Articles | Volume 15, issue 10
https://doi.org/10.5194/acp-15-5683-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-5683-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Molecular composition of fresh and aged secondary organic aerosol from a mixture of biogenic volatile compounds: a high-resolution mass spectrometry study
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, United Kingdom
J.-F. Doussin
LISA, Universités Paris-Est-Créteil et Paris Diderot, CNRS UMR 7583, 61 Avenue du Général de Gaulle, 94010, Créteil, France
C. Giorio
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, United Kingdom
National Centre for Atmospheric Science, School of Geography, Earth and Environmental Sciences, Division of Environmental Health and Risk Management, University of Birmingham, Edgbaston, Birmingham B15 2TT, United Kingdom
B. Mahon
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, United Kingdom
E. M. Wilson
Department of Chemistry and Environmental Research Institute, University College Cork, Cork, Ireland
N. Maurin
LISA, Universités Paris-Est-Créteil et Paris Diderot, CNRS UMR 7583, 61 Avenue du Général de Gaulle, 94010, Créteil, France
E. Pangui
LISA, Universités Paris-Est-Créteil et Paris Diderot, CNRS UMR 7583, 61 Avenue du Général de Gaulle, 94010, Créteil, France
D. S. Venables
Department of Chemistry and Environmental Research Institute, University College Cork, Cork, Ireland
J. C. Wenger
Department of Chemistry and Environmental Research Institute, University College Cork, Cork, Ireland
M. Kalberer
CORRESPONDING AUTHOR
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, United Kingdom
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Cited
75 citations as recorded by crossref.
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- Rapid Aqueous-Phase Photooxidation of Dimers in the α-Pinene Secondary Organic Aerosol R. Zhao et al. 10.1021/acs.estlett.7b00148
- Influence of Polycyclic Aromatic Compounds and Oxidation States of Soot Organics on the Metabolome of Human-Lung Cells (A549): Implications for Vehicle Fuel Selection L. Wang et al. 10.1021/acs.est.3c05228
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- Molecular characterization of atmospheric organic aerosols in typical megacities in China M. Zhang et al. 10.1038/s41612-024-00784-1
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- Cloud condensation nuclei activity, droplet growth kinetics, and hygroscopicity of biogenic and anthropogenic secondary organic aerosol (SOA) D. Zhao et al. 10.5194/acp-16-1105-2016
- UHPLC-Orbitrap mass spectrometric characterization of organic aerosol from a central European city (Mainz, Germany) and a Chinese megacity (Beijing) K. Wang et al. 10.1016/j.atmosenv.2018.06.036
- Varying chiral ratio of pinic acid enantiomers above the Amazon rainforest D. Leppla et al. 10.5194/acp-23-809-2023
- Mass spectrometry-based Aerosolomics: a new approach to resolve sources, composition, and partitioning of secondary organic aerosol M. Thoma et al. 10.5194/amt-15-7137-2022
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- Aerosol Chemistry Resolved by Mass Spectrometry: Insights into Particle Growth after Ambient New Particle Formation A. Vogel et al. 10.1021/acs.est.6b01673
- Photodegradation of α-Pinene Secondary Organic Aerosol Dominated by Moderately Oxidized Molecules V. Pospisilova et al. 10.1021/acs.est.0c06752
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- Formation of Metal–Cyanide Complexes in Deliquescent Airborne Particles: A New Possible Sink for HCN in Urban Environments C. Giorio et al. 10.1021/acs.est.7b03123
- Molecular Insights on Dissolved Organic Matter Transformation by Supraglacial Microbial Communities R. Antony et al. 10.1021/acs.est.6b05780
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- Impact of anthropogenic and biogenic sources on the seasonal variation in the molecular composition of urban organic aerosols: a field and laboratory study using ultra-high-resolution mass spectrometry K. Daellenbach et al. 10.5194/acp-19-5973-2019
- Spiers Memorial Lecture : Introductory lecture: chemistry in the urban atmosphere U. Baltensperger 10.1039/C6FD00065G
- Indoor Illumination of Terpenes and Bleach Emissions Leads to Particle Formation and Growth C. Wang et al. 10.1021/acs.est.9b04261
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
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- Molecular composition and origin of water-soluble organic matter in marine aerosols in the Pacific off China H. Bao et al. 10.1016/j.atmosenv.2018.07.059
- Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol C. Kenseth et al. 10.1021/acs.est.0c01566
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- The effect of sub-zero temperature on the formation and composition of secondary organic aerosol from ozonolysis of alpha-pinene K. Kristensen et al. 10.1039/C7EM00231A
- Dissolved organic matter in the deep TALDICE ice core: A nano-UPLC-nano-ESI-HRMS method R. Zangrando et al. 10.1016/j.scitotenv.2019.134432
- Chemical Characterization of Cloudwater Collected at Puy de Dôme by FT-ICR MS Reveals the Presence of SOA Components A. Bianco et al. 10.1021/acsearthspacechem.9b00153
- Overlooked Trace Molecules in Organic Aerosol Revealed by Gas Chromatography–Orbitrap Mass Spectrometry T. Wang et al. 10.1021/acs.est.4c03171
- Emerging investigator series: secondary organic aerosol formation from photooxidation of acyclic terpenes in an oxidation flow reactor S. Gu et al. 10.1039/D4EM00063C
- Source and formation process impact the chemodiversity of rainwater dissolved organic matter along the Yangtze River Basin in summer S. Chen et al. 10.1016/j.watres.2021.118024
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- Chemical Characteristics of Organic Aerosols in Shanghai: A Study by Ultrahigh‐Performance Liquid Chromatography Coupled With Orbitrap Mass Spectrometry X. Wang et al. 10.1002/2017JD026930
- Enhanced Volatile Organic Compounds emissions and organic aerosol mass increase the oligomer content of atmospheric aerosols I. Kourtchev et al. 10.1038/srep35038
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- Direct target and non-target analysis of urban aerosol sample extracts using atmospheric pressure photoionisation high-resolution mass spectrometry C. Giorio et al. 10.1016/j.chemosphere.2019.02.151
- Molecular characterization of organic aerosols in Taiyuan, China: Seasonal variation and source identification W. Wang et al. 10.1016/j.scitotenv.2021.149419
- Effect of relative humidity on the composition of secondary organic aerosol from the oxidation of toluene M. Hinks et al. 10.5194/acp-18-1643-2018
- NOx enhances secondary organic aerosol formation from nighttime γ-terpinene ozonolysis L. Xu et al. 10.1016/j.atmosenv.2020.117375
- Impact of biogenic secondary organic aerosol (SOA) loading on the molecular composition of wintertime PM2.5 in urban Tianjin: an insight from Fourier transform ion cyclotron resonance mass spectrometry S. Zhong et al. 10.5194/acp-23-2061-2023
- High-Molecular Weight Dimer Esters Are Major Products in Aerosols from α-Pinene Ozonolysis and the Boreal Forest K. Kristensen et al. 10.1021/acs.estlett.6b00152
- The Interplay Between Hydrogen Bonding and Coulombic Forces in Determining the Structure of Sulfuric Acid-Amine Clusters S. Waller et al. 10.1021/acs.jpclett.8b00161
- The Aarhus Chamber Campaign on Highly Oxygenated Organic Molecules and Aerosols (ACCHA): particle formation, organic acids, and dimer esters from <i>α</i>-pinene ozonolysis at different temperatures K. Kristensen et al. 10.5194/acp-20-12549-2020
- Synergetic effects of NH<sub>3</sub> and NO<sub><i>x</i></sub> on the production and optical absorption of secondary organic aerosol formation from toluene photooxidation S. Liu et al. 10.5194/acp-21-17759-2021
- Chemical Characterization of Rural Organic Aerosol in the North China Plain Using Ultrahigh-Resolution Mass Spectrometry Y. Zhang et al. 10.3390/atmos14111636
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- Prolonged Dark Chemical Processes in Secondary Organic Aerosols on Filters and in Aqueous Solution J. Resch et al. 10.1021/acs.est.4c01647
- Compositional Evolution of Secondary Organic Aerosol as Temperature and Relative Humidity Cycle in Atmospherically Relevant Ranges Z. Zhao et al. 10.1021/acsearthspacechem.9b00232
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- On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames R. Benoit et al. 10.5194/acp-21-7845-2021
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- CCN activation of ultrafine biogenic-WSOC under restricted anthropogenic emissions: A study over eastern Himalaya in India M. Dutta et al. 10.1016/j.atmosres.2023.106704
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- Overcoming the lack of authentic standards for the quantification of biogenic secondary organic aerosol markers D. Bryant et al. 10.1039/D2EA00074A
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- Spatial and diurnal variations of aerosol organosulfates in summertime Shanghai, China: potential influence of photochemical processes and anthropogenic sulfate pollution T. Yang et al. 10.5194/acp-23-13433-2023
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- Effects of NO x on the molecular composition of secondary organic aerosol formed by the ozonolysis and photooxidation of α-pinene J. Park et al. 10.1016/j.atmosenv.2017.07.022
- Synergistic O 3 + OH oxidation pathway to extremely low-volatility dimers revealed in β-pinene secondary organic aerosol C. Kenseth et al. 10.1073/pnas.1804671115
- Direct Surface Analysis Coupled to High-Resolution Mass Spectrometry Reveals Heterogeneous Composition of the Cuticle of Hibiscus trionum Petals C. Giorio et al. 10.1021/acs.analchem.5b02498
- Monoterpene SOA – Contribution of first-generation oxidation products to formation and chemical composition A. Mutzel et al. 10.1016/j.atmosenv.2015.10.080
73 citations as recorded by crossref.
- Characterization of Highly Oxidized Molecules in Fresh and Aged Biogenic Secondary Organic Aerosol P. Tu et al. 10.1021/acs.analchem.6b00378
- Rapid Aqueous-Phase Photooxidation of Dimers in the α-Pinene Secondary Organic Aerosol R. Zhao et al. 10.1021/acs.estlett.7b00148
- Influence of Polycyclic Aromatic Compounds and Oxidation States of Soot Organics on the Metabolome of Human-Lung Cells (A549): Implications for Vehicle Fuel Selection L. Wang et al. 10.1021/acs.est.3c05228
- Structural Characterisation of Dimeric Esters in α-Pinene Secondary Organic Aerosol Using N2 and CO2 Ion Mobility Mass Spectrometry Y. Iinuma et al. 10.3390/atmos12010017
- On the formation of highly oxidized pollutants by autoxidation of terpenes under low-temperature-combustion conditions: the case of limonene and α-pinene R. Benoit et al. 10.5194/acp-23-5715-2023
- Detailed Source-Specific Molecular Composition of Ambient Aerosol Organic Matter Using Ultrahigh Resolution Mass Spectrometry and 1H NMR A. Willoughby et al. 10.3390/atmos7060079
- Molecular composition of organic aerosols in central Amazonia: an ultra-high-resolution mass spectrometry study I. Kourtchev et al. 10.5194/acp-16-11899-2016
- Molecular formula composition of β-caryophyllene ozonolysis SOA formed in humid and dry conditions S. Kundu et al. 10.1016/j.atmosenv.2016.12.031
- Molecular characterization of atmospheric organic aerosols in typical megacities in China M. Zhang et al. 10.1038/s41612-024-00784-1
- Effects of the sample matrix on the photobleaching and photodegradation of toluene-derived secondary organic aerosol compounds A. Klodt et al. 10.5194/acp-22-10155-2022
- Cloud condensation nuclei activity, droplet growth kinetics, and hygroscopicity of biogenic and anthropogenic secondary organic aerosol (SOA) D. Zhao et al. 10.5194/acp-16-1105-2016
- UHPLC-Orbitrap mass spectrometric characterization of organic aerosol from a central European city (Mainz, Germany) and a Chinese megacity (Beijing) K. Wang et al. 10.1016/j.atmosenv.2018.06.036
- Varying chiral ratio of pinic acid enantiomers above the Amazon rainforest D. Leppla et al. 10.5194/acp-23-809-2023
- Mass spectrometry-based Aerosolomics: a new approach to resolve sources, composition, and partitioning of secondary organic aerosol M. Thoma et al. 10.5194/amt-15-7137-2022
- Large Gas-Phase Source of Esters and Other Accretion Products in the Atmosphere O. Peräkylä et al. 10.1021/jacs.2c10398
- Effects of Photolysis on the Chemical and Optical Properties of Secondary Organic Material Over Extended Time Scales E. Walhout et al. 10.1021/acsearthspacechem.9b00109
- Aerosol Chemistry Resolved by Mass Spectrometry: Insights into Particle Growth after Ambient New Particle Formation A. Vogel et al. 10.1021/acs.est.6b01673
- Photodegradation of α-Pinene Secondary Organic Aerosol Dominated by Moderately Oxidized Molecules V. Pospisilova et al. 10.1021/acs.est.0c06752
- On the correlation between hygroscopic properties and chemical composition of cloud condensation nuclei obtained from the chemical aging of soot particles with O3 and SO2 J. Wu et al. 10.1016/j.scitotenv.2023.167745
- Formation of Metal–Cyanide Complexes in Deliquescent Airborne Particles: A New Possible Sink for HCN in Urban Environments C. Giorio et al. 10.1021/acs.est.7b03123
- Molecular Insights on Dissolved Organic Matter Transformation by Supraglacial Microbial Communities R. Antony et al. 10.1021/acs.est.6b05780
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- Impact of anthropogenic and biogenic sources on the seasonal variation in the molecular composition of urban organic aerosols: a field and laboratory study using ultra-high-resolution mass spectrometry K. Daellenbach et al. 10.5194/acp-19-5973-2019
- Spiers Memorial Lecture : Introductory lecture: chemistry in the urban atmosphere U. Baltensperger 10.1039/C6FD00065G
- Indoor Illumination of Terpenes and Bleach Emissions Leads to Particle Formation and Growth C. Wang et al. 10.1021/acs.est.9b04261
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Observations of sesquiterpenes and their oxidation products in central Amazonia during the wet and dry seasons L. Yee et al. 10.5194/acp-18-10433-2018
- Molecular composition and origin of water-soluble organic matter in marine aerosols in the Pacific off China H. Bao et al. 10.1016/j.atmosenv.2018.07.059
- Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol C. Kenseth et al. 10.1021/acs.est.0c01566
- Particle-phase accretion forms dimer esters in pinene secondary organic aerosol C. Kenseth et al. 10.1126/science.adi0857
- Light absorption properties and molecular compositions of water-soluble and methanol-soluble organic carbon emitted from wood pyrolysis and combustion R. Zhao et al. 10.1016/j.scitotenv.2021.151136
- The effect of sub-zero temperature on the formation and composition of secondary organic aerosol from ozonolysis of alpha-pinene K. Kristensen et al. 10.1039/C7EM00231A
- Dissolved organic matter in the deep TALDICE ice core: A nano-UPLC-nano-ESI-HRMS method R. Zangrando et al. 10.1016/j.scitotenv.2019.134432
- Chemical Characterization of Cloudwater Collected at Puy de Dôme by FT-ICR MS Reveals the Presence of SOA Components A. Bianco et al. 10.1021/acsearthspacechem.9b00153
- Overlooked Trace Molecules in Organic Aerosol Revealed by Gas Chromatography–Orbitrap Mass Spectrometry T. Wang et al. 10.1021/acs.est.4c03171
- Emerging investigator series: secondary organic aerosol formation from photooxidation of acyclic terpenes in an oxidation flow reactor S. Gu et al. 10.1039/D4EM00063C
- Source and formation process impact the chemodiversity of rainwater dissolved organic matter along the Yangtze River Basin in summer S. Chen et al. 10.1016/j.watres.2021.118024
- Nontarget Screening Exhibits a Seasonal Cycle of PM2.5 Organic Aerosol Composition in Beijing J. Ma et al. 10.1021/acs.est.1c06905
- Molecular and Structural Characterization of Isomeric Compounds in Atmospheric Organic Aerosol Using Ion Mobility-Mass Spectrometry C. West et al. 10.1021/acs.jpca.2c06459
- Chemical Characteristics of Organic Aerosols in Shanghai: A Study by Ultrahigh‐Performance Liquid Chromatography Coupled With Orbitrap Mass Spectrometry X. Wang et al. 10.1002/2017JD026930
- Enhanced Volatile Organic Compounds emissions and organic aerosol mass increase the oligomer content of atmospheric aerosols I. Kourtchev et al. 10.1038/srep35038
- Influence of relative humidity on cyclohexene SOA formation from OH photooxidation S. Liu et al. 10.1016/j.chemosphere.2019.05.131
- Direct target and non-target analysis of urban aerosol sample extracts using atmospheric pressure photoionisation high-resolution mass spectrometry C. Giorio et al. 10.1016/j.chemosphere.2019.02.151
- Molecular characterization of organic aerosols in Taiyuan, China: Seasonal variation and source identification W. Wang et al. 10.1016/j.scitotenv.2021.149419
- Effect of relative humidity on the composition of secondary organic aerosol from the oxidation of toluene M. Hinks et al. 10.5194/acp-18-1643-2018
- NOx enhances secondary organic aerosol formation from nighttime γ-terpinene ozonolysis L. Xu et al. 10.1016/j.atmosenv.2020.117375
- Impact of biogenic secondary organic aerosol (SOA) loading on the molecular composition of wintertime PM2.5 in urban Tianjin: an insight from Fourier transform ion cyclotron resonance mass spectrometry S. Zhong et al. 10.5194/acp-23-2061-2023
- High-Molecular Weight Dimer Esters Are Major Products in Aerosols from α-Pinene Ozonolysis and the Boreal Forest K. Kristensen et al. 10.1021/acs.estlett.6b00152
- The Interplay Between Hydrogen Bonding and Coulombic Forces in Determining the Structure of Sulfuric Acid-Amine Clusters S. Waller et al. 10.1021/acs.jpclett.8b00161
- The Aarhus Chamber Campaign on Highly Oxygenated Organic Molecules and Aerosols (ACCHA): particle formation, organic acids, and dimer esters from <i>α</i>-pinene ozonolysis at different temperatures K. Kristensen et al. 10.5194/acp-20-12549-2020
- Synergetic effects of NH<sub>3</sub> and NO<sub><i>x</i></sub> on the production and optical absorption of secondary organic aerosol formation from toluene photooxidation S. Liu et al. 10.5194/acp-21-17759-2021
- Chemical Characterization of Rural Organic Aerosol in the North China Plain Using Ultrahigh-Resolution Mass Spectrometry Y. Zhang et al. 10.3390/atmos14111636
- Iodometry-Assisted Liquid Chromatography Electrospray Ionization Mass Spectrometry for Analysis of Organic Peroxides: An Application to Atmospheric Secondary Organic Aerosol R. Zhao et al. 10.1021/acs.est.7b04863
- Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
- Molecular Characterization of Cloud Water Samples Collected at the Puy de Dôme (France) by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry A. Bianco et al. 10.1021/acs.est.8b01964
- Prolonged Dark Chemical Processes in Secondary Organic Aerosols on Filters and in Aqueous Solution J. Resch et al. 10.1021/acs.est.4c01647
- Compositional Evolution of Secondary Organic Aerosol as Temperature and Relative Humidity Cycle in Atmospherically Relevant Ranges Z. Zhao et al. 10.1021/acsearthspacechem.9b00232
- Regional differences in molecular characteristics of atmospheric water-soluble organic carbon over northern China: Comparison of remote, rural, and urban environments H. Wen et al. 10.1016/j.scitotenv.2024.174170
- A parameterisation for the co-condensation of semi-volatile organics into multiple aerosol particle modes M. Crooks et al. 10.5194/gmd-11-3261-2018
- High-molecular-weight esters in <i>α</i>-pinene ozonolysis secondary organic aerosol: structural characterization and mechanistic proposal for their formation from highly oxygenated molecules A. Kahnt et al. 10.5194/acp-18-8453-2018
- On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames R. Benoit et al. 10.5194/acp-21-7845-2021
- Cloud Processing of Secondary Organic Aerosol from Isoprene and Methacrolein Photooxidation C. Giorio et al. 10.1021/acs.jpca.7b05933
- Characterisation of atmospheric organic aerosols with one- and multidimensional liquid chromatography and mass spectrometry: State of the art and future perspectives S. Hildmann & T. Hoffmann 10.1016/j.trac.2024.117698
- Sulfur Dioxide Modifies Aerosol Particle Formation and Growth by Ozonolysis of Monoterpenes and Isoprene C. Stangl et al. 10.1029/2018JD030064
- CCN activation of ultrafine biogenic-WSOC under restricted anthropogenic emissions: A study over eastern Himalaya in India M. Dutta et al. 10.1016/j.atmosres.2023.106704
- Molecular composition of organic aerosols at urban background and road tunnel sites using ultra-high resolution mass spectrometry H. Tong et al. 10.1039/C5FD00206K
- Overcoming the lack of authentic standards for the quantification of biogenic secondary organic aerosol markers D. Bryant et al. 10.1039/D2EA00074A
- Structural and Light-Absorption Characteristics of Complex Water-Insoluble Organic Mixtures in Urban Submicrometer Aerosols Q. Chen et al. 10.1021/acs.est.7b01630
- Spatial and diurnal variations of aerosol organosulfates in summertime Shanghai, China: potential influence of photochemical processes and anthropogenic sulfate pollution T. Yang et al. 10.5194/acp-23-13433-2023
- Modeling the Effects of Dimerization and Bulk Diffusion on the Evaporative Behavior of Secondary Organic Aerosol Formed from α-Pinene and 1,3,5-Trimethylbenzene Y. Morino et al. 10.1021/acsearthspacechem.0c00106
- Using GECKO-A to derive mechanistic understanding of secondary organic aerosol formation from the ubiquitous but understudied camphene I. Afreh et al. 10.5194/acp-21-11467-2021
- Effects of NO x on the molecular composition of secondary organic aerosol formed by the ozonolysis and photooxidation of α-pinene J. Park et al. 10.1016/j.atmosenv.2017.07.022
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