Articles | Volume 15, issue 18
https://doi.org/10.5194/acp-15-10669-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-10669-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Influence of crustal dust and sea spray supermicron particle concentrations and acidity on inorganic NO3− aerosol during the 2013 Southern Oxidant and Aerosol Study
H. M. Allen
now at: Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA, USA
Department of Chemistry, Reed College, Portland, OR, USA
D. C. Draper
Department of Chemistry, Reed College, Portland, OR, USA
now at: Department of Chemistry, University of California, Irvine, CA, USA
B. R. Ayres
Department of Chemistry, Reed College, Portland, OR, USA
Department of Environmental Health Sciences, University of Michigan, Ann Arbor, MI, USA
Department of Chemistry, University of Michigan, Ann Arbor, MI, USA
A. Bondy
Department of Chemistry, University of Michigan, Ann Arbor, MI, USA
S. Takahama
École Polytechnique Fèdèrale de Lausanne, Lausanne, Switzerland
R. L. Modini
École Polytechnique Fèdèrale de Lausanne, Lausanne, Switzerland
K. Baumann
Atmospheric Research & Analysis, Inc., Cary, NC, USA
E. Edgerton
Atmospheric Research & Analysis, Inc., Cary, NC, USA
C. Knote
Meteorologisches Institut, Ludwig-Maximilians-Universität, Munich, Germany
A. Laskin
William R. Wiley Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA, USA
B. Wang
William R. Wiley Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA, USA
Department of Chemistry, Reed College, Portland, OR, USA
Viewed
Total article views: 5,114 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 13 May 2015)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
2,772 | 1,921 | 421 | 5,114 | 519 | 96 | 131 |
- HTML: 2,772
- PDF: 1,921
- XML: 421
- Total: 5,114
- Supplement: 519
- BibTeX: 96
- EndNote: 131
Total article views: 4,174 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 25 Sep 2015)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
2,393 | 1,376 | 405 | 4,174 | 358 | 85 | 108 |
- HTML: 2,393
- PDF: 1,376
- XML: 405
- Total: 4,174
- Supplement: 358
- BibTeX: 85
- EndNote: 108
Total article views: 940 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 13 May 2015)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
379 | 545 | 16 | 940 | 161 | 11 | 23 |
- HTML: 379
- PDF: 545
- XML: 16
- Total: 940
- Supplement: 161
- BibTeX: 11
- EndNote: 23
Cited
51 citations as recorded by crossref.
- Secondary sulfate is internally mixed with sea spray aerosol and organic aerosol in the winter Arctic R. Kirpes et al. 10.5194/acp-18-3937-2018
- Effects of NH3 and alkaline metals on the formation of particulate sulfate and nitrate in wintertime Beijing R. Huang et al. 10.1016/j.scitotenv.2020.137190
- Unexpected Contributions of Sea Spray and Lake Spray Aerosol to Inland Particulate Matter N. May et al. 10.1021/acs.estlett.8b00254
- The underappreciated role of nonvolatile cations in aerosol ammonium-sulfate molar ratios H. Guo et al. 10.5194/acp-18-17307-2018
- Elaborations of the influencing factors on the formation of secondary inorganic aerosols in a heavily polluted urban area of China S. Wang et al. 10.1016/j.jes.2023.03.022
- The lifetime of nitrogen oxides in an isoprene-dominated forest P. Romer et al. 10.5194/acp-16-7623-2016
- The diverse chemical mixing state of aerosol particles in the southeastern United States A. Bondy et al. 10.5194/acp-18-12595-2018
- Inland Sea Spray Aerosol Transport and Incomplete Chloride Depletion: Varying Degrees of Reactive Processing Observed during SOAS A. Bondy et al. 10.1021/acs.est.7b02085
- Spatial distribution and potential sources of arsenic and water-soluble ions in the snow at Ili River Valley, China X. Liu et al. 10.1016/j.chemosphere.2022.133845
- Measurements of PM10 ions and trace gases with the online system MARGA at the research station Melpitz in Germany – A five-year study B. Stieger et al. 10.1007/s10874-017-9361-0
- Atmospheric NH3 in urban Beijing: long-term variations and implications for secondary inorganic aerosol control Z. Lan et al. 10.5194/acp-24-9355-2024
- Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama A. Hettiyadura et al. 10.5194/acp-17-1343-2017
- Chromatography related performance of the Monitor for AeRosols and GAses in ambient air (MARGA): laboratory and field-based evaluation X. Chen et al. 10.5194/amt-10-3893-2017
- Enhanced secondary aerosol formation driven by excess ammonia during fog episodes in Delhi, India P. Acharja et al. 10.1016/j.chemosphere.2021.133155
- pH of Aerosols in a Polluted Atmosphere: Source Contributions to Highly Acidic Aerosol G. Shi et al. 10.1021/acs.est.6b05736
- Organic nitrate aerosol formation via NO<sub>3</sub> + biogenic volatile organic compounds in the southeastern United States B. Ayres et al. 10.5194/acp-15-13377-2015
- Computer-controlled Raman microspectroscopy (CC-Raman): A method for the rapid characterization of individual atmospheric aerosol particles R. Craig et al. 10.1080/02786826.2017.1337268
- Detailed Analysis of Estimated pH, Activity Coefficients, and Ion Concentrations between the Three Aerosol Thermodynamic Models X. Peng et al. 10.1021/acs.est.9b00181
- The impact of relative humidity on the size distribution and chemical processes of major water-soluble inorganic ions in the megacity of Chongqing, China L. Wang et al. 10.1016/j.atmosres.2017.03.016
- Investigation of global particulate nitrate from the AeroCom phase III experiment H. Bian et al. 10.5194/acp-17-12911-2017
- Secondary PM<sub>2.5</sub> decreases significantly less than NO<sub>2</sub> emission reductions during COVID lockdown in Germany V. Balamurugan et al. 10.5194/acp-22-7105-2022
- Coupling of organic and inorganic aerosol systems and the effect on gas–particle partitioning in the southeastern US H. Pye et al. 10.5194/acp-18-357-2018
- Speciation of the major inorganic salts in atmospheric aerosols of Beijing, China: Measurements and comparison with model X. Tang et al. 10.1016/j.atmosenv.2016.03.013
- The sensitivity of PM<sub>2.5</sub> acidity to meteorological parameters and chemical composition changes: 10-year records from six Canadian monitoring sites Y. Tao & J. Murphy 10.5194/acp-19-9309-2019
- Atmospheric Aerosol Chemistry: Spectroscopic and Microscopic Advances A. Ault & J. Axson 10.1021/acs.analchem.6b04670
- Linked Response of Aerosol Acidity and Ammonia to SO2 and NOx Emissions Reductions in the United States A. Lawal et al. 10.1021/acs.est.8b00711
- Photochemical organonitrate formation in wet aerosols Y. Lim et al. 10.5194/acp-16-12631-2016
- Wet deposition of inorganic ions in 320 cities across China: spatio-temporal variation, source apportionment, and dominant factors R. Li et al. 10.5194/acp-19-11043-2019
- Characteristics and source apportionment of ambient single particles in Tianjin, China: The close association between oxalic acid and biomass burning J. Xu et al. 10.1016/j.atmosres.2020.104843
- Isoprene-Derived Organosulfates: Vibrational Mode Analysis by Raman Spectroscopy, Acidity-Dependent Spectral Modes, and Observation in Individual Atmospheric Particles A. Bondy et al. 10.1021/acs.jpca.7b10587
- Polarization properties of aerosol particles over western Japan: classification, seasonal variation, and implications for air quality X. Pan et al. 10.5194/acp-16-9863-2016
- Urban and rural coarse aerosol mass across the United States: Spatial and seasonal variability and long-term trends J. Hand et al. 10.1016/j.atmosenv.2019.117025
- Aerosol Mixing State: Measurements, Modeling, and Impacts N. Riemer et al. 10.1029/2018RG000615
- Synthesis of the Southeast Atmosphere Studies: Investigating Fundamental Atmospheric Chemistry Questions A. Carlton et al. 10.1175/BAMS-D-16-0048.1
- How aerosol pH responds to nitrate to sulfate ratio of fine-mode particulate Y. Cao et al. 10.1007/s11356-020-09810-0
- Exploring controls on perfluorocarboxylic acid (PFCA) gas–particle partitioning using a model with observational constraints Y. Tao et al. 10.1039/D2EM00261B
- Source apportionment of organic carbon in Centreville, AL using organosulfates in organic tracer-based positive matrix factorization A. Hettiyadura et al. 10.1016/j.atmosenv.2018.05.007
- Analysis of secondary inorganic aerosols over the greater Athens area using the EPISODE–CityChem source dispersion and photochemistry model S. Myriokefalitakis et al. 10.5194/acp-24-7815-2024
- Raman spectra of atmospheric particles measured in Maryland, USA over 22.5 h using an automated aerosol Raman spectrometer D. Doughty & S. Hill 10.1016/j.jqsrt.2020.106839
- Study on main sources of aerosol pH and new methods for additional reduction of PM2.5 during winter severe pollution: Based on the PMF-GAS model Y. Wei et al. 10.1016/j.jclepro.2024.143401
- Lake Spray Aerosol: A Chemical Signature from Individual Ambient Particles J. Axson et al. 10.1021/acs.est.6b01661
- A simplified parameterization of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) for global chemistry and climate models: a case study with GEOS-Chem v11-02-rc D. Jo et al. 10.5194/gmd-12-2983-2019
- Modeling biogenic secondary organic aerosol (BSOA) formation from monoterpene reactions with NO3: A case study of the SOAS campaign using CMAQ M. Qin et al. 10.1016/j.atmosenv.2018.03.042
- Quantification of Non-refractory Aerosol Nitrate in Ambient Air by Thermal Dissociation Cavity Ring-Down Spectroscopy N. Garner et al. 10.1021/acs.est.0c01156
- Determining the Role of Acidity, Fate and Formation of IEPOX-Derived SOA in CMAQ P. Vasilakos et al. 10.3390/atmos12060707
- Water-soluble ionic species in atmospheric aerosols over Dhauladhar region of North-Western Himalaya D. Kaushal et al. 10.1007/s11356-020-10117-3
- Response of the Aerodyne Aerosol Mass Spectrometer to Inorganic Sulfates and Organosulfur Compounds: Applications in Field and Laboratory Measurements Y. Chen et al. 10.1021/acs.est.9b00884
- Effect of ammonia on fine-particle pH in agricultural regions of China: comparison between urban and rural sites S. Wang et al. 10.5194/acp-20-2719-2020
- Trends in remote PM2.5 residual mass across the United States: Implications for aerosol mass reconstruction in the IMPROVE network J. Hand et al. 10.1016/j.atmosenv.2019.01.049
- Elevated Concentrations of Lead in Particulate Matter on the Neighborhood-Scale in Delhi, India As Determined by Single Particle Analysis H. Shen et al. 10.1021/acs.est.5b06202
- Organic nitrate aerosol formation via NO<sub>3</sub> + BVOC in the Southeastern US B. Ayres et al. 10.5194/acpd-15-16235-2015
50 citations as recorded by crossref.
- Secondary sulfate is internally mixed with sea spray aerosol and organic aerosol in the winter Arctic R. Kirpes et al. 10.5194/acp-18-3937-2018
- Effects of NH3 and alkaline metals on the formation of particulate sulfate and nitrate in wintertime Beijing R. Huang et al. 10.1016/j.scitotenv.2020.137190
- Unexpected Contributions of Sea Spray and Lake Spray Aerosol to Inland Particulate Matter N. May et al. 10.1021/acs.estlett.8b00254
- The underappreciated role of nonvolatile cations in aerosol ammonium-sulfate molar ratios H. Guo et al. 10.5194/acp-18-17307-2018
- Elaborations of the influencing factors on the formation of secondary inorganic aerosols in a heavily polluted urban area of China S. Wang et al. 10.1016/j.jes.2023.03.022
- The lifetime of nitrogen oxides in an isoprene-dominated forest P. Romer et al. 10.5194/acp-16-7623-2016
- The diverse chemical mixing state of aerosol particles in the southeastern United States A. Bondy et al. 10.5194/acp-18-12595-2018
- Inland Sea Spray Aerosol Transport and Incomplete Chloride Depletion: Varying Degrees of Reactive Processing Observed during SOAS A. Bondy et al. 10.1021/acs.est.7b02085
- Spatial distribution and potential sources of arsenic and water-soluble ions in the snow at Ili River Valley, China X. Liu et al. 10.1016/j.chemosphere.2022.133845
- Measurements of PM10 ions and trace gases with the online system MARGA at the research station Melpitz in Germany – A five-year study B. Stieger et al. 10.1007/s10874-017-9361-0
- Atmospheric NH3 in urban Beijing: long-term variations and implications for secondary inorganic aerosol control Z. Lan et al. 10.5194/acp-24-9355-2024
- Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama A. Hettiyadura et al. 10.5194/acp-17-1343-2017
- Chromatography related performance of the Monitor for AeRosols and GAses in ambient air (MARGA): laboratory and field-based evaluation X. Chen et al. 10.5194/amt-10-3893-2017
- Enhanced secondary aerosol formation driven by excess ammonia during fog episodes in Delhi, India P. Acharja et al. 10.1016/j.chemosphere.2021.133155
- pH of Aerosols in a Polluted Atmosphere: Source Contributions to Highly Acidic Aerosol G. Shi et al. 10.1021/acs.est.6b05736
- Organic nitrate aerosol formation via NO<sub>3</sub> + biogenic volatile organic compounds in the southeastern United States B. Ayres et al. 10.5194/acp-15-13377-2015
- Computer-controlled Raman microspectroscopy (CC-Raman): A method for the rapid characterization of individual atmospheric aerosol particles R. Craig et al. 10.1080/02786826.2017.1337268
- Detailed Analysis of Estimated pH, Activity Coefficients, and Ion Concentrations between the Three Aerosol Thermodynamic Models X. Peng et al. 10.1021/acs.est.9b00181
- The impact of relative humidity on the size distribution and chemical processes of major water-soluble inorganic ions in the megacity of Chongqing, China L. Wang et al. 10.1016/j.atmosres.2017.03.016
- Investigation of global particulate nitrate from the AeroCom phase III experiment H. Bian et al. 10.5194/acp-17-12911-2017
- Secondary PM<sub>2.5</sub> decreases significantly less than NO<sub>2</sub> emission reductions during COVID lockdown in Germany V. Balamurugan et al. 10.5194/acp-22-7105-2022
- Coupling of organic and inorganic aerosol systems and the effect on gas–particle partitioning in the southeastern US H. Pye et al. 10.5194/acp-18-357-2018
- Speciation of the major inorganic salts in atmospheric aerosols of Beijing, China: Measurements and comparison with model X. Tang et al. 10.1016/j.atmosenv.2016.03.013
- The sensitivity of PM<sub>2.5</sub> acidity to meteorological parameters and chemical composition changes: 10-year records from six Canadian monitoring sites Y. Tao & J. Murphy 10.5194/acp-19-9309-2019
- Atmospheric Aerosol Chemistry: Spectroscopic and Microscopic Advances A. Ault & J. Axson 10.1021/acs.analchem.6b04670
- Linked Response of Aerosol Acidity and Ammonia to SO2 and NOx Emissions Reductions in the United States A. Lawal et al. 10.1021/acs.est.8b00711
- Photochemical organonitrate formation in wet aerosols Y. Lim et al. 10.5194/acp-16-12631-2016
- Wet deposition of inorganic ions in 320 cities across China: spatio-temporal variation, source apportionment, and dominant factors R. Li et al. 10.5194/acp-19-11043-2019
- Characteristics and source apportionment of ambient single particles in Tianjin, China: The close association between oxalic acid and biomass burning J. Xu et al. 10.1016/j.atmosres.2020.104843
- Isoprene-Derived Organosulfates: Vibrational Mode Analysis by Raman Spectroscopy, Acidity-Dependent Spectral Modes, and Observation in Individual Atmospheric Particles A. Bondy et al. 10.1021/acs.jpca.7b10587
- Polarization properties of aerosol particles over western Japan: classification, seasonal variation, and implications for air quality X. Pan et al. 10.5194/acp-16-9863-2016
- Urban and rural coarse aerosol mass across the United States: Spatial and seasonal variability and long-term trends J. Hand et al. 10.1016/j.atmosenv.2019.117025
- Aerosol Mixing State: Measurements, Modeling, and Impacts N. Riemer et al. 10.1029/2018RG000615
- Synthesis of the Southeast Atmosphere Studies: Investigating Fundamental Atmospheric Chemistry Questions A. Carlton et al. 10.1175/BAMS-D-16-0048.1
- How aerosol pH responds to nitrate to sulfate ratio of fine-mode particulate Y. Cao et al. 10.1007/s11356-020-09810-0
- Exploring controls on perfluorocarboxylic acid (PFCA) gas–particle partitioning using a model with observational constraints Y. Tao et al. 10.1039/D2EM00261B
- Source apportionment of organic carbon in Centreville, AL using organosulfates in organic tracer-based positive matrix factorization A. Hettiyadura et al. 10.1016/j.atmosenv.2018.05.007
- Analysis of secondary inorganic aerosols over the greater Athens area using the EPISODE–CityChem source dispersion and photochemistry model S. Myriokefalitakis et al. 10.5194/acp-24-7815-2024
- Raman spectra of atmospheric particles measured in Maryland, USA over 22.5 h using an automated aerosol Raman spectrometer D. Doughty & S. Hill 10.1016/j.jqsrt.2020.106839
- Study on main sources of aerosol pH and new methods for additional reduction of PM2.5 during winter severe pollution: Based on the PMF-GAS model Y. Wei et al. 10.1016/j.jclepro.2024.143401
- Lake Spray Aerosol: A Chemical Signature from Individual Ambient Particles J. Axson et al. 10.1021/acs.est.6b01661
- A simplified parameterization of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) for global chemistry and climate models: a case study with GEOS-Chem v11-02-rc D. Jo et al. 10.5194/gmd-12-2983-2019
- Modeling biogenic secondary organic aerosol (BSOA) formation from monoterpene reactions with NO3: A case study of the SOAS campaign using CMAQ M. Qin et al. 10.1016/j.atmosenv.2018.03.042
- Quantification of Non-refractory Aerosol Nitrate in Ambient Air by Thermal Dissociation Cavity Ring-Down Spectroscopy N. Garner et al. 10.1021/acs.est.0c01156
- Determining the Role of Acidity, Fate and Formation of IEPOX-Derived SOA in CMAQ P. Vasilakos et al. 10.3390/atmos12060707
- Water-soluble ionic species in atmospheric aerosols over Dhauladhar region of North-Western Himalaya D. Kaushal et al. 10.1007/s11356-020-10117-3
- Response of the Aerodyne Aerosol Mass Spectrometer to Inorganic Sulfates and Organosulfur Compounds: Applications in Field and Laboratory Measurements Y. Chen et al. 10.1021/acs.est.9b00884
- Effect of ammonia on fine-particle pH in agricultural regions of China: comparison between urban and rural sites S. Wang et al. 10.5194/acp-20-2719-2020
- Trends in remote PM2.5 residual mass across the United States: Implications for aerosol mass reconstruction in the IMPROVE network J. Hand et al. 10.1016/j.atmosenv.2019.01.049
- Elevated Concentrations of Lead in Particulate Matter on the Neighborhood-Scale in Delhi, India As Determined by Single Particle Analysis H. Shen et al. 10.1021/acs.est.5b06202
1 citations as recorded by crossref.
Saved (final revised paper)
Saved (preprint)
Latest update: 21 Nov 2024
Short summary
We report ion chromatographic measurements of gas- and aerosol-phase inorganic species at the SOAS 2013 field study. Our particular focus is on inorganic nitrate aerosol formation via HNO3 uptake onto coarse-mode dust and sea salt particles, which we find to be the dominant source of episodic inorganic nitrate at this site, due to the high acidity of the particles preventing formation of NH4NO3. We calculate a production rate of inorganic nitrate aerosol.
We report ion chromatographic measurements of gas- and aerosol-phase inorganic species at the...
Altmetrics
Final-revised paper
Preprint