Articles | Volume 16, issue 5
Atmos. Chem. Phys., 16, 3033–3040, 2016
Atmos. Chem. Phys., 16, 3033–3040, 2016
Research article
09 Mar 2016
Research article | 09 Mar 2016

Brown carbon aerosols from burning of boreal peatlands: microphysical properties, emission factors, and implications for direct radiative forcing

Rajan K. Chakrabarty1, Madhu Gyawali2, Reddy L. N. Yatavelli2,3, Apoorva Pandey1, Adam C. Watts2, Joseph Knue2, Lung-Wen A. Chen2,4, Robert R. Pattison5, Anna Tsibart6, Vera Samburova2, and Hans Moosmüller2 Rajan K. Chakrabarty et al.
  • 1Aerosol Impacts and Research (AIR) Laboratory, Department of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, St. Louis, MO 63130, USA
  • 2Desert Research Institute, Nevada System of Higher Education, Reno, NV 89512, USA
  • 3California Air Resources Board, El Monte, CA 91731, USA
  • 4Department of Environmental and Occupational Health, University of Nevada Las Vegas, Las Vegas, NV 89154, USA
  • 5United States Forest Service, Pacific Northwest Research Station, Anchorage, AK 99501, USA
  • 6Department of Landscape Geochemistry and Soil Geography, Moscow State University, Moscow, Russian Federation

Abstract. The surface air warming over the Arctic has been almost twice as much as the global average in recent decades. In this region, unprecedented amounts of smoldering peat fires have been identified as a major emission source of climate-warming agents. While much is known about greenhouse gas emissions from these fires, there is a knowledge gap on the nature of particulate emissions and their potential role in atmospheric warming. Here, we show that aerosols emitted from burning of Alaskan and Siberian peatlands are predominantly brown carbon (BrC) – a class of visible light-absorbing organic carbon (OC) – with a negligible amount of black carbon content. The mean fuel-based emission factors for OC aerosols ranged from 3.8 to 16.6 g kg−1. Their mass absorption efficiencies were in the range of 0.2–0.8 m2 g−1 at 405 nm (violet) and dropped sharply to 0.03–0.07 m2 g−1 at 532 nm (green), characterized by a mean Ångström exponent of  ≈  9. Electron microscopy images of the particles revealed their morphologies to be either single sphere or agglomerated “tar balls”. The shortwave top-of-atmosphere aerosol radiative forcing per unit optical depth under clear-sky conditions was estimated as a function of surface albedo. Only over bright surfaces with albedo greater than 0.6, such as snow cover and low-level clouds, the emitted aerosols could result in a net warming (positive forcing) of the atmosphere.

Short summary
Brown carbon aerosols dominate particulate emissions from the burning of Alaskan and Siberian peatlands. They physically occur as amorphous "tar balls" with negligible black carbon mixing. They absorb very strongly in the shorter visible wavelengths, characterized by a mean Ångström coefficient of ≈ 9. These aerosols could result in a net warming of the atmosphere, provided the albedo of the underlying surface is greater than 0.6.
Final-revised paper