Articles | Volume 23, issue 23
https://doi.org/10.5194/acp-23-14735-2023
https://doi.org/10.5194/acp-23-14735-2023
Research article
 | 
29 Nov 2023
Research article |  | 29 Nov 2023

Development, intercomparison, and evaluation of an improved mechanism for the oxidation of dimethyl sulfide in the UKCA model

Ben A. Cala, Scott Archer-Nicholls, James Weber, N. Luke Abraham, Paul T. Griffiths, Lorrie Jacob, Y. Matthew Shin, Laura E. Revell, Matthew Woodhouse, and Alexander T. Archibald

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Cited articles

Archibald, A., Cala, B., Archer-Nicholls, S., Weber, J., Abraham, N. L., Griffiths, P. T., Jacob, L., Shin, Y. M., Revell, L. E., and Woodhouse, M.: BOXMOX files for Cala et al. acp-2023-42 (Version 1), Zenodo [code], https://doi.org/10.5281/zenodo.10114476, 2023. 
Assaf, E., Finewax, Z., Marshall, P., Veres, P. R., Neuman, J. A., and Burkholder, J. B.: Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical between 314 and 433 K, J. Phys. Chem. A, 127, 2336–2350, 2023. 
Andreae, M. O.: Ocean-atmosphere interactions in the global biogeochemical sulfur cycle, Mar. Chem., 30, 1–29, https://doi.org/10.1016/0304-4203(90)90059-L, 1990. 
Archer-Nicholls, S., Abraham, N. L., Shin, Y. M., Weber, J., Russo, M. R., Lowe, D., Utembe, S. R., O'Connor, F. M., Kerridge, B., Latter, B., Siddans, R., Jenkin, M., Wild, O., and Archibald, A. T.: The Common Representative Intermediates Mechanism Version 2 in the United Kingdom Chemistry and Aerosols Model, J. Adv. Model. Earth Sy., 13, e2020MS002420, https://doi.org/10.1029/2020MS002420, 2021. 
Archibald, A. T., Jenkin, M. E., and Shallcross, D. E.: An isoprene mechanism intercomparison, Atmos. Environ., 44, 5356–5364, https://doi.org/10.1016/j.atmosenv.2009.09.016, 2010. 
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Dimethyl sulfide (DMS)  is an important trace gas emitted from the ocean recognised as setting the sulfate aerosol background, but its oxidation is complex. As a result representation in chemistry-climate models is greatly simplified. We develop and compare a new mechanism to existing mechanisms via a series of global and box model experiments. Our studies show our updated DMS scheme is a significant improvement but significant variance exists between mechanisms.
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