Articles | Volume 15, issue 6
Atmos. Chem. Phys., 15, 3339–3358, 2015
Atmos. Chem. Phys., 15, 3339–3358, 2015

Research article 25 Mar 2015

Research article | 25 Mar 2015

Relating hygroscopicity and optical properties to chemical composition and structure of secondary organic aerosol particles generated from the ozonolysis of α-pinene

C. Denjean1,2, P. Formenti1, B. Picquet-Varrault1, E. Pangui1, P. Zapf1, Y. Katrib1, C. Giorio3,*, A. Tapparo3, A. Monod4, B. Temime-Roussel4, P. Decorse5, C. Mangeney5, and J. F. Doussin1 C. Denjean et al.
  • 1Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR-CNRS 7583, Université Paris-Est-Créteil (UPEC) et Université Paris Diderot (UPD), Institut Pierre Simon Laplace (IPSL), Créteil, France
  • 2Leibniz Institute for Tropospheric Research, Permoserstr. 15, 04318, Leipzig, Germany
  • 3Dipartimento di Scienze Chimiche, Università degli Studi di Padova, via Marzolo 1, 35131 Padova, Italy
  • 4Aix Marseille Université, CNRS, Laboratoire Chimie de l'Environnement (LCE), FRE 3416, 13331 Marseille, France
  • 5ITODYS, Université Paris Diderot, Sorbonne Paris Cité, CNRS UMR 7086, 15 rue J-A de Baïf, 75013 Paris, France
  • *now at: Department of Chemistry, University of Cambridge, Lensfield road, CB2 1EW Cambridge, UK

Abstract. Secondary organic aerosol (SOA) were generated from the ozonolysis of α-pinene in the CESAM (French acronym for Experimental Multiphasic Atmospheric Simulation Chamber) simulation chamber. The SOA formation and aging were studied by following their optical, hygroscopic and chemical properties. The optical properties were investigated by determining the particle complex refractive index (CRI). The hygroscopicity was quantified by measuring the effect of relative humidity (RH) on the particle size (size growth factor, GF) and on the scattering coefficient (scattering growth factor, f(RH)). The oxygen to carbon atomic ratios (O : C) of the particle surface and bulk were used as a sensitive parameter to correlate the changes in hygroscopic and optical properties of the SOA composition during their formation and aging in CESAM.

The real CRI at 525 nm wavelength decreased from 1.43–1.60 (±0.02) to 1.32–1.38 (±0.02) during the SOA formation. The decrease in the real CRI correlated to the O : C decrease from 0.68 (±0.20) to 0.55 (±0.16). In contrast, the GF remained roughly constant over the reaction time, with values of 1.02–1.07 (±0.02) at 90% (±4.2%) RH. Simultaneous measurements of O : C of the particle surface revealed that the SOA was not composed of a homogeneous mixture, but contained less oxidised species at the surface which may limit water absorption. In addition, an apparent change in both mobility diameter and scattering coefficient with increasing RH from 0 to 30% was observed for SOA after 14 h of reaction. We postulate that this change could be due to a change in the viscosity of the SOA from a predominantly glassy state to a predominantly liquid state.

Final-revised paper