Articles | Volume 15, issue 6
Atmos. Chem. Phys., 15, 2953–2968, 2015
https://doi.org/10.5194/acp-15-2953-2015
Atmos. Chem. Phys., 15, 2953–2968, 2015
https://doi.org/10.5194/acp-15-2953-2015
Research article
17 Mar 2015
Research article | 17 Mar 2015

Gaseous products and secondary organic aerosol formation during long term oxidation of isoprene and methacrolein

L. Brégonzio-Rozier et al.

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Cited articles

Aiken, A. C., DeCarlo, P. F., and Jimenez, J. L.: Elemental analysis of organic species with electron ionization high-resolution mass spectrometry, Anal. Chem., 79, 8350–8358, 2007.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006.
Bahreini, R., Keywood, M. D., Ng, N. L., Varutbangkul, V., Gao, S., Flagan, R. C., Seinfeld, J. H., Worsnop, D. R., and Jimenez, J. L.: Measurements of secondary organic aerosol from oxidation of cycloalkenes, terpenes, and m-xylene using an Aerodyne aerosol mass spectrometer, Environ. Sci. Technol., 39, 5674–5688, 2005.
Biesenthal, T. A., Wu, Q., Shepson, P. B., Wiebe, H. A., Anlauf, K. G., and Mackay, G. I.: A study of relationships between isoprene, its oxidation products, and ozone, in the Lower Fraser Valley, BC, Atmos. Environ., 31, 2049–2058, 1997.
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First- and higher order -generation products formed from the oxidation of isoprene and methacrolein with OH radicals in the presence of NOx have been studied in a simulation chamber. Differences in light source are proposed to partially explain the discrepancies observed between different studies in the literature for both isoprene- and methacrolein-SOA mass yields. According to our results, these SOA yields in the atmosphere could be lower than suggested by most of the current chamber studies.
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