Articles | Volume 19, issue 13
https://doi.org/10.5194/acp-19-8817-2019
https://doi.org/10.5194/acp-19-8817-2019
Research article
 | 
11 Jul 2019
Research article |  | 11 Jul 2019

Measuring light absorption by freshly emitted organic aerosols: optical artifacts in traditional solvent-extraction-based methods

Nishit J. Shetty, Apoorva Pandey, Stephen Baker, Wei Min Hao, and Rajan K. Chakrabarty

Related authors

Correcting for filter-based aerosol light absorption biases at the Atmospheric Radiation Measurement program's Southern Great Plains site using photoacoustic measurements and machine learning
Joshin Kumar, Theo Paik, Nishit J. Shetty, Patrick Sheridan, Allison C. Aiken, Manvendra K. Dubey, and Rajan K. Chakrabarty
Atmos. Meas. Tech., 15, 4569–4583, https://doi.org/10.5194/amt-15-4569-2022,https://doi.org/10.5194/amt-15-4569-2022, 2022
Short summary
Diel cycle impacts on the chemical and light absorption properties of organic carbon aerosol from wildfires in the western United States
Benjamin Sumlin, Edward Fortner, Andrew Lambe, Nishit J. Shetty, Conner Daube, Pai Liu, Francesca Majluf, Scott Herndon, and Rajan K. Chakrabarty
Atmos. Chem. Phys., 21, 11843–11856, https://doi.org/10.5194/acp-21-11843-2021,https://doi.org/10.5194/acp-21-11843-2021, 2021
Short summary

Cited articles

Akagi, S., Yokelson, R. J., Wiedinmyer, C., Alvarado, M., Reid, J., Karl, T., Crounse, J., and Wennberg, P.: Emission factors for open and domestic biomass burning for use in atmospheric models, Atmos. Chem. Phys., 11, 4039–4072, https://doi.org/10.5194/acp-11-4039-2011, 2011. 
Alexander, D. T., Crozier, P. A., and Anderson, J. R.: Brown carbon spheres in East Asian outflow and their optical properties, Science, 321, 833–836, https://doi.org/10.1126/science.1155296, 2008. 
Andreae, M. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006. 
Arnott, W., Moosmüller, H., Sheridan, P., Ogren, J., Raspet, R., Slaton, W., Hand, J., Kreidenweis, S., and Collett Jr., J.: Photoacoustic and filter-based ambient aerosol light absorption measurements: Instrument comparisons and the role of relative humidity, J. Geophys. Res.-Atmos., 108, AAC15-1–AAC15-11, https://doi.org/10.1029/2002JD002165, 2003. 
Arnott, W. P., Hamasha, K., Moosmüller, H., Sheridan, P. J., and Ogren, J. A.: Towards aerosol light-absorption measurements with a 7-wavelength aethalometer: Evaluation with a photoacoustic instrument and 3-wavelength nephelometer, Aerosol Sci. Technol., 39, 17–29, https://doi.org/10.1080/027868290901972, 2005. 
Download
Short summary
We investigated biases in particle-phase absorption coefficients for organic aerosol from bulk-phase absorbance measurements of solvent extracts in the visible spectrum. These biases were systematically studied as a function of organic-to-total carbon mass ratios and aerosol single scattering albedo. A linear correlation between SSA and OC / TC ratios was observed. Differences in the absorption Ångström exponents from bulk- and particle-phase measurements were also investigated.
Share
Altmetrics
Final-revised paper
Preprint