Articles | Volume 14, issue 22
https://doi.org/10.5194/acp-14-12055-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-14-12055-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
17 Nov 2014
Research article |
| 17 Nov 2014
The impact of aerosol hygroscopic growth on the single-scattering albedo and its application on the NO2 photolysis rate coefficient
J. C. Tao
Department of Atmospheric and Oceanic Sciences, School of Physics, Peking University, Beijing, China
C. S. Zhao
CORRESPONDING AUTHOR
Department of Atmospheric and Oceanic Sciences, School of Physics, Peking University, Beijing, China
N. Ma
Department of Atmospheric and Oceanic Sciences, School of Physics, Peking University, Beijing, China
Leibniz Institute for Tropospheric Research, Leipzig, Germany
P. F. Liu
Department of Atmospheric and Oceanic Sciences, School of Physics, Peking University, Beijing, China
School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA
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A novel approach is proposed in this research to derive the aerosol hygroscopicity parameter based only on measurements from a humidified nephelometer system without any additional information about particle number size distribution and black carbon. New findings in this research can bridge the gap between κ-Köhler theory and the aerosol light-scattering enhancement factor and will make the humidified nephelometer system more convenient when it comes to aerosol hygroscopicity research.
Nan Ma, Chunsheng Zhao, Jiangchuan Tao, Zhijun Wu, Simonas Kecorius, Zhibin Wang, Johannes Größ, Hongjian Liu, Yuxuan Bian, Ye Kuang, Monique Teich, Gerald Spindler, Konrad Müller, Dominik van Pinxteren, Hartmut Herrmann, Min Hu, and Alfred Wiedensohler
Atmos. Chem. Phys., 16, 8593–8607, https://doi.org/10.5194/acp-16-8593-2016, https://doi.org/10.5194/acp-16-8593-2016, 2016
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New particle formation (NPF) is one of main sources of cloud condensation nuclei (CCN) in the atmosphere. Based on in situ measurements, we found that CCN activity of newly formed particles largely differs in different NPF events. It is therefore difficult to find a simple parameterization of CCN activity for NPF events. Using a fixed size-resolved activation ratio curve or critical diameter is very likely to result in large biases up to 50 % in the calculated NCCN during NPF events.
Y. Kuang, C. S. Zhao, J. C. Tao, and N. Ma
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Our study shows that the optical properties of brown carbon depend on its source. Brown carbon from ozone pollution had the weakest light absorption but the strongest wavelength dependence, while biomass burning brown carbon showed the strongest absorption and the weakest wavelength dependence. Nitrogen-containing organic carbon compounds were identified as key light absorbers. These results improve understanding of brown carbon sources and help refine climate models.
Bishuo He and Chunsheng Zhao
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Factor uncertainty analysis helps us understand the impacts of factors on complex systems. Traditional methods have many limitations. This study introduces a new method to measure how each factor contributes to uncertainty. It gains insights into the role of each variable and works for all multi-factor systems. As an application, we analyzed how aerosols affect solar radiation and identified the key factors. These analyses can improve our understanding of the role of aerosols in climate change.
Jingnan Shi, Zhisheng Zhang, Li Li, Li Liu, Yaqing Zhou, Shuang Han, Shaobin Zhang, Minghua Liang, Linhong Xie, Weikang Ran, Shaowen Zhu, Hanbing Xu, Jiangchuan Tao, Alfred Wiedensohler, Qiaoqiao Wang, Qiyuan Wang, Nan Ma, and Juan Hong
EGUsphere, https://doi.org/10.5194/egusphere-2025-2643, https://doi.org/10.5194/egusphere-2025-2643, 2025
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Lifei Yin, Yiqi Zheng, Bin Bai, Bingqing Zhang, Rachel Silvern, Jingqiu Mao, Loretta Mickley, and Pengfei Liu
EGUsphere, https://doi.org/10.5194/egusphere-2025-2872, https://doi.org/10.5194/egusphere-2025-2872, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Chengyi Fan, Bishuo He, Shuqi Guo, Jie Qiu, and Chunsheng Zhao
Atmos. Chem. Phys., 25, 5761–5771, https://doi.org/10.5194/acp-25-5761-2025, https://doi.org/10.5194/acp-25-5761-2025, 2025
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Zheng Yang, Qiaoqiao Wang, Qiyuan Wang, Nan Ma, Jie Tian, Yaqing Zhou, Ge Xu, Miao Gao, Xiaoxian Zhou, Yang Zhang, Weikang Ran, Ning Yang, Jiangchuan Tao, Juan Hong, Yunfei Wu, Junji Cao, Hang Su, and Yafang Cheng
EGUsphere, https://doi.org/10.5194/egusphere-2025-1020, https://doi.org/10.5194/egusphere-2025-1020, 2025
Short summary
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Our results demonstrate that the reduction in mass absorption efficiency from biomass burning is mainly driven by the decline in the imaginary part, with particle size playing a minor role. And light absorption of oxygenated BrC increases significantly with aging, but hydrocarbon-like BrC decrease over time. These results emphasize the necessity to classify BrC into different groups based on their mass absorption efficiency and atmospheric behavior in climate models.
Ye Kuang, Jiangchuan Tao, Hanbing Xu, Li Liu, Pengfei Liu, Wanyun Xu, Weiqi Xu, Yele Sun, and Chunsheng Zhao
Atmos. Chem. Phys., 25, 1163–1174, https://doi.org/10.5194/acp-25-1163-2025, https://doi.org/10.5194/acp-25-1163-2025, 2025
Short summary
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This study presents a novel optical framework to measure supersaturation, a fundamental parameter in cloud physics, by observing the scattering properties of particles that have or have not grown into cloud droplets. The technique offers high-resolution measurements, capturing essential fluctuations in supersaturation necessary for understanding cloud physics.
Weiqi Xu, Ye Kuang, Wanyun Xu, Zhiqiang Zhang, Biao Luo, Xiaoyi Zhang, Jiangchuang Tao, Hongqin Qiao, Li Liu, and Yele Sun
Atmos. Chem. Phys., 24, 9387–9399, https://doi.org/10.5194/acp-24-9387-2024, https://doi.org/10.5194/acp-24-9387-2024, 2024
Short summary
Short summary
We deployed an advanced aerosol–fog sampling system at a rural site in the North China Plain to investigate impacts of aerosol hygroscopic growth and activation on the physicochemical properties of submicron aerosols. Observed results highlighted remarkably different aqueous processing of primary and secondary submicron aerosol components under distinct ambient relative humidity (RH) conditions and that RH levels significantly impact aerosol sampling through the aerosol swelling effect.
Jiangchuan Tao, Biao Luo, Weiqi Xu, Gang Zhao, Hanbin Xu, Biao Xue, Miaomiao Zhai, Wanyun Xu, Huarong Zhao, Sanxue Ren, Guangsheng Zhou, Li Liu, Ye Kuang, and Yele Sun
Atmos. Chem. Phys., 24, 9131–9154, https://doi.org/10.5194/acp-24-9131-2024, https://doi.org/10.5194/acp-24-9131-2024, 2024
Short summary
Short summary
Using simultaneous measurements of DMA–CCNC, H(/V)TDMA, and DMA–SP2, impacts of primary emissions and secondary aerosol formations on changes in aerosol physicochemical properties were comprehensively investigated. It was found that intercomparisons among aerosol mixing-state parameters derived from different techniques can help us gain more insight into aerosol physical properties which, in turn, will aid the investigation of emission characteristics and secondary aerosol formation pathways.
Meghna Soni, Rolf Sander, Lokesh K. Sahu, Domenico Taraborrelli, Pengfei Liu, Ankit Patel, Imran A. Girach, Andrea Pozzer, Sachin S. Gunthe, and Narendra Ojha
Atmos. Chem. Phys., 23, 15165–15180, https://doi.org/10.5194/acp-23-15165-2023, https://doi.org/10.5194/acp-23-15165-2023, 2023
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The study presents the implementation of comprehensive multiphase chlorine chemistry in the box model CAABA/MECCA. Simulations for contrasting urban environments of Asia and Europe highlight the significant impacts of chlorine on atmospheric oxidation capacity and composition. Chemical processes governing the production and loss of chlorine-containing species has been discussed. The updated chemical mechanism will be useful to interpret field measurements and for future air quality studies.
Weilun Zhao, Ying Li, Gang Zhao, Song Guo, Nan Ma, Shuya Hu, and Chunsheng Zhao
Atmos. Chem. Phys., 23, 14889–14902, https://doi.org/10.5194/acp-23-14889-2023, https://doi.org/10.5194/acp-23-14889-2023, 2023
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Studies have concentrated on particles containing black carbon (BC) smaller than 700 nm because of technical limitations. In this study, BC-containing particles larger than 700 nm (BC>700) were measured, highlighting their importance to total BC mass and absorption. The contribution of BC>700 to the BC direct radiative effect was estimated, highlighting the necessity to consider the whole size range of BC-containing particles in the model estimation of BC radiative effects.
Xurong Wang, Qiaoqiao Wang, Maria Prass, Christopher Pöhlker, Daniel Moran-Zuloaga, Paulo Artaxo, Jianwei Gu, Ning Yang, Xiajie Yang, Jiangchuan Tao, Juan Hong, Nan Ma, Yafang Cheng, Hang Su, and Meinrat O. Andreae
Atmos. Chem. Phys., 23, 9993–10014, https://doi.org/10.5194/acp-23-9993-2023, https://doi.org/10.5194/acp-23-9993-2023, 2023
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In this work, with an optimized particle mass size distribution, we captured observed aerosol optical depth (AOD) and coarse aerosol concentrations over source and/or receptor regions well, demonstrating good performance in simulating export of African dust toward the Amazon Basin. In addition to factors controlling the transatlantic transport of African dust, the study investigated the impact of African dust over the Amazon Basin, including the nutrient inputs associated with dust deposition.
Juan Hong, Min Tang, Qiaoqiao Wang, Nan Ma, Shaowen Zhu, Shaobin Zhang, Xihao Pan, Linhong Xie, Guo Li, Uwe Kuhn, Chao Yan, Jiangchuan Tao, Ye Kuang, Yao He, Wanyun Xu, Runlong Cai, Yaqing Zhou, Zhibin Wang, Guangsheng Zhou, Bin Yuan, Yafang Cheng, and Hang Su
Atmos. Chem. Phys., 23, 5699–5713, https://doi.org/10.5194/acp-23-5699-2023, https://doi.org/10.5194/acp-23-5699-2023, 2023
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A comprehensive investigation of the characteristics of new particle formation (NPF) events was conducted at a rural site on the North China Plain (NCP), China, during the wintertime of 2018 by covering the particle number size distribution down to sub–3 nm. Potential mechanisms for NPF under the current environment were explored, followed by a further discussion on the factors governing the occurrence of NPF at this rural site compared with other regions (e.g., urban areas) in the NCP region.
Miaomiao Zhai, Ye Kuang, Li Liu, Yao He, Biao Luo, Wanyun Xu, Jiangchuan Tao, Yu Zou, Fei Li, Changqin Yin, Chunhui Li, Hanbing Xu, and Xuejiao Deng
Atmos. Chem. Phys., 23, 5119–5133, https://doi.org/10.5194/acp-23-5119-2023, https://doi.org/10.5194/acp-23-5119-2023, 2023
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Using year-long aerosol mass spectrometer measurements, roles of secondary organic aerosols (SOA) during haze formations in an urban area of southern China were systematically analyzed. Almost all severe haze events were accompanied by continuous daytime and nighttime SOA formations, whereas coordinated gas-phase photochemistry and aqueous-phase reactions likely played significant roles in quick daytime SOA formations, and nitrate radicals played significant roles in nighttime SOA formations.
Liang Yuan and Chunsheng Zhao
Atmos. Chem. Phys., 23, 3195–3205, https://doi.org/10.5194/acp-23-3195-2023, https://doi.org/10.5194/acp-23-3195-2023, 2023
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Chemical compositions vary between and within particles due to the complex sources and aging processes, causing particle-to-particle heterogeneity in aerosol hygroscopicity, which is of great importance to aerosol climatic and environmental effects. This study proposes an algorithm to quantify the heterogeneity from in situ measurements, sheds light on the reanalysis of the existing H-TDMA datasets, and could have a large impact on how we use and think about these datasets.
Weilun Zhao, Gang Zhao, Ying Li, Song Guo, Nan Ma, Lizi Tang, Zirui Zhang, and Chunsheng Zhao
Atmos. Meas. Tech., 15, 6807–6817, https://doi.org/10.5194/amt-15-6807-2022, https://doi.org/10.5194/amt-15-6807-2022, 2022
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A new method to determine black carbon mass size distribution (BCMSD) was proposed using the size-resolved absorption coefficient measured by an aerodynamic aerosol classifier in tandem with an aethalometer. This new method fills the gap in the high-time-resolution measurement of BCMSD ranging from upper submicron particle sizes to larger than 1 µm. This method can be applied to field measurement of BCMSD extensively for better understanding BC aging and better estimating the BC climate effect.
Li Liu, Ye Kuang, Miaomiao Zhai, Biao Xue, Yao He, Jun Tao, Biao Luo, Wanyun Xu, Jiangchuan Tao, Changqin Yin, Fei Li, Hanbing Xu, Tao Deng, Xuejiao Deng, Haobo Tan, and Min Shao
Atmos. Chem. Phys., 22, 7713–7726, https://doi.org/10.5194/acp-22-7713-2022, https://doi.org/10.5194/acp-22-7713-2022, 2022
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Using simultaneous measurements of a humidified nephelometer system and an aerosol chemical speciation monitor in winter in Guangzhou, the strongest scattering ability of more oxidized oxygenated organic aerosol (MOOA) among aerosol components considering their dry-state scattering ability and water uptake ability was revealed, leading to large impacts of MOOA on visibility degradation. This has important implications for visibility improvement in China and aerosol radiative effect simulation.
Jingnan Shi, Juan Hong, Nan Ma, Qingwei Luo, Yao He, Hanbing Xu, Haobo Tan, Qiaoqiao Wang, Jiangchuan Tao, Yaqing Zhou, Shuang Han, Long Peng, Linhong Xie, Guangsheng Zhou, Wanyun Xu, Yele Sun, Yafang Cheng, and Hang Su
Atmos. Chem. Phys., 22, 4599–4613, https://doi.org/10.5194/acp-22-4599-2022, https://doi.org/10.5194/acp-22-4599-2022, 2022
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In this study, we investigated the hygroscopicity of submicron aerosols at a rural site in the North China Plain during the winter of 2018, using a HTDMA and a CV-ToF-ACSM. We observed differences in aerosol hygroscopicity during two distinct episodes with different primary emissions and secondary aerosol formation processes. These results provide an improved understanding of the complex influence of sources and aerosol evolution processes on their hygroscopicity.
Shuang Han, Juan Hong, Qingwei Luo, Hanbing Xu, Haobo Tan, Qiaoqiao Wang, Jiangchuan Tao, Yaqing Zhou, Long Peng, Yao He, Jingnan Shi, Nan Ma, Yafang Cheng, and Hang Su
Atmos. Chem. Phys., 22, 3985–4004, https://doi.org/10.5194/acp-22-3985-2022, https://doi.org/10.5194/acp-22-3985-2022, 2022
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We present the hygroscopicity of 23 organic species with different physicochemical properties using a hygroscopicity tandem differential mobility analyzer (HTDMA) and compare the results with previous studies. Based on the hygroscopicity parameter κ, the influence of different physicochemical properties that potentially drive hygroscopicity, such as the functionality, water solubility, molar volume, and O : C ratio of organics, are examined separately.
Xiajie Yang, Qiaoqiao Wang, Nan Ma, Weiwei Hu, Yang Gao, Zhijiong Huang, Junyu Zheng, Bin Yuan, Ning Yang, Jiangchuan Tao, Juan Hong, Yafang Cheng, and Hang Su
Atmos. Chem. Phys., 22, 3743–3762, https://doi.org/10.5194/acp-22-3743-2022, https://doi.org/10.5194/acp-22-3743-2022, 2022
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We use the GEOS-Chem model with additional anthropogenic and biomass burning chlorine emissions combined with updated parameterizations for N2O5 ＋ Cl chemistry to investigate the impacts of chlorine chemistry on air quality in China. Our study not only significantly improves the model's performance but also demonstrates the importance of non-sea-salt chlorine sources as well as an appropriate parameterization for N2O5 ＋ Cl chemistry to the impact of chlorine chemistry in China.
Yaqing Zhou, Nan Ma, Qiaoqiao Wang, Zhibin Wang, Chunrong Chen, Jiangchuan Tao, Juan Hong, Long Peng, Yao He, Linhong Xie, Shaowen Zhu, Yuxuan Zhang, Guo Li, Wanyun Xu, Peng Cheng, Uwe Kuhn, Guangsheng Zhou, Pingqing Fu, Qiang Zhang, Hang Su, and Yafang Cheng
Atmos. Chem. Phys., 22, 2029–2047, https://doi.org/10.5194/acp-22-2029-2022, https://doi.org/10.5194/acp-22-2029-2022, 2022
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This study characterizes size-resolved particle effective densities and their evolution associated with emissions and aging processes in a rural area of the North China Plain. Particle effective density exhibits a high-frequency bimodal distribution, and two density modes exhibit opposite trends with increasing particle size. SIA and BC mass fractions are key factors of particle effective density, and a value of 0.6 g cm−3 is appropriate to represent BC effective density in bulk particles.
Gang Zhao, Tianyi Tan, Yishu Zhu, Min Hu, and Chunsheng Zhao
Atmos. Chem. Phys., 21, 18055–18063, https://doi.org/10.5194/acp-21-18055-2021, https://doi.org/10.5194/acp-21-18055-2021, 2021
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In this study, the black carbon (BC) mixing state index (χ) is developed to quantify the dispersion of ambient black carbon aerosol mixing states based on binary systems of BC and other non-black carbon components. We demonstrate that the BC light absorption enhancement increases with χ for the same MR, which indicates that χ can be employed as a factor to constrain the light absorption enhancement of ambient BC.
Shixian Zhai, Daniel J. Jacob, Jared F. Brewer, Ke Li, Jonathan M. Moch, Jhoon Kim, Seoyoung Lee, Hyunkwang Lim, Hyun Chul Lee, Su Keun Kuk, Rokjin J. Park, Jaein I. Jeong, Xuan Wang, Pengfei Liu, Gan Luo, Fangqun Yu, Jun Meng, Randall V. Martin, Katherine R. Travis, Johnathan W. Hair, Bruce E. Anderson, Jack E. Dibb, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jung-Hun Woo, Younha Kim, Qiang Zhang, and Hong Liao
Atmos. Chem. Phys., 21, 16775–16791, https://doi.org/10.5194/acp-21-16775-2021, https://doi.org/10.5194/acp-21-16775-2021, 2021
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Geostationary satellite aerosol optical depth (AOD) has tremendous potential for monitoring surface fine particulate matter (PM2.5). Our study explored the physical relationship between AOD and PM2.5 by integrating data from surface networks, aircraft, and satellites with the GEOS-Chem chemical transport model. We quantitatively showed that accurate simulation of aerosol size distributions, boundary layer depths, relative humidity, coarse particles, and diurnal variations in PM2.5 are essential.
Jie Qiu, Wangshu Tan, Gang Zhao, Yingli Yu, and Chunsheng Zhao
Atmos. Meas. Tech., 14, 4879–4891, https://doi.org/10.5194/amt-14-4879-2021, https://doi.org/10.5194/amt-14-4879-2021, 2021
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Considering nephelometers' major problems of a nonideal Lambertian light source and angle truncation, a new correction method based on a machine learning model is proposed. Our method has the advantage of obtaining data with high accuracy while achieving self-correction, which means that researchers can get more accurate scattering coefficients without the need for additional observation data. This method provides a more precise estimation of the aerosol’s direct radiative forcing.
Gang Zhao, Yishu Zhu, Zhijun Wu, Taomou Zong, Jingchuan Chen, Tianyi Tan, Haichao Wang, Xin Fang, Keding Lu, Chunsheng Zhao, and Min Hu
Atmos. Chem. Phys., 21, 9995–10004, https://doi.org/10.5194/acp-21-9995-2021, https://doi.org/10.5194/acp-21-9995-2021, 2021
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New particle formation is thought to contribute half of the global cloud condensation nuclei. We find that the new particle formation is more likely to happen in the upper boundary layer than that at the ground, which can be partially explained by the aerosol–radiation interaction. Our study emphasizes the influence of aerosol–radiation interaction on the NPF.
Bingqing Zhang, Huizhong Shen, Pengfei Liu, Hongyu Guo, Yongtao Hu, Yilin Chen, Shaodong Xie, Ziyan Xi, T. Nash Skipper, and Armistead G. Russell
Atmos. Chem. Phys., 21, 8341–8356, https://doi.org/10.5194/acp-21-8341-2021, https://doi.org/10.5194/acp-21-8341-2021, 2021
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Extended ground-level measurements are coupled with model simulations to comprehensively compare the aerosol acidity in China and the United States. Aerosols in China are significantly less acidic than those in the United States, with pH values 1–2 units higher. Higher aerosol mass concentrations and the abundance of ammonia and ammonium in China, compared to the United States, are leading causes of the pH difference between these two countries.
Jiangchuan Tao, Ye Kuang, Nan Ma, Juan Hong, Yele Sun, Wanyun Xu, Yanyan Zhang, Yao He, Qingwei Luo, Linhong Xie, Hang Su, and Yafang Cheng
Atmos. Chem. Phys., 21, 7409–7427, https://doi.org/10.5194/acp-21-7409-2021, https://doi.org/10.5194/acp-21-7409-2021, 2021
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The mechanism of secondary aerosol (SA) formation can be affected by relative humidity (RH) and has different influences on the particle CCN activity under different RH conditions. In the North China Plain, we find different responses of CCN activity and enhancements of CCN number concentration to SA formation under different RH conditions. In addition, variations of aerosol mixing state due to SA formation contribute some of the largest uncertainties in predicting CCN number concentration.
Weilun Zhao, Wangshu Tan, Gang Zhao, Chuanyang Shen, Yingli Yu, and Chunsheng Zhao
Atmos. Meas. Tech., 14, 1319–1331, https://doi.org/10.5194/amt-14-1319-2021, https://doi.org/10.5194/amt-14-1319-2021, 2021
Chuanyang Shen, Gang Zhao, and Chunsheng Zhao
Atmos. Meas. Tech., 14, 1293–1301, https://doi.org/10.5194/amt-14-1293-2021, https://doi.org/10.5194/amt-14-1293-2021, 2021
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Aerosol hygroscopicity measured by the humidified tandem differential mobility analyzer (HTDMA) is affected by multiply charged particles from two aspects: (1) number contribution and (2) the weakening effect. An algorithm is proposed to do the multi-charge correction and applied to a field measurement. Results show that the difference between corrected and measured size-resolved κ can reach 0.05, highlighting that special attention needs to be paid to the multi-charge effect when using HTDMA.
Chuanyang Shen, Gang Zhao, Weilun Zhao, Ping Tian, and Chunsheng Zhao
Atmos. Chem. Phys., 21, 1375–1388, https://doi.org/10.5194/acp-21-1375-2021, https://doi.org/10.5194/acp-21-1375-2021, 2021
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Submicron particles larger than 300 nm dominate the aerosol light extinction and mass concentration in the urban environment. Aerosol hygroscopic properties extended to 600 nm were investigated at an urban site. Our results find that there exists a large fraction of a less hygroscopic group above 300 nm, and the hygroscopicity in this size range is enhanced significantly with the development of pollution levels. The hygroscopicity variation contributes greatly to the low visibility.
Shaojie Song, Tao Ma, Yuzhong Zhang, Lu Shen, Pengfei Liu, Ke Li, Shixian Zhai, Haotian Zheng, Meng Gao, Jonathan M. Moch, Fengkui Duan, Kebin He, and Michael B. McElroy
Atmos. Chem. Phys., 21, 457–481, https://doi.org/10.5194/acp-21-457-2021, https://doi.org/10.5194/acp-21-457-2021, 2021
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We simulate the atmospheric chemical processes of an important sulfur-containing organic aerosol species, which is produced by the reaction between sulfur dioxide and formaldehyde. We can predict its distribution on a global scale. We find it is particularly rich in East Asia. This aerosol species is more abundant in the colder season partly because of weaker sunlight.
Yang Li, Loretta J. Mickley, Pengfei Liu, and Jed O. Kaplan
Atmos. Chem. Phys., 20, 8827–8838, https://doi.org/10.5194/acp-20-8827-2020, https://doi.org/10.5194/acp-20-8827-2020, 2020
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Using a coupled vegetation–fire–climate modeling framework, we show a northward shift in forests and increased lightning fire activity in northern US states, including Idaho, Montana, and Wyoming. Our findings suggest a large climate penalty on ecosystem, air quality, visibility, and human health in a region valued for its national forests and parks. The fine-scale smoke PM predictions provided in this study should prove useful to human health and environmental assessments.
Quan Liu, Dantong Liu, Qian Gao, Ping Tian, Fei Wang, Delong Zhao, Kai Bi, Yangzhou Wu, Shuo Ding, Kang Hu, Jiale Zhang, Deping Ding, and Chunsheng Zhao
Atmos. Chem. Phys., 20, 3931–3944, https://doi.org/10.5194/acp-20-3931-2020, https://doi.org/10.5194/acp-20-3931-2020, 2020
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We present a series of aircraft-based in situ measurements of aerosol chemical components and size distributions over the North China Plain, and the hygroscopicity is derived from aerosol chemical composition. These results reveal the vertical characteristics of aerosol hygroscopicity, and we investigated their impacts on optical properties and activation under different moisture and pollution conditions over this polluted region.
Ping Tian, Dantong Liu, Delong Zhao, Chenjie Yu, Quan Liu, Mengyu Huang, Zhaoze Deng, Liang Ran, Yunfei Wu, Shuo Ding, Kang Hu, Gang Zhao, Chunsheng Zhao, and Deping Ding
Atmos. Chem. Phys., 20, 2603–2622, https://doi.org/10.5194/acp-20-2603-2020, https://doi.org/10.5194/acp-20-2603-2020, 2020
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This study paints a full picture of the evolution of vertical characteristics of aerosol optical properties and shortwave heating impacts of carbonaceous aerosols during different stages of pollution events over the Beijing region and highlights the increased contribution of brown carbon absorption, especially at higher levels, during pollution.
Yu Wang, Ying Chen, Zhijun Wu, Dongjie Shang, Yuxuan Bian, Zhuofei Du, Sebastian H. Schmitt, Rong Su, Georgios I. Gkatzelis, Patrick Schlag, Thorsten Hohaus, Aristeidis Voliotis, Keding Lu, Limin Zeng, Chunsheng Zhao, M. Rami Alfarra, Gordon McFiggans, Alfred Wiedensohler, Astrid Kiendler-Scharr, Yuanhang Zhang, and Min Hu
Atmos. Chem. Phys., 20, 2161–2175, https://doi.org/10.5194/acp-20-2161-2020, https://doi.org/10.5194/acp-20-2161-2020, 2020
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Severe haze events, with high particulate nitrate (pNO3−) burden, frequently prevail in Beijing. In this study, we demonstrate a mutual-promotion effect between aerosol water uptake and pNO3− formation backed up by theoretical calculations and field observations throughout a typical pNO3−-dominated haze event in Beijing wintertime. This self-amplified mutual-promotion effect between aerosol water content and particulate nitrate can rapidly deteriorate air quality and degrade visibility.
Ye Kuang, Yao He, Wanyun Xu, Pusheng Zhao, Yafang Cheng, Gang Zhao, Jiangchuan Tao, Nan Ma, Hang Su, Yanyan Zhang, Jiayin Sun, Peng Cheng, Wenda Yang, Shaobin Zhang, Cheng Wu, Yele Sun, and Chunsheng Zhao
Atmos. Chem. Phys., 20, 865–880, https://doi.org/10.5194/acp-20-865-2020, https://doi.org/10.5194/acp-20-865-2020, 2020
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A new method was developed to calculate hygroscopicity parameter κ of organic aerosols (κOA) based on aerosol light-scattering measurements and bulk aerosol chemical-composition measurements. Derived high-time-resolution κOA varied in a wide range (near 0 to 0.25), and the organic aerosol oxidation degree significantly impacts variations in κOA. Distinct diurnal variation in κOA is found, and its relationship with oxygenated organic aerosol is discussed.
Gang Zhao, Jiangchuan Tao, Ye Kuang, Chuanyang Shen, Yingli Yu, and Chunsheng Zhao
Atmos. Chem. Phys., 19, 13175–13188, https://doi.org/10.5194/acp-19-13175-2019, https://doi.org/10.5194/acp-19-13175-2019, 2019
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Characteristics of the black carbon size distribution (BCMSD) are studied by using our developed measurement system. Results show that the BCMSDs have two modes and the mean peak diameters are 150 nm and 503 nm, respectively. The coarser mode varies significantly under different pollution conditions, which gives rise to significant variation in aerosol bulk optical properties. Our study reveals that the BCMSD as well as the mixing state in estimating aerosol radiative forcing matters.
Gang Zhao, Tianyi Tan, Weilun Zhao, Song Guo, Ping Tian, and Chunsheng Zhao
Atmos. Chem. Phys., 19, 12875–12885, https://doi.org/10.5194/acp-19-12875-2019, https://doi.org/10.5194/acp-19-12875-2019, 2019
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Traditionally, the real part of the refractive index (RRI) of ambient aerosols is calculated by their chemical components. In this study, we demonstrate that the RRI is highly related to effective density rather than chemical components using field measurements. For the first time, a parameterization scheme for ambient aerosol RRI using effective density is proposed. This simple scheme is more reliable and ready to use in the calculation of aerosol optics and radiation.
Wanyun Xu, Ye Kuang, Chunsheng Zhao, Jiangchuan Tao, Gang Zhao, Yuxuan Bian, Wen Yang, Yingli Yu, Chuanyang Shen, Linlin Liang, Gen Zhang, Weili Lin, and Xiaobin Xu
Atmos. Chem. Phys., 19, 10557–10570, https://doi.org/10.5194/acp-19-10557-2019, https://doi.org/10.5194/acp-19-10557-2019, 2019
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The study of HONO, the primary source of OH radicals, is crucial for atmospheric photochemistry and heterogeneous chemistry. Heterogeneous NO2 conversion was shown to be one of the missing sources of HONO on the North China Plain, but the reaction path is still under debate. In this work, evidence was found that NH3 was the key factor that promoted the hydrolysis of NO2, leading to the explosive growth of HONO and nitrate, suggesting that NH3 emission control measures are urgently needed.
Wangshu Tan, Gang Zhao, Yingli Yu, Chengcai Li, Jian Li, Ling Kang, Tong Zhu, and Chunsheng Zhao
Atmos. Meas. Tech., 12, 3825–3839, https://doi.org/10.5194/amt-12-3825-2019, https://doi.org/10.5194/amt-12-3825-2019, 2019
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A new method to retrieve CCN number concentrations using multiwavelength Raman lidars is proposed. The method implements hygroscopic enhancements of backscatter and extinction with relative humidity to represent particle hygroscopicity. The retrieved CCN number concentrations are in good agreement with theoretical calculated values. Sensitivity tests indicate that retrieval error in CCN arises mostly from uncertainties in extinction coefficients and RH profiles.
Gang Zhao, Weilun Zhao, and Chunsheng Zhao
Atmos. Meas. Tech., 12, 3541–3550, https://doi.org/10.5194/amt-12-3541-2019, https://doi.org/10.5194/amt-12-3541-2019, 2019
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A new method is proposed to retrieve the size-resolved real part of the refractive index (RRI). The main principle of deriving the RRI is measuring the scattering intensity by a single-particle soot photometer of a size-selected aerosol. This method is validated by a series of calibration experiments using the components of the known RI. The retrieved size-resolved RRI covers a wide range, from 200 nm to 450 nm, with uncertainty of less than 0.02.
Gang Zhao, Chunsheng Zhao, Ye Kuang, Yuxuan Bian, Jiangchuan Tao, Chuanyang Shen, and Yingli Yu
Atmos. Chem. Phys., 18, 9049–9060, https://doi.org/10.5194/acp-18-9049-2018, https://doi.org/10.5194/acp-18-9049-2018, 2018
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The aerosol asymmetry factor (g) is one of the most important factors for assessing direct aerosol radiative forcing (DARF) and remote sensing. So far, few studies have focused on the measurements and parameterization of g. Our study shows that relative humidity has significant impacts on g and DARF due to aerosol hygroscopic growth. For the first time, a novel method based on measurements from the humidified nephelometer system is proposed to calculate g accurately with high time resolution.
Ye Kuang, Chun Sheng Zhao, Gang Zhao, Jiang Chuan Tao, Wanyun Xu, Nan Ma, and Yu Xuan Bian
Atmos. Meas. Tech., 11, 2967–2982, https://doi.org/10.5194/amt-11-2967-2018, https://doi.org/10.5194/amt-11-2967-2018, 2018
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Aerosol water has become an important topic recently because of its implications for multiphase secondary aerosol formation during severe haze events in Asia. This is a timely paper on this topic; a novel method is proposed to calculate ambient aerosol liquid water contents based only on measurements of a three-wavelength humidified nephelometer system. The advantage of this method is that this technique can provide continuous measurements of the changing ambient conditions.
Jing Li, Chengcai Li, and Chunsheng Zhao
Atmos. Chem. Phys., 18, 3289–3298, https://doi.org/10.5194/acp-18-3289-2018, https://doi.org/10.5194/acp-18-3289-2018, 2018
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Our study investigates the long-term trends of extreme aerosol pollution in China over the past ~ 30 years. In the 1980s, an overall positive trend is found throughout China with the extreme trend exceeding the mean trend, except for Northwest China and the North China Plain. In the 1990s, the extreme trends continued to dominate in the south while they yield to the mean trend in the north. After 2000, the extreme trend became weaker than the mean trend overall.
Jiangchuan Tao, Chunsheng Zhao, Ye Kuang, Gang Zhao, Chuanyang Shen, Yingli Yu, Yuxuan Bian, and Wanyun Xu
Atmos. Meas. Tech., 11, 895–906, https://doi.org/10.5194/amt-11-895-2018, https://doi.org/10.5194/amt-11-895-2018, 2018
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Existing chamber technologies for direct measurements of number concentration of cloud condensation nuclei (NCCN) are sophisticated and expensive. In this paper, a new method is proposed to calculate NCCN based only on measurements of a humidified nephelometer system which have accounted for influences of both aerosol size and aerosol hygroscopicity on NCCN calculation. This new method makes NCCN measurements more convenient and is capable of obtaining NCCN at lower supersaturations.
Gang Zhao, Chunsheng Zhao, Ye Kuang, Jiangchuan Tao, Wangshu Tan, Yuxuan Bian, Jing Li, and Chengcai Li
Atmos. Chem. Phys., 17, 12133–12143, https://doi.org/10.5194/acp-17-12133-2017, https://doi.org/10.5194/acp-17-12133-2017, 2017
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In this paper, influences of aerosol hygroscopic growth on the lidar ratio are studied. Results indicate that both the magnitude and vertical structures of the retrieved aerosol extinction coefficient (σext) profile from lidar signals are significantly biased. This study proposes a feasible method for reducing the bias of retrieving the σext profile and this method can be implemented in operational retrieval of the aerosol σext profile and for pollution monitoring.
Mijung Song, Pengfei Liu, Scot T. Martin, and Allan K. Bertram
Atmos. Chem. Phys., 17, 11261–11271, https://doi.org/10.5194/acp-17-11261-2017, https://doi.org/10.5194/acp-17-11261-2017, 2017
Yuxuan Bian, Chunsheng Zhao, Wanyun Xu, Gang Zhao, Jiangchuan Tao, and Ye Kuang
Atmos. Meas. Tech., 10, 2313–2322, https://doi.org/10.5194/amt-10-2313-2017, https://doi.org/10.5194/amt-10-2313-2017, 2017
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Aerosol phase function is crucial for understanding the climate effects of aerosols. So far, there is a lack of instruments for measuring the aerosol phase function directly and accurately in laboratory studies and in situ measurements. A novel portable instrument with high angular range and resolution named
charge-coupled device-laser aerosol detective system(CCD-LADS) has been developed and validated for the measurement of the phase function of ambient aerosols in this study.
Ye Kuang, Chunsheng Zhao, Jiangchuan Tao, Yuxuan Bian, Nan Ma, and Gang Zhao
Atmos. Chem. Phys., 17, 6651–6662, https://doi.org/10.5194/acp-17-6651-2017, https://doi.org/10.5194/acp-17-6651-2017, 2017
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A novel approach is proposed in this research to derive the aerosol hygroscopicity parameter based only on measurements from a humidified nephelometer system without any additional information about particle number size distribution and black carbon. New findings in this research can bridge the gap between κ-Köhler theory and the aerosol light-scattering enhancement factor and will make the humidified nephelometer system more convenient when it comes to aerosol hygroscopicity research.
Yee Jun Tham, Zhe Wang, Qinyi Li, Hui Yun, Weihao Wang, Xinfeng Wang, Likun Xue, Keding Lu, Nan Ma, Birger Bohn, Xin Li, Simonas Kecorius, Johannes Größ, Min Shao, Alfred Wiedensohler, Yuanhang Zhang, and Tao Wang
Atmos. Chem. Phys., 16, 14959–14977, https://doi.org/10.5194/acp-16-14959-2016, https://doi.org/10.5194/acp-16-14959-2016, 2016
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This work addresses the unclear global significance of chlorine activation processes in the troposphere. The first high-quality measurement data set of ClNO2 in northern China revealed strong ClNO2 production in the residual layers, and demonstrated its significant effects on radical budget and ozone production. Our findings imply the widespread effects of ClNO2 over the polluted regions of northern China, which may increase photochemical and haze pollution.
Hang Su, Yafang Cheng, Nan Ma, Zhibin Wang, Xiaoxiang Wang, Mira L. Pöhlker, Björn Nillius, Alfred Wiedensohler, and Ulrich Pöschl
Atmos. Meas. Tech., 9, 5183–5192, https://doi.org/10.5194/amt-9-5183-2016, https://doi.org/10.5194/amt-9-5183-2016, 2016
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In cloud condensation nuclei (CCN) measurements, the supersaturation scan is often time-consuming and limits the temporal resolution of CCN measurements. Here we present a new concept, termed the broad supersaturation scanning (BS2) method, in which a range of supersaturation is simultaneously scanned, resulting in fast measurements of CCN activity.
Mijung Song, Pengfei F. Liu, Sarah J. Hanna, Rahul A. Zaveri, Katie Potter, Yuan You, Scot T. Martin, and Allan K. Bertram
Atmos. Chem. Phys., 16, 8817–8830, https://doi.org/10.5194/acp-16-8817-2016, https://doi.org/10.5194/acp-16-8817-2016, 2016
Nan Ma, Chunsheng Zhao, Jiangchuan Tao, Zhijun Wu, Simonas Kecorius, Zhibin Wang, Johannes Größ, Hongjian Liu, Yuxuan Bian, Ye Kuang, Monique Teich, Gerald Spindler, Konrad Müller, Dominik van Pinxteren, Hartmut Herrmann, Min Hu, and Alfred Wiedensohler
Atmos. Chem. Phys., 16, 8593–8607, https://doi.org/10.5194/acp-16-8593-2016, https://doi.org/10.5194/acp-16-8593-2016, 2016
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New particle formation (NPF) is one of main sources of cloud condensation nuclei (CCN) in the atmosphere. Based on in situ measurements, we found that CCN activity of newly formed particles largely differs in different NPF events. It is therefore difficult to find a simple parameterization of CCN activity for NPF events. Using a fixed size-resolved activation ratio curve or critical diameter is very likely to result in large biases up to 50 % in the calculated NCCN during NPF events.
Lindsay Renbaum-Wolff, Mijung Song, Claudia Marcolli, Yue Zhang, Pengfei F. Liu, James W. Grayson, Franz M. Geiger, Scot T. Martin, and Allan K. Bertram
Atmos. Chem. Phys., 16, 7969–7979, https://doi.org/10.5194/acp-16-7969-2016, https://doi.org/10.5194/acp-16-7969-2016, 2016
Ying Chen, Ya-Fang Cheng, Stephan Nordmann, Wolfram Birmili, Hugo A. C. Denier van der Gon, Nan Ma, Ralf Wolke, Birgit Wehner, Jia Sun, Gerald Spindler, Qing Mu, Ulrich Pöschl, Hang Su, and Alfred Wiedensohler
Atmos. Chem. Phys., 16, 1823–1835, https://doi.org/10.5194/acp-16-1823-2016, https://doi.org/10.5194/acp-16-1823-2016, 2016
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We evaluated the EC point sources in Germany with high-resolution simulation by WRF-Chem, and find out that point sources contribute too much EC in the coarse mode aerosol mass. The area emissions in Eastern Europe and Russia also allocate too much EC emission in coarse mode in the EUCAARI EC emission inventory. Because of the shorter life time of coarse mode EC, about 20–40 % less EC can be transported to Melpitz from Eastern Europe. Size segregation information is important for EC inventories.
Y. Zhang, M. S. Sanchez, C. Douet, Y. Wang, A. P. Bateman, Z. Gong, M. Kuwata, L. Renbaum-Wolff, B. B. Sato, P. F. Liu, A. K. Bertram, F. M. Geiger, and S. T. Martin
Atmos. Chem. Phys., 15, 7819–7829, https://doi.org/10.5194/acp-15-7819-2015, https://doi.org/10.5194/acp-15-7819-2015, 2015
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The present work estimates the viscosity of submicron organic particles while they are still suspended as an aerosol without further post-processing techniques that can possibly alter the properties of semi-volatile materials. Results imply that atmospheric particles, at least those similar to the ones of this study and for low- to middle-RH regimes, can reach equilibrium or react rather slowly with the surrounding gas phase on time scales even longer than the residence time in the atmosphere.
Y. Kuang, C. S. Zhao, J. C. Tao, and N. Ma
Atmos. Chem. Phys., 15, 5761–5772, https://doi.org/10.5194/acp-15-5761-2015, https://doi.org/10.5194/acp-15-5761-2015, 2015
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In this paper, it is found that the diurnal variations of single scattering albedo (SSA) and asymmetry factor (g) for ambient aerosol are both evident and far different from those of dry state aerosol in the North China Plain (NCP. The diurnal changes of SSA and g have significant impacts on the estimation of daily average direct aerosol radiative effect (DARE) at the top of the atmosphere. In addition, several suggestions are proposed to improve the accurate prediction of DARE in the NCP.
Z. Wang, H. Su, X. Wang, N. Ma, A. Wiedensohler, U. Pöschl, and Y. Cheng
Atmos. Meas. Tech., 8, 2161–2172, https://doi.org/10.5194/amt-8-2161-2015, https://doi.org/10.5194/amt-8-2161-2015, 2015
J. Huang, H. Liu, J. H. Crawford, C. Chan, D. B. Considine, Y. Zhang, X. Zheng, C. Zhao, V. Thouret, S. J. Oltmans, S. C. Liu, D. B. A. Jones, S. D. Steenrod, and M. R. Damon
Atmos. Chem. Phys., 15, 5161–5179, https://doi.org/10.5194/acp-15-5161-2015, https://doi.org/10.5194/acp-15-5161-2015, 2015
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High ozone concentrations (up to 94.7ppbv) were frequently observed at an altitude of ~1.5--2km over Beijing during April--May 2005. Ozone due to Asian anthropogenic pollution made major contributions to the observed ozone enhancements. These enhancements typically occurred under southerly wind and warmer conditions. An earlier onset of the Asian summer monsoon would cause more ozone enhancement events in the lower troposphere over the North China Plain in late spring and early summer.
M. Song, P. F. Liu, S. J. Hanna, Y. J. Li, S. T. Martin, and A. K. Bertram
Atmos. Chem. Phys., 15, 5145–5159, https://doi.org/10.5194/acp-15-5145-2015, https://doi.org/10.5194/acp-15-5145-2015, 2015
P. F. Liu, N. Abdelmalki, H.-M. Hung, Y. Wang, W. H. Brune, and S. T. Martin
Atmos. Chem. Phys., 15, 1435–1446, https://doi.org/10.5194/acp-15-1435-2015, https://doi.org/10.5194/acp-15-1435-2015, 2015
G. Q. Fu, W. Y. Xu, R. F. Yang, J. B. Li, and C. S. Zhao
Atmos. Chem. Phys., 14, 11949–11958, https://doi.org/10.5194/acp-14-11949-2014, https://doi.org/10.5194/acp-14-11949-2014, 2014
J. Chen, C. S. Zhao, N. Ma, and P. Yan
Atmos. Chem. Phys., 14, 8105–8118, https://doi.org/10.5194/acp-14-8105-2014, https://doi.org/10.5194/acp-14-8105-2014, 2014
W. Y. Xu, C. S. Zhao, L. Ran, W. L. Lin, P. Yan, and X. B. Xu
Atmos. Chem. Phys., 14, 7757–7768, https://doi.org/10.5194/acp-14-7757-2014, https://doi.org/10.5194/acp-14-7757-2014, 2014
Y. X. Bian, C. S. Zhao, N. Ma, J. Chen, and W. Y. Xu
Atmos. Chem. Phys., 14, 6417–6426, https://doi.org/10.5194/acp-14-6417-2014, https://doi.org/10.5194/acp-14-6417-2014, 2014
N. Ma, W. Birmili, T. Müller, T. Tuch, Y. F. Cheng, W. Y. Xu, C. S. Zhao, and A. Wiedensohler
Atmos. Chem. Phys., 14, 6241–6259, https://doi.org/10.5194/acp-14-6241-2014, https://doi.org/10.5194/acp-14-6241-2014, 2014
H. J. Liu, C. S. Zhao, B. Nekat, N. Ma, A. Wiedensohler, D. van Pinxteren, G. Spindler, K. Müller, and H. Herrmann
Atmos. Chem. Phys., 14, 2525–2539, https://doi.org/10.5194/acp-14-2525-2014, https://doi.org/10.5194/acp-14-2525-2014, 2014
Z. Z. Deng, C. S. Zhao, N. Ma, L. Ran, G. Q. Zhou, D. R. Lu, and X. J. Zhou
Atmos. Chem. Phys., 13, 6227–6237, https://doi.org/10.5194/acp-13-6227-2013, https://doi.org/10.5194/acp-13-6227-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Microphysical properties of refractory black carbon aerosols for different air masses at a central European background site
Source-dependent optical properties and molecular characteristics of atmospheric brown carbon
Multi-year black carbon observations and modeling close to the largest gas flaring and wildfire regions in the Western Siberian Arctic
Pollution affects Arabian and Saharan dust optical properties in the eastern Mediterranean
Phase matrix characterization of long-range-transported Saharan dust using multiwavelength-polarized polar imaging nephelometry
Measurement report: The influence of particle number size distribution and hygroscopicity on the microphysical properties of cloud droplets at a mountain site
Measurement report: Long-term assessment of primary and secondary organic aerosols in the Shanghai megacity throughout China's Clean Air actions since 2010
The evolution of aerosol mixing state derived from a field campaign in Beijing: implications for particle aging timescales in urban atmospheres
Field Observations Reveal Substantially Higher Scattering Refractive Index in Secondary Versus Primary Organic Aerosols
Measurement report: Size-resolved particle effective density measured by an AAC-SMPS and implications for chemical composition
Locally emitted fungal spores serve as high temperature ice nucleating particles in the European sub-Arctic
Measurement report: Aircraft observations of aerosol and microphysical quantities of stratocumulus in autumn over Guangxi Province, China – daylight variation, vertical distribution, and aerosol–cloud interactions
Hygroscopic aerosols amplify longwave downward radiation in the Arctic
Measurement report: Aerosol and cloud nuclei properties along the Central and Northern Great Barrier Reef: Impact of continental emissions
Measurement report: Optical and structural properties of atmospheric water-soluble organic carbon in China – insights from multi-site spectroscopic measurements
Measurement report: The variation properties of aerosol hygroscopic growth related to chemical composition during new particle formation days in a coastal city of Southeast China
In situ vertical observations of the layered structure of air pollution in a continental high-latitude urban boundary layer during winter
Size-resolved hygroscopicity and volatility properties of ambient urban aerosol particles measured by a volatility hygroscopicity tandem differential mobility analyzer system in Beijing
Terrestrial runoff is an important source of biological ice-nucleating particles in Arctic marine systems
Characterization of aerosol over the eastern Mediterranean by polarization-sensitive Raman lidar measurements during A-LIFE – aerosol type classification and type separation
Aerosol spectral optical properties in the Paris urban area and its peri-urban and forested surroundings during summer 2022 from ACROSS surface observations
Measurement report: An investigation of the spatiotemporal variability in aerosols in the mountainous terrain of the upper Colorado River basin using SAIL-Net
Contributions of the synoptic meteorology to the seasonal cloud condensation nuclei cycle over the Southern Ocean
Measurement report: Cloud condensation nuclei (CCN) activity in the South China Sea from shipborne observations during the summer and winter of 2021 – seasonal variation and anthropogenic influence
Biomass burning smoke transport and radiative impact over the city of Sao Paulo: An extreme event case study
Differential characterization of air ions in boreal forest of Finland and megacity of eastern China
On-road vehicle emission measurements show a significant reduction of black carbon and nitrogen oxides emissions in Euro6c and 6d diesel-powered cars
Bioaerosols as indicators of central Arctic ice nucleating particle sources
Measurement report: A comparative analysis of an intensive incursion of fluorescing African dust particles over Puerto Rico and another over Spain
Measurement report: Analysis of aerosol optical depth variation at Zhongshan Station in Antarctica
External particle mixing influences hygroscopicity in a sub-urban area
Long-term observations of black carbon and carbon monoxide in the Poker Flat Research Range, central Alaska, with a focus on forest wildfire emissions
Origin, size distribution and hygroscopic properties of marine aerosols in the south-western Indian Ocean: report of 6 campaigns of shipborne observations
High ice-nucleating particle concentrations associated with Arctic haze in springtime cold-air outbreaks
CCN estimations at a high-altitude remote site: role of organic aerosol variability and hygroscopicity
Aerosol hygroscopicity over the South-East Atlantic Ocean during the biomass burning season: Part II – Influence of burning conditions on CCN hygroscopicity
Aerosol hygroscopicity over the southeast Atlantic Ocean during the biomass burning season – Part 1: From the perspective of scattering enhancement
Spatial, temporal, and meteorological impact of the 26 February 2023 dust storm: increase in particulate matter concentrations across New Mexico and West Texas
Large spatiotemporal variability in aerosol properties over central Argentina during the CACTI field campaign
Quantification and characterization of primary biological aerosol particles and microbes aerosolized from Baltic seawater
Brownness of organics in anthropogenic biomass burning aerosols over South Asia
Divergent changes in aerosol optical hygroscopicity and new particle formation induced by heatwaves
Strong influence of Black Carbon on aerosol optical properties in Central Amazonia during the fire season
Source apportionment of particle number size distribution at the street canyon and urban background sites
Long-range transport of coarse mineral dust: an evaluation of the Met Office Unified Model against aircraft observations
Extreme Saharan dust events expand northward over the Atlantic and Europe, prompting record-breaking PM10 and PM2.5 episodes
Atmospheric black carbon in the metropolitan area of La Paz and El Alto, Bolivia: concentration levels and emission sources
Changing optical properties of black carbon and brown carbon aerosols during long-range transport from the Indo-Gangetic Plain to the equatorial Indian Ocean
Aerosol size distribution properties associated with cold-air outbreaks in the Norwegian Arctic
Ice-nucleating particles active below −24 °C in a Finnish boreal forest and their relationship to bioaerosols
Yifan Yang, Thomas Müller, Laurent Poulain, Samira Atabakhsh, Bruna A. Holanda, Jens Voigtländer, Shubhi Arora, and Mira L. Pöhlker
Atmos. Chem. Phys., 25, 8637–8655, https://doi.org/10.5194/acp-25-8637-2025, https://doi.org/10.5194/acp-25-8637-2025, 2025
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Black carbon (BC) is the major atmospheric aerosol that can absorb light and influence climate. We measured the physical properties of BC at a background site in Germany. In summer, BC particles were smaller and the mixture with other atmospheric components occurred during the daytime. In winter, emissions from residential heating significantly influenced BC's properties. Understanding these characteristics of BC can help to improve the accuracy of aerosol optic simulation.
Jinghao Zhai, Yin Zhang, Pengfei Liu, Yujie Zhang, Antai Zhang, Yaling Zeng, Baohua Cai, Jingyi Zhang, Chunbo Xing, Honglong Yang, Xiaofei Wang, Jianhuai Ye, Chen Wang, Tzung-May Fu, Lei Zhu, Huizhong Shen, Shu Tao, and Xin Yang
Atmos. Chem. Phys., 25, 7959–7972, https://doi.org/10.5194/acp-25-7959-2025, https://doi.org/10.5194/acp-25-7959-2025, 2025
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Our study shows that the optical properties of brown carbon depend on its source. Brown carbon from ozone pollution had the weakest light absorption but the strongest wavelength dependence, while biomass burning brown carbon showed the strongest absorption and the weakest wavelength dependence. Nitrogen-containing organic carbon compounds were identified as key light absorbers. These results improve understanding of brown carbon sources and help refine climate models.
Olga B. Popovicheva, Marina A. Chichaeva, Nikolaos Evangeliou, Sabine Eckhardt, Evangelia Diapouli, and Nikolay S. Kasimov
Atmos. Chem. Phys., 25, 7719–7739, https://doi.org/10.5194/acp-25-7719-2025, https://doi.org/10.5194/acp-25-7719-2025, 2025
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High-quality measurements of light-absorbing carbon were performed at the polar aerosol station "Island Bely” (Western Siberian Arctic) from 2019 to 2022. The maximum light absorption coefficients were seen in summer due to gas flaring, which is the most significant source in the region. However, the increasing Siberian wildfires had a special share in carbon contribution at this high Arctic station, with a persistent smoke layer extending over the whole troposphere in summer.
Marilena Teri, Josef Gasteiger, Katharina Heimerl, Maximilian Dollner, Manuel Schöberl, Petra Seibert, Anne Tipka, Thomas Müller, Sudharaj Aryasree, Konrad Kandler, and Bernadett Weinzierl
Atmos. Chem. Phys., 25, 6633–6662, https://doi.org/10.5194/acp-25-6633-2025, https://doi.org/10.5194/acp-25-6633-2025, 2025
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The A-LIFE aircraft field experiment was carried out in the eastern Mediterranean in 2017. Using A-LIFE data, we studied the change in mineral dust optical properties due to mixing with anthropogenic aerosols. We found that increasing pollution affects dust optical properties, which has implications for identifying dust events and understanding their climate effects. We also show that optical properties of Saharan and Arabian dust are similar when comparing cases with equal pollution content.
Elena Bazo, Daniel Pérez-Ramírez, Antonio Valenzuela, J. Vanderlei Martins, Gloria Titos, Alberto Cazorla, Fernando Rejano, Diego Patrón, Arlett Díaz-Zurita, Francisco José García-Izquierdo, David Fuertes, Lucas Alados-Arboledas, and Francisco José Olmo
Atmos. Chem. Phys., 25, 6325–6352, https://doi.org/10.5194/acp-25-6325-2025, https://doi.org/10.5194/acp-25-6325-2025, 2025
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This works analyzes the aerosol scattering phase function for transported Saharan dust to the city of Granada – located in southwestern Europe. We use the novel technique polar imaging nephelometry that helps to determine the phase functions using a CMOS camera. The capability of measuring with polarized light helps to infer new properties about the mixture of Saharan dust particles with those of anthropogenic origin.
Xiaojing Shen, Quan Liu, Junying Sun, Wanlin Kong, Qianli Ma, Bing Qi, Lujie Han, Yangmei Zhang, Linlin Liang, Lei Liu, Shuo Liu, Xinyao Hu, Jiayuan Lu, Aoyuan Yu, Huizheng Che, and Xiaoye Zhang
Atmos. Chem. Phys., 25, 5711–5725, https://doi.org/10.5194/acp-25-5711-2025, https://doi.org/10.5194/acp-25-5711-2025, 2025
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In this work, an automatic switched inlet system was developed and employed to investigate the aerosols and cloud droplets at a mountain site with frequent cloud processes. It showed different characteristics of cloud residual and interstitial particles. Stronger particle hygroscopicity reduced liquid water content and smaller cloud droplet diameters. This investigation contributes to understanding aerosol–cloud interactions by assessing the impact of aerosol particles on cloud microphysics.
Haifeng Yu, Yunhua Chang, Lin Cheng, Yusen Duan, and Jianlin Hu
Atmos. Chem. Phys., 25, 5355–5369, https://doi.org/10.5194/acp-25-5355-2025, https://doi.org/10.5194/acp-25-5355-2025, 2025
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This study presents long-term measurements and comprehensive analysis of carbonaceous aerosols in fine particles in Shanghai. We further estimated primary and secondary carbon levels, examining their temporal variations on interannual, monthly, seasonal, and diurnal scales. Through rigorous statistical analysis and correlation studies with meteorological parameters and pollutant concentrations, the origins, formation mechanisms, and spatial distribution patterns of secondary organic carbon were elucidated.
Jieyao Liu, Fang Zhang, Jingye Ren, Lu Chen, Anran Zhang, Zhe Wang, Songjian Zou, Honghao Xu, and Xingyan Yue
Atmos. Chem. Phys., 25, 5075–5086, https://doi.org/10.5194/acp-25-5075-2025, https://doi.org/10.5194/acp-25-5075-2025, 2025
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Particle mixing states and aging timescales are important for the evaluation of aerosol climate effects, but they are poorly parameterized in current models. We unravel the evolution of real-time mixing states and the aging timescale of size-resolved particles based on field measurements in urban Beijing. This study provides an observational basis for accurately parameterizing the aging timescale of aerosol particles in climate models.
Junlin Shen, Li Liu, Fengling Yuan, Biao Luo, Hongqing Qiao, Miaomiao Zhai, Gang Zhao, Hanbing Xu, Fei Li, Yu Zou, Tao Deng, Xuejiao Deng, and Ye Kuang
EGUsphere, https://doi.org/10.5194/egusphere-2025-1410, https://doi.org/10.5194/egusphere-2025-1410, 2025
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This study provides direct observational evidence that secondary organic aerosols have substantially higher real refractive indices than primary organic aerosols, challenging current model assumptions and offering recommended values that improve the accuracy of aerosol radiative effect simulations.
Yao Song, Jing Wei, Wenlong Zhao, Jinmei Ding, Xiangyu Pei, Fei Zhang, Zhengning Xu, Ruifang Shi, Ya Wei, Lu Zhang, Lingling Jin, and Zhibin Wang
Atmos. Chem. Phys., 25, 4755–4766, https://doi.org/10.5194/acp-25-4755-2025, https://doi.org/10.5194/acp-25-4755-2025, 2025
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This study investigates the size-resolved effective density (ρeff) of aerosol particles in Hangzhou using a tandem aerodynamic aerosol classifier and scanning mobility particle sizer system. The ρeff values ranged from 1.47 to 1.63 g cm-3, increasing with particle diameter. The relationship between ρeff and the particle diameter varies due to differences in the chemical composition of the particles. A new method to derive the size-resolved chemical composition of particles from ρeff is proposed.
Jürgen Gratzl, Alexander Böhmländer, Sanna Pätsi, Clara-E. Pogner, Markus Gorfer, David Brus, Konstantino Matthaios Doulgeris, Florian Wieland, Eija Asmi, Annika Saarto, Ottmar Möhler, Dominik Stolzenburg, and Hinrich Grothe
EGUsphere, https://doi.org/10.5194/egusphere-2025-1599, https://doi.org/10.5194/egusphere-2025-1599, 2025
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We studied particles in the air over one year in the Finnish sub-Arctic to understand how biological particles affect ice formation in clouds. We found that fungal spores are the main contributors to ice formation at warmer temperatures. These particles are released locally and vary with weather. Our results also show that we know very little about which fungi can form ice in the atmosphere, highlighting a major gap in our understanding of how nature influences weather and climate.
Sihan Liu, Honglei Wang, Delong Zhao, Wei Zhou, Yuanmou Du, Zhengguo Zhang, Peng Cheng, Tianliang Zhao, Yue Ke, Zihao Wu, and Mengyu Huang
Atmos. Chem. Phys., 25, 4151–4165, https://doi.org/10.5194/acp-25-4151-2025, https://doi.org/10.5194/acp-25-4151-2025, 2025
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To understand the effect of aerosols on the vertical distribution of stratocumulus microphysical quantities in southwest China, the daily variation characteristics and formation mechanism of the vertical profiles of stratocumulus microphysical characteristics in this region were described using the data of nine cloud-crossing aircraft observations over Guangxi from 10 October to 3 November 2020.
Denghui Ji, Mathias Palm, Matthias Buschmann, Kerstin Ebell, Marion Maturilli, Xiaoyu Sun, and Justus Notholt
Atmos. Chem. Phys., 25, 3889–3904, https://doi.org/10.5194/acp-25-3889-2025, https://doi.org/10.5194/acp-25-3889-2025, 2025
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Our study explores how certain aerosols, like sea salt, affect infrared heat radiation in the Arctic, potentially speeding up warming. We used advanced technology to measure aerosol composition and found that these particles grow with humidity, significantly increasing their heat-trapping effect in the infrared region, especially in winter. Our findings suggest these aerosols could be a key factor in Arctic warming, emphasizing the importance of understanding aerosols for climate prediction.
E. Johanna Horchler, Joel Alroe, Luke Harrison, Luke Cravigan, Daniel P. Harrison, and Zoran D. Ristovski
EGUsphere, https://doi.org/10.5194/egusphere-2025-465, https://doi.org/10.5194/egusphere-2025-465, 2025
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Aerosols play a role in global climate by interacting with incoming solar radiation and by taking up water vapour from the atmosphere to form clouds. Enhancing local-scale cloud cover can reduce sea surface temperatures. Coral bleaching events increased in the Great Barrier Reef (GBR) as sea surface temperatures rise. Our study found that the number of aerosols and the cloud forming ability over the GBR increased if the aerosols were transported from inland Australia rather than the ocean.
Haibiao Chen, Caiqing Yan, Liubin Huang, Lin Du, Yang Yue, Xinfeng Wang, Qingcai Chen, Mingjie Xie, Junwen Liu, Fengwen Wang, Shuhong Fang, Qiaoyun Yang, Hongya Niu, Mei Zheng, Yan Wu, and Likun Xue
Atmos. Chem. Phys., 25, 3647–3667, https://doi.org/10.5194/acp-25-3647-2025, https://doi.org/10.5194/acp-25-3647-2025, 2025
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A comprehensive understanding of the optical properties of brown carbon (BrC) is essential to accurately assess its climatic effects. Based on multi-site spectroscopic measurements, this study demonstrated the significant spatial heterogeneity in the optical and structural properties of water-soluble organic carbon (WSOC) in different regions of China and revealed factors affecting WSOC light absorption and the relationship between fluorophores and light absorption of WSOC.
Lingjun Li, Mengren Li, Xiaolong Fan, Yuping Chen, Ziyi Lin, Anqi Hou, Siqing Zhang, Ronghua Zheng, and Jinsheng Chen
Atmos. Chem. Phys., 25, 3669–3685, https://doi.org/10.5194/acp-25-3669-2025, https://doi.org/10.5194/acp-25-3669-2025, 2025
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Here, we show differences and variations in the aerosol scattering hygroscopic growth factor (f(RH)) between new particle formation (NPF) and non-NPF days and the effect of aerosol chemical compositions on f(RH) in Xiamen with in situ observations. The findings are helpful for the further understanding of aerosol hygroscopicity in a coastal city and the use of hygroscopic growth factors in models of air quality and climate change.
Roman Pohorsky, Andrea Baccarini, Natalie Brett, Brice Barret, Slimane Bekki, Gianluca Pappaccogli, Elsa Dieudonné, Brice Temime-Roussel, Barbara D'Anna, Meeta Cesler-Maloney, Antonio Donateo, Stefano Decesari, Kathy S. Law, William R. Simpson, Javier Fochesatto, Steve R. Arnold, and Julia Schmale
Atmos. Chem. Phys., 25, 3687–3715, https://doi.org/10.5194/acp-25-3687-2025, https://doi.org/10.5194/acp-25-3687-2025, 2025
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This study presents an analysis of vertical measurements of pollution in an Alaskan city during winter. It investigates the relationship between the atmospheric structure and the layering of aerosols and trace gases. Results indicate an overall very shallow surface mixing layer. The height of this layer is strongly influenced by a local shallow wind. The study also provides information on the pollution chemical composition at different altitudes, including pollution signatures from power plants.
Aoyuan Yu, Xiaojing Shen, Qianli Ma, Jiayuan Lu, Xinyao Hu, Yangmei Zhang, Quan Liu, Linlin Liang, Lei Liu, Shuo Liu, Hongfei Tong, Huizheng Che, Xiaoye Zhang, and Junying Sun
Atmos. Chem. Phys., 25, 3389–3412, https://doi.org/10.5194/acp-25-3389-2025, https://doi.org/10.5194/acp-25-3389-2025, 2025
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In this work, we utilized a volatility hygroscopicity tandem differential mobility analyzer (VH-TDMA) to investigate, for the first time, the hygroscopicity and volatility of submicron aerosols, as well as their hygroscopicity after heating, in urban Beijing during the autumn of 2023. We analyzed the size-resolved characteristics of hygroscopicity and volatility, the relationship between hygroscopic and volatile properties, and the hygroscopicity of heated submicron aerosols.
Corina Wieber, Lasse Z. Jensen, Leendert Vergeynst, Lorenz Meire, Thomas Juul-Pedersen, Kai Finster, and Tina Šantl-Temkiv
Atmos. Chem. Phys., 25, 3327–3346, https://doi.org/10.5194/acp-25-3327-2025, https://doi.org/10.5194/acp-25-3327-2025, 2025
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The Arctic region is subject to profound changes due to a warming climate. Ice-nucleating particles (INPs) in the seawater can get transported to the atmosphere and impact cloud formation. However, the sources of characteristics of INPs in the marine areas are poorly understood. We investigated the INPs in seawater from Greenlandic fjords and identified a seasonal variability, with highly active INPs originating from terrestrial sources such as glacial and soil runoff.
Silke Groß, Volker Freudenthaler, Moritz Haarig, Albert Ansmann, Carlos Toledano, David Mateos, Petra Seibert, Rodanthi-Elisavet Mamouri, Argyro Nisantzi, Josef Gasteiger, Maximilian Dollner, Anne Tipka, Manuel Schöberl, Marilena Teri, and Bernadett Weinzierl
Atmos. Chem. Phys., 25, 3191–3211, https://doi.org/10.5194/acp-25-3191-2025, https://doi.org/10.5194/acp-25-3191-2025, 2025
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Aerosols contribute to the largest uncertainties in climate change predictions. The eastern Mediterranean is a hotspot for aerosols with natural and anthropogenic contributions. We present lidar measurements performed during A-LIFE (Absorbing aerosol layers in a changing climate: aging, lifetime and dynamics) to characterize aerosols and aerosol mixtures. We extend current lidar classification and separation schemes and compare them to classification schemes using different methods.
Ludovico Di Antonio, Claudia Di Biagio, Paola Formenti, Aline Gratien, Vincent Michoud, Christopher Cantrell, Astrid Bauville, Antonin Bergé, Mathieu Cazaunau, Servanne Chevaillier, Manuela Cirtog, Patrice Coll, Barbara D'Anna, Joel F. de Brito, David O. De Haan, Juliette R. Dignum, Shravan Deshmukh, Olivier Favez, Pierre-Marie Flaud, Cecile Gaimoz, Lelia N. Hawkins, Julien Kammer, Brigitte Language, Franck Maisonneuve, Griša Močnik, Emilie Perraudin, Jean-Eudes Petit, Prodip Acharja, Laurent Poulain, Pauline Pouyes, Eva Drew Pronovost, Véronique Riffault, Kanuri I. Roundtree, Marwa Shahin, Guillaume Siour, Eric Villenave, Pascal Zapf, Gilles Foret, Jean-François Doussin, and Matthias Beekmann
Atmos. Chem. Phys., 25, 3161–3189, https://doi.org/10.5194/acp-25-3161-2025, https://doi.org/10.5194/acp-25-3161-2025, 2025
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The spectral complex refractive index (CRI) and single scattering albedo were retrieved from submicron aerosol measurements at three sites within the greater Paris area during the ACROSS field campaign (June–July 2022). Measurements revealed urban emission impact on surrounding areas. CRI full period averages at 520 nm were 1.41 – 0.037i (urban), 1.52 – 0.038i (peri-urban), and 1.50 – 0.025i (rural). Organic aerosols dominated the aerosol mass and contributed up to 22 % of absorption at 370 nm.
Leah D. Gibson, Ezra J. T. Levin, Ethan Emerson, Nick Good, Anna Hodshire, Gavin McMeeking, Kate Patterson, Bryan Rainwater, Tom Ramin, and Ben Swanson
Atmos. Chem. Phys., 25, 2745–2762, https://doi.org/10.5194/acp-25-2745-2025, https://doi.org/10.5194/acp-25-2745-2025, 2025
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From fall 2021 to summer 2023, SAIL-Net, a network of six aerosol measurement nodes, was deployed in the East River watershed (Colorado, USA) to study aerosol variability across space and time in mountainous terrain. We found that aerosol variability is influenced by elevation differences, with the most representative site in the region changing seasonally, suggesting aerosol spatial variability also varies seasonally. This work offers a blueprint for future studies in other mountainous regions.
Tahereh Alinejadtabrizi, Yi Huang, Francisco Lang, Steven Siems, Michael Manton, Luis Ackermann, Melita Keywood, Ruhi Humphries, Paul Krummel, Alastair Williams, and Greg Ayers
Atmos. Chem. Phys., 25, 2631–2648, https://doi.org/10.5194/acp-25-2631-2025, https://doi.org/10.5194/acp-25-2631-2025, 2025
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Clouds over the Southern Ocean are crucial to Earth's energy balance, but understanding the factors that control them is complex. Our research examines how weather patterns affect tiny particles called cloud condensation nuclei (CCN), which influence cloud properties. Using data from Kennaook / Cape Grim, we found that winter air from Antarctica brings cleaner conditions with lower CCN, while summer patterns from Australia transport more particles. Precipitation also helps reduce CCN in winter.
Hengjia Ou, Mingfu Cai, Yongyun Zhang, Xue Ni, Baoling Liang, Qibin Sun, Shixin Mai, Cuizhi Sun, Shengzhen Zhou, Haichao Wang, Jiaren Sun, and Jun Zhao
Atmos. Chem. Phys., 25, 2495–2513, https://doi.org/10.5194/acp-25-2495-2025, https://doi.org/10.5194/acp-25-2495-2025, 2025
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Two shipborne observations in the South China Sea (SCS) in summer and winter 2021 were conducted. Our study found aerosol hygroscopicity is higher in the SCS in summer than winter, with significant influences from various terrestrial air masses. Aerosol size distribution had a stronger effect on activation ratio than aerosol hygroscopicity in summer and vice versa in winter. Our study provides valuable information to enhance our understanding of cloud condensation nuclei activities in the SCS.
Jorge Rosas Santana, Gabriela Lima da Silva, Marcia Akemi Yamasoe, and Nilton Èvora do Rosario
EGUsphere, https://doi.org/10.5194/egusphere-2025-9, https://doi.org/10.5194/egusphere-2025-9, 2025
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This study examines a rare event in São Paulo, Brazil, where wildfire smoke from South America mixed with clouds, causing midday darkness on 19 August 2019. Satellite data, surface measurements, and air mass modeling tracked the smoke from fires in Brazil, Bolivia, and Paraguay, transported to São Paulo within two days. The smoke-cloud interaction reduced surface irradiance to zero for 40 minutes and increased radiative efficiency by 7 %, highlighting impacts on air quality, energy, and climate.
Tinghan Zhang, Ximeng Qi, Janne Lampilahti, Liangduo Chen, Xuguang Chi, Wei Nie, Xin Huang, Zehao Zou, Wei Du, Tom Kokkonen, Tuukka Petäjä, Katrianne Lehtipalo, Veli-Matti Kerminen, Aijun Ding, and Markku Kulmala
EGUsphere, https://doi.org/10.5194/egusphere-2024-3370, https://doi.org/10.5194/egusphere-2024-3370, 2025
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By comparing air ions at two “flagship” sites —the SMEAR II site in the boreal forest of Finland and the SORPES site in a megacity in eastern China—we characterized ion concentrations and their roles in new particle formation (NPF) across contrasting environments. The ion-induced fraction was much higher in clean areas. However, earlier activation of charged particles and high ion-induced fraction during quiet NPF at SORPES imply a non-negligible role for ion-induced NPF in polluted areas.
Irena Ježek Brecelj, Asta Gregorič, Lucijan Zgonik, Tjaša Rutar, Matic Ivančič, Balint Alfoldy, Griša Močnik, and Martin Rigler
EGUsphere, https://doi.org/10.5194/egusphere-2024-3553, https://doi.org/10.5194/egusphere-2024-3553, 2025
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Following a major car industry scandal involving diesel emissions tests, Europe introduced new testing procedures. However, concerns remained about their effectiveness. Our independent study examined real-world vehicle emissions and revealed encouraging findings: modern diesel cars perform as well as, or even better than, gasoline cars in terms of nitrogen oxides emissions. We found the same pattern for soot particles, challenging common perceptions about diesel's environmental impact.
Kevin R. Barry, Thomas C. J. Hill, Sonia M. Kreidenweis, Paul J. DeMott, Yutaka Tobo, and Jessie M. Creamean
EGUsphere, https://doi.org/10.5194/egusphere-2025-128, https://doi.org/10.5194/egusphere-2025-128, 2025
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The Arctic is changing rapidly, and we sought to better understand how their clouds may change in the future through quantifying the natural cloud seeding particles over a year and uncover what they are made of. We wanted to determine their likely sources through concurrent DNA sequencing of airborne bacteria and fungi and found a persistent mixture of local and longer-range sources at all times.
Bighnaraj Sarangi, Darrel Baumgardner, Ana Isabel Calvo, Benjamin Bolaños-Rosero, Roberto Fraile, Alberto Rodríguez-Fernández, Delia Fernández-González, Carlos Blanco-Alegre, Cátia Gonçalves, Estela D. Vicente, and Olga L. Mayol-Bracero
Atmos. Chem. Phys., 25, 843–865, https://doi.org/10.5194/acp-25-843-2025, https://doi.org/10.5194/acp-25-843-2025, 2025
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Measurements of fluorescing aerosol particle properties have been made during two major African dust events, one over the island of Puerto Rico and the other over the city of León, Spain. The measurements were made with two wideband integrated bioaerosol spectrometers. A significant change in the background aerosol properties, at both locations, is observed when the dust is in the respective regions.
Lijing Chen, Lei Zhang, Yong She, Zhaoliang Zeng, Yu Zheng, Biao Tian, Wenqian Zhang, Zhaohui Liu, Huizheng Che, and Minghu Ding
Atmos. Chem. Phys., 25, 727–739, https://doi.org/10.5194/acp-25-727-2025, https://doi.org/10.5194/acp-25-727-2025, 2025
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Aerosol optical depth (AOD) at Zhongshan Station varies seasonally, with lower values in summer and higher values in winter. Winter and spring AOD increases due to reduced fine-mode particles, while summer and autumn increases are linked to particle growth. Diurnal AOD variation correlates positively with temperature but negatively with wind speed and humidity. Backward trajectories show that aerosols on high-AOD (low-AOD) days primarily originate from the ocean (interior Antarctica).
Shravan Deshmukh, Laurent Poulain, Birgit Wehner, Silvia Henning, Jean-Eudes Petit, Pauline Fombelle, Olivier Favez, Hartmut Herrmann, and Mira Pöhlker
Atmos. Chem. Phys., 25, 741–758, https://doi.org/10.5194/acp-25-741-2025, https://doi.org/10.5194/acp-25-741-2025, 2025
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Aerosol hygroscopicity has been investigated at a sub-urban site in Paris; analysis shows the sub-saturated regime's measured hygroscopicity and the chemically derived hygroscopic growth, shedding light on the large effect of external particle mixing and its influence on predicting hygroscopicity.
Takeshi Kinase, Fumikazu Taketani, Masayuki Takigawa, Chunmao Zhu, Yongwon Kim, Petr Mordovskoi, and Yugo Kanaya
Atmos. Chem. Phys., 25, 143–156, https://doi.org/10.5194/acp-25-143-2025, https://doi.org/10.5194/acp-25-143-2025, 2025
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Boreal forest wildfires in interior Alaska represent an important black carbon (BC) source for the Arctic and surrounding regions. We observed BC and carbon monoxide (CO) concentrations in the Poker Flat Research Range since 2016 and found a positive correlation between the observed BC / ∆CO ratio and fire radiative power (FRP) observed in Alaska and Canada. Our finding suggests the BC emission factor and/or inventory could be potentially improved by using FRP.
Meredith Dournaux, Pierre Tulet, Joris Pianezze, Jérome Brioude, Jean-Marc Metzger, and Melilotus Thyssen
EGUsphere, https://doi.org/10.5194/egusphere-2024-3747, https://doi.org/10.5194/egusphere-2024-3747, 2025
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Aerosol measurements collected during six oceanographic campaigns carried out in 2021 and 2023 in the southwest Indian Ocean are presented and analyzed in this paper. The results highlight a large variability in the aerosol concentration, size and water vapor affinity depending on in-situ conditions and air mass transport over the ocean. Marine aerosol chemical composition is highly variable over this region, and should be considered to better study their impacts on regional weather and climate.
Erin N. Raif, Sarah L. Barr, Mark D. Tarn, James B. McQuaid, Martin I. Daily, Steven J. Abel, Paul A. Barrett, Keith N. Bower, Paul R. Field, Kenneth S. Carslaw, and Benjamin J. Murray
Atmos. Chem. Phys., 24, 14045–14072, https://doi.org/10.5194/acp-24-14045-2024, https://doi.org/10.5194/acp-24-14045-2024, 2024
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Ice-nucleating particles (INPs) allow ice to form in clouds at temperatures warmer than −35°C. We measured INP concentrations over the Norwegian and Barents seas in weather events where cold air is ejected from the Arctic. These concentrations were among the highest measured in the Arctic. It is likely that the INPs were transported to the Arctic from distant regions. These results show it is important to consider hemispheric-scale INP processes to understand INP concentrations in the Arctic.
Fernando Rejano, Andrea Casans, Marta Via, Juan Andrés Casquero-Vera, Sonia Castillo, Hassan Lyamani, Alberto Cazorla, Elisabeth Andrews, Daniel Pérez-Ramírez, Andrés Alastuey, Francisco Javier Gómez-Moreno, Lucas Alados-Arboledas, Francisco José Olmo, and Gloria Titos
Atmos. Chem. Phys., 24, 13865–13888, https://doi.org/10.5194/acp-24-13865-2024, https://doi.org/10.5194/acp-24-13865-2024, 2024
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This study provides valuable insights to improve cloud condensation nuclei (CCN) estimations at a high-altitude remote site which is influenced by nearby urban pollution. Understanding the factors that affect CCN estimations is essential to improve the CCN data coverage worldwide and assess aerosol–cloud interactions on a global scale. This is crucial for improving climate models, since aerosol–cloud interactions are the most important source of uncertainty in climate projections.
Haochi Che, Lu Zhang, Michal Segal-Rozenhaimer, Caroline Dang, Paquita Zuidema, and Arthur J. Sedlacek III
EGUsphere, https://doi.org/10.5194/egusphere-2024-3304, https://doi.org/10.5194/egusphere-2024-3304, 2024
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We investigated how biomass burning (BB) affects cloud formation in the southeast Atlantic. We found that aerosol hygroscopicity, which influences cloud droplet formation, varied monthly and differed significantly between 2016 and 2017, due to changes in sulfate aerosols. These changes were driven by BB burning conditions, which were likely influenced by meteorological factors. This study highlights the important role of BB in shaping aerosol properties and clouds in the region.
Lu Zhang, Michal Segal-Rozenhaimer, Haochi Che, Caroline Dang, Junying Sun, Ye Kuang, Paola Formenti, and Steven G. Howell
Atmos. Chem. Phys., 24, 13849–13864, https://doi.org/10.5194/acp-24-13849-2024, https://doi.org/10.5194/acp-24-13849-2024, 2024
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Using airborne measurements over the southeast Atlantic Ocean, we examined how much moisture aerosols take up during Africa’s biomass burning season. Our study revealed the important role of organic aerosols and introduced a predictive model for moisture uptake, accounting for organics, sulfate, and black carbon, summarizing results from various campaigns. These findings improve our understanding of aerosol–moisture interactions and their radiative effects in this climatically critical region.
Mary C. Robinson, Kaitlin Schueth, and Karin Ardon-Dryer
Atmos. Chem. Phys., 24, 13733–13750, https://doi.org/10.5194/acp-24-13733-2024, https://doi.org/10.5194/acp-24-13733-2024, 2024
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On 26 February 2023, New Mexico and West Texas were impacted by a severe dust storm. To analyze this storm, 28 meteorological stations and 19 PM2.5 and PM10 stations were used. Dust particles were in the air for 16 h, and dust storm conditions lasted for up to 120 min. Hourly PM2.5 and PM10 concentrations were up to 518 and 9983 µg m−3, respectively. For Lubbock, Texas, the maximum PM2.5 concentrations were the highest ever recorded.
Jerome D. Fast, Adam C. Varble, Fan Mei, Mikhail Pekour, Jason Tomlinson, Alla Zelenyuk, Art J. Sedlacek III, Maria Zawadowicz, and Louisa Emmons
Atmos. Chem. Phys., 24, 13477–13502, https://doi.org/10.5194/acp-24-13477-2024, https://doi.org/10.5194/acp-24-13477-2024, 2024
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Aerosol property measurements recently collected on the ground and by a research aircraft in central Argentina during the Cloud, Aerosol, and Complex Terrain Interactions (CACTI) campaign exhibit large spatial and temporal variability. These measurements coupled with coincident meteorological information provide a valuable data set needed to evaluate and improve model predictions of aerosols in a traditionally data-sparse region of South America.
Julika Zinke, Gabriel Pereira Freitas, Rachel Ann Foster, Paul Zieger, Ernst Douglas Nilsson, Piotr Markuszewski, and Matthew Edward Salter
Atmos. Chem. Phys., 24, 13413–13428, https://doi.org/10.5194/acp-24-13413-2024, https://doi.org/10.5194/acp-24-13413-2024, 2024
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Bioaerosols, which can influence climate and human health, were studied in the Baltic Sea. In May and August 2021, we used a sea spray simulation chamber during two ship-based campaigns to collect and measure these aerosols. We found that microbes were enriched in air compared to seawater. Bacterial diversity was analysed using DNA sequencing. Our methods provided consistent estimates of microbial emission fluxes, aligning with previous studies.
Chimurkar Navinya, Taveen Singh Kapoor, Gupta Anurag, Chandra Venkataraman, Harish C. Phuleria, and Rajan K. Chakrabarty
Atmos. Chem. Phys., 24, 13285–13297, https://doi.org/10.5194/acp-24-13285-2024, https://doi.org/10.5194/acp-24-13285-2024, 2024
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Brown carbon (BrC) aerosols show an order-of-magnitude variation in their light absorption strength. Our understanding of BrC from real-world biomass burning remains limited, complicating the determination of its radiative impact. Our study reports absorption properties of BrC emitted from four major biomass burning sources using field measurements in India. It develops an absorption parameterization for BrC and examines the spatial variability in BrC's absorption strength across India.
Yuhang Hao, Peizhao Li, Yafeng Gou, Zhenshuai Wang, Mi Tian, Yang Chen, Ye Kuang, Hanbing Xu, Fenglian Wan, Yuqian Luo, Wei Huang, and Jing Chen
EGUsphere, https://doi.org/10.5194/egusphere-2024-3242, https://doi.org/10.5194/egusphere-2024-3242, 2024
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Intensified heatwaves with the global warming have influenced new particle formation (NPF) and related aerosol physicochemical properties. We show that aerosol optical hygroscopicity (f(RH)) was generally higher on NPF event days than non-event cases, likely due to enhanced secondary formation and subsequent growth of both pre-existing and newly formed particles with stronger photooxidation specifically under persistent heatwaves. This would further impact the aerosol direct radiative forcing.
Rafael Stern, Joel F. de Brito, Samara Carbone, Luciana Varanda Rizzo, Jonathan Daniel Muller, and Paulo Artaxo
EGUsphere, https://doi.org/10.5194/egusphere-2024-3339, https://doi.org/10.5194/egusphere-2024-3339, 2024
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Our work reveals the impact of forest fires on climate. We found that particles related to direct emissions from fires, beyond the well-known effect of absorbing light and thus heating the atmosphere, are also very efficient in scattering light, which causes an atmospheric cooling effect. In our remote study site, most of the particles presented a different chemical composition then particles directly emitted by the fires, but those were the main responsible for total light extinction.
Sami D. Harni, Minna Aurela, Sanna Saarikoski, Jarkko V. Niemi, Harri Portin, Hanna Manninen, Ville Leinonen, Pasi Aalto, Phil K. Hopke, Tuukka Petäjä, Topi Rönkkö, and Hilkka Timonen
Atmos. Chem. Phys., 24, 12143–12160, https://doi.org/10.5194/acp-24-12143-2024, https://doi.org/10.5194/acp-24-12143-2024, 2024
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In this study, particle number size distribution data were used in a novel way in positive matrix factorization analysis to find aerosol source profiles in the area. Measurements were made in Helsinki at a street canyon and urban background sites between February 2015 and June 2019. Five different aerosol sources were identified. These sources underline the significance of traffic-related emissions in urban environments despite recent improvements in emission reduction technologies.
Natalie G. Ratcliffe, Claire L. Ryder, Nicolas Bellouin, Stephanie Woodward, Anthony Jones, Ben Johnson, Lisa-Maria Wieland, Maximilian Dollner, Josef Gasteiger, and Bernadett Weinzierl
Atmos. Chem. Phys., 24, 12161–12181, https://doi.org/10.5194/acp-24-12161-2024, https://doi.org/10.5194/acp-24-12161-2024, 2024
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Large mineral dust particles are more abundant in the atmosphere than expected and have different impacts on the environment than small particles, which are better represented in climate models. We use aircraft measurements to assess a climate model representation of large-dust transport. We find that the model underestimates the amount of large dust at all stages of transport and that fast removal of the large particles increases this underestimation with distance from the Sahara.
Sergio Rodríguez and Jessica López-Darias
Atmos. Chem. Phys., 24, 12031–12053, https://doi.org/10.5194/acp-24-12031-2024, https://doi.org/10.5194/acp-24-12031-2024, 2024
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Extreme Saharan dust events expanded northward to the Atlantic and Europe, prompting record-breaking PM10 and PM2.5 events. These episodes are caused by low-to-high dipole meteorology during hemispheric anomalies characterized by subtropical anticyclones shifting to higher latitudes, anomalous low pressures beyond the tropics and amplified Rossby waves. Extreme dust events occur in a paradoxical context of a multidecadal decrease in dust emissions, a topic that requires further investigation.
Valeria Mardoñez-Balderrama, Griša Močnik, Marco Pandolfi, Robin L. Modini, Fernando Velarde, Laura Renzi, Angela Marinoni, Jean-Luc Jaffrezo, Isabel Moreno R., Diego Aliaga, Federico Bianchi, Claudia Mohr, Martin Gysel-Beer, Patrick Ginot, Radovan Krejci, Alfred Wiedensohler, Gaëlle Uzu, Marcos Andrade, and Paolo Laj
Atmos. Chem. Phys., 24, 12055–12077, https://doi.org/10.5194/acp-24-12055-2024, https://doi.org/10.5194/acp-24-12055-2024, 2024
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Levels of black carbon (BC) are scarcely reported in the Southern Hemisphere, especially in high-altitude conditions. This study provides insight into the concentration level, variability, and optical properties of BC in La Paz and El Alto and at the Chacaltaya Global Atmosphere Watch Station. Two methods of source apportionment of absorption were tested and compared showing traffic as the main contributor to absorption in the urban area, in addition to biomass and open waste burning.
Krishnakant Budhavant, Mohanan Remani Manoj, Hari Ram Chandrika Rajendran Nair, Samuel Mwaniki Gaita, Henry Holmstrand, Abdus Salam, Ahmed Muslim, Sreedharan Krishnakumari Satheesh, and Örjan Gustafsson
Atmos. Chem. Phys., 24, 11911–11925, https://doi.org/10.5194/acp-24-11911-2024, https://doi.org/10.5194/acp-24-11911-2024, 2024
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The South Asian Pollution Experiment 2018 used access to three strategically located receptor observatories. Observational constraints revealed opposing trends in the mass absorption cross sections of black carbon (BC MAC) and brown carbon (BrC MAC) during long-range transport. Models estimating the climate effects of BC aerosols may have underestimated the ambient BC MAC over distant receptor areas, leading to discrepancies in aerosol absorption predicted by observation-constrained models.
Abigail S. Williams, Jeramy L. Dedrick, Lynn M. Russell, Florian Tornow, Israel Silber, Ann M. Fridlind, Benjamin Swanson, Paul J. DeMott, Paul Zieger, and Radovan Krejci
Atmos. Chem. Phys., 24, 11791–11805, https://doi.org/10.5194/acp-24-11791-2024, https://doi.org/10.5194/acp-24-11791-2024, 2024
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The measured aerosol size distribution modes reveal distinct properties characteristic of cold-air outbreaks in the Norwegian Arctic. We find higher sea spray number concentrations, smaller Hoppel minima, lower effective supersaturations, and accumulation-mode particle scavenging during cold-air outbreaks. These results advance our understanding of cold-air outbreak aerosol–cloud interactions in order to improve their accurate representation in models.
Franziska Vogel, Michael P. Adams, Larissa Lacher, Polly B. Foster, Grace C. E. Porter, Barbara Bertozzi, Kristina Höhler, Julia Schneider, Tobias Schorr, Nsikanabasi S. Umo, Jens Nadolny, Zoé Brasseur, Paavo Heikkilä, Erik S. Thomson, Nicole Büttner, Martin I. Daily, Romy Fösig, Alexander D. Harrison, Jorma Keskinen, Ulrike Proske, Jonathan Duplissy, Markku Kulmala, Tuukka Petäjä, Ottmar Möhler, and Benjamin J. Murray
Atmos. Chem. Phys., 24, 11737–11757, https://doi.org/10.5194/acp-24-11737-2024, https://doi.org/10.5194/acp-24-11737-2024, 2024
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Primary ice formation in clouds strongly influences their properties; hence, it is important to understand the sources of ice-nucleating particles (INPs) and their variability. We present 2 months of INP measurements in a Finnish boreal forest using a new semi-autonomous INP counting device based on gas expansion. These results show strong variability in INP concentrations, and we present a case that the INPs we observe are, at least some of the time, of biological origin.
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