Articles | Volume 21, issue 2
https://doi.org/10.5194/acp-21-813-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-813-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Jan 2021
Research article |
| 20 Jan 2021
| 20 Jan 2021
Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis
Yiwei Gong
State Key Laboratory of Environmental Simulation and Pollution
Control, College of Environmental Sciences and Engineering, Peking
University, Beijing 100871, China
Zhongming Chen
CORRESPONDING AUTHOR
State Key Laboratory of Environmental Simulation and Pollution
Control, College of Environmental Sciences and Engineering, Peking
University, Beijing 100871, China
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Cited
22 citations as recorded by crossref.
- Atmospheric Kinetics: Bimolecular Reactions of Carbonyl Oxide by a Triple-Level Strategy B. Long et al. https://doi.org/10.1021/jacs.1c02029
- Influence of relative humidity on the heterogeneous ozonolysis rate constant of myrtenal and ketolimonene on quartz M. Alossaily et al. https://doi.org/10.1016/j.atmosenv.2026.122157
- Water Plays Multifunctional Roles in the Intervening Formation of Secondary Organic Aerosols in Ozonolysis of Limonene: A Valence Photoelectron Spectroscopy and Density Functional Theory Study J. Huang et al. https://doi.org/10.1021/acs.jpclett.3c00560
- Pressure and temperature dependent kinetics and the reaction mechanism of Criegee intermediates with vinyl alcohol: a theoretical study C. Sun et al. https://doi.org/10.1039/D3CP06115A
- Exploring the Intricate Mechanism and Kinetics of the Reaction between C2-Criegee Intermediates (CH3CHOO) and Acetaldehyde: A Study Using Cavity Ring-Down Spectroscopy and Computational Methods A. Debnath & B. Rajakumar https://doi.org/10.1021/acs.jpca.5c00521
- Quantitative kinetics for the atmospheric reactions of Criegee intermediates with acetonitrile Y. Zhang et al. https://doi.org/10.1039/D2CP02849B
- Oligomer formation from the gas-phase reactions of Criegee intermediates with hydroperoxide esters: mechanism and kinetics L. Chen et al. https://doi.org/10.5194/acp-22-14529-2022
- Organic aerosol formation from 222 nm germicidal light: ozone-initiated vs. non-ozone pathways M. Goss & J. Kroll https://doi.org/10.1039/D4EM00384E
- Barrierless reactions of C2 Criegee intermediates with H2SO4 and their implication to oligomers and new particle formation Y. Cheng et al. https://doi.org/10.1016/j.jes.2023.12.020
- Reactions with Criegee intermediates are the dominant gas-phase sink for formyl fluoride in the atmosphere Y. Xia et al. https://doi.org/10.1016/j.fmre.2023.02.012
- Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids Y. Luo et al. https://doi.org/10.5194/acp-25-4655-2025
- OH-initiated atmospheric degradation of hydroxyalkyl hydroperoxides: mechanism, kinetics, and structure–activity relationship L. Chen et al. https://doi.org/10.5194/acp-22-3693-2022
- Reaction of Carbonyl Oxide with Hydroperoxymethyl Thioformate: Quantitative Kinetics and Atmospheric Implications B. Long et al. https://doi.org/10.34133/research.0525
- Quantitative Kinetics of the Reaction between CH2OO and H2O2 in the Atmosphere Y. Zhao et al. https://doi.org/10.1021/acs.jpca.2c04408
- Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism S. Zhang et al. https://doi.org/10.5194/acp-23-10809-2023
- The reaction of Criegee intermediates with formamide and its implication to atmospheric aerosols Y. Wei et al. https://doi.org/10.1016/j.chemosphere.2022.133717
- Temperature-dependent kinetics of the atmospheric reaction between CH2OO and acetone P. Wang et al. https://doi.org/10.1039/D2CP01118B
- Nontrivial Impact of Relative Humidity on Organic New Particle Formation from Ozonolysis of cis-3-Hexenyl Acetate A. Flueckiger et al. https://doi.org/10.3390/air1040017
- How Do the Position and Number of Methyl Substituents Affect the Photochemical Process of Criegee Intermediate? Trajectory Surface-Hopping Dynamics of Four-Carbon CIs X. Geng et al. https://doi.org/10.1021/acs.jpca.4c02112
- Multidimensional tunneling and reaction-path dynamics in oxygen-insertion reactions of Criegee intermediates with small alkanes K. Chou et al. https://doi.org/10.1063/5.0315481
- Impact of temperature on the role of Criegee intermediates and peroxy radicals in dimer formation from β-pinene ozonolysis Y. Gong et al. https://doi.org/10.5194/acp-24-167-2024
- Elucidation of the myrcene ozonolysis mechanism from a Criegee Chemistry perspective M. Chen et al. https://doi.org/10.5194/acp-26-2103-2026
22 citations as recorded by crossref.
- Atmospheric Kinetics: Bimolecular Reactions of Carbonyl Oxide by a Triple-Level Strategy B. Long et al. https://doi.org/10.1021/jacs.1c02029
- Influence of relative humidity on the heterogeneous ozonolysis rate constant of myrtenal and ketolimonene on quartz M. Alossaily et al. https://doi.org/10.1016/j.atmosenv.2026.122157
- Water Plays Multifunctional Roles in the Intervening Formation of Secondary Organic Aerosols in Ozonolysis of Limonene: A Valence Photoelectron Spectroscopy and Density Functional Theory Study J. Huang et al. https://doi.org/10.1021/acs.jpclett.3c00560
- Pressure and temperature dependent kinetics and the reaction mechanism of Criegee intermediates with vinyl alcohol: a theoretical study C. Sun et al. https://doi.org/10.1039/D3CP06115A
- Exploring the Intricate Mechanism and Kinetics of the Reaction between C2-Criegee Intermediates (CH3CHOO) and Acetaldehyde: A Study Using Cavity Ring-Down Spectroscopy and Computational Methods A. Debnath & B. Rajakumar https://doi.org/10.1021/acs.jpca.5c00521
- Quantitative kinetics for the atmospheric reactions of Criegee intermediates with acetonitrile Y. Zhang et al. https://doi.org/10.1039/D2CP02849B
- Oligomer formation from the gas-phase reactions of Criegee intermediates with hydroperoxide esters: mechanism and kinetics L. Chen et al. https://doi.org/10.5194/acp-22-14529-2022
- Organic aerosol formation from 222 nm germicidal light: ozone-initiated vs. non-ozone pathways M. Goss & J. Kroll https://doi.org/10.1039/D4EM00384E
- Barrierless reactions of C2 Criegee intermediates with H2SO4 and their implication to oligomers and new particle formation Y. Cheng et al. https://doi.org/10.1016/j.jes.2023.12.020
- Reactions with Criegee intermediates are the dominant gas-phase sink for formyl fluoride in the atmosphere Y. Xia et al. https://doi.org/10.1016/j.fmre.2023.02.012
- Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids Y. Luo et al. https://doi.org/10.5194/acp-25-4655-2025
- OH-initiated atmospheric degradation of hydroxyalkyl hydroperoxides: mechanism, kinetics, and structure–activity relationship L. Chen et al. https://doi.org/10.5194/acp-22-3693-2022
- Reaction of Carbonyl Oxide with Hydroperoxymethyl Thioformate: Quantitative Kinetics and Atmospheric Implications B. Long et al. https://doi.org/10.34133/research.0525
- Quantitative Kinetics of the Reaction between CH2OO and H2O2 in the Atmosphere Y. Zhao et al. https://doi.org/10.1021/acs.jpca.2c04408
- Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism S. Zhang et al. https://doi.org/10.5194/acp-23-10809-2023
- The reaction of Criegee intermediates with formamide and its implication to atmospheric aerosols Y. Wei et al. https://doi.org/10.1016/j.chemosphere.2022.133717
- Temperature-dependent kinetics of the atmospheric reaction between CH2OO and acetone P. Wang et al. https://doi.org/10.1039/D2CP01118B
- Nontrivial Impact of Relative Humidity on Organic New Particle Formation from Ozonolysis of cis-3-Hexenyl Acetate A. Flueckiger et al. https://doi.org/10.3390/air1040017
- How Do the Position and Number of Methyl Substituents Affect the Photochemical Process of Criegee Intermediate? Trajectory Surface-Hopping Dynamics of Four-Carbon CIs X. Geng et al. https://doi.org/10.1021/acs.jpca.4c02112
- Multidimensional tunneling and reaction-path dynamics in oxygen-insertion reactions of Criegee intermediates with small alkanes K. Chou et al. https://doi.org/10.1063/5.0315481
- Impact of temperature on the role of Criegee intermediates and peroxy radicals in dimer formation from β-pinene ozonolysis Y. Gong et al. https://doi.org/10.5194/acp-24-167-2024
- Elucidation of the myrcene ozonolysis mechanism from a Criegee Chemistry perspective M. Chen et al. https://doi.org/10.5194/acp-26-2103-2026
Saved (final revised paper)
Latest update: 20 Aug 2026
Short summary
Stabilized Criegee intermediates (SCIs) are important factors in estimating aerosol formation in the atmosphere. Here the results show that SCIs account for more than 60 % of aerosol formation in limonene ozonolysis and water is an uncertainty in SCI performances. The aerosol formation potential of SCIs under high-humidity conditions is double that under dry and low-humidity conditions, suggesting SCI reactions are still important in contributing to aerosols at high relative humidity.
Stabilized Criegee intermediates (SCIs) are important factors in estimating aerosol formation in...
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