Articles | Volume 21, issue 2
Atmos. Chem. Phys., 21, 813–829, 2021
https://doi.org/10.5194/acp-21-813-2021
Atmos. Chem. Phys., 21, 813–829, 2021
https://doi.org/10.5194/acp-21-813-2021
Research article
20 Jan 2021
Research article | 20 Jan 2021

Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis

Yiwei Gong and Zhongming Chen

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Cited articles

Ahmad, W., Coeur, C., Cuisset, A., Coddeville, P., and Tomas, A.: Effects of scavengers of Criegee intermediates and OH radicals on the formation of secondary organic aerosol in the ozonolysis of limonene, J. Aerosol Sci., 110, 70–83, https://doi.org/10.1016/j.jaerosci.2017.05.010, 2017. 
Andersson-Sköld, Y. and Simpson, D.: Secondary organic aerosol formation in northern Europe: A model study, J. Geophys. Res., 106, 7357–7374, https://doi.org/10.1029/2000JD900656, 2001. 
Anglada, J. M., Aplincourt, P., Bofill, J. M., and Cremer, D.: Atmospheric formation of OH radicals and H2O2 from alkene ozonolysis under humid conditions, Chem. Phys. Chem., 3, 215–221, https://doi.org/10.1002/1439-7641(20020215)3:2<215::AID-CPHC215>3.0.CO;2-3, 2002. 
Aplincourt, P. and Ruiz-Loìpez, M. F.: Theoretical study of formic acid anhydride formation from carbonyl oxide in the atmosphere, J. Phys. Chem. A, 104, 380–388, https://doi.org/10.1021/jp9928208, 2000. 
Aroeira, G. J. R., Abbott, A. S., Elliott, S. N., Turney, J. M., and Schaefer, H. F.: The addition of methanol to Criegee intermediates, Phys. Chem. Chem. Phys., 21, 17760–17771, https://doi.org/10.1039/C9CP03480C, 2019. 
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Short summary
Stabilized Criegee intermediates (SCIs) are important factors in estimating aerosol formation in the atmosphere. Here the results show that SCIs account for more than 60 % of aerosol formation in limonene ozonolysis and water is an uncertainty in SCI performances. The aerosol formation potential of SCIs under high-humidity conditions is double that under dry and low-humidity conditions, suggesting SCI reactions are still important in contributing to aerosols at high relative humidity.
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