Articles | Volume 15, issue 19
https://doi.org/10.5194/acp-15-11341-2015
https://doi.org/10.5194/acp-15-11341-2015
Research article
 | 
12 Oct 2015
Research article |  | 12 Oct 2015

Sea salt aerosols as a reactive surface for inorganic and organic acidic gases in the Arctic troposphere

J. W. Chi, W. J. Li, D. Z. Zhang, J. C. Zhang, Y. T. Lin, X. J. Shen, J. Y. Sun, J. M. Chen, X. Y. Zhang, Y. M. Zhang, and W. X. Wang

Related authors

Measurement report: The influence of particle number size distribution and hygroscopicity on the microphysical properties of cloud droplets at a mountain site
Xiaojing Shen, Quan Liu, Junying Sun, Wanlin Kong, Qianli Ma, Bing Qi, Lujie Han, Yangmei Zhang, Linlin Liang, Lei Liu, Shuo Liu, Xinyao Hu, Jiayuan Lu, Aoyuan Yu, Huizheng Che, and Xiaoye Zhang
Atmos. Chem. Phys., 25, 5711–5725, https://doi.org/10.5194/acp-25-5711-2025,https://doi.org/10.5194/acp-25-5711-2025, 2025
Short summary
Size-resolved hygroscopicity and volatility properties of ambient urban aerosol particles measured by a volatility hygroscopicity tandem differential mobility analyzer system in Beijing
Aoyuan Yu, Xiaojing Shen, Qianli Ma, Jiayuan Lu, Xinyao Hu, Yangmei Zhang, Quan Liu, Linlin Liang, Lei Liu, Shuo Liu, Hongfei Tong, Huizheng Che, Xiaoye Zhang, and Junying Sun
Atmos. Chem. Phys., 25, 3389–3412, https://doi.org/10.5194/acp-25-3389-2025,https://doi.org/10.5194/acp-25-3389-2025, 2025
Short summary
Characterization of fog microphysics and their relationships with visibility at a mountain site in China
Quan Liu, Xiaojing Shen, Junying Sun, Yangmei Zhang, Bing Qi, Qianli Ma, Lujie Han, Honghui Xu, Xinyao Hu, Jiayuan Lu, Shuo Liu, Aoyuan Yu, Linlin Liang, Qian Gao, Hong Wang, Huizheng Che, and Xiaoye Zhang
Atmos. Chem. Phys., 25, 3253–3267, https://doi.org/10.5194/acp-25-3253-2025,https://doi.org/10.5194/acp-25-3253-2025, 2025
Short summary
Insights into microphysical and optical properties of typical mineral dust within industrial-polluted snowpack via wet/dry deposition in Changchun, Northeastern China
Tenglong Shi, Jiayao Wang, Daizhou Zhang, Jiecan Cui, Zihang Wang, Yue Zhou, Wei Pu, Yang Bai, Zhigang Han, Meng Liu, Yanbiao Liu, Hongbin Xie, Minghui Yang, Ying Li, Meng Gao, and Xin Wang
EGUsphere, https://doi.org/10.5194/egusphere-2025-124,https://doi.org/10.5194/egusphere-2025-124, 2025
Short summary
Investigating the impact of subgrid-scale aerosol-cloud interaction on mesoscale meteorology prediction
Wenjie Zhang, Hong Wang, Xiaoye Zhang, Yue Peng, Zhaodong Liu, Deying Wang, Da Zhang, Chen Han, Yang Zhao, Junting Zhong, Wenxing Jia, Huiqiong Ning, and Huizheng Che
EGUsphere, https://doi.org/10.5194/egusphere-2024-3677,https://doi.org/10.5194/egusphere-2024-3677, 2025
Short summary

Related subject area

Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Enhanced emission of intermediate-volatility/semi-volatile organic matter in gas and particle phases from ship exhausts with low-sulfur fuels
Binyu Xiao, Fan Zhang, Zeyu Liu, Yan Zhang, Rui Li, Can Wu, Xinyi Wan, Yi Wang, Yubao Chen, Yong Han, Min Cui, Libo Zhang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 25, 7053–7069, https://doi.org/10.5194/acp-25-7053-2025,https://doi.org/10.5194/acp-25-7053-2025, 2025
Short summary
Measurement report: Crustal materials play an increasing role in elevating particle pH – insights from 12-year records in a typical inland city of China
Hongyu Zhang, Shenbo Wang, Zhangsen Dong, Xiao Li, and Ruiqin Zhang
Atmos. Chem. Phys., 25, 6943–6955, https://doi.org/10.5194/acp-25-6943-2025,https://doi.org/10.5194/acp-25-6943-2025, 2025
Short summary
Significant contributions of biomass burning to PM2.5-bound aromatic compounds: insights from field observations and quantum chemical calculations
Yanqin Ren, Zhenhai Wu, Fang Bi, Hong Li, Haijie Zhang, Junling Li, Rui Gao, Fangyun Long, Zhengyang Liu, Yuanyuan Ji, and Gehui Wang
Atmos. Chem. Phys., 25, 6975–6990, https://doi.org/10.5194/acp-25-6975-2025,https://doi.org/10.5194/acp-25-6975-2025, 2025
Short summary
Measurement report: In-depth characterization of ship emissions during operations in a Mediterranean port
Lise Le Berre, Brice Temime-Roussel, Grazia Maria Lanzafame, Barbara D'Anna, Nicolas Marchand, Stéphane Sauvage, Marvin Dufresne, Liselotte Tinel, Thierry Leonardis, Joel Ferreira de Brito, Alexandre Armengaud, Grégory Gille, Ludovic Lanzi, Romain Bourjot, and Henri Wortham
Atmos. Chem. Phys., 25, 6575–6605, https://doi.org/10.5194/acp-25-6575-2025,https://doi.org/10.5194/acp-25-6575-2025, 2025
Short summary
Direct measurement of N2O5 heterogeneous uptake coefficients on atmospheric aerosols in southwestern China and evaluation of current parameterizations
Jiayin Li, Tianyu Zhai, Xiaorui Chen, Haichao Wang, Shuyang Xie, Shiyi Chen, Chunmeng Li, Yuanjun Gong, Huabin Dong, and Keding Lu
Atmos. Chem. Phys., 25, 6395–6406, https://doi.org/10.5194/acp-25-6395-2025,https://doi.org/10.5194/acp-25-6395-2025, 2025
Short summary

Cited articles

Allen, H. C., Laux, J. M., Vogt, R., Finlayson-Pitts, B. J., and Hemminger, J. C.: Water-induced reorganization of ultrathin nitrate films on NaCl: implications for the tropospheric chemistry of sea salt particles, J. Phys. Chem., 100, 6371–6375, https://doi.org/10.1021/jp953675a, 1996.
Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates, Atmos. Chem. Phys., 13, 8045–8228, https://doi.org/10.5194/acp-13-8045-2013, 2013.
Andreae, M. O., Charlson, R. J., Bruynseels, F., Storms, H., Van Grieken, R., and Maeahaut, W.: Internal mixture of sea salt, silicates, and excess sulfate in marine aerosols, Science, 232, 1620–1623, https://doi.org/10.1126/science.232.4758.1620, 1986.
Ault, A. P., Peters, T. M., Sawvel, E. J., Casuccio, G. S., Willis, R. D., Norris, G. A., and Grassian, V. H.: Single-particle SEM-EDX analysis of iron-containing coarse particulate matter in an urban environment: sources and distribution of iron within Cleveland, Ohio, Environ. Sci. Technol., 46, 4331–4339, 2012.
Ault, A. P., Guasco, T. L., Ryder, O. S., Baltrusaitis, J., Cuadra-Rodriguez, L. A., Collins, D. B., Ruppel, M. J., Bertram, T. H., Prather, K. A., and Grassian, V. H.: Inside versus outside: ion redistribution in nitric acid reacted sea spray aerosol particles as determined by single particle analysis, J. Am. Chem. Soc., 135, 14528–14531, https://doi.org/10.1021/ja407117x, 2013a.
Download
Short summary
Sea salt aerosols (SSA) are dominant particles in the Arctic atmosphere. Our result suggests that the hydrophilic MgCl2 coating in fresh SSA likely intrigued the heterogeneous reactions at the beginning of SSA and acidic gases in the Arctic. The content of organic matter increased in the aged SSA compared with the fresh SSA, which suggests organic acids (beside inorganic acids) participate in the ageing of SSA in the Arctic.
Share
Altmetrics
Final-revised paper
Preprint