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ACP | Articles | Volume 19, issue 12
Atmos. Chem. Phys., 19, 8175–8187, 2019
https://doi.org/10.5194/acp-19-8175-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 19, 8175–8187, 2019
https://doi.org/10.5194/acp-19-8175-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 24 Jun 2019

Research article | 24 Jun 2019

Influence of functional groups on toxicity of carbon nanomaterials

Yongchun Liu et al.

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Adachi, K., Chung, S. H., and Buseck, P. R.: Shapes of soot aerosol particles and implications for their effects on climate, J. Geophys. Res.-Atmos., 115, D15206, https://doi.org/10.1029/2009jd012868, 2010. 
Andreae, M. O. and Gelencser, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006. 
Antinolo, M., Willis, M. D., Zhou, S., and Abbatt, J. P. D.: Connecting the oxidation of soot to its redox cycling abilities, Nat. Commun., 6, 6812, https://doi.org/10.1038/ncomms7812, 2015. 
Apicella, B., Barbella, R., Ciajolo, A., and Tregrossi, A.: Comparative analysis of the structure of carbon materials relevant in combustion, Chemosphere, 51, 1063–1069, https://doi.org/10.1016/S0045-6535(02)00715-4, 2003. 
Balakrishna, S., Lomnicki, S., McAvey, K. M., Cole, R. B., Dellinger, B., and Cormier, S. A.: Environmentally persistent free radicals amplify ultrafine particle mediated cellular oxidative stress and cytotoxicity, Part. Fibre Toxicol., 6, 11, https://doi.org/10.1186/1743-8977-6-11, 2009. 
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During production and use of carbon nanomaterials, they are prone to enter the environment and ultimately the human body, and subsequently to pose a risk of adverse health effects. This work has for the first time found that epoxide is highly active to form ROS, possibly leading to a strong oxidation stress to humans, while carboxylation and hydroxylation have little influence on the oxidation potential. This suggests that more attention should be paid to epoxide-containing carbon nanomaterials.
During production and use of carbon nanomaterials, they are prone to enter the environment and...
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