–7028, https://doi.org/10.5194/acp-22-7005-2022, https://doi.org/10.5194/acp-22-7005-2022, 2022
Short summary
Short summary
This paper presents the first OH and HO2 radical observations made in the Yangtze River Delta in China, and strong oxidation capacity is discovered based on direct measurements. The impacts of new OH regeneration mechanisms, monoterpene oxidation, and HO2 uptake processes are examined and discussed. The sources and the factors to sustain such strong oxidation are the key to understanding the ozone pollution formed in this area.
Taku Umezawa, Satoshi Sugawara, Kenji Kawamura, Ikumi Oyabu, Stephen J. Andrews, Takuya Saito, Shuji Aoki, and Takakiyo Nakazawa
Atmos. Chem. Phys., 22, 6899–6917, https://doi.org/10.5194/acp-22-6899-2022, https://doi.org/10.5194/acp-22-6899-2022, 2022
Short summary
Short summary
Greenhouse gas methane in the Arctic atmosphere has not been accurately reported for 1900–1980 from either direct observations or ice core reconstructions. By using trace gas data from firn (compacted snow layers above ice sheet), air samples at two Greenland sites, and a firn air transport model, this study suggests a likely range of the Arctic methane reconstruction for the 20th century. Atmospheric scenarios from two previous studies are also evaluated for consistency with the firn data sets.
Susann Tegtmeier, Christa Marandino, Yue Jia, Birgit Quack, and Anoop S. Mahajan
Atmos. Chem. Phys., 22, 6625–6676, https://doi.org/10.5194/acp-22-6625-2022, https://doi.org/10.5194/acp-22-6625-2022, 2022
Short summary
Short summary
In the atmosphere over the Indian Ocean, intense anthropogenic pollution from Southeast Asia mixes with pristine oceanic air. During the winter monsoon, high pollution levels are regularly observed over the entire northern Indian Ocean, while during the summer monsoon, clean air dominates. Here, we review current progress in detecting and understanding atmospheric gas-phase composition over the Indian Ocean and its impacts on the upper atmosphere, oceanic biogeochemistry, and marine ecosystems.
Lian Zong, Yuanjian Yang, Haiyun Xia, Meng Gao, Zhaobin Sun, Zuofang Zheng, Xianxiang Li, Guicai Ning, Yubin Li, and Simone Lolli
Atmos. Chem. Phys., 22, 6523–6538, https://doi.org/10.5194/acp-22-6523-2022, https://doi.org/10.5194/acp-22-6523-2022, 2022
Short summary
Short summary
Heatwaves (HWs) paired with higher ozone (O3) concentration at surface level pose a serious threat to human health. Taking Beijing as an example, three unfavorable synoptic weather patterns were identified to dominate the compound HW and O3 pollution events. Under the synergistic stress of HWs and O3 pollution, public mortality risk increased, and synoptic patterns and urbanization enhanced the compound risk of events in Beijing by 33.09 % and 18.95 %, respectively.
Colm Sweeney, Abhishek Chatterjee, Sonja Wolter, Kathryn McKain, Robert Bogue, Stephen Conley, Tim Newberger, Lei Hu, Lesley Ott, Benjamin Poulter, Luke Schiferl, Brad Weir, Zhen Zhang, and Charles E. Miller
Atmos. Chem. Phys., 22, 6347–6364, https://doi.org/10.5194/acp-22-6347-2022, https://doi.org/10.5194/acp-22-6347-2022, 2022
Short summary
Short summary
The Arctic Carbon Atmospheric Profiles (Arctic-CAP) project demonstrates the utility of aircraft profiles for independent evaluation of model-derived emissions and uptake of atmospheric CO2, CH4, and CO from land and ocean. Comparison with the Goddard Earth Observing System (GEOS) modeling system suggests that fluxes of CO2 are very consistent with observations, while those of CH4 have some regional and seasonal biases, and that CO comparison is complicated by transport errors.
Roseline C. Thakur, Lubna Dada, Lisa J. Beck, Lauriane L. J. Quéléver, Tommy Chan, Marjan Marbouti, Xu-Cheng He, Carlton Xavier, Juha Sulo, Janne Lampilahti, Markus Lampimäki, Yee Jun Tham, Nina Sarnela, Katrianne Lehtipalo, Alf Norkko, Markku Kulmala, Mikko Sipilä, and Tuija Jokinen
Atmos. Chem. Phys., 22, 6365–6391, https://doi.org/10.5194/acp-22-6365-2022, https://doi.org/10.5194/acp-22-6365-2022, 2022
Short summary
Short summary
Every year intense cyanobacterial and macroalgal blooms occur in the Baltic Sea and in the coastal areas surrounding Helsinki, yet no studies have addressed the impact of biogenic emissions from these blooms on gas vapor concentrations, which in turn could influence new particle formation. This is the first study of its kind to address the chemistry driving new particle formation (NPF) during a bloom period in this region, highlighting the role of biogenic sulfuric acid and iodic acid.
Gordon A. Novak, Delaney B. Kilgour, Christopher M. Jernigan, Michael P. Vermeuel, and Timothy H. Bertram
Atmos. Chem. Phys., 22, 6309–6325, https://doi.org/10.5194/acp-22-6309-2022, https://doi.org/10.5194/acp-22-6309-2022, 2022
Short summary
Short summary
We describe field measurements of the mixing ratio and oceanic emission flux of dimethyl sulfide (DMS) and methanethiol (MeSH) from a coastal ocean site. DMS is known to impact aerosol formation and growth in the marine atmosphere, influencing cloud formation and climate. Measurements of MeSH, which is produced by the same oceanic source as DMS, are rare. We show that MeSH emissions are large and must be measured alongside DMS to understand marine sulfur chemistry and aerosol formation.
Yuting Zhu, Youfeng Wang, Xianliang Zhou, Yasin F. Elshorbany, Chunxiang Ye, Matthew Hayden, and Andrew J. Peters
Atmos. Chem. Phys., 22, 6327–6346, https://doi.org/10.5194/acp-22-6327-2022, https://doi.org/10.5194/acp-22-6327-2022, 2022
Short summary
Short summary
The daytime chemistry of nitrous acid (HONO), which plays an important role in the oxidation capacity of the troposphere, is not well understood. In this work, we report new field measurement results of HONO and the relevant parameters in the marine boundary layer at Tudor Hill Marine Atmospheric Observatory in Bermuda. We evaluate the daytime HONO budgets in air masses under different types of interaction with the island and examine the strengths of different HONO formation and loss mechanisms.
Clara M. Nussbaumer, Andrea Pozzer, Ivan Tadic, Lenard Röder, Florian Obersteiner, Hartwig Harder, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 22, 6151–6165, https://doi.org/10.5194/acp-22-6151-2022, https://doi.org/10.5194/acp-22-6151-2022, 2022
Short summary
Short summary
The European COVID-19 lockdowns have significantly reduced the emission of primary pollutants such as NOx, which impacts the tropospheric photochemical processes and the abundance of O3. In this study, we present how the lockdowns have affected tropospheric trace gases and ozone production based on in situ observations and modeling simulations. We additionally show that the chemical regime shifted from a transition point to a NOx limitation in the upper troposphere.
M. Dolores Andrés Hernández, Andreas Hilboll, Helmut Ziereis, Eric Förster, Ovid O. Krüger, Katharina Kaiser, Johannes Schneider, Francesca Barnaba, Mihalis Vrekoussis, Jörg Schmidt, Heidi Huntrieser, Anne-Marlene Blechschmidt, Midhun George, Vladyslav Nenakhov, Theresa Harlass, Bruna A. Holanda, Jennifer Wolf, Lisa Eirenschmalz, Marc Krebsbach, Mira L. Pöhlker, Anna B. Kalisz Hedegaard, Linlu Mei, Klaus Pfeilsticker, Yangzhuoran Liu, Ralf Koppmann, Hans Schlager, Birger Bohn, Ulrich Schumann, Andreas Richter, Benjamin Schreiner, Daniel Sauer, Robert Baumann, Mariano Mertens, Patrick Jöckel, Markus Kilian, Greta Stratmann, Christopher Pöhlker, Monica Campanelli, Marco Pandolfi, Michael Sicard, José L. Gómez-Amo, Manuel Pujadas, Katja Bigge, Flora Kluge, Anja Schwarz, Nikos Daskalakis, David Walter, Andreas Zahn, Ulrich Pöschl, Harald Bönisch, Stephan Borrmann, Ulrich Platt, and John P. Burrows
Atmos. Chem. Phys., 22, 5877–5924, https://doi.org/10.5194/acp-22-5877-2022, https://doi.org/10.5194/acp-22-5877-2022, 2022
Short summary
Short summary
EMeRGe provides a unique set of in situ and remote sensing airborne measurements of trace gases and aerosol particles along selected flight routes in the lower troposphere over Europe. The interpretation uses also complementary collocated ground-based and satellite measurements. The collected data help to improve the current understanding of the complex spatial distribution of trace gases and aerosol particles resulting from mixing, transport, and transformation of pollution plumes over Europe.
Lisa Kaser, Arianna Peron, Martin Graus, Marcus Striednig, Georg Wohlfahrt, Stanislav Juráň, and Thomas Karl
Atmos. Chem. Phys., 22, 5603–5618, https://doi.org/10.5194/acp-22-5603-2022, https://doi.org/10.5194/acp-22-5603-2022, 2022
Short summary
Short summary
Biogenic volatile organic compounds (e.g., terpenoids) play an essential role in atmospheric chemistry. Urban greening activities need to consider the ozone- and aerosol-forming potential of these compounds released from vegetation. NMVOC emissions in urban environments are complex, and the biogenic component remains poorly quantified. For summer conditions biogenic emissions dominate terpene emissions and heat waves can significantly modulate urban biogenic terpenoid emissions.
Hannah Walker, Daniel Stone, Trevor Ingham, Sina Hackenberg, Danny Cryer, Shalini Punjabi, Katie Read, James Lee, Lisa Whalley, Dominick V. Spracklen, Lucy J. Carpenter, Steve R. Arnold, and Dwayne E. Heard
Atmos. Chem. Phys., 22, 5535–5557, https://doi.org/10.5194/acp-22-5535-2022, https://doi.org/10.5194/acp-22-5535-2022, 2022
Short summary
Short summary
Glyoxal is a ubiquitous reactive organic compound in the atmosphere, which may form organic aerosol and impact the atmosphere's oxidising capacity. There are limited measurements of glyoxal's abundance in the remote marine atmosphere. We made new measurements of glyoxal using a highly sensitive technique over two 4-week periods in the tropical Atlantic atmosphere. We show that daytime measurements are mostly consistent with our chemical understanding but a potential missing source at night.
Marcel Zauner-Wieczorek, Martin Heinritzi, Manuel Granzin, Timo Keber, Andreas Kürten, Katharina Kaiser, Johannes Schneider, and Joachim Curtius
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-238, https://doi.org/10.5194/acp-2022-238, 2022
Revised manuscript accepted for ACP
Short summary
Short summary
We present measurements of ambient ions in the free troposphere and lower stratosphere over Europe in spring 2020. We observed nitrate and hydrogen sulfate, amongst others. From their ratio, the number concentrations of gaseous sulfuric acid were inferred. Nitrate increased towards the stratosphere, whilst sulfuric acid was slightly decreased there. The average values for sulfuric acid were 1.8 to 9.1E5 cm–3. Protonated pyridine was identified in an altitude range of 4.6 to 8.5 km.
Haklim Choi, Mi-Kyung Park, Paul J. Fraser, Hyeri Park, Sohyeon Geum, Jens Mühle, Jooil Kim, Ian Porter, Peter K. Salameh, Christina M. Harth, Bronwyn L. Dunse, Paul B. Krummel, Ray F. Weiss, Simon O'Doherty, Dickon Young, and Sunyoung Park
Atmos. Chem. Phys., 22, 5157–5173, https://doi.org/10.5194/acp-22-5157-2022, https://doi.org/10.5194/acp-22-5157-2022, 2022
Short summary
Short summary
We observed 12-year continuous CH3Br pollution signals at Gosan and estimated anthropogenic CH3Br emissions in eastern China. The analysis revealed a significant discrepancy between top-down estimates and the bottom-up emissions from the fumigation usage reported to the United Nations Environment Programme, likely due to unreported or inaccurately reported fumigation usage. This result provides information to monitor international compliance with the Montreal Protocol.
Shenglun Wu, Hyung Joo Lee, Andrea Anderson, Shang Liu, Toshihiro Kuwayama, John H. Seinfeld, and Michael J. Kleeman
Atmos. Chem. Phys., 22, 4929–4949, https://doi.org/10.5194/acp-22-4929-2022, https://doi.org/10.5194/acp-22-4929-2022, 2022
Short summary
Short summary
An ozone control experiment usually conducted in the laboratory was installed in a trailer and moved to the outdoor environment to directly confirm that we are controlling the right sources in order to lower ambient ozone concentrations. Adding small amounts of precursor oxides of nitrogen and volatile organic compounds to ambient air showed that the highest ozone concentrations are best controlled by reducing concentrations of oxides of nitrogen. The results confirm satellite measurements.
Katherine Hayden, Shao-Meng Li, John Liggio, Michael Wheeler, Jeremy Wentzell, Amy Leithead, Peter Brickell, Richard Mittermeier, Zachary Oldham, Cris Mihele, Ralf Staebler, Samar Moussa, Andrea Darlington, Alexandra Steffen, Mengistu Wolde, Daniel Thompson, Jack Chen, Debora Griffin, Ellen Eckert, Jenna Ditto, Megan He, and Drew Gentner
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-245, https://doi.org/10.5194/acp-2022-245, 2022
Revised manuscript accepted for ACP
Short summary
Short summary
In this study, airborne measurements provided the most detailed characterization, to date, of boreal forest wildfire emissions. Measurements showed a large diversity of air pollutants expanding the volatility range typically reported. A large portion of organic species was unidentified, likely comprised of complex organic compounds. Aircraft-derived emissions improve wildfire chemical speciation and can support reliable model predictions of pollution from boreal forest wildfires.
Andrew J. Lindsay, Daniel C. Anderson, Rebecca A. Wernis, Yutong Liang, Allen H. Goldstein, Scott C. Herndon, Joseph R. Roscioli, Christoph Dyroff, Ed C. Fortner, Philip L. Croteau, Francesca Majluf, Jordan E. Krechmer, Tara I. Yacovitch, Walter B. Knighton, and Ezra C. Wood
Atmos. Chem. Phys., 22, 4909–4928, https://doi.org/10.5194/acp-22-4909-2022, https://doi.org/10.5194/acp-22-4909-2022, 2022
Short summary
Short summary
Wildfire smoke dramatically impacts air quality and often has elevated concentrations of ozone. We present measurements of ozone and its precursors at a rural site periodically impacted by wildfire smoke. Measurements of total peroxy radicals, key ozone precursors that have been studied little within wildfires, compare well with chemical box model predictions. Our results indicate no serious issues with using current chemistry mechanisms to model chemistry in aged wildfire plumes.
Kun Zhang, Zhiqiang Liu, Xiaojuan Zhang, Qing Li, Andrew Jensen, Wen Tan, Ling Huang, Yangjun Wang, Joost de Gouw, and Li Li
Atmos. Chem. Phys., 22, 4853–4866, https://doi.org/10.5194/acp-22-4853-2022, https://doi.org/10.5194/acp-22-4853-2022, 2022
Short summary
Short summary
A significant increase in O3 concentrations was found during the lockdown period of COVID-19 in most areas of China. By field measurements coupled with machine learning, an observation-based model (OBM) and sensitivity analysis, we found the changes in the NOx / VOC ratio were a key reason for the significant rise in O3. To restrain O3 pollution, more efforts should be devoted to the control of anthropogenic OVOCs, alkenes and aromatics.
Amy Foulds, Grant Allen, Jacob T. Shaw, Prudence Bateson, Patrick A. Barker, Langwen Huang, Joseph R. Pitt, James D. Lee, Shona E. Wilde, Pamela Dominutti, Ruth M. Purvis, David Lowry, James L. France, Rebecca E. Fisher, Alina Fiehn, Magdalena Pühl, Stéphane J. B. Bauguitte, Stephen A. Conley, Mackenzie L. Smith, Tom Lachlan-Cope, Ignacio Pisso, and Stefan Schwietzke
Atmos. Chem. Phys., 22, 4303–4322, https://doi.org/10.5194/acp-22-4303-2022, https://doi.org/10.5194/acp-22-4303-2022, 2022
Short summary
Short summary
We measured CH4 emissions from 21 offshore oil and gas facilities in the Norwegian Sea in 2019. Measurements compared well with operator-reported emissions but were greatly underestimated when compared with a 2016 global fossil fuel inventory. This study demonstrates the need for up-to-date and accurate inventories for use in research and policy and the important benefits of best-practice reporting methods by operators. Airborne measurements are an effective tool to validate such inventories.
Hisahiro Takashima, Yugo Kanaya, Saki Kato, Martina M. Friedrich, Michel Van Roozendael, Fumikazu Taketani, Takuma Miyakawa, Yuichi Komazaki, Carlos A. Cuevas, Alfonso Saiz-Lopez, and Takashi Sekiya
Atmos. Chem. Phys., 22, 4005–4018, https://doi.org/10.5194/acp-22-4005-2022, https://doi.org/10.5194/acp-22-4005-2022, 2022
Short summary
Short summary
We have undertaken atmospheric iodine monoxide (IO) observations in the global marine boundary layer with a wide latitudinal coverage and sea surface temperature (SST) range. We conclude that atmospheric iodine is abundant over the Western Pacific warm pool, appearing as an iodine fountain, where ozone (O3) minima occur. Our study also found negative correlations between IO and O3 concentrations over IO maxima, which requires reconsideration of the initiation process of halogen activation.
Wenjie Wang, Bin Yuan, Yuwen Peng, Hang Su, Yafang Cheng, Suxia Yang, Caihong Wu, Jipeng Qi, Fengxia Bao, Yibo Huangfu, Chaomin Wang, Chenshuo Ye, Zelong Wang, Baolin Wang, Xinming Wang, Wei Song, Weiwei Hu, Peng Cheng, Manni Zhu, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 22, 4117–4128, https://doi.org/10.5194/acp-22-4117-2022, https://doi.org/10.5194/acp-22-4117-2022, 2022
Short summary
Short summary
From thorough measurements of numerous oxygenated volatile organic compounds, we show that their photodissociation can be important for radical production and ozone formation in the atmosphere. This effect was underestimated in previous studies, as measurements of them were lacking.
Helen L. Fitzmaurice, Alexander J. Turner, Jinsol Kim, Katherine Chan, Erin R. Delaria, Catherine Newman, Paul Wooldridge, and Ronald C. Cohen
Atmos. Chem. Phys., 22, 3891–3900, https://doi.org/10.5194/acp-22-3891-2022, https://doi.org/10.5194/acp-22-3891-2022, 2022
Short summary
Short summary
On-road emissions are thought to vary widely from existing predictions, as the effects of the age of the vehicle fleet, the performance of emission control systems, and variations in speed are difficult to assess under ambient driving conditions. We present an observational approach to characterize on-road emissions and show that the method is consistent with other approaches to within ~ 3 %.
Danilo Custódio, Katrine Aspmo Pfaffhuber, T. Gerard Spain, Fidel F. Pankratov, Iana Strigunova, Koketso Molepo, Henrik Skov, Johannes Bieser, and Ralf Ebinghaus
Atmos. Chem. Phys., 22, 3827–3840, https://doi.org/10.5194/acp-22-3827-2022, https://doi.org/10.5194/acp-22-3827-2022, 2022
Short summary
Short summary
As a poison in the air that we breathe and the food that we eat, mercury is a human health concern for society as a whole. In that regard, this work deals with monitoring and modelling mercury in the environment, improving wherewithal, identifying the strength of the different components at play, and interpreting information to support the efforts that seek to safeguard public health.
Xiaorui Chen, Haichao Wang, and Keding Lu
Atmos. Chem. Phys., 22, 3525–3533, https://doi.org/10.5194/acp-22-3525-2022, https://doi.org/10.5194/acp-22-3525-2022, 2022
Short summary
Short summary
We use a complete set of simulations to evaluate whether equilibrium and steady state are appropriate for a chemical system involving several reactive nitrogen-containing species (NO2, NO3, and N2O5) under various conditions. A previously neglected bias for the coefficient applied for interpreting their effects is disclosed, and the relevant ambient factors are examined. We therefore provide a good solution to an accurate representation of nighttime chemistry in high-aerosol areas.
Jens Mühle, Lambert J. M. Kuijpers, Kieran M. Stanley, Matthew Rigby, Luke M. Western, Jooil Kim, Sunyoung Park, Christina M. Harth, Paul B. Krummel, Paul J. Fraser, Simon O'Doherty, Peter K. Salameh, Roland Schmidt, Dickon Young, Ronald G. Prinn, Ray H. J. Wang, and Ray F. Weiss
Atmos. Chem. Phys., 22, 3371–3378, https://doi.org/10.5194/acp-22-3371-2022, https://doi.org/10.5194/acp-22-3371-2022, 2022
Short summary
Short summary
Emissions of the strong greenhouse gas perfluorocyclobutane (c-C4F8) into the atmosphere have been increasing sharply since the early 2000s. These c-C4F8 emissions are highly correlated with the amount of hydrochlorofluorocarbon-22 produced to synthesize polytetrafluoroethylene (known for its non-stick properties) and related chemicals. From this process, c-C4F8 by-product is vented to the atmosphere. Avoiding these unnecessary c-C4F8 emissions could reduce the climate impact of this industry.
Chaoyang Xue, Can Ye, Jörg Kleffmann, Chenglong Zhang, Valéry Catoire, Fengxia Bao, Abdelwahid Mellouki, Likun Xue, Jianmin Chen, Keding Lu, Yong Zhao, Hengde Liu, Zhaoxin Guo, and Yujing Mu
Atmos. Chem. Phys., 22, 3149–3167, https://doi.org/10.5194/acp-22-3149-2022, https://doi.org/10.5194/acp-22-3149-2022, 2022
Short summary
Short summary
Summertime measurements of nitrous acid (HONO) and related parameters were conducted at the foot and the summit of Mt. Tai (1534 m above sea level). We proposed a rapid vertical air mass exchange between the foot and the summit level, which enhances the role of HONO in the oxidizing capacity of the upper boundary layer. Kinetics for aerosol-derived HONO sources were constrained. HONO formation from different paths was quantified and discussed.
Kathryn D. Kulju, Stephen M. McNamara, Qianjie Chen, Hannah S. Kenagy, Jacinta Edebeli, Jose D. Fuentes, Steven B. Bertman, and Kerri A. Pratt
Atmos. Chem. Phys., 22, 2553–2568, https://doi.org/10.5194/acp-22-2553-2022, https://doi.org/10.5194/acp-22-2553-2022, 2022
Short summary
Short summary
N2O5 uptake by chloride-containing surfaces produces ClNO2, which photolyzes, producing NO2 and highly reactive Cl radicals that impact air quality. In the inland urban atmosphere, ClNO2 was elevated during lower air turbulence and over snow-covered ground, from snowpack ClNO2 production. N2O5 and ClNO2 levels were lowest, on average, during rainfall and fog because of scavenging, with N2O5 scavenging by fog droplets likely contributing to observed increased particulate nitrate concentrations.
Huiming Lin, Yindong Tong, Chenghao Yu, Long Chen, Xiufeng Yin, Qianggong Zhang, Shichang Kang, Lun Luo, James Schauer, Benjamin de Foy, and Xuejun Wang
Atmos. Chem. Phys., 22, 2651–2668, https://doi.org/10.5194/acp-22-2651-2022, https://doi.org/10.5194/acp-22-2651-2022, 2022
Short summary
Short summary
The Tibetan Plateau is known as
The Third Poleand is generally considered to be a clean area owing to its high altitude. However, it may receive be impacted by air pollutants transported from the Indian subcontinent. Pollutants generally enter the Tibetan Plateau in several ways. Among them is the Yarlung Zangbu–Brahmaputra Grand Canyon. In this study, we identified the influence of the Indian summer monsoon on the origin, transport, and behavior of mercury in this area.
Dominique Rust, Ioannis Katharopoulos, Martin K. Vollmer, Stephan Henne, Simon O'Doherty, Daniel Say, Lukas Emmenegger, Renato Zenobi, and Stefan Reimann
Atmos. Chem. Phys., 22, 2447–2466, https://doi.org/10.5194/acp-22-2447-2022, https://doi.org/10.5194/acp-22-2447-2022, 2022
Short summary
Short summary
Artificial halocarbons contribute to ozone layer depletion and to global warming. We measured the atmospheric concentrations of halocarbons at the Beromünster tower, modelled the Swiss emissions, and compared the results to the internationally reported Swiss emissions inventory. For most of the halocarbons, we found good agreement, whereas one refrigerant might be overestimated in the inventory. In addition, we present first emission estimates of the newest types of halocarbons.
Xinping Yang, Keding Lu, Xuefei Ma, Yue Gao, Zhaofeng Tan, Haichao Wang, Xiaorui Chen, Xin Li, Xiaofeng Huang, Lingyan He, Mengxue Tang, Bo Zhu, Shiyi Chen, Huabin Dong, Limin Zeng, and Yuanhang Zhang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-113, https://doi.org/10.5194/acp-2022-113, 2022
Revised manuscript accepted for ACP
Short summary
Short summary
The STORM campaign was carried out at Shenzhen site in autumn 2018. The maximum diurnal OH and HO2 concentrations were 4.5 × 106 cm−3 and 4.5 × 108 cm−3, respectively. The unclassical OH recycling was identified again. AOC exhibited well-defined diurnal patterns, and OH was the dominant oxidant as expected. The strong positive correlation between F(O3) and AOC makes the quantification of F(O3) achieved, indicating AOC is the core driving force for the generation of secondary pollutants.
Tuija Jokinen, Katrianne Lehtipalo, Roseline Cutting Thakur, Ilona Ylivinkka, Kimmo Neitola, Nina Sarnela, Totti Laitinen, Markku Kulmala, Tuukka Petäjä, and Mikko Sipilä
Atmos. Chem. Phys., 22, 2237–2254, https://doi.org/10.5194/acp-22-2237-2022, https://doi.org/10.5194/acp-22-2237-2022, 2022
Short summary
Short summary
New particle formation is an important source of cloud condensation nuclei; however, long-term measurements of aerosol-forming vapors are close to nonexistent in the Arctic. Here, we report 7 months of CI-APi-TOF measurements of sulfuric acid, iodic acid, methane sulfonic acid and the sum of highly oxygenated organic molecules from the SMEAR I station in the Finnish subarctic. The results help us to understand atmospheric chemical processes and aerosol formation in this rapidly changing area.
Cited articles
Butler, J. H., King, D. B., Lobert, J. M., Montzka, S. A., Yvon-Lewis, S. A., Hall, B. D., Warwick, N. J., Mondeel, D. J., Aydin, M., and Elkins, J. W.: Oceanic distributions and emissions of short-lived halocarbons, Global Biogeochem. Cy., 21, GB1023, https://doi.org/10.1029/2006GB002732, 2007.
Carpenter, L., Liss, P., and Penkett, S.: Marine organohalogens in the atmosphere over the Atlantic and Southern Oceans, J. Geophys. Res.-Atmos., 108, 4256, https://doi.org/10.1029/2002JD002769, 2003.
Carpenter, L., Fleming, Z., Read, K., Lee, J., Moller, S., Hopkins, J., Purvis, R., Lewis, A., Muller, K., Heinold, B., Herrmann, H., Fomba, K., van Pinxteren, D., Muller, C., Tegen, I., Wiedensohler, A., Muller, T., Niedermeier, N., Achterberg, E., Patey, M., Kozlova, E., Heimann, M., Heard, D., Plane, J., Mahajan, A., Oetjen, H., Ingham, T., Stone, D., Whalley, L., Evans, M., Pilling, M., Leigh, R., Monks, P., Karunaharan, A., Vaughan, S., Arnold, S., Tschritter, J., Pohler, D., Friess, U., Holla, R., Mendes, L., Lopez, H., Faria, B., Manning, A., and Wallace, D.: Seasonal characteristics of tropical marine boundary layer air measured at the Cape Verde Atmospheric Observatory, J. Atmos. Chem., 67, 87–140, 2010.
Carpenter, L. J. and Liss, P. S.: On temperate sources of bromoform and other reactive organic bromine gases, J. Geophys. Res., 105, 20539–20547, 2000.
Carpenter, L. J., Wevill, D. J., O'Doherty, S., Spain, G., and Simmonds, P. G.: Atmospheric bromoform at Mace Head, Ireland: seasonality and evidence for a peatland source, Atmos. Chem. Phys., 5, 2927–2934, https://doi.org/10.5194/acp-5-2927-2005, 2005.
Carpenter, L. J., Reimann, S., Burkholder, J. B., Clerbaux, C., Hall, B. D., Hossaini, R., Laube, J. C., and Yvon-Lewis, S. A.: Update on Ozone-Depleting Substances (ODSs) and Other Gases of Interest to the Montreal Protocol, in: Scientific Assessment of Ozone Depletion: 2014, edited by: Engel, A. and Montzka, S. A., World Meteorological Organization, Geneva, 2014.
Codispoti, L. A., Dugdale, R. C., and Minas, H. J.: A comparison of the nutrient regimes off Northwest Africa, Peru and Baja California, Rapports et Proces-Verbaux Reunions, International Council for the Exploration of the Sea, Copenhagen, Vol. 180, 184–201, 1982.
Dee, D. P., Uppala, S. M., Simmons, A. J., Berrisford, P., Poli, P., Kobayashi, S., Andrae, U., Balmaseda, M. A., Balsamo, G., Bauer, P., Bechtold, P., Beljaars, A. C. M., van de Berg, L., Bidlot, J., Bormann, N., Delsol, C., Dragani, R., Fuentes, M., Geer, A. J., Haimberger, L., Healy, S. B., Hersbach, H., Hólm, E. V., Isaksen, L., Kållberg, P., Köhler, M., Matricardi, M., McNally, A. P., Monge-Sanz, B. M., Morcrette, J.-J., Park, B.-K., Peubey, C., de Rosnay, P., Tavolato, C., Thépaut, J.-N. and Vitart, F.: The ERA-Interim reanalysis: configuration and performance of the data assimilation system, Q. J. Roy. Meteor. Soc., 137, 553–597, https://doi.org/10.1002/qj.828, 2011.
Forster, C., Stohl, A., and Seibert, P.: Parameterization of convective transport in a Lagrangian particle dispersion model and its evaluation, J. Appl. Meteorol. Clim., 46, 403–422, 2007.
Fuhlbrügge, S., Krüger, K., Quack, B., Atlas, E., Hepach, H., and Ziska, F.: Impact of the marine atmospheric boundary layer conditions on VSLS abundances in the eastern tropical and subtropical North Atlantic Ocean, Atmos. Chem. Phys., 13, 6345–6357, https://doi.org/10.5194/acp-13-6345-2013, 2013.
Fuhlbrügge, S., Quack, B., Tegtmeier, S., Atlas, E., Hepach, H., Shi, Q., Raimund, S., and Krüger, K.: The contribution of oceanic halocarbons to marine and free tropospheric air over the tropical West Pacific, Atmos. Chem. Phys., 16, 7569–7585, https://doi.org/10.5194/acp-16-7569-2016, 2016.
Garreaud, R. and Munoz, R.: The low-level jet off the west coast of subtropical South America: Structure and variability, Mon. Weather Rev., 133, 2246–2261, 2005.
Gómez Martin, J., Mahajan, A., Hay, T., Prados-Roman, C., Ordonez, C., MacDonald, S., Plane, J., Sorribas, M., Gil, M., Mora, J., Reyes, M., Oram, D., Leedham, E., and Saiz-Lopez, A.: Iodine chemistry in the eastern Pacific marine boundary layer, J. Geophys. Res.-Atmos., 118, 887–904, 2013.
Hepach, H., Quack, B., Ziska, F., Fuhlbrügge, S., Atlas, E. L., Krüger, K., Peeken, I., and Wallace, D. W. R.: Drivers of diel and regional variations of halocarbon emissions from the tropical North East Atlantic, Atmos. Chem. Phys., 14, 1255–1275, https://doi.org/10.5194/acp-14-1255-2014, 2014.
Hepach, H., Quack, B., Raimund, S., Fischer, T., Atlas, E. L., and Bracher, A.: Halocarbon emissions and sources in the equatorial Atlantic Cold Tongue, Biogeosciences, 12, 6369–6387, https://doi.org/10.5194/bg-12-6369-2015, 2015.
Hepach, H., Quack, B., Tegtmeier, S., Engel, A., Bracher, A., Fuhlbrügge, S., Galgani, L., Atlas, E. L., Lampel, J., Frieß, U., and Krüger, K.: Biogenic halocarbons from the Peruvian upwelling region as tropospheric halogen source, Atmos. Chem. Phys., 16, 12219–12237, https://doi.org/10.5194/acp-16-12219-2016, 2016.
Höflich, O.: The meteorological effects of cold upwelling water areas, Geoforum, 3, 35–46, 1972.
Leedham, E. C., Hughes, C., Keng, F. S. L., Phang, S.-M., Malin, G., and Sturges, W. T.: Emission of atmospherically significant halocarbons by naturally occurring and farmed tropical macroalgae, Biogeosciences, 10, 3615–3633, https://doi.org/10.5194/bg-10-3615-2013, 2013.
Lennartz, S. T., Krysztofiak, G., Marandino, C. A., Sinnhuber, B.-M., Tegtmeier, S., Ziska, F., Hossaini, R., Krüger, K., Montzka, S. A., Atlas, E., Oram, D. E., Keber, T., Bönisch, H., and Quack, B.: Modelling marine emissions and atmospheric distributions of halocarbons and dimethyl sulfide: the influence of prescribed water concentration vs. prescribed emissions, Atmos. Chem. Phys., 15, 11753–11772, https://doi.org/10.5194/acp-15-11753-2015, 2015.
Liu, Y., Yvon-Lewis, S., Thornton, D., Butler, J., Bianchi, T., Campbell, L., Hu, L., and Smith, R.: Spatial and temporal distributions of bromoform and dibromomethane in the Atlantic Ocean and their relationship with photosynthetic biomass, J. Geophys. Res.-Oceans, 118, 3950–3965, 2013.
Mahajan, A. S., Gómez Martín, J. C., Hay, T. D., Royer, S.-J., Yvon-Lewis, S., Liu, Y., Hu, L., Prados-Roman, C., Ordóñez, C., Plane, J. M. C., and Saiz-Lopez, A.: Latitudinal distribution of reactive iodine in the Eastern Pacific and its link to open ocean sources, Atmos. Chem. Phys., 12, 11609–11617, https://doi.org/10.5194/acp-12-11609-2012, 2012.
McGivern, W., Sorkhabi, O., Suits, A., Derecskei-Kovacs, A., and North, S.: Primary and secondary processes in the photodissociation of CHBr3, J. Phys. Chem. A, 104, 10085–10091, 2000.
Nightingale, P., Malin, G., Law, C., Watson, A., Liss, P., Liddicoat, M., Boutin, J., and Upstill-Goddard, R.: In situ evaluation of air-sea gas exchange parameterizations using novel conservative and volatile tracers, Global Biogeochem. Cy., 14, 373–387, 2000.
O'Brien, L. M., Harris, N. R. P., Robinson, A. D., Gostlow, B., Warwick, N., Yang, X., and Pyle, J. A.: Bromocarbons in the tropical marine boundary layer at the Cape Verde Observatory – measurements and modelling, Atmos. Chem. Phys., 9, 9083–9099, https://doi.org/10.5194/acp-9-9083-2009, 2009.
Quack, B. and Wallace, D. W. R.: Air-sea flux of bromoform: Controls, rates, and implications, Global Biogeochem. Cy., 17, 1023, https://doi.org/10.1029/2002GB001890, 2003.
Quack, B., Atlas, E., Petrick, G., Stroud, V., Schauffler, S., and Wallace, D.: Oceanic bromoform sources for the tropical atmosphere, Geophys. Res. Lett., 31, L23S05, https://doi.org/10.1029/2004GL020597, 2004.
Quack, B., Atlas, E., Petrick, G., and Wallace, D.: Bromoform and dibromomethane above the Mauritanian upwelling: Atmospheric distributions and oceanic emissions, J. Geophys. Res.-Atmos., 112, D09312, https://doi.org/10.1029/2006JD007614, 2007.
Raimund, S., Quack, B., Bozec, Y., Vernet, M., Rossi, V., Garçon, V., Morel, Y., and Morin, P.: Sources of short-lived bromocarbons in the Iberian upwelling system, Biogeosciences, 8, 1551–1564, https://doi.org/10.5194/bg-8-1551-2011, 2011.
Rasmussen, R., Khalil, M., Gunawardena, R., and Hoyt, S.: Atmospheric methyl-iodide (CH3I), J. Geophys. Res.-Oc. Atm., 87, 3086–3090, 1982.
Riehl, H.: Tropical meteorology, McGraw-Hill, New York-London, 1954.
Riehl, H.: Climate and Weather in the Tropics, Academic Press, London, 1979.
Saiz-Lopez, A. and von Glasow, R.: Reactive halogen chemistry in the troposphere, Chem. Soc. Rev., 41, 6448–6472, 2012.
Saiz-Lopez, A., Lamarque, J.-F., Kinnison, D. E., Tilmes, S., Ordóñez, C., Orlando, J. J., Conley, A. J., Plane, J. M. C., Mahajan, A. S., Sousa Santos, G., Atlas, E. L., Blake, D. R., Sander, S. P., Schauffler, S., Thompson, A. M., and Brasseur, G.: Estimating the climate significance of halogen-driven ozone loss in the tropical marine troposphere, Atmos. Chem. Phys., 12, 3939–3949, https://doi.org/10.5194/acp-12-3939-2012, 2012.
Schauffler, S., Atlas, E., Blake, D., Flocke, F., Lueb, R., Lee-Taylor, J., Stroud, V., and Travnicek, W.: Distributions of brominated organic compounds in the troposphere and lower stratosphere, J. Geophys. Res.-Atmos., 104, 21513–21535, 1999.
Schönhardt, A., Richter, A., Wittrock, F., Kirk, H., Oetjen, H., Roscoe, H. K., and Burrows, J. P.: Observations of iodine monoxide columns from satellite, Atmos. Chem. Phys., 8, 637–653, https://doi.org/10.5194/acp-8-637-2008, 2008.
Seibert, P., Beyrich, F., Gryning, S., Joffre, S., Rasmussen, A., and Tercier, P.: Review and intercomparison of operational methods for the determination of the mixing height, Atmos. Environ., 34, 1001–1027, 2000.
Simpson, W., Brown, S., Saiz-Lopez, A., Thornton, J., and von Glasow, R.: Tropospheric Halogen Chemistry: Sources, Cycling, and Impacts, Chemical Reviews Article ASAP, 115, 4035–4062, https://doi.org/10.1021/cr5006638, 2015.
Stohl, A. and Thomson, D.: A density correction for Lagrangian particle dispersion models, Bound.-Lay. Meteorol., 90, 155–167, 1999.
Stohl, A. and Trickl, T.: A textbook example of long-range transport: Simultaneous observation of ozone maxima of stratospheric and North American origin in the free troposphere over Europe, J. Geophys. Res.-Atmos., 104, 30445–30462, 1999.
Stohl, A., Hittenberger, M., and Wotawa, G.: Validation of the Lagrangian particle dispersion model FLEXPART against large-scale tracer experiment data, Atmos. Environ., 32, 4245–4264, 1998.
Stohl, A., Forster, C., Frank, A., Seibert, P., and Wotawa, G.: Technical note: The Lagrangian particle dispersion model FLEXPART version 6.2, Atmos. Chem. Phys., 5, 2461–2474, https://doi.org/10.5194/acp-5-2461-2005, 2005.
Stull, R.: An Introduction to Boundary Layer Meteorology, Kluwer Academic Publishers, Dordrecht, 1988.
Yokouchi, Y., Hasebe, F., Fujiwara, M., Takashima, H., Shiotani, M., Nishi, N., Kanaya, Y., Hashimoto, S., Fraser, P., Toom-Sauntry, D., Mukai, H., and Nojiri, Y.: Correlations and emission ratios among bromoform, dibromochloromethane, and dibromomethane in the atmosphere, J. Geophys. Res.-Atmos., 110, D23309, https://doi.org/10.1029/2005JD006303, 2005.
Yokouchi, Y., Osada, K., Wada, M., Hasebe, F., Agama, M., Murakami, R., Mukai, H., Nojiri, Y., Inuzuka, Y., Toom-Sauntry, D., and Fraser, P.: Global distribution and seasonal concentration change of methyl iodide in the atmosphere, J. Geophys. Res.-Atmos., 113, D18311, https://doi.org/10.1029/2008JD009861, 2008.
Ziska, F., Quack, B., Abrahamsson, K., Archer, S. D., Atlas, E., Bell, T., Butler, J. H., Carpenter, L. J., Jones, C. E., Harris, N. R. P., Hepach, H., Heumann, K. G., Hughes, C., Kuss, J., Krüger, K., Liss, P., Moore, R. M., Orlikowska, A., Raimund, S., Reeves, C. E., Reifenhäuser, W., Robinson, A. D., Schall, C., Tanhua, T., Tegtmeier, S., Turner, S., Wang, L., Wallace, D., Williams, J., Yamamoto, H., Yvon-Lewis, S., and Yokouchi, Y.: Global sea-to-air flux climatology for bromoform, dibromomethane and methyl iodide, Atmos. Chem. Phys., 13, 8915–8934, https://doi.org/10.5194/acp-13-8915-2013, 2013.
Short summary
This study presents novel observations of the very short lived substances (VSLSs) bromoform, dibromomethane and methyl iodide with high-resolution meteorological measurements and Lagrangian transport in the Peruvian upwelling. With a simple source–loss estimate we identified VSLS abundances below the trade inversion to be significantly influenced by advection of regional sources, underscoring the importance of oceanic upwelling and trade winds on the atmospheric distribution of VSLS emission.
This study presents novel observations of the very short lived substances (VSLSs) bromoform,...
Altmetrics
Final-revised paper
Preprint