Articles | Volume 21, issue 10
https://doi.org/10.5194/acp-21-7579-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-7579-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
19 May 2021
Research article |
| 19 May 2021
| 19 May 2021
Model simulations of chemical effects of sprites in relation with observed HO2 enhancements over sprite-producing thunderstorms
Holger Winkler
CORRESPONDING AUTHOR
Institute of Environmental Physics, University of Bremen, Bremen, Germany
Takayoshi Yamada
Terahertz Technology Research Center, National Institute of Information and Communications Technology, Tokyo, Japan
Yasuko Kasai
Terahertz Technology Research Center, National Institute of Information and Communications Technology, Tokyo, Japan
Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, Tokyo, Japan
Uwe Berger
Leibniz Institute of Atmospheric Physics, Kühlungsborn, Germany
deceased, 4 April 2019
Justus Notholt
Institute of Environmental Physics, University of Bremen, Bremen, Germany
Related authors
No articles found.
Thibault Cavalié, Raphael Moreno, Ladislav Rezac, Fabrice Herpin, Christopher Jarchow, Paul Hartogh, Alberto Carrasco Gallardo, Samuel Goodyear, Pierre Mancini, Ali Schulz-Ravanbakhsh, Borys Dabrowski, Yasuko Kasai, Emmanuel Lellouch, Axel Murk, Donal Murtagh, Michael Olberg, Miriam Rengel, Hideo Sagawa, Slawomira Szutowicz, and Eva Wirström
EGUsphere, https://doi.org/10.5194/egusphere-2026-584, https://doi.org/10.5194/egusphere-2026-584, 2026
This preprint is open for discussion and under review for Annales Geophysicae (ANGEO).
Short summary
Short summary
The Submillimetre Wave Instrument (SWI) aboard the Juice mission is a sophisticated and first-of-its-kind payload. SWI is designed to support the diverse science objectives of the Juice mission targeting Jupiter's middle atmosphere, icy-moon's exospheres as well as near sub-surface thermophysical properties. This presents significant planning, operations and commanding challenges which are described in this paper in the context of the Lunar and Earth Gravity Assist (LEGA).
Constantina Rousogenous, Christof Petri, Pierre-Yves Quéhé, Thomas Laemmel, Joshua L. Laughner, Maximilien Desservettaz, Michael Pikridas, Michel Ramonet, Efstratios Bourtsoukidis, Matthias Buschmann, Justus Notholt, Thorsten Warneke, Jean-Daniel Paris, Jean Sciare, and Mihalis Vrekoussis
Atmos. Meas. Tech., 19, 565–581, https://doi.org/10.5194/amt-19-565-2026, https://doi.org/10.5194/amt-19-565-2026, 2026
Short summary
Short summary
The Eastern Mediterranean and Middle East is a greenhouse gas emission hotspot but lacks atmospheric monitoring. Our study introduces the first Total Carbon Column Observing Network site in this region, in Cyprus, providing high-precision columnar measurement of key greenhouse gases. This new dataset enhances global climate monitoring efforts, supports the validation of satellites, will help assess regional emission trends, filling a critical observational gap in this climate-sensitive region.
Denghui Ji, Xiaoyu Sun, Christoph Ritter, and Justus Notholt
Atmos. Meas. Tech., 19, 421–436, https://doi.org/10.5194/amt-19-421-2026, https://doi.org/10.5194/amt-19-421-2026, 2026
Short summary
Short summary
We have developed a new method that uses machine learning to analyse aerosols by combining different instruments measuring at different wavelengths. This method can identify the composition of these aerosols faster and more accurately. We tested it using ground-based data. Our results show that this method can help monitor air quality and better understand the impact of aerosols on the climate.
Xiaoyu Sun, Mathias Palm, Katrin Müller, Denghui Ji, and Justus Notholt
EGUsphere, https://doi.org/10.5194/egusphere-2025-5394, https://doi.org/10.5194/egusphere-2025-5394, 2025
Short summary
Short summary
Near-surface ozone over the tropical Pacific is among the lowest on Earth, and this study provides rare observations from this key region. Using sunlight measurements with an infrared spectrometer in Palau, we found that ozone rises in the morning and falls after noon. This daily rhythm and very low levels show how clean ocean air and weak thunderstorms shape atmospheric chemistry and affect Earth’s climate.
Jonas Hachmeister, Debra Wunch, Erin McGee, Kimberly Strong, Rigel Kivi, Justus Notholt, Thorsten Warneke, and Matthias Buschmann
Atmos. Meas. Tech., 18, 7105–7128, https://doi.org/10.5194/amt-18-7105-2025, https://doi.org/10.5194/amt-18-7105-2025, 2025
Short summary
Short summary
Methane measurements from the Total Carbon Column Observing Network (TCCON) are important for climate research, especially in the Arctic, where few measurements are available. We show that during early spring systematic errors are present in these data that are correlated to the presence of the polar vortex. These errors occur due to the usage of wrong methane prior shapes in the retrieval and can be alleviated by modifying the prior shape accordingly.
Denghui Ji, Christoph Ritter, Xiaoyu Sun, Manuel Moser, Christiane Voigt, Mathias Palm, and Justus Notholt
Atmos. Chem. Phys., 25, 13037–13052, https://doi.org/10.5194/acp-25-13037-2025, https://doi.org/10.5194/acp-25-13037-2025, 2025
Short summary
Short summary
We discovered a process where large aerosols help small water droplets in Arctic clouds grow, even when conditions normally favor ice. Unlike the traditional view, this process may explain how liquid and ice can coexist in cold clouds. Based on theory and aircraft data, our findings provide new insight into the microphysics of mixed-phase clouds, which could improve understanding of how Arctic clouds affect climate.
Roeland Van Malderen, Zhou Zang, Kai-Lan Chang, Robin Björklund, Owen R. Cooper, Jane Liu, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, Audrey Gaudel, David W. Tarasick, Herman G. J. Smit, Anne M. Thompson, Ryan M. Stauffer, Debra E. Kollonige, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Isamu Morino, Glen McConville, Katrin Müller, Isao Murata, Justus Notholt, Ankie Piters, Maxime Prignon, Richard Querel, Vincenzo Rizi, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
Atmos. Chem. Phys., 25, 9905–9935, https://doi.org/10.5194/acp-25-9905-2025, https://doi.org/10.5194/acp-25-9905-2025, 2025
Short summary
Short summary
Tropospheric ozone is an important greenhouse gas and an air pollutant whose distribution and time variability are mainly governed by anthropogenic emissions and dynamics. In this paper, we assess regional trends of tropospheric ozone column amounts, based on two different approaches of merging or synthesizing ground-based observations and their trends within specific regions. Our findings clearly demonstrate regional trend differences but also consistently higher pre-COVID than post-COVID trends.
Lukas Heizmann, Mathias Palm, Justus Notholt, and Matthias Buschmann
EGUsphere, https://doi.org/10.5194/egusphere-2025-3691, https://doi.org/10.5194/egusphere-2025-3691, 2025
Short summary
Short summary
Fourier transform infrared emission spectroscopy measures the infrared radiation originating from the thermal emission of the atmosphere. The measured interferograms are transformed into spectra via Fourier transformation. The established method for calibration is strictly speaking only valid for infinitely long interferograms. We quantify the errors caused by this idealization in a case study and find that they are generally below 0.05 % in spectral regions that are of interest for retrievals.
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, Herman G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, David W. Tarasick, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
Atmos. Chem. Phys., 25, 7187–7225, https://doi.org/10.5194/acp-25-7187-2025, https://doi.org/10.5194/acp-25-7187-2025, 2025
Short summary
Short summary
Tropospheric ozone is an important greenhouse gas and is an air pollutant. The time variability of tropospheric ozone is mainly driven by anthropogenic emissions. In this paper, we study the distribution and time variability of ozone from harmonized ground-based observations from five different measurement techniques. Our findings provide clear standard references for atmospheric models and evolving tropospheric ozone satellite data for the 2000–2022 period.
Xiaoyu Sun, Katrin Müller, Mathias Palm, Christoph Ritter, Denghui Ji, Tim Balthasar Röpke, and Justus Notholt
Atmos. Chem. Phys., 25, 6881–6902, https://doi.org/10.5194/acp-25-6881-2025, https://doi.org/10.5194/acp-25-6881-2025, 2025
Short summary
Short summary
We studied how air moves from the lower atmosphere to the stratosphere over the tropical western Pacific. Using observations and air tracking, we found that, in winter, air ascends and cold temperatures freeze water out, drying it before it enters the stratosphere. In summer, air tends to sink after cloud formation. This process affects water vapor amounts in the stratosphere, influencing the greenhouse effect and climate.
Denghui Ji, Mathias Palm, Matthias Buschmann, Kerstin Ebell, Marion Maturilli, Xiaoyu Sun, and Justus Notholt
Atmos. Chem. Phys., 25, 3889–3904, https://doi.org/10.5194/acp-25-3889-2025, https://doi.org/10.5194/acp-25-3889-2025, 2025
Short summary
Short summary
Our study explores how certain aerosols, like sea salt, affect infrared heat radiation in the Arctic, potentially speeding up warming. We used advanced technology to measure aerosol composition and found that these particles grow with humidity, significantly increasing their heat-trapping effect in the infrared region, especially in winter. Our findings suggest these aerosols could be a key factor in Arctic warming, emphasizing the importance of understanding aerosols for climate prediction.
Frank Hase, Paolo Castracane, Angelika Dehn, Omaira Elena García, David W. T. Griffith, Lukas Heizmann, Nicholas B. Jones, Tomi Karppinen, Rigel Kivi, Martine de Mazière, Justus Notholt, and Mahesh Kumar Sha
Atmos. Meas. Tech., 18, 1257–1267, https://doi.org/10.5194/amt-18-1257-2025, https://doi.org/10.5194/amt-18-1257-2025, 2025
Short summary
Short summary
The primary measurement result delivered by a Fourier transform spectrometer is an interferogram, and the spectrum required for further analysis needs to be calculated from the interferogram by Fourier analysis. The paper deals with technical aspects of this process and shows how the reconstruction of the spectrum can be optimized.
Jamal Makkor, Mathias Palm, Matthias Buschmann, Emmanuel Mahieu, Martyn P. Chipperfield, and Justus Notholt
Atmos. Meas. Tech., 18, 1105–1114, https://doi.org/10.5194/amt-18-1105-2025, https://doi.org/10.5194/amt-18-1105-2025, 2025
Short summary
Short summary
During the years 1950 and 1951, Marcel Migeotte took regular solar measurements in the form of paper rolls at the Jungfraujoch site. These historical spectra proved to be valuable for atmospheric research and needed to be saved for posterity. Therefore, a digitization method which used image-processing techniques was developed to extract them from the historical paper rolls. This allowed them to be saved in a machine-readable format that is easily accessible to the scientific community.
Hella van Asperen, Thorsten Warneke, Alessandro Carioca de Araújo, Bruce Forsberg, Sávio José Filgueiras Ferreira, Thomas Röckmann, Carina van der Veen, Sipko Bulthuis, Leonardo Ramos de Oliveira, Thiago de Lima Xavier, Jailson da Mata, Marta de Oliveira Sá, Paulo Ricardo Teixeira, Julie Andrews de França e Silva, Susan Trumbore, and Justus Notholt
Biogeosciences, 21, 3183–3199, https://doi.org/10.5194/bg-21-3183-2024, https://doi.org/10.5194/bg-21-3183-2024, 2024
Short summary
Short summary
Carbon monoxide (CO) is regarded as an important indirect greenhouse gas. Soils can emit and take up CO, but, until now, uncertainty remains as to which process dominates in tropical rainforests. We present the first soil CO flux measurements from a tropical rainforest. Based on our observations, we report that tropical rainforest soils are a net source of CO. In addition, we show that valley streams and inundated areas are likely additional hot spots of CO in the ecosystem.
Joshua L. Laughner, Geoffrey C. Toon, Joseph Mendonca, Christof Petri, Sébastien Roche, Debra Wunch, Jean-Francois Blavier, David W. T. Griffith, Pauli Heikkinen, Ralph F. Keeling, Matthäus Kiel, Rigel Kivi, Coleen M. Roehl, Britton B. Stephens, Bianca C. Baier, Huilin Chen, Yonghoon Choi, Nicholas M. Deutscher, Joshua P. DiGangi, Jochen Gross, Benedikt Herkommer, Pascal Jeseck, Thomas Laemmel, Xin Lan, Erin McGee, Kathryn McKain, John Miller, Isamu Morino, Justus Notholt, Hirofumi Ohyama, David F. Pollard, Markus Rettinger, Haris Riris, Constantina Rousogenous, Mahesh Kumar Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Steven C. Wofsy, Minqiang Zhou, and Paul O. Wennberg
Earth Syst. Sci. Data, 16, 2197–2260, https://doi.org/10.5194/essd-16-2197-2024, https://doi.org/10.5194/essd-16-2197-2024, 2024
Short summary
Short summary
This paper describes a new version, called GGG2020, of a data set containing column-integrated observations of greenhouse and related gases (including CO2, CH4, CO, and N2O) made by ground stations located around the world. Compared to the previous version (GGG2014), improvements have been made toward site-to-site consistency. This data set plays a key role in validating space-based greenhouse gas observations and in understanding the carbon cycle.
Alexandra Klemme, Thorsten Warneke, Heinrich Bovensmann, Matthias Weigelt, Jürgen Müller, Tim Rixen, Justus Notholt, and Claus Lämmerzahl
Hydrol. Earth Syst. Sci., 28, 1527–1538, https://doi.org/10.5194/hess-28-1527-2024, https://doi.org/10.5194/hess-28-1527-2024, 2024
Short summary
Short summary
Satellite data help estimate groundwater depletion, but earlier assessments missed mass loss from river sediment. In the Ganges–Brahmaputra–Meghna (GBM) river system, sediment accounts for 4 % of the depletion. Correcting for sediment in the GBM mountains reduces estimated depletion by 14 %. It's important to note that the Himalayas' uplift may offset some sediment-induced mass loss. This understanding is vital for accurate water storage trend assessments and sustainable groundwater management.
Jean-François Müller, Trissevgeni Stavrakou, Glenn-Michael Oomen, Beata Opacka, Isabelle De Smedt, Alex Guenther, Corinne Vigouroux, Bavo Langerock, Carlos Augusto Bauer Aquino, Michel Grutter, James Hannigan, Frank Hase, Rigel Kivi, Erik Lutsch, Emmanuel Mahieu, Maria Makarova, Jean-Marc Metzger, Isamu Morino, Isao Murata, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Amelie Röhling, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, and Alan Fried
Atmos. Chem. Phys., 24, 2207–2237, https://doi.org/10.5194/acp-24-2207-2024, https://doi.org/10.5194/acp-24-2207-2024, 2024
Short summary
Short summary
Formaldehyde observations from satellites can be used to constrain the emissions of volatile organic compounds, but those observations have biases. Using an atmospheric model, aircraft and ground-based remote sensing data, we quantify these biases, propose a correction to the data, and assess the consequence of this correction for the evaluation of emissions.
Katrin Müller, Jordis S. Tradowsky, Peter von der Gathen, Christoph Ritter, Sharon Patris, Justus Notholt, and Markus Rex
Atmos. Chem. Phys., 24, 2169–2193, https://doi.org/10.5194/acp-24-2169-2024, https://doi.org/10.5194/acp-24-2169-2024, 2024
Short summary
Short summary
The Palau Atmospheric Observatory is introduced as an ideal site to detect changes in atmospheric composition and dynamics above the remote tropical western Pacific. We focus on the ozone sounding program from 2016–2021, including El Niño 2016. The year-round high convective activity is reflected in dominant low tropospheric ozone and high relative humidity. Their seasonal distributions are unique compared to other tropical sites and are modulated by the Intertropical Convergence Zone.
Yajun Xu, Tomohiro O. Sato, Ayano Nakamura, Tamaki Fujinawa, Suyun Wang, and Yasuko Kasai
EGUsphere, https://doi.org/10.5194/egusphere-2024-194, https://doi.org/10.5194/egusphere-2024-194, 2024
Preprint withdrawn
Short summary
Short summary
Usually, the vertical column density of NO2 is obtained by converting the slant column density derived from the measured spectra using an air mass factor (AMF). This work proposes two deep neural network models for calculating the tropospheric AMF and altitude-dependent AMF. Experiments shown that the RMSPE and computation time are approximately 30 times smaller and two times shorter compared to the traditional method.
Victoria A. Flood, Kimberly Strong, Cynthia H. Whaley, Kaley A. Walker, Thomas Blumenstock, James W. Hannigan, Johan Mellqvist, Justus Notholt, Mathias Palm, Amelie N. Röhling, Stephen Arnold, Stephen Beagley, Rong-You Chien, Jesper Christensen, Makoto Deushi, Srdjan Dobricic, Xinyi Dong, Joshua S. Fu, Michael Gauss, Wanmin Gong, Joakim Langner, Kathy S. Law, Louis Marelle, Tatsuo Onishi, Naga Oshima, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Manu A. Thomas, Svetlana Tsyro, and Steven Turnock
Atmos. Chem. Phys., 24, 1079–1118, https://doi.org/10.5194/acp-24-1079-2024, https://doi.org/10.5194/acp-24-1079-2024, 2024
Short summary
Short summary
It is important to understand the composition of the Arctic atmosphere and how it is changing. Atmospheric models provide simulations that can inform policy. This study examines simulations of CH4, CO, and O3 by 11 models. Model performance is assessed by comparing results matched in space and time to measurements from five high-latitude ground-based infrared spectrometers. This work finds that models generally underpredict the concentrations of these gases in the Arctic troposphere.
Jonas Hachmeister, Oliver Schneising, Michael Buchwitz, John P. Burrows, Justus Notholt, and Matthias Buschmann
Atmos. Chem. Phys., 24, 577–595, https://doi.org/10.5194/acp-24-577-2024, https://doi.org/10.5194/acp-24-577-2024, 2024
Short summary
Short summary
We quantified changes in atmospheric methane concentrations using satellite data and a dynamic linear model approach. We calculated global annual methane increases for the years 2019–2022, which are in good agreement with other sources. For zonal methane growth rates, we identified strong inter-hemispheric differences in 2019 and 2022. For 2022, we could attribute decreases in the global growth rate to the Northern Hemisphere, possibly related to a reduction in anthropogenic emissions.
Minqiang Zhou, Bavo Langerock, Mahesh Kumar Sha, Christian Hermans, Nicolas Kumps, Rigel Kivi, Pauli Heikkinen, Christof Petri, Justus Notholt, Huilin Chen, and Martine De Mazière
Atmos. Meas. Tech., 16, 5593–5608, https://doi.org/10.5194/amt-16-5593-2023, https://doi.org/10.5194/amt-16-5593-2023, 2023
Short summary
Short summary
Atmospheric N2O and CH4 columns are successfully retrieved from low-resolution FTIR spectra recorded by a Bruker VERTEX 70. The 1-year measurements at Sodankylä show that the N2O total columns retrieved from 125HR and VERTEX 70 spectra are −0.3 ± 0.7 % with an R value of 0.93. The relative differences between the CH4 total columns retrieved from the 125HR and VERTEX spectra are 0.0 ± 0.8 % with an R value of 0.87. Such a technique can help to fill the gap in NDACC N2O and CH4 measurements.
Michael Kiefer, Dale F. Hurst, Gabriele P. Stiller, Stefan Lossow, Holger Vömel, John Anderson, Faiza Azam, Jean-Loup Bertaux, Laurent Blanot, Klaus Bramstedt, John P. Burrows, Robert Damadeo, Bianca Maria Dinelli, Patrick Eriksson, Maya García-Comas, John C. Gille, Mark Hervig, Yasuko Kasai, Farahnaz Khosrawi, Donal Murtagh, Gerald E. Nedoluha, Stefan Noël, Piera Raspollini, William G. Read, Karen H. Rosenlof, Alexei Rozanov, Christopher E. Sioris, Takafumi Sugita, Thomas von Clarmann, Kaley A. Walker, and Katja Weigel
Atmos. Meas. Tech., 16, 4589–4642, https://doi.org/10.5194/amt-16-4589-2023, https://doi.org/10.5194/amt-16-4589-2023, 2023
Short summary
Short summary
We quantify biases and drifts (and their uncertainties) between the stratospheric water vapor measurement records of 15 satellite-based instruments (SATs, with 31 different retrievals) and balloon-borne frost point hygrometers (FPs) launched at 27 globally distributed stations. These comparisons of measurements during the period 2000–2016 are made using robust, consistent statistical methods. With some exceptions, the biases and drifts determined for most SAT–FP pairs are < 10 % and < 1 % yr−1.
Rafaella Chiarella, Matthias Buschmann, Joshua Laughner, Isamu Morino, Justus Notholt, Christof Petri, Geoffrey Toon, Voltaire A. Velazco, and Thorsten Warneke
Atmos. Meas. Tech., 16, 3987–4007, https://doi.org/10.5194/amt-16-3987-2023, https://doi.org/10.5194/amt-16-3987-2023, 2023
Short summary
Short summary
The goal is to establish a window and strategy for xCO2 retrieval from ground-based Fourier transform spectrometers for NDACC. In the study we describe the spectroscopy of the region, the locations and instruments used, and the methods of calculating the retrieved xCO2. We performed tests to assess the sensitivity to diverse factors and sources of errors while comparing the retrieval to a well-established xCO2 retrieval from TCCON.
Xiaoyu Sun, Mathias Palm, Katrin Müller, Jonas Hachmeister, and Justus Notholt
Atmos. Chem. Phys., 23, 7075–7090, https://doi.org/10.5194/acp-23-7075-2023, https://doi.org/10.5194/acp-23-7075-2023, 2023
Short summary
Short summary
The tropical western Pacific (TWP) is an active interhemispheric transport region contributing significantly to the global climate. A method to determine the chemical equator was developed by model simulations of a virtual passive tracer to analyze transport in the tropics, with a focus on the TWP region. We compare the chemical equator with tropical rain belts and wind fields and obtain a vertical pattern of interhemispheric transport processes which shows tilt structure in certain seasons.
Yifan Guan, Gretchen Keppel-Aleks, Scott C. Doney, Christof Petri, Dave Pollard, Debra Wunch, Frank Hase, Hirofumi Ohyama, Isamu Morino, Justus Notholt, Kei Shiomi, Kim Strong, Rigel Kivi, Matthias Buschmann, Nicholas Deutscher, Paul Wennberg, Ralf Sussmann, Voltaire A. Velazco, and Yao Té
Atmos. Chem. Phys., 23, 5355–5372, https://doi.org/10.5194/acp-23-5355-2023, https://doi.org/10.5194/acp-23-5355-2023, 2023
Short summary
Short summary
We characterize spatial–temporal patterns of interannual variability (IAV) in atmospheric CO2 based on NASA’s Orbiting Carbon Observatory-2 (OCO-2). CO2 variation is strongly impacted by climate events, with higher anomalies during El Nino years. We show high correlation in IAV between space-based and ground-based CO2 from long-term sites. Because OCO-2 has near-global coverage, our paper provides a roadmap to study IAV where in situ observation is sparse, such as open oceans and remote lands.
Antonio G. Bruno, Jeremy J. Harrison, Martyn P. Chipperfield, David P. Moore, Richard J. Pope, Christopher Wilson, Emmanuel Mahieu, and Justus Notholt
Atmos. Chem. Phys., 23, 4849–4861, https://doi.org/10.5194/acp-23-4849-2023, https://doi.org/10.5194/acp-23-4849-2023, 2023
Short summary
Short summary
A 3-D chemical transport model, TOMCAT; satellite data; and ground-based observations have been used to investigate hydrogen cyanide (HCN) variability. We found that the oxidation by O(1D) drives the HCN loss in the middle stratosphere and the currently JPL-recommended OH reaction rate overestimates HCN atmospheric loss. We also evaluated two different ocean uptake schemes. We found them to be unrealistic, and we need to scale these schemes to obtain good agreement with HCN observations.
Denghui Ji, Mathias Palm, Christoph Ritter, Philipp Richter, Xiaoyu Sun, Matthias Buschmann, and Justus Notholt
Atmos. Meas. Tech., 16, 1865–1879, https://doi.org/10.5194/amt-16-1865-2023, https://doi.org/10.5194/amt-16-1865-2023, 2023
Short summary
Short summary
To measuring aerosol components, a Fourier transform infrared spectrometer (FTIS) and a lidar are operated in Ny-Ålesund, Spitsbergen (78° N, 11° E). Using the FTIS, a retrieval algorithm is developed for dust, sea salt, black carbon, and sulfate. The distribution of aerosols or clouds is provided by lidar and used as an indicator for aerosol or cloud retrieval with the FTS. Thus, a two-instrument joint-observation scheme is designed and is used on the data measured from 2019 to the present.
Brendan Byrne, David F. Baker, Sourish Basu, Michael Bertolacci, Kevin W. Bowman, Dustin Carroll, Abhishek Chatterjee, Frédéric Chevallier, Philippe Ciais, Noel Cressie, David Crisp, Sean Crowell, Feng Deng, Zhu Deng, Nicholas M. Deutscher, Manvendra K. Dubey, Sha Feng, Omaira E. García, David W. T. Griffith, Benedikt Herkommer, Lei Hu, Andrew R. Jacobson, Rajesh Janardanan, Sujong Jeong, Matthew S. Johnson, Dylan B. A. Jones, Rigel Kivi, Junjie Liu, Zhiqiang Liu, Shamil Maksyutov, John B. Miller, Scot M. Miller, Isamu Morino, Justus Notholt, Tomohiro Oda, Christopher W. O'Dell, Young-Suk Oh, Hirofumi Ohyama, Prabir K. Patra, Hélène Peiro, Christof Petri, Sajeev Philip, David F. Pollard, Benjamin Poulter, Marine Remaud, Andrew Schuh, Mahesh K. Sha, Kei Shiomi, Kimberly Strong, Colm Sweeney, Yao Té, Hanqin Tian, Voltaire A. Velazco, Mihalis Vrekoussis, Thorsten Warneke, John R. Worden, Debra Wunch, Yuanzhi Yao, Jeongmin Yun, Andrew Zammit-Mangion, and Ning Zeng
Earth Syst. Sci. Data, 15, 963–1004, https://doi.org/10.5194/essd-15-963-2023, https://doi.org/10.5194/essd-15-963-2023, 2023
Short summary
Short summary
Changes in the carbon stocks of terrestrial ecosystems result in emissions and removals of CO2. These can be driven by anthropogenic activities (e.g., deforestation), natural processes (e.g., fires) or in response to rising CO2 (e.g., CO2 fertilization). This paper describes a dataset of CO2 emissions and removals derived from atmospheric CO2 observations. This pilot dataset informs current capabilities and future developments towards top-down monitoring and verification systems.
Hao Yin, Youwen Sun, Justus Notholt, Mathias Palm, Chunxiang Ye, and Cheng Liu
Atmos. Chem. Phys., 22, 14401–14419, https://doi.org/10.5194/acp-22-14401-2022, https://doi.org/10.5194/acp-22-14401-2022, 2022
Short summary
Short summary
Improved knowledge of the chemistry and drivers of surface ozone over the Qinghai-Tibet Plateau (QTP) is significant for regulatory and control purposes in this high-altitude region in the Himalayas. Our study investigates the processes and drivers of surface ozone anomalies by using machine-learning model-based meteorological normalization methods between 2015 and 2020 in urban areas over the QTP. This study can provide valuable implication for ozone mitigation over the QTP.
Youwen Sun, Hao Yin, Wei Wang, Changgong Shan, Justus Notholt, Mathias Palm, Ke Liu, Zhenyi Chen, and Cheng Liu
Atmos. Meas. Tech., 15, 4819–4834, https://doi.org/10.5194/amt-15-4819-2022, https://doi.org/10.5194/amt-15-4819-2022, 2022
Short summary
Short summary
This study summarizes an overview of the status and perspective of GHG monitoring in China. This study not only improves our understanding with respect to the status, advances, and challenges of GHG monitoring in China but also presents an outlook for further improving GHG monitoring capacity in China.
Jonas Hachmeister, Oliver Schneising, Michael Buchwitz, Alba Lorente, Tobias Borsdorff, John P. Burrows, Justus Notholt, and Matthias Buschmann
Atmos. Meas. Tech., 15, 4063–4074, https://doi.org/10.5194/amt-15-4063-2022, https://doi.org/10.5194/amt-15-4063-2022, 2022
Short summary
Short summary
Sentinel-5P trace gas retrievals rely on elevation data in their calculations. Outdated or inaccurate data can lead to significant errors in e.g. dry-air mole fractions of methane (XCH4). We show that the use of inadequate elevation data leads to strong XCH4 anomalies in Greenland. Similar problems can be expected for other regions with inaccurate elevation data. However, we expect these to be more localized. We show that updating elevation data used in the retrieval solves this issue.
Philipp Richter, Mathias Palm, Christine Weinzierl, Hannes Griesche, Penny M. Rowe, and Justus Notholt
Earth Syst. Sci. Data, 14, 2767–2784, https://doi.org/10.5194/essd-14-2767-2022, https://doi.org/10.5194/essd-14-2767-2022, 2022
Short summary
Short summary
We present a dataset of cloud optical depths, effective radii and water paths from optically thin clouds observed in the Arctic around Svalbard. The data have been retrieved from infrared spectral radiance measured using a Fourier-transform infrared (FTIR) spectrometer. Besides a description of the measurements and retrieval technique, the data are put into context with results of corresponding measurements from microwave radiometer, lidar and cloud radar.
Alexandra Klemme, Tim Rixen, Denise Müller-Dum, Moritz Müller, Justus Notholt, and Thorsten Warneke
Biogeosciences, 19, 2855–2880, https://doi.org/10.5194/bg-19-2855-2022, https://doi.org/10.5194/bg-19-2855-2022, 2022
Short summary
Short summary
Tropical peat-draining rivers contain high amounts of carbon. Surprisingly, measured carbon dioxide (CO2) emissions from those rivers are comparatively moderate. We compiled data from 10 Southeast Asian rivers and found that CO2 production within these rivers is hampered by low water pH, providing a natural threshold for CO2 emissions. Furthermore, we find that enhanced carbonate input, e.g. caused by human activities, suspends this natural threshold and causes increased CO2 emissions.
William G. Read, Gabriele Stiller, Stefan Lossow, Michael Kiefer, Farahnaz Khosrawi, Dale Hurst, Holger Vömel, Karen Rosenlof, Bianca M. Dinelli, Piera Raspollini, Gerald E. Nedoluha, John C. Gille, Yasuko Kasai, Patrick Eriksson, Christopher E. Sioris, Kaley A. Walker, Katja Weigel, John P. Burrows, and Alexei Rozanov
Atmos. Meas. Tech., 15, 3377–3400, https://doi.org/10.5194/amt-15-3377-2022, https://doi.org/10.5194/amt-15-3377-2022, 2022
Short summary
Short summary
This paper attempts to provide an assessment of the accuracy of 21 satellite-based instruments that remotely measure atmospheric humidity in the upper troposphere of the Earth's atmosphere. The instruments made their measurements from 1984 to the present time; however, most of these instruments began operations after 2000, and only a few are still operational. The objective of this study is to quantify the accuracy of each satellite humidity data set.
Stefan Noël, Maximilian Reuter, Michael Buchwitz, Jakob Borchardt, Michael Hilker, Oliver Schneising, Heinrich Bovensmann, John P. Burrows, Antonio Di Noia, Robert J. Parker, Hiroshi Suto, Yukio Yoshida, Matthias Buschmann, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Rigel Kivi, Cheng Liu, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, Christof Petri, David F. Pollard, Markus Rettinger, Coleen Roehl, Constantina Rousogenous, Mahesh Kumar Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Mihalis Vrekoussis, and Thorsten Warneke
Atmos. Meas. Tech., 15, 3401–3437, https://doi.org/10.5194/amt-15-3401-2022, https://doi.org/10.5194/amt-15-3401-2022, 2022
Short summary
Short summary
We present a new version (v3) of the GOSAT and GOSAT-2 FOCAL products.
In addition to an increased number of XCO2 data, v3 also includes products for XCH4 (full-physics and proxy), XH2O and the relative ratio of HDO to H2O (δD). For GOSAT-2, we also present first XCO and XN2O results. All FOCAL data products show reasonable spatial distribution and temporal variations and agree well with TCCON. Global XN2O maps show a gradient from the tropics to higher latitudes on the order of 15 ppb.
Hao Yin, Youwen Sun, Justus Notholt, Mathias Palm, and Cheng Liu
Atmos. Chem. Phys., 22, 4167–4185, https://doi.org/10.5194/acp-22-4167-2022, https://doi.org/10.5194/acp-22-4167-2022, 2022
Short summary
Short summary
In this study, we quantity the long-term variabilities and the underlying drivers of NO2 from 2005 to 2020 over the Yangtze River Delta (YRD), one of the most densely populated and highly industrialized city clusters in China. We reveal the significant effect of the Action Plan on the Prevention and Control of Air Pollution since 2013 adopted by the Chinese government to reduce NOx pollution. Our study can improve the understanding of pollution control measures on a regional scale.
Thomas E. Taylor, Christopher W. O'Dell, David Crisp, Akhiko Kuze, Hannakaisa Lindqvist, Paul O. Wennberg, Abhishek Chatterjee, Michael Gunson, Annmarie Eldering, Brendan Fisher, Matthäus Kiel, Robert R. Nelson, Aronne Merrelli, Greg Osterman, Frédéric Chevallier, Paul I. Palmer, Liang Feng, Nicholas M. Deutscher, Manvendra K. Dubey, Dietrich G. Feist, Omaira E. García, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Cheng Liu, Martine De Mazière, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, David F. Pollard, Markus Rettinger, Matthias Schneider, Coleen M. Roehl, Mahesh Kumar Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Mihalis Vrekoussis, Thorsten Warneke, and Debra Wunch
Earth Syst. Sci. Data, 14, 325–360, https://doi.org/10.5194/essd-14-325-2022, https://doi.org/10.5194/essd-14-325-2022, 2022
Short summary
Short summary
We provide an analysis of an 11-year record of atmospheric carbon dioxide (CO2) concentrations derived using an optimal estimation retrieval algorithm on measurements made by the GOSAT satellite. The new product (version 9) shows improvement over the previous version (v7.3) as evaluated against independent estimates of CO2 from ground-based sensors and atmospheric inversion systems. We also compare the new GOSAT CO2 values to collocated estimates from NASA's Orbiting Carbon Observatory-2.
Youwen Sun, Hao Yin, Xiao Lu, Justus Notholt, Mathias Palm, Cheng Liu, Yuan Tian, and Bo Zheng
Atmos. Chem. Phys., 21, 18589–18608, https://doi.org/10.5194/acp-21-18589-2021, https://doi.org/10.5194/acp-21-18589-2021, 2021
Short summary
Short summary
This study uses high-resolution nested-grid GEOS-Chem simulation, the eXtreme Gradient Boosting (XGBoost) machine learning method, and the exposure–response relationship to determine the drivers and evaluate the health risks of the unexpected surface O3 enhancements over the Sichuan Basin in 2020. These unexpected O3 enhancements were induced by meteorological anomalies and caused dramatically high health risks.
Joseph Mendonca, Ray Nassar, Christopher W. O'Dell, Rigel Kivi, Isamu Morino, Justus Notholt, Christof Petri, Kimberly Strong, and Debra Wunch
Atmos. Meas. Tech., 14, 7511–7524, https://doi.org/10.5194/amt-14-7511-2021, https://doi.org/10.5194/amt-14-7511-2021, 2021
Short summary
Short summary
Machine learning has become an important tool for pattern recognition in many applications. In this study, we used a neural network to improve the data quality of OCO-2 measurements made at northern high latitudes. The neural network was trained and used as a binary classifier to filter out bad OCO-2 measurements in order to increase the accuracy and precision of OCO-2 XCO2 measurements in the Boreal and Arctic regions.
Nicole Jacobs, William R. Simpson, Kelly A. Graham, Christopher Holmes, Frank Hase, Thomas Blumenstock, Qiansi Tu, Matthias Frey, Manvendra K. Dubey, Harrison A. Parker, Debra Wunch, Rigel Kivi, Pauli Heikkinen, Justus Notholt, Christof Petri, and Thorsten Warneke
Atmos. Chem. Phys., 21, 16661–16687, https://doi.org/10.5194/acp-21-16661-2021, https://doi.org/10.5194/acp-21-16661-2021, 2021
Short summary
Short summary
Spatial patterns of carbon dioxide seasonal cycle amplitude and summer drawdown timing derived from the OCO-2 satellite over northern high latitudes agree well with corresponding estimates from two models. The Asian boreal forest is anomalous with the largest amplitude and earliest seasonal drawdown. Modeled land contact tracers suggest that accumulated CO2 exchanges during atmospheric transport play a major role in shaping carbon dioxide seasonality in northern high-latitude regions.
Mahesh Kumar Sha, Bavo Langerock, Jean-François L. Blavier, Thomas Blumenstock, Tobias Borsdorff, Matthias Buschmann, Angelika Dehn, Martine De Mazière, Nicholas M. Deutscher, Dietrich G. Feist, Omaira E. García, David W. T. Griffith, Michel Grutter, James W. Hannigan, Frank Hase, Pauli Heikkinen, Christian Hermans, Laura T. Iraci, Pascal Jeseck, Nicholas Jones, Rigel Kivi, Nicolas Kumps, Jochen Landgraf, Alba Lorente, Emmanuel Mahieu, Maria V. Makarova, Johan Mellqvist, Jean-Marc Metzger, Isamu Morino, Tomoo Nagahama, Justus Notholt, Hirofumi Ohyama, Ivan Ortega, Mathias Palm, Christof Petri, David F. Pollard, Markus Rettinger, John Robinson, Sébastien Roche, Coleen M. Roehl, Amelie N. Röhling, Constantina Rousogenous, Matthias Schneider, Kei Shiomi, Dan Smale, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, Osamu Uchino, Voltaire A. Velazco, Corinne Vigouroux, Mihalis Vrekoussis, Pucai Wang, Thorsten Warneke, Tyler Wizenberg, Debra Wunch, Shoma Yamanouchi, Yang Yang, and Minqiang Zhou
Atmos. Meas. Tech., 14, 6249–6304, https://doi.org/10.5194/amt-14-6249-2021, https://doi.org/10.5194/amt-14-6249-2021, 2021
Short summary
Short summary
This paper presents, for the first time, Sentinel-5 Precursor methane and carbon monoxide validation results covering a period from November 2017 to September 2020. For this study, we used global TCCON and NDACC-IRWG network data covering a wide range of atmospheric and surface conditions across different terrains. We also show the influence of a priori alignment, smoothing uncertainties and the sensitivity of the validation results towards the application of advanced co-location criteria.
Youwen Sun, Hao Yin, Cheng Liu, Emmanuel Mahieu, Justus Notholt, Yao Té, Xiao Lu, Mathias Palm, Wei Wang, Changgong Shan, Qihou Hu, Min Qin, Yuan Tian, and Bo Zheng
Atmos. Chem. Phys., 21, 11759–11779, https://doi.org/10.5194/acp-21-11759-2021, https://doi.org/10.5194/acp-21-11759-2021, 2021
Short summary
Short summary
The variability, sources, and transport of ethane (C2H6) over eastern China from 2015 to 2020 were studied using ground-based Fourier transform infrared (FTIR) spectroscopy and GEOS-Chem simulations. C2H6 variability is driven by both meteorological and emission factors. The reduction in C2H6 in recent years over eastern China points to air quality improvement in China.
Ilya Stanevich, Dylan B. A. Jones, Kimberly Strong, Martin Keller, Daven K. Henze, Robert J. Parker, Hartmut Boesch, Debra Wunch, Justus Notholt, Christof Petri, Thorsten Warneke, Ralf Sussmann, Matthias Schneider, Frank Hase, Rigel Kivi, Nicholas M. Deutscher, Voltaire A. Velazco, Kaley A. Walker, and Feng Deng
Atmos. Chem. Phys., 21, 9545–9572, https://doi.org/10.5194/acp-21-9545-2021, https://doi.org/10.5194/acp-21-9545-2021, 2021
Short summary
Short summary
We explore the utility of a weak-constraint (WC) four-dimensional variational (4D-Var) data assimilation scheme for mitigating systematic errors in methane simulation in the GEOS-Chem model. We use data from the Greenhouse Gases Observing Satellite (GOSAT) and show that, compared to the traditional 4D-Var approach, the WC scheme improves the agreement between the model and independent observations. We find that the WC corrections to the model provide insight into the source of the errors.
Matthieu Dogniaux, Cyril Crevoisier, Raymond Armante, Virginie Capelle, Thibault Delahaye, Vincent Cassé, Martine De Mazière, Nicholas M. Deutscher, Dietrich G. Feist, Omaira E. Garcia, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Isamu Morino, Justus Notholt, David F. Pollard, Coleen M. Roehl, Kei Shiomi, Kimberly Strong, Yao Té, Voltaire A. Velazco, and Thorsten Warneke
Atmos. Meas. Tech., 14, 4689–4706, https://doi.org/10.5194/amt-14-4689-2021, https://doi.org/10.5194/amt-14-4689-2021, 2021
Short summary
Short summary
We present the Adaptable 4A Inversion (5AI), an implementation of the optimal estimation (OE) algorithm, relying on the Automatized Atmospheric Absorption Atlas (4A/OP) radiative transfer model, that enables the retrieval of greenhouse gas atmospheric weighted columns from infrared measurements. It is tested on a sample of Orbiting Carbon Observatory-2 observations, and its results satisfactorily compare to several reference products, thus showing the reliability of 5AI OE implementation.
Hyunkwang Lim, Sujung Go, Jhoon Kim, Myungje Choi, Seoyoung Lee, Chang-Keun Song, and Yasuko Kasai
Atmos. Meas. Tech., 14, 4575–4592, https://doi.org/10.5194/amt-14-4575-2021, https://doi.org/10.5194/amt-14-4575-2021, 2021
Short summary
Short summary
Aerosol property observations by satellites from geostationary Earth orbit (GEO) in particular have advantages of frequent sampling better than 1 h in addition to broader spatial coverage. This study provides data fusion products of aerosol optical properties from four different algorithms for two different GEO satellites: GOCI and AHI. The fused aerosol products adopted ensemble-mean and maximum-likelihood estimation methods. The data fusion provides improved results with better accuracy.
Youwen Sun, Hao Yin, Yuan Cheng, Qianggong Zhang, Bo Zheng, Justus Notholt, Xiao Lu, Cheng Liu, Yuan Tian, and Jianguo Liu
Atmos. Chem. Phys., 21, 9201–9222, https://doi.org/10.5194/acp-21-9201-2021, https://doi.org/10.5194/acp-21-9201-2021, 2021
Short summary
Short summary
We quantified the variability, source, and transport of urban CO over the Himalayas and Tibetan Plateau (HTP) by using measurement, model simulation, and the analysis of meteorological fields. Urban CO over the HTP is dominated by anthropogenic and biomass burning emissions from local, South Asia and East Asia, and oxidation sources. The decreasing trends in surface CO since 2015 in most cities over the HTP are attributed to the reduction in local and transported CO emissions in recent years.
Stefan Noël, Maximilian Reuter, Michael Buchwitz, Jakob Borchardt, Michael Hilker, Heinrich Bovensmann, John P. Burrows, Antonio Di Noia, Hiroshi Suto, Yukio Yoshida, Matthias Buschmann, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Rigel Kivi, Isamu Morino, Justus Notholt, Hirofumi Ohyama, Christof Petri, James R. Podolske, David F. Pollard, Mahesh Kumar Sha, Kei Shiomi, Ralf Sussmann, Yao Té, Voltaire A. Velazco, and Thorsten Warneke
Atmos. Meas. Tech., 14, 3837–3869, https://doi.org/10.5194/amt-14-3837-2021, https://doi.org/10.5194/amt-14-3837-2021, 2021
Short summary
Short summary
We present the first GOSAT and GOSAT-2 XCO2 data derived with the FOCAL retrieval algorithm. Comparisons of the GOSAT-FOCAL product with other data reveal long-term agreement within about 1 ppm over 1 decade, differences in seasonal variations of about 0.5 ppm, and a mean regional bias to ground-based TCCON data of 0.56 ppm with a mean scatter of 1.89 ppm. GOSAT-2-FOCAL data are preliminary only, but first comparisons show that they compare well with the GOSAT-FOCAL results and TCCON.
Michaela I. Hegglin, Susann Tegtmeier, John Anderson, Adam E. Bourassa, Samuel Brohede, Doug Degenstein, Lucien Froidevaux, Bernd Funke, John Gille, Yasuko Kasai, Erkki T. Kyrölä, Jerry Lumpe, Donal Murtagh, Jessica L. Neu, Kristell Pérot, Ellis E. Remsberg, Alexei Rozanov, Matthew Toohey, Joachim Urban, Thomas von Clarmann, Kaley A. Walker, Hsiang-Jui Wang, Carlo Arosio, Robert Damadeo, Ryan A. Fuller, Gretchen Lingenfelser, Christopher McLinden, Diane Pendlebury, Chris Roth, Niall J. Ryan, Christopher Sioris, Lesley Smith, and Katja Weigel
Earth Syst. Sci. Data, 13, 1855–1903, https://doi.org/10.5194/essd-13-1855-2021, https://doi.org/10.5194/essd-13-1855-2021, 2021
Short summary
Short summary
An overview of the SPARC Data Initiative is presented, to date the most comprehensive assessment of stratospheric composition measurements spanning 1979–2018. Measurements of 26 chemical constituents obtained from an international suite of space-based limb sounders were compiled into vertically resolved, zonal monthly mean time series. The quality and consistency of these gridded datasets are then evaluated using a climatological validation approach and a range of diagnostics.
Youwen Sun, Hao Yin, Cheng Liu, Lin Zhang, Yuan Cheng, Mathias Palm, Justus Notholt, Xiao Lu, Corinne Vigouroux, Bo Zheng, Wei Wang, Nicholas Jones, Changong Shan, Min Qin, Yuan Tian, Qihou Hu, Fanhao Meng, and Jianguo Liu
Atmos. Chem. Phys., 21, 6365–6387, https://doi.org/10.5194/acp-21-6365-2021, https://doi.org/10.5194/acp-21-6365-2021, 2021
Short summary
Short summary
This study mapped the drivers of HCHO variability from 2015 to 2019 over eastern China. Hydroxyl (OH) radical production rates from HCHO photolysis were evaluated. The relative contributions of emitted and photochemical sources to the observed HCHO abundance were analyzed. Contributions of various emission sources and geographical regions to the observed HCHO summertime enhancements were determined.
Hella van Asperen, João Rafael Alves-Oliveira, Thorsten Warneke, Bruce Forsberg, Alessandro Carioca de Araújo, and Justus Notholt
Biogeosciences, 18, 2609–2625, https://doi.org/10.5194/bg-18-2609-2021, https://doi.org/10.5194/bg-18-2609-2021, 2021
Short summary
Short summary
Termites are insects that are highly abundant in tropical ecosystems. It is known that termites emit CH4, an important greenhouse gas, but their absolute emission remains uncertain. In the Amazon rainforest, we measured CH4 emissions from termite nests and groups of termites. In addition, we tested a fast and non-destructive field method to estimate termite nest colony size. We found that termites play a significant role in an ecosystem's CH4 budget and probably emit more than currently assumed.
Thomas Blumenstock, Frank Hase, Axel Keens, Denis Czurlok, Orfeo Colebatch, Omaira Garcia, David W. T. Griffith, Michel Grutter, James W. Hannigan, Pauli Heikkinen, Pascal Jeseck, Nicholas Jones, Rigel Kivi, Erik Lutsch, Maria Makarova, Hamud K. Imhasin, Johan Mellqvist, Isamu Morino, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Uwe Raffalski, Markus Rettinger, John Robinson, Matthias Schneider, Christian Servais, Dan Smale, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, and Voltaire A. Velazco
Atmos. Meas. Tech., 14, 1239–1252, https://doi.org/10.5194/amt-14-1239-2021, https://doi.org/10.5194/amt-14-1239-2021, 2021
Short summary
Short summary
This study investigates the level of channeling (optical resonances) of each FTIR spectrometer within the Network for the Detection of Atmospheric Composition Change (NDACC). Since the air gap of the beam splitter is a significant source of channeling, we propose new beam splitters with an increased wedge of the air gap. This study shows the potential for reducing channeling in the FTIR spectrometers operated by the NDACC, thereby increasing the quality of recorded spectra across the network.
Cited articles
Arnone, E., Kero, A., Dinelli, B. M., Enell, C.-F., Arnold, N. F., Papandrea,
E., Rodger, C. J., Carlotti, M., Ridolfi, M., and Turunen, E.: Seeking
sprite-induced signatures in remotely sensed middle atmosphere NO2,
Geophys. Res. Lett., 35, L05807, https://doi.org/10.1029/2007GL031791, 2008. a
Arnone, E., Kero, A., Enell, C.-F., Carlotti, M., Rodger, C. J., Papandrea, E., Arnold, N. F., Dinelli, B. M., Ridolfi, M., and Turunen, E.: Seeking
sprite-induced signatures in remotely sensed middle atmosphere NO2:
latitude and time variations, Plasma Sources Sci. T., 18, 034014,
https://doi.org/10.1088/0963-0252/18/3/034014, 2009. a
Arnone, E., Smith, A. K., Enell, C.-F., Kero, A., and Dinelli, B. M.: WACCM
climate chemistry sensitivity to sprite perturbations, J. Geophys. Res.-Atmos., 119, 6958–6970, https://doi.org/10.1002/2013JD020825, 2014. a, b, c
Banerjee, A., Archibald, A. T., Maycock, A. C., Telford, P., Abraham, N. L., Yang, X., Braesicke, P., and Pyle, J. A.: Lightning NOx, a key chemistry–climate interaction: impacts of future climate change and consequences for tropospheric oxidising capacity, Atmos. Chem. Phys., 14, 9871–9881, https://doi.org/10.5194/acp-14-9871-2014, 2014. a
Banks, P. and Kockarts, G.: Aeronomy, Part 2, 1st edn., Academic Press, New York, USA, 372 pp., 1973. a
Becker, E. and Schmitz, G.: Energy Deposition and Turbulent Dissipation Owing
to Gravity Waves in the Mesosphere, J. Atmos. Sci., 59, 54–68,
https://doi.org/10.1175/1520-0469(2002)059<0054:EDATDO>2.0.CO;2, 2002. a
Berger, U.: Modeling of middle atmosphere dynamics with LIMA,
J. Atmos. Sol.-Terr. Phy., 70, 1170–1200, https://doi.org/10.1016/j.jastp.2008.02.004, 2008. a
Brasseur, G. P. and Solomon, S.: Aeronomy of the Middle Atmosphere, Chemistry and Physics of the Stratosphere and Mesosphere, edn. 3, Springer, Dordrecht, the Netherlands, 646 pp., https://doi.org/10.1007/1-4020-3824-0, 2005. a, b, c
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., and Wine, P. H.:
Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies,
Evaluation No. 18, JPL Publication 15–10, Jet Propulsion Laboratory,
Pasadena, California, USA, available at: https://jpldataeval.jpl.nasa.gov/pdf/JPL_Publication_15-10.pdf (last access: 17 May 2021), 2015. a
Chern, J., Hsu, R., Su, H., Mende, S., Fukunishi, H., Takahashi, Y., and Lee,
L.: Global survey of upper atmospheric transient luminous events on the
ROCSAT-2 satellite, J. Atmos. Sol.-Terr. Phy., 65, 647–659,
https://doi.org/10.1016/S1364-6826(02)00317-6, 2003. a
Chern, R. J.-S., Lin, S.-F., and Wu, A.-M.: Ten-year transient luminous events and Earth observations of FORMOSAT-2, Acta Astronaut., 112, 37–47, https://doi.org/10.1016/j.actaastro.2015.02.030, 2015. a
Crank, J. and Nicolson, P.: A practical method for numerical evaluation of
solutions of partial differential equations of the heat-conduction type,
Adv. Comput. Math., 6, 207–226, https://doi.org/10.1007/BF02127704, 1996. a
Das, U., Sinha, H. S. S., Sharma, S., Chandra, H., and Das, S. K.: Fine
structure of the low-latitude mesospheric turbulence, J. Geophys. Res.-Atmos., 114, D10111, https://doi.org/10.1029/2008JD011307, 2009. a
Denison, M. R., Lamb, J. J., Bjorndahl, W. D., Wong, E. Y., and Lohn, P. D.:
Solid rocket exhaust in the stratosphere – Plume diffusion and chemical
reactions, J. Spacecraft Rockets, 31, 435–442, https://doi.org/10.2514/3.26457, 1994. a, b
Ebel, A.: Eddy diffusion models for the mesosphere and lower thermosphere, J. Atmos. Sol.-Terr. Phy., 42, 617–628,
https://doi.org/10.1016/0021-9169(80)90096-3, 1980. a, b
Egmond, N. V. and Kesseboom, H.: Mesoscale air pollution dispersion
models – II. Lagrangian puff model and comparison with Eulerian GRID model,
Atmos. Environ., 17, 267–274, https://doi.org/10.1016/0004-6981(83)90042-2, 1983. a
Enell, C.-F., Arnone, E., Adachi, T., Chanrion, O., Verronen, P. T., Seppälä, A., Neubert, T., Ulich, T., Turunen, E., Takahashi, Y., and Hsu, R.-R.: Parameterisation of the chemical effect of sprites in the middle atmosphere, Ann. Geophys., 26, 13–27, https://doi.org/10.5194/angeo-26-13-2008, 2008. a, b
Eriksson, P., Rydberg, B., Sagawa, H., Johnston, M. S., and Kasai, Y.: Overview and sample applications of SMILES and Odin-SMR retrievals of upper tropospheric humidity and cloud ice mass, Atmos. Chem. Phys., 14, 12613–12629, https://doi.org/10.5194/acp-14-12613-2014, 2014. a
Evtushenko, A., Kuterin, F., and Mareev, E.: A model of sprite influence on the chemical balance of mesosphere, J. Atmos. Sol.-Terr. Phy., 102, 298–310, https://doi.org/10.1016/j.jastp.2013.06.005, 2013. a, b, c
Franz, R. C., Nemzek, R. J., and Winckler, J. R.: Television Image of a Large
Upward Electrical Discharge Above a Thunderstorm System, Science, 249,
48–51, https://doi.org/10.1126/science.249.4964.48, 1990. a
Gardner, C. S., Plane, J. M. C., Pan, W., Vondrak, T., Murray, B. J., and Chu, X.: Seasonal variations of the Na and Fe layers at the South Pole and their implications for the chemistry and general circulation of the polar
mesosphere, J. Geophys. Res.-Atmos., 110, D10302, https://doi.org/10.1029/2004JD005670, 2005. a
Gordillo-Vázquez, F. J.: Air plasma kinetics under the influence of
sprites, J. Phys. D Appl. Phys., 41, 234016, https://doi.org/10.1088/0022-3727/41/23/234016, 2008. a, b, c
Grygalashvyly, M., Becker, E., and Sonnemann, G. R.: Gravity Wave Mixing and
Effective Diffusivity for Minor Chemical Constituents in the Mesosphere/Lower
Thermosphere, Space Sci. Rev., 168, 333–362, https://doi.org/10.1007/s11214-011-9857-x, 2012. a
Hagelaar, G. J. M. and Pitchford, L. C.: Solving the Boltzmann equation to
obtain electron transport coefficients and rate coefficients for fluid
models, Plasma Sources Sci. T., 14, 722–733,
https://doi.org/10.1088/0963-0252/14/4/011, 2005. a, b
Heavner, M. J., Sentman, D. D., Moudry, D. R., Wescott, E. M., Siefring, C. L., Morrill, J. S., and Bucsela, E. J.: Sprites, Blue Jets, and Elves: Optical Evidence of Energy Transport Across the Stratopause, in: Atmospheric Science Across the Stratopause, edited by: Siskind, D. E., Eckermann, S. D., and Summers, M. E., AGU Monograph 123, 69–82, AGU, Washington, USA, 2000. a
Hiraki, Y., Tong, L., Fukunishi, H., Nanbu, K., Kasai, Y., and Ichimura, A.:
Generation of metastable oxygen atom O(1D) in sprite halos, Geophys.
Res. Lett., 31, L14105, https://doi.org/10.1029/2004GL020048, 2004. a
Hu, W., Cummer, S. A., and Lyons, W. A.: Testing sprite initiation theory using lightning measurements and modeled electromagnetic fields, J. Geophys. Res.-Atmos., 112, D13115, https://doi.org/10.1029/2006JD007939, 2007. a, b
Itikawa, Y. and Mason, N.: Cross Sections for Electron Collisions with Water
Molecules, J. Phys. Chem. Ref. Data, 34, 1–22, https://doi.org/10.1063/1.1799251,
2005. a
Karol, I. L., Ozolin, Y. E., and Rozanov, E. V.: Box and Gaussian plume models of the exhaust composition evolution of subsonic transport aircraft in- and out of the flight corridor, Ann. Geophys., 15, 88–96, https://doi.org/10.1007/s00585-997-0088-0, 1997. a, b
Kasai, Y., Sagawa, H., Kreyling, D., Dupuy, E., Baron, P., Mendrok, J., Suzuki, K., Sato, T. O., Nishibori, T., Mizobuchi, S., Kikuchi, K., Manabe, T., Ozeki, H., Sugita, T., Fujiwara, M., Irimajiri, Y., Walker, K. A., Bernath, P. F., Boone, C., Stiller, G., von Clarmann, T., Orphal, J., Urban, J., Murtagh, D., Llewellyn, E. J., Degenstein, D., Bourassa, A. E., Lloyd, N. D., Froidevaux, L., Birk, M., Wagner, G., Schreier, F., Xu, J., Vogt, P., Trautmann, T., and Yasui, M.: Validation of stratospheric and mesospheric ozone observed by SMILES from International Space Station, Atmos. Meas. Tech., 6, 2311–2338, https://doi.org/10.5194/amt-6-2311-2013, 2013. a
Kelley, M. C., Seyler, C. E., and Larsen, M. F.: Two-dimensional turbulence,
space shuttle plume transport in the thermosphere, and a possible relation to
the Great Siberian Impact Event, Geophys. Res. Lett., 36, L14103,
https://doi.org/10.1029/2009GL038362, 2009. a
Kikuchi, K.-I., Nishibori, T., Ochiai, S., Ozeki, H., Irimajiri, Y., Kasai, Y., Koike, M., Manabe, T., Mizukoshi, K., Murayama, Y., Nagahama, T., Sano, T., Sato, R., Seta, M., Takahashi, C., Takayanagi, M., Masuko, H., Inatani, J., Suzuki, M., and Shiotani, M.: Overview and early results of the
Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES), J.
Geophys. Res.-Atmos., 115, D23306, https://doi.org/10.1029/2010JD014379, 2010. a
Konopka, P.: Analytical Gaussian Solutions for Anisotropie Diffusion in a
Linear Shear Flow, J. Non-Equil. Thermody., 20, 78–91,
https://doi.org/10.1515/jnet.1995.20.1.78, 1995. a
Kuo, C. L., Chen, A. B., Chou, J. K., Tsai, L. Y., Hsu, R. R., Su, H. T., Frey, H. U., Mende, S. B., Takahashi, Y., and Lee, L. C.: Radiative emission and energy deposition in transient luminous events,
J. Phys. D Appl. Phys., 41, 234014, https://doi.org/10.1088/0022-3727/41/23/234014,, 2008. a
Li, K.-F., Zhang, Q., Wang, S., Sander, S. P., and Yung, Y. L.: Resolving the Model-Observation Discrepancy in the Mesospheric and Stratospheric HOx Chemistry, Earth and Space Science, 4, 607–624, https://doi.org/10.1002/2017EA000283, 2017. a, b, c
Luque, A. and Ebert, U.: Sprites in varying air density: Charge conservation,
glowing negative trails and changing velocity, Geophys. Res. Lett.,
37, L06806, https://doi.org/10.1029/2009GL041982, 2010. a, b, c, d
Neubert, T., Rycroft, M., Farges, T., Blanc, E., Chanrion, O., Arnone, E.,
Odzimek, A., Arnold, N., Enell, C.-F., Turunen, E., Bösinger, T., Mika,
Á., Haldoupis, C., Steiner, R., Velde, O., Soula, S., Berg, P., Boberg,
F., Thejll, P., Christiansen, B., Ignaccolo, M., Füllekrug, M., Verronen,
P., Montanya, J., and Crosby, N.: Recent Results from Studies of Electric
Discharges in the Mesosphere, Surv. Geophys., 29, 71–137,
https://doi.org/10.1007/s10712-008-9043-1, 2008. a
Parra-Rojas, F. C., Luque, A., and Gordillo-Vázquez, F. J.: Chemical and
electrical impact of lightning on the Earth mesosphere: The case of sprite
halos, J. Geophys. Res.-Space, 118, 5190–5214, https://doi.org/10.1002/jgra.50449, 2013. a
Parra-Rojas, F. C., Luque, A., and Gordillo-Vázquez, F. J.: Chemical and thermal impacts of sprite streamers in the Earth's mesosphere, J. Geophys.
Res.-Space, 120, 8899–8933, https://doi.org/10.1002/2014JA020933, 2015. a
Pasko, V. P., Inan, U. S., Taranenko, Y. N., and Bell, T. F.: Heating,
ionization and upward discharges in the mesosphere, due to intense
quasi-electrostatic thundercloud fields, Geophys. Res. Lett., 22, 365–368,
https://doi.org/10.1029/95GL00008, 1995. a
Pérez-Invernón, F. J., Luque, A., and Gordillo-Vázquez, F. J.:
Modeling the Chemical Impact and the Optical Emissions Produced by
Lightning-Induced Electromagnetic Fields in the Upper Atmosphere: The case of
Halos and Elves Triggered by Different Lightning Discharges, J. Geophys.
Res.-Atmos., 123, 7615–7641, https://doi.org/10.1029/2017JD028235, 2018. a
Pérez-Invernón, F. J., Malagón-Romero, A., Gordillo-Vázquez,
F. J., and Luque, A.: The Contribution of Sprite Streamers to the Chemical
Composition of the Mesosphere-Lower Thermosphere, Geophys. Res. Lett., 47,
e2020GL088578, https://doi.org/10.1029/2020GL088578, 2020. a
Picone, J. M., Hedin, A. E., Drob, D. P., and Aikin, A. C.: NRLMSISE-00
empirical model of the atmosphere: Statistical comparisons and scientific
issues, J. Geophys. Res.-Space, 107, 1468,
https://doi.org/10.1029/2002JA009430, 2002. a
Reid, G. C.: The production of water-cluster positive ions in the quiet daytime D region, Planet. Space Sci., 25, 275–290,
https://doi.org/10.1016/0032-0633(77)90138-6, 1977. a
Rodger, C. J., Seppälä, A., and Clilverd, M. A.: Significance of
transient luminous events to neutral chemistry: Experimental measurements,
Geophys. Res. Lett., 35, L07803, https://doi.org/10.1029/2008GL033221, 2008. a
Russell, J., Mlynczak, M., Gordley, L., Tansock, J., and Esplin, R.: Overview
of the SABER experiment and preliminary calibration results, Optical Spectroscopic Techniques and Instrumentation for Atmospheric
and Space Research III, in: Proc. SPIE 3756, SPIE'S International Symposium on optical Science, Engineering, and Instrumentation, Denver, Colorado, USA,
18–23 July 1999, 277–288, https://doi.org/10.1117/12.366382, 1999. a
Schumann, U. and Huntrieser, H.: The global lightning-induced nitrogen oxides source, Atmos. Chem. Phys., 7, 3823–3907, https://doi.org/10.5194/acp-7-3823-2007, 2007. a
Selvaraj, D., Patra, A., Chandra, H., Sinha, H., and Das, U.: Scattering cross section of mesospheric echoes and turbulence parameters from Gadanki radar observations, J. Atmos. Sol.-Terr. Phy., 119, 162–172,
https://doi.org/10.1016/j.jastp.2014.08.004, 2014. a
Sentman, D. D., Wescott, E., Picard, R., Winick, J., Stenbaek-Nielsen, H., Dewan, E., Moudry, D., Sabbas, F. S., Heavner, M., and Morrill, J.: Simultaneous observations of mesospheric gravity waves and sprites generated by a midwestern thunderstorm, J. Atmos. Sol.-Terr. Phy., 65, 537–550,
https://doi.org/10.1016/S1364-6826(02)00328-0, 2003. a
Shimazaki, T.: Effective eddy diffusion coefficient and atmospheric composition in the lower thermosphere, J. Atmos. Sol.-Terr. Phy., 33, 1383–1401, https://doi.org/10.1016/0021-9169(71)90011-0, 1971. a
Siskind, D. E., Stevens, M. H., Englert, C. R., and Mlynczak, M. G.: Comparison of a photochemical model with observations of mesospheric hydroxyl and ozone, J. Geophys. Res.-Atmos., 118, 195–207, https://doi.org/10.1029/2012JD017971, 2013. a, b
Smith, A. K. and Marsh, D. R.: Processes that account for the ozone maximum at the mesopause, J. Geophys. Res., 110, D23305, https://doi.org/10.1029/2005JD006298, 2005. a
Solomon, S., Crutzen, P. J., and Roble, R. G.: Photochemical coupling between the thermosphere and the lower atmosphere: 1. Odd nitrogen from 50 to 120 km, J. Geophys. Res.-Oceans, 87, 7206–7220, https://doi.org/10.1029/JC087iC09p07206, 1982. a
Sonnemann, G. R., Grygalashvyly, M., and Berger, U.: Autocatalytic water vapor production as a source of large mixing ratios within the middle to upper mesosphere, J. Geophys. Res.-Atmos., 110, D15303, https://doi.org/10.1029/2004JD005593, 2005. a
Takahashi, Y., Yoshida, A., Sato, M., Adachi, T., Kondo, S., Hsu, R.-R., Su,
H.-T., Chen, A. B., Mende, S. B., Frey, H. U., and Lee, L.-C.: Absolute
optical energy of sprites and its relationship to charge moment of parent
lightning discharge based on measurement by ISUAL/AP, J. Geophys. Res.-Space, 115, A00E55, https://doi.org/10.1029/2009JA014814, 2010. a
Waters, J. W., Froidevaux, L., Harwood, R. S., Jarnot, R. F.,
Pickett, H. M., Read, W. G., Siegel, P. H., Cofield, R. E.,
Filipiak, M. J., Flower, D. A., Holden, J. R., Lau, G. K., Livesey,
N. J., Manney, G. L., Pumphrey, H. C., Santee, M. L., Wu, D. L.,
Cuddy, D. T., Lay, R. R., Loo, M. S., Perun, V. S., Schwartz,
M. J., Stek, P. C., Thurstans, R. P., Boyles, M. A., Chandra, K. M.,
Chavez, M. C., , Chudasama, B. V., Dodge, R., Fuller, R. A.,
Girard, M. A., Jiang, J. H., , Knosp, B. W., LaBelle, R. C., Lam,
J. C., Lee, K. A., Miller, D., Oswald, J. E., Patel, N. C., Pukala,
D. M., Quintero, O., Scaff, D. M., Van Snyder, W., Tope, M. C.,
Wagner, P. A., and Walch, M. J.: The Earth observing system microwave
limb sounder (EOS MLS) on the aura Satellite, IEEE T. Geosci. Remote, 44, 1075–1092, https://doi.org/10.1109/TGRS.2006.873771, 2006. a
Winkler, H. and Notholt, J.: A model study of the plasma chemistry of
stratospheric Blue Jets, J. Atmos. Sol.-Terr. Phy., 122, 75–85,
https://doi.org/10.1016/j.jastp.2014.10.015, 2015. a, b
Winkler, H., Kazeminejad, S., Sinnhuber, M., Kallenrode, M.-B., and Notholt,
J.: Conversion of mesospheric HCl into active chlorine during the solar
proton event in July 2000 in the northern polar region, J. Geophys. Res.-Atmos., 114, D00I03, https://doi.org/10.1029/2008JD011587, 2009. a
Wong, W. and Davis, D. D.: A flash photolysis-resonance fluorescence study of the reaction of atomic hydrogen with molecular oxygen
Yamada, T., Sato, T. O., Adachi, T., Winkler, H., Kuribayashi, K., Larsson, R., Yoshida, N., Takahashi, Y., Sato, M., Chen, A. B., Hsu, R. R., Nakano, Y., Fujinawa, T., Nara, S., Uchiyama, Y., and Kasai, Y.: HO2 Generation Above Sprite-Producing Thunderstorms Derived from Low-Noise SMILES Observation Spectra, Geophys. Res. Lett., 47, e60090, https://doi.org/10.1029/2019GL085529, 2020. a, b, c, d, e, f, g, h, i, j, k, l, m
Yoon, J.-S., Song, M.-Y., Han, J.-M., Hwang, S. H., Chang, W.-S., Lee, B., and Itikawa, Y.: Cross Sections for Electron Collisions with Hydrogen
Molecules, J. Phys. Chem. Ref. Data, 37, 913–931, https://doi.org/10.1063/1.2838023, 2008. a
Short summary
Sprites are electrical discharges above thunderstorms. We performed model simulations of the chemical processes in sprites to compare them with measurements of chemical perturbations above sprite-producing thunderstorms.
Sprites are electrical discharges above thunderstorms. We performed model simulations of the...
Altmetrics
Final-revised paper
Preprint