Articles | Volume 18, issue 7
https://doi.org/10.5194/acp-18-4519-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-4519-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 Apr 2018
Research article |
| 04 Apr 2018
| 04 Apr 2018
Nucleation of nitric acid hydrates in polar stratospheric clouds by meteoric material
Alexander D. James
School of Chemistry, University of Leeds, Leeds LS2 9JT, UK
James S. A. Brooke
School of Chemistry, University of Leeds, Leeds LS2 9JT, UK
Thomas P. Mangan
School of Chemistry, University of Leeds, Leeds LS2 9JT, UK
Thomas F. Whale
School of Earth and Environment, University of Leeds, Leeds LS2 9JT,
UK
School of Chemistry, University of Leeds, Leeds LS2 9JT, UK
Benjamin J. Murray
CORRESPONDING AUTHOR
School of Earth and Environment, University of Leeds, Leeds LS2 9JT,
UK
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Sea spray aerosol particles are a mixture of inorganic salts and organic matter from phytoplankton organisms. At low temperatures in the upper troposphere, both inorganic and organic constituents can induce the formation of ice crystals and thereby impact cloud properties and climate. In this study, we performed experiments in a cloud simulation chamber with particles produced from Arctic seawater samples to quantify the relative contribution of inorganic and organic species in ice formation.
Michael P. Adams, Nina S. Atanasova, Svetlana Sofieva, Janne Ravantti, Aino Heikkinen, Zoé Brasseur, Jonathan Duplissy, Dennis H. Bamford, and Benjamin J. Murray
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The formation of ice in clouds is critically important for the planet's climate. Hence, we need to know which aerosol types nucleate ice and how effectively they do so. Here we show that virus particles, with a range of architectures, nucleate ice when immersed in supercooled water. However, we also show that they only make a minor contribution to the ice-nucleating particle population in the terrestrial atmosphere, but we cannot rule them out as being important in the marine environment.
Rachel E. Hawker, Annette K. Miltenberger, Jonathan M. Wilkinson, Adrian A. Hill, Ben J. Shipway, Zhiqiang Cui, Richard J. Cotton, Ken S. Carslaw, Paul R. Field, and Benjamin J. Murray
Atmos. Chem. Phys., 21, 5439–5461, https://doi.org/10.5194/acp-21-5439-2021, https://doi.org/10.5194/acp-21-5439-2021, 2021
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Bingkun Yu, Xianghui Xue, Christopher J. Scott, Jianfei Wu, Xinan Yue, Wuhu Feng, Yutian Chi, Daniel R. Marsh, Hanli Liu, Xiankang Dou, and John M. C. Plane
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Julia Schneider, Kristina Höhler, Paavo Heikkilä, Jorma Keskinen, Barbara Bertozzi, Pia Bogert, Tobias Schorr, Nsikanabasi Silas Umo, Franziska Vogel, Zoé Brasseur, Yusheng Wu, Simo Hakala, Jonathan Duplissy, Dmitri Moisseev, Markku Kulmala, Michael P. Adams, Benjamin J. Murray, Kimmo Korhonen, Liqing Hao, Erik S. Thomson, Dimitri Castarède, Thomas Leisner, Tuukka Petäjä, and Ottmar Möhler
Atmos. Chem. Phys., 21, 3899–3918, https://doi.org/10.5194/acp-21-3899-2021, https://doi.org/10.5194/acp-21-3899-2021, 2021
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By triggering the formation of ice crystals, ice-nucleating particles (INP) strongly influence cloud formation. Continuous, long-term measurements are needed to characterize the atmospheric INP variability. Here, a first long-term time series of INP spectra measured in the boreal forest for more than 1 year is presented, showing a clear seasonal cycle. It is shown that the seasonal dependency of INP concentrations and prevalent INP types is driven by the abundance of biogenic aerosol.
Ottmar Möhler, Michael Adams, Larissa Lacher, Franziska Vogel, Jens Nadolny, Romy Ullrich, Cristian Boffo, Tatjana Pfeuffer, Achim Hobl, Maximilian Weiß, Hemanth S. K. Vepuri, Naruki Hiranuma, and Benjamin J. Murray
Atmos. Meas. Tech., 14, 1143–1166, https://doi.org/10.5194/amt-14-1143-2021, https://doi.org/10.5194/amt-14-1143-2021, 2021
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The Earth's climate is influenced by clouds, which are impacted by ice-nucleating particles (INPs), a minor fraction of atmospheric aerosols. INPs induce ice formation in clouds and thus often initiate precipitation formation. The Portable Ice Nucleation Experiment (PINE) is the first fully automated instrument to study cloud ice formation and to obtain long-term records of INPs. This is a timely development, and the capabilities it offers for research and atmospheric monitoring are significant.
Benjamin J. Murray, Kenneth S. Carslaw, and Paul R. Field
Atmos. Chem. Phys., 21, 665–679, https://doi.org/10.5194/acp-21-665-2021, https://doi.org/10.5194/acp-21-665-2021, 2021
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The balance between the amounts of ice and supercooled water in clouds over the world's oceans strongly influences how much these clouds can dampen or amplify global warming. Aerosol particles which catalyse ice formation can dramatically reduce the amount of supercooled water in clouds; hence we argue that we need a concerted effort to improve our understanding of these ice-nucleating particles if we are to improve our predictions of climate change.
Luisa Ickes, Grace C. E. Porter, Robert Wagner, Michael P. Adams, Sascha Bierbauer, Allan K. Bertram, Merete Bilde, Sigurd Christiansen, Annica M. L. Ekman, Elena Gorokhova, Kristina Höhler, Alexei A. Kiselev, Caroline Leck, Ottmar Möhler, Benjamin J. Murray, Thea Schiebel, Romy Ullrich, and Matthew E. Salter
Atmos. Chem. Phys., 20, 11089–11117, https://doi.org/10.5194/acp-20-11089-2020, https://doi.org/10.5194/acp-20-11089-2020, 2020
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The Arctic is a region where aerosols are scarce. Sea spray might be a potential source of aerosols acting as ice-nucleating particles. We investigate two common phytoplankton species (Melosira arctica and Skeletonema marinoi) and present their ice nucleation activity in comparison with Arctic seawater microlayer samples from different field campaigns. We also aim to understand the aerosolization process of marine biological samples and the potential effect on the ice nucleation activity.
Thomas R. Lewis, Juan Carlos Gómez Martín, Mark A. Blitz, Carlos A. Cuevas, John M. C. Plane, and Alfonso Saiz-Lopez
Atmos. Chem. Phys., 20, 10865–10887, https://doi.org/10.5194/acp-20-10865-2020, https://doi.org/10.5194/acp-20-10865-2020, 2020
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Iodine-bearing gasses emitted from the sea surface are chemically processed in the atmosphere, leading to iodine accumulation in aerosol and transport to continental ecosystems. Such processing involves light-induced break-up of large, particle-forming iodine oxides into smaller, ozone-depleting molecules. We combine experiments and theory to report the photolysis efficiency of iodine oxides required to assess the impact of iodine on ozone depletion and particle formation.
Grace C. E. Porter, Sebastien N. F. Sikora, Michael P. Adams, Ulrike Proske, Alexander D. Harrison, Mark D. Tarn, Ian M. Brooks, and Benjamin J. Murray
Atmos. Meas. Tech., 13, 2905–2921, https://doi.org/10.5194/amt-13-2905-2020, https://doi.org/10.5194/amt-13-2905-2020, 2020
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Ice-nucleating particles affect cloud development, lifetime, and radiative properties. Hence it is important to know the abundance of INPs throughout the atmosphere. Here we present the development and application of a radio-controlled payload capable of collecting size-resolved aerosol from a tethered balloon for the primary purpose of offline INP analysis. Test data are presented from four locations: southern Finland, northern England, Svalbard, and southern England.
Alberto Sanchez-Marroquin, Duncan H. P. Hedges, Matthew Hiscock, Simon T. Parker, Philip D. Rosenberg, Jamie Trembath, Richard Walshaw, Ian T. Burke, James B. McQuaid, and Benjamin J. Murray
Atmos. Meas. Tech., 12, 5741–5763, https://doi.org/10.5194/amt-12-5741-2019, https://doi.org/10.5194/amt-12-5741-2019, 2019
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Sampling coarse-mode aerosol from a fast-moving research aircraft is challenging and can be subject to substantial losses and enhancements. We characterise these losses and enhancements for an inlet system designed to collect aerosol onto filters. We go on to present an application of this inlet system where we use electron microscopy to study the size and composition of the collected aerosol particles.
Tasha Aylett, James S. A. Brooke, Alexander D. James, Mario Nachbar, Denis Duft, Thomas Leisner, and John M. C. Plane
Atmos. Chem. Phys., 19, 12767–12777, https://doi.org/10.5194/acp-19-12767-2019, https://doi.org/10.5194/acp-19-12767-2019, 2019
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Interplanetary dust particles entering the Earth's atmosphere often melt and evaporate, injecting metals such as iron and magnesium into the atmosphere between 80 and 105 km. These metals become oxidized and then coagulate into small particles a few nanometres is size, known as meteoric smoke. In this study, iron oxide smoke particles were created in the laboratory, and their composition and optical properties were determined in order to understand satellite measurements.
Alexander D. Harrison, Katherine Lever, Alberto Sanchez-Marroquin, Mark A. Holden, Thomas F. Whale, Mark D. Tarn, James B. McQuaid, and Benjamin J. Murray
Atmos. Chem. Phys., 19, 11343–11361, https://doi.org/10.5194/acp-19-11343-2019, https://doi.org/10.5194/acp-19-11343-2019, 2019
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Mineral dusts are a source of ice-nucleating particles (INPs) in the atmosphere. Here we present a comprehensive survey of the ice-nucleating ability of naturally occurring quartz. We show the ice-nucleating variability of quartz and its sensitivity to time spent in water and air. We propose four new parameterizations for the minerals quartz, K feldspar, albite and plagioclase to predict INP concentrations in the atmosphere and show that K-feldspar is the dominant INP type in mineral dusts.
Elena C. Maters, Donald B. Dingwell, Corrado Cimarelli, Dirk Müller, Thomas F. Whale, and Benjamin J. Murray
Atmos. Chem. Phys., 19, 5451–5465, https://doi.org/10.5194/acp-19-5451-2019, https://doi.org/10.5194/acp-19-5451-2019, 2019
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This experimental study investigates the influence of volcanic ash chemical composition, crystallinity, and mineralogy on its ability to promote freezing of supercooled water. The results indicate that crystals in ash play a key role in this process and suggest that feldspars and perhaps pyroxenes in ash may be highly ice-active. These findings contribute to improving understanding of the potential of ash emissions from different explosive eruptions to impact ice formation in the atmosphere.
Naruki Hiranuma, Kouji Adachi, David M. Bell, Franco Belosi, Hassan Beydoun, Bhaskar Bhaduri, Heinz Bingemer, Carsten Budke, Hans-Christian Clemen, Franz Conen, Kimberly M. Cory, Joachim Curtius, Paul J. DeMott, Oliver Eppers, Sarah Grawe, Susan Hartmann, Nadine Hoffmann, Kristina Höhler, Evelyn Jantsch, Alexei Kiselev, Thomas Koop, Gourihar Kulkarni, Amelie Mayer, Masataka Murakami, Benjamin J. Murray, Alessia Nicosia, Markus D. Petters, Matteo Piazza, Michael Polen, Naama Reicher, Yinon Rudich, Atsushi Saito, Gianni Santachiara, Thea Schiebel, Gregg P. Schill, Johannes Schneider, Lior Segev, Emiliano Stopelli, Ryan C. Sullivan, Kaitlyn Suski, Miklós Szakáll, Takuya Tajiri, Hans Taylor, Yutaka Tobo, Romy Ullrich, Daniel Weber, Heike Wex, Thomas F. Whale, Craig L. Whiteside, Katsuya Yamashita, Alla Zelenyuk, and Ottmar Möhler
Atmos. Chem. Phys., 19, 4823–4849, https://doi.org/10.5194/acp-19-4823-2019, https://doi.org/10.5194/acp-19-4823-2019, 2019
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A total of 20 ice nucleation measurement techniques contributed to investigate the immersion freezing behavior of cellulose particles – natural polymers. Our data showed several types of cellulose are able to nucleate ice as efficiently as some mineral dust samples and cellulose has the potential to be an important atmospheric ice-nucleating particle. Continued investigation/collaboration is necessary to obtain further insight into consistency or diversity of ice nucleation measurements.
Mario Nachbar, Henrike Wilms, Denis Duft, Tasha Aylett, Kensei Kitajima, Takuya Majima, John M. C. Plane, Markus Rapp, and Thomas Leisner
Atmos. Chem. Phys., 19, 4311–4322, https://doi.org/10.5194/acp-19-4311-2019, https://doi.org/10.5194/acp-19-4311-2019, 2019
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Polar mesospheric clouds (PMC) are water ice clouds forming on nanoparticles in the polar summer mesopause. We investigate the impact of solar radiation on PMC formation in the laboratory. We show that Mie theory calculations combined with an equilibrium temperature model presented in this work predict the warming of the particles very well. Using this model we demonstrate that the impact of solar radiation on ice particle formation is significantly lower than previously assumed.
Tao Yuan, Wuhu Feng, John M. C. Plane, and Daniel R. Marsh
Atmos. Chem. Phys., 19, 3769–3777, https://doi.org/10.5194/acp-19-3769-2019, https://doi.org/10.5194/acp-19-3769-2019, 2019
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The Na layer in the upper atmosphere is very sensitive to solar radiation and varies considerably during sunrise and sunset. In this paper, we use the lidar observations and an advanced model to investigate this process. We found that the variation is mostly due to the changes in several photochemical reactions involving Na compounds, especially NaHCO3. We also reveal that the Fe layer in the same region changes more quickly than the Na layer due to a faster reaction rate of FeOH to sunlight.
Claire L. Ryder, Franco Marenco, Jennifer K. Brooke, Victor Estelles, Richard Cotton, Paola Formenti, James B. McQuaid, Hannah C. Price, Dantong Liu, Patrick Ausset, Phil D. Rosenberg, Jonathan W. Taylor, Tom Choularton, Keith Bower, Hugh Coe, Martin Gallagher, Jonathan Crosier, Gary Lloyd, Eleanor J. Highwood, and Benjamin J. Murray
Atmos. Chem. Phys., 18, 17225–17257, https://doi.org/10.5194/acp-18-17225-2018, https://doi.org/10.5194/acp-18-17225-2018, 2018
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Every year, millions of tons of Saharan dust particles are carried across the Atlantic by the wind, where they can affect weather patterns and climate. Their sizes span orders of magnitude, but the largest (over 10 microns – around the width of a human hair) are difficult to measure and few observations exist. Here we show new aircraft observations of large dust particles, finding more than we would expect, and we quantify their properties which allow them to interact with atmospheric radiation.
Paul J. DeMott, Ottmar Möhler, Daniel J. Cziczo, Naruki Hiranuma, Markus D. Petters, Sarah S. Petters, Franco Belosi, Heinz G. Bingemer, Sarah D. Brooks, Carsten Budke, Monika Burkert-Kohn, Kristen N. Collier, Anja Danielczok, Oliver Eppers, Laura Felgitsch, Sarvesh Garimella, Hinrich Grothe, Paul Herenz, Thomas C. J. Hill, Kristina Höhler, Zamin A. Kanji, Alexei Kiselev, Thomas Koop, Thomas B. Kristensen, Konstantin Krüger, Gourihar Kulkarni, Ezra J. T. Levin, Benjamin J. Murray, Alessia Nicosia, Daniel O'Sullivan, Andreas Peckhaus, Michael J. Polen, Hannah C. Price, Naama Reicher, Daniel A. Rothenberg, Yinon Rudich, Gianni Santachiara, Thea Schiebel, Jann Schrod, Teresa M. Seifried, Frank Stratmann, Ryan C. Sullivan, Kaitlyn J. Suski, Miklós Szakáll, Hans P. Taylor, Romy Ullrich, Jesus Vergara-Temprado, Robert Wagner, Thomas F. Whale, Daniel Weber, André Welti, Theodore W. Wilson, Martin J. Wolf, and Jake Zenker
Atmos. Meas. Tech., 11, 6231–6257, https://doi.org/10.5194/amt-11-6231-2018, https://doi.org/10.5194/amt-11-6231-2018, 2018
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The ability to measure ice nucleating particles is vital to quantifying their role in affecting clouds and precipitation. Methods for measuring droplet freezing were compared while co-sampling relevant particle types. Measurement correspondence was very good for ice nucleating particles of bacterial and natural soil origin, and somewhat more disparate for those of mineral origin. Results reflect recently improved capabilities and provide direction toward addressing remaining measurement issues.
Meng Si, Victoria E. Irish, Ryan H. Mason, Jesús Vergara-Temprado, Sarah J. Hanna, Luis A. Ladino, Jacqueline D. Yakobi-Hancock, Corinne L. Schiller, Jeremy J. B. Wentzell, Jonathan P. D. Abbatt, Ken S. Carslaw, Benjamin J. Murray, and Allan K. Bertram
Atmos. Chem. Phys., 18, 15669–15685, https://doi.org/10.5194/acp-18-15669-2018, https://doi.org/10.5194/acp-18-15669-2018, 2018
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Using the concentrations of ice-nucleating particles (INPs) and total aerosol particles measured at three coastal marine sites, the ice-nucleating ability of aerosol particles on a per number basis and a per surface-area basis were determined as a function of size. The ice-nucleating ability was strongly dependent on size, with larger particles being more efficient. This type of information can help determine the sources of INPs and constrain the future modelling of INPs and mixed-phase clouds.
John M. C. Plane, Wuhu Feng, Juan Carlos Gómez Martín, Michael Gerding, and Shikha Raizada
Atmos. Chem. Phys., 18, 14799–14811, https://doi.org/10.5194/acp-18-14799-2018, https://doi.org/10.5194/acp-18-14799-2018, 2018
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Meteoric ablation creates layers of metal atoms in the atmosphere around 90 km. Although Ca and Na have similar elemental abundances in most minerals found in the solar system, surprisingly the Ca abundance in the atmosphere is less than 1 % that of Na. This study uses a detailed chemistry model of Ca, largely based on laboratory kinetics measurements, in a whole-atmosphere model to show that the depletion is caused by inefficient ablation of Ca and the formation of stable molecular reservoirs.
Alexander D. Harrison, Thomas F. Whale, Rupert Rutledge, Stephen Lamb, Mark D. Tarn, Grace C. E. Porter, Michael P. Adams, James B. McQuaid, George J. Morris, and Benjamin J. Murray
Atmos. Meas. Tech., 11, 5629–5641, https://doi.org/10.5194/amt-11-5629-2018, https://doi.org/10.5194/amt-11-5629-2018, 2018
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The detection of low concentrations of ice-nucleating particles (INPs) is challenging. Here we present a new technique (IR-NIPI) that is sensitive to low concentrations of INPs (> 0.01 L−1) and uses an infrared camera with a novel calibration to detect the freezing of experimental suspensions. IR-NIPI temperature measurements prove to be robust with a series of comparisons to thermocouple measurements. Experimental comparisons to other freezing assay instruments are also in agreement.
Tao Li, Chao Ban, Xin Fang, Jing Li, Zhaopeng Wu, Wuhu Feng, John M. C. Plane, Jiangang Xiong, Daniel R. Marsh, Michael J. Mills, and Xiankang Dou
Atmos. Chem. Phys., 18, 11683–11695, https://doi.org/10.5194/acp-18-11683-2018, https://doi.org/10.5194/acp-18-11683-2018, 2018
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A total of 154 nights of observations by the USTC Na temperature and wind lidar (32° N, 117° E) suggest significant seasonal variability in the mesopause. Chemistry plays an important role in Na atom formation. More than half of the observed gravity wave (GW) momentum flux (MF), whose divergence determines the GW forcing, is induced by short-period (10 min–2 h) waves. The anticorrelation between MF and zonal wind (U) suggests strong filtering of short-period GWs by semiannual oscillation U.
Victoria E. Irish, Pablo Elizondo, Jessie Chen, Cédric Chou, Joannie Charette, Martine Lizotte, Luis A. Ladino, Theodore W. Wilson, Michel Gosselin, Benjamin J. Murray, Elena Polishchuk, Jonathan P. D. Abbatt, Lisa A. Miller, and Allan K. Bertram
Atmos. Chem. Phys., 17, 10583–10595, https://doi.org/10.5194/acp-17-10583-2017, https://doi.org/10.5194/acp-17-10583-2017, 2017
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The ocean is a possible source of atmospheric ice-nucleating particles (INPs). In this study we found that INPs were ubiquitous in the sea-surface microlayer and bulk seawater in the Canadian Arctic. A strong negative correlation was observed between salinity and freezing temperatures (after correcting for freezing point depression). Heat and filtration treatments of the samples showed that the INPs were likely biological material with sizes between 0.02 μm and 0.2 μm in diameter.
Martin P. Langowski, Christian von Savigny, John P. Burrows, Didier Fussen, Erin C. M. Dawkins, Wuhu Feng, John M. C. Plane, and Daniel R. Marsh
Atmos. Meas. Tech., 10, 2989–3006, https://doi.org/10.5194/amt-10-2989-2017, https://doi.org/10.5194/amt-10-2989-2017, 2017
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Meteoric metals form metal layers in the upper atmosphere anandplay a role in the formation of middle-atmospheric clouds and aerosols. However, the total metal influx rate is not well known. Global Na datasets from measurements and a model are available, which had not been compared yet on a global scale until this paper. Overall the agreement is good, and many differences between measurements are also found in the model simulations. However, the modeled layer altitude is too low.
Stefanie Unterguggenberger, Stefan Noll, Wuhu Feng, John M. C. Plane, Wolfgang Kausch, Stefan Kimeswenger, Amy Jones, and Sabine Moehler
Atmos. Chem. Phys., 17, 4177–4187, https://doi.org/10.5194/acp-17-4177-2017, https://doi.org/10.5194/acp-17-4177-2017, 2017
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This study focuses on the analysis of astronomical medium-resolution spectra from the VLT in Chile to measure airglow pseudo-continuum emission of FeO in the optical regime. Compared to OH or Na emissions, this emission is difficult to measure. Using 3.5 years of spectroscopic data, we found annual and semi-annual variations of the FeO emission. Furthermore, we used WACCM to determine the quantum yield of the FeO-producing Fe + O3 reaction in the atmosphere, which has not been done before.
Jesús Vergara-Temprado, Benjamin J. Murray, Theodore W. Wilson, Daniel O'Sullivan, Jo Browse, Kirsty J. Pringle, Karin Ardon-Dryer, Allan K. Bertram, Susannah M. Burrows, Darius Ceburnis, Paul J. DeMott, Ryan H. Mason, Colin D. O'Dowd, Matteo Rinaldi, and Ken S. Carslaw
Atmos. Chem. Phys., 17, 3637–3658, https://doi.org/10.5194/acp-17-3637-2017, https://doi.org/10.5194/acp-17-3637-2017, 2017
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We quantify the importance in the atmosphere of different aerosol components to contribute to global ice-nucleating particles concentrations (INPs). The aim is to improve the way atmospheric cloud-ice processes are represented in climate models so they will be able to make better predictions in the future. We found that a kind of dust (K-feldspar), together with marine organic aerosols, can help to improve the representation of INPs and explain most of their observations.
Tamás Kovács, Wuhu Feng, Anna Totterdill, John M. C. Plane, Sandip Dhomse, Juan Carlos Gómez-Martín, Gabriele P. Stiller, Florian J. Haenel, Christopher Smith, Piers M. Forster, Rolando R. García, Daniel R. Marsh, and Martyn P. Chipperfield
Atmos. Chem. Phys., 17, 883–898, https://doi.org/10.5194/acp-17-883-2017, https://doi.org/10.5194/acp-17-883-2017, 2017
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Sulfur hexafluoride (SF6) is a very potent greenhouse gas, which is present in the atmosphere only through its industrial use, for example as an electrical insulator. To estimate accurately the impact of SF6 emissions on climate we need to know how long it persists in the atmosphere before being removed. Previous estimates of the SF6 lifetime indicate a large degree of uncertainty. Here we use a detailed atmospheric model to calculate a current best estimate of the SF6 lifetime.
Alfonso Saiz-Lopez, John M. C. Plane, Carlos A. Cuevas, Anoop S. Mahajan, Jean-François Lamarque, and Douglas E. Kinnison
Atmos. Chem. Phys., 16, 15593–15604, https://doi.org/10.5194/acp-16-15593-2016, https://doi.org/10.5194/acp-16-15593-2016, 2016
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Electronic structure calculations are used to survey possible reactions that HOI and I2 could undergo at night in the lower troposphere, and hence reconcile measurements and models. The reactions NO3 + HOI and I2 + NO3 are included in two models to explore a new nocturnal iodine radical activation mechanism, leading to a reduction of nighttime HOI and I2. This chemistry can have a large impact on NO3 levels in the MBL, and hence upon the nocturnal oxidizing capacity of the marine atmosphere.
Wayne K. Hocking, Reynold E. Silber, John M. C. Plane, Wuhu Feng, and Marcial Garbanzo-Salas
Ann. Geophys., 34, 1119–1144, https://doi.org/10.5194/angeo-34-1119-2016, https://doi.org/10.5194/angeo-34-1119-2016, 2016
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Meteoroids entering the atmosphere produce trails of ionized particles which can be detected with radar. The weakest ones are called underdense (the most common), the strongest are called overdense, and intermediate ones are transitional. Meteor radar signatures are used to determine atmospheric parameters like temperature and winds. We present new results which show the effect of ozone on the transitional trail lifetimes, which may eventually allow radar to measure mesospheric ozone.
Anna Totterdill, Tamás Kovács, Wuhu Feng, Sandip Dhomse, Christopher J. Smith, Juan Carlos Gómez-Martín, Martyn P. Chipperfield, Piers M. Forster, and John M. C. Plane
Atmos. Chem. Phys., 16, 11451–11463, https://doi.org/10.5194/acp-16-11451-2016, https://doi.org/10.5194/acp-16-11451-2016, 2016
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In this study we have experimentally determined the infrared absorption cross sections of NF3 and CFC-115, calculated the radiative forcing and efficiency using two radiative transfer models and identified the effect of clouds and stratospheric adjustment. We have also determined their atmospheric lifetimes using the Whole Atmosphere Community Climate Model.
Tamás Kovács, John M. C. Plane, Wuhu Feng, Tibor Nagy, Martyn P. Chipperfield, Pekka T. Verronen, Monika E. Andersson, David A. Newnham, Mark A. Clilverd, and Daniel R. Marsh
Geosci. Model Dev., 9, 3123–3136, https://doi.org/10.5194/gmd-9-3123-2016, https://doi.org/10.5194/gmd-9-3123-2016, 2016
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This study was completed on D-region atmospheric model development. The sophisticated 3-D Whole Atmosphere Community Climate Model (WACCM) and the 1-D Sodynkalä Ion and Neutral Chemistry Model (SIC) were combined in order to provide a detailed, accurate model (WACCM-SIC) that considers the processes taking place in solar proton events. The original SIC model was reduced by mechanism reduction, which provided an accurate sub-mechanism (rSIC, WACCM-rSIC) of the original model.
Alexander D. Harrison, Thomas F. Whale, Michael A. Carpenter, Mark A. Holden, Lesley Neve, Daniel O'Sullivan, Jesus Vergara Temprado, and Benjamin J. Murray
Atmos. Chem. Phys., 16, 10927–10940, https://doi.org/10.5194/acp-16-10927-2016, https://doi.org/10.5194/acp-16-10927-2016, 2016
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Mineral dust particles are known to act as effective ice nucleating particles in the atmosphere and to play a role in the glaciation of mixed phase clouds. We have measured the ice nucleation activity of 15 different feldspar samples using a droplet freezing experiment and shown that alkali feldspars nucleate ice much more efficiently than plagioclase feldspars. We have also shown that certain "hyper-active" alkali feldspars nucleate ice very efficiently compared to typical alkali feldspars.
Daniel O'Sullivan, Benjamin J. Murray, James F. Ross, and Michael E. Webb
Atmos. Chem. Phys., 16, 7879–7887, https://doi.org/10.5194/acp-16-7879-2016, https://doi.org/10.5194/acp-16-7879-2016, 2016
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In the absence of particles which can trigger freezing, cloud droplets can exist in a supercooled liquid state well below the melting point. However, the sources of efficient ice-nucleating particles in the atmosphere are uncertain. Here we show that ice-nucleating proteins produced by soil fungi can bind to clay particles in soils. Hence, the subsequent dispersion of soil particles into the atmosphere acts as a route through which biological ice nucleators can influence clouds.
T. F. Whale, B. J. Murray, D. O'Sullivan, T. W. Wilson, N. S. Umo, K. J. Baustian, J. D. Atkinson, D. A. Workneh, and G. J. Morris
Atmos. Meas. Tech., 8, 2437–2447, https://doi.org/10.5194/amt-8-2437-2015, https://doi.org/10.5194/amt-8-2437-2015, 2015
N. S. Umo, B. J. Murray, M. T. Baeza-Romero, J. M. Jones, A. R. Lea-Langton, T. L. Malkin, D. O'Sullivan, L. Neve, J. M. C. Plane, and A. Williams
Atmos. Chem. Phys., 15, 5195–5210, https://doi.org/10.5194/acp-15-5195-2015, https://doi.org/10.5194/acp-15-5195-2015, 2015
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Combustion ash particles nucleate ice in the immersion mode at conditions relevant to mixed-phase clouds. Hence, combustion ashes could play an important role in primary ice formation in mixed-phase clouds, especially in clouds that are formed near the emission source of these aerosol particles. From this study, there is a need to quantify the atmospheric abundance of combustion ashes in order to quantitatively assess the impact of combustion ashes on mixed-phase clouds.
N. Hiranuma, S. Augustin-Bauditz, H. Bingemer, C. Budke, J. Curtius, A. Danielczok, K. Diehl, K. Dreischmeier, M. Ebert, F. Frank, N. Hoffmann, K. Kandler, A. Kiselev, T. Koop, T. Leisner, O. Möhler, B. Nillius, A. Peckhaus, D. Rose, S. Weinbruch, H. Wex, Y. Boose, P. J. DeMott, J. D. Hader, T. C. J. Hill, Z. A. Kanji, G. Kulkarni, E. J. T. Levin, C. S. McCluskey, M. Murakami, B. J. Murray, D. Niedermeier, M. D. Petters, D. O'Sullivan, A. Saito, G. P. Schill, T. Tajiri, M. A. Tolbert, A. Welti, T. F. Whale, T. P. Wright, and K. Yamashita
Atmos. Chem. Phys., 15, 2489–2518, https://doi.org/10.5194/acp-15-2489-2015, https://doi.org/10.5194/acp-15-2489-2015, 2015
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Seventeen ice nucleation measurement techniques contributed to investigate the immersion freezing behavior of illite NX. All data showed a similar temperature trend, but the measured ice nucleation activity was on average smaller for the wet suspended samples and higher for the dry-dispersed aerosol samples at high temperatures. A continued investigation and collaboration is necessary to obtain further insights into consistency or diversity of ice nucleation measurements.
M. P. Langowski, C. von Savigny, J. P. Burrows, W. Feng, J. M. C. Plane, D. R. Marsh, D. Janches, M. Sinnhuber, A. C. Aikin, and P. Liebing
Atmos. Chem. Phys., 15, 273–295, https://doi.org/10.5194/acp-15-273-2015, https://doi.org/10.5194/acp-15-273-2015, 2015
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Global concentration fields of Mg and Mg+ in the Earth's upper mesosphere and lower thermosphere (70-150km) are presented. These are retrieved from SCIAMACHY/Envisat satellite grating spectrometer measurements in limb viewing geometry between 2008 and 2012.
These were compared with WACCM-Mg model results and a large fraction of the available measurement results for these species, and an interpretation of the results is done. The variation of these species during NLC presence is discussed.
H. Berresheim, M. Adam, C. Monahan, C. O'Dowd, J. M. C. Plane, B. Bohn, and F. Rohrer
Atmos. Chem. Phys., 14, 12209–12223, https://doi.org/10.5194/acp-14-12209-2014, https://doi.org/10.5194/acp-14-12209-2014, 2014
Short summary
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Sulfuric acid plays a major role in the formation of aerosol particles and clouds. Measurements at the west coast of Ireland reveal that oxidation of SO2 by OH explains only 20%, on average, of H2SO4 formation in coastal marine air. Additional sources may be (a) oxidation by Criegee intermediates produced photolytically and/or (b) formation from SO3 instead of SO2 in the oxidation of dimethyl sulfide, suggesting an important role of marine emissions in the self-cleaning power of the atmosphere.
Y. J. Liu, J. M. C. Plane, B. R. Clemesha, J. H. Wang, and X. W. Cheng
Ann. Geophys., 32, 1321–1332, https://doi.org/10.5194/angeo-32-1321-2014, https://doi.org/10.5194/angeo-32-1321-2014, 2014
A. Spolaor, P. Vallelonga, J. Gabrieli, T. Martma, M. P. Björkman, E. Isaksson, G. Cozzi, C. Turetta, H. A. Kjær, M. A. J. Curran, A. D. Moy, A. Schönhardt, A.-M. Blechschmidt, J. P. Burrows, J. M. C. Plane, and C. Barbante
Atmos. Chem. Phys., 14, 9613–9622, https://doi.org/10.5194/acp-14-9613-2014, https://doi.org/10.5194/acp-14-9613-2014, 2014
R. J. Herbert, B. J. Murray, T. F. Whale, S. J. Dobbie, and J. D. Atkinson
Atmos. Chem. Phys., 14, 8501–8520, https://doi.org/10.5194/acp-14-8501-2014, https://doi.org/10.5194/acp-14-8501-2014, 2014
S. M. MacDonald, J. C. Gómez Martín, R. Chance, S. Warriner, A. Saiz-Lopez, L. J. Carpenter, and J. M. C. Plane
Atmos. Chem. Phys., 14, 5841–5852, https://doi.org/10.5194/acp-14-5841-2014, https://doi.org/10.5194/acp-14-5841-2014, 2014
H. C. Price, B. J. Murray, J. Mattsson, D. O'Sullivan, T. W. Wilson, K. J. Baustian, and L. G. Benning
Atmos. Chem. Phys., 14, 3817–3830, https://doi.org/10.5194/acp-14-3817-2014, https://doi.org/10.5194/acp-14-3817-2014, 2014
D. O'Sullivan, B. J. Murray, T. L. Malkin, T. F. Whale, N. S. Umo, J. D. Atkinson, H. C. Price, K. J. Baustian, J. Browse, and M. E. Webb
Atmos. Chem. Phys., 14, 1853–1867, https://doi.org/10.5194/acp-14-1853-2014, https://doi.org/10.5194/acp-14-1853-2014, 2014
A. Spolaor, J. Gabrieli, T. Martma, J. Kohler, M. B. Björkman, E. Isaksson, C. Varin, P. Vallelonga, J. M. C. Plane, and C. Barbante
The Cryosphere, 7, 1645–1658, https://doi.org/10.5194/tc-7-1645-2013, https://doi.org/10.5194/tc-7-1645-2013, 2013
A. Spolaor, P. Vallelonga, J. M. C. Plane, N. Kehrwald, J. Gabrieli, C. Varin, C. Turetta, G. Cozzi, R. Kumar, C. Boutron, and C. Barbante
Atmos. Chem. Phys., 13, 6623–6635, https://doi.org/10.5194/acp-13-6623-2013, https://doi.org/10.5194/acp-13-6623-2013, 2013
M. Rapp, J. M. C. Plane, B. Strelnikov, G. Stober, S. Ernst, J. Hedin, M. Friedrich, and U.-P. Hoppe
Ann. Geophys., 30, 1661–1673, https://doi.org/10.5194/angeo-30-1661-2012, https://doi.org/10.5194/angeo-30-1661-2012, 2012
A. S. Mahajan, J. C. Gómez Martín, T. D. Hay, S.-J. Royer, S. Yvon-Lewis, Y. Liu, L. Hu, C. Prados-Roman, C. Ordóñez, J. M. C. Plane, and A. Saiz-Lopez
Atmos. Chem. Phys., 12, 11609–11617, https://doi.org/10.5194/acp-12-11609-2012, https://doi.org/10.5194/acp-12-11609-2012, 2012
Related subject area
Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Stratosphere | Science Focus: Chemistry (chemical composition and reactions)
The importance of acid-processed meteoric smoke relative to meteoric fragments for crystal nucleation in polar stratospheric clouds
Heterogeneous reaction of HO2 with airborne TiO2 particles and its implication for climate change mitigation strategies
Evaporation of sulfate aerosols at low relative humidity
Heterogeneous kinetics of H2O, HNO3 and HCl on HNO3 hydrates (α-NAT, β-NAT, NAD) in the range 175–200 K
Complex chemical composition of colored surface films formed from reactions of propanal in sulfuric acid at upper troposphere/lower stratosphere aerosol acidities
Interactions of meteoric smoke particles with sulphuric acid in the Earth's stratosphere
Quantification of PM2.5 organic carbon sampling artifacts in US networks
Alexander D. James, Finn Pace, Sebastien N. F. Sikora, Graham W. Mann, John M. C. Plane, and Benjamin J. Murray
Atmos. Chem. Phys., 23, 2215–2233, https://doi.org/10.5194/acp-23-2215-2023, https://doi.org/10.5194/acp-23-2215-2023, 2023
Short summary
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Here, we examine whether several materials of meteoric origin can nucleate crystallisation in stratospheric cloud droplets which would affect ozone depletion. We find that material which could fragment on atmospheric entry without melting is unlikely to be present in high enough concentration in the stratosphere to contribute to observed crystalline clouds. Material which ablates completely then forms a new solid known as meteoric smoke can provide enough nucleation to explain observed clouds.
Daniel R. Moon, Giorgio S. Taverna, Clara Anduix-Canto, Trevor Ingham, Martyn P. Chipperfield, Paul W. Seakins, Maria-Teresa Baeza-Romero, and Dwayne E. Heard
Atmos. Chem. Phys., 18, 327–338, https://doi.org/10.5194/acp-18-327-2018, https://doi.org/10.5194/acp-18-327-2018, 2018
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One geoengineering mitigation strategy for global temperature rises is to inject particles into the stratosphere to scatter solar radiation back to space. However, the injection of such particles must not perturb ozone. We measured the rate of uptake of HO2 radicals, an important stratospheric intermediate, onto TiO2 particles. Using the atmospheric model TOMCAT, we showed that surface reactions between HO2 and TiO2 would have a negligible effect on stratospheric concentrations of HO2 and ozone.
Georgios Tsagkogeorgas, Pontus Roldin, Jonathan Duplissy, Linda Rondo, Jasmin Tröstl, Jay G. Slowik, Sebastian Ehrhart, Alessandro Franchin, Andreas Kürten, Antonio Amorim, Federico Bianchi, Jasper Kirkby, Tuukka Petäjä, Urs Baltensperger, Michael Boy, Joachim Curtius, Richard C. Flagan, Markku Kulmala, Neil M. Donahue, and Frank Stratmann
Atmos. Chem. Phys., 17, 8923–8938, https://doi.org/10.5194/acp-17-8923-2017, https://doi.org/10.5194/acp-17-8923-2017, 2017
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The H2SO4 vapour pressure plays key role in Earth's and Venus' atmospheres. In regions where RH is low and stabilising bases are scarce, H2SO4 can evaporate from particles; however the H2SO4 vapour pressure at low RH is uncertain. To address this, we measured H2SO4 evaporation versus T and RH in the CLOUD chamber and constrained the equilibrium constants for dissociation and dehydration of H2SO4. This study is important for nucleation, particle growth and H2SO4 formation occurring in atmosphere.
Riccardo Iannarelli and Michel J. Rossi
Atmos. Chem. Phys., 16, 11937–11960, https://doi.org/10.5194/acp-16-11937-2016, https://doi.org/10.5194/acp-16-11937-2016, 2016
Short summary
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Both adsorption and evaporation kinetics of water, nitric acid and hydrochloric acid on nitric acid hydrates were measured under upper tropospheric/lower stratospheric conditions. The evaporative lifetimes of "contaminated" ice clouds are important parameters for heterogeneous processing controlling polar ozone in the winter/spring season ("ozone hole"). We measured both the adsorption and evaporation kinetics, resulting in the corresponding vapor pressure as a validity check of the results.
A. L. Van Wyngarden, S. Pérez-Montaño, J. V. H. Bui, E. S. W. Li, T. E. Nelson, K. T. Ha, L. Leong, and L. T. Iraci
Atmos. Chem. Phys., 15, 4225–4239, https://doi.org/10.5194/acp-15-4225-2015, https://doi.org/10.5194/acp-15-4225-2015, 2015
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We have observed the formation of colored organic surface films on solutions of propanal and sulfuric acid at acidities chosen to mimic the highly acidic aerosols in the upper troposphere and lower stratosphere. The films were found to be composed of aldol condensation products and polyacetals. If such species also form coatings on atmospheric aerosols, they could impact climate by changing the chemical, optical and cloud-forming properties of aerosols.
R. W. Saunders, S. Dhomse, W. S. Tian, M. P. Chipperfield, and J. M. C. Plane
Atmos. Chem. Phys., 12, 4387–4398, https://doi.org/10.5194/acp-12-4387-2012, https://doi.org/10.5194/acp-12-4387-2012, 2012
J. C. Chow, J. G. Watson, L.-W. A. Chen, J. Rice, and N. H. Frank
Atmos. Chem. Phys., 10, 5223–5239, https://doi.org/10.5194/acp-10-5223-2010, https://doi.org/10.5194/acp-10-5223-2010, 2010
Cited articles
Bardeen, C. G., Toon, O. B., Jensen, E. J., Marsh, D. R., and Harvey, V. L.:
Numerical simulations of the three-dimensional distribution of meteoric dust
in the mesosphere and upper stratosphere, J. Geophys. Res.-Atmos., 113,
D17202, https://doi.org/10.1029/2007JD009515, 2008.
Beyer, K. D. and Hansen, A. R.: Phase diagram of the nitric acid/water
system:? implications for polar stratospheric clouds, J. Phys. Chem. A, 106,
10275–10284, https://doi.org/10.1021/jp025535o, 2002.
Biermann, U. M., Presper, T., Koop, T., Mößinger, J., Crutzen, P. J.,
and Peter, T.: The unsuitability of meteoritic and other nuclei for polar
stratospheric cloud freezing, Geophys. Res. Lett., 23, 1693–1696, https://doi.org/10.1029/96gl01577, 1996.
Bogdan, A., Molina, M. J., Kulmala, M., MacKenzie, A. R., and Laaksonen, A.:
Study of finely divided aqueous systems as an aid to understanding the
formation mechanism of polar stratospheric clouds: Case of HNO3/H2O
and H2SO4/H2O systems, J. Geophys. Res.-Atmos., 108, 4302, https://doi.org/10.1029/2002JD002605, 2003.
Brakebusch, M., Randall, C. E., Kinnison, D. E., Tilmes, S., Santee, M. L.,
and Manney, G. L.: Evaluation of Whole Atmosphere Community Climate Model
simulations of ozone during Arctic winter 2004–2005, J. Geophy. Res.-Atmos., 118, 2673–2688,
https://doi.org/10.1002/jgrd.50226, 2013.
Broadley, S. L., Murray, B. J., Herbert, R. J., Atkinson, J. D., Dobbie, S.,
Malkin, T. L., Condliffe, E., and Neve, L.: Immersion mode heterogeneous ice
nucleation by an illite rich powder representative of atmospheric mineral
dust, Atmos. Chem. Phys., 12, 287–307,
https://doi.org/10.5194/acp-12-287-2012, 2012.
Brooke, J. S. A., Feng, W., Carrillo-Sánchez, J. D., Mann, G. W., James,
A. D., Bardeen, C. G., and Plane, J. M. C.: Meteoric smoke deposition in the
polar regions: A comparison of measurements with global atmospheric models,
J. Geophys. Res.-Atmos., 122, 11112–111130, https://doi.org/10.1002/2017JD027143, 2017.
Carrillo-Sánchez, J. D., Nesvorný, D., Pokorný, P., Janches, D.,
and Plane, J. M. C.: Sources of cosmic dust in the Earth's atmosphere,
Geophys. Res. Lett., 43, 11979–11986, https://doi.org/10.1002/2016GL071697, 2016.
Clarke, R., Jarosevich, E., Mason, B., Nelen, J., Gomez, M., and Hyde, J. R.:
The Allende, Mexico, Meteoroite Shower, Smithsonian Institution Press,
Washington, 1971.
Clegg, S. L., Brimblecombe, P., and Wexler, A. S.: Thermodynamic model of the
system H+-NH
Cziczo, D. J., Thomson, D. S., and Murphy, D. M.: Ablation, flux, and
atmospheric implications of meteors inferred from stratospheric aerosol,
Science, 291, 1772–1775, https://doi.org/10.1126/science.1057737, 2001.
Dhomse, S. S., Saunders, R. W., Tian, W., Chipperfield, M. P., and Plane, J.
M. C.: Plutonium-238 observations as a test of modeled transport and surface
deposition of meteoric smoke particles, Geophys. Res. Lett., 40, 4454–4458,
2013.
Frankland, V. L., James, A. D., Feng, W., and Plane, J. M. C.: The uptake of
HNO3 on meteoric smoke analogues, J. Atmos. Sol.-Terr. Phy., 127,
150–160, https://doi.org/10.1016/j.jastp.2015.01.010, 2015.
Gómez-Martín, J. C., Bones, D. L., Carrillo-Sánchez, J. D.,
James, A. D., Trigo-Rodríguez, J. M., B. Fegley, J., and Plane, J. M.
C.: Novel experimental simulations of the atmospheric injection of meteoric
metals, Astrophys. J., 836, 212–238, 2017.
Grothe, H., Tizek, H., and Ortega, I. K.: Metastable nitric acid
hydrates-possible constituents of polar stratospheric clouds?, Faraday
Discss., 137, 223–234, 2008.
Harrison, A. D., Whale, T. F., Carpenter, M. A., Holden, M. A., Neve, L.,
O'Sullivan, D., Vergara Temprado, J., and Murray, B. J.: Not all feldspars
are equal: a survey of ice nucleating properties across the feldspar group of
minerals, Atmos. Chem. Phys., 16, 10927–10940,
https://doi.org/10.5194/acp-16-10927-2016, 2016.
Herbert, R. J., Murray, B. J., Whale, T. F., Dobbie, S. J., and Atkinson, J.
D.: Representing time-dependent freezing behaviour in immersion mode ice
nucleation, Atmos. Chem. Phys., 14, 8501–8520,
https://doi.org/10.5194/acp-14-8501-2014, 2014.
Hiranuma, N., Hoffmann, N., Kiselev, A., Dreyer, A., Zhang, K., Kulkarni, G.,
Koop, T., and Möhler, O.: Influence of surface morphology on the immersion
mode ice nucleation efficiency of hematite particles, Atmos. Chem. Phys., 14,
2315–2324, https://doi.org/10.5194/acp-14-2315-2014, 2014.
Hiranuma, N., Augustin-Bauditz, S., Bingemer, H., Budke, C., Curtius, J.,
Danielczok, A., Diehl, K., Dreischmeier, K., Ebert, M., Frank, F., Hoffmann,
N., Kandler, K., Kiselev, A., Koop, T., Leisner, T., Möhler, O., Nillius,
B., Peckhaus, A., Rose, D., Weinbruch, S., Wex, H., Boose, Y., DeMott, P. J.,
Hader, J. D., Hill, T. C. J., Kanji, Z. A., Kulkarni, G., Levin, E. J. T.,
McCluskey, C. S., Murakami, M., Murray, B. J., Niedermeier, D., Petters, M.
D., O'Sullivan, D., Saito, A., Schill, G. P., Tajiri, T., Tolbert, M. A.,
Welti, A., Whale, T. F., Wright, T. P., and Yamashita, K.: A comprehensive
laboratory study on the immersion freezing behavior of illite NX particles: a
comparison of 17 ice nucleation measurement techniques, Atmos. Chem. Phys.,
15, 2489–2518, https://doi.org/10.5194/acp-15-2489-2015, 2015.
Höpfner, M., Luo, B. P., Massoli, P., Cairo, F., Spang, R., Snels, M., Di
Donfrancesco, G., Stiller, G., von Clarmann, T., Fischer, H., and Biermann,
U.: Spectroscopic evidence for NAT, STS, and ice in MIPAS infrared limb
emission measurements of polar stratospheric clouds, Atmos. Chem. Phys., 6,
1201–1219, https://doi.org/10.5194/acp-6-1201-2006, 2006.
Hoyle, C. R., Engel, I., Luo, B. P., Pitts, M. C., Poole, L. R., Grooß,
J.-U., and Peter, T.: Heterogeneous formation of polar stratospheric clouds
– Part 1: Nucleation of nitric acid trihydrate (NAT), Atmos. Chem. Phys.,
13, 9577–9595, https://doi.org/10.5194/acp-13-9577-2013, 2013.
Iannarelli, R. and Rossi, M. J.: The mid-IR absorption cross sections of
α- and β-NAT (HNO3 ⋅ 3H2O) in the range 170 to
185 K and of metastable NAD (HNO3 ⋅ 2H2O) in the range 172 to
182 K, J. Geophys. Res.-Atmos., 120, 11707–11727, https://doi.org/10.1002/2015JD023903,
2015.
James, A. D., Frankland, V. L. F., Trigo-Rodríguez, J. M.,
Alonso-Azcárate, J., Gómez Martín, J.-C., and Plane, J. M. C.:
Synthesis and characterisation of analogues for interplanetary dust and
meteoric smoke particles, J. Atmos. Sol.-Terr. Phy., 162, 178–191,
https://doi.org/10.1016/j.jastp.2016.08.011, 2017.
James, A. D., Brooke, J. S. A.,
Mangan, T. P., Whale, T. F., Plane, J. M. C., and
Murray, B. J.: Numerical data pertaining to “Nucleation of nitric acid hydrates
in polar stratospheric clouds by meteoric material”, University of Leeds research data management,
available at: https://doi.org/10.5518/312, last access:
3 April 2018.
Jessberger, E. K., Stephan, T., Rost, D., Arndt, P., Maetz, M., Stadermann,
F. J., Brownlee, D. E., Bradley, J. P., and Kurat, G.: Properties of
interplanetary dust: information from collected samples, in: Interplanetary
Dust, edited by: Grün, E., Gustafson, B. Å. S., Dermott, S., and
Fechtig, H., Springer Berlin Heidelberg, Berlin, Heidelberg, 253–294, 2001.
Knopf, D. A.: Do NAD and NAT form in liquid stratospheric aerosols by
pseudoheterogeneous nucleation?, J. Phys. Chem. A, 110, 5745–5750,
https://doi.org/10.1021/jp055376j, 2006.
Knopf, D. A., Koop, T., Luo, B. P., Weers, U. G., and Peter, T.: Homogeneous
nucleation of NAD and NAT in liquid stratospheric aerosols: insufficient to
explain denitrification, Atmos. Chem. Phys., 2, 207–214,
https://doi.org/10.5194/acp-2-207-2002, 2002.
Lambert, A., Santee, M. L., and Livesey, N. J.: Interannual variations of
early winter Antarctic polar stratospheric cloud formation and nitric acid
observed by CALIOP and MLS, Atmos. Chem. Phys., 16, 15219–15246,
https://doi.org/10.5194/acp-16-15219-2016, 2016.
Mann, G. W., Carslaw, K. S., Chipperfield, M. P., Davies, S., and Eckermann,
S. D.: Large nitric acid trihydrate particles and denitrification caused by
mountain waves in the Arctic stratosphere, J. Geophys. Res.-Atmos., 110,
D08202, https://doi.org/10.1029/2004JD005271, 2005.
Marsh, D. R., Mills, M. J., Kinnison, D. E., Lamarque, J. F., Calvo, N., and
Polvani, L. M.: Climate Change from 1850 to 2005 Simulated in CESM1 (WACCM),
J. Climate, 26, 7372–7391, https://doi.org/10.1175/jcli-d-12-00558.1, 2013.
Martin, S. T.: Phase transitions of aqueous atmospheric particles, Chem.
Rev., 100, 3403–3454, https://doi.org/10.1021/cr990034t, 2000.
Meilinger, S. K., Koop, T., Luo, B. P., Huthwelker, T., Carslaw, K. S.,
Krieger, U., Crutzen, P. J., and Peter, T.: Size-dependent stratospheric
droplet composition in Lee wave temperature fluctuations and their potential
role in PSC freezing, Geophys. Res. Lett., 22, 3031–3034,
https://doi.org/10.1029/95GL03056, 1995.
Möhler, O., Bunz, H., and Stetzer, O.: Homogeneous nucleation rates of
nitric acid dihydrate (NAD) at simulated stratospheric conditions – Part II:
Modelling, Atmos. Chem. Phys., 6, 3035–3047,
https://doi.org/10.5194/acp-6-3035-2006, 2006.
Murphy, D. M., Froyd, K. D., Schwarz, J. P., and Wilson, J. C.: Observations
of the chemical composition of stratospheric aerosol particles, Q. J. Roy. Meteor. Soc., 140, 1269–1278, 2014.
Murray, B. J. and Bertram, A. K.: Inhibition of solute crystallisation in
aqueous H+-NH4+-SO
Murray, B. J., O'Sullivan, D., Atkinson, J. D., and Webb, M. E.: Ice
nucleation by particles immersed in supercooled cloud droplets, Chem. Soc.
Rev., 41, 6519–6554, https://doi.org/10.1039/C2CS35200A, 2012.
Neely, R. R., English, J. M., Toon, O. B., Solomon, S., Mills, M., and
Thayer, J. P.: Implications of extinction due to meteoritic smoke in the
upper stratosphere, Geophys. Res. Lett., 38, L24808, https://doi.org/10.1029/2011gl049865,
2011.
Niedermeier, D., Hartmann, S., Clauss, T., Wex, H., Kiselev, A., Sullivan, R.
C., DeMott, P. J., Petters, M. D., Reitz, P., Schneider, J., Mikhailov, E.,
Sierau, B., Stetzer, O., Reimann, B., Bundke, U., Shaw, R. A., Buchholz, A.,
Mentel, T. F., and Stratmann, F.: Experimental study of the role of
physicochemical surface processing on the IN ability of mineral dust
particles, Atmos. Chem. Phys., 11, 11131–11144,
https://doi.org/10.5194/acp-11-11131-2011, 2011.
Peter, T. and Grooß, J. U.: Polar stratospheric clouds and sulfate
aerosol particles: Microphysics, denitrification and heterogeneous chemistry,
Chapter 4, in: Stratospheric Ozone Depletion and Climate Change, edited by:
Muller, R., The Royal Society of Chemistry,
Cambridge, UK, 108–144, 2012.
Plane, J. M. C., Feng, W., and Dawkins, E. C. M.: The mesosphere and metals:
Chemistry and changes, Chem. Rev., 115, 4497–4541, https://doi.org/10.1021/cr500501m,
2015.
Pruppacher, H. R. and Klett, J. D.: Microphysics of clouds and precipitation,
D. Reidel Publishing Company, Dordrecht,
Holland, 1978.
Rienecker, M. M., Suarez, M. J., Gelaro, R., Todling, R., Bacmeister, J.,
Liu, E., Bosilovich, M. G., Schubert, S. D., Takacs, L., Kim, G. K., Bloom,
S., Chen, J. Y., Collins, D., Conaty, A., Da Silva, A., Gu, W., Joiner, J.,
Koster, R. D., Lucchesi, R., Molod, A., Owens, T., Pawson, S., Pegion, P.,
Redder, C. R., Reichle, R., Robertson, F. R., Ruddick, A. G., Sienkiewicz,
M., and Woollen, J.: MERRA: NASA's Modern-Era Retrospective Analysis for
Research and Applications, J. Climate, 24, 3624–3648,
https://doi.org/10.1175/jcli-d-11-00015.1, 2011.
Russell, S. S., Zolensky, M., Righter, K., Folco, L., Jones, R., Connolly, H.
C., Grady, M. M., and Grossman, J. N.: The meteoritical bulletin, No. 89,
2005 September, Meteorit. Plan. Sci., 40, A201–A263,
https://doi.org/10.1111/j.1945-5100.2005.tb00425.x, 2005.
Saunders, R. W. and Plane, J. M. C.: A laboratory study of meteor smoke
analogues: Composition, optical properties and growth kinetics, J. Atmos.
Sol.-Terr. Phy., 68, 2182–2202,
https://doi.org/10.1016/j.jastp.2006.09.006, 2006.
Saunders, R. W., Dhomse, S., Tian, W. S., Chipperfield, M. P., and Plane, J.
M. C.: Interactions of meteoric smoke particles with sulphuric acid in the
Earth's stratosphere, Atmos. Chem. Phys., 12, 4387–4398,
https://doi.org/10.5194/acp-12-4387-2012, 2012.
Solomon, S.: Stratospheric ozone depletion: A review of concepts and history,
Rev. Geophys., 37, 275–316, https://doi.org/10.1029/1999RG900008, 1999.
Solomon, S., Kinnison, D., Bandoro, J., and Garcia, R.: Simulation of polar
ozone depletion: An update, J. Geophys. Res.-Atmos., 120, 7958–7974,
https://doi.org/10.1002/2015JD023365, 2015.
Stetzer, O., Möhler, O., Wagner, R., Benz, S., Saathoff, H., Bunz, H., and
Indris, O.: Homogeneous nucleation rates of nitric acid dihydrate (NAD) at
simulated stratospheric conditions – Part I: Experimental results, Atmos.
Chem. Phys., 6, 3023–3033, https://doi.org/10.5194/acp-6-3023-2006, 2006.
Subasinghe, D., Campbell-Brown, M. D., and Stokan, E.: Physical
characteristics of faint meteors by light curve and high-resolution
observations, and the implications for parent bodies, Mon. Not. Royal Astro.
Soc., 457, 1289–1298, 2016.
Taylor, S., Matrajt, G., and Guan, Y.: Fine-grained precursors dominate the
micrometeorite flux, Meteorit. Planet. Sci., 47, 550–564,
https://doi.org/10.1111/j.1945-5100.2011.01292.x, 2012.
Toon, O. B., Turco, R. P., Hamill, P., Kiang, C. S., and Whitten, R. C.:
One-dimensional model describing aerosol formation and evolution in the
stratosphere. 2. Sensitivity studies and comparison with observations, J.
Atmos. Sci., 36, 718–736,
https://doi.org/10.1175/1520-0469(1979)036<0718:aodmda>2.0.co;2, 1979.
Toon, O. B., Turco, R. P., Westphal, D., Malone, R., and Liu, M.: A
Multidimensional Model for Aerosols: Description of Computational Analogs, J.
Atmos. Sci., 45, 2123–2144,
https://doi.org/10.1175/1520-0469(1988)045<2123:ammfad>2.0.co;2, 1988.
Turco, R. P., Hamill, P., Toon, O. B., Whitten, R. C., and Kiang, C. S.:
One-dimensional model describing aerosol formation and evolution in the
stratosphere. 1. Physical processes and mathematical analogs, J. Atmos. Sci.,
36, 699–717,
https://doi.org/10.1175/1520-0469(1979)036<0699:aodmda>2.0.co;2, 1979.
Voigt, C., Schlager, H., Luo, B. P., Dörnbrack, A., Roiger, A., Stock, P.,
Curtius, J., Vössing, H., Borrmann, S., Davies, S., Konopka, P., Schiller,
C., Shur, G., and Peter, T.: Nitric Acid Trihydrate (NAT) formation at low
NAT supersaturation in Polar Stratospheric Clouds (PSCs), Atmos. Chem. Phys.,
5, 1371–1380, https://doi.org/10.5194/acp-5-1371-2005, 2005.
Wegner, T., Grooß, J.-U., von Hobe, M., Stroh, F., Suminska-Ebersoldt,
O., Volk, C. M., Hösen, E., Mitev, V., Shur, G., and Müller, R.:
Heterogeneous chlorine activation on stratospheric aerosols and clouds in the
Arctic polar vortex, Atmos. Chem. Phys., 12, 11095–11106,
https://doi.org/10.5194/acp-12-11095-2012, 2012.
Weigel, R., Volk, C. M., Kandler, K., Hösen, E., Günther, G., Vogel, B.,
Grooß, J.-U., Khaykin, S., Belyaev, G. V., and Borrmann, S.: Enhancements
of the refractory submicron aerosol fraction in the Arctic polar vortex:
feature or exception?, Atmos. Chem. Phys., 14, 12319–12342,
https://doi.org/10.5194/acp-14-12319-2014, 2014.
Weisberg, M. K., Smith, C., Benedix, G., Folco, L., Righter, K., Zipfel, J.,
Yamaguchi, A., and Aoudjehane, H. C.: The Meteoritical Bulletin, No. 94,
September 2008, Meteorit. Planet. Sci., 43, 1551–1584,
https://doi.org/10.1111/j.1945-5100.2008.tb01027.x, 2008.
Weiss, F., Kubel, F., Gálvez, Ó., Hoelzel, M., Parker, S. F., Baloh,
P., Iannarelli, R., Rossi, M. J., and Grothe, H.: Metastable nitric acid
trihydrate in ice clouds, Angew. Chem. Int. Ed., 55, 3276–3280,
https://doi.org/10.1002/anie.201510841, 2016.
Whale, T. F., Murray, B. J., O'Sullivan, D., Wilson, T. W., Umo, N. S.,
Baustian, K. J., Atkinson, J. D., Workneh, D. A., and Morris, G. J.: A
technique for quantifying heterogeneous ice nucleation in microlitre
supercooled water droplets, Atmos. Meas. Tech., 8, 2437–2447,
https://doi.org/10.5194/amt-8-2437-2015, 2015.
Whale, T. F., Holden, M. A., Kulak, A. N., Kim, Y. Y., Meldrum, F. C.,
Christenson, H. K., and Murray, B. J.: The role of phase separation and
related topography in the exceptional ice-nucleating ability of alkali
feldspars, Phys. Chem. Chem. Phys., 19, 31186–31193,
https://doi.org/10.1039/C7CP04898J, 2017.
Wise, M. E., Brooks, S. D., Garland, R. M., Cziczo, D. J., Martin, S. T., and
Tolbert, M. A.: Solubility and freezing effects of Fe2+ and Mg2+ in
H2SO4 solutions representative of upper tropospheric and lower
stratospheric sulfate particles, J. Geophys. Res.-Atmos., 108, 4434, https://doi.org/10.1029/2003JD003420, 2003.
Short summary
Crystal nucleation in polar stratospheric clouds (PSCs) has a direct impact on stratospheric chemistry and ozone. However, the mechanism of nucleation has been unclear for decades, limiting prediction of the response of ozone to atmospheric changes. We experimentally demonstrate that meteoric material can trigger nucleation heterogeneously and this can produce observed crystal concentrations in PSCs. This discovery paves the way to robust modelling of past and future trends in PSCs and ozone.
Crystal nucleation in polar stratospheric clouds (PSCs) has a direct impact on stratospheric...
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