Articles | Volume 15, issue 18
https://doi.org/10.5194/acp-15-10669-2015
https://doi.org/10.5194/acp-15-10669-2015
Research article
 | 
25 Sep 2015
Research article |  | 25 Sep 2015

Influence of crustal dust and sea spray supermicron particle concentrations and acidity on inorganic NO3 aerosol during the 2013 Southern Oxidant and Aerosol Study

H. M. Allen, D. C. Draper, B. R. Ayres, A. Ault, A. Bondy, S. Takahama, R. L. Modini, K. Baumann, E. Edgerton, C. Knote, A. Laskin, B. Wang, and J. L. Fry

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Cited articles

Arimoto, R., Ray, B. J., Lewis, N. F., Tomza, U., and Duce, R. A.: Mass-particle size distributions of atmospheric dust and the dry deposition of dust to the remote ocean, J. Geophys. Res.-Atmos., 102, 15867–15874, 1997.
Ault, A. P., Peters, T. M., Sawvel, E. J., Casuccio, G. S., Willis, R. D., Norris, G. A., and Grassian, V. H.: Single-particle SEM-EDX analysis of iron-containing coarse particulate matter in an urban environment: sources and distribution of iron within Cleveland, Ohio, Environ. Sci. Technol., 46, 4331–4339, 2012.
Ault, A. P., Guasco, T. L., Ryder, O. S., Baltrusaitis, J. Cuadra-Rodriguez, L. A., Collins, D. B., Ruppel, M. J., Bertram, T. H., Prather, K. A., and Grassian, V. H.: Inside versus outside: Ion redistribution in nitric acid reacted sea spray aerosol particles as determined by single-particle analysis, J. Am. Chem. Soc., 135, 14528–14531, 2013a.
Ault, A. P., Moffet, R. C., Baltrusaitis, J., Collins, D. B., Ruppel, M. J., Cuadra-Rodriguez, L. A., Zhao, D., Guasco, T. L., Ebben, C. J., Geiger, F. M., Bertram, T. H., Prather, K. A., and Grassian, V. H.: Size-dependent changes in sea spray aerosol composition and properties with different seawater conditions, Environ. Sci. Technol., 47, 5603–5612, 2013b.
Short summary
We report ion chromatographic measurements of gas- and aerosol-phase inorganic species at the SOAS 2013 field study. Our particular focus is on inorganic nitrate aerosol formation via HNO3 uptake onto coarse-mode dust and sea salt particles, which we find to be the dominant source of episodic inorganic nitrate at this site, due to the high acidity of the particles preventing formation of NH4NO3. We calculate a production rate of inorganic nitrate aerosol.
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