Articles | Volume 23, issue 7
https://doi.org/10.5194/acp-23-4185-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-4185-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Nitrate chemistry in the northeast US – Part 1: Nitrogen isotope seasonality tracks nitrate formation chemistry
Claire Bekker
Department of Earth, Environmental, and Planetary Sciences, Brown
University, Providence, RI 02912, USA
now at: Department of Environmental Health Sciences, University of
California Los Angeles, Los Angeles, CA 90095, USA
Wendell W. Walters
CORRESPONDING AUTHOR
Institute at Brown for Environment and Society, Brown University,
Providence, RI 02912, USA
now at: Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA
Lee T. Murray
Department of Earth and Environmental Sciences, University of
Rochester, Rochester, NY 14627, USA
Meredith G. Hastings
Department of Earth, Environmental, and Planetary Sciences, Brown
University, Providence, RI 02912, USA
Institute at Brown for Environment and Society, Brown University,
Providence, RI 02912, USA
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Heejeong Kim, Wendell W. Walters, Claire Bekker, Lee T. Murray, and Meredith G. Hastings
Atmos. Chem. Phys., 23, 4203–4219, https://doi.org/10.5194/acp-23-4203-2023, https://doi.org/10.5194/acp-23-4203-2023, 2023
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Atmospheric nitrate has an important impact on human and ecosystem health. We evaluated atmospheric nitrate formation pathways in the northeastern US utilizing oxygen isotope compositions, which indicated a significant difference between the phases of nitrate (i.e., gas vs. particle). Comparing the observations with model simulations indicated that N2O5 hydrolysis chemistry was overpredicted. Our study has important implications for improving atmospheric chemistry model representation.
William J. Collins, Fiona M. O'Connor, Rachael E. Byrom, Øivind Hodnebrog, Patrick Jöckel, Mariano Mertens, Gunnar Myhre, Matthias Nützel, Dirk Olivié, Ragnhild Bieltvedt Skeie, Laura Stecher, Larry W. Horowitz, Vaishali Naik, Gregory Faluvegi, Ulas Im, Lee T. Murray, Drew Shindell, Kostas Tsigaridis, Nathan Luke Abraham, and James Keeble
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Methane and carbon dioxide emission rates were calculated for facilities across several sectors in New York State using aerial observations. Of the sampled facilities, landfills dominated the methane emission rates while combustion facilities had the highest carbon dioxide emission rates, followed by landfills. The self-reported EPA inventory is mostly underestimating landfill methane emissions apart from a few facilities with comparable numbers.
Wendell W. Walters, Masayuki Takeuchi, Danielle E. Blum, Gamze Eris, David Tanner, Weiqi Xu, Jean Rivera-Rios, Fobang Liu, Tianchang Xu, Greg Huey, Justin B. Min, Rodney Weber, Nga L. Ng, and Meredith G. Hastings
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We studied how chemicals released from plants and pollution interact in the atmosphere, affecting air quality and climate. By combining laboratory experiments and chemistry models, we tracked unique chemical fingerprints to understand how nitrogen compounds transform to form particles in the air. Our findings help explain the role of these reactions in pollution and provide tools to improve predictions for cleaner air and better climate policies.
Benjamin Hmiel, Vasilii V. Petrenko, Christo Buizert, Andrew M. Smith, Michael N. Dyonisius, Philip Place, Bin Yang, Quan Hua, Ross Beaudette, Jeffrey P. Severinghaus, Christina Harth, Ray F. Weiss, Lindsey Davidge, Melisa Diaz, Matthew Pacicco, James A. Menking, Michael Kalk, Xavier Faïn, Alden Adolph, Isaac Vimont, and Lee T. Murray
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Wendell W. Walters, Masayuki Takeuchi, Nga L. Ng, and Meredith G. Hastings
Geosci. Model Dev., 17, 4673–4687, https://doi.org/10.5194/gmd-17-4673-2024, https://doi.org/10.5194/gmd-17-4673-2024, 2024
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The study introduces a novel chemical mechanism for explicitly tracking oxygen isotope transfer in oxidized reactive nitrogen and odd oxygen using the Regional Atmospheric Chemistry Mechanism, version 2. This model enhances our ability to simulate and compare oxygen isotope compositions of reactive nitrogen, revealing insights into oxidation chemistry. The approach shows promise for improving atmospheric chemistry models and tropospheric oxidation capacity predictions.
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Atmos. Chem. Phys., 23, 5605–5622, https://doi.org/10.5194/acp-23-5605-2023, https://doi.org/10.5194/acp-23-5605-2023, 2023
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A seasonal analysis of the nitrogen isotopes of atmospheric nitrate over the remote Southern Ocean reveals that similar natural NOx sources dominate in spring and summer, while winter is representative of background-level conditions. The oxygen isotopes suggest that similar oxidation pathways involving more ozone occur in spring and winter, while the hydroxyl radical is the main oxidant in summer. This work helps to constrain NOx cycling and oxidant budgets in a data-sparse remote marine region.
Heejeong Kim, Wendell W. Walters, Claire Bekker, Lee T. Murray, and Meredith G. Hastings
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Atmospheric nitrate has an important impact on human and ecosystem health. We evaluated atmospheric nitrate formation pathways in the northeastern US utilizing oxygen isotope compositions, which indicated a significant difference between the phases of nitrate (i.e., gas vs. particle). Comparing the observations with model simulations indicated that N2O5 hydrolysis chemistry was overpredicted. Our study has important implications for improving atmospheric chemistry model representation.
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Hao Guo, Clare M. Flynn, Michael J. Prather, Sarah A. Strode, Stephen D. Steenrod, Louisa Emmons, Forrest Lacey, Jean-Francois Lamarque, Arlene M. Fiore, Gus Correa, Lee T. Murray, Glenn M. Wolfe, Jason M. St. Clair, Michelle Kim, John Crounse, Glenn Diskin, Joshua DiGangi, Bruce C. Daube, Roisin Commane, Kathryn McKain, Jeff Peischl, Thomas B. Ryerson, Chelsea Thompson, Thomas F. Hanisco, Donald Blake, Nicola J. Blake, Eric C. Apel, Rebecca S. Hornbrook, James W. Elkins, Eric J. Hintsa, Fred L. Moore, and Steven C. Wofsy
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The nitrogen (N) isotopic composition of atmospheric nitrate in the Southern Ocean (SO) marine boundary layer (MBL) reveals the importance of oceanic alkyl nitrate emissions as a source of reactive N to the atmosphere. The oxygen isotopic composition suggests peroxy radicals contribute up to 63 % to NO oxidation and that nitrate forms via the OH pathway. This work improves our understanding of reactive N sources and cycling in a remote marine region, a proxy for the pre-industrial atmosphere.
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Lee T. Murray, Eric M. Leibensperger, Clara Orbe, Loretta J. Mickley, and Melissa Sulprizio
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Chemical-transport models are tools used to study air pollution and inform public policy. However, they are limited by the availability of archived meteorology. Here, we describe how the GEOS-Chem chemical-transport model may now be driven by meteorology archived from a state-of-the-art general circulation model for past and future climates, allowing it to be used to explore the impact of climate change on air pollution and atmospheric composition.
Hao Guo, Clare M. Flynn, Michael J. Prather, Sarah A. Strode, Stephen D. Steenrod, Louisa Emmons, Forrest Lacey, Jean-Francois Lamarque, Arlene M. Fiore, Gus Correa, Lee T. Murray, Glenn M. Wolfe, Jason M. St. Clair, Michelle Kim, John Crounse, Glenn Diskin, Joshua DiGangi, Bruce C. Daube, Roisin Commane, Kathryn McKain, Jeff Peischl, Thomas B. Ryerson, Chelsea Thompson, Thomas F. Hanisco, Donald Blake, Nicola J. Blake, Eric C. Apel, Rebecca S. Hornbrook, James W. Elkins, Eric J. Hintsa, Fred L. Moore, and Steven Wofsy
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Jiajue Chai, Jack E. Dibb, Bruce E. Anderson, Claire Bekker, Danielle E. Blum, Eric Heim, Carolyn E. Jordan, Emily E. Joyce, Jackson H. Kaspari, Hannah Munro, Wendell W. Walters, and Meredith G. Hastings
Atmos. Chem. Phys., 21, 13077–13098, https://doi.org/10.5194/acp-21-13077-2021, https://doi.org/10.5194/acp-21-13077-2021, 2021
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Huan Fang, Wendell W. Walters, David Mase, and Greg Michalski
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A new photochemical reaction scheme that incorporates nitrogen isotopes has been developed to simulate isotope tracers in air pollution. The model contains 16 N compounds, and 96 reactions involving N used in the Regional Atmospheric Chemistry Mechanism (RACM) were replicated using 15N in a new mechanism called iNRACM. The model is able to predict d15N variations in NOx, HONO, and HNO3 that are similar to those observed in aerosol and gases in the troposphere.
Veronica R. Rollinson, Julie Granger, Sydney C. Clark, Mackenzie L. Blanusa, Claudia P. Koerting, Jamie M. P. Vaudrey, Lija A. Treibergs, Holly C. Westbrook, Catherine M. Matassa, Meredith G. Hastings, and Craig R. Tobias
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We measured nutrients and the naturally occurring nitrogen (N) and oxygen (O) stable isotope ratios of nitrate discharged from a New England river over an annual cycle, to monitor N loading and identify dominant sources from the watershed. We uncovered a seasonality to loading and sources of N from the watershed. Seasonality in the nitrate isotope ratios also informed on N cycling, conforming to theoretical expectations of riverine nutrient cycling.
Paul T. Griffiths, Lee T. Murray, Guang Zeng, Youngsub Matthew Shin, N. Luke Abraham, Alexander T. Archibald, Makoto Deushi, Louisa K. Emmons, Ian E. Galbally, Birgit Hassler, Larry W. Horowitz, James Keeble, Jane Liu, Omid Moeini, Vaishali Naik, Fiona M. O'Connor, Naga Oshima, David Tarasick, Simone Tilmes, Steven T. Turnock, Oliver Wild, Paul J. Young, and Prodromos Zanis
Atmos. Chem. Phys., 21, 4187–4218, https://doi.org/10.5194/acp-21-4187-2021, https://doi.org/10.5194/acp-21-4187-2021, 2021
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We analyse the CMIP6 Historical and future simulations for tropospheric ozone, a species which is important for many aspects of atmospheric chemistry. We show that the current generation of models agrees well with observations, being particularly successful in capturing trends in surface ozone and its vertical distribution in the troposphere. We analyse the factors that control ozone and show that they evolve over the period of the CMIP6 experiments.
Vasilii V. Petrenko, Andrew M. Smith, Edward M. Crosier, Roxana Kazemi, Philip Place, Aidan Colton, Bin Yang, Quan Hua, and Lee T. Murray
Atmos. Meas. Tech., 14, 2055–2063, https://doi.org/10.5194/amt-14-2055-2021, https://doi.org/10.5194/amt-14-2055-2021, 2021
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This paper presents an improved methodology for measurements of atmospheric concentration of carbon-14-containing carbon monoxide (14CO), as well as a 1-year dataset that demonstrates the methodology. Atmospheric 14CO concentration measurements are useful for improving the understanding of spatial and temporal variability of hydroxyl radical concentrations. Key improvements over prior methods include a greatly reduced air sample size and accurate procedural blank characterization.
Guitao Shi, Hongmei Ma, Zhengyi Hu, Zhenlou Chen, Chunlei An, Su Jiang, Yuansheng Li, Tianming Ma, Jinhai Yu, Danhe Wang, Siyu Lu, Bo Sun, and Meredith G. Hastings
The Cryosphere, 15, 1087–1095, https://doi.org/10.5194/tc-15-1087-2021, https://doi.org/10.5194/tc-15-1087-2021, 2021
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It is important to understand atmospheric chemistry over Antarctica under a changing climate. Thus snow collected on a traverse from the coast to Dome A was used to investigate variations in snow chemistry. The non-sea-salt fractions of K+, Mg2+, and Ca2+ are associated with terrestrial inputs, and nssCl− is from HCl. In general, proportions of non-sea-salt fractions of ions to the totals are higher in the interior areas than on the coast, and the proportions are higher in summer than in winter.
David S. Stevenson, Alcide Zhao, Vaishali Naik, Fiona M. O'Connor, Simone Tilmes, Guang Zeng, Lee T. Murray, William J. Collins, Paul T. Griffiths, Sungbo Shim, Larry W. Horowitz, Lori T. Sentman, and Louisa Emmons
Atmos. Chem. Phys., 20, 12905–12920, https://doi.org/10.5194/acp-20-12905-2020, https://doi.org/10.5194/acp-20-12905-2020, 2020
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We present historical trends in atmospheric oxidizing capacity (OC) since 1850 from the latest generation of global climate models and compare these with estimates from measurements. OC controls levels of many key reactive gases, including methane (CH4). We find small model trends up to 1980, then increases of about 9 % up to 2014, disagreeing with (uncertain) measurement-based trends. Major drivers of OC trends are emissions of CH4, NOx, and CO; these will be important for future CH4 trends.
Wendell W. Walters, Linlin Song, Jiajue Chai, Yunting Fang, Nadia Colombi, and Meredith G. Hastings
Atmos. Chem. Phys., 20, 11551–11567, https://doi.org/10.5194/acp-20-11551-2020, https://doi.org/10.5194/acp-20-11551-2020, 2020
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This article details new field observations of the nitrogen stable isotopic composition of ammonia emitted from vehicles conducted in the US and China. Vehicle emissions of ammonia may be a significant source to urban regions with important human health and environmental implications. Our measurements have indicated a consistent isotopic signature from vehicle ammonia emissions. The nitrogen isotopic composition of ammonia may be a useful tool for tracking vehicle emissions.
Cited articles
Alexander, B., Sherwen, T., Holmes, C. D., Fisher, J. A., Chen, Q., Evans, M. J., and Kasibhatla, P.: Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations, Atmos. Chem. Phys., 20, 3859–3877, https://doi.org/10.5194/acp-20-3859-2020, 2020.
Amos, H. M., Jacob, D. J., Holmes, C. D., Fisher, J. A., Wang, Q., Yantosca, R. M., Corbitt, E. S., Galarneau, E., Rutter, A. P., Gustin, M. S., Steffen, A., Schauer, J. J., Graydon, J. A., Louis, V. L. St., Talbot, R. W., Edgerton, E. S., Zhang, Y., and Sunderland, E. M.: Gas-particle partitioning of atmospheric Hg(II) and its effect on global mercury deposition, Atmos. Chem. Phys., 12, 591–603, https://doi.org/10.5194/acp-12-591-2012, 2012.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Bates, K. H. and Jacob, D. J.: A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol, Atmos. Chem. Phys., 19, 9613–9640, https://doi.org/10.5194/acp-19-9613-2019, 2019.
Bauer, S. E., Koch, D., Unger, N., Metzger, S. M., Shindell, D. T., and Streets, D. G.: Nitrate aerosols today and in 2030: a global simulation including aerosols and tropospheric ozone, Atmos. Chem. Phys., 7, 5043–5059, https://doi.org/10.5194/acp-7-5043-2007, 2007.
Baumgardner, Ralph E., Lavery, T. F., Rogers, C. M., and Isil, S. S.:
Estimates of the Atmospheric Deposition of Sulfur and Nitrogen Species:
Clean Air Status and Trends Network, 1990–2000, Environ. Sci. Technol., 36,
2614–2629, https://doi.org/10.1021/es011146g, 2002.
Benedict, K. B., Carrico, C. M., Kreidenweis, S. M., Schichtel, B., Malm, W.
C., and Collett Jr., J. L.: A seasonal nitrogen deposition budget for Rocky
Mountain National Park, Ecol. Appl., 23, 1156–1169,
https://doi.org/10.1890/12-1624.1, 2013.
Bey, I., Jacob, D. J., Yantosca, R. M., Logan, J. A., Field, B. D., Fiore,
A. M., Li, Q., Liu, H. Y., Mickley, L. J., and Schultz, M. G.: Global
modeling of tropospheric chemistry with assimilated meteorology: Model
description and evaluation, J. Geophys. Atmos., 106, 23073–23095,
https://doi.org/10.1029/2001JD000807, 2001.
Beyn, F., Matthias, V., and Dähnke, K.: Changes in atmospheric nitrate
deposition in Germany – An isotopic perspective, Environ. Pollut., 194,
1–10, https://doi.org/10.1016/j.envpol.2014.06.043, 2014.
Beyn, F., Matthias, V., Aulinger, A., and Dähnke, K.: Do N-isotopes in
atmospheric nitrate deposition reflect air pollution levels?, Atmos.
Environ., 107, 281–288, https://doi.org/10.1016/j.atmosenv.2015.02.057,
2015.
Bloss, W. J., Evans, M. J., Lee, J. D., Sommariva, R., Heard, D. E., and
Pilling, M. J.: The oxidative capacity of the troposphere: Coupling of field
measurements of OH and a global chemistry transport model, Faraday Discuss.,
130, 425–436, https://doi.org/10.1039/B419090D, 2005.
Böhlke, J. K., Gwinn, C. J., and Coplen, T. B.: New Reference Materials
for Nitrogen-Isotope-Ratio Measurements, Geostandard. Newslett., 17,
159–164, https://doi.org/10.1111/j.1751-908X.1993.tb00131.x, 1993.
Böhlke, J. K., Mroczkowski, S. J., and Coplen, T. B.: Oxygen isotopes in
nitrate: New reference materials for 18O: 17O: 16O measurements and
observations on nitrate-water equilibration, Rapid Commun. Mass. Sp., 17,
1835–1846, https://doi.org/10.1002/rcm.1123, 2003.
Breider, T. J., Mickley, L. J., Jacob, D. J., Ge, C., Wang, J., Payer
Sulprizio, M., Croft, B., Ridley, D. A., McConnell, J. R., and Sharma, S.:
Multidecadal trends in aerosol radiative forcing over the Arctic:
Contribution of changes in anthropogenic aerosol to Arctic warming since
1980, J. Geophys. Atmos., 122, 3573–3594,
https://doi.org/10.1002/2016JD025321, 2017.
Carslaw, D. C. and Ropkins, K.: Openair – an R package for air quality data
analysis, Environ. Modell. Softw., 27, 52–61,
https://doi.org/10.1016/j.envsoft.2011.09.008, 2012.
Casciotti, K. L., Sigman, D. M., Hastings, M. G., Böhlke, J. K., and
Hilkert, A.: Measurement of the oxygen isotopic composition of nitrate in
seawater and freshwater using the denitrifier method, Anal. Chem., 74,
4905–4912, https://doi.org/10.1021/ac020113w, 2002.
CASTNET Site Locations: https://www.epa.gov/castnet/castnet-site-locations,
last access: 7 February 2023.
Chang, Y., Zhang, Y., Tian, C., Zhang, S., Ma, X., Cao, F., Liu, X., Zhang, W., Kuhn, T., and Lehmann, M. F.: Nitrogen isotope fractionation during gas-to-particle conversion of NOx to NO in the atmosphere – implications for isotope-based NOx source apportionment, Atmos. Chem. Phys., 18, 11647–11661, https://doi.org/10.5194/acp-18-11647-2018, 2018.
Chang, Y., Zhang, Y.-L., Li, J., Tian, C., Song, L., Zhai, X., Zhang, W., Huang, T., Lin, Y.-C., Zhu, C., Fang, Y., Lehmann, M. F., and Chen, J.: Isotopic constraints on the atmospheric sources and formation of nitrogenous species in clouds influenced by biomass burning, Atmos. Chem. Phys., 19, 12221–12234, https://doi.org/10.5194/acp-19-12221-2019, 2019.
Cheng, I., Zhang, L., Blanchard, P., Dalziel, J., and Tordon, R.: Concentration-weighted trajectory approach to identifying potential sources of speciated atmospheric mercury at an urban coastal site in Nova Scotia, Canada, Atmos. Chem. Phys., 13, 6031–6048, https://doi.org/10.5194/acp-13-6031-2013, 2013.
Clarke, J. F., Edgerton, E., and Martin, B. E.: Dry deposition calculations
for the clean air status and trends network, Atmos. Environ., 31,
3667–3678, https://doi.org/10.1016/S1352-2310(97)00141-6, 1997.
Delmas, R., Serça, D., and Jambert, C.: Global inventory of NOx
sources, Nutr. Cycl. Agroecosys., 48, 51–60,
https://doi.org/10.1023/A:1009793806086, 1997.
Dimitriou, K., Remoundaki, E., Mantas, E., and Kassomenos, P.: Spatial
distribution of source areas of PM2.5 by Concentration Weighted
Trajectory (CWT) model applied in PM2.5 concentration and composition
data, Atmos. Environ., 116, 138–145,
https://doi.org/10.1016/j.atmosenv.2015.06.021, 2015.
Ehn, M., Thornton, J. A., Kleist, E., Sipilä, M., Junninen, H.,
Pullinen, I., Springer, M., Rubach, F., Tillmann, R., and Lee, B.: A large
source of low-volatility secondary organic aerosol, Nature, 506, 476–479,
https://doi.org/10.1038/nature13032, 2014.
Elliott, E. M., Kendall, C., Wankel, S. D., Burns, D. A., Boyer, E. W.,
Harlin, K., Bain, D. J., and Butler, T. J.: Nitrogen isotopes as indicators
of NOx source contributions to atmospheric nitrate deposition across
the midwestern and northeastern United States, Environ. Sci. Technol., 41,
7661–7667, https://doi.org/10.1021/es070898t, 2007.
Elliott, E. M., Kendall, C., Boyer, E. W., Burns, D. A., Lear, G. G.,
Golden, H. E., Harlin, K., Bytnerowicz, A., Butler, T. J., and Glatz, R.:
Dual nitrate isotopes in dry deposition: Utility for partitioning NOx
source contributions to landscape nitrogen deposition, J. Geophys.
Res.-Biogeo., 114, G04020, https://doi.org/10.1029/2008JG000889, 2009.
Environmental Protection Agency Clean Air Markets Division Clean Air Status and Trends Network (CASTNET): Filter Pack Concentrations – Weekly, https://www.epa.gov/castnet, last access: 4 March 2022.
Fang, H., Walters, W. W., Mase, D., and Michalski, G.: iNRACM: incorporating 15N into the Regional Atmospheric Chemistry Mechanism (RACM) for assessing the role photochemistry plays in controlling the isotopic composition of NOx, NOy, and atmospheric nitrate, Geosci. Model Dev., 14, 5001–5022, https://doi.org/10.5194/gmd-14-5001-2021, 2021.
Felix, J. D., Elliott, E. M., and Shaw, S. L.: Nitrogen Isotopic Composition
of Coal-Fired Power Plant NOx: Influence of Emission Controls and
Implications for Global Emission Inventories, Environ. Sci. Technol., 46,
3528–3535, https://doi.org/10.1021/es203355v, 2012.
Feng, X., Li, Q., Tao, Y., Ding, S., Chen, Y., and Li, X.-D.: Impact of Coal
Replacing Project on atmospheric fine aerosol nitrate loading and formation
pathways in urban Tianjin: Insights from chemical composition and 15N and
18O isotope ratios, Sci. Total Environ., 708, 134797,
https://doi.org/10.1016/j.scitotenv.2019.134797, 2020.
Fountoukis, C. and Nenes, A.: ISORROPIA II: a computationally efficient
thermodynamic equilibrium model for
K+–Ca2+–Mg2+– –Na+– – –Cl−–H2O
aerosols, Atmos. Chem. Phys., 7, 4639–4659,
https://doi.org/10.5194/acp-7-4639-2007, 2007.
Freyer, H. D.: Seasonal variation of ratios in atmospheric nitrate
species, Tellus B, 43, 30–44,
https://doi.org/10.3402/tellusb.v43i1.15244, 1991.
Freyer, H. D., Kley, D., Volz-Thomas, A., and Kobel, K.: On the interaction
of isotopic exchange processes with photochemical reactions in atmospheric
oxides of nitrogen, J. Geophys. Res., 98, 14791–14796,
https://doi.org/10.1029/93JD00874, 1993.
Frost, G. J., McKeen, S. A., Trainer, M., Ryerson, T. B., Neuman, J. A.,
Roberts, J. M., Swanson, A., Holloway, J. S., Sueper, D. T., Fortin, T.,
Parrish, D. D., Fehsenfeld, F. C., Flocke, F., Peckham, S. E., Grell, G. A.,
Kowal, D., Cartwright, J., Auerbach, N., and Habermann, T.: Effects of
changing power plant NOx emissions on ozone in the eastern United
States: Proof of concept, J. Geophys. Res.-Atmos., 111, D12306,
https://doi.org/10.1029/2005JD006354, 2006.
Galloway, J. N., Dentener, F. J., Capone, D. G., Boyer, E. W., Howarth, R.
W., Seitzinger, S. P., Asner, G. P., Cleveland, C., Green, P., and Holland,
E.: Nitrogen cycles: past, present, and future, Biogeochemistry, 70,
153–226, https://doi.org/10.1007/s10533-004-0370-0, 2004.
Geng, L., Alexander, B., Cole-Dai, J., Steig, E. J., Savarino, J., Sofen, E.
D., and Schauer, A. J.: Nitrogen isotopes in ice core nitrate linked to
anthropogenic atmospheric acidity change, P. Natl. Acad. Sci. USA, 111,
5808–5812, https://doi.org/10.1073/pnas.1319441111, 2014.
Granger, J. and Sigman, D. M.: Removal of nitrite with sulfamic acid for
nitrate N and O isotope analysis with the denitrifier method, Rapid. Commun.
Mass. Sp., 23, 3753–3762, https://doi.org/10.1002/rcm.4307, 2009.
Greaver, T. L., Clark, C. M., Compton, J. E., Vallano, D., Talhelm, A. F.,
Weaver, C. P., Band, L. E., Baron, J. S., Davidson, E. A., and Tague, C. L.:
Key ecological responses to nitrogen are altered by climate change, Nat.
Clim. Change, 6, 836–843, https://doi.org/10.1038/nclimate3088, 2016.
Guenther, A. B., Jiang, X., Heald, C. L., Sakulyanontvittaya, T., Duhl, T., Emmons, L. K., and Wang, X.: The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions, Geosci. Model Dev., 5, 1471–1492, https://doi.org/10.5194/gmd-5-1471-2012, 2012.
Hand, J. L., Schichtel, B. A., Malm, W. C., Copeland, S., Molenar, J. V.,
Frank, N., and Pitchford, M.: Widespread reductions in haze across the
United States from the early 1990s through 2011, Atmos. Environ., 94,
671–679, https://doi.org/10.1016/j.atmosenv.2014.05.062, 2014.
Hastings, M. G., Jarvis, J. C., and Steig, E. J.: Anthropogenic Impacts on
Nitrogen Isotopes of Ice-Core Nitrate, Science, 324, 1288–1288,
https://doi.org/10.1126/science.1170510, 2009.
Hastings, M. G., Casciotti, K. L., and Elliott, E. M.: Stable isotopes as
tracers of anthropogenic nitrogen sources, deposition, and impacts,
Elements, 9, 339–344, https://doi.org/10.2113/gselements.9.5.339, 2013.
Hoering, T.: The isotopic composition of the ammonia and the nitrate ion in
rain, Geochim. Cosmochim. Ac., 12, 97–102,
https://doi.org/10.1016/0016-7037(57)90021-2, 1957.
Hoesly, R. M., Smith, S. J., Feng, L., Klimont, Z., Janssens-Maenhout, G., Pitkanen, T., Seibert, J. J., Vu, L., Andres, R. J., Bolt, R. M., Bond, T. C., Dawidowski, L., Kholod, N., Kurokawa, J.-I., Li, M., Liu, L., Lu, Z., Moura, M. C. P., O'Rourke, P. R., and Zhang, Q.: Historical (1750–2014) anthropogenic emissions of reactive gases and aerosols from the Community Emissions Data System (CEDS), Geosci. Model Dev., 11, 369–408, https://doi.org/10.5194/gmd-11-369-2018, 2018.
Hsu, Y.-K., Holsen, T. M., and Hopke, P. K.: Comparison of hybrid receptor
models to locate PCB sources in Chicago, Atmos. Environ., 37, 545–562,
https://doi.org/10.1016/S1352-2310(02)00886-5, 2003.
Hu, L., Millet, D. B., Baasandorj, M., Griffis, T. J., Turner, P., Helmig,
D., Curtis, A. J., and Hueber, J.: Isoprene emissions and impacts over an
ecological transition region in the US Upper Midwest inferred from tall
tower measurements, J. Geophys. Res.-Atmos., 120, 3553–3571,
https://doi.org/10.1002/2014JD022732, 2015.
Huang, J. and Jaeglé, L.: Wintertime enhancements of sea salt aerosol in polar regions consistent with a sea ice source from blowing snow, Atmos. Chem. Phys., 17, 3699–3712, https://doi.org/10.5194/acp-17-3699-2017, 2017.
Hudman, R. C., Moore, N. E., Mebust, A. K., Martin, R. V., Russell, A. R., Valin, L. C., and Cohen, R. C.: Steps towards a mechanistic model of global soil nitric oxide emissions: implementation and space based-constraints, Atmos. Chem. Phys., 12, 7779–7795, https://doi.org/10.5194/acp-12-7779-2012, 2012.
Jaeglé, L., Steinberger, L., Martin, R. V., and Chance, K.: Global
partitioning of NOx sources using satellite observations: Relative
roles of fossil fuel combustion, biomass burning and soil emissions, Faraday
Discuss., 130, 407–423, https://doi.org/10.1039/b502128f, 2005.
Jaeglé, L., Quinn, P. K., Bates, T. S., Alexander, B., and Lin, J.-T.: Global distribution of sea salt aerosols: new constraints from in situ and remote sensing observations, Atmos. Chem. Phys., 11, 3137–3157, https://doi.org/10.5194/acp-11-3137-2011, 2011.
Jaeglé, L., Shah, V., Thornton, J. A., Lopez-Hilfiker, F. D., Lee, B.
H., McDuffie, E. E., Fibiger, D., Brown, S. S., Veres, P., Sparks, T. L.,
Ebben, C. J., Wooldridge, P. J., Kenagy, H. S., Cohen, R. C., Weinheimer, A.
J., Campos, T. L., Montzka, D. D., Digangi, J. P., Wolfe, G. M., Hanisco,
T., Schroder, J. C., Campuzano-Jost, P., Day, D. A., Jimenez, J. L.,
Sullivan, A. P., Guo, H., and Weber, R. J.: Nitrogen Oxides Emissions,
Chemistry, Deposition, and Export Over the Northeast United States During
the WINTER Aircraft Campaign, J. Geophys. Res.-Atmos., 123, 12368–12393,
https://doi.org/10.1029/2018JD029133, 2018.
Kaiser, J., Hastings, M. G., Houlton, B. Z., Röckmann, T., and Sigman,
D. M.: Triple Oxygen Isotope Analysis of Nitrate Using the Denitrifier
Method and Thermal Decomposition of N2O, Anal. Chem., 79, 599–607,
https://doi.org/10.1021/ac061022s, 2007.
Kim, H., Walters, W. W., Bekker, C., Murray, L. T., and Hastings, M. G.: Nitrate chemistry in the northeast US – Part 2: Oxygen isotopes reveal differences in particulate and gas-phase formation, Atmos. Chem. Phys., 23, 4203–4219, https://doi.org/10.5194/acp-23-4203-2023, 2023.
Li, D. and Wang, X.: Nitrogen isotopic signature of soil-released nitric
oxide (NO) after fertilizer application, Atmos. Environ., 42, 4747–4754,
https://doi.org/10.1016/j.atmosenv.2008.01.042, 2008.
Li, J., Zhang, X., Orlando, J., Tyndall, G., and Michalski, G.: Quantifying the nitrogen isotope effects during photochemical equilibrium between NO and NO2: implications for δ15N in tropospheric reactive nitrogen, Atmos. Chem. Phys., 20, 9805–9819, https://doi.org/10.5194/acp-20-9805-2020, 2020.
Li, J., Davy, P., Harvey, M., Katzman, T., Mitchell, T., and Michalski, G.:
Nitrogen isotopes in nitrate aerosols collected in the remote marine
boundary layer: Implications for nitrogen isotopic fractionations among
atmospheric reactive nitrogen species, Atmos. Environ., 245, 118028,
https://doi.org/10.1016/j.atmosenv.2020.118028, 2021.
Li, Z., Walters, W. W., Hastings, M. G., Zhang, Y., Song, L., Liu, D.,
Zhang, W., Pan, Y., Fu, P., and Fang, Y.: Nitrate Isotopic Composition in
Precipitation at a Chinese Megacity: Seasonal Variations, Atmospheric
Processes, and Implications for Sources, Earth Space Sci., 6,
2200–2213, https://doi.org/10.1029/2019EA000759, 2019.
Liu, H., Jacob, D. J., Bey, I., and Yantosca, R. M.: Constraints from 210Pb
and 7Be on wet deposition and transport in a global three-dimensional
chemical tracer model driven by assimilated meteorological fields, J.
Geophys. Res.-Atmos., 106, 12109–12128,
https://doi.org/10.1029/2000JD900839, 2001.
McDuffie, E. E., Smith, S. J., O'Rourke, P., Tibrewal, K., Venkataraman, C., Marais, E. A., Zheng, B., Crippa, M., Brauer, M., and Martin, R. V.: A global anthropogenic emission inventory of atmospheric pollutants from sector- and fuel-specific sources (1970–2017): an application of the Community Emissions Data System (CEDS), Earth Syst. Sci. Data, 12, 3413–3442, https://doi.org/10.5194/essd-12-3413-2020, 2020.
Michalski, G., Scott, Z., Kabiling, M., and Thiemens, M. H.: First
measurements and modeling of Δ17O in atmospheric nitrate, Geophys.
Res. Lett., 30, 1870, https://doi.org/10.1029/2003GL017015, 2003.
Miller, D. J., Wojtal, P. K., Clark, S. C., and Hastings, M. G.: Vehicle NOx
emission plume isotopic signatures: Spatial variability across the eastern
United States, J. Geophys. Res.-Atmos., 122, 2016JD025877,
https://doi.org/10.1002/2016JD025877, 2017.
Miller, D. J., Chai, J., Guo, F., Dell, C. J., Karsten, H., and Hastings, M.
G.: Isotopic Composition of In Situ Soil NOx Emissions in
Manure-Fertilized Cropland, Geophys. Res. Lett., 45, 12–058,
https://doi.org/10.1029/2018GL079619, 2018.
Millet, D. B., Guenther, A., Siegel, D. A., Nelson, N. B., Singh, H. B., de Gouw, J. A., Warneke, C., Williams, J., Eerdekens, G., Sinha, V., Karl, T., Flocke, F., Apel, E., Riemer, D. D., Palmer, P. I., and Barkley, M.: Global atmospheric budget of acetaldehyde: 3-D model analysis and constraints from in-situ and satellite observations, Atmos. Chem. Phys., 10, 3405–3425, https://doi.org/10.5194/acp-10-3405-2010, 2010.
Miyazaki, K., Eskes, H., Sudo, K., Boersma, K. F., Bowman, K., and Kanaya, Y.: Decadal changes in global surface NOx emissions from multi-constituent satellite data assimilation, Atmos. Chem. Phys., 17, 807–837, https://doi.org/10.5194/acp-17-807-2017, 2017.
Murray, L. T.: Lightning NOx and impacts on air quality, Current
Pollution Reports, 2, 115–133, https://doi.org/10.1007/s40726-016-0031-7,
2016.
Murray, L. T., Jacob, D. J., Logan, J. A., Hudman, R. C., and Koshak, W. J.:
Optimized regional and interannual variability of lightning in a global
chemical transport model constrained by LIS/OTD satellite data, J. Geophys.
Res.-Atmos., 117, D20307, https://doi.org/10.1029/2012JD017934, 2012.
Pinder, R. W., Davidson, E. A., Goodale, C. L., Greaver, T. L., Herrick, J.
D., and Liu, L.: Climate change impacts of US reactive nitrogen, P. Natl.
Acad. Sci. USA, 109, 7671–7675, https://doi.org/10.1073/pnas.1114243109, 2012.
Prinn, R. G.: The cleansing capacity of the atmosphere, Annu. Rev. Environ.
Res., 28, 29–57,
https://doi.org/10.1146/annurev.energy.28.011503.163425, 2003.
Pye, H. O. T., Chan, A. W. H., Barkley, M. P., and Seinfeld, J. H.: Global modeling of organic aerosol: the importance of reactive nitrogen (NOx and NO3), Atmos. Chem. Phys., 10, 11261–11276, https://doi.org/10.5194/acp-10-11261-2010, 2010.
Ridley, D. A., Heald, C. L., and Ford, B.: North African dust export and
deposition: A satellite and model perspective, J. Geophys. Res.-Atmos., 117, D02202,
https://doi.org/10.1029/2011JD016794, 2012.
Salamalikis, V., Argiriou, A. A., and Dotsika, E.: Stable isotopic
composition of atmospheric water vapor in Patras, Greece: A concentration
weighted trajectory approach, Atmos. Res., 152, 93–104,
https://doi.org/10.1016/j.atmosres.2014.02.021, 2015.
Savard, M. M., Cole, A., Smirnoff, A., and Vet, R.: δ15N values of
atmospheric N species simultaneously collected using sector-based samplers
distant from sources – Isotopic inheritance and fractionation, Atmos.
Environ., 162, 11–22, https://doi.org/10.1016/j.atmosenv.2017.05.010, 2017.
Savarino, J., Morin, S., Erbland, J., Grannec, F., Patey, M. D., Vicars, W.,
Alexander, B., and Achterberg, E. P.: Isotopic composition of atmospheric
nitrate in a tropical marine boundary layer, P. Natl. Acad. Sci. USA, 110,
17668–17673, https://doi.org/10.1073/pnas.1216639110, 2013.
Sharma, H. D., Jervis, R. E., and Wong, K. Y.: Isotopic exchange reactions
in nitrogen oxides, J. Phys. Chem., 74, 923–933,
https://doi.org/10.1021/j100699a044, 1970.
Sickles II, J. E. and Shadwick, D. S.: Air quality and atmospheric deposition in the eastern US: 20 years of change, Atmos. Chem. Phys., 15, 173–197, https://doi.org/10.5194/acp-15-173-2015, 2015.
Sigman, D. M., Casciotti, K. L., Andreani, M., Barford, C., Galanter, M.,
and Böhlke, J. K.: A bacterial method for the nitrogen isotopic analysis
of nitrate in seawater and freshwater, Anal. Chem., 73, 4145–4153,
https://doi.org/10.1021/ac010088e, 2001.
Stein, A. F., Draxler, R. R., Rolph, G. D., Stunder, B. J., Cohen, M. D.,
and Ngan, F.: NOAA's HYSPLIT atmospheric transport and dispersion modeling
system, B. Am. Meteorol. Soc., 96, 2059–2077,
https://doi.org/10.1175/BAMS-D-14-00110.1, 2015.
U.S. Environmental Protection Agency Clean Air Markets Division Clean Air Status and Trends Network (CASTNET): Filter Pack Concentrations – Weekly, http://www.epa.gov/castnet, last access: 4 March 2022.
van der Werf, G. R., Randerson, J. T., Giglio, L., van Leeuwen, T. T., Chen, Y., Rogers, B. M., Mu, M., van Marle, M. J. E., Morton, D. C., Collatz, G. J., Yokelson, R. J., and Kasibhatla, P. S.: Global fire emissions estimates during 1997–2016, Earth Syst. Sci. Data, 9, 697–720, https://doi.org/10.5194/essd-9-697-2017, 2017.
Vicars, W. C., Morin, S., Savarino, J., Wagner, N. L., Erbland, J., Vince,
E., Martins, J. M. F., Lerner, B. M., Quinn, P. K., Coffman, D. J., and
others: Spatial and diurnal variability in reactive nitrogen oxide chemistry
as reflected in the isotopic composition of atmospheric nitrate: Results
from the CalNex 2010 field study, J. Geophys. Res.-Atmos., 118, 10567–10588,
https://doi.org/10.1002/jgrd.50680, 2013.
Walker, J. M., Philip, S., Martin, R. V., and Seinfeld, J. H.: Simulation of nitrate, sulfate, and ammonium aerosols over the United States, Atmos. Chem. Phys., 12, 11213–11227, https://doi.org/10.5194/acp-12-11213-2012, 2012.
Walker, J. T., Beachley, G., Amos, H. M., Baron, J. S., Bash, J.,
Baumgardner, R., Bell, M. D., Benedict, K. B., Chen, X., and Clow, D. W.:
Toward the improvement of total nitrogen deposition budgets in the United
States, Sci. Total Environ., 691, 1328–1352,
https://doi.org/10.1016/j.scitotenv.2019.07.058, 2019.
Walters, W.: Data for, “Nitrate Chemistry in the Northeast US Part 1 & Part 2”, Harvard Dataverse V1 [data set], https://doi.org/10.7910/DVN/X6BB1I, 2022.
Walters, W. W. and Michalski, G.: Theoretical calculation of nitrogen
isotope equilibrium exchange fractionation factors for various NOy
molecules, Geochim. Cosmochim. Ac., 164, 284–297,
https://doi.org/10.1016/j.gca.2015.05.029, 2015.
Walters, W. W. and Michalski, G.: Ab initio study of nitrogen and
position-specific oxygen kinetic isotope effects in the NO + O3
reaction, J. Chem. Phys., 145, 224311, https://doi.org/10.1063/1.4968562,
2016a.
Walters, W. W. and Michalski, G.: Theoretical calculation of oxygen
equilibrium isotope fractionation factors involving various NOy
molecules, OH, and H2O and its implications for isotope variations in
atmospheric nitrate, Geochim. Cosmochim. Ac., 191, 89–101,
https://doi.org/10.1016/j.gca.2016.06.039, 2016b.
Walters, W. W., Tharp, B. D., Fang, H., Kozak, B. J., and Michalski, G.:
Nitrogen isotope composition of thermally produced NOx from various
fossil-fuel combustion sources, Environ. Sci. Technol., 49, 11363–11371,
https://doi.org/10.1021/acs.est.5b02769, 2015a.
Walters, W. W., Goodwin, S. R., and Michalski, G.: Nitrogen Stable Isotope
Composition (δ15N) of Vehicle-Emitted NOx, Environ. Sci.
Technol., 49, 2278–2285, https://doi.org/10.1021/es505580v, 2015b.
Walters, W. W., Simonini, D. S., and Michalski, G.: Nitrogen isotope
exchange between NO and NO2 and its implications for δ15N
variations in tropospheric NOx and atmospheric nitrate, Geophys. Res.
Lett., 43, 2015GL066438, https://doi.org/10.1002/2015GL066438, 2016.
Walters, W. W., Fang, H., and Michalski, G.: Summertime diurnal variations
in the isotopic composition of atmospheric nitrogen dioxide at a small
midwestern United States city, Atmos. Environ., 179, 1–11,
https://doi.org/10.1016/j.atmosenv.2018.01.047, 2018.
Wang, X., Jacob, D. J., Downs, W., Zhai, S., Zhu, L., Shah, V., Holmes, C. D., Sherwen, T., Alexander, B., Evans, M. J., Eastham, S. D., Neuman, J. A., Veres, P. R., Koenig, T. K., Volkamer, R., Huey, L. G., Bannan, T. J., Percival, C. J., Lee, B. H., and Thornton, J. A.: Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants, Atmos. Chem. Phys., 21, 13973–13996, https://doi.org/10.5194/acp-21-13973-2021, 2021.
Wesely, M. L. and Lesht, B. M.: Comparison of RADM dry deposition algorithms
with a site-specific method for inferring dry deposition, Water Air
Soil Pollut., 44, 273–293, https://doi.org/10.1007/BF00279259, 1989.
Xing, Y.-F., Xu, Y.-H., Shi, M.-H., and Lian, Y.-X.: The impact of PM2.5 on
the human respiratory system, J. Thorac. Dis., 8, E69–E74,
https://doi.org/10.3978/j.issn.2072-1439.2016.01.19, 2016.
Yu, Z. and Elliott, E. M.: Novel Method for Nitrogen Isotopic Analysis of
Soil-Emitted Nitric Oxide, Environ. Sci. Technol., 51, 6268–6278,
https://doi.org/10.1021/acs.est.7b00592, 2017.
Zhang, R., Tie, X., and Bond, D. W.: Impacts of anthropogenic and natural
NOx sources over the U.S. on tropospheric chemistry, P. Natl. Acad. Sci.,
100, 1505–1509, https://doi.org/10.1073/pnas.252763799, 2003.
Zong, Z., Wang, X., Tian, C., Chen, Y., Fang, Y., Zhang, F., Li, C., Sun,
J., Li, J., and Zhang, G.: First Assessment of NOx Sources at a Regional
Background Site in North China Using Isotopic Analysis Linked with Modeling,
Environ. Sci. Technol., 51, 5923–5931,
https://doi.org/10.1021/acs.est.6b06316, 2017.
Short summary
Nitrate is a critical component of the atmosphere that degrades air quality and ecosystem health. We have investigated the nitrogen isotope compositions of nitrate from deposition samples collected across the northeastern United States. Spatiotemporal variability in the nitrogen isotope compositions was found to track with nitrate formation chemistry. Our results highlight that nitrogen isotope compositions may be a robust tool for improving model representation of nitrate chemistry.
Nitrate is a critical component of the atmosphere that degrades air quality and ecosystem...
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