Articles | Volume 20, issue 4
https://doi.org/10.5194/acp-20-2591-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-2591-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
03 Mar 2020
Research article |
| 03 Mar 2020
| 03 Mar 2020
Wintertime new particle formation and its contribution to cloud condensation nuclei in the Northeastern United States
Atmospheric Sciences Research Center, State University of New York,
Albany, New York 12203, USA
Atmospheric Sciences Research Center, State University of New York,
Albany, New York 12203, USA
Arshad Arjunan Nair
Atmospheric Sciences Research Center, State University of New York,
Albany, New York 12203, USA
James J. Schwab
Atmospheric Sciences Research Center, State University of New York,
Albany, New York 12203, USA
James P. Sherman
Department of Physics and Astronomy, Appalachian State University, Boone, North Carolina 28608, USA
Yanda Zhang
Atmospheric Sciences Research Center, State University of New York,
Albany, New York 12203, USA
Related authors
Naveed Ahmad, Changqing Lin, Alexis K. H. Lau, Jhoon Kim, Tianshu Zhang, Fangqun Yu, Chengcai Li, Ying Li, Jimmy C. H. Fung, and Xiang Qian Lao
Atmos. Chem. Phys., 24, 9645–9665, https://doi.org/10.5194/acp-24-9645-2024, https://doi.org/10.5194/acp-24-9645-2024, 2024
Short summary
Short summary
This study developed a nested machine learning model to convert the GEMS NO2 column measurements into ground-level concentrations across China. The model directly incorporates the NO2 mixing height (NMH) into the methodological framework. The study underscores the importance of considering NMH when estimating ground-level NO2 from satellite column measurements and highlights the significant advantages of new-generation geostationary satellites in air quality monitoring.
Huiyun Du, Jie Li, Xueshun Chen, Gabriele Curci, Fangqun Yu, Yele Sun, Xu Dao, Song Guo, Zhe Wang, Wenyi Yang, Lianfang Wei, and Zifa Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1432, https://doi.org/10.5194/egusphere-2024-1432, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Inadequate consideration of mixing state and coatings on BC hinders aerosol radiation forcing quantification. While core-shell mixing results match observations closely, partial internal mixing and coating are more realistic. The fraction of embedded BC and coating aerosols resolved by a microphysics module were used to constrain the mixing state. This led to a 30~43 % absorption enhancement decrease over Northern China, offering valuable insights for the assessment of BC's radiative effects.
Hongyu Liu, Bo Zhang, Richard H. Moore, Luke D. Ziemba, Richard A. Ferrare, Hyundeok Choi, Armin Sorooshian, David Painemal, Hailong Wang, Michael A. Shook, Amy Jo Scarino, Johnathan W. Hair, Ewan C. Crosbie, Marta A. Fenn, Taylor J. Shingler, Chris A. Hostetler, Gao Chen, Mary M. Kleb, Gan Luo, Fangqun Yu, Jason L. Tackett, Mark A. Vaughan, Yongxiang Hu, Glenn S. Diskin, John B. Nowak, Joshua P. DiGangi, Yonghoon Choi, Christoph A. Keller, and Matthew S. Johnson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1127, https://doi.org/10.5194/egusphere-2024-1127, 2024
Short summary
Short summary
We use the GEOS-Chem model to simulate aerosols over the western North Atlantic Ocean (WNAO) during the winter and summer campaigns of ACTIVATE 2020. Model results are evaluated against in situ and remote sensing measurements from two aircraft as well as ground-based and satellite observations. The improved understanding of the aerosol life cycle, composition, transport pathways, and distribution has important implications for characterizing aerosol-cloud-meteorology interactions over the WNAO.
Shixian Zhai, Daniel J. Jacob, Drew C. Pendergrass, Nadia K. Colombi, Viral Shah, Laura Hyesung Yang, Qiang Zhang, Shuxiao Wang, Hwajin Kim, Yele Sun, Jin-Soo Choi, Jin-Soo Park, Gan Luo, Fangqun Yu, Jung-Hun Woo, Younha Kim, Jack E. Dibb, Taehyoung Lee, Jin-Seok Han, Bruce E. Anderson, Ke Li, and Hong Liao
Atmos. Chem. Phys., 23, 4271–4281, https://doi.org/10.5194/acp-23-4271-2023, https://doi.org/10.5194/acp-23-4271-2023, 2023
Short summary
Short summary
Anthropogenic fugitive dust in East Asia not only causes severe coarse particulate matter air pollution problems, but also affects fine particulate nitrate. Due to emission control efforts, coarse PM decreased steadily. We find that the decrease of coarse PM is a major driver for a lack of decrease of fine particulate nitrate, as it allows more nitric acid to form fine particulate nitrate. The continuing decrease of coarse PM requires more stringent ammonia and nitrogen oxides emission controls.
Kun Wang, Xiaoyan Ma, Rong Tian, and Fangqun Yu
Atmos. Chem. Phys., 23, 4091–4104, https://doi.org/10.5194/acp-23-4091-2023, https://doi.org/10.5194/acp-23-4091-2023, 2023
Short summary
Short summary
From 12 March to 6 April 2016 in Beijing, there were 11 typical new particle formation days, 13 non-event days, and 2 undefined days. We first analyzed the favorable background of new particle formation in Beijing and then conducted the simulations using four nucleation schemes based on a global chemistry transport model (GEOS-Chem) to understand the nucleation mechanism.
Fangqun Yu, Gan Luo, Arshad Arjunan Nair, Sebastian Eastham, Christina J. Williamson, Agnieszka Kupc, and Charles A. Brock
Atmos. Chem. Phys., 23, 1863–1877, https://doi.org/10.5194/acp-23-1863-2023, https://doi.org/10.5194/acp-23-1863-2023, 2023
Short summary
Short summary
Particle number concentrations and size distributions in the stratosphere are studied through model simulations and comparisons with measurements. The nucleation scheme used in most of the solar geoengineering modeling studies overpredicts the nucleation rates and particle number concentrations in the stratosphere. The model based on updated nucleation schemes captures reasonably well some aspects of particle size distributions but misses some features. The possible reasons are discussed.
Noah S. Hirshorn, Lauren M. Zuromski, Christopher Rapp, Ian McCubbin, Gerardo Carrillo-Cardenas, Fangqun Yu, and A. Gannet Hallar
Atmos. Chem. Phys., 22, 15909–15924, https://doi.org/10.5194/acp-22-15909-2022, https://doi.org/10.5194/acp-22-15909-2022, 2022
Short summary
Short summary
New particle formation (NPF) is a source of atmospheric aerosol number concentration that can impact climate by growing to larger sizes and under proper conditions form cloud condensation nuclei (CCN). Using novel methods, we find that at Storm Peak Laboratory, a remote, mountaintop site in Colorado, NPF is observed to enhance CCN concentrations in the spring by a factor of 1.54 and in the winter by a factor of 1.36 which can occur on a regional scale having important climate implications.
Katherine R. Travis, James H. Crawford, Gao Chen, Carolyn E. Jordan, Benjamin A. Nault, Hwajin Kim, Jose L. Jimenez, Pedro Campuzano-Jost, Jack E. Dibb, Jung-Hun Woo, Younha Kim, Shixian Zhai, Xuan Wang, Erin E. McDuffie, Gan Luo, Fangqun Yu, Saewung Kim, Isobel J. Simpson, Donald R. Blake, Limseok Chang, and Michelle J. Kim
Atmos. Chem. Phys., 22, 7933–7958, https://doi.org/10.5194/acp-22-7933-2022, https://doi.org/10.5194/acp-22-7933-2022, 2022
Short summary
Short summary
The 2016 Korea–United States Air Quality (KORUS-AQ) field campaign provided a unique set of observations to improve our understanding of PM2.5 pollution in South Korea. Models typically have errors in simulating PM2.5 in this region, which is of concern for the development of control measures. We use KORUS-AQ observations to improve our understanding of the mechanisms driving PM2.5 and the implications of model errors for determining PM2.5 that is attributable to local or foreign sources.
Yanda Zhang, Fangqun Yu, Gan Luo, Jiwen Fan, and Shuai Liu
Atmos. Chem. Phys., 21, 17433–17451, https://doi.org/10.5194/acp-21-17433-2021, https://doi.org/10.5194/acp-21-17433-2021, 2021
Short summary
Short summary
This paper explores the impacts of dust on summertime convective cloud and precipitation through a numerical experiment. The result indicates that the long-range-transported dust can notably affect the properties of convective cloud and precipitation by enhancing immersion freezing and invigorating convection. We also analyze the different dust effects predicted by the Morrison and SBM schemes, which are partially attributed to the saturation adjustment approach utilized in the bulk schemes.
Shixian Zhai, Daniel J. Jacob, Jared F. Brewer, Ke Li, Jonathan M. Moch, Jhoon Kim, Seoyoung Lee, Hyunkwang Lim, Hyun Chul Lee, Su Keun Kuk, Rokjin J. Park, Jaein I. Jeong, Xuan Wang, Pengfei Liu, Gan Luo, Fangqun Yu, Jun Meng, Randall V. Martin, Katherine R. Travis, Johnathan W. Hair, Bruce E. Anderson, Jack E. Dibb, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jung-Hun Woo, Younha Kim, Qiang Zhang, and Hong Liao
Atmos. Chem. Phys., 21, 16775–16791, https://doi.org/10.5194/acp-21-16775-2021, https://doi.org/10.5194/acp-21-16775-2021, 2021
Short summary
Short summary
Geostationary satellite aerosol optical depth (AOD) has tremendous potential for monitoring surface fine particulate matter (PM2.5). Our study explored the physical relationship between AOD and PM2.5 by integrating data from surface networks, aircraft, and satellites with the GEOS-Chem chemical transport model. We quantitatively showed that accurate simulation of aerosol size distributions, boundary layer depths, relative humidity, coarse particles, and diurnal variations in PM2.5 are essential.
Gongda Lu, Eloise A. Marais, Tuan V. Vu, Jingsha Xu, Zongbo Shi, James D. Lee, Qiang Zhang, Lu Shen, Gan Luo, and Fangqun Yu
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-428, https://doi.org/10.5194/acp-2021-428, 2021
Revised manuscript not accepted
Short summary
Short summary
Emission controls were imposed in Beijing-Tianjin-Hebei in northern China in autumn-winter 2017. We find that regional PM2.5 targets (15 % decrease relative to previous year) were exceeded. Our analysis shows that decline in precursor emissions only leads to less than half (43 %) the improved air quality. Most of the change (57 %) is due to interannual variability in meteorology. Stricter emission controls may be necessary in years with unfavourable meteorology.
Xueshun Chen, Fangqun Yu, Wenyi Yang, Yele Sun, Huansheng Chen, Wei Du, Jian Zhao, Ying Wei, Lianfang Wei, Huiyun Du, Zhe Wang, Qizhong Wu, Jie Li, Junling An, and Zifa Wang
Atmos. Chem. Phys., 21, 9343–9366, https://doi.org/10.5194/acp-21-9343-2021, https://doi.org/10.5194/acp-21-9343-2021, 2021
Short summary
Short summary
Atmospheric aerosol particles have significant climate and health effects that depend on aerosol size, composition, and mixing state. A new global-regional nested aerosol model with an advanced particle microphysics module and a volatility basis set organic aerosol module was developed to simulate aerosol microphysical processes. Simulations strongly suggest the important role of anthropogenic organic species in particle formation over the areas influenced by anthropogenic sources.
Xiaojing Shen, Junying Sun, Fangqun Yu, Ying Wang, Junting Zhong, Yangmei Zhang, Xinyao Hu, Can Xia, Sinan Zhang, and Xiaoye Zhang
Atmos. Chem. Phys., 21, 7039–7052, https://doi.org/10.5194/acp-21-7039-2021, https://doi.org/10.5194/acp-21-7039-2021, 2021
Short summary
Short summary
In this work, we revealed the changes of PNSD and NPF events during the COVID-19 lockdown period in Beijing, China, to illustrate the impact of reduced primary emission and elavated atmospheric oxidized capicity on the nucleation and growth processes. The subsequent growth of nucleated particles and their contribution to the aerosol pollution formation were also explored, to highlight the necessity of controlling the nanoparticles in the future air quality management.
Ling Liu, Fangqun Yu, Kaipeng Tu, Zhi Yang, and Xiuhui Zhang
Atmos. Chem. Phys., 21, 6221–6230, https://doi.org/10.5194/acp-21-6221-2021, https://doi.org/10.5194/acp-21-6221-2021, 2021
Short summary
Short summary
Trifluoroacetic acid (TFA) was previously proved to participate in sulfuric acid (SA)–dimethylamine (DMA) nucleation in Shanghai, China. However, complex atmospheric environments can influence the nucleation of aerosol significantly. We show the influence of different atmospheric conditions on the SA-DMA-TFA nucleation and find the enhancement by TFA can be significant in cold and polluted areas, which provides the perspective of the realistic role of TFA in different atmospheric environments.
Arshad Arjunan Nair and Fangqun Yu
Atmos. Chem. Phys., 20, 12853–12869, https://doi.org/10.5194/acp-20-12853-2020, https://doi.org/10.5194/acp-20-12853-2020, 2020
Short summary
Short summary
Small particles in the atmosphere can affect cloud formation and properties and thus Earth's energy budget. These cloud condensation nuclei (CCN) contribute the largest uncertainties in climate change modeling. To reduce these uncertainties, it is important to quantify CCN numbers accurately, measurements of which are sparse. We propose and evaluate a machine learning method to estimate CCN, in the absence of their direct measurements, using more common measurements of weather and air quality.
Katherine R. Travis, Colette L. Heald, Hannah M. Allen, Eric C. Apel, Stephen R. Arnold, Donald R. Blake, William H. Brune, Xin Chen, Róisín Commane, John D. Crounse, Bruce C. Daube, Glenn S. Diskin, James W. Elkins, Mathew J. Evans, Samuel R. Hall, Eric J. Hintsa, Rebecca S. Hornbrook, Prasad S. Kasibhatla, Michelle J. Kim, Gan Luo, Kathryn McKain, Dylan B. Millet, Fred L. Moore, Jeffrey Peischl, Thomas B. Ryerson, Tomás Sherwen, Alexander B. Thames, Kirk Ullmann, Xuan Wang, Paul O. Wennberg, Glenn M. Wolfe, and Fangqun Yu
Atmos. Chem. Phys., 20, 7753–7781, https://doi.org/10.5194/acp-20-7753-2020, https://doi.org/10.5194/acp-20-7753-2020, 2020
Short summary
Short summary
Atmospheric models overestimate the rate of removal of trace gases by the hydroxyl radical (OH). This is a concern for studies of the climate and air quality impacts of human activities. Here, we evaluate the performance of a commonly used model of atmospheric chemistry against data from the NASA Atmospheric Tomography Mission (ATom) over the remote oceans where models have received little validation. The model is generally successful, suggesting that biases in OH may be a concern over land.
Gan Luo, Fangqun Yu, and Jonathan M. Moch
Geosci. Model Dev., 13, 2879–2903, https://doi.org/10.5194/gmd-13-2879-2020, https://doi.org/10.5194/gmd-13-2879-2020, 2020
Short summary
Short summary
This work improved pH calculation for cloud, rain, and wet surfaces, fraction of cloud available for aqueous-phase chemistry, rainout efficiencies for various types of cloud, empirical washout by rain and snow, and wet surface uptake in GEOS-Chem v12.6.0. We compared simulated mass concentrations of aerosol precursors and aerosols with surface monitoring networks, Arctic sites, and ATom observations, and showed that the model results with the updated wet processes agree better for most species.
Fangqun Yu, Alexey B. Nadykto, Gan Luo, and Jason Herb
Geosci. Model Dev., 13, 2663–2670, https://doi.org/10.5194/gmd-13-2663-2020, https://doi.org/10.5194/gmd-13-2663-2020, 2020
Short summary
Short summary
Secondary particles formed via nucleation have important implications for air quality and climate. Here we describe nucleation rate lookup tables for four different nucleation mechanisms that can be readily used in chemistry transport and climate models. The nucleation rates predicted have been assessed against state-of-the-art laboratory measurements. The lookup tables cover a wide range of key parameters controlling binary, ternary, and ion-mediated nucleation in the Earth's atmosphere.
Xiaoyan Ma, Hailing Jia, Rong Tian, Fangqun Yu, and Jiagnan Li
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-54, https://doi.org/10.5194/acp-2020-54, 2020
Preprint withdrawn
Short summary
Short summary
BC Mixing state, is one of critical microphysical properties to modulate optical properties, radiative forcing (RF), and climatic effect. However, it has been simply assumed previously as either external or internal mixing. In this study, by employing a nested GEOS-Chem-APM with predicted BC mixing state, we examined the effect of mixing state on aerosol optical properties, RF, and heating rate over East Asia. This will improve the predictions of aerosol climatic effect in the future.
Gan Luo, Fangqun Yu, and James Schwab
Geosci. Model Dev., 12, 3439–3447, https://doi.org/10.5194/gmd-12-3439-2019, https://doi.org/10.5194/gmd-12-3439-2019, 2019
Short summary
Short summary
GEOS-Chem 12.0.0 has been recognized to significantly overestimate the concentrations of gaseous nitric acid, aerosol nitrate, and aerosol ammonium over the United States. In this study, we show that most or all of the overestimation issue appears to be associated with wet scavenging processes. With the updated wet scavenging scheme in this work, we successfully improve the skill of the model in predicting the three species concentrations, which are important for air quality and climate studies.
George S. Fanourgakis, Maria Kanakidou, Athanasios Nenes, Susanne E. Bauer, Tommi Bergman, Ken S. Carslaw, Alf Grini, Douglas S. Hamilton, Jill S. Johnson, Vlassis A. Karydis, Alf Kirkevåg, John K. Kodros, Ulrike Lohmann, Gan Luo, Risto Makkonen, Hitoshi Matsui, David Neubauer, Jeffrey R. Pierce, Julia Schmale, Philip Stier, Kostas Tsigaridis, Twan van Noije, Hailong Wang, Duncan Watson-Parris, Daniel M. Westervelt, Yang Yang, Masaru Yoshioka, Nikos Daskalakis, Stefano Decesari, Martin Gysel-Beer, Nikos Kalivitis, Xiaohong Liu, Natalie M. Mahowald, Stelios Myriokefalitakis, Roland Schrödner, Maria Sfakianaki, Alexandra P. Tsimpidi, Mingxuan Wu, and Fangqun Yu
Atmos. Chem. Phys., 19, 8591–8617, https://doi.org/10.5194/acp-19-8591-2019, https://doi.org/10.5194/acp-19-8591-2019, 2019
Short summary
Short summary
Effects of aerosols on clouds are important for climate studies but are among the largest uncertainties in climate projections. This study evaluates the skill of global models to simulate aerosol, cloud condensation nuclei (CCN) and cloud droplet number concentrations (CDNCs). Model results show reduced spread in CDNC compared to CCN due to the negative correlation between the sensitivities of CDNC to aerosol number concentration (air pollution) and updraft velocity (atmospheric dynamics).
Fangqun Yu, Alexey B. Nadykto, Jason Herb, Gan Luo, Kirill M. Nazarenko, and Lyudmila A. Uvarova
Atmos. Chem. Phys., 18, 17451–17474, https://doi.org/10.5194/acp-18-17451-2018, https://doi.org/10.5194/acp-18-17451-2018, 2018
Short summary
Short summary
Aerosol nucleation exerts important influences on the climate, hydrological cycle, and air quality. We have developed an advanced physical–chemical model that describes ion-induced and neutral nucleation involving ammonia, sulfuric acid, and water vapors. The model is shown to reproduce laboratory measurements taken under a wide range of conditions, offers physiochemical insights into the ternary nucleation process, and provides an accurate approach to calculate ternary rate in the atmosphere.
Jingbo Mao, Fangqun Yu, Yan Zhang, Jingyu An, Lin Wang, Jun Zheng, Lei Yao, Gan Luo, Weichun Ma, Qi Yu, Cheng Huang, Li Li, and Limin Chen
Atmos. Chem. Phys., 18, 7933–7950, https://doi.org/10.5194/acp-18-7933-2018, https://doi.org/10.5194/acp-18-7933-2018, 2018
Short summary
Short summary
A few pptv of gaseous amines have been observed to affect particle nucleation and growth, and it is necessary to understand the sources and concentrations of atmospheric amines. This study presents the source-dependent amines to ammonia emission ratios and simulates methylamines concentrations in a polluted region in China with WRF-Chem. The performance of simulations based on source-dependent ratios is much better than those based on fixed ratios that have been assumed in all previous studies.
Maria Sand, Bjørn H. Samset, Yves Balkanski, Susanne Bauer, Nicolas Bellouin, Terje K. Berntsen, Huisheng Bian, Mian Chin, Thomas Diehl, Richard Easter, Steven J. Ghan, Trond Iversen, Alf Kirkevåg, Jean-François Lamarque, Guangxing Lin, Xiaohong Liu, Gan Luo, Gunnar Myhre, Twan van Noije, Joyce E. Penner, Michael Schulz, Øyvind Seland, Ragnhild B. Skeie, Philip Stier, Toshihiko Takemura, Kostas Tsigaridis, Fangqun Yu, Kai Zhang, and Hua Zhang
Atmos. Chem. Phys., 17, 12197–12218, https://doi.org/10.5194/acp-17-12197-2017, https://doi.org/10.5194/acp-17-12197-2017, 2017
Short summary
Short summary
The role of aerosols in the changing polar climate is not well understood and the aerosols are poorly constrained in the models. In this study we have compared output from 16 different aerosol models with available observations at both poles. We show that the model median is representative of the observations, but the model spread is large. The Arctic direct aerosol radiative effect over the industrial area is positive during spring due to black carbon and negative during summer due to sulfate.
Fangqun Yu, Gan Luo, Alexey B. Nadykto, and Jason Herb
Atmos. Chem. Phys., 17, 4997–5005, https://doi.org/10.5194/acp-17-4997-2017, https://doi.org/10.5194/acp-17-4997-2017, 2017
Short summary
Short summary
H2SO4–organics clustering thermodynamics from quantum studies has been employed to develop a scheme to include temperature dependence in an H2SO4–organics nucleation parameterization. We show that temperature has a strong impact on nucleation rates, particle number concentrations, and aerosol first indirect radiative forcing in summer. To our knowledge, the study represents the first attempt to study the temperature effect on organics-mediated nucleation in the global atmosphere.
F. Yu, G. Luo, S. C. Pryor, P. R. Pillai, S. H. Lee, J. Ortega, J. J. Schwab, A. G. Hallar, W. R. Leaitch, V. P. Aneja, J. N. Smith, J. T. Walker, O. Hogrefe, and K. L. Demerjian
Atmos. Chem. Phys., 15, 13993–14003, https://doi.org/10.5194/acp-15-13993-2015, https://doi.org/10.5194/acp-15-13993-2015, 2015
Short summary
Short summary
The role of low-volatility organics in new particle formation (NPF) in the atmosphere is assessed. An empirical formulation in which formation rate is a function of the concentrations of sulfuric acid and low-volatility organics significantly overpredicts NPF in the summer.
Two different schemes predict quite different nucleation rates (including their spatial patterns), concentrations of cloud condensation nuclei, and aerosol first indirect radiative forcing in North America.
F. Yu and G. Luo
Atmos. Chem. Phys., 14, 12455–12464, https://doi.org/10.5194/acp-14-12455-2014, https://doi.org/10.5194/acp-14-12455-2014, 2014
Short summary
Short summary
Global lifetimes and concentrations of gaseous methylamines (MMA, DMA, and TMA) have been simulated.
Oxidation and aerosol uptakes are dominant sinks for these methylamines. The oxidation alone leads to their lifetimes of 5-10h in most parts of low and middle latitude regions. The uptake by secondary species can shorten their lifetime to as low as 1-2h over central Europe, eastern Asia, and the eastern US.
The modeled concentrations are substantially lower than observed values available.
G. W. Mann, K. S. Carslaw, C. L. Reddington, K. J. Pringle, M. Schulz, A. Asmi, D. V. Spracklen, D. A. Ridley, M. T. Woodhouse, L. A. Lee, K. Zhang, S. J. Ghan, R. C. Easter, X. Liu, P. Stier, Y. H. Lee, P. J. Adams, H. Tost, J. Lelieveld, S. E. Bauer, K. Tsigaridis, T. P. C. van Noije, A. Strunk, E. Vignati, N. Bellouin, M. Dalvi, C. E. Johnson, T. Bergman, H. Kokkola, K. von Salzen, F. Yu, G. Luo, A. Petzold, J. Heintzenberg, A. Clarke, J. A. Ogren, J. Gras, U. Baltensperger, U. Kaminski, S. G. Jennings, C. D. O'Dowd, R. M. Harrison, D. C. S. Beddows, M. Kulmala, Y. Viisanen, V. Ulevicius, N. Mihalopoulos, V. Zdimal, M. Fiebig, H.-C. Hansson, E. Swietlicki, and J. S. Henzing
Atmos. Chem. Phys., 14, 4679–4713, https://doi.org/10.5194/acp-14-4679-2014, https://doi.org/10.5194/acp-14-4679-2014, 2014
X. Ma, K. Bartlett, K. Harmon, and F. Yu
Atmos. Meas. Tech., 6, 2391–2401, https://doi.org/10.5194/amt-6-2391-2013, https://doi.org/10.5194/amt-6-2391-2013, 2013
Naveed Ahmad, Changqing Lin, Alexis K. H. Lau, Jhoon Kim, Tianshu Zhang, Fangqun Yu, Chengcai Li, Ying Li, Jimmy C. H. Fung, and Xiang Qian Lao
Atmos. Chem. Phys., 24, 9645–9665, https://doi.org/10.5194/acp-24-9645-2024, https://doi.org/10.5194/acp-24-9645-2024, 2024
Short summary
Short summary
This study developed a nested machine learning model to convert the GEMS NO2 column measurements into ground-level concentrations across China. The model directly incorporates the NO2 mixing height (NMH) into the methodological framework. The study underscores the importance of considering NMH when estimating ground-level NO2 from satellite column measurements and highlights the significant advantages of new-generation geostationary satellites in air quality monitoring.
Huiyun Du, Jie Li, Xueshun Chen, Gabriele Curci, Fangqun Yu, Yele Sun, Xu Dao, Song Guo, Zhe Wang, Wenyi Yang, Lianfang Wei, and Zifa Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1432, https://doi.org/10.5194/egusphere-2024-1432, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Inadequate consideration of mixing state and coatings on BC hinders aerosol radiation forcing quantification. While core-shell mixing results match observations closely, partial internal mixing and coating are more realistic. The fraction of embedded BC and coating aerosols resolved by a microphysics module were used to constrain the mixing state. This led to a 30~43 % absorption enhancement decrease over Northern China, offering valuable insights for the assessment of BC's radiative effects.
Jie Zhang, Tianyu Zhu, Alexandra Catena, Yaowei Li, Margaret Schwab, Pengfei Liu, Akua Asa-Awuku, and James Schwab
EGUsphere, https://doi.org/10.5194/egusphere-2024-1390, https://doi.org/10.5194/egusphere-2024-1390, 2024
Short summary
Short summary
This study shows the derived organic aerosol hygroscopicity under high humidity conditions based on a simple optical scatter monitor system, including two nephelometric monitors (pDR-1500), after knowing the aerosol chemical composition.
Hongyu Liu, Bo Zhang, Richard H. Moore, Luke D. Ziemba, Richard A. Ferrare, Hyundeok Choi, Armin Sorooshian, David Painemal, Hailong Wang, Michael A. Shook, Amy Jo Scarino, Johnathan W. Hair, Ewan C. Crosbie, Marta A. Fenn, Taylor J. Shingler, Chris A. Hostetler, Gao Chen, Mary M. Kleb, Gan Luo, Fangqun Yu, Jason L. Tackett, Mark A. Vaughan, Yongxiang Hu, Glenn S. Diskin, John B. Nowak, Joshua P. DiGangi, Yonghoon Choi, Christoph A. Keller, and Matthew S. Johnson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1127, https://doi.org/10.5194/egusphere-2024-1127, 2024
Short summary
Short summary
We use the GEOS-Chem model to simulate aerosols over the western North Atlantic Ocean (WNAO) during the winter and summer campaigns of ACTIVATE 2020. Model results are evaluated against in situ and remote sensing measurements from two aircraft as well as ground-based and satellite observations. The improved understanding of the aerosol life cycle, composition, transport pathways, and distribution has important implications for characterizing aerosol-cloud-meteorology interactions over the WNAO.
Shixian Zhai, Daniel J. Jacob, Drew C. Pendergrass, Nadia K. Colombi, Viral Shah, Laura Hyesung Yang, Qiang Zhang, Shuxiao Wang, Hwajin Kim, Yele Sun, Jin-Soo Choi, Jin-Soo Park, Gan Luo, Fangqun Yu, Jung-Hun Woo, Younha Kim, Jack E. Dibb, Taehyoung Lee, Jin-Seok Han, Bruce E. Anderson, Ke Li, and Hong Liao
Atmos. Chem. Phys., 23, 4271–4281, https://doi.org/10.5194/acp-23-4271-2023, https://doi.org/10.5194/acp-23-4271-2023, 2023
Short summary
Short summary
Anthropogenic fugitive dust in East Asia not only causes severe coarse particulate matter air pollution problems, but also affects fine particulate nitrate. Due to emission control efforts, coarse PM decreased steadily. We find that the decrease of coarse PM is a major driver for a lack of decrease of fine particulate nitrate, as it allows more nitric acid to form fine particulate nitrate. The continuing decrease of coarse PM requires more stringent ammonia and nitrogen oxides emission controls.
Jun-Wei Xu, Jintai Lin, Gan Luo, Jamiu Adeniran, and Hao Kong
Atmos. Chem. Phys., 23, 4149–4163, https://doi.org/10.5194/acp-23-4149-2023, https://doi.org/10.5194/acp-23-4149-2023, 2023
Short summary
Short summary
Research on the sources of Chinese PM2.5 pollution has focused on the contributions of China’s domestic emissions. However, the impact of foreign anthropogenic emissions has typically been simplified or neglected. Here we find that foreign anthropogenic emissions play an important role in Chinese PM2.5 pollution through chemical interactions between foreign-transported pollutants and China’s local emissions. Thus, foreign emission reductions are essential for improving Chinese air quality.
Kun Wang, Xiaoyan Ma, Rong Tian, and Fangqun Yu
Atmos. Chem. Phys., 23, 4091–4104, https://doi.org/10.5194/acp-23-4091-2023, https://doi.org/10.5194/acp-23-4091-2023, 2023
Short summary
Short summary
From 12 March to 6 April 2016 in Beijing, there were 11 typical new particle formation days, 13 non-event days, and 2 undefined days. We first analyzed the favorable background of new particle formation in Beijing and then conducted the simulations using four nucleation schemes based on a global chemistry transport model (GEOS-Chem) to understand the nucleation mechanism.
Fangqun Yu, Gan Luo, Arshad Arjunan Nair, Sebastian Eastham, Christina J. Williamson, Agnieszka Kupc, and Charles A. Brock
Atmos. Chem. Phys., 23, 1863–1877, https://doi.org/10.5194/acp-23-1863-2023, https://doi.org/10.5194/acp-23-1863-2023, 2023
Short summary
Short summary
Particle number concentrations and size distributions in the stratosphere are studied through model simulations and comparisons with measurements. The nucleation scheme used in most of the solar geoengineering modeling studies overpredicts the nucleation rates and particle number concentrations in the stratosphere. The model based on updated nucleation schemes captures reasonably well some aspects of particle size distributions but misses some features. The possible reasons are discussed.
Christopher E. Lawrence, Paul Casson, Richard Brandt, James J. Schwab, James E. Dukett, Phil Snyder, Elizabeth Yerger, Daniel Kelting, Trevor C. VandenBoer, and Sara Lance
Atmos. Chem. Phys., 23, 1619–1639, https://doi.org/10.5194/acp-23-1619-2023, https://doi.org/10.5194/acp-23-1619-2023, 2023
Short summary
Short summary
Atmospheric aqueous chemistry can have profound effects on our environment, as illustrated by historical data from Whiteface Mountain (WFM) that were critical for uncovering the process of acid rain. The current study updates the long-term trends in cloud water composition at WFM for the period 1994 to 2021. We highlight the emergence of a new chemical regime at WFM dominated by organics and ammonium, quite different from the highly acidic regime observed in the past but not necessarily
clean.
Noah S. Hirshorn, Lauren M. Zuromski, Christopher Rapp, Ian McCubbin, Gerardo Carrillo-Cardenas, Fangqun Yu, and A. Gannet Hallar
Atmos. Chem. Phys., 22, 15909–15924, https://doi.org/10.5194/acp-22-15909-2022, https://doi.org/10.5194/acp-22-15909-2022, 2022
Short summary
Short summary
New particle formation (NPF) is a source of atmospheric aerosol number concentration that can impact climate by growing to larger sizes and under proper conditions form cloud condensation nuclei (CCN). Using novel methods, we find that at Storm Peak Laboratory, a remote, mountaintop site in Colorado, NPF is observed to enhance CCN concentrations in the spring by a factor of 1.54 and in the winter by a factor of 1.36 which can occur on a regional scale having important climate implications.
Katherine R. Travis, James H. Crawford, Gao Chen, Carolyn E. Jordan, Benjamin A. Nault, Hwajin Kim, Jose L. Jimenez, Pedro Campuzano-Jost, Jack E. Dibb, Jung-Hun Woo, Younha Kim, Shixian Zhai, Xuan Wang, Erin E. McDuffie, Gan Luo, Fangqun Yu, Saewung Kim, Isobel J. Simpson, Donald R. Blake, Limseok Chang, and Michelle J. Kim
Atmos. Chem. Phys., 22, 7933–7958, https://doi.org/10.5194/acp-22-7933-2022, https://doi.org/10.5194/acp-22-7933-2022, 2022
Short summary
Short summary
The 2016 Korea–United States Air Quality (KORUS-AQ) field campaign provided a unique set of observations to improve our understanding of PM2.5 pollution in South Korea. Models typically have errors in simulating PM2.5 in this region, which is of concern for the development of control measures. We use KORUS-AQ observations to improve our understanding of the mechanisms driving PM2.5 and the implications of model errors for determining PM2.5 that is attributable to local or foreign sources.
Yanda Zhang, Fangqun Yu, Gan Luo, Jiwen Fan, and Shuai Liu
Atmos. Chem. Phys., 21, 17433–17451, https://doi.org/10.5194/acp-21-17433-2021, https://doi.org/10.5194/acp-21-17433-2021, 2021
Short summary
Short summary
This paper explores the impacts of dust on summertime convective cloud and precipitation through a numerical experiment. The result indicates that the long-range-transported dust can notably affect the properties of convective cloud and precipitation by enhancing immersion freezing and invigorating convection. We also analyze the different dust effects predicted by the Morrison and SBM schemes, which are partially attributed to the saturation adjustment approach utilized in the bulk schemes.
Clémence Rose, Martine Collaud Coen, Elisabeth Andrews, Yong Lin, Isaline Bossert, Cathrine Lund Myhre, Thomas Tuch, Alfred Wiedensohler, Markus Fiebig, Pasi Aalto, Andrés Alastuey, Elisabeth Alonso-Blanco, Marcos Andrade, Begoña Artíñano, Todor Arsov, Urs Baltensperger, Susanne Bastian, Olaf Bath, Johan Paul Beukes, Benjamin T. Brem, Nicolas Bukowiecki, Juan Andrés Casquero-Vera, Sébastien Conil, Konstantinos Eleftheriadis, Olivier Favez, Harald Flentje, Maria I. Gini, Francisco Javier Gómez-Moreno, Martin Gysel-Beer, Anna Gannet Hallar, Ivo Kalapov, Nikos Kalivitis, Anne Kasper-Giebl, Melita Keywood, Jeong Eun Kim, Sang-Woo Kim, Adam Kristensson, Markku Kulmala, Heikki Lihavainen, Neng-Huei Lin, Hassan Lyamani, Angela Marinoni, Sebastiao Martins Dos Santos, Olga L. Mayol-Bracero, Frank Meinhardt, Maik Merkel, Jean-Marc Metzger, Nikolaos Mihalopoulos, Jakub Ondracek, Marco Pandolfi, Noemi Pérez, Tuukka Petäjä, Jean-Eudes Petit, David Picard, Jean-Marc Pichon, Veronique Pont, Jean-Philippe Putaud, Fabienne Reisen, Karine Sellegri, Sangeeta Sharma, Gerhard Schauer, Patrick Sheridan, James Patrick Sherman, Andreas Schwerin, Ralf Sohmer, Mar Sorribas, Junying Sun, Pierre Tulet, Ville Vakkari, Pieter Gideon van Zyl, Fernando Velarde, Paolo Villani, Stergios Vratolis, Zdenek Wagner, Sheng-Hsiang Wang, Kay Weinhold, Rolf Weller, Margarita Yela, Vladimir Zdimal, and Paolo Laj
Atmos. Chem. Phys., 21, 17185–17223, https://doi.org/10.5194/acp-21-17185-2021, https://doi.org/10.5194/acp-21-17185-2021, 2021
Short summary
Short summary
Aerosol particles are a complex component of the atmospheric system the effects of which are among the most uncertain in climate change projections. Using data collected at 62 stations, this study provides the most up-to-date picture of the spatial distribution of particle number concentration and size distribution worldwide, with the aim of contributing to better representation of aerosols and their interactions with clouds in models and, therefore, better evaluation of their impact on climate.
Shixian Zhai, Daniel J. Jacob, Jared F. Brewer, Ke Li, Jonathan M. Moch, Jhoon Kim, Seoyoung Lee, Hyunkwang Lim, Hyun Chul Lee, Su Keun Kuk, Rokjin J. Park, Jaein I. Jeong, Xuan Wang, Pengfei Liu, Gan Luo, Fangqun Yu, Jun Meng, Randall V. Martin, Katherine R. Travis, Johnathan W. Hair, Bruce E. Anderson, Jack E. Dibb, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jung-Hun Woo, Younha Kim, Qiang Zhang, and Hong Liao
Atmos. Chem. Phys., 21, 16775–16791, https://doi.org/10.5194/acp-21-16775-2021, https://doi.org/10.5194/acp-21-16775-2021, 2021
Short summary
Short summary
Geostationary satellite aerosol optical depth (AOD) has tremendous potential for monitoring surface fine particulate matter (PM2.5). Our study explored the physical relationship between AOD and PM2.5 by integrating data from surface networks, aircraft, and satellites with the GEOS-Chem chemical transport model. We quantitatively showed that accurate simulation of aerosol size distributions, boundary layer depths, relative humidity, coarse particles, and diurnal variations in PM2.5 are essential.
Gloria Titos, María A. Burgos, Paul Zieger, Lucas Alados-Arboledas, Urs Baltensperger, Anne Jefferson, James Sherman, Ernest Weingartner, Bas Henzing, Krista Luoma, Colin O'Dowd, Alfred Wiedensohler, and Elisabeth Andrews
Atmos. Chem. Phys., 21, 13031–13050, https://doi.org/10.5194/acp-21-13031-2021, https://doi.org/10.5194/acp-21-13031-2021, 2021
Short summary
Short summary
This paper investigates the impact of water uptake on aerosol optical properties, in particular the aerosol light-scattering coefficient. Although in situ measurements are performed at low relative humidity (typically at
RH < 40 %), to address the climatic impact of aerosol particles it is necessary to take into account the effect that water uptake may have on the aerosol optical properties.
Gongda Lu, Eloise A. Marais, Tuan V. Vu, Jingsha Xu, Zongbo Shi, James D. Lee, Qiang Zhang, Lu Shen, Gan Luo, and Fangqun Yu
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-428, https://doi.org/10.5194/acp-2021-428, 2021
Revised manuscript not accepted
Short summary
Short summary
Emission controls were imposed in Beijing-Tianjin-Hebei in northern China in autumn-winter 2017. We find that regional PM2.5 targets (15 % decrease relative to previous year) were exceeded. Our analysis shows that decline in precursor emissions only leads to less than half (43 %) the improved air quality. Most of the change (57 %) is due to interannual variability in meteorology. Stricter emission controls may be necessary in years with unfavourable meteorology.
Xueshun Chen, Fangqun Yu, Wenyi Yang, Yele Sun, Huansheng Chen, Wei Du, Jian Zhao, Ying Wei, Lianfang Wei, Huiyun Du, Zhe Wang, Qizhong Wu, Jie Li, Junling An, and Zifa Wang
Atmos. Chem. Phys., 21, 9343–9366, https://doi.org/10.5194/acp-21-9343-2021, https://doi.org/10.5194/acp-21-9343-2021, 2021
Short summary
Short summary
Atmospheric aerosol particles have significant climate and health effects that depend on aerosol size, composition, and mixing state. A new global-regional nested aerosol model with an advanced particle microphysics module and a volatility basis set organic aerosol module was developed to simulate aerosol microphysical processes. Simulations strongly suggest the important role of anthropogenic organic species in particle formation over the areas influenced by anthropogenic sources.
Xiaojing Shen, Junying Sun, Fangqun Yu, Ying Wang, Junting Zhong, Yangmei Zhang, Xinyao Hu, Can Xia, Sinan Zhang, and Xiaoye Zhang
Atmos. Chem. Phys., 21, 7039–7052, https://doi.org/10.5194/acp-21-7039-2021, https://doi.org/10.5194/acp-21-7039-2021, 2021
Short summary
Short summary
In this work, we revealed the changes of PNSD and NPF events during the COVID-19 lockdown period in Beijing, China, to illustrate the impact of reduced primary emission and elavated atmospheric oxidized capicity on the nucleation and growth processes. The subsequent growth of nucleated particles and their contribution to the aerosol pollution formation were also explored, to highlight the necessity of controlling the nanoparticles in the future air quality management.
Ling Liu, Fangqun Yu, Kaipeng Tu, Zhi Yang, and Xiuhui Zhang
Atmos. Chem. Phys., 21, 6221–6230, https://doi.org/10.5194/acp-21-6221-2021, https://doi.org/10.5194/acp-21-6221-2021, 2021
Short summary
Short summary
Trifluoroacetic acid (TFA) was previously proved to participate in sulfuric acid (SA)–dimethylamine (DMA) nucleation in Shanghai, China. However, complex atmospheric environments can influence the nucleation of aerosol significantly. We show the influence of different atmospheric conditions on the SA-DMA-TFA nucleation and find the enhancement by TFA can be significant in cold and polluted areas, which provides the perspective of the realistic role of TFA in different atmospheric environments.
Arshad Arjunan Nair and Fangqun Yu
Atmos. Chem. Phys., 20, 12853–12869, https://doi.org/10.5194/acp-20-12853-2020, https://doi.org/10.5194/acp-20-12853-2020, 2020
Short summary
Short summary
Small particles in the atmosphere can affect cloud formation and properties and thus Earth's energy budget. These cloud condensation nuclei (CCN) contribute the largest uncertainties in climate change modeling. To reduce these uncertainties, it is important to quantify CCN numbers accurately, measurements of which are sparse. We propose and evaluate a machine learning method to estimate CCN, in the absence of their direct measurements, using more common measurements of weather and air quality.
María A. Burgos, Elisabeth Andrews, Gloria Titos, Angela Benedetti, Huisheng Bian, Virginie Buchard, Gabriele Curci, Zak Kipling, Alf Kirkevåg, Harri Kokkola, Anton Laakso, Julie Letertre-Danczak, Marianne T. Lund, Hitoshi Matsui, Gunnar Myhre, Cynthia Randles, Michael Schulz, Twan van Noije, Kai Zhang, Lucas Alados-Arboledas, Urs Baltensperger, Anne Jefferson, James Sherman, Junying Sun, Ernest Weingartner, and Paul Zieger
Atmos. Chem. Phys., 20, 10231–10258, https://doi.org/10.5194/acp-20-10231-2020, https://doi.org/10.5194/acp-20-10231-2020, 2020
Short summary
Short summary
We investigate how well models represent the enhancement in scattering coefficients due to particle water uptake, and perform an evaluation of several implementation schemes used in ten Earth system models. Our results show the importance of the parameterization of hygroscopicity and model chemistry as drivers of some of the observed diversity amongst model estimates. The definition of dry conditions and the phenomena taking place in this relative humidity range also impact the model evaluation.
Paolo Laj, Alessandro Bigi, Clémence Rose, Elisabeth Andrews, Cathrine Lund Myhre, Martine Collaud Coen, Yong Lin, Alfred Wiedensohler, Michael Schulz, John A. Ogren, Markus Fiebig, Jonas Gliß, Augustin Mortier, Marco Pandolfi, Tuukka Petäja, Sang-Woo Kim, Wenche Aas, Jean-Philippe Putaud, Olga Mayol-Bracero, Melita Keywood, Lorenzo Labrador, Pasi Aalto, Erik Ahlberg, Lucas Alados Arboledas, Andrés Alastuey, Marcos Andrade, Begoña Artíñano, Stina Ausmeel, Todor Arsov, Eija Asmi, John Backman, Urs Baltensperger, Susanne Bastian, Olaf Bath, Johan Paul Beukes, Benjamin T. Brem, Nicolas Bukowiecki, Sébastien Conil, Cedric Couret, Derek Day, Wan Dayantolis, Anna Degorska, Konstantinos Eleftheriadis, Prodromos Fetfatzis, Olivier Favez, Harald Flentje, Maria I. Gini, Asta Gregorič, Martin Gysel-Beer, A. Gannet Hallar, Jenny Hand, Andras Hoffer, Christoph Hueglin, Rakesh K. Hooda, Antti Hyvärinen, Ivo Kalapov, Nikos Kalivitis, Anne Kasper-Giebl, Jeong Eun Kim, Giorgos Kouvarakis, Irena Kranjc, Radovan Krejci, Markku Kulmala, Casper Labuschagne, Hae-Jung Lee, Heikki Lihavainen, Neng-Huei Lin, Gunter Löschau, Krista Luoma, Angela Marinoni, Sebastiao Martins Dos Santos, Frank Meinhardt, Maik Merkel, Jean-Marc Metzger, Nikolaos Mihalopoulos, Nhat Anh Nguyen, Jakub Ondracek, Noemi Pérez, Maria Rita Perrone, Jean-Eudes Petit, David Picard, Jean-Marc Pichon, Veronique Pont, Natalia Prats, Anthony Prenni, Fabienne Reisen, Salvatore Romano, Karine Sellegri, Sangeeta Sharma, Gerhard Schauer, Patrick Sheridan, James Patrick Sherman, Maik Schütze, Andreas Schwerin, Ralf Sohmer, Mar Sorribas, Martin Steinbacher, Junying Sun, Gloria Titos, Barbara Toczko, Thomas Tuch, Pierre Tulet, Peter Tunved, Ville Vakkari, Fernando Velarde, Patricio Velasquez, Paolo Villani, Sterios Vratolis, Sheng-Hsiang Wang, Kay Weinhold, Rolf Weller, Margarita Yela, Jesus Yus-Diez, Vladimir Zdimal, Paul Zieger, and Nadezda Zikova
Atmos. Meas. Tech., 13, 4353–4392, https://doi.org/10.5194/amt-13-4353-2020, https://doi.org/10.5194/amt-13-4353-2020, 2020
Short summary
Short summary
The paper establishes the fiducial reference of the GAW aerosol network providing the fully characterized value chain to the provision of four climate-relevant aerosol properties from ground-based sites. Data from almost 90 stations worldwide are reported for a reference year, 2017, providing a unique and very robust view of the variability of these variables worldwide. Current gaps in the GAW network are analysed and requirements for the Global Climate Monitoring System are proposed.
Martine Collaud Coen, Elisabeth Andrews, Andrés Alastuey, Todor Petkov Arsov, John Backman, Benjamin T. Brem, Nicolas Bukowiecki, Cédric Couret, Konstantinos Eleftheriadis, Harald Flentje, Markus Fiebig, Martin Gysel-Beer, Jenny L. Hand, András Hoffer, Rakesh Hooda, Christoph Hueglin, Warren Joubert, Melita Keywood, Jeong Eun Kim, Sang-Woo Kim, Casper Labuschagne, Neng-Huei Lin, Yong Lin, Cathrine Lund Myhre, Krista Luoma, Hassan Lyamani, Angela Marinoni, Olga L. Mayol-Bracero, Nikos Mihalopoulos, Marco Pandolfi, Natalia Prats, Anthony J. Prenni, Jean-Philippe Putaud, Ludwig Ries, Fabienne Reisen, Karine Sellegri, Sangeeta Sharma, Patrick Sheridan, James Patrick Sherman, Junying Sun, Gloria Titos, Elvis Torres, Thomas Tuch, Rolf Weller, Alfred Wiedensohler, Paul Zieger, and Paolo Laj
Atmos. Chem. Phys., 20, 8867–8908, https://doi.org/10.5194/acp-20-8867-2020, https://doi.org/10.5194/acp-20-8867-2020, 2020
Short summary
Short summary
Long-term trends of aerosol radiative properties (52 stations) prove that aerosol load has significantly decreased over the last 20 years. Scattering trends are negative in Europe (EU) and North America (NA), not ss in Asia, and show a mix of positive and negative trends at polar stations. Absorption has mainly negative trends. The single scattering albedo has positive trends in Asia and eastern EU and negative in western EU and NA, leading to a global positive median trend of 0.02 % per year.
Katherine R. Travis, Colette L. Heald, Hannah M. Allen, Eric C. Apel, Stephen R. Arnold, Donald R. Blake, William H. Brune, Xin Chen, Róisín Commane, John D. Crounse, Bruce C. Daube, Glenn S. Diskin, James W. Elkins, Mathew J. Evans, Samuel R. Hall, Eric J. Hintsa, Rebecca S. Hornbrook, Prasad S. Kasibhatla, Michelle J. Kim, Gan Luo, Kathryn McKain, Dylan B. Millet, Fred L. Moore, Jeffrey Peischl, Thomas B. Ryerson, Tomás Sherwen, Alexander B. Thames, Kirk Ullmann, Xuan Wang, Paul O. Wennberg, Glenn M. Wolfe, and Fangqun Yu
Atmos. Chem. Phys., 20, 7753–7781, https://doi.org/10.5194/acp-20-7753-2020, https://doi.org/10.5194/acp-20-7753-2020, 2020
Short summary
Short summary
Atmospheric models overestimate the rate of removal of trace gases by the hydroxyl radical (OH). This is a concern for studies of the climate and air quality impacts of human activities. Here, we evaluate the performance of a commonly used model of atmospheric chemistry against data from the NASA Atmospheric Tomography Mission (ATom) over the remote oceans where models have received little validation. The model is generally successful, suggesting that biases in OH may be a concern over land.
Gan Luo, Fangqun Yu, and Jonathan M. Moch
Geosci. Model Dev., 13, 2879–2903, https://doi.org/10.5194/gmd-13-2879-2020, https://doi.org/10.5194/gmd-13-2879-2020, 2020
Short summary
Short summary
This work improved pH calculation for cloud, rain, and wet surfaces, fraction of cloud available for aqueous-phase chemistry, rainout efficiencies for various types of cloud, empirical washout by rain and snow, and wet surface uptake in GEOS-Chem v12.6.0. We compared simulated mass concentrations of aerosol precursors and aerosols with surface monitoring networks, Arctic sites, and ATom observations, and showed that the model results with the updated wet processes agree better for most species.
Fangqun Yu, Alexey B. Nadykto, Gan Luo, and Jason Herb
Geosci. Model Dev., 13, 2663–2670, https://doi.org/10.5194/gmd-13-2663-2020, https://doi.org/10.5194/gmd-13-2663-2020, 2020
Short summary
Short summary
Secondary particles formed via nucleation have important implications for air quality and climate. Here we describe nucleation rate lookup tables for four different nucleation mechanisms that can be readily used in chemistry transport and climate models. The nucleation rates predicted have been assessed against state-of-the-art laboratory measurements. The lookup tables cover a wide range of key parameters controlling binary, ternary, and ion-mediated nucleation in the Earth's atmosphere.
Xiaoyan Ma, Hailing Jia, Rong Tian, Fangqun Yu, and Jiagnan Li
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-54, https://doi.org/10.5194/acp-2020-54, 2020
Preprint withdrawn
Short summary
Short summary
BC Mixing state, is one of critical microphysical properties to modulate optical properties, radiative forcing (RF), and climatic effect. However, it has been simply assumed previously as either external or internal mixing. In this study, by employing a nested GEOS-Chem-APM with predicted BC mixing state, we examined the effect of mixing state on aerosol optical properties, RF, and heating rate over East Asia. This will improve the predictions of aerosol climatic effect in the future.
Gan Luo, Fangqun Yu, and James Schwab
Geosci. Model Dev., 12, 3439–3447, https://doi.org/10.5194/gmd-12-3439-2019, https://doi.org/10.5194/gmd-12-3439-2019, 2019
Short summary
Short summary
GEOS-Chem 12.0.0 has been recognized to significantly overestimate the concentrations of gaseous nitric acid, aerosol nitrate, and aerosol ammonium over the United States. In this study, we show that most or all of the overestimation issue appears to be associated with wet scavenging processes. With the updated wet scavenging scheme in this work, we successfully improve the skill of the model in predicting the three species concentrations, which are important for air quality and climate studies.
George S. Fanourgakis, Maria Kanakidou, Athanasios Nenes, Susanne E. Bauer, Tommi Bergman, Ken S. Carslaw, Alf Grini, Douglas S. Hamilton, Jill S. Johnson, Vlassis A. Karydis, Alf Kirkevåg, John K. Kodros, Ulrike Lohmann, Gan Luo, Risto Makkonen, Hitoshi Matsui, David Neubauer, Jeffrey R. Pierce, Julia Schmale, Philip Stier, Kostas Tsigaridis, Twan van Noije, Hailong Wang, Duncan Watson-Parris, Daniel M. Westervelt, Yang Yang, Masaru Yoshioka, Nikos Daskalakis, Stefano Decesari, Martin Gysel-Beer, Nikos Kalivitis, Xiaohong Liu, Natalie M. Mahowald, Stelios Myriokefalitakis, Roland Schrödner, Maria Sfakianaki, Alexandra P. Tsimpidi, Mingxuan Wu, and Fangqun Yu
Atmos. Chem. Phys., 19, 8591–8617, https://doi.org/10.5194/acp-19-8591-2019, https://doi.org/10.5194/acp-19-8591-2019, 2019
Short summary
Short summary
Effects of aerosols on clouds are important for climate studies but are among the largest uncertainties in climate projections. This study evaluates the skill of global models to simulate aerosol, cloud condensation nuclei (CCN) and cloud droplet number concentrations (CDNCs). Model results show reduced spread in CDNC compared to CCN due to the negative correlation between the sensitivities of CDNC to aerosol number concentration (air pollution) and updraft velocity (atmospheric dynamics).
Fangqun Yu, Alexey B. Nadykto, Jason Herb, Gan Luo, Kirill M. Nazarenko, and Lyudmila A. Uvarova
Atmos. Chem. Phys., 18, 17451–17474, https://doi.org/10.5194/acp-18-17451-2018, https://doi.org/10.5194/acp-18-17451-2018, 2018
Short summary
Short summary
Aerosol nucleation exerts important influences on the climate, hydrological cycle, and air quality. We have developed an advanced physical–chemical model that describes ion-induced and neutral nucleation involving ammonia, sulfuric acid, and water vapors. The model is shown to reproduce laboratory measurements taken under a wide range of conditions, offers physiochemical insights into the ternary nucleation process, and provides an accurate approach to calculate ternary rate in the atmosphere.
Jingbo Mao, Fangqun Yu, Yan Zhang, Jingyu An, Lin Wang, Jun Zheng, Lei Yao, Gan Luo, Weichun Ma, Qi Yu, Cheng Huang, Li Li, and Limin Chen
Atmos. Chem. Phys., 18, 7933–7950, https://doi.org/10.5194/acp-18-7933-2018, https://doi.org/10.5194/acp-18-7933-2018, 2018
Short summary
Short summary
A few pptv of gaseous amines have been observed to affect particle nucleation and growth, and it is necessary to understand the sources and concentrations of atmospheric amines. This study presents the source-dependent amines to ammonia emission ratios and simulates methylamines concentrations in a polluted region in China with WRF-Chem. The performance of simulations based on source-dependent ratios is much better than those based on fixed ratios that have been assumed in all previous studies.
Jie Zhang, Sara Lance, Jeffrey M. Freedman, Yele Sun, Brian A. Crandall, Xiuli Wei, and James J. Schwab
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-529, https://doi.org/10.5194/acp-2018-529, 2018
Preprint retracted
Short summary
Short summary
The impact of fireworks (FW) events on air quality was studied using a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and collocated instruments during the Independence Day (July 4) holiday. The Independence Day FW events resulted in significant increases in both organic and inorganic (potassium, sulfate, chloride) chemical components, and the contribution from different aerosol sources was discussed.
Jie Zhang, Joseph P. Marto, and James J. Schwab
Atmos. Meas. Tech., 11, 2995–3005, https://doi.org/10.5194/amt-11-2995-2018, https://doi.org/10.5194/amt-11-2995-2018, 2018
Short summary
Short summary
The performance of two kinds of optical instruments for aerosol mass measurements was explained by a Mie scattering theory. At the same time, the response of optical instruments for ambient aerosol with different size, chemical composition, and refractive index were also studied. These would help evaluate the applicability and limitations of these optical scattering instruments.
James P. Sherman and Allison McComiskey
Atmos. Chem. Phys., 18, 4131–4152, https://doi.org/10.5194/acp-18-4131-2018, https://doi.org/10.5194/acp-18-4131-2018, 2018
Short summary
Short summary
This paper highlights the first multi-year ground-based climatology of aerosol direct radiative effect (DRE) in the southeastern US Aerosol DRE at the co-located NOAA and NASA aerosol monitoring sites at Appalachian State University is approximately five times more negative during summer than winter. Aerosol DRE is most sensitive to aerosol optical depth (AOD). Use of MODIS-measured increases DRE uncertainty by a factor of 2.5 to 5.
Maria Sand, Bjørn H. Samset, Yves Balkanski, Susanne Bauer, Nicolas Bellouin, Terje K. Berntsen, Huisheng Bian, Mian Chin, Thomas Diehl, Richard Easter, Steven J. Ghan, Trond Iversen, Alf Kirkevåg, Jean-François Lamarque, Guangxing Lin, Xiaohong Liu, Gan Luo, Gunnar Myhre, Twan van Noije, Joyce E. Penner, Michael Schulz, Øyvind Seland, Ragnhild B. Skeie, Philip Stier, Toshihiko Takemura, Kostas Tsigaridis, Fangqun Yu, Kai Zhang, and Hua Zhang
Atmos. Chem. Phys., 17, 12197–12218, https://doi.org/10.5194/acp-17-12197-2017, https://doi.org/10.5194/acp-17-12197-2017, 2017
Short summary
Short summary
The role of aerosols in the changing polar climate is not well understood and the aerosols are poorly constrained in the models. In this study we have compared output from 16 different aerosol models with available observations at both poles. We show that the model median is representative of the observations, but the model spread is large. The Arctic direct aerosol radiative effect over the industrial area is positive during spring due to black carbon and negative during summer due to sulfate.
Lauren Schmeisser, Elisabeth Andrews, John A. Ogren, Patrick Sheridan, Anne Jefferson, Sangeeta Sharma, Jeong Eun Kim, James P. Sherman, Mar Sorribas, Ivo Kalapov, Todor Arsov, Christo Angelov, Olga L. Mayol-Bracero, Casper Labuschagne, Sang-Woo Kim, András Hoffer, Neng-Huei Lin, Hao-Ping Chia, Michael Bergin, Junying Sun, Peng Liu, and Hao Wu
Atmos. Chem. Phys., 17, 12097–12120, https://doi.org/10.5194/acp-17-12097-2017, https://doi.org/10.5194/acp-17-12097-2017, 2017
Short summary
Short summary
Three methods are used to classify aerosol type from aerosol optical properties measured in situ at 24 surface sites. Classification methods work best at sites with stable, homogenous aerosol at particularly polluted and dust-prone continental and marine sites. Classification methods are poor at remote marine and Arctic sites. Using these methods to extrapolate aerosol type from optical properties can help determine aerosol radiative forcing and improve aerosol satellite retrieval algorithms.
K. Max Zhang, George Allen, Bo Yang, Geng Chen, Jiajun Gu, James Schwab, Dirk Felton, and Oliver Rattigan
Atmos. Chem. Phys., 17, 11441–11452, https://doi.org/10.5194/acp-17-11441-2017, https://doi.org/10.5194/acp-17-11441-2017, 2017
Short summary
Short summary
Woodsmoke is a worldwide public health concern. A reliable marker for woodsmoke will be very useful in air-quality management. DC (Delta-C) has been proposed as a woodsmoke marker in previous studies. However, several researchers raised concerns of whether it is reliable. Our study took advantage of aerosol light absorption and PM2.5 data collected at three US cities/towns dominated by woodsmoke. We showed that DC can be a good qualitative and semi-quantitive marker, but with limitations.
Fangqun Yu, Gan Luo, Alexey B. Nadykto, and Jason Herb
Atmos. Chem. Phys., 17, 4997–5005, https://doi.org/10.5194/acp-17-4997-2017, https://doi.org/10.5194/acp-17-4997-2017, 2017
Short summary
Short summary
H2SO4–organics clustering thermodynamics from quantum studies has been employed to develop a scheme to include temperature dependence in an H2SO4–organics nucleation parameterization. We show that temperature has a strong impact on nucleation rates, particle number concentrations, and aerosol first indirect radiative forcing in summer. To our knowledge, the study represents the first attempt to study the temperature effect on organics-mediated nucleation in the global atmosphere.
F. Yu, G. Luo, S. C. Pryor, P. R. Pillai, S. H. Lee, J. Ortega, J. J. Schwab, A. G. Hallar, W. R. Leaitch, V. P. Aneja, J. N. Smith, J. T. Walker, O. Hogrefe, and K. L. Demerjian
Atmos. Chem. Phys., 15, 13993–14003, https://doi.org/10.5194/acp-15-13993-2015, https://doi.org/10.5194/acp-15-13993-2015, 2015
Short summary
Short summary
The role of low-volatility organics in new particle formation (NPF) in the atmosphere is assessed. An empirical formulation in which formation rate is a function of the concentrations of sulfuric acid and low-volatility organics significantly overpredicts NPF in the summer.
Two different schemes predict quite different nucleation rates (including their spatial patterns), concentrations of cloud condensation nuclei, and aerosol first indirect radiative forcing in North America.
J. P. Sherman, P. J. Sheridan, J. A. Ogren, E. Andrews, D. Hageman, L. Schmeisser, A. Jefferson, and S. Sharma
Atmos. Chem. Phys., 15, 12487–12517, https://doi.org/10.5194/acp-15-12487-2015, https://doi.org/10.5194/acp-15-12487-2015, 2015
Short summary
Short summary
Variability in aerosol optical properties relevant to radiative forcing were studied on several timescales at four continental North American NOAA-ESRL sites. Light scattering and intensive properties varied most on seasonal scales while absorption variability on weekly and diurnal timescales was comparable to its seasonal variability. Large reductions in light scattering were observed at the two long-term sites (relative to late 1990s), along with a smaller contribution by sub-1µm particles.
F. Yu and G. Luo
Atmos. Chem. Phys., 14, 12455–12464, https://doi.org/10.5194/acp-14-12455-2014, https://doi.org/10.5194/acp-14-12455-2014, 2014
Short summary
Short summary
Global lifetimes and concentrations of gaseous methylamines (MMA, DMA, and TMA) have been simulated.
Oxidation and aerosol uptakes are dominant sinks for these methylamines. The oxidation alone leads to their lifetimes of 5-10h in most parts of low and middle latitude regions. The uptake by secondary species can shorten their lifetime to as low as 1-2h over central Europe, eastern Asia, and the eastern US.
The modeled concentrations are substantially lower than observed values available.
G. W. Mann, K. S. Carslaw, C. L. Reddington, K. J. Pringle, M. Schulz, A. Asmi, D. V. Spracklen, D. A. Ridley, M. T. Woodhouse, L. A. Lee, K. Zhang, S. J. Ghan, R. C. Easter, X. Liu, P. Stier, Y. H. Lee, P. J. Adams, H. Tost, J. Lelieveld, S. E. Bauer, K. Tsigaridis, T. P. C. van Noije, A. Strunk, E. Vignati, N. Bellouin, M. Dalvi, C. E. Johnson, T. Bergman, H. Kokkola, K. von Salzen, F. Yu, G. Luo, A. Petzold, J. Heintzenberg, A. Clarke, J. A. Ogren, J. Gras, U. Baltensperger, U. Kaminski, S. G. Jennings, C. D. O'Dowd, R. M. Harrison, D. C. S. Beddows, M. Kulmala, Y. Viisanen, V. Ulevicius, N. Mihalopoulos, V. Zdimal, M. Fiebig, H.-C. Hansson, E. Swietlicki, and J. S. Henzing
Atmos. Chem. Phys., 14, 4679–4713, https://doi.org/10.5194/acp-14-4679-2014, https://doi.org/10.5194/acp-14-4679-2014, 2014
X. Ma, K. Bartlett, K. Harmon, and F. Yu
Atmos. Meas. Tech., 6, 2391–2401, https://doi.org/10.5194/amt-6-2391-2013, https://doi.org/10.5194/amt-6-2391-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Revealing dominant patterns of aerosol regimes in the lower troposphere and their evolution from preindustrial times to the future in global climate model simulations
Improving estimation of a record-breaking east Asian dust storm emission with lagged aerosol Ångström exponent observations
Impact of biomass burning aerosols (BBA) on the tropical African climate in an ocean–atmosphere–aerosol coupled climate model
Retrieval of refractive index and water content for the coating materials of aged black carbon aerosol based on optical properties: a theoretical analysis
Predicting hygroscopic growth of organosulfur aerosol particles using COSMOtherm
Dust aerosol from the Aralkum Desert influences the radiation budget and atmospheric dynamics of Central Asia
Global modeling of aerosol nucleation with a semi-explicit chemical mechanism for highly oxygenated organic molecules (HOMs)
Synergistic effects of the winter North Atlantic Oscillation (NAO) and El Niño–Southern Oscillation (ENSO) on dust activities in North China during the following spring
Aerosol composition, air quality, and boundary layer dynamics in the urban background of Stuttgart in winter
Measurement report: Source attribution and estimation of black carbon levels in an urban hotspot of the central Po Valley – an integrated approach combining high-resolution dispersion modelling and micro-aethalometers
Microphysical modelling of aerosol scavenging by different types of clouds: description and validation of the approach
Insights into the sources of ultrafine particle numbers at six European urban sites obtained by investigating COVID-19 lockdowns
In-plume and out-of-plume analysis of aerosol–cloud interactions derived from the 2014–2015 Holuhraun volcanic eruption
Impacts of atmospheric circulation patterns and cloud inhibition on aerosol radiative effect and boundary layer structure during winter air pollution in Sichuan Basin, China
Investigating the sign of stratocumulus adjustments to aerosols in the ICON global storm-resolving model
A model study investigating the sensitivity of aerosol forcing to the volatilities of semi-volatile organic compounds
Decomposing the effective radiative forcing of anthropogenic aerosols based on CMIP6 Earth system models
The role of interfacial tension in the size-dependent phase separation of atmospheric aerosol particles
Modeling impacts of dust mineralogy on fast climate response
Representation of iron aerosol size distributions is critical in evaluating atmospheric soluble iron input to the ocean
Gaps in our understanding of ice-nucleating particle sources exposed by global simulation of the UK climate model
Uncertainties in laboratory-measured shortwave refractive indices of mineral dust aerosols and derived optical properties: a theoretical assessment
Diagnosing uncertainties in global biomass burning emission inventories and their impact on modeled air pollutants
Solar radiation estimation in West Africa: impact of dust conditions during 2021 dry season
Role of atmospheric aerosols in severe winter fog over the Indo-Gangetic Plain of India: a case study
Long-term variability in black carbon emissions constrained by gap-filled absorption aerosol optical depth and associated premature mortality in China
Intercomparison of aerosol optical depths from four reanalyses and their multi-reanalysis consensus
Biomass Burning Emissions Analysis Based on MODIS AOD and AeroCom Multi-Model Simulations
Global aviation contrail climate effects from 2019 to 2021
Multi-model effective radiative forcing of the 2020 sulphur cap for shipping
Rapid iodine oxoacid nucleation enhanced by dimethylamine in broad marine regions
Simulations of the impact of cloud condensation nuclei and ice-nucleating particles perturbations on the microphysics and radar reflectivity factor of stratiform mixed-phase clouds
Warming effects of reduced sulfur emissions from shipping
Aerosols in the central Arctic cryosphere: satellite and model integrated insights during Arctic spring and summer
Observationally constrained regional variations of shortwave absorption by iron oxides emphasize the cooling effect of dust
Droplet collection efficiencies inferred from satellite retrievals constrain effective radiative forcing of aerosol–cloud interactions
Global aerosol-type classification using a new hybrid algorithm and Aerosol Robotic Network data
Tropospheric aerosols over the western North Atlantic Ocean during the winter and summer campaigns of ACTIVATE 2020: Life cycle, transport, and distribution
Simulated phase state and viscosity of secondary organic aerosols over China
Comparing the simulated influence of biomass burning plumes on low-level clouds over the southeastern Atlantic under varying smoke conditions
A global dust emission dataset for estimating dust radiative forcings in climate models
Improved simulations of biomass burning aerosol optical properties and lifetimes in the NASA GEOS Model during the ORACLES-I campaign
Sharp increase in Saharan dust intrusions over the western Euro-Mediterranean in February–March 2020–2022 and associated atmospheric circulation
Temporal and spatial variations in dust activity in Australia based on remote sensing and reanalysis datasets
Sensitivity of global direct aerosol shortwave radiative forcing to uncertainties in aerosol optical properties
Molecular-level study on the role of methanesulfonic acid in iodine oxoacid nucleation
Regional to global distributions, trends, and drivers of biogenic volatile organic compound emission from 2001 to 2020
Impacts of ice-nucleating particles on cirrus clouds and radiation derived from global model simulations with MADE3 in EMAC
Seasonal characteristics of emission, distribution, and radiative effect of marine organic aerosols over the western Pacific Ocean: an investigation with a coupled regional climate aerosol model
Fire–precipitation interactions amplify the quasi-biennial variability in fires over southern Mexico and Central America
Jingmin Li, Mattia Righi, Johannes Hendricks, Christof G. Beer, Ulrike Burkhardt, and Anja Schmidt
Atmos. Chem. Phys., 24, 12727–12747, https://doi.org/10.5194/acp-24-12727-2024, https://doi.org/10.5194/acp-24-12727-2024, 2024
Short summary
Short summary
Aiming to understand underlying patterns and trends in aerosols, we characterize the spatial patterns and long-term evolution of lower tropospheric aerosols by clustering multiple aerosol properties from preindustrial times to the year 2050 under three Shared
Socioeconomic Pathway scenarios. The results provide a clear and condensed picture of the spatial extent and distribution of aerosols for different time periods and emission scenarios.
Socioeconomic Pathway scenarios. The results provide a clear and condensed picture of the spatial extent and distribution of aerosols for different time periods and emission scenarios.
Yueming Cheng, Tie Dai, Junji Cao, Daisuke Goto, Jianbing Jin, Teruyuki Nakajima, and Guangyu Shi
Atmos. Chem. Phys., 24, 12643–12659, https://doi.org/10.5194/acp-24-12643-2024, https://doi.org/10.5194/acp-24-12643-2024, 2024
Short summary
Short summary
In March 2021, east Asia experienced an outbreak of severe dust storms after an absence of 1.5 decades. Here, we innovatively used the time-lagged ground-based aerosol size information with the fixed-lag ensemble Kalman smoother to optimize dust emission and reproduce the dust storm. This work is valuable for not only the quantification of health damage, aviation risks, and profound impacts on the Earth's system but also revealing the climatic driving force and the process of desertification.
Marc Mallet, Aurore Voldoire, Fabien Solmon, Pierre Nabat, Thomas Drugé, and Romain Roehrig
Atmos. Chem. Phys., 24, 12509–12535, https://doi.org/10.5194/acp-24-12509-2024, https://doi.org/10.5194/acp-24-12509-2024, 2024
Short summary
Short summary
This study investigates the interactions between smoke aerosols and climate in tropical Africa using a coupled ocean–atmosphere–aerosol climate model. The work shows that smoke plumes have a significant impact by increasing the low-cloud fraction, decreasing the ocean and continental surface temperature and reducing the precipitation of coastal western Africa. It also highlights the role of the ocean temperature response and its feedbacks for the September–November season.
Jia Liu, Cancan Zhu, Donghui Zhou, and Jinbao Han
Atmos. Chem. Phys., 24, 12341–12354, https://doi.org/10.5194/acp-24-12341-2024, https://doi.org/10.5194/acp-24-12341-2024, 2024
Short summary
Short summary
The hydrophilic coatings of aged black carbon (BC) particles absorb moisture during the hygroscopic growth process, but it is difficult to characterize how much water is absorbed under different relative humidities (RHs). In this study, we propose a method to obtain the water content in the coatings based on the equivalent complex refractive index retrieved from optical properties. This method is verified from a theoretical perspective, and it performs well for thickly coated BC at high RHs.
Zijun Li, Angela Buchholz, and Noora Hyttinen
Atmos. Chem. Phys., 24, 11717–11725, https://doi.org/10.5194/acp-24-11717-2024, https://doi.org/10.5194/acp-24-11717-2024, 2024
Short summary
Short summary
Evaluating organosulfur (OS) hygroscopicity is important for assessing aerosol–cloud climate interactions in the post-fossil-fuel future, when SO2 emissions decrease and OS compounds become increasingly important. Here a state-of-the-art quantum-chemistry-based method was used to predict the hygroscopic growth factors (HGFs) of a group of atmospherically relevant OS compounds and their mixtures with (NH4)2SO4. A good agreement was observed between their model-estimated and experimental HGFs.
Jamie R. Banks, Bernd Heinold, and Kerstin Schepanski
Atmos. Chem. Phys., 24, 11451–11475, https://doi.org/10.5194/acp-24-11451-2024, https://doi.org/10.5194/acp-24-11451-2024, 2024
Short summary
Short summary
The Aralkum is a new desert in Central Asia formed by the desiccation of the Aral Sea. This has created a source of atmospheric dust, with implications for the balance of solar and thermal radiation. Simulating these effects using a dust transport model, we find that Aralkum dust adds radiative cooling effects to the surface and atmosphere on average but also adds heating events. Increases in surface pressure due to Aralkum dust strengthen the Siberian High and weaken the summer Asian heat low.
Xinyue Shao, Minghuai Wang, Xinyi Dong, Yaman Liu, Wenxiang Shen, Stephen R. Arnold, Leighton A. Regayre, Meinrat O. Andreae, Mira L. Pöhlker, Duseong S. Jo, Man Yue, and Ken S. Carslaw
Atmos. Chem. Phys., 24, 11365–11389, https://doi.org/10.5194/acp-24-11365-2024, https://doi.org/10.5194/acp-24-11365-2024, 2024
Short summary
Short summary
Highly oxygenated organic molecules (HOMs) play an important role in atmospheric new particle formation (NPF). By semi-explicitly coupling the chemical mechanism of HOMs and a comprehensive nucleation scheme in a global climate model, the updated model shows better agreement with measurements of nucleation rate, growth rate, and NPF event frequency. Our results reveal that HOM-driven NPF leads to a considerable increase in particle and cloud condensation nuclei burden globally.
Falei Xu, Shuang Wang, Yan Li, and Juan Feng
Atmos. Chem. Phys., 24, 10689–10705, https://doi.org/10.5194/acp-24-10689-2024, https://doi.org/10.5194/acp-24-10689-2024, 2024
Short summary
Short summary
This study examines how the winter North Atlantic Oscillation (NAO) and El Niño–Southern Oscillation (ENSO) affect dust activities in North China during the following spring. The results show that the NAO and ENSO, particularly in their negative phases, greatly influence dust activities. When both are negative, their combined effect on dust activities is even greater. This research highlights the importance of these climate patterns in predicting spring dust activities in North China.
Hengheng Zhang, Wei Huang, Xiaoli Shen, Ramakrishna Ramisetty, Junwei Song, Olga Kiseleva, Christopher Claus Holst, Basit Khan, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 24, 10617–10637, https://doi.org/10.5194/acp-24-10617-2024, https://doi.org/10.5194/acp-24-10617-2024, 2024
Short summary
Short summary
Our study unravels how stagnant winter conditions elevate aerosol levels in Stuttgart. Cloud cover at night plays a pivotal role, impacting morning air quality. Validating a key model, our findings aid accurate air quality predictions, crucial for effective pollution mitigation in urban areas.
Giorgio Veratti, Alessandro Bigi, Michele Stortini, Sergio Teggi, and Grazia Ghermandi
Atmos. Chem. Phys., 24, 10475–10512, https://doi.org/10.5194/acp-24-10475-2024, https://doi.org/10.5194/acp-24-10475-2024, 2024
Short summary
Short summary
In a study of two consecutive winter seasons, we used measurements and modelling tools to identify the levels and sources of black carbon pollution in a medium-sized urban area of the Po Valley, Italy. Our findings show that biomass burning and traffic-related emissions (especially from Euro 4 diesel cars) significantly contribute to BC concentrations. This research offers crucial insights for policymakers and urban planners aiming to improve air quality in cities.
Pascal Lemaitre, Arnaud Quérel, Alexis Dépée, Alice Guerra Devigne, Marie Monier, Thibault Hiron, Chloé Soto Minguez, Daniel Hardy, and Andrea Flossmann
Atmos. Chem. Phys., 24, 9713–9732, https://doi.org/10.5194/acp-24-9713-2024, https://doi.org/10.5194/acp-24-9713-2024, 2024
Short summary
Short summary
A new in-cloud scavenging scheme is proposed. It is based on a microphysical model of cloud formation and may be applied to long-distance atmospheric transport models (> 100 km) and climatic models. This model is applied to the two most extreme precipitating cloud types in terms of both relative humidity and vertical extension: cumulonimbus and stratus.
Alex Rowell, James Brean, David C. S. Beddows, Tuukka Petäjä, Máté Vörösmarty, Imre Salma, Jarkko V. Niemi, Hanna E. Manninen, Dominik van Pinxteren, Thomas Tuch, Kay Weinhold, Zongbo Shi, and Roy M. Harrison
Atmos. Chem. Phys., 24, 9515–9531, https://doi.org/10.5194/acp-24-9515-2024, https://doi.org/10.5194/acp-24-9515-2024, 2024
Short summary
Short summary
Different sources of airborne particles in the atmospheres of four European cities were distinguished by recognising their particle size distributions using a statistical procedure, positive matrix factorisation. The various sources responded differently to the changes in emissions associated with COVID-19 lockdowns, and the reasons are investigated. While traffic emissions generally decreased, particles formed from reactions of atmospheric gases decreased in some cities but increased in others.
Amy H. Peace, Ying Chen, George Jordan, Daniel G. Partridge, Florent Malavelle, Eliza Duncan, and Jim M. Haywood
Atmos. Chem. Phys., 24, 9533–9553, https://doi.org/10.5194/acp-24-9533-2024, https://doi.org/10.5194/acp-24-9533-2024, 2024
Short summary
Short summary
Natural aerosols from volcanic eruptions can help us understand how anthropogenic aerosols modify climate. We use observations and model simulations of the 2014–2015 Holuhraun eruption plume to examine aerosol–cloud interactions in September 2014. We find a shift to clouds with smaller, more numerous cloud droplets in the first 2 weeks of the eruption. In the third week, the background meteorology and previous conditions experienced by air masses modulate the aerosol perturbation to clouds.
Hua Lu, Min Xie, Bingliang Zhuang, Danyang Ma, Bojun Liu, Yangzhihao Zhan, Tijian Wang, Shu Li, Mengmeng Li, and Kuanguang Zhu
Atmos. Chem. Phys., 24, 8963–8982, https://doi.org/10.5194/acp-24-8963-2024, https://doi.org/10.5194/acp-24-8963-2024, 2024
Short summary
Short summary
To identify cloud, aerosol, and planetary boundary layer (PBL) interactions from an air quality perspective, we summarized two pollution patterns characterized by denser liquid cloud and by obvious cloud radiation interaction (CRI). Numerical simulation experiments showed CRI could cause a 50 % reduction in aerosol radiation interaction (ARI) under a low-trough system. The results emphasized the nonnegligible role of CRI and its inhibition of ARI under wet and cloudy pollution synoptic patterns.
Emilie Fons, Ann Kristin Naumann, David Neubauer, Theresa Lang, and Ulrike Lohmann
Atmos. Chem. Phys., 24, 8653–8675, https://doi.org/10.5194/acp-24-8653-2024, https://doi.org/10.5194/acp-24-8653-2024, 2024
Short summary
Short summary
Aerosols can modify the liquid water path (LWP) of stratocumulus and, thus, their radiative effect. We compare storm-resolving model and satellite data that disagree on the sign of LWP adjustments and diagnose this discrepancy with causal inference. We find that strong precipitation, the absence of wet scavenging, and cloud deepening under a weak inversion contribute to positive LWP adjustments to aerosols in the model, despite weak negative effects from cloud-top entrainment enhancement.
Muhammed Irfan, Thomas Kühn, Taina Yli-Juuti, Anton Laakso, Eemeli Holopainen, Douglas R. Worsnop, Annele Virtanen, and Harri Kokkola
Atmos. Chem. Phys., 24, 8489–8506, https://doi.org/10.5194/acp-24-8489-2024, https://doi.org/10.5194/acp-24-8489-2024, 2024
Short summary
Short summary
The study examines how the volatility of semi-volatile organic compounds affects secondary organic aerosol (SOA) formation and climate. Our simulations show that uncertainties in these volatilities influence aerosol mass and climate impacts. Accurate representation of these compounds in climate models is crucial for predicting global climate patterns.
Alkiviadis Kalisoras, Aristeidis K. Georgoulias, Dimitris Akritidis, Robert J. Allen, Vaishali Naik, Chaincy Kuo, Sophie Szopa, Pierre Nabat, Dirk Olivié, Twan van Noije, Philippe Le Sager, David Neubauer, Naga Oshima, Jane Mulcahy, Larry W. Horowitz, and Prodromos Zanis
Atmos. Chem. Phys., 24, 7837–7872, https://doi.org/10.5194/acp-24-7837-2024, https://doi.org/10.5194/acp-24-7837-2024, 2024
Short summary
Short summary
Effective radiative forcing (ERF) is a metric for estimating how human activities and natural agents change the energy flow into and out of the Earth’s climate system. We investigate the anthropogenic aerosol ERF, and we estimate the contribution of individual processes to the total ERF using simulations from Earth system models within the Coupled Model Intercomparison Project Phase 6 (CMIP6). Our findings highlight that aerosol–cloud interactions drive ERF variability during the last 150 years.
Ryan Schmedding and Andreas Zuend
EGUsphere, https://doi.org/10.5194/egusphere-2024-1690, https://doi.org/10.5194/egusphere-2024-1690, 2024
Short summary
Short summary
Four different approaches for computing the interfacial tension between liquid phases in aerosol particles were tested for particles with diameters from 10 nm to more than 5 μm. Antonov's rule led to the strongest reductions in the onset relative humidity of liquid–liquid phase separation and reproduced measured interfacial tensions for highly immiscible systems. A modified form of the Butler equation was able to best reproduce measured interfacial tensions in more miscible systems.
Qianqian Song, Paul Ginoux, María Gonçalves Ageitos, Ron L. Miller, Vincenzo Obiso, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 24, 7421–7446, https://doi.org/10.5194/acp-24-7421-2024, https://doi.org/10.5194/acp-24-7421-2024, 2024
Short summary
Short summary
We implement and simulate the distribution of eight dust minerals in the GFDL AM4.0 model. We found that resolving the eight minerals reduces dust absorption compared to the homogeneous dust used in the standard GFDL AM4.0 model that assumes a globally uniform hematite content of 2.7 % by volume. Resolving dust mineralogy results in significant impacts on radiation, land surface temperature, surface winds, and precipitation over North Africa in summer.
Mingxu Liu, Hitoshi Matsui, Douglas Hamilton, Sagar Rathod, Kara Lamb, and Natalie Mahowald
EGUsphere, https://doi.org/10.5194/egusphere-2024-1454, https://doi.org/10.5194/egusphere-2024-1454, 2024
Short summary
Short summary
Atmospheric aerosol deposition provides iron to promote marine primary production, yet its amount remains highly uncertain. This study demonstrates that iron-containing particle size at emission is a critical factor in regulating their input to open oceans by performing global aerosol simulations. Further observational constraints on this are needed to reduce modelling uncertainties.
Ross J. Herbert, Alberto Sanchez-Marroquin, Daniel P. Grosvenor, Kirsty J. Pringle, Stephen R. Arnold, Benjamin J. Murray, and Kenneth S. Carslaw
EGUsphere, https://doi.org/10.5194/egusphere-2024-1538, https://doi.org/10.5194/egusphere-2024-1538, 2024
Short summary
Short summary
Aerosol particles that help form ice in clouds vary in number and type around the world and with time. However, in many weather and climate models cloud ice is not linked to aerosol that are known to nucleate ice. Here we report the first steps towards representing ice-nucleating particles within the UK's Earth System Model. We conclude that in addition to ice nucleation by sea spray and mineral components of soil dust we also need to represent ice nucleation by the organic components of soils.
Senyi Kong, Zheng Wang, and Lei Bi
Atmos. Chem. Phys., 24, 6911–6935, https://doi.org/10.5194/acp-24-6911-2024, https://doi.org/10.5194/acp-24-6911-2024, 2024
Short summary
Short summary
The retrieval of refractive indices of dust aerosols from laboratory optical measurements is commonly done assuming spherical particles. This paper aims to investigate the uncertainties in the shortwave refractive indices and corresponding optical properties by considering non-spherical and inhomogeneous models for dust samples. The study emphasizes the significance of using non-spherical models for simulating dust aerosols.
Wenxuan Hua, Sijia Lou, Xin Huang, Lian Xue, Ke Ding, Zilin Wang, and Aijun Ding
Atmos. Chem. Phys., 24, 6787–6807, https://doi.org/10.5194/acp-24-6787-2024, https://doi.org/10.5194/acp-24-6787-2024, 2024
Short summary
Short summary
In this study, we diagnose uncertainties in carbon monoxide and organic carbon emissions from four inventories for seven major wildfire-prone regions. Uncertainties in vegetation classification methods, fire detection products, and cloud obscuration effects lead to bias in these biomass burning (BB) emission inventories. By comparing simulations with measurements, we provide certain inventory recommendations. Our study has implications for reducing uncertainties in emissions in further studies.
Léo Clauzel, Sandrine Anquetin, Christophe Lavaysse, Gilles Bergametti, Christel Bouet, Guillaume Siour, Rémy Lapere, Béatrice Marticorena, and Jennie Thomas
EGUsphere, https://doi.org/10.5194/egusphere-2024-1604, https://doi.org/10.5194/egusphere-2024-1604, 2024
Short summary
Short summary
Solar energy production in West Africa is set to rise, needing accurate solar radiation estimates, which is affected by desert dust. This work analyses a March 2021 dust event using a modelling strategy incorporating desert dust. Results show that considering desert dust cut errors in solar radiation estimates by 75 % and reduces surface solar radiation by 18 %. This highlights the importance of incorporating dust aerosols into solar forecasting for better accuracy.
Chandrakala Bharali, Mary Barth, Rajesh Kumar, Sachin D. Ghude, Vinayak Sinha, and Baerbel Sinha
Atmos. Chem. Phys., 24, 6635–6662, https://doi.org/10.5194/acp-24-6635-2024, https://doi.org/10.5194/acp-24-6635-2024, 2024
Short summary
Short summary
This study examines the role of atmospheric aerosols in winter fog over the Indo-Gangetic Plains of India using WRF-Chem. The increase in RH with aerosol–radiation feedback (ARF) is found to be important for fog formation as it promotes the growth of aerosols in the polluted environment. Aqueous-phase chemistry in the fog increases PM2.5 concentration, further affecting ARF. ARF and aqueous-phase chemistry affect the fog intensity and the timing of fog formation by ~1–2 h.
Wenxin Zhao, Yu Zhao, Yu Zheng, Dong Chen, Jinyuan Xin, Kaitao Li, Huizheng Che, Zhengqiang Li, Mingrui Ma, and Yun Hang
Atmos. Chem. Phys., 24, 6593–6612, https://doi.org/10.5194/acp-24-6593-2024, https://doi.org/10.5194/acp-24-6593-2024, 2024
Short summary
Short summary
We evaluate the long-term (2000–2020) variabilities of aerosol absorption optical depth, black carbon emissions, and associated health risks in China with an integrated framework that combines multiple observations and modeling techniques. We demonstrate the remarkable emission abatement resulting from the implementation of national pollution controls and show how human activities affected the emissions with a spatiotemporal heterogeneity, thus supporting differentiated policy-making by region.
Peng Xian, Jeffrey S. Reid, Melanie Ades, Angela Benedetti, Peter R. Colarco, Arlindo da Silva, Tom F. Eck, Johannes Flemming, Edward J. Hyer, Zak Kipling, Samuel Rémy, Tsuyoshi Thomas Sekiyama, Taichu Tanaka, Keiya Yumimoto, and Jianglong Zhang
Atmos. Chem. Phys., 24, 6385–6411, https://doi.org/10.5194/acp-24-6385-2024, https://doi.org/10.5194/acp-24-6385-2024, 2024
Short summary
Short summary
The study compares and evaluates monthly AOD of four reanalyses (RA) and their consensus (i.e., ensemble mean). The basic verification characteristics of these RA versus both AERONET and MODIS retrievals are presented. The study discusses the strength of each RA and identifies regions where divergence and challenges are prominent. The RA consensus usually performs very well on a global scale in terms of how well it matches the observational data, making it a good choice for various applications.
Mariya Petrenko, Ralph Kahn, Mian Chin, Susanne E. Bauer, Tommi Bergman, Huisheng Bian, Gabriele Curci, Ben Johnson, Johannes Kaiser, Zak Kipling, Harri Kokkola, Xiaohong Liu, Keren Mezuman, Tero Mielonen, Gunnar Myhre, Xiaohua Pan, Anna Protonotariou, Samuel Remy, Ragnhild Bieltvedt Skeie, Philip Stier, Toshihiko Takemura, Kostas Tsigaridis, Hailong Wang, Duncan Watson-Parris, and Kai Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1487, https://doi.org/10.5194/egusphere-2024-1487, 2024
Short summary
Short summary
We compared smoke plume simulations from 11 global models to each other and to satellite smoke-amount observations, aimed at constraining smoke source strength. In regions where plumes are thick and background aerosol is low, models and satellites compare well. However, the input emission inventory tends to underestimate in many places, and particle property and loss-rate assumptions vary enormously among models, causing uncertainties that require systematic in-situ measurements to resolve.
Roger Teoh, Zebediah Engberg, Ulrich Schumann, Christiane Voigt, Marc Shapiro, Susanne Rohs, and Marc E. J. Stettler
Atmos. Chem. Phys., 24, 6071–6093, https://doi.org/10.5194/acp-24-6071-2024, https://doi.org/10.5194/acp-24-6071-2024, 2024
Short summary
Short summary
The radiative forcing (RF) due to aviation contrails is comparable to that caused by CO2. We estimate that global contrail net RF in 2019 was 62.1 mW m−2. This is ~1/2 the previous best estimate for 2018. Contrail RF varies regionally due to differences in conditions required for persistent contrails. COVID-19 reduced contrail RF by 54% in 2020 relative to 2019. Globally, 2 % of all flights account for 80 % of the annual contrail energy forcing, suggesting a opportunity to mitigate contrail RF.
Ragnhild Bieltvedt Skeie, Rachael Byrom, Øivind Hodnebrog, Caroline Jouan, and Gunnar Myhre
EGUsphere, https://doi.org/10.5194/egusphere-2024-1394, https://doi.org/10.5194/egusphere-2024-1394, 2024
Short summary
Short summary
In 2020 new regulations by the International Maritime Organization of sulphur emissions came into force that reduced emissions of SO2 from the shipping sector by approximately 80 %. In this study, we use multiple models to calculate by how much the Earth energy balance changed due to the emission reduction, the so called effective radiative forcing. The calculated effective radiative forcing is weak, comparable to the effect of the increase in CO2 over the last two to three years.
Haotian Zu, Biwu Chu, Yiqun Lu, Ling Liu, and Xiuhui Zhang
Atmos. Chem. Phys., 24, 5823–5835, https://doi.org/10.5194/acp-24-5823-2024, https://doi.org/10.5194/acp-24-5823-2024, 2024
Short summary
Short summary
The nucleation of iodic acid (HIO3) and iodous acid (HIO2) was proven to be critical in marine areas. However, HIO3–HIO2 nucleation cannot effectively derive the rapid nucleation in some polluted coasts. We find a significant enhancement of dimethylamine (DMA) on the HIO3–HIO2 nucleation in marine and polar regions with abundant DMA sources, which may establish reasonable connections between the HIO3–HIO2 nucleation and the rapid formation of new particles in polluted marine and polar regions.
Junghwa Lee, Patric Seifert, Tempei Hashino, Maximilian Maahn, Fabian Senf, and Oswald Knoth
Atmos. Chem. Phys., 24, 5737–5756, https://doi.org/10.5194/acp-24-5737-2024, https://doi.org/10.5194/acp-24-5737-2024, 2024
Short summary
Short summary
Spectral bin model simulations of an idealized supercooled stratiform cloud were performed with the AMPS model for variable CCN and INP concentrations. We performed radar forward simulations with PAMTRA to transfer the simulations into radar observational space. The derived radar reflectivity factors were compared to observational studies of stratiform mixed-phase clouds. These studies report a similar response of the radar reflectivity factor to aerosol perturbations as we found in our study.
Masaru Yoshioka, Daniel P. Grosvenor, Ben B. B. Booth, Colin P. Morice, and Kenneth S. Carslaw
EGUsphere, https://doi.org/10.5194/egusphere-2024-1428, https://doi.org/10.5194/egusphere-2024-1428, 2024
Short summary
Short summary
Sulfur emissions from shipping has been reduced by about 80 % as a result of the new regulation introduced in 2020. This has reduced aerosol in the atmosphere and its cooling effect through interactions with clouds. As a result, our coupled climate model simulations predict a global warming of 0.04 K averaged over three decades, potentially surpassing the Paris target of 1.5 K or contributing to recent temperature spikes, particularly notable in the Arctic with a mean warming of 0.15 K.
Basudev Swain, Marco Vountas, Aishwarya Singh, Nidhi L. Anchan, Adrien Deroubaix, Luca Lelli, Yanick Ziegler, Sachin S. Gunthe, Hartmut Bösch, and John P. Burrows
Atmos. Chem. Phys., 24, 5671–5693, https://doi.org/10.5194/acp-24-5671-2024, https://doi.org/10.5194/acp-24-5671-2024, 2024
Short summary
Short summary
Arctic amplification (AA) accelerates the warming of the central Arctic cryosphere and affects aerosol dynamics. Limited observations hinder a comprehensive analysis. This study uses AEROSNOW aerosol optical density (AOD) data and GEOS-Chem simulations to assess AOD variability. Discrepancies highlight the need for improved observational integration into models to refine our understanding of aerosol effects on cloud microphysics, ice nucleation, and radiative forcing under evolving AA.
Vincenzo Obiso, María Gonçalves Ageitos, Carlos Pérez García-Pando, Jan P. Perlwitz, Gregory L. Schuster, Susanne E. Bauer, Claudia Di Biagio, Paola Formenti, Kostas Tsigaridis, and Ron L. Miller
Atmos. Chem. Phys., 24, 5337–5367, https://doi.org/10.5194/acp-24-5337-2024, https://doi.org/10.5194/acp-24-5337-2024, 2024
Short summary
Short summary
We calculate the dust direct radiative effect (DRE) in an Earth system model accounting for regionally varying soil mineralogy through a new observationally constrained method. Linking dust absorption at solar wavelengths to the varying amount of specific minerals (i.e., iron oxides) improves the modeled range of dust single scattering albedo compared to observations and increases the global cooling by dust. Our results may contribute to improved estimates of the dust DRE and its climate impact.
Charlotte M. Beall, Po-Lun Ma, Matthew W. Christensen, Johannes Mülmenstädt, Adam Varble, Kentaroh Suzuki, and Takuro Michibata
Atmos. Chem. Phys., 24, 5287–5302, https://doi.org/10.5194/acp-24-5287-2024, https://doi.org/10.5194/acp-24-5287-2024, 2024
Short summary
Short summary
Single-layer warm liquid clouds cover nearly one-third of the Earth's surface, and uncertainties regarding the impact of aerosols on their radiative properties pose a significant challenge to climate prediction. Here, we demonstrate how satellite observations can be used to constrain Earth system model estimates of the radiative forcing from the interactions of aerosols with clouds due to warm rain processes.
Xiaoli Wei, Qian Cui, Leiming Ma, Feng Zhang, Wenwen Li, and Peng Liu
Atmos. Chem. Phys., 24, 5025–5045, https://doi.org/10.5194/acp-24-5025-2024, https://doi.org/10.5194/acp-24-5025-2024, 2024
Short summary
Short summary
A new aerosol-type classification algorithm has been proposed. It includes an optical database built by Mie scattering and a complex refractive index working as a baseline to identify different aerosol types. The new algorithm shows high accuracy and efficiency. Hence, a global map of aerosol types was generated to characterize aerosol types across the five continents. It will help improve the accuracy of aerosol inversion and determine the sources of aerosol pollution.
Hongyu Liu, Bo Zhang, Richard H. Moore, Luke D. Ziemba, Richard A. Ferrare, Hyundeok Choi, Armin Sorooshian, David Painemal, Hailong Wang, Michael A. Shook, Amy Jo Scarino, Johnathan W. Hair, Ewan C. Crosbie, Marta A. Fenn, Taylor J. Shingler, Chris A. Hostetler, Gao Chen, Mary M. Kleb, Gan Luo, Fangqun Yu, Jason L. Tackett, Mark A. Vaughan, Yongxiang Hu, Glenn S. Diskin, John B. Nowak, Joshua P. DiGangi, Yonghoon Choi, Christoph A. Keller, and Matthew S. Johnson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1127, https://doi.org/10.5194/egusphere-2024-1127, 2024
Short summary
Short summary
We use the GEOS-Chem model to simulate aerosols over the western North Atlantic Ocean (WNAO) during the winter and summer campaigns of ACTIVATE 2020. Model results are evaluated against in situ and remote sensing measurements from two aircraft as well as ground-based and satellite observations. The improved understanding of the aerosol life cycle, composition, transport pathways, and distribution has important implications for characterizing aerosol-cloud-meteorology interactions over the WNAO.
Zhiqiang Zhang, Ying Li, Haiyan Ran, Junling An, Yu Qu, Wei Zhou, Weiqi Xu, Weiwei Hu, Hongbin Xie, Zifa Wang, Yele Sun, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 4809–4826, https://doi.org/10.5194/acp-24-4809-2024, https://doi.org/10.5194/acp-24-4809-2024, 2024
Short summary
Short summary
Secondary organic aerosols (SOAs) can exist in liquid, semi-solid, or amorphous solid states, which are rarely accounted for in current chemical transport models. We predict the phase state of SOA particles over China and find that in northwestern China SOA particles are mostly highly viscous or glassy solid. Our results indicate that the particle phase state should be considered in SOA formation in chemical transport models for more accurate prediction of SOA mass concentrations.
Alejandro Baró Pérez, Michael S. Diamond, Frida A.-M. Bender, Abhay Devasthale, Matthias Schwarz, Julien Savre, Juha Tonttila, Harri Kokkola, Hyunho Lee, David Painemal, and Annica M. L. Ekman
Atmos. Chem. Phys., 24, 4591–4610, https://doi.org/10.5194/acp-24-4591-2024, https://doi.org/10.5194/acp-24-4591-2024, 2024
Short summary
Short summary
We use a numerical model to study interactions between humid light-absorbing aerosol plumes, clouds, and radiation over the southeast Atlantic. We find that the warming produced by the aerosols reduces cloud cover, especially in highly polluted situations. Aerosol impacts on drizzle play a minor role. However, aerosol effects on cloud reflectivity and moisture-induced changes in cloud cover dominate the climatic response and lead to an overall cooling by the biomass burning plumes.
Danny M. Leung, Jasper F. Kok, Longlei Li, David M. Lawrence, Natalie M. Mahowald, Simone Tilmes, and Erik Kluzek
EGUsphere, https://doi.org/10.5194/egusphere-2024-1124, https://doi.org/10.5194/egusphere-2024-1124, 2024
Short summary
Short summary
This study derives a desert dust emission dataset for 1841–2000, by employing a combination of observed dust records from sedimentary cores as well as reanalyzed global dust cycle constraints. We evaluate the ability of global models to replicate the observed historical dust variability by using the emission dataset to force a historical simulation in an Earth system model. We show that prescribing our emissions forces the model to match better against observations than other mechanistic models.
Sampa Das, Peter R. Colarco, Huisheng Bian, and Santiago Gassó
Atmos. Chem. Phys., 24, 4421–4449, https://doi.org/10.5194/acp-24-4421-2024, https://doi.org/10.5194/acp-24-4421-2024, 2024
Short summary
Short summary
The smoke aerosols emitted from vegetation burning can alter the regional energy budget via multiple pathways. We utilized detailed observations from the NASA ORACLES airborne campaign based in Namibia during September 2016 to improve the representation of smoke aerosol properties and lifetimes in our GEOS Earth system model. The improved model simulations are for the first time able to capture the observed changes in the smoke absorption during long-range plume transport.
Emilio Cuevas-Agulló, David Barriopedro, Rosa Delia García, Silvia Alonso-Pérez, Juan Jesús González-Alemán, Ernest Werner, David Suárez, Juan José Bustos, Gerardo García-Castrillo, Omaira García, África Barreto, and Sara Basart
Atmos. Chem. Phys., 24, 4083–4104, https://doi.org/10.5194/acp-24-4083-2024, https://doi.org/10.5194/acp-24-4083-2024, 2024
Short summary
Short summary
During February–March (FM) 2020–2022, unusually intense dust storms from northern Africa hit the western Euro-Mediterranean (WEM). Using dust products from satellites and atmospheric reanalysis for 2003–2022, results show that cut-off lows and European blocking are key drivers of FM dust intrusions over the WEM. A higher frequency of cut-off lows associated with subtropical ridges is observed in the late 2020–2022 period.
Yahui Che, Bofu Yu, and Katherine Bracco
Atmos. Chem. Phys., 24, 4105–4128, https://doi.org/10.5194/acp-24-4105-2024, https://doi.org/10.5194/acp-24-4105-2024, 2024
Short summary
Short summary
Dust events occur more frequently during the Austral spring and summer in dust regions, including central Australia, the southwest of Western Australia, and the northern and southern regions of eastern Australia using remote sensing and reanalysis datasets. High-concentration dust is distributed around central Australia and in the downwind northern and southern Australia. Typically, around 50 % of the dust lifted settles on Australian land, with the remaining half being deposited in the ocean.
Jonathan Elsey, Nicolas Bellouin, and Claire Ryder
Atmos. Chem. Phys., 24, 4065–4081, https://doi.org/10.5194/acp-24-4065-2024, https://doi.org/10.5194/acp-24-4065-2024, 2024
Short summary
Short summary
Aerosols influence the Earth's energy balance. The uncertainty in this radiative forcing is large depending partly on uncertainty in measurements of aerosol optical properties. We have developed a freely available new framework of millions of radiative transfer simulations spanning aerosol uncertainty and assess the impact on radiative forcing uncertainty. We find that reducing these uncertainties would reduce radiative forcing uncertainty, but non-aerosol uncertainties must also be considered.
Jing Li, Nan Wu, Biwu Chu, An Ning, and Xiuhui Zhang
Atmos. Chem. Phys., 24, 3989–4000, https://doi.org/10.5194/acp-24-3989-2024, https://doi.org/10.5194/acp-24-3989-2024, 2024
Short summary
Short summary
Iodic acid (HIO3) nucleates with iodous acid (HIO2) efficiently in marine areas; however, whether methanesulfonic acid (MSA) can synergistically participate in the HIO3–HIO2-based nucleation is unclear. We provide molecular-level evidence that MSA can efficiently promote the formation of HIO3–HIO2-based clusters using a theoretical approach. The proposed MSA-enhanced iodine nucleation mechanism may help us to deeply understand marine new particle formation events with bursts of iodine particles.
Hao Wang, Xiaohong Liu, Chenglai Wu, and Guangxing Lin
Atmos. Chem. Phys., 24, 3309–3328, https://doi.org/10.5194/acp-24-3309-2024, https://doi.org/10.5194/acp-24-3309-2024, 2024
Short summary
Short summary
We quantified different global- and regional-scale drivers of biogenic volatile organic compound (BVOC) emission trends over the past 20 years. The results show that global greening trends significantly boost BVOC emissions and deforestation reduces BVOC emissions in South America and Southeast Asia. Elevated temperature in Europe and increased soil moisture in East and South Asia enhance BVOC emissions. The results deepen our understanding of long-term BVOC emission trends in hotspots.
Christof G. Beer, Johannes Hendricks, and Mattia Righi
Atmos. Chem. Phys., 24, 3217–3240, https://doi.org/10.5194/acp-24-3217-2024, https://doi.org/10.5194/acp-24-3217-2024, 2024
Short summary
Short summary
Ice-nucleating particles (INPs) have important influences on cirrus clouds and the climate system; however, the understanding of their global impacts is still uncertain. We perform numerical simulations with a global aerosol–climate model to analyse INP-induced cirrus changes and the resulting climate impacts. We evaluate various sources of uncertainties, e.g. the ice-nucleating ability of INPs and the role of model dynamics, and provide a new estimate for the global INP–cirrus effect.
Jiawei Li, Zhiwei Han, Pingqing Fu, Xiaohong Yao, and Mingjie Liang
Atmos. Chem. Phys., 24, 3129–3161, https://doi.org/10.5194/acp-24-3129-2024, https://doi.org/10.5194/acp-24-3129-2024, 2024
Short summary
Short summary
Organic aerosols of marine origin are important for aerosol climatic effects but are poorly understood. For the first time, an online coupled regional chemistry–climate model is applied to explore the characteristics of emission, distribution, and direct and indirect radiative effects of marine organic aerosols over the western Pacific, which reveals an important role of marine organic aerosols in perturbing cloud and radiation and promotes understanding of global aerosol climatic impact.
Yawen Liu, Yun Qian, Philip J. Rasch, Kai Zhang, Lai-yung Ruby Leung, Yuhang Wang, Minghuai Wang, Hailong Wang, Xin Huang, and Xiu-Qun Yang
Atmos. Chem. Phys., 24, 3115–3128, https://doi.org/10.5194/acp-24-3115-2024, https://doi.org/10.5194/acp-24-3115-2024, 2024
Short summary
Short summary
Fire management has long been a challenge. Here we report that spring-peak fire activity over southern Mexico and Central America (SMCA) has a distinct quasi-biennial signal by measuring multiple fire metrics. This signal is initially driven by quasi-biennial variability in precipitation and is further amplified by positive feedback of fire–precipitation interaction at short timescales. This work highlights the importance of fire–climate interactions in shaping fires on an interannual scale.
Cited articles
Charlson, R. J., Schwartz, S. E., Hales, J. M., Cess, R. D., Coakley Jr., J. A.,
Hansen, J. E., and Hofmann, D. J.: Climate forcing by anthropogenic aerosols,
Science, 255, 423–430, 1992.
Clough, S. A., Shephard, M. W., Mlawer, E. J., Delamere, J. S., Iacono, M. J.,
Cady-Pereira, K., Boukabara, S., and Brown, P. D.: Atmospheric radiative transfer
modeling: A summary of the AER codes, J. Quant. Spectrosc. Ra.,
91, 233–244, https://doi.org/10.1016/j.jqsrt.2004.05.058, 2005.
Erupe, M. E., Benson, D. R., Li, J., Young, L.-H., Verheggen, B., Al-Refai, M., Tahboub,
O., Cunningham, V., Frimpong, F., Viggiano, A. A., and Lee, S.-H.:
Correlation of aerosol nucleation rate with sulfuric acid and ammonia in
Kent Ohio: an atmospheric observation, J. Geophys. Res., 115, D23216,
https://doi.org/10.1029/2010JD013942, 2010.
Fountoukis, C. and Nenes, A.: ISORROPIA II: a computationally efficient
thermodynamic equilibrium model for
K+–Ca2+–Mg2+–
Gaudet, L. C., Sulia, K. J., Yu, F., and Luo, G.: Sensitivity of Lake-Effect
Cloud Microphysical Processes to Ice Crystal Habit and Nucleation during
OWLeS IOP4, J. Climate, 76, 3411–3434, https://doi.org/10.1175/JAS-D-19-0004.1, 2019.
Grell, G. A. and Freitas, S. R.: A scale and aerosol aware stochastic convective parameterization for weather and air quality modeling, Atmos. Chem. Phys., 14, 5233–5250, https://doi.org/10.5194/acp-14-5233-2014, 2014.
Grell, G. A., Peckham, S. E., McKeen, S., Schmitz, R., Frost, G., Skamarock,
W. C., and Eder, B.: Fully coupled “online” chem-istry within the WRF
model, Atmos. Environ., 39, 6957–6975, 2005.
Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P. I., and Geron, C.: Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmos. Chem. Phys., 6, 3181–3210, https://doi.org/10.5194/acp-6-3181-2006, 2006.
Han, Y., Zhu, T., Guan, T., Zhu, Y., Liu, J., Ji, Y., Gao, S., Wang, F., Lu, H., and
Huang, W.: Association between size-segregated particles in ambient air and
acute respiratory inflammation, Sci. Total Environ., 565,
412–419, 2016.
Hong, S.-Y., Noh, Y., and Dudhia, J.: A new vertical diffusion package with an
explicittreatment of entrainment processes, Mon. Weather Rev. 134,
2318–2341, 2006.
Kanawade, V. P., Benson, D. R., and Lee, S.-H.: Statistical analysis of 4-year
observations of aerosol sizes in a semi-rural continental environment,
Atmos. Environ., 59, 30–38, 2012.
Kirkby, J., Curtius, J., Almeida, J., Dunne, E., Duplissy, J., Ehrhart, S., Franchin, A., Gagné, S., Ickes, L., Kürten, A., Kupc, A., Metzger, A., Riccobono, F., Rondo, L., Schobesberger, S., Tsagkogeorgas, G., Wimmer, D., Amorim, A., Bianchi, F., Breitenlechner, M., David, A., Dommen, J., Downard, A., Ehn, M., Flagan, R.C., Haider, S., Hansel, A., Hauser, D., Jud, W., Junninen, H., Kreissl, F., Kvashin, A., Laaksonen, A., Lehtipalo, K., Lima, J., Lovejoy, E. R., Makhmutov, V., Mathot, S., Mikkilä, J., Minginette, P., Mogo, S., Nieminen, T., Onnela, A., Pereira, P., Petäjä, T., Schnitzhofer, R., Seinfeld, J. H., Sipilä, M., Stozhkov, Y., Stratmann, F., Tomé, A., Vanhanen, J., Viisanen, Y., Vrtala, A., Wagner, P. E., Walther, H., Weingartner, E., Wex, H., Winkler, P. M., Carslaw, K. S., Worsnop, D. R., Baltensperger, U., and Kulmala, M.: Role of sulphuric acid, ammonia and galactic
cosmic rays in atmospheric aerosol nucleation, Nature, 476, 429–433, 2011.
Knibbs, L. D., Cole-Hunter, T., and Morawska, L.: A review of commuter exposure
toultrafine particles and its health effects, Atmos. Environ., 45, 2611–2622,
https://doi.org/10.1016/j.atmosenv.2011.02.065, 2011.
Kürten, A., Bergen, A., Heinritzi, M., Leiminger, M., Lorenz, V., Piel, F., Simon, M., Sitals, R., Wagner, A. C., and Curtius, J.: Observation of new particle formation and measurement of sulfuric acid, ammonia, amines and highly oxidized organic molecules at a rural site in central Germany, Atmos. Chem. Phys., 16, 12793–12813, https://doi.org/10.5194/acp-16-12793-2016, 2016.
Lee, S.-H., Gordon, H., Yu, H., Lehtipalo, K., Haley, R., Li, Y., and Zhang,
R.: New particle formation in the atmosphere: From molecular clusters to
global climate, J. Geophys. Res., 124, 7098–7146, https://doi.org/10.1029/2018JD029356,
2019.
Luo, G. and Yu, F.: Simulation of particle formation and number concentration over the Eastern United States with the WRF-Chem + APM model, Atmos. Chem. Phys., 11, 11521–11533, https://doi.org/10.5194/acp-11-11521-2011, 2011.
Morrison, H., Thompson, G., and Tatarskii, V.: Impact of cloudmicrophysics on
the development of trailing stratiform precipitation in asimulated squall
line: Comparison of one- and two-moment schemes, Mon. Weather Rev., 137,
991–1007, https://doi.org/10.1175/2008MWR2556.1, 2009.
NADP: National Atmospheric Deposition Program 2017 Annual Summary, Wisconsin
State Laboratory of Hygiene, University of Wisconsin-Madison, WI, USA, available
at: http://nadp.slh.wisc.edu/lib/dataReports.aspx (last access: 29 February 2020), 2018.
National Atmospheric Deposition Program (NRSP3): Ammonia Monitoring Network (AMoN) data, NADP Program Office, Illinois State Water Survey, University of Illinois, Champaign, IL 61820, available at: http://nadp.slh.wisc.edu/data/AMoN/ (last access: 29 February 2020), 2017.
Neitola, K., Brus, D., Makkonen, U., Sipilä, M., Mauldin III, R. L., Sarnela, N., Jokinen, T., Lihavainen, H., and Kulmala, M.: Total sulfate vs. sulfuric acid monomer concenterations in nucleation studies, Atmos. Chem. Phys., 15, 3429–3443, https://doi.org/10.5194/acp-15-3429-2015, 2015.
Pierce, J. R. and Adams, P. J.: Uncertainty in global CCN concentrations from uncertain aerosol nucleation and primary emission rates, Atmos. Chem. Phys., 9, 1339–1356, https://doi.org/10.5194/acp-9-1339-2009, 2009.
Schell B., Ackermann, I. J., Hass, H., Binkowski, F. S., and Ebel, A.: Modeling
the formation of secondary organic aerosol within a comprehensive air
quality model system, J. Geophys. Res., 106, 28275–28293,
2001.
Schwab, J. J., Spicer, J. B., and Demerjian, K. L.: Ozone, Trace Gas, and
Particulate Matter Measurements at a Rural Site in Southwestern New York
State: 1995–2005, J. Air Waste Manage. Assoc., 59, 293–309, https://doi.org/10.3155/1047-3289.59.3.293, 2009.
Sherman, J. P., Sheridan, P. J., Ogren, J. A., Andrews, E., Hageman, D., Schmeisser, L., Jefferson, A., and Sharma, S.: A multi-year study of lower tropospheric aerosol variability and systematic relationships from four North American regions, Atmos. Chem. Phys., 15, 12487–12517, https://doi.org/10.5194/acp-15-12487-2015, 2015.
Spracklen, D., Carslaw, K., Kulmala, M., Kerminen, V.-M., Si-hto, S.-L.,
Riipinen, I., Merikanto, J., Mann, G., Chipperfield, M., Wiedensohler, A.,
Birmili, W., and Lihavainen, H.: Contribution of particle formation to global
cloud condensa-tion nuclei concentrations, Geophys. Res. Lett., 35,
L06808, https://doi.org/10.1029/2007GL033038, 2008.
Tiszenkel, L., Stangl, C., Krasnomowitz, J., Ouyang, Q., Yu, H., Apsokardu, M. J., Johnston, M. V., and Lee, S.-H.: Temperature effects on sulfuric acid aerosol nucleation and growth: initial results from the TANGENT study, Atmos. Chem. Phys., 19, 8915–8929, https://doi.org/10.5194/acp-19-8915-2019, 2019.
Twomey, S.: The Influence of Pollution on the Shortwave Albedo of
Clouds, J. Atmos. Sci., 34, 1149–1152, https://doi.org/10.1175/1520-0469(1977)034<1149:TIOPOT>2.0.CO;2,
1977.
UCAR/NCAR/CISL/TDD: NCAR Command Language (Version 6.6.2) [Software], Boulder, Colorado, https://doi.org/10.5065/D6WD3XH5, 2019.
Yarwood, G., Rao, S., Yocke, M., and Whitten, G. Z.: Updates to the Carbon Bond
Mechanism: CB05. US EPA Final Report, 161 pp., available at:
http://www.camx.com/publ/pdfs/CB05_Final_Report_120805.pdf (last access: 29 February 2020), 2005.
Yu, F.: A secondary organic aerosol formation model considering successive oxidation aging and kinetic condensation of organic compounds: global scale implications, Atmos. Chem. Phys., 11, 1083–1099, https://doi.org/10.5194/acp-11-1083-2011, 2011.
Yu, F. and Luo, G.: Simulation of particle size distribution with a global aerosol model: contribution of nucleation to aerosol and CCN number concentrations, Atmos. Chem. Phys., 9, 7691–7710, https://doi.org/10.5194/acp-9-7691-2009, 2009.
Yu, F., Luo, G., and Ma, X.: Regional and global modeling of aerosol optical properties with a size, composition, and mixing state resolved particle microphysics model, Atmos. Chem. Phys., 12, 5719–5736, https://doi.org/10.5194/acp-12-5719-2012, 2012.
Yu, F., Luo, G., Pryor, S. C., Pillai, P. R., Lee, S. H., Ortega, J., Schwab, J. J., Hallar, A. G., Leaitch, W. R., Aneja, V. P., Smith, J. N., Walker, J. T., Hogrefe, O., and Demerjian, K. L.: Spring and summer contrast in new particle formation over nine forest areas in North America, Atmos. Chem. Phys., 15, 13993–14003, https://doi.org/10.5194/acp-15-13993-2015, 2015.
Yu, F., Luo, G., Nadykto, A. B., and Herb, J.: Impact of temperature dependence on the possible contribution of organics to new particle formation in the atmosphere, Atmos. Chem. Phys., 17, 4997–5005, https://doi.org/10.5194/acp-17-4997-2017, 2017.
Yu, F., Nadykto, A. B., Herb, J., Luo, G., Nazarenko, K. M., and Uvarova, L. A.:
Yu, H., Haller, A. G., You, Y., Sedlacek, A., Springston, S., Kanawade, V. P., Lee,
Y.-N., Wang, J., Kuang, C., McGraw, R. L., McCubbin, I., Mikkala, J., and Lee,
S.-H.: Sub-3 nm particles observed at the coastal and continental sites
in the United States, J. Geophys. Res., 119, 860–879, https://doi.org/10.1002/2013JD020841, 2014.
Short summary
Particle number concentration (PNC) is a key parameter important for the health and climate impacts of atmospheric aerosols. We show that, even during wintertime, regional nucleation occurs and contributes significantly to number concentrations of ultrafine particles and cloud condensation nuclei. Due to low biogenic emissions, wintertime regional nucleation is solely controlled by inorganic species, and ternary ion-mediated nucleation is able to capture the observed variations in PNC.
Particle number concentration (PNC) is a key parameter important for the health and climate...
Altmetrics
Final-revised paper
Preprint