Articles | Volume 20, issue 4
Research article
02 Mar 2020
Research article |  | 02 Mar 2020

Molecular compositions and optical properties of dissolved brown carbon in biomass burning, coal combustion, and vehicle emission aerosols illuminated by excitation–emission matrix spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry analysis

Jiao Tang, Jun Li, Tao Su, Yong Han, Yangzhi Mo, Hongxing Jiang, Min Cui, Bin Jiang, Yingjun Chen, Jianhui Tang, Jianzhong Song, Ping'an Peng, and Gan Zhang

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Cited articles

Andersson, C. A. and Bro, R.: The N-way Toolbox for MATLAB, Chemom. Intell. Lab. Syst., 52, 1–4,, 2000. 
Andrade-Eiroa, Á., Canle, M., and Cerdá, V.: Environmental Applications of Excitation-Emission Spectrofluorimetry: An In-Depth Review I, Appl. Spectrosc. Rev., 48, 1–49,, 2013. 
Bahram, M., Bro, R., Stedmon, C., and Afkhami, A.: Handling of Rayleigh and Raman scatter for PARAFAC modeling of fluorescence data using interpolation, J. Chemom., 20, 99–105,, 2006. 
Bhattacharya, R. and Osburn, C. L.: Multivariate Analyses of Phytoplankton Pigment Fluorescence from a Freshwater River Network, Environ. Sci. Technol., 51, 6683–6690,, 2017. 
Budisulistiorini, S. H., Riva, M., Williams, M., Chen, J., Itoh, M., Surratt, J. D., and Kuwata, M.: Light-Absorbing Brown Carbon Aerosol Constituents from Combustion of Indonesian Peat and Biomass, Environ. Sci. Technol., 51, 4415–4423,, 2017. 
Short summary
We investigated the light absorption, fluorescence, and molecular composition of dissolved organic carbon from the simulated combustion of biomass and coal and vehicle emissions with UV–vis spectra, EEM-PARAFAC, and FT-ICR MS. We observed high light absorption capacity from source emissions, and fluorescence spectra and molecular structures varied by source. We concluded that an EEM- and molecular-composition-based methodology could be helpful in the source apportionment of atmospheric aerosols.
Final-revised paper