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Volume 15, issue 10
Atmos. Chem. Phys., 15, 5683–5695, 2015
https://doi.org/10.5194/acp-15-5683-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 15, 5683–5695, 2015
https://doi.org/10.5194/acp-15-5683-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 26 May 2015

Research article | 26 May 2015

Molecular composition of fresh and aged secondary organic aerosol from a mixture of biogenic volatile compounds: a high-resolution mass spectrometry study

I. Kourtchev1, J.-F. Doussin2, C. Giorio1,3, B. Mahon1, E. M. Wilson4, N. Maurin2, E. Pangui2, D. S. Venables4, J. C. Wenger4, and M. Kalberer1 I. Kourtchev et al.
  • 1Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, United Kingdom
  • 2LISA, Universités Paris-Est-Créteil et Paris Diderot, CNRS UMR 7583, 61 Avenue du Général de Gaulle, 94010, Créteil, France
  • 3National Centre for Atmospheric Science, School of Geography, Earth and Environmental Sciences, Division of Environmental Health and Risk Management, University of Birmingham, Edgbaston, Birmingham B15 2TT, United Kingdom
  • 4Department of Chemistry and Environmental Research Institute, University College Cork, Cork, Ireland

Abstract. Field observations over the past decade indicate that a significant fraction of organic aerosol in remote areas may contain highly oxidized molecules. Aerosol processing or further oxidation (aging) of organic aerosol has been suggested to be responsible for their formation through heterogeneous reaction with oxidants and multigenerational oxidation of vapours by OH radicals. In this study we investigated the influence of several aging processes on the molecular composition of secondary organic aerosols (SOA) using direct infusion and liquid chromatography high-resolution mass spectrometry. SOA was formed in simulation chamber experiments from ozonolysis of a mixture of four biogenic volatile organic compounds (BVOC): α-pinene, β-pinene, Δ3-carene and isoprene. The SOA was subsequently aged under three different sets of conditions: in the dark in the presence of residual ozone, with UV irradiation and OH radicals, and using UV light only. Among all studied conditions, only OH radical-initiated aging was found to influence the molecular composition of the aerosol and showed an increase in carbon oxidation state (OSC) and elemental O / C ratios of the SOA components. None of the aging processes produced an observable effect on the oligomers formed from ozonolysis of the BVOC mixture, which were found to be equally abundant in both "fresh" and "aged" SOA. Additional experiments using α-pinene as the sole precursor demonstrated that oligomers are an important group of compounds in SOA produced from both ozonolysis and OH radical-initiated oxidation processes; however, a completely different set of oligomers is formed under these two oxidation regimes. SOA from the OH-initiated oxidation of α-pinene had a significantly higher overall OSC and O / C compared to that from pure ozonolysis experiments confirming that the OH radical reaction is more likely to be responsible for the occurrence of highly oxidized species in ambient biogenic SOA.

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