Articles | Volume 23, issue 16
https://doi.org/10.5194/acp-23-9597-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-9597-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
30 Aug 2023
Research article |
| 30 Aug 2023
| 30 Aug 2023
In-depth study of the formation processes of single atmospheric particles in the south-eastern margin of the Tibetan Plateau
Li Li
Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
University of Chinese Academy of Sciences, Beijing 100049, China
Qiyuan Wang
CORRESPONDING AUTHOR
Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
CAS Center for Excellence in Quaternary Science and Global Change, Xi'an 710061, China
University of Chinese Academy of Sciences, Beijing 100049, China
Jie Tian
Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
Huikun Liu
Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
Yong Zhang
Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
Steven Sai Hang Ho
Division of Atmospheric Sciences, Desert Research Institute, Reno, NV 89512, United States
Weikang Ran
Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
Junji Cao
CORRESPONDING AUTHOR
Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China
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Action Plan for the Prevention and Control of Air Pollution.
Yonggang Xue, Yu Huang, Steven Sai Hang Ho, Long Chen, Liqin Wang, Shuncheng Lee, and Junji Cao
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Jiarui Wu, Naifang Bei, Bo Hu, Suixin Liu, Meng Zhou, Qiyuan Wang, Xia Li, Lang Liu, Tian Feng, Zirui Liu, Yichen Wang, Junji Cao, Xuexi Tie, Jun Wang, Luisa T. Molina, and Guohui Li
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Yang Chen, Mi Tian, Ru-Jin Huang, Guangming Shi, Huanbo Wang, Chao Peng, Junji Cao, Qiyuan Wang, Shumin Zhang, Dongmei Guo, Leiming Zhang, and Fumo Yang
Atmos. Chem. Phys., 19, 3245–3255, https://doi.org/10.5194/acp-19-3245-2019, https://doi.org/10.5194/acp-19-3245-2019, 2019
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Amine-containing particles were characterized in an urban area of Chongqing during both summer and winter using a single-particle aerosol mass spectrometer (SPAMS). Amines were observed to internally mix with elemental carbon (EC), organic carbon (OC), sulfate, and nitrate. Diethylamine (DEA) was the most abundant in both number and peak area among amine-containing particles. Vegetation and traffic were the primary sources of particulate amines.
Qiyuan Wang, Suixin Liu, Nan Li, Wenting Dai, Yunfei Wu, Jie Tian, Yaqing Zhou, Meng Wang, Steven Sai Hang Ho, Yang Chen, Renjian Zhang, Shuyu Zhao, Chongshu Zhu, Yongming Han, Xuexi Tie, and Junji Cao
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Bowei Li, Steven Sai Hang Ho, Sunling Gong, Jingwei Ni, Huairui Li, Liyan Han, Yi Yang, Yijin Qi, and Dongxu Zhao
Atmos. Chem. Phys., 19, 617–638, https://doi.org/10.5194/acp-19-617-2019, https://doi.org/10.5194/acp-19-617-2019, 2019
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Ozone (O3) pollution is affecting Chinese cities. Volatile organic compounds (VOCs) are important contributors in the production of tropospheric O3. The local chemical species that play a vital role in O3 formation are identified. Vehicle emissions, coal + biomass burning and solvent use were the most important sources for ambient VOCs. This study provides first-hand information on the characteristics of VOCs and assists in overcoming the O3 pollution issue in Zhengzhou, China.
Nan Li, Qingyang He, Jim Greenberg, Alex Guenther, Jingyi Li, Junji Cao, Jun Wang, Hong Liao, Qiyuan Wang, and Qiang Zhang
Atmos. Chem. Phys., 18, 7489–7507, https://doi.org/10.5194/acp-18-7489-2018, https://doi.org/10.5194/acp-18-7489-2018, 2018
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Qiyuan Wang, Junji Cao, Yongming Han, Jie Tian, Chongshu Zhu, Yonggang Zhang, Ningning Zhang, Zhenxing Shen, Haiyan Ni, Shuyu Zhao, and Jiarui Wu
Atmos. Chem. Phys., 18, 4639–4656, https://doi.org/10.5194/acp-18-4639-2018, https://doi.org/10.5194/acp-18-4639-2018, 2018
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Black carbon (BC) aerosol in the Tibetan Plateau (TP) has important effects on the regional climate and hydrological processes in South and East Asia. We characterized BC at a high-altitude remote site in the southeastern Tibetan Plateau using a single-particle soot photometer and a photoacoustic extinctiometer. Our study provides insight into the sources and evolution of BC aerosol on the TP, and the results will be useful for improving models of the radiative effects in this area.
Jian Sun, Zhenxing Shen, Yu Huang, Junji Cao, Steven Sai Hang Ho, Xinyi Niu, Taobo Wang, Qian Zhang, Yali Lei, Hongmei Xu, and Hongxia Liu
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-36, https://doi.org/10.5194/acp-2018-36, 2018
Revised manuscript not accepted
Xin Long, Xuexi Tie, Junji Cao, Rujin Huang, Tian Feng, Nan Li, Suyu Zhao, Jie Tian, Guohui Li, and Qiang Zhang
Atmos. Chem. Phys., 16, 9675–9691, https://doi.org/10.5194/acp-16-9675-2016, https://doi.org/10.5194/acp-16-9675-2016, 2016
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We studied the impact of crop field burning (CFB) on air pollution in North China Plain (NCP) using MODIS observations and the numerical model WRF-CHEM. The CFB plume emitted in southern NCP and went through a long-range transport to northern NCP. The long-range transport and the effect of mountains obviously enhanced the PM2.5 pollution in northern NCP. The prohibition of CFB should be strict not just in or around Beijing, but also on the ulterior crop growth areas of southern NCP.
Miriam Elser, Ru-Jin Huang, Robert Wolf, Jay G. Slowik, Qiyuan Wang, Francesco Canonaco, Guohui Li, Carlo Bozzetti, Kaspar R. Daellenbach, Yu Huang, Renjian Zhang, Zhengqiang Li, Junji Cao, Urs Baltensperger, Imad El-Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 16, 3207–3225, https://doi.org/10.5194/acp-16-3207-2016, https://doi.org/10.5194/acp-16-3207-2016, 2016
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This work represents the first online chemical characterization of the PM2.5 using a high-resolution time-of flight aerosol mass spectrometer during extreme haze events China. The application of novel source apportionment techniques allowed for an improved identification and quantification of the sources of organic aerosols. The main sources and processes driving the extreme haze events are assessed.
Q. Y. Wang, R.-J. Huang, J. J. Cao, X. X. Tie, H. Y. Ni, Y. Q. Zhou, Y. M. Han, T. F. Hu, C. S. Zhu, T. Feng, N. Li, and J. D. Li
Atmos. Chem. Phys., 15, 13059–13069, https://doi.org/10.5194/acp-15-13059-2015, https://doi.org/10.5194/acp-15-13059-2015, 2015
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An intensive campaign was conducted at the Qinghai-Tibetan Plateau using a ground-based single particle soot photometer and a photoacoustic extinctiometer. Significant enhancements of rBC loadings and number fraction of coated rBC were observed during the pollution episode. Biomass burning from N. India is determined to be an important potential source influencing the northeastern Qinghai-Tibetan Plateau. The rBC mixing state is important in determining absorption during the pollution episode.
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
In situ measurement of organic aerosol molecular markers in urban Hong Kong during a summer period: temporal variations and source apportionment
Technical note: Determining chemical composition of atmospheric single particles by a standard-free mass calibration algorithm
Different formation pathways of nitrogen-containing organic compounds in aerosols and fog water in northern China
Impact of weather patterns and meteorological factors on PM2.5 and O3 responses to the COVID-19 lockdown in China
Daytime and nighttime aerosol soluble iron formation in clean and slightly polluted moist air in a coastal city in eastern China
Non-negligible secondary contribution to brown carbon in autumn and winter: inspiration from particulate nitrated and oxygenated aromatic compounds in urban Beijing
Simultaneous organic aerosol source apportionment at two Antarctic sites reveals large-scale and ecoregion-specific components
Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations
Bayesian inference-based estimation of hourly primary and secondary organic carbon in suburban Hong Kong: multi-temporal-scale variations and evolution characteristics during PM2.5 episodes
Measurement report: Characteristics of nitrogen-containing organics in PM2.5 in Ürümqi, northwestern China – differential impacts of combustion of fresh and aged biomass materials
Measurement report: Bio-physicochemistry of tropical clouds at Maïdo (Réunion, Indian Ocean): overview of results from the BIO-MAÏDO campaign
Chemical properties and single-particle mixing state of soot aerosol in Houston during the TRACER campaign
High Altitude Aerosol Chemical Characterization and Source Identification: Insights from the CALISHTO Campaign
Characterizing water solubility of fresh and aged secondary organic aerosol in PM2.5 with the stable carbon isotope technique
Measurement report: Evaluation of the TOF-ACSM-CV for PM1.0 and PM2.5 measurements during the RITA-2021 field campaign
Sea salt reactivity over the northwest Atlantic: an in-depth look using the airborne ACTIVATE dataset
Measurement report: Atmospheric ice nuclei in the Changbai Mountains (2623 m a.s.l.) in northeastern Asia
Morphological and optical properties of carbonaceous aerosol particles from ship emissions and biomass burning during a summer cruise measurement in the South China Sea
Critical contribution of chemically diverse carbonyl molecules to the oxidative potential of atmospheric aerosols
Tropical tropospheric aerosol sources and chemical composition observed at high altitude in the Bolivian Andes
Chemical composition, sources and formation mechanism of urban PM2.5 in Southwest China: a case study at the beginning of 2023
Chemical characterization of atmospheric aerosols at a high-altitude mountain site: a study of source apportionment
Composition and sources of carbonaceous aerosol in the European Arctic at Zeppelin Observatory, Svalbard (2017 to 2020)
Measurement Report: Size-resolved secondary organic aerosol formation modulated by aerosol water uptake in wintertime haze
Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments
Elucidating the mechanisms of atmospheric new particle formation in the highly polluted Po Valley, Italy
Water-insoluble organic carbon in PM2.5 over China: light-absorbing properties, potential sources, radiative forcing effects and possible light-absorbing continuum
Diverging trends in aerosol sulfate and nitrate measured in the remote North Atlantic on Barbados are attributed to clean air policies, African smoke, and anthropogenic emissions
Local ship speed reduction effect on black carbon emissions measured at remote marine station
Roles of marine biota in the formation of atmospheric bioaerosols, cloud condensation nuclei, and ice-nucleating particles over the North Pacific Ocean, Bering Sea, and Arctic Ocean
Evolution of nucleophilic high molecular-weight organic compounds in ambient aerosols: a case study
Fractional solubility of iron in mineral dust aerosols over coastal Namibia: a link to marine biogenic emissions?
Real-world observations of reduced nitrogen and ultrafine particles in commercial cooking organic aerosol emissions
Source apportionment of PM2.5 in Montréal, Canada, and health risk assessment for potentially toxic elements
Physicochemical and temporal characteristics of individual atmospheric aerosol particles in urban Seoul during KORUS-AQ campaign: insights from single-particle analysis
Mass spectrometric analysis of unprecedented high levels of carbonaceous aerosol particles long-range transported from wildfires in the Siberian Arctic
Short-term source apportionment of fine particulate matter with time-dependent profiles using SoFi Pro: exploring the reliability of rolling positive matrix factorization (PMF) applied to bihourly molecular and elemental tracer data
Particulate-bound alkyl nitrate pollution and formation mechanisms in Beijing, China
Measurement report: Impact of emission control measures on environmental persistent free radicals and reactive oxygen species – A short-term case study in Beijing
Characterization of water-soluble brown carbon chromophores from wildfire plumes in the western USA using size-exclusion chromatography
Marine carbohydrates in Arctic aerosol particles and fog – diversity of oceanic sources and atmospheric transformations
Investigating the contribution of grown new particles to cloud condensation nuclei with largely varying preexisting particles – Part 1: Observational data analysis
Measurement report: Brown carbon aerosol in polluted urban air of the North China Plain – day–night differences in the chromophores and optical properties
Measurement report: Secondary organic aerosols at a forested mountain site in southeastern China
Source apportionment of soot particles and aqueous-phase processing of black carbon coatings in an urban environment
Measurement report: Characteristics of airborne black carbon-containing particles during the 2021 summer COVID-19 lockdown in Yangzhou, China
Seasonal variations in composition and sources of atmospheric ultrafine particles in urban Beijing based on near-continuous measurements
Summertime response of ozone and fine particulate matter to mixing layer meteorology over the North China Plain
Trace elements in PM2.5 aerosols in East Asian outflow in the spring of 2018: emission, transport, and source apportionment
Measurement Report: Investigation on the sources and formation processes of dicarboxylic acids and related species in urban aerosols before and during the COVID-19 lockdown in Jinan, East China
Hongyong Li, Xiaopu Lyu, Likun Xue, Yunxi Huo, Dawen Yao, Haoxian Lu, and Hai Guo
Atmos. Chem. Phys., 24, 7085–7100, https://doi.org/10.5194/acp-24-7085-2024, https://doi.org/10.5194/acp-24-7085-2024, 2024
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Organic aerosol is ubiquitous in the atmosphere and largely explains the gap between current levels of fine particulate matter in many cities and the World Health Organization guideline values. This study highlights the dominant contributions of cooking emissions to organic aerosol when marine air prevailed in Hong Kong, which were occasionally overwhelmed by aromatics-derived secondary organic aerosol in continental ouflows.
Shao Shi, Jinghao Zhai, Xin Yang, Yechun Ruan, Yuanlong Huang, Xujian Chen, Antai Zhang, Jianhuai Ye, Guomao Zheng, Baohua Cai, Yaling Zeng, Yixiang Wang, Chunbo Xing, Yujie Zhang, Tzung-May Fu, Lei Zhu, Huizhong Shen, and Chen Wang
Atmos. Chem. Phys., 24, 7001–7012, https://doi.org/10.5194/acp-24-7001-2024, https://doi.org/10.5194/acp-24-7001-2024, 2024
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The determination of ions in the mass spectra of individual particles remains uncertain. We have developed a standard-free mass calibration algorithm applicable to more than 98 % of ambient particles. With our algorithm, ions with ~ 0.05 Th mass difference could be determined. Therefore, many more atmospheric species could be determined and involved in the source apportionment of aerosols, the study of chemical reaction mechanisms, and the analysis of single-particle mixing states.
Wei Sun, Xiaodong Hu, Yuzhen Fu, Guohua Zhang, Yujiao Zhu, Xinfeng Wang, Caiqing Yan, Likun Xue, He Meng, Bin Jiang, Yuhong Liao, Xinming Wang, Ping'an Peng, and Xinhui Bi
Atmos. Chem. Phys., 24, 6987–6999, https://doi.org/10.5194/acp-24-6987-2024, https://doi.org/10.5194/acp-24-6987-2024, 2024
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The formation pathways of nitrogen-containing compounds (NOCs) in the atmosphere remain unclear. We investigated the composition of aerosols and fog water by state-of-the-art mass spectrometry and compared the formation pathways of NOCs. We found that NOCs in aerosols were mainly formed through nitration reaction, while ammonia addition played a more important role in fog water. The results deepen our understanding of the processes of organic particulate pollution.
Fuzhen Shen, Michaela I. Hegglin, and Yue Yuan
Atmos. Chem. Phys., 24, 6539–6553, https://doi.org/10.5194/acp-24-6539-2024, https://doi.org/10.5194/acp-24-6539-2024, 2024
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We attempt to use a novel structural self-organising map and machine learning models to identify a weather system and quantify the importance of each meteorological factor in driving the unexpected PM2.5 and O3 changes under the specific weather system during the COVID-19 lockdown in China. The result highlights that temperature under the double-centre high-pressure system plays the most crucial role in abnormal events.
Wenshuai Li, Yuxuan Qi, Yingchen Liu, Guanru Wu, Yanjing Zhang, Jinhui Shi, Wenjun Qu, Lifang Sheng, Wencai Wang, Daizhou Zhang, and Yang Zhou
Atmos. Chem. Phys., 24, 6495–6508, https://doi.org/10.5194/acp-24-6495-2024, https://doi.org/10.5194/acp-24-6495-2024, 2024
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Aerosol particles from mainland can transport to oceans and deposit, providing soluble Fe and affecting phytoplankton growth. Thus, we studied the dissolution process of aerosol Fe and found that photochemistry played a key role in promoting Fe dissolution in clean conditions. RH-dependent reactions were more influential in slightly polluted conditions. These results highlight the distinct roles of two weather-related parameters (radiation and RH) in influencing geochemical cycles related to Fe.
Yanqin Ren, Zhenhai Wu, Yuanyuan Ji, Fang Bi, Junling Li, Haijie Zhang, Hao Zhang, Hong Li, and Gehui Wang
Atmos. Chem. Phys., 24, 6525–6538, https://doi.org/10.5194/acp-24-6525-2024, https://doi.org/10.5194/acp-24-6525-2024, 2024
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Nitrated aromatic compounds (NACs) and oxygenated derivatives of polycyclic aromatic hydrocarbons (OPAHs) in PM2.5 were examined from an urban area in Beijing during the autumn and winter. The OPAH and NAC concentrations were much higher during heating than before heating. They majorly originated from the combustion of biomass and automobile emissions, and the secondary generation was the major contributor throughout the whole sampling period.
Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
Atmos. Chem. Phys., 24, 6305–6322, https://doi.org/10.5194/acp-24-6305-2024, https://doi.org/10.5194/acp-24-6305-2024, 2024
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Applying factor analysis techniques to H-NMR spectra, we present the organic aerosol (OA) source apportionment of PM1 samples collected in parallel at two Antarctic stations, namely Signy and Halley, allowing investigation of aerosol–climate interactions in an unperturbed atmosphere. Our results show remarkable differences between pelagic (open-ocean) and sympagic (sea-ice-influenced) air masses and indicate that various sources and processes are controlling Antarctic aerosols.
Zhichao Dong, Chandra Mouli Pavuluri, Peisen Li, Zhanjie Xu, Junjun Deng, Xueyan Zhao, Xiaomai Zhao, Pingqing Fu, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 5887–5905, https://doi.org/10.5194/acp-24-5887-2024, https://doi.org/10.5194/acp-24-5887-2024, 2024
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Comprehensive study of optical properties of brown carbon (BrC) in fine aerosols from Tianjin, China, implied that biological emissions are major sources of BrC in summer, whereas fossil fuel combustion and biomass burning emissions are in cold periods. The direct radiation absorption caused by BrC in short wavelengths contributed about 40 % to that caused by BrC in 300–700 nm. Water-insoluble but methanol-soluble BrC contains more protein-like chromophores (PLOM) than that of water-soluble BrC.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 5803–5821, https://doi.org/10.5194/acp-24-5803-2024, https://doi.org/10.5194/acp-24-5803-2024, 2024
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In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal-scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Yi-Jia Ma, Yu Xu, Ting Yang, Hong-Wei Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 24, 4331–4346, https://doi.org/10.5194/acp-24-4331-2024, https://doi.org/10.5194/acp-24-4331-2024, 2024
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This study provides field-based evidence about the differential impacts of combustion of fresh and aged biomass materials on aerosol nitrogen-containing organic compounds (NOCs) in different seasons in Ürümqi, bridging the linkages between the observations and previous laboratory studies showing the formation mechanisms of NOCs.
Maud Leriche, Pierre Tulet, Laurent Deguillaume, Frédéric Burnet, Aurélie Colomb, Agnès Borbon, Corinne Jambert, Valentin Duflot, Stéphan Houdier, Jean-Luc Jaffrezo, Mickaël Vaïtilingom, Pamela Dominutti, Manon Rocco, Camille Mouchel-Vallon, Samira El Gdachi, Maxence Brissy, Maroua Fathalli, Nicolas Maury, Bert Verreyken, Crist Amelynck, Niels Schoon, Valérie Gros, Jean-Marc Pichon, Mickael Ribeiro, Eric Pique, Emmanuel Leclerc, Thierry Bourrianne, Axel Roy, Eric Moulin, Joël Barrie, Jean-Marc Metzger, Guillaume Péris, Christian Guadagno, Chatrapatty Bhugwant, Jean-Mathieu Tibere, Arnaud Tournigand, Evelyn Freney, Karine Sellegri, Anne-Marie Delort, Pierre Amato, Muriel Joly, Jean-Luc Baray, Pascal Renard, Angelica Bianco, Anne Réchou, and Guillaume Payen
Atmos. Chem. Phys., 24, 4129–4155, https://doi.org/10.5194/acp-24-4129-2024, https://doi.org/10.5194/acp-24-4129-2024, 2024
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Aerosol particles in the atmosphere play a key role in climate change and air pollution. A large number of aerosol particles are formed from the oxidation of volatile organic compounds (VOCs and secondary organic aerosols – SOA). An important field campaign was organized on Réunion in March–April 2019 to understand the formation of SOA in a tropical atmosphere mostly influenced by VOCs emitted by forest and in the presence of clouds. This work synthesizes the results of this campaign.
Ryan N. Farley, James E. Lee, Laura-Hélèna Rivellini, Alex K. Y. Lee, Rachael Dal Porto, Christopher D. Cappa, Kyle Gorkowski, Abu Sayeed Md Shawon, Katherine B. Benedict, Allison C. Aiken, Manvendra K. Dubey, and Qi Zhang
Atmos. Chem. Phys., 24, 3953–3971, https://doi.org/10.5194/acp-24-3953-2024, https://doi.org/10.5194/acp-24-3953-2024, 2024
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The black carbon aerosol composition and mixing state were characterized using a soot particle aerosol mass spectrometer. Single-particle measurements revealed the major role of atmospheric processing in modulating the black carbon mixing state. A significant fraction of soot particles were internally mixed with oxidized organic aerosol and sulfate, with implications for activation as cloud nuclei.
Olga Zografou, Maria Gini, Prodromos Fetfatzis, Konstantinos Granakis, Romanos Foskinis, Manousos Ioannis Manousakas, Fotios Tsopelas, Evangelia Diapouli, Eleni Dovrou, Christina N. Vasilakopoulou, Alexandros Papayannis, Spyros N. Pandis, Athanasios Nenes, and Konstantinos Eleftheriadis
EGUsphere, https://doi.org/10.5194/egusphere-2024-737, https://doi.org/10.5194/egusphere-2024-737, 2024
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PM1 chemical characterization and PMF source apportionment on the combined organic and inorganic fraction took place at the high-altitude (HAC)2 station. Cloud presence was found to reduce PM1 concentrations, affecting sulphate more than organics. Interstitial aerosol was richer in low hygroscopic organics and acidic inorganics, compared to activated. Higher relative abundance of eBC compared to the other components was revealed for FT conditions compared to PBL.
Fenghua Wei, Xing Peng, Liming Cao, Mengxue Tang, Ning Feng, Xiaofeng Huang, and Lingyan He
EGUsphere, https://doi.org/10.5194/egusphere-2024-736, https://doi.org/10.5194/egusphere-2024-736, 2024
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The water solubility of secondary organic aerosols (SOA) is a crucial factor in determining their hygroscopicity and climatic impact. Stable carbon isotope and mass spectrometry techniques were combined to assess the water solubility of SOA with different aging degrees in a coastal megacity in China. This work revealed a much higher water-soluble fraction of aged SOA compared to fresh SOA, indicating that the aging degree of SOA has considerable impacts on its water solubility.
Xinya Liu, Bas Henzing, Arjan Hensen, Jan Mulder, Peng Yao, Danielle van Dinther, Jerry van Bronckhorst, Rujin Huang, and Ulrike Dusek
Atmos. Chem. Phys., 24, 3405–3420, https://doi.org/10.5194/acp-24-3405-2024, https://doi.org/10.5194/acp-24-3405-2024, 2024
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We evaluated the time-of-flight aerosol chemical speciation monitor (TOF-ACSM) following the implementation of the PM2.5 aerodynamic lens and a capture vaporizer (CV). The results showed that it significantly improved the accuracy and precision of ACSM in the field observations. The paper elucidates the measurement outcomes of various instruments and provides an analysis of their biases. This comprehensive evaluation is expected to benefit the ACSM community and other aerosol field measurements.
Eva-Lou Edwards, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Claire E. Robinson, Michael A. Shook, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 3349–3378, https://doi.org/10.5194/acp-24-3349-2024, https://doi.org/10.5194/acp-24-3349-2024, 2024
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We investigate Cl− depletion in sea salt particles over the northwest Atlantic from December 2021 to June 2022 using an airborne dataset. Losses of Cl− are greatest in May and least in December–February and March. Inorganic acidic species can account for all depletion observed for December–February, March, and June near Bermuda but none in May. Quantifying Cl− depletion as a percentage captures seasonal trends in depletion but fails to convey the effects it may have on atmospheric oxidation.
Yue Sun, Yujiao Zhu, Yanbin Qi, Lanxiadi Chen, Jiangshan Mu, Ye Shan, Yu Yang, Yanqiu Nie, Ping Liu, Can Cui, Ji Zhang, Mingxuan Liu, Lingli Zhang, Yufei Wang, Xinfeng Wang, Mingjin Tang, Wenxing Wang, and Likun Xue
Atmos. Chem. Phys., 24, 3241–3256, https://doi.org/10.5194/acp-24-3241-2024, https://doi.org/10.5194/acp-24-3241-2024, 2024
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Field observations were conducted at the summit of Changbai Mountain in northeast Asia. The cumulative number concentration of ice-nucleating particles (INPs) varied from 1.6 × 10−3 to 78.3 L−1 over the temperature range of −5.5 to −29.0 ℃. Biological INPs (bio-INPs) accounted for the majority of INPs, and the proportion exceeded 90% above −13.0 ℃. Planetary boundary layer height, valley breezes, and long-distance transport of air mass influence the abundance of bio-INPs.
Cuizhi Sun, Yongyun Zhang, Baoling Liang, Min Gao, Xi Sun, Fei Li, Xue Ni, Qibin Sun, Hengjia Ou, Dexian Chen, Shengzhen Zhou, and Jun Zhao
Atmos. Chem. Phys., 24, 3043–3063, https://doi.org/10.5194/acp-24-3043-2024, https://doi.org/10.5194/acp-24-3043-2024, 2024
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In a May–June 2021 expedition in the South China Sea, we analyzed black and brown carbon in marine aerosols, key to light absorption and climate impact. Using advanced in situ and microscope techniques, we observed particle size, structure, and tar balls mixed with various elements. Results showed biomass burning and fossil fuels majorly influence light absorption, especially during significant burning events. This research aids the understanding of carbonaceous aerosols' role in marine climate.
Feifei Li, Shanshan Tang, Jitao Lv, Shiyang Yu, Xu Sun, Dong Cao, Yawei Wang, and Guibin Jiang
EGUsphere, https://doi.org/10.5194/egusphere-2024-37, https://doi.org/10.5194/egusphere-2024-37, 2024
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Targeted derivatization and non-targeted analysis with FT-ICR MS were used to reveal the molecular composition of carbonyl molecules in PM2.5, and the important role of carbonyls in increasing the oxidative potential of organic aerosol was found in the real samples.
C. Isabel Moreno, Radovan Krejci, Jean-Luc Jaffrezo, Gaëlle Uzu, Andrés Alastuey, Marcos F. Andrade, Valeria Mardóñez, Alkuin Maximilian Koenig, Diego Aliaga, Claudia Mohr, Laura Ticona, Fernando Velarde, Luis Blacutt, Ricardo Forno, David N. Whiteman, Alfred Wiedensohler, Patrick Ginot, and Paolo Laj
Atmos. Chem. Phys., 24, 2837–2860, https://doi.org/10.5194/acp-24-2837-2024, https://doi.org/10.5194/acp-24-2837-2024, 2024
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Aerosol chemical composition (ions, sugars, carbonaceous matter) from 2011 to 2020 was studied at Mt. Chacaltaya (5380 m a.s.l., Bolivian Andes). Minimum concentrations occur in the rainy season with maxima in the dry and transition seasons. The origins of the aerosol are located in a radius of hundreds of kilometers: nearby urban and rural areas, natural biogenic emissions, vegetation burning from Amazonia and Chaco, Pacific Ocean emissions, soil dust, and Peruvian volcanism.
Junke Zhang, Yunfei Su, Chunying Chen, Wenkai Guo, Qinwen Tan, Miao Feng, Danlin Song, Tao Jiang, Qiang Chen, Yuan Li, Wei Li, Yizhi Wang, Xiaojuan Huang, Lin Han, Wanqing Wu, and Gehui Wang
Atmos. Chem. Phys., 24, 2803–2820, https://doi.org/10.5194/acp-24-2803-2024, https://doi.org/10.5194/acp-24-2803-2024, 2024
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Typical haze events in Chengdu at the beginning of 2023 were investigated with bulk-chemical and single-particle analyses along with numerical model simulations. By integrating the obtained chemical composition, source, mixing state and numerical simulation results, we infer that Haze-1 was mainly caused by pollutants related to fossil fuel combustion, especially local mobile sources, while Haze-2 was triggered by the secondary pollutants, which mainly came from regional transmission.
Elena Barbaro, Matteo Feltracco, Fabrizio De Blasi, Clara Turetta, Marta Radaelli, Warren Cairns, Giulio Cozzi, Giovanna Mazzi, Marco Casula, Jacopo Gabrieli, Carlo Barbante, and Andrea Gambaro
Atmos. Chem. Phys., 24, 2821–2835, https://doi.org/10.5194/acp-24-2821-2024, https://doi.org/10.5194/acp-24-2821-2024, 2024
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The study analyzed a year of atmospheric aerosol composition at Col Margherita in the Italian Alps. Over 100 chemical markers were identified, including major ions, organic compounds, and trace elements. It revealed sources of aerosol, highlighted impacts of Saharan dust events, and showed anthropogenic pollution's influence despite the site's remoteness. Enrichment factors emphasized non-natural sources of trace elements. Source apportionment identified four key factors affecting the area.
Karl Espen Yttri, Are Bäcklund, Franz Conen, Sabine Eckhardt, Nikolaos Evangeliou, Markus Fiebig, Anne Kasper-Giebl, Avram Gold, Hans Gundersen, Cathrine Lund Myhre, Stephen Matthew Platt, David Simpson, Jason D. Surratt, Sönke Szidat, Martin Rauber, Kjetil Tørseth, Martin Album Ytre-Eide, Zhenfa Zhang, and Wenche Aas
Atmos. Chem. Phys., 24, 2731–2758, https://doi.org/10.5194/acp-24-2731-2024, https://doi.org/10.5194/acp-24-2731-2024, 2024
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We discuss carbonaceous aerosol (CA) observed at the high Arctic Zeppelin Observatory (2017 to 2020). We find that organic aerosol is a significant fraction of the Arctic aerosol, though less than sea salt aerosol and mineral dust, as well as non-sea-salt sulfate, originating mainly from anthropogenic sources in winter and from natural sources in summer, emphasizing the importance of wildfires for biogenic secondary organic aerosol and primary biological aerosol particles observed in the Arctic.
Jing Duan, Ru-Jin Huang, Ying Wang, Wei Xu, Haobin Zhong, Chunshui Lin, Wei Huang, Yifang Gu, Jurgita Ovadnevaite, Darius Ceburnis, and Colin O’Dowd
EGUsphere, https://doi.org/10.5194/egusphere-2024-573, https://doi.org/10.5194/egusphere-2024-573, 2024
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The chemical composition of atmospheric particles showed significant changes in recent years. We investigated the potential effects of inorganics changes on aerosol water uptake and thus secondary organic aerosol formation in wintertime haze, based on the size-resolved measurements of non-refractory fine particulate matter (NR-PM2.5) in Xi’an, Northwest China. This study highlights the key role of aerosol water as a medium to link inorganics and organics in their multiphase processes.
Wei Huang, Cheng Wu, Linyu Gao, Yvette Gramlich, Sophie L. Haslett, Joel Thornton, Felipe D. Lopez-Hilfiker, Ben H. Lee, Junwei Song, Harald Saathoff, Xiaoli Shen, Ramakrishna Ramisetty, Sachchida N. Tripathi, Dilip Ganguly, Feng Jiang, Magdalena Vallon, Siegfried Schobesberger, Taina Yli-Juuti, and Claudia Mohr
Atmos. Chem. Phys., 24, 2607–2624, https://doi.org/10.5194/acp-24-2607-2024, https://doi.org/10.5194/acp-24-2607-2024, 2024
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We present distinct molecular composition and volatility of oxygenated organic aerosol particles in different rural, urban, and mountain environments. We do a comprehensive investigation of the relationship between the chemical composition and volatility of oxygenated organic aerosol particles across different systems and environments. This study provides implications for volatility descriptions of oxygenated organic aerosol particles in different model frameworks.
Jing Cai, Juha Sulo, Yifang Gu, Sebastian Holm, Runlong Cai, Steven Thomas, Almuth Neuberger, Fredrik Mattsson, Marco Paglione, Stefano Decesari, Matteo Rinaldi, Rujing Yin, Diego Aliaga, Wei Huang, Yuanyuan Li, Yvette Gramlich, Giancarlo Ciarelli, Lauriane Quéléver, Nina Sarnela, Katrianne Lehtipalo, Nora Zannoni, Cheng Wu, Wei Nie, Juha Kangasluoma, Claudia Mohr, Markku Kulmala, Qiaozhi Zha, Dominik Stolzenburg, and Federico Bianchi
Atmos. Chem. Phys., 24, 2423–2441, https://doi.org/10.5194/acp-24-2423-2024, https://doi.org/10.5194/acp-24-2423-2024, 2024
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By combining field measurements, simulations and recent chamber experiments, we investigate new particle formation (NPF) and growth in the Po Valley, where both haze and frequent NPF occur. Our results show that sulfuric acid, ammonia and amines are the dominant NPF precursors there. A high NPF rate and a lower condensation sink lead to a greater survival probability for newly formed particles, highlighting the importance of gas-to-particle conversion for aerosol concentrations.
Yangzhi Mo, Jun Li, Guangcai Zhong, Sanyuan Zhu, Shizhen Zhao, Jiao Tang, Hongxing Jiang, Zhineng Cheng, Chongguo Tian, Yingjun Chen, and Gan Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-130, https://doi.org/10.5194/egusphere-2024-130, 2024
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In this study, we found that biomass burning (31.0 %) and coal combustion (31.1 %), were the dominant sources of water-insoluble organic carbon in China, with coal combustion sources exhibited the strongest light-absorbing capacity. Additionally, we propose a light-absorbing carbonaceous continuum, revealing that components enriched with fossil sources tend to have stronger light-absorbing capacity, higher aromaticity, higher molecular weights, and greater recalcitrance in the atmosphere.
Cassandra J. Gaston, Joseph M. Prospero, Kristen Foley, Havala O. T. Pye, Lillian Custals, Edmund Blades, Peter Sealy, and James A. Christie
EGUsphere, https://doi.org/10.5194/egusphere-2024-11, https://doi.org/10.5194/egusphere-2024-11, 2024
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To understand how changing emissions have impacted aerosols in remote regions, we measured nitrate and sulfate at Barbados and compared to model predictions from EPA’s Air QUAlity TimE Series (EQUATES). Nitrate was stable except for spikes in 2008 and 2010 due to transported smoke. Sulfate decreased in the 1990s due to reductions of sulfur dioxide (SO2) in the U.S. and Europe, then increased in the 2000s due to anthropogenic emissions from Africa and more efficient oxidation of SO2.
Mikko Heikkilä, Krista Luoma, Timo Mäkelä, and Tiia Grönholm
EGUsphere, https://doi.org/10.5194/egusphere-2023-2823, https://doi.org/10.5194/egusphere-2023-2823, 2024
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Black carbon (BC) concentration was measured from 211 ship exhaust gas plumes at a remote marine station. Emission factors of BC were calculated in grams/kilograms fuel. Ships using exhaust gas cleaning systems (EGCS) were found to emit 80 % less BC than ships without EGCS. Emission factors were used to model BC emissions as a function of speed to define the effect of speed reduction. BC emissions increased with a decrease in speed from the ship’s service speed.
Kaori Kawana, Fumikazu Taketani, Kazuhiko Matsumoto, Yutaka Tobo, Yoko Iwamoto, Takuma Miyakawa, Akinori Ito, and Yugo Kanaya
Atmos. Chem. Phys., 24, 1777–1799, https://doi.org/10.5194/acp-24-1777-2024, https://doi.org/10.5194/acp-24-1777-2024, 2024
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Based on comprehensive shipborne observations, we found strong links between sea-surface biological materials and the formation of atmospheric fluorescent bioaerosols, cloud condensation nuclei, and ice-nucleating particles over the Arctic Ocean and Bering Sea during autumn 2019. Taking the wind-speed effect into account, we propose equations to approximate the links for this cruise, which can be used as a guide for modeling as well as for systematic comparisons with other observations.
Chen He, Hanxiong Che, Zier Bao, Yiliang Liu, Qing Li, Miao Hu, Jiawei Zhou, Shumin Zhang, Xiaojiang Yao, Quan Shi, Chunmao Chen, Yan Han, Lingshuo Meng, Xin Long, Fumo Yang, and Yang Chen
Atmos. Chem. Phys., 24, 1627–1639, https://doi.org/10.5194/acp-24-1627-2024, https://doi.org/10.5194/acp-24-1627-2024, 2024
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We examined the daily evolution of high molecular-weight organic compounds with a molecular weight of up to 1000 Da in order to comprehend their behaviors in the atmosphere under actual conditions. These compounds were proven to undergo multi-generation oxidation, carboxylation, and nitrification via both day- and nighttime chemistry.
Karine Desboeufs, Paola Formenti, Raquel Torres-Sánchez, Kerstin Schepanski, Jean-Pierre Chaboureau, Hendrik Andersen, Jan Cermak, Stefanie Feuerstein, Benoit Laurent, Danitza Klopper, Andreas Namwoonde, Mathieu Cazaunau, Servanne Chevaillier, Anaïs Feron, Cécile Mirande-Bret, Sylvain Triquet, and Stuart J. Piketh
Atmos. Chem. Phys., 24, 1525–1541, https://doi.org/10.5194/acp-24-1525-2024, https://doi.org/10.5194/acp-24-1525-2024, 2024
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This study investigates the fractional solubility of iron (Fe) in dust particles along the coast of Namibia, a critical region for the atmospheric Fe supply of the South Atlantic Ocean. Our results suggest a possible two-way interplay whereby marine biogenic emissions from the coastal marine ecosystems into the atmosphere would increase the solubility of Fe-bearing dust by photo-reduction processes. The subsequent deposition of soluble Fe could act to further enhance marine biogenic emissions.
Sunhye Kim, Jo Machesky, Drew R. Gentner, and Albert A. Presto
Atmos. Chem. Phys., 24, 1281–1298, https://doi.org/10.5194/acp-24-1281-2024, https://doi.org/10.5194/acp-24-1281-2024, 2024
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Cooking emissions are often an overlooked source of air pollution. We used a mobile lab to measure the characteristics of particles emitted from cooking sites in two cities. Our findings showed that cooking releases a substantial number of fine particles. While most emissions were similar, a bakery site showed distinctive chemical compositions with higher nitrogen compound levels. Thus, understanding the particle emissions from different cooking activities is crucial.
Nansi Fakhri, Robin Stevens, Arnold Downey, Konstantina Oikonomou, Jean Sciare, Charbel Afif, and Patrick L. Hayes
Atmos. Chem. Phys., 24, 1193–1212, https://doi.org/10.5194/acp-24-1193-2024, https://doi.org/10.5194/acp-24-1193-2024, 2024
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We investigated the chemical composition of atmospheric fine particles, their emission sources, and the potential human health risk associated with trace elements in particles for an urban site in Montréal over a 3-month period (August–November). This study represents the first time that such extensive composition measurements were included in an urban source apportionment study in Canada, and it provides greater resolution of fine-particle sources than has been previously achieved in Canada.
Hanjin Yoo, Li Wu, Hong Geng, and Chul-Un Ro
Atmos. Chem. Phys., 24, 853–867, https://doi.org/10.5194/acp-24-853-2024, https://doi.org/10.5194/acp-24-853-2024, 2024
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We conducted an investigation of atmospheric aerosols collected in Seoul, South Korea, during the KORUS-AQ campaign on a single-particle basis. We were able to identify their sources, the atmospheric fate, and the impacts of local emissions and long-range transport on aerosol composition. Additionally, we traced potential sources of non-exhaust heavy-metal particles. This comprehensive analysis provides valuable insights into the complex dynamics of urban aerosols.
Eric Schneider, Hendryk Czech, Olga Popovicheva, Marina Chichaeva, Vasily Kobelev, Nikolay Kasimov, Tatiana Minkina, Christopher Paul Rüger, and Ralf Zimmermann
Atmos. Chem. Phys., 24, 553–576, https://doi.org/10.5194/acp-24-553-2024, https://doi.org/10.5194/acp-24-553-2024, 2024
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This study provides insights into the complex chemical composition of long-range-transported wildfire plumes from Yakutia, which underwent different levels of atmospheric processing. With complementary mass spectrometric techniques, we improve our understanding of the chemical processes and atmospheric fate of wildfire plumes. Unprecedented high levels of carbonaceous aerosols crossed the polar circle with implications for the Arctic ecosystem and consequently climate.
Qiongqiong Wang, Shuhui Zhu, Shan Wang, Cheng Huang, Yusen Duan, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 475–486, https://doi.org/10.5194/acp-24-475-2024, https://doi.org/10.5194/acp-24-475-2024, 2024
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We investigated short-term source apportionment of PM2.5 utilizing rolling positive matrix factorization (PMF) and online PM chemical speciation data, which included source-specific organic tracers collected over a period of 37 d during the winter of 2019–2020 in suburban Shanghai, China. The findings highlight that by imposing constraints on the primary source profiles, short-term PMF analysis successfully replicated both the individual primary sources and the total secondary sources.
Jiyuan Yang, Guoyang Lei, Jinfeng Zhu, Yutong Wu, Chang Liu, Kai Hu, Junsong Bao, Zitong Zhang, Weili Lin, and Jun Jin
Atmos. Chem. Phys., 24, 123–136, https://doi.org/10.5194/acp-24-123-2024, https://doi.org/10.5194/acp-24-123-2024, 2024
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The atmospheric pollution and formation mechanisms of particulate-bound alkyl nitrate in Beijing were studied. C9–C16 long-chain n-alkyl nitrates negatively correlated with O3 but positively correlated with PM2.5 and NO2, so they may not be produced during gas-phase homogeneous reactions in the photochemical process but form through reactions between alkanes and nitrates on PM surfaces. Particulate-bound n-alkyl nitrates strongly affect both haze pollution and atmospheric visibility.
Yuanyuan Qin, Xinghua Zhang, Wei Huang, Juanjuan Qin, Xiaoyu Hu, Yuxuan Cao, Tianyi Zhao, Yang Zhang, Jihua Tan, Ziyin Zhang, Xinming Wang, and Zhenzhen Wang
EGUsphere, https://doi.org/10.5194/egusphere-2023-2703, https://doi.org/10.5194/egusphere-2023-2703, 2024
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Environmental persistent free radicals (EPFRs) and reactive oxygen species (ROS) play an active role in the atmosphere. We quantified the impact of control measures on EPFRs and ROS and found that strict control measures have effectively reduced their emissions, largely linked to a significant decrease in secondary aerosols. Our findings have great implications for further understanding the formation and sources and for developing future air quality management policies targeting EPFRs and ROS.
Lisa Azzarello, Rebecca A. Washenfelder, Michael A. Robinson, Alessandro Franchin, Caroline C. Womack, Christopher D. Holmes, Steven S. Brown, Ann Middlebrook, Tim Newberger, Colm Sweeney, and Cora J. Young
Atmos. Chem. Phys., 23, 15643–15654, https://doi.org/10.5194/acp-23-15643-2023, https://doi.org/10.5194/acp-23-15643-2023, 2023
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We present a molecular size-resolved offline analysis of water-soluble brown carbon collected on an aircraft during FIREX-AQ. The smoke plumes were aged 0 to 5 h, where absorption was dominated by small molecular weight molecules, brown carbon absorption downwind did not consistently decrease, and the measurements differed from online absorption measurements of the same samples. We show how differences between online and offline absorption could be related to different measurement conditions.
Sebastian Zeppenfeld, Manuela van Pinxteren, Markus Hartmann, Moritz Zeising, Astrid Bracher, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 15561–15587, https://doi.org/10.5194/acp-23-15561-2023, https://doi.org/10.5194/acp-23-15561-2023, 2023
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Marine carbohydrates are produced in the surface of the ocean, enter the atmophere as part of sea spray aerosol particles, and potentially contribute to the formation of fog and clouds. Here, we present the results of a sea–air transfer study of marine carbohydrates conducted in the high Arctic. Besides a chemo-selective transfer, we observed a quick atmospheric aging of carbohydrates, possibly as a result of both biotic and abiotic processes.
Xing Wei, Yanjie Shen, Xiao-Ying Yu, Yang Gao, Huiwang Gao, Ming Chu, Yujiao Zhu, and Xiaohong Yao
Atmos. Chem. Phys., 23, 15325–15350, https://doi.org/10.5194/acp-23-15325-2023, https://doi.org/10.5194/acp-23-15325-2023, 2023
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We investigate the contribution of grown new particles to Nccn at a rural mountain site in the North China Plain. The total particle number concentrations (Ncn) observed on 8 new particle formation (NPF) days were higher compared to non-NPF days. The Nccn at 0.2 % supersaturation (SS) and 0.4 % SS on the NPF days was significantly lower than on non-NPF days. Only one of eight NPF events had detectable net contributions to Nccn at 0.4 % SS and 1.0 % SS with increased κ values.
Yuquan Gong, Ru-Jin Huang, Lu Yang, Ting Wang, Wei Yuan, Wei Xu, Wenjuan Cao, Yang Wang, and Yongjie Li
Atmos. Chem. Phys., 23, 15197–15207, https://doi.org/10.5194/acp-23-15197-2023, https://doi.org/10.5194/acp-23-15197-2023, 2023
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This study reveals the large day–night differences in brown carbon (BrC) chromophore composition, which was not known previously. The results provide insights into the effects of atmospheric processes and emissions on BrC composition.
Zijun Zhang, Weiqi Xu, Yi Zhang, Wei Zhou, Xiangyu Xu, Aodong Du, Yinzhou Zhang, Hongqin Qiao, Ye Kuang, Xiaole Pan, Zifa Wang, Xueling Cheng, Lanzhong Liu, Qingyang Fu, Douglas R. Worsnop, Jie Li, and Yele Sun
EGUsphere, https://doi.org/10.5194/egusphere-2023-2684, https://doi.org/10.5194/egusphere-2023-2684, 2023
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We investigated aerosol composition, sources, and the interaction between secondary organic aerosol (SOA) and clouds at a regional mountain site in southeastern China. Clouds efficiently scavenge more-oxidized SOA; however, cloud evaporation leads to the production of less-oxidized SOA. The unexpectedly high presence of nitrate in aerosol particles indicates that nitrate formed in polluted areas has undergone interactions with clouds, significantly influencing the regional background site.
Ryan N. Farley, Sonya Collier, Christopher D. Cappa, Leah R. Williams, Timothy B. Onasch, Lynn M. Russell, Hwajin Kim, and Qi Zhang
Atmos. Chem. Phys., 23, 15039–15056, https://doi.org/10.5194/acp-23-15039-2023, https://doi.org/10.5194/acp-23-15039-2023, 2023
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Soot particles, also known as black carbon (BC), have important implications for global climate and regional air quality. After the particles are emitted, BC can be coated with other material, impacting the aerosol properties. We selectively measured the composition of particles containing BC to explore their sources and chemical transformations in the atmosphere. We focus on a persistent, multiday fog event in order to study the effects of chemical reactions occurring within liquid droplets.
Yuan Dai, Junfeng Wang, Houjun Wang, Shijie Cui, Yunjiang Zhang, Haiwei Li, Yun Wu, Ming Wang, Eleonora Aruffo, and Xinlei Ge
EGUsphere, https://doi.org/10.5194/egusphere-2023-2454, https://doi.org/10.5194/egusphere-2023-2454, 2023
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Short-term strict emission control can improve air quality but the effectiveness requires assessment. During 2021 summer COVID-19 lockdown in Yangzhou, we showed that the PM2.5 level did not decrease with decrease of gaseous pollutants as aged black carbon-containing particles increased substantially, due to enhanced atmospheric oxidizing capacity and high relative humidity. The results highlights the importance of a regionally balanced control strategy for future air quality management.
Xiaoxiao Li, Yijing Chen, Yuyang Li, Runlong Cai, Yiran Li, Chenjuan Deng, Jin Wu, Chao Yan, Hairong Cheng, Yongchun Liu, Markku Kulmala, Jiming Hao, James N. Smith, and Jingkun Jiang
Atmos. Chem. Phys., 23, 14801–14812, https://doi.org/10.5194/acp-23-14801-2023, https://doi.org/10.5194/acp-23-14801-2023, 2023
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Near-continuous measurements show the composition, sources, and seasonal variations of ultrafine particles (UFPs) in urban Beijing. Vehicle and cooking emissions and new particle formation are the main sources of UFPs, and aqueous/heterogeneous processes increase UFP mode diameters. UFPs are the highest in winter due to the highest primary particle emission rates and new particle formation rates, and CHO fractions are the highest in summer due to the strongest photooxidation.
Jiaqi Wang, Jian Gao, Fei Che, Xin Yang, Yuanqin Yang, Lei Liu, Yan Xiang, and Haisheng Li
Atmos. Chem. Phys., 23, 14715–14733, https://doi.org/10.5194/acp-23-14715-2023, https://doi.org/10.5194/acp-23-14715-2023, 2023
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Regional-scale observations of surface O3, PM2.5 and its major chemical species, mixing layer height (MLH), and other meteorological parameters were made in the North China Plain during summer. Unlike the cold season, synchronized increases in MDA8 O3 and PM2.5 under medium MLH conditions have been witnessed. The increasing trend of PM2.5 was associated with enhanced secondary chemical formation. The correlation between MLH and secondary air pollutants should be treated with care in hot seasons.
Takuma Miyakawa, Akinori Ito, Chunmao Zhu, Atsushi Shimizu, Erika Matsumoto, Yusuke Mizuno, and Yugo Kanaya
Atmos. Chem. Phys., 23, 14609–14626, https://doi.org/10.5194/acp-23-14609-2023, https://doi.org/10.5194/acp-23-14609-2023, 2023
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This study conducted semi-continuous measurements of PM2.5 aerosols and their elemental composition in western Japan, during spring 2018. It analyzed the emissions, transport, and wet removal of elements such as Pb, Cu, Fe, and Mn. It also assessed the accuracy of modeled concentrations and found overestimations of BC and underestimations of Cu and anthropogenic Fe in East Asia. Insights into emissions, removals, and source apportionment of trace metals in the East Asian outflow were provided.
Jingjing Meng, Yachen Wang, Yuanyuan Li, Tonglin Huang, Zhifei Wang, Yiqiu Wang, Min Chen, Zhanfang Hou, Houhua Zhou, Keding Lu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 14481–14503, https://doi.org/10.5194/acp-23-14481-2023, https://doi.org/10.5194/acp-23-14481-2023, 2023
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This study investigated the effect of COVID-19 lockdown (LCD) measures on the formation and evolutionary process of diacids and related compounds from field observations. Results demonstrate that more aged organic aerosols are observed during the LCD due to the enhanced photochemical oxidation. Our study also found that the reactivity of 13C was higher than that of 12C in the gaseous photochemical oxidation, leading to higher δ13C values of C2 during the LCD than before the LCD.
Cited articles
Alexander, B., Hastings, M. G., Allman, D. J., Dachs, J., Thornton, J. A., and Kunasek, S. A.: Quantifying atmospheric nitrate formation pathways based on a global model of the oxygen isotopic composition (Δ17O) of atmospheric nitrate, Atmos. Chem. Phys., 9, 5043–5056, https://doi.org/10.5194/acp-9-5043-2009, 2009.
Allen, J. O., Fergenson, D. P., Gard, E. E., Hughes, L. S., Morrical, B. D.,
Kleeman, M. J., Gross, D. S., Gälli, M. E., Prather, K. A., and Cass, G.
R.: Particle Detection Efficiencies of Aerosol Time of Flight Mass
Spectrometers under Ambient Sampling Conditions, Environ. Sci. Technol., 34,
211–217, https://doi.org/10.1021/es9904179, 2000.
Aruffo, E., Wang, J., Ye, J., Ohno, P., Qin, Y., Stewart, M., McKinney, K.,
Di Carlo, P., and Martin, S. T.: Partitioning of Organonitrates in the
Production of Secondary Organic Aerosols from α-Pinene Photo-Oxidation, Environ. Sci. Technol., 56, 5421–5429,
https://doi.org/10.1021/acs.est.1c08380, 2022.
Bi, X. H., Zhang, G. H., Li, L., Wang, X. M., Li, M., Sheng, G. Y., Fu, J.
M., and Zhou, Z.: Mixing state of biomass burning particles by single
particle aerosol mass spectrometer in the urban area of PRD, China, Atmos.
Environ., 45, 3447–3453, https://doi.org/10.1016/j.atmosenv.2011.03.034,
2011.
Bi, X. H., Lin, Q. H., Peng, L., Zhang, G. H., Wang, X. M., Brechtel, F. J.,
Chen, D. H., Li, M., Peng, P. A., Sheng, G. Y., and Zhou, Z.: In situ
detection of the chemistry of individual fog droplet residues in the Pearl
River Delta region, China, J. Geophys. Res.-Atmos., 121, 9105–9116,
https://doi.org/10.1002/2016jd024886, 2016.
Budisulistiorini, S. H., Riva, M., Williams, M., Chen, J., Itoh, M.,
Surratt, J. D., and Kuwata, M.: Light-absorbing brown carbon aerosol
constituents from combustion of Indonesian peat and biomass, Environ. Sci.
Technol., 51, 4415–4423, https://doi.org/10.1021/acs.est.7b00397, 2017.
Cahill, J. F., Suski, K., Seinfeld, J. H., Zaveri, R. A., and Prather, K. A.: The mixing state of carbonaceous aerosol particles in northern and southern California measured during CARES and CalNex 2010, Atmos. Chem. Phys., 12, 10989–11002, https://doi.org/10.5194/acp-12-10989-2012, 2012.
Canagaratna, M. R., Jayne, J. T., Jimenez, J. L., Allan, J. D., Alfarra, M.
R., Zhang, Q., Onasch, T. B., Drewnick, F., Coe, H., Middlebrook, A., Delia,
A., Williams, L. R., Trimborn, A. M., Northway, M. J., DeCarlo, P. F., Kolb,
C. E., Davidovits, P., and Worsnop, D. R.: Chemical and microphysical
characterization of ambient aerosols with the aerodyne aerosol mass
spectrometer, Mass Spectrom. Rev., 26, 185–222, https://doi.org/10.1002/mas.20115, 2007.
Chan, C. Y., Wong, K. H., Li, Y. S., Chan, Y., and Zhang, X. D.: The effects
of Southeast Asia fire activities on tropospheric ozone, trace gases and
aerosols at a remote site over the Tibetan Plateau of Southwest China,
Tellus B, 58, 310–318, https://doi.org/10.1111/j.1600-0889.2006.00187.x, 2017.
Chen, J. Q. and Bordoni, S.: Orographic effects of the Tibetan Plateau on
the East Asian Summer Monsoon: An energetic perspective, J. Climate, 27,
3052–3072, https://doi.org/10.1175/JCLI-D-13-00479.1, 2014.
Chen, Y., Cao, J. J., Huang, R. J., Yang, F. M., Wang, Q. Y., and Wang, Y.
C.: Characterization, mixing state, and evolution of urban single particles
in Xi'an (China) during wintertime haze days, Sci. Total Environ., 573,
937–945, https://doi.org/10.1016/j.scitotenv.2016.08.151, 2016.
Chen, Y., Wenger, J. C., Yang, F. M., Cao, J. J., Huang, R. J., Shi, G. M.,
Zhang, S. M., Tian, M., and Wang, H. B.: Source characterization of urban
particles from meat smoking activities in Chongqing, China using single
particle aerosol mass spectrometry, Environ. Pollut., 228, 92–101,
https://doi.org/10.1016/j.envpol.2017.05.022, 2017.
Chen, Y., Tian, M., Huang, R.-J., Shi, G., Wang, H., Peng, C., Cao, J., Wang, Q., Zhang, S., Guo, D., Zhang, L., and Yang, F.: Characterization of urban amine-containing particles in southwestern China: seasonal variation, source, and processing, Atmos. Chem. Phys., 19, 3245–3255, https://doi.org/10.5194/acp-19-3245-2019, 2019.
Cheng, C., Li, M., Chan, C. K., Tong, H., Chen, C., Chen, D., Wu, D., Li, L., Wu, C., Cheng, P., Gao, W., Huang, Z., Li, X., Zhang, Z., Fu, Z., Bi, Y., and Zhou, Z.: Mixing state of oxalic acid containing particles in the rural area of Pearl River Delta, China: implications for the formation mechanism of oxalic acid, Atmos. Chem. Phys., 17, 9519–9533, https://doi.org/10.5194/acp-17-9519-2017, 2017.
Crippa, M., DeCarlo, P. F., Slowik, J. G., Mohr, C., Heringa, M. F., Chirico, R., Poulain, L., Freutel, F., Sciare, J., Cozic, J., Di Marco, C. F., Elsasser, M., Nicolas, J. B., Marchand, N., Abidi, E., Wiedensohler, A., Drewnick, F., Schneider, J., Borrmann, S., Nemitz, E., Zimmermann, R., Jaffrezo, J.-L., Prévôt, A. S. H., and Baltensperger, U.: Wintertime aerosol chemical composition and source apportionment of the organic fraction in the metropolitan area of Paris, Atmos. Chem. Phys., 13, 961–981, https://doi.org/10.5194/acp-13-961-2013, 2013.
Dall'Osto, M. and Harrison, R. M.: Urban organic aerosols measured by single particle mass spectrometry in the megacity of London, Atmos. Chem. Phys., 12, 4127–4142, https://doi.org/10.5194/acp-12-4127-2012, 2012.
Dall'Osto, M., Beddows, D. C. S., Gietl, J. K., Olatunbosun, O. A., Yang, X.
G., and Harrison, R. M.: Characteristics of tyre dust in polluted air:
studies by single particle mass spectrometry (ATOFMS), Atmos. Environ., 94,
224–230, https://doi.org/10.1016/j.atmosenv.2014.05.026, 2014.
Ding, J., Dai, Q. L., Zhang, Y. F., Xu, J., Huangfu, Y. Q., and Feng, Y. C.: Air humidity affects secondary aerosol formation in different pathways, Sci.
Total Environ., 759, 143540–143549, https://doi.org/10.1016/j.scitotenv.2020.143540, 2021.
Draxler, R. and Hess, G.: An overview of the HYSPLIT_4 modelling system for trajectories, Aust. Meteorol. Mag., 47, 295–308, 1998.
Du, W., Sun, Y. L., Xu, Y. S., Jiang, Q., Wang, Q. Q., Yang, W., Wang, F., Bai, Z. P., Zhao, X. D., and Yang, Y. C.: Chemical characterization of submicron aerosol and particle growth events at a national background site (3295 m a.s.l.) on the Tibetan Plateau, Atmos. Chem. Phys., 15, 10811–10824, https://doi.org/10.5194/acp-15-10811-2015, 2015.
Engling, G., Zhang, Y. N., Chan, C. Y., Sang, X. F., Lin, M., Ho, K. F., Li,
Y. S., Lin, C. Y., and Lee, J. J.: Characterization and sources of aerosol
particles over the southeastern Tibetan Plateau during the Southeast Asia
biomass-burning season, Tellus B, 63, 117–128,
https://doi.org/10.1111/j.1600-0889.2010.00512.x, 2011.
Ervens, B., Turpin, B. J., and Weber, R. J.: Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies, Atmos. Chem. Phys., 11, 11069–11102, https://doi.org/10.5194/acp-11-11069-2011, 2011.
Fang, X. Z., Liu, Y. Y., Li, K. J., Wang, T., Deng, Y., Feng, Y. Q., Yang,
Y., Cheng, H. Y., Chen, J. M., and Zhang, L. W.: Atmospheric Nitrate
Formation through Oxidation by Carbonate Radical, ACS Earth Space Chem., 5,
1801–1811, https://doi.org/10.1021/acsearthspacechem.1c00169, 2021.
Fry, J. L., Draper, D. C., Barsanti, K. C., Smith, J. N., Ortega, J.,
Winkler, P. M., Lawler, M. J., Brown, S. S., Edwards, P. M., Cohen, R. C.,
and Lee, L.: Secondary Organic Aerosol Formation and Organic Nitrate Yield
from NO3 Oxidation of Biogenic Hydrocarbons, Environ. Sci. Technol., 48,
11944–11953, https://doi.org/10.1021/es502204x, 2014.
Furukawa, T. and Takahashi, Y.: Oxalate metal complexes in aerosol particles: implications for the hygroscopicity of oxalate-containing particles, Atmos. Chem. Phys., 11, 4289–4301, https://doi.org/10.5194/acp-11-4289-2011, 2011.
Gettelman, A., Morrison, H., Terai, C. R., and Wood, R.: Corrigendum to “Microphysical Process Rates and Global Aerosol-Cloud Interactions” published in Atmos. Chem. Phys., 13, 9855–9867, 2013, Atmos. Chem. Phys., 14, 9099–9103, https://doi.org/10.5194/acp-14-9099-2014, 2013.
Han, H., Wu, Y., Liu, J., Zhao, T., Zhuang, B., Wang, H., Li, Y., Chen, H., Zhu, Y., Liu, H., Wang, Q., Li, S., Wang, T., Xie, M., and Li, M.: Impacts of atmospheric transport and biomass burning on the inter-annual variation in black carbon aerosols over the Tibetan Plateau, Atmos. Chem. Phys., 20, 13591–13610, https://doi.org/10.5194/acp-20-13591-2020, 2020.
Healy, R. M., Sciare, J., Poulain, L., Crippa, M., Wiedensohler, A., Prévôt, A. S. H., Baltensperger, U., Sarda-Estève, R., McGuire, M. L., Jeong, C.-H., McGillicuddy, E., O'Connor, I. P., Sodeau, J. R., Evans, G. J., and Wenger, J. C.: Quantitative determination of carbonaceous particle mixing state in Paris using single-particle mass spectrometer and aerosol mass spectrometer measurements, Atmos. Chem. Phys., 13, 9479–9496, https://doi.org/10.5194/acp-13-9479-2013, 2013.
Hua, S., Liu, Y. Z., Luo, R., Shao, T. B., and Zhu, Q. Z.: Inconsistent aerosol indirect effects on water clouds and ice clouds over the Tibetan Plateau, Int. J. Climatol., 40, 3832–3848, https://doi.org/10.1002/joc.6430, 2019.
Huang, X. J., Zhang, J. K., Luo, B., Luo, J. Q., Zhang, W., and Rao, Z. H.:
Characterization of oxalic acid-containing particles in summer and winter
seasons in Chengdu China, Atmos. Environ., 198, 133–141,
https://doi.org/10.1016/j.atmosenv.2018.10.050, 2019.
Immerzeel, W. W., van Beek, L. P. H., and Bierkens, M. F. P.: Climate change
will affect the Asian water towers, Science, 328, 1382–1385,
https://doi.org/10.1126/science.1183188, 2010.
Jacobson, M. Z.: Analysis of aerosol interactions with numerical techniques
for solving coagulation, nucleation, condensation, dissolution, and
reversible chemistry among multiple size distributions, J. Geophys. Res.,
107, 4366, https://doi.org/10.1029/2001JD002044, 2002.
Jiang, H. H., Frie, A. L., Lavi, A., Chen, J. Y., Zhang, H., Bahreini, R.,
and Lin, Y. H.: Brown carbon formation from nighttime chemistry of
unsaturated heterocyclic volatile organic compounds, Environ. Sci. Tech. Let., 6, 184190, https://doi.org/10.1021/acs.estlett.9b00017, 2019.
Kumar, M., Raju, M. P., Singh, R. K., Singh, A. K., Singh, R. S., and
Banerjee, T.: Wintertime characteristics of aerosols over middle
Indo-Gangetic Plain: vertical profile, transport and radiative forcing,
Atmos. Res., 183, 268–282, https://doi.org/10.1016/j.atmosres.2016.09.012,
2017.
Kundu, S., Kawamura, K., Andreae, T. W., Hoffer, A., and Andreae, M. O.: Molecular distributions of dicarboxylic acids, ketocarboxylic acids and α-dicarbonyls in biomass burning aerosols: implications for photochemical production and degradation in smoke layers, Atmos. Chem. Phys., 10, 2209–2225, https://doi.org/10.5194/acp-10-2209-2010, 2010.
Li, C. L., Bosch, C., Kang, S. C., Andersson, A., Chen, P. F., Zhang, Q. G.,
Cong, Z. Y., Chen, B., Qin, D. H., and Gustafsson, Ö.: Sources of black
carbon to the Himalayan–Tibetan Plateau glaciers, Nat. Commun., 7, 12574,
https://doi.org/10.1038/ncomms12574, 2016.
Li, C. L., Bosch, C., Kang, S. C., Andersson, A., Chen, P. F., Zhang, Q. G.,
Cong, Z. Y., Tripathee, L., and Örjanb, G.: 14C characteristics of
organic carbon in the atmosphere and at glacier region of the Tibetan
Plateau, Sci. Total Environ., 832, 155020, https://doi.org/10.1016/j.scitotenv.2022.155020, 2022.
Li, J. J., Wang, G. H., Wang, X. M., Cao, J. J., Sun, T., Cheng, C. L.,
Meng, J. J., Hu, T. F., and Liu, S. X.: Abundance, composition and source of
atmospheric PM2.5 at a remote site in the Tibetan Plateau, China, Tellus B, 65, 20281, https://doi.org/10.3402/tellusb.v65i0.20281, 2013.
Li, L., Huang, Z. X., Dong, J. G., Li, M., Gao, W., Nian, H. Q., Fu, Z.,
Zhang, G. H., Bi, X. H., Cheng, P., and Zhou, Z.: Real time bipolar
time-of-flight mass spectrometer for analyzing single aerosol particles, Int.
J. Mass Spectrom., 303, 118–124, https://doi.org/10.1016/j.ijms.2011.01.017, 2011.
Li, L., Wang, Q. Y., Zhang, Y., Liu, S. X., Zhang, T., Wang, S., Tian, J.,
Chen, Y., Hang Ho, S. S., Han, Y., and Cao, J. J.: Impact of reduced
anthropogenic emissions on chemical characteristics of urban aerosol by
individual particle analysis, Chemosphere, 303, 135013,
https://doi.org/10.1016/j.chemosphere.2022.135013, 2022a.
Li, L., Wang, Q., Tian, J., Liu, H., Zhang, Y., Sai Hang Ho, S., Ran, w., and Cao, J.: In-depth study of the formation processes of single atmospheric particles in the southeastern margin of Tibetan Plateau, Version 1, Zenodo [data set], https://doi.org/10.5281/zenodo.7336857, 2022b.
Li, Y. J., Sun, Y. L., Zhang, Q., Li, X., Li, M., Zhou, Z., and Chan, C. K.:
Real-time chemical characterization of atmospheric particulate matter in
China: A review, Atmos. Environ., 158, 270–304,
https://doi.org/10.1016/j.atmosenv.2017.02.027, 2017.
Liang, Z. C., Zhou, L. Y., Cuevas, R. A., Li, X. Y., Cheng, C. L., Li, M.,
Tang, R. Z., Zhang, R. F., Lee, P. K. H., Lai, A. C. K., and Chan, C. K.: Sulfate Formation in Incense Burning Particles: A Single-Particle Mass
Spectrometric Study, Environ. Sci. Tech. Let., 9, 718–725,
https://doi.org/10.1021/acs.estlett.2c00492, 2022.
Lin, Q., Bi, X., Zhang, G., Yang, Y., Peng, L., Lian, X., Fu, Y., Li, M., Chen, D., Miller, M., Ou, J., Tang, M., Wang, X., Peng, P., Sheng, G., and Zhou, Z.: In-cloud formation of secondary species in iron-containing particles, Atmos. Chem. Phys., 19, 1195–1206, https://doi.org/10.5194/acp-19-1195-2019, 2019.
Link, M. F., Kim, J., Park, G., Lee, T., Park, T., Babar, Z. B., Sung, K.,
Kim, P., Kang, S., Kim, J. S., Choi, Y., Son, J., Lim, H. J., and Farmer,
D. K.: Elevated production of NH4NO3 from the photochemical processing of vehicle exhaust: Implications for air quality in the Seoul Metropolitan
Region, Atmos. Environ., 156, 95–101, https://doi.org/10.1016/j.atmosenv.2017.02.031, 2017.
Liu, D. T., Hu, K., Zhao, D. L., Ding, S., Wu, Y. F., Zhou, C., Yu, C. J.,
Tian, P., Liu, Q., Bi, K., Wu, Y. Z., Hu, B., Ji, D. S., Kong, S. F.,
Ouyang, B., He, H., Huang, M. Y., and Ding, D.P.: Efficient Vertical
Transport of Black Carbon in the Planetary Boundary Layer, Geophys. Res. Lett., 47, e2020GL088858, https://doi.org/10.1029/2020GL088858, 2020.
Liu, H., Wang, Q., Xing, L., Zhang, Y., Zhang, T., Ran, W., and Cao, J.: Measurement report: quantifying source contribution of fossil fuels and biomass-burning black carbon aerosol in the southeastern margin of the Tibetan Plateau, Atmos. Chem. Phys., 21, 973–987, https://doi.org/10.5194/acp-21-973-2021, 2021.
Liu, Q., Liu, D., Gao, Q., Tian, P., Wang, F., Zhao, D., Bi, K., Wu, Y., Ding, S., Hu, K., Zhang, J., Ding, D., and Zhao, C.: Vertical characteristics of aerosol hygroscopicity and impacts on optical properties over the North China Plain during winter, Atmos. Chem. Phys., 20, 3931–3944, https://doi.org/10.5194/acp-20-3931-2020, 2020.
Liu, X. D., Dong, B. W., Yin, Z. Y., Smith, R. S., and Guo, Q. C.: Continental drift and plateau uplift control origination and evolution of Asian and Australian monsoons, Scientific Reports, 7, 40344, https://doi.org/10.1038/srep40344, 2017.
Luo, M., Liu, Y. Z., Zhu, Q. Z., Tang, Y. H., and Alam, K.: Role and
mechanisms of black carbon affecting water vapor transport to Tibet, Remote
Sensing, 12, 231, https://doi.org/10.3390/rs12020231, 2020.
Ma, X., Yu, F., and Luo, G.: Aerosol direct radiative forcing based on GEOS-Chem-APM and uncertainties, Atmos. Chem. Phys., 12, 5563–5581, https://doi.org/10.5194/acp-12-5563-2012, 2012.
Matsui, H.: Black carbon simulations using a size- and mixingstate-resolved
three-dimensional model: 2. Aging timescale and its impact over East Asia,
J. Geophys. Res.-Atmos., 121, 1808–1821, https://doi.org/10.1002/2015jd023999, 2016.
Meng, J. J, Wang, G. H, Li, J. J, Cheng, C. L, Ren, Y. Q, Huang, Y., Cheng,
Y. T., Cao, J. J., and Zhang, T.: Seasonal characteristics of oxalic acid and
related SOA in the free troposphere of Mt. Hua, central China: implications
for sources and formation mechanisms, Sci. Total Environ., 493, 1088–1097,
https://doi.org/10.1016/j.scitotenv.2014.04.086, 2014.
Meng, J. J., Liu, X. D., Hou, Z. F., Yi, Y. N., Yan, L., Li, Z., Cao, J. J.,
Li, J. J., and Wang, G. H.: Molecular characteristics and stable carbon isotope compositions of dicarboxylic acids and related compounds in the urban
atmosphere of the North China Plain: implications for aqueous phase
formation of SOA during the haze periods, Sci. Total Environ., 705, 135256,
https://doi.org/10.1016/j.scitotenv.2019.135256, 2020.
National Centers for Environmental Prediction, National Weather Service, NOAA, and U.S. Department of Commerce: NCEP FNL Operational Model Global Tropospheric Analyses, continuing from July 1999, Research Data Archive at the National Center for Atmospheric Research, Computational and Information Systems Laboratory [data set], https://doi.org/10.5065/D6M043C6, 2000.
Ng, N. L., Canagaratna, M. R., Jimenez, J. L., Chhabra, P. S., Seinfeld, J. H., and Worsnop, D. R.: Changes in organic aerosol composition with aging inferred from aerosol mass spectra, Atmos. Chem. Phys., 11, 6465–6474, https://doi.org/10.5194/acp-11-6465-2011, 2011.
Peng, J. F., Hu, M., Guo, S., Du, Z. F., Zheng, J., Shang, D. J., Zamora, M.
L., Zeng, L. M., Shao, M., Wu, Y. S., Zheng, J., Wang, Y., Glen, C. R.,
Collins, D. R., Molina, M. J., and Zhang, R. Y.: Markedly enhanced
absorption and direct radiative forcing of black carbon under polluted urban
environments, P. Natl. Acad. Sci. USA, 113, 4266–4271,
https://doi.org/10.1073/pnas.1602310113, 2016.
Pratt, K. A., Murphy, S. M., Subramanian, R., DeMott, P. J., Kok, G. L., Campos, T., Rogers, D. C., Prenni, A. J., Heymsfield, A. J., Seinfeld, J. H., and Prather, K. A.: Flight-based chemical characterization of biomass burning aerosols within two prescribed burn smoke plumes, Atmos. Chem. Phys., 11, 12549–12565, https://doi.org/10.5194/acp-11-12549-2011, 2011.
Qian, Y., Flanner, M. G., Leung, L. R., and Wang, W.: Sensitivity studies on the impacts of Tibetan Plateau snowpack pollution on the Asian hydrological cycle and monsoon climate, Atmos. Chem. Phys., 11, 1929–1948, https://doi.org/10.5194/acp-11-1929-2011, 2011.
Rehbein, P. J., Jeong, C. H., McGuire, M. L., Yao, X., Corbin, J. C., and
Evans, G. J.: Cloud and fog processing enhanced gas-toparticle partitioning
of trimethylamine, Environ. Sci. Technol., 45, 4346–4352,
https://doi.org/10.1021/es1042113, 2011.
Roth, A., Schneider, J., Klimach, T., Mertes, S., van Pinxteren, D., Herrmann, H., and Borrmann, S.: Aerosol properties, source identification, and cloud processing in orographic clouds measured by single particle mass spectrometry on a central European mountain site during HCCT-2010, Atmos. Chem. Phys., 16, 505–524, https://doi.org/10.5194/acp-16-505-2016, 2016.
Shen, L. J., Wang, H. L., Lü, S., Zhang, X. H., Yuan, J., Tao, S. K.,
Zhang, G. J., Wang, F., and Li, L.: In?uence of pollution control on air
pollutants and the mixing state of aerosol particles during the 2nd World
Internet Conference in Jiaxing, China, J. Clean. Prod., 149, 436–447,
https://doi.org/10.1016/j.jclepro.2017.02.114, 2017.
Shen, R.-Q., Ding, X., He, Q.-F., Cong, Z.-Y., Yu, Q.-Q., and Wang, X.-M.: Seasonal variation of secondary organic aerosol tracers in Central Tibetan Plateau, Atmos. Chem. Phys., 15, 8781–8793, https://doi.org/10.5194/acp-15-8781-2015, 2015.
Sirois, A. and Bottenheim, J. W.: Use of backward trajectories to interpret
the 5-year record of PAN and O3 ambient air concentrations at Kejimkujik
National Park, Nova Scotia, J. Geophys. Res., 100, 2867–2881,
https://doi.org/10.1029/94JD02951, 1995.
Song, X. H. and Hopke, P. K.: Classifcation of single particles analyzed by
ATOFMS using an artifcial neural network, ART-2A, Anal. Chem., 71, 860–865,
https://doi.org/10.1021/ac9809682, 1999.
Sorooshian, A., Lu, M. L., Brechtel, F. J., Jonsson, H., Feingold, G.,
Flagan, R. C., and Seinfeld, J. H.: On the source of organic acid aerosol
layers above clouds, Environ. Sci. Technol., 41, 4647–4654,
https://doi.org/10.1021/es0630442, 2007.
Sullivan, R. C., Guazzotti, S. A., Sodeman, D. A., and Prather, K. A.: Direct observations of the atmospheric processing of Asian mineral dust, Atmos. Chem. Phys., 7, 1213–1236, https://doi.org/10.5194/acp-7-1213-2007,
2007.
Sun, Y. L, Wang, Z. F., Fu, P. Q., Jiang, Q. J., Yang, T., Li, J., and Ge,
X. L.: The impact of relative humidity on aerosol composition and evolution
processes during wintertime in Beijing, China, Atmos. Environ., 77,
927–934, https://doi.org/10.1016/j.atmosenv.2013.06.019, 2013.
Tian, J., Wang, Q. Y., Zhang, Y., Yan, M. Y., Liu, H. K., Zhang, N. N., Ran,
W. K., and Cao, J. J.: Impacts of primary emissions and secondary aerosol
formation on air pollution in an urban area of China during the COVID-19
lockdown, Environ. Int., 150, 106426–14,
https://doi.org/10.1016/j.envint.2021.106426, 2021.
Wang, A. Q., Xie, X. N., Liu, X. D., and Yin, Z. Y.: Direct Radiative Effect
(DRE) of Dust Aerosols on West African and East Asian Monsoon: The Role of
Ocean-Atmosphere Interactions, J. Geophys. Res.-Atmos., 127, 1–20,
https://doi.org/10.1029/2021JD035917, 2022.
Wang, G. H., Zhang, R. Y., Gomez, M. E., Yang, L. X., Zamora, M. L., Hu, M.,
Lin, Y., Peng, J. F., Guo, S., Meng, J. J., Li, J. J., Cheng, C. L., Hu, T.
F., Ren, Y. Q., Wang, Y. S., Gao, J., Cao, J. J., An, Z. S., Zhou, W. J.,
Li, G. H., Wang, J. Y., Tian, P. F., Marrero-Ortiz, W., Secrest, J., Du, Z.
F., Zheng, J., Shang, D. J., Zeng, L. M., Shao, M., Wang, W. G., Huang, Y.,
Wang, Y., Zhu, Y. J., Li, Y. X., Hu, J. X., Pan, B. W., Cai, L., Cheng, Y.
T., Ji, Y. M., Zhang, Y., Rosenfeld, D., Liss, P. S., Duce, R. A., Kolb, C.
E., and Molina, M. J.: Persistent sulfate formation from London Fog to
Chinese haze, P. Natl. Acad. Sci. USA, 113, 13630–13635,
https://doi.org/10.1073/pnas.1616540113, 2016.
Wang, H. C., Lu, K. D., Chen, X. R., Zhu, Q. D., Chen, Q., Guo, S., Jiang,
M. Q., Li, X., Shang, D. J., Tan, Z. F., Wu, Y. S., Wu, Z. J., Zou, Q.,
Zheng, Y., Zeng, L. M., Zhu, T., Hu, M., and Zhang, Y. H.: High N2O5
concentrations observed in urban Beijing: implications of a large nitrate
formation pathway, Environ. Sci. Tech. Let., 4, 416–420,
https://doi.org/10.1021/acs.estlett.7b00341, 2017.
Wang, H. L., An, J. L., Shen, L. J., Zhu, B., Xia, L., Duan, Q., and Zou, J.
N.: Mixing state of ambient aerosols in Nanjing city by single particle mass
spectrometry, Atmos. Environ., 132, 123–132,
https://doi.org/10.1016/j.atmosenv.2016.02.032, 2016.
Wang, H. L., Shen, L. J., Yin, Y., Chen, K., Chen, J. H., and Wang, Y. S.:
Characteristics and mixing state of aerosol at the summit of Mount Tai (1534 m) in Central East China: First measurements with SPAMS, Atmos. Environ., 213, 273–284, https://doi.org/10.1016/j.atmosenv.2019.06.021, 2019.
Wang, Q. Y., Han, Y. M., Ye, J. H., Liu, S. X., Pongpiachan, S., Zhang, N.
N., Han, Y. M., Tian, J., Wu, C., Long, X., Zhang, Q., Zhang, W. Y., Zhao,
Z. Z., and Cao, J. J.: High contribution of secondary brown carbon to
aerosol light absorption in the southeastern margin of Tibetan Plateau,
Geophys. Res. Lett., 46, 4962–4970, https://doi.org/10.1029/2019GL082731, 2019.
Wenzel, R. J., Liu, D.-Y., Edgerton, E. S., and Prather, K. A.: Aerosol
time-of-flight mass spectrometry during the Atlanta Supersite Experiment: 2.
Scaling procedures, J. Geophys. Res., 108, 8427, https://doi.org/10.1029/2001jd001563, 2003.
Wood, E. C., Canagaratna, M. R., Herndon, S. C., Onasch, T. B., Kolb, C. E., Worsnop, D. R., Kroll, J. H., Knighton, W. B., Seila, R., Zavala, M., Molina, L. T., DeCarlo, P. F., Jimenez, J. L., Weinheimer, A. J., Knapp, D. J., Jobson, B. T., Stutz, J., Kuster, W. C., and Williams, E. J.: Investigation of the correlation between odd oxygen and secondary organic aerosol in Mexico City and Houston, Atmos. Chem. Phys., 10, 8947–8968, https://doi.org/10.5194/acp-10-8947-2010, 2010.
Xu, L. L., Wu, X., Hong, Z. Y., Zhang, Y. R., Deng, J. J., Hong, Y. W., and
Chen, J. S.: Composition, mixing state, and size distribution of single
submicron particles during pollution episodes in a coastal city in southeast
China, Environ. Sci. Pollut. R., 26, 1464–1473, https://doi.org/10.1007/s11356-018-3469-x, 2018.
Xu, W. Q., Han, T. T., Du, W., Wang, Q. Q., Chen, C., Zhao, J., Zhang, Y.
J., Li, J., Fu, P. Q., Wang, Z. F., Worsnop, D. R., and Sun, Y. L.: Effects
of aqueous-phase and photochemical processing on secondary organic aerosol
formation and evolution in Beijing, China, Environ. Sci. Technol., 51,
762–770, https://doi.org/10.1021/acs.est.6b04498, 2017.
Xue, J., Griffth, S. M., Yu, X., Lau, A. K. H., and Yu, J. Z.: Effect of
nitrate and sulfate relative abundance in PM2.5 on liquid water content
explored through half-hourly observations of inorganic soluble aerosols at a
polluted receptor site, Atmos. Environ., 99, 24–31,
https://doi.org/10.1016/j.atmosenv.2014.09.049, 2014.
Yang, J., Ma, S. X., Gao, B., Li, X. Y., Zhang, Y. J., Cai, J., Li, M., Yao,
L. A., Huang, B., and Zheng, M.: Single particle mass spectral signatures
from vehicle exhaust particles and the source apportionment of on-line PM2.5 by single particle aerosol mass spectrometry, Sci. Total Environ., 593, 310–318, https://doi.org/10.1016/j.scitotenv.2017.03.099, 2017.
Zauscher, M. D., Wang, Y., Moore, M. J. K., Gaston, C. J., and Prather, K.
A.: Air Quality Impact and Physicochemical Aging of Biomass Burning Aerosols
during the 2007 San Diego Wildfires, Environ. Sci. Technol., 47, 7633–7643,
https://doi.org/10.1021/es4004137, 2013.
Zaveri, R. A., Barnard, J., Easter, R., Riemer, N., and West, M.:
Particle-resolved simulation of aerosol size, composition, mixing state, and
the associated optical and cloud condensation nuclei activation properties
in an evolving urban plume, J. Geophys. Res., 115, D17210,
https://doi.org/10.1029/2009JD013616, 2010.
Zhang, G., Lin, Q., Peng, L., Yang, Y., Fu, Y., Bi, X., Li, M., Chen, D., Chen, J., Cai, Z., Wang, X., Peng, P., Sheng, G., and Zhou, Z.: Insight into the in-cloud formation of oxalate based on in situ measurement by single particle mass spectrometry, Atmos. Chem. Phys., 17, 13891–13901, https://doi.org/10.5194/acp-17-13891-2017, 2017.
Zhang, G., Lian, X., Fu, Y., Lin, Q., Li, L., Song, W., Wang, Z., Tang, M., Chen, D., Bi, X., Wang, X., and Sheng, G.: High secondary formation of nitrogen-containing organics (NOCs) and its possible link to oxidized organics and ammonium, Atmos. Chem. Phys., 20, 1469–1481, https://doi.org/10.5194/acp-20-1469-2020, 2020.
Zhang, G. H., Bi, X. H., Chan, L. Y., Li, L., Wang, X. M., Feng, J. L.,
Sheng, G. Y., Fu, J. M., Li, M., and Zhou, Z.: Enhanced
trimethylamine-containing particles during fog events detected by single
particle aerosol mass spectrometry in urban Guangzhou, China, Atmos.
Environ., 55, 121–126, https://doi.org/10.1016/j.atmosenv.2012.03.038, 2012.
Zhang, G. H., Han, B. X., Bi, X. H., Dai, S. X., Huang, W., Chen, D. H.,
Wang, X. M., Sheng, G. Y., Fu, J. M., and Zhou, Z.: Characteristics of
individual particles in the atmosphere of Guangzhou by single particle mass
spectrometry, Atmos. Res., 153, 286–295, https://doi.org/10.1016/j.atmosres.2014.08.016, 2015.
Zhang, G. H., Lin, Q. H., Peng, L., Yang, Y. X., Jiang, F., Liu, F. X.,
Song, W., Chen, D. H., Cai, Z., Bi, X. H., Miller, M., Tang, M. J., Huang,
W. L., Wang, X. M., Peng, P. A., and Shen, G. Y.: Oxalate Formation Enhanced by Fe-Containing Particles and Environmental Implications, Environ. Sci.
Technol., 53, 1269–1277, https://doi.org/10.1021/acs.est.8b05280, 2019.
Zhang, J. K., Luo, B., Zhang, J. Q., Ouyang, F., Song, H. Y., Liu, P. C.,
Cao, P., Schäfer, K., Wang, S. G., Huang, X. J., and Lin, Y. F.:
Analysis of the characteristics of single atmospheric particles in Chengdu
using single particle mass spectrometry, Atmos. Environ., 157, 91–100,
https://doi.org/10.1016/j.atmosenv.2017.03.012, 2017.
Zhang, N. N., Cao, J. J., Xu, H. M., and Zhu, C. S.: Elemental compositions
of PM2.5 and TSP in Lijiang, southeastern edge of Tibetan Plateau during
pre-monsoon period, Particuology, 11, 63–69,
https://doi.org/10.1016/j.partic.2012.08.002, 2013.
Zhang, S. P., Xing, J., Sarwar, G., Ge, Y. L., He, H., Duan, F. K., Zhao,
Y., He, K. B., Zhu, L. D., and Chu, B. W.: Parameterization of heterogeneous
reaction of SO2 to sulfate on dust with coexistence of NH3 and NO2 under different humidity conditions, Atmos. Environ., 208, 133–140,
https://doi.org/10.1016/j.atmosenv.2019.04.004, 2019.
Zhang, X., Xu, J., Kang, S., Zhang, Q., and Sun, J.: Chemical characterization and sources of submicron aerosols in the northeastern Qinghai–Tibet Plateau: insights from high-resolution mass spectrometry, Atmos. Chem. Phys., 19, 7897–7911, https://doi.org/10.5194/acp-19-7897-2019, 2019.
Zhao, S. Y., Tie, X. X., Long, X., and Cao, J. J.: Impacts of Himalayas on
black carbon over the Tibetan Plateau during summer monsoon, Sci. Total
Environ., 598, 307–318, https://doi.org/10.1016/j.scitotenv.2017.04.101,
2017.
Short summary
The Tibetan Plateau has a unique geographical location, but there is a lack of detailed research on the real-time characteristics of full aerosol composition. This study elaborates the changes in chemical characteristics between transport and local fine particles during the pre-monsoon, reveals the size distribution and the mixing states of different individual particles, and highlights the contributions of photooxidation and aqueous reaction to the formation of the secondary species.
The Tibetan Plateau has a unique geographical location, but there is a lack of detailed research...
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