Articles | Volume 20, issue 9
https://doi.org/10.5194/acp-20-5679-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-5679-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
13 May 2020
Research article |
| 13 May 2020
| 13 May 2020
Thermodynamic properties of isoprene- and monoterpene-derived organosulfates estimated with COSMOtherm
Nano and Molecular Systems Research Unit, University of Oulu, P.O. Box 3000, 90014 Oulu, Finland
Jonas Elm
Department of Chemistry and iClimate, Aarhus University, Langelandsgade 140, 8000 Aarhus C, Denmark
Jussi Malila
Nano and Molecular Systems Research Unit, University of Oulu, P.O. Box 3000, 90014 Oulu, Finland
Silvia M. Calderón
Nano and Molecular Systems Research Unit, University of Oulu, P.O. Box 3000, 90014 Oulu, Finland
Nano and Molecular Systems Research Unit, University of Oulu, P.O. Box 3000, 90014 Oulu, Finland
Related authors
Zijun Li, Angela Buchholz, and Noora Hyttinen
Atmos. Chem. Phys., 24, 11717–11725, https://doi.org/10.5194/acp-24-11717-2024, https://doi.org/10.5194/acp-24-11717-2024, 2024
Short summary
Short summary
Evaluating organosulfur (OS) hygroscopicity is important for assessing aerosol–cloud climate interactions in the post-fossil-fuel future, when SO2 emissions decrease and OS compounds become increasingly important. Here a state-of-the-art quantum-chemistry-based method was used to predict the hygroscopic growth factors (HGFs) of a group of atmospherically relevant OS compounds and their mixtures with (NH4)2SO4. A good agreement was observed between their model-estimated and experimental HGFs.
Noora Hyttinen
Atmos. Chem. Phys., 23, 13809–13817, https://doi.org/10.5194/acp-23-13809-2023, https://doi.org/10.5194/acp-23-13809-2023, 2023
Short summary
Short summary
Water activity in aerosol particles describes how particles respond to variations in relative humidity. Here, water activities were calculated for a set of 80 salts that may be present in aerosol particles using a state-of-the-art quantum-chemistry-based method. The effect of the dissociated salt on water activity varies with both the cation and anion. Most of the studied salts increase water uptake compared to pure water-soluble organic particles.
Lukas Pichelstorfer, Pontus Roldin, Matti Rissanen, Noora Hyttinen, Olga Garmash, Carlton Xavier, Putian Zhou, Petri Clusius, Benjamin Foreback, Thomas Golin Almeida, Chenjuan Deng, Metin Baykara, Theo Kurten, and Michael Boy
EGUsphere, https://doi.org/10.5194/egusphere-2023-1415, https://doi.org/10.5194/egusphere-2023-1415, 2023
Preprint archived
Short summary
Short summary
Secondary organic aerosols (SOA) form effectively from gaseous precursors via a process called autoxidation. While key chemical reaction types seem to be known, no general description of autoxidation chemistry exists. In the present work, we present a method to create autoxidation chemistry schemes for any atmospherically relevant hydrocarbon. We exemplarily investigate benzene and its potential to form aerosols. We found that autoxidation, under some conditions, can dominate the SOA formation.
Zijun Li, Noora Hyttinen, Miika Vainikka, Olli-Pekka Tikkasalo, Siegfried Schobesberger, and Taina Yli-Juuti
Atmos. Chem. Phys., 23, 6863–6877, https://doi.org/10.5194/acp-23-6863-2023, https://doi.org/10.5194/acp-23-6863-2023, 2023
Short summary
Short summary
The saturation vapor pressure (psat) of low-volatility organic compounds (LVOCs) governs their partitioning between the gas and particle phases. To estimate the psat of selected LVOCs, we performed particle evaporation measurements in a residence time chamber at a temperature setting relevant to atmospheric aerosol formation and conducted state-of-the-art computational calculations. We found good agreement between the experimentally measured and model-estimated psat values for most LVOCs.
Noora Hyttinen, Iida Pullinen, Aki Nissinen, Siegfried Schobesberger, Annele Virtanen, and Taina Yli-Juuti
Atmos. Chem. Phys., 22, 1195–1208, https://doi.org/10.5194/acp-22-1195-2022, https://doi.org/10.5194/acp-22-1195-2022, 2022
Short summary
Short summary
Accurate saturation vapor pressure estimates of atmospherically relevant organic compounds are critical for modeling secondary organic aerosol (SOA) formation. We investigated vapor pressures of highly oxygenated SOA constituents using state-of-the-art computational and experimental methods. We found a good agreement between low and extremely low vapor pressures estimated using the two methods, and the smallest molecules detected in our experiment were likely products of thermal decomposition.
Robin Wollesen de Jonge, Jonas Elm, Bernadette Rosati, Sigurd Christiansen, Noora Hyttinen, Dana Lüdemann, Merete Bilde, and Pontus Roldin
Atmos. Chem. Phys., 21, 9955–9976, https://doi.org/10.5194/acp-21-9955-2021, https://doi.org/10.5194/acp-21-9955-2021, 2021
Short summary
Short summary
This study presents a detailed analysis of the OH-initiated oxidation of dimethyl sulfide (DMS) based on experiments performed in the Aarhus University Research on Aerosol (AURA) smog chamber and the gas- and particle-phase chemistry kinetic multilayer model (ADCHAM). We capture the formation, growth and chemical composition of aerosols in the chamber setup by an improved multiphase oxidation mechanism and utilize our results to reproduce the important role of DMS in the marine boundary layer.
Noora Hyttinen, Reyhaneh Heshmatnezhad, Jonas Elm, Theo Kurtén, and Nønne L. Prisle
Atmos. Chem. Phys., 20, 13131–13143, https://doi.org/10.5194/acp-20-13131-2020, https://doi.org/10.5194/acp-20-13131-2020, 2020
Short summary
Short summary
We present aqueous solubilities and activity coefficients of mono- and dicarboxylic acids (C1–C6 and C2–C8, respectively) estimated using the COSMOtherm program. In addition, we have calculated effective equilibrium constants of dimerization and hydration of the same acids in the condensed phase. We were also able to improve the agreement between experimental and estimated properties of monocarboxylic acids in aqueous solutions by including clustering reactions in COSMOtherm calculations.
Theo Kurtén, Noora Hyttinen, Emma Louise D'Ambro, Joel Thornton, and Nønne Lyng Prisle
Atmos. Chem. Phys., 18, 17589–17600, https://doi.org/10.5194/acp-18-17589-2018, https://doi.org/10.5194/acp-18-17589-2018, 2018
Short summary
Short summary
We use COSMO-RS to compute saturation vapor pressures for two products of isoprene photo-oxidation and compare the results to measurements. COSMO-RS is an attractive option for calculating properties of molecules, as it is based on quantum mechanics and requires few fitting parameters. However, we show that the default implementation of this method suffers from errors related to both conformational sampling and intramolecular hydrogen bonding. We propose solutions to these problems.
Ulrich K. Krieger, Franziska Siegrist, Claudia Marcolli, Eva U. Emanuelsson, Freya M. Gøbel, Merete Bilde, Aleksandra Marsh, Jonathan P. Reid, Andrew J. Huisman, Ilona Riipinen, Noora Hyttinen, Nanna Myllys, Theo Kurtén, Thomas Bannan, Carl J. Percival, and David Topping
Atmos. Meas. Tech., 11, 49–63, https://doi.org/10.5194/amt-11-49-2018, https://doi.org/10.5194/amt-11-49-2018, 2018
Short summary
Short summary
Vapor pressures of low-volatility organic molecules at atmospheric temperatures reported in the literature often differ by several orders of magnitude between measurement techniques. These discrepancies exceed the stated uncertainty of each technique, which is generally reported to be smaller than a factor of 2. We determined saturation vapor pressures for the homologous series of polyethylene glycols ranging in vapor pressure at 298 K from 1E−7 Pa to 5E−2 Pa as a reference set.
Alison Bain, Kunal Ghosh, Konstantin Tumashevich, Nonne L. Prisle, and Bryan R. Bzdek
EGUsphere, https://doi.org/10.5194/egusphere-2024-3993, https://doi.org/10.5194/egusphere-2024-3993, 2025
Short summary
Short summary
In this work, we measure the surface tension of picolitre volume droplets containing strong ionic surfactants and cosolutes. These measurements are compared to surface tension predictions using two independent surfactant partitioning models. We find that when salting out occurs, one model outperforms the other. These results highlight the importance of validating surfactant partitioning models against experimental data before applying them to predict the surface tension of ambient aerosol.
Haide Wu, Yosef Knattrup, Andreas Buchgraitz Jensen, and Jonas Elm
Aerosol Research, 2, 303–314, https://doi.org/10.5194/ar-2-303-2024, https://doi.org/10.5194/ar-2-303-2024, 2024
Short summary
Short summary
The exact point at which a given assembly of molecules represents an atmospheric molecular cluster or a particle remains ambiguous. Using quantum chemical methods, here we explore a cluster-to-particle transition point. Based on our results, we deduce a property-based criterion for defining freshly nucleated particles (FNPs) that act as a boundary between discrete cluster configurations and bulk particles.
Yosef Knattrup and Jonas Elm
Aerosol Research Discuss., https://doi.org/10.5194/ar-2024-37, https://doi.org/10.5194/ar-2024-37, 2024
Revised manuscript accepted for AR
Short summary
Short summary
Using quantum chemical methods we studied the uptake of first generation oxidation products onto freshly nucleated particles (FNPs). We find that pinic acid can condense on these small FNPs at realistic atmospheric conditions, thereby contributing to the early particle growth. The mechanism involves two pinic acid molecules interacting with each other, showing that direct organic-organic interactions during co-condensation onto the particle contributes to the growth.
Galib Hasan, Haide Wu, Yosef Knattrup, and Jonas Elm
Aerosol Research Discuss., https://doi.org/10.5194/ar-2024-28, https://doi.org/10.5194/ar-2024-28, 2024
Revised manuscript accepted for AR
Short summary
Short summary
Aerosol formation is an important process for our global climate. However, there are large uncertainties associated with the formation of new aerosol particles. We present quantum chemical calculations of large atmospheric molecular cluster composed of sulfuric acid (SA), ammonia (AM) and dimethyl amine (DMA). We find that mixed SA-AM-DMA clusters more efficiently for freshly nucleated particles compared to the pure SA-AM and SA-DMA systems.
Zijun Li, Angela Buchholz, and Noora Hyttinen
Atmos. Chem. Phys., 24, 11717–11725, https://doi.org/10.5194/acp-24-11717-2024, https://doi.org/10.5194/acp-24-11717-2024, 2024
Short summary
Short summary
Evaluating organosulfur (OS) hygroscopicity is important for assessing aerosol–cloud climate interactions in the post-fossil-fuel future, when SO2 emissions decrease and OS compounds become increasingly important. Here a state-of-the-art quantum-chemistry-based method was used to predict the hygroscopic growth factors (HGFs) of a group of atmospherically relevant OS compounds and their mixtures with (NH4)2SO4. A good agreement was observed between their model-estimated and experimental HGFs.
Astrid Nørskov Pedersen, Yosef Knattrup, and Jonas Elm
Aerosol Research, 2, 123–134, https://doi.org/10.5194/ar-2-123-2024, https://doi.org/10.5194/ar-2-123-2024, 2024
Short summary
Short summary
Aerosol formation is an important process for our global climate. While inorganic species have been shown to be important for aerosol formation, there remains a large gap in our knowledge about the exact involvement of organics. We present a new quantum chemical procedure for screening relevant organics that for the first time allows us to obtain direct molecular-level insight into the organics involved in aerosol formation.
Gargi Sengupta, Minjie Zheng, and Nønne L. Prisle
Atmos. Chem. Phys., 24, 1467–1487, https://doi.org/10.5194/acp-24-1467-2024, https://doi.org/10.5194/acp-24-1467-2024, 2024
Short summary
Short summary
The effect of organic acid aerosol on sulfur chemistry and cloud properties was investigated in an atmospheric model. Organic acid dissociation was considered using both bulk and surface-related properties. We found that organic acid dissociation leads to increased hydrogen ion concentrations and sulfate aerosol mass in aqueous aerosols, increasing cloud formation. This could be important in large-scale climate models as many organic aerosol components are both acidic and surface-active.
Sampo Vepsäläinen, Silvia M. Calderón, and Nønne L. Prisle
Atmos. Chem. Phys., 23, 15149–15164, https://doi.org/10.5194/acp-23-15149-2023, https://doi.org/10.5194/acp-23-15149-2023, 2023
Short summary
Short summary
Atmospheric aerosols act as seeds for cloud formation. Many aerosols contain surface active material that accumulates at the surface of growing droplets. This can affect cloud droplet activation, but the broad significance of the effect and the best way to model it are still debated. We compare predictions of six models to surface activity of strongly surface active aerosol and find significant differences between the models, especially with large fractions of surfactant in the dry particles.
Minjie Zheng, Hongyu Liu, Florian Adolphi, Raimund Muscheler, Zhengyao Lu, Mousong Wu, and Nønne L. Prisle
Geosci. Model Dev., 16, 7037–7057, https://doi.org/10.5194/gmd-16-7037-2023, https://doi.org/10.5194/gmd-16-7037-2023, 2023
Short summary
Short summary
The radionuclides 7Be and 10Be are useful tracers for atmospheric transport studies. Here we use the GEOS-Chem to simulate 7Be and 10Be with different production rates: the default production rate in GEOS-Chem and two from the state-of-the-art beryllium production model. We demonstrate that reduced uncertainties in the production rates can enhance the utility of 7Be and 10Be as tracers for evaluating transport and scavenging processes in global models.
Noora Hyttinen
Atmos. Chem. Phys., 23, 13809–13817, https://doi.org/10.5194/acp-23-13809-2023, https://doi.org/10.5194/acp-23-13809-2023, 2023
Short summary
Short summary
Water activity in aerosol particles describes how particles respond to variations in relative humidity. Here, water activities were calculated for a set of 80 salts that may be present in aerosol particles using a state-of-the-art quantum-chemistry-based method. The effect of the dissociated salt on water activity varies with both the cation and anion. Most of the studied salts increase water uptake compared to pure water-soluble organic particles.
Lukas Pichelstorfer, Pontus Roldin, Matti Rissanen, Noora Hyttinen, Olga Garmash, Carlton Xavier, Putian Zhou, Petri Clusius, Benjamin Foreback, Thomas Golin Almeida, Chenjuan Deng, Metin Baykara, Theo Kurten, and Michael Boy
EGUsphere, https://doi.org/10.5194/egusphere-2023-1415, https://doi.org/10.5194/egusphere-2023-1415, 2023
Preprint archived
Short summary
Short summary
Secondary organic aerosols (SOA) form effectively from gaseous precursors via a process called autoxidation. While key chemical reaction types seem to be known, no general description of autoxidation chemistry exists. In the present work, we present a method to create autoxidation chemistry schemes for any atmospherically relevant hydrocarbon. We exemplarily investigate benzene and its potential to form aerosols. We found that autoxidation, under some conditions, can dominate the SOA formation.
Jonas Elm, Aladár Czitrovszky, Andreas Held, Annele Virtanen, Astrid Kiendler-Scharr, Benjamin J. Murray, Daniel McCluskey, Daniele Contini, David Broday, Eirini Goudeli, Hilkka Timonen, Joan Rosell-Llompart, Jose L. Castillo, Evangelia Diapouli, Mar Viana, Maria E. Messing, Markku Kulmala, Naděžda Zíková, and Sebastian H. Schmitt
Aerosol Research, 1, 13–16, https://doi.org/10.5194/ar-1-13-2023, https://doi.org/10.5194/ar-1-13-2023, 2023
Zijun Li, Noora Hyttinen, Miika Vainikka, Olli-Pekka Tikkasalo, Siegfried Schobesberger, and Taina Yli-Juuti
Atmos. Chem. Phys., 23, 6863–6877, https://doi.org/10.5194/acp-23-6863-2023, https://doi.org/10.5194/acp-23-6863-2023, 2023
Short summary
Short summary
The saturation vapor pressure (psat) of low-volatility organic compounds (LVOCs) governs their partitioning between the gas and particle phases. To estimate the psat of selected LVOCs, we performed particle evaporation measurements in a residence time chamber at a temperature setting relevant to atmospheric aerosol formation and conducted state-of-the-art computational calculations. We found good agreement between the experimentally measured and model-estimated psat values for most LVOCs.
Bernadette Rosati, Sini Isokääntä, Sigurd Christiansen, Mads Mørk Jensen, Shamjad P. Moosakutty, Robin Wollesen de Jonge, Andreas Massling, Marianne Glasius, Jonas Elm, Annele Virtanen, and Merete Bilde
Atmos. Chem. Phys., 22, 13449–13466, https://doi.org/10.5194/acp-22-13449-2022, https://doi.org/10.5194/acp-22-13449-2022, 2022
Short summary
Short summary
Sulfate aerosols have a strong influence on climate. Due to the reduction in sulfur-based fossil fuels, natural sulfur emissions play an increasingly important role. Studies investigating the climate relevance of natural sulfur aerosols are scarce. We study the water uptake of such particles in the laboratory, demonstrating a high potential to take up water and form cloud droplets. During atmospheric transit, chemical processing affects the particles’ composition and thus their water uptake.
Jingwen Xue, Fangfang Ma, Jonas Elm, Jingwen Chen, and Hong-Bin Xie
Atmos. Chem. Phys., 22, 11543–11555, https://doi.org/10.5194/acp-22-11543-2022, https://doi.org/10.5194/acp-22-11543-2022, 2022
Short summary
Short summary
·OH/·Cl initiated indole reactions mainly form organonitrates, alkoxy radicals and hydroperoxide products, showing a varying mechanism from previously reported amines reactions. This study reveals carcinogenic nitrosamines cannot be formed in indole oxidation reactions despite radicals formed from -NH- H abstraction. The results are important to understand the atmospheric impact of indole oxidation and extend current understanding on the atmospheric chemistry of organic nitrogen compounds.
Sampo Vepsäläinen, Silvia M. Calderón, Jussi Malila, and Nønne L. Prisle
Atmos. Chem. Phys., 22, 2669–2687, https://doi.org/10.5194/acp-22-2669-2022, https://doi.org/10.5194/acp-22-2669-2022, 2022
Short summary
Short summary
Atmospheric aerosols act as seeds for cloud formation. Many aerosols contain surface active material that accumulates at the surface of growing droplets. This can affect cloud droplet activation, but the broad significance of the effect and the best way to model it are still debated. We compare predictions of six different model approaches to surface activity of organic aerosols and find significant differences between the models, especially with large fractions of organics in the dry particles.
Rongjie Zhang, Jiewen Shen, Hong-Bin Xie, Jingwen Chen, and Jonas Elm
Atmos. Chem. Phys., 22, 2639–2650, https://doi.org/10.5194/acp-22-2639-2022, https://doi.org/10.5194/acp-22-2639-2022, 2022
Short summary
Short summary
Formic acid is screened out as the species that can effectively catalyze the new particle formation (NPF) of the methanesulfonic acid (MSA)–methylamine system, indicating organic acids might be required to facilitate MSA-driven NPF in the atmosphere. The results are significant to comprehensively understand the MSA-driven NPF and expand current knowledge of the contribution of OAs to NPF.
Noora Hyttinen, Iida Pullinen, Aki Nissinen, Siegfried Schobesberger, Annele Virtanen, and Taina Yli-Juuti
Atmos. Chem. Phys., 22, 1195–1208, https://doi.org/10.5194/acp-22-1195-2022, https://doi.org/10.5194/acp-22-1195-2022, 2022
Short summary
Short summary
Accurate saturation vapor pressure estimates of atmospherically relevant organic compounds are critical for modeling secondary organic aerosol (SOA) formation. We investigated vapor pressures of highly oxygenated SOA constituents using state-of-the-art computational and experimental methods. We found a good agreement between low and extremely low vapor pressures estimated using the two methods, and the smallest molecules detected in our experiment were likely products of thermal decomposition.
Nønne L. Prisle
Atmos. Chem. Phys., 21, 16387–16411, https://doi.org/10.5194/acp-21-16387-2021, https://doi.org/10.5194/acp-21-16387-2021, 2021
Short summary
Short summary
A mass-based Gibbs adsorption model is presented to enable predictive Köhler calculations of droplet growth and activation with considerations of surface partitioning, surface tension, and non-ideal water activity for chemically complex and unresolved surface active aerosol mixtures, including actual atmospheric samples. The model is used to calculate cloud condensation nuclei (CCN) activity of aerosol particles comprising strongly surface-active model atmospheric humic-like substances (HULIS).
Robin Wollesen de Jonge, Jonas Elm, Bernadette Rosati, Sigurd Christiansen, Noora Hyttinen, Dana Lüdemann, Merete Bilde, and Pontus Roldin
Atmos. Chem. Phys., 21, 9955–9976, https://doi.org/10.5194/acp-21-9955-2021, https://doi.org/10.5194/acp-21-9955-2021, 2021
Short summary
Short summary
This study presents a detailed analysis of the OH-initiated oxidation of dimethyl sulfide (DMS) based on experiments performed in the Aarhus University Research on Aerosol (AURA) smog chamber and the gas- and particle-phase chemistry kinetic multilayer model (ADCHAM). We capture the formation, growth and chemical composition of aerosols in the chamber setup by an improved multiphase oxidation mechanism and utilize our results to reproduce the important role of DMS in the marine boundary layer.
Jack J. Lin, Kamal Raj R Mundoli, Stella Wang, Esko Kokkonen, Mikko-Heikki Mikkelä, Samuli Urpelainen, and Nønne L. Prisle
Atmos. Chem. Phys., 21, 4709–4727, https://doi.org/10.5194/acp-21-4709-2021, https://doi.org/10.5194/acp-21-4709-2021, 2021
Short summary
Short summary
We used surface-sensitive X-ray photoelectron spectroscopy (XPS) to study laboratory-generated nanoparticles of atmospheric interest at 0–16 % relative humidity. XPS gives direct information about changes in the chemical state from the binding energies of probed elements. Our results indicate water adsorption and associated chemical changes at the particle surfaces well below deliquescence, with distinct features for different particle components and implications for atmospheric chemistry.
Georgia Michailoudi, Jack J. Lin, Hayato Yuzawa, Masanari Nagasaka, Marko Huttula, Nobuhiro Kosugi, Theo Kurtén, Minna Patanen, and Nønne L. Prisle
Atmos. Chem. Phys., 21, 2881–2894, https://doi.org/10.5194/acp-21-2881-2021, https://doi.org/10.5194/acp-21-2881-2021, 2021
Short summary
Short summary
This study provides insight into hydration of two significant atmospheric compounds, glyoxal and methylglyoxal. Using synchrotron radiation excited X-ray absorption spectroscopy, we confirm that glyoxal is fully hydrated in water, and for the first time, we experimentally detect enol structures in aqueous methylglyoxal. Our results support the contribution of these compounds to secondary organic aerosol formation, known to have a large uncertainty in atmospheric models and climate predictions.
Ari Laaksonen, Jussi Malila, and Athanasios Nenes
Atmos. Chem. Phys., 20, 13579–13589, https://doi.org/10.5194/acp-20-13579-2020, https://doi.org/10.5194/acp-20-13579-2020, 2020
Short summary
Short summary
Aerosol particles containing black carbon are ubiquitous in the atmosphere and originate from combustion processes. We examine their capability to act as condensation centers for water vapor. We make use of published experimental data sets for different types of black carbon particles, ranging from very pure particles to particles that contain both black carbon and water soluble organic matter, and we show that a recently developed theory reproduces most of the experimental results.
Noora Hyttinen, Reyhaneh Heshmatnezhad, Jonas Elm, Theo Kurtén, and Nønne L. Prisle
Atmos. Chem. Phys., 20, 13131–13143, https://doi.org/10.5194/acp-20-13131-2020, https://doi.org/10.5194/acp-20-13131-2020, 2020
Short summary
Short summary
We present aqueous solubilities and activity coefficients of mono- and dicarboxylic acids (C1–C6 and C2–C8, respectively) estimated using the COSMOtherm program. In addition, we have calculated effective equilibrium constants of dimerization and hydration of the same acids in the condensed phase. We were also able to improve the agreement between experimental and estimated properties of monocarboxylic acids in aqueous solutions by including clustering reactions in COSMOtherm calculations.
Kasper Kristensen, Louise N. Jensen, Lauriane L. J. Quéléver, Sigurd Christiansen, Bernadette Rosati, Jonas Elm, Ricky Teiwes, Henrik B. Pedersen, Marianne Glasius, Mikael Ehn, and Merete Bilde
Atmos. Chem. Phys., 20, 12549–12567, https://doi.org/10.5194/acp-20-12549-2020, https://doi.org/10.5194/acp-20-12549-2020, 2020
Short summary
Short summary
Atmospheric particles are important in relation to human health and the global climate. As the global temperature changes, so may the atmospheric chemistry controlling the formation of particles from reactions of naturally emitted volatile organic compounds (VOCs). In the current work, we show how temperatures influence the formation and chemical composition of atmospheric particles from α-pinene: a biogenic VOC largely emitted in high-latitude environments such as the boreal forests.
Nønne L. Prisle, Jack J. Lin, Sara Purdue, Haisheng Lin, J. Carson Meredith, and Athanasios Nenes
Atmos. Chem. Phys., 19, 4741–4761, https://doi.org/10.5194/acp-19-4741-2019, https://doi.org/10.5194/acp-19-4741-2019, 2019
Short summary
Short summary
We measure surface activity and cloud-forming potential of pollenkitt, an organic mixture coating pollen grains. Cloud droplet formation is affected through both surface tension and bulk depletion, with a consistent particle size-dependent signature. We observe nonideal solution effects in pollenkitt mixtures with ammonium sulfate salt. Our results suggest sensitivity of general water interactions, including cloud formation by pollen and their fragments, to both atmospheric humidity and aging.
Michael Boy, Erik S. Thomson, Juan-C. Acosta Navarro, Olafur Arnalds, Ekaterina Batchvarova, Jaana Bäck, Frank Berninger, Merete Bilde, Zoé Brasseur, Pavla Dagsson-Waldhauserova, Dimitri Castarède, Maryam Dalirian, Gerrit de Leeuw, Monika Dragosics, Ella-Maria Duplissy, Jonathan Duplissy, Annica M. L. Ekman, Keyan Fang, Jean-Charles Gallet, Marianne Glasius, Sven-Erik Gryning, Henrik Grythe, Hans-Christen Hansson, Margareta Hansson, Elisabeth Isaksson, Trond Iversen, Ingibjorg Jonsdottir, Ville Kasurinen, Alf Kirkevåg, Atte Korhola, Radovan Krejci, Jon Egill Kristjansson, Hanna K. Lappalainen, Antti Lauri, Matti Leppäranta, Heikki Lihavainen, Risto Makkonen, Andreas Massling, Outi Meinander, E. Douglas Nilsson, Haraldur Olafsson, Jan B. C. Pettersson, Nønne L. Prisle, Ilona Riipinen, Pontus Roldin, Meri Ruppel, Matthew Salter, Maria Sand, Øyvind Seland, Heikki Seppä, Henrik Skov, Joana Soares, Andreas Stohl, Johan Ström, Jonas Svensson, Erik Swietlicki, Ksenia Tabakova, Throstur Thorsteinsson, Aki Virkkula, Gesa A. Weyhenmeyer, Yusheng Wu, Paul Zieger, and Markku Kulmala
Atmos. Chem. Phys., 19, 2015–2061, https://doi.org/10.5194/acp-19-2015-2019, https://doi.org/10.5194/acp-19-2015-2019, 2019
Short summary
Short summary
The Nordic Centre of Excellence CRAICC (Cryosphere–Atmosphere Interactions in a Changing Arctic Climate), funded by NordForsk in the years 2011–2016, is the largest joint Nordic research and innovation initiative to date and aimed to strengthen research and innovation regarding climate change issues in the Nordic region. The paper presents an overview of the main scientific topics investigated and provides a state-of-the-art comprehensive summary of what has been achieved in CRAICC.
Theo Kurtén, Noora Hyttinen, Emma Louise D'Ambro, Joel Thornton, and Nønne Lyng Prisle
Atmos. Chem. Phys., 18, 17589–17600, https://doi.org/10.5194/acp-18-17589-2018, https://doi.org/10.5194/acp-18-17589-2018, 2018
Short summary
Short summary
We use COSMO-RS to compute saturation vapor pressures for two products of isoprene photo-oxidation and compare the results to measurements. COSMO-RS is an attractive option for calculating properties of molecules, as it is based on quantum mechanics and requires few fitting parameters. However, we show that the default implementation of this method suffers from errors related to both conformational sampling and intramolecular hydrogen bonding. We propose solutions to these problems.
Ulrich K. Krieger, Franziska Siegrist, Claudia Marcolli, Eva U. Emanuelsson, Freya M. Gøbel, Merete Bilde, Aleksandra Marsh, Jonathan P. Reid, Andrew J. Huisman, Ilona Riipinen, Noora Hyttinen, Nanna Myllys, Theo Kurtén, Thomas Bannan, Carl J. Percival, and David Topping
Atmos. Meas. Tech., 11, 49–63, https://doi.org/10.5194/amt-11-49-2018, https://doi.org/10.5194/amt-11-49-2018, 2018
Short summary
Short summary
Vapor pressures of low-volatility organic molecules at atmospheric temperatures reported in the literature often differ by several orders of magnitude between measurement techniques. These discrepancies exceed the stated uncertainty of each technique, which is generally reported to be smaller than a factor of 2. We determined saturation vapor pressures for the homologous series of polyethylene glycols ranging in vapor pressure at 298 K from 1E−7 Pa to 5E−2 Pa as a reference set.
Juan Hong, Mikko Äijälä, Silja A. K. Häme, Liqing Hao, Jonathan Duplissy, Liine M. Heikkinen, Wei Nie, Jyri Mikkilä, Markku Kulmala, Nønne L. Prisle, Annele Virtanen, Mikael Ehn, Pauli Paasonen, Douglas R. Worsnop, Ilona Riipinen, Tuukka Petäjä, and Veli-Matti Kerminen
Atmos. Chem. Phys., 17, 4387–4399, https://doi.org/10.5194/acp-17-4387-2017, https://doi.org/10.5194/acp-17-4387-2017, 2017
Short summary
Short summary
Estimates of volatility of secondary organic aerosols was characterized in a boreal forest environment of Hyytiälä, southern Finland. This was done by interpreting field measurements using a volatility tandem differential mobility analyzer (VTDMA) with a kinetic evaporation model and by applying positive matrix factorization (PMF) to high-resolution aerosol mass spectrometer data. About 16 % of the variation can be explained by the linear regression between the results from these two methods.
Bjarke Mølgaard, Jarno Vanhatalo, Pasi P. Aalto, Nønne L. Prisle, and Kaarle Hämeri
Atmos. Meas. Tech., 9, 741–751, https://doi.org/10.5194/amt-9-741-2016, https://doi.org/10.5194/amt-9-741-2016, 2016
Short summary
Short summary
We have improved the reliability of submicron aerosol particle size distributions measured in urban locations. This improvement was obtained by processing the data in a new way and avoiding a problematic assumption of a stationary aerosol during each size distribution measurement.
H. Vuollekoski, M. Vogt, V. A. Sinclair, J. Duplissy, H. Järvinen, E.-M. Kyrö, R. Makkonen, T. Petäjä, N. L. Prisle, P. Räisänen, M. Sipilä, J. Ylhäisi, and M. Kulmala
Hydrol. Earth Syst. Sci., 19, 601–613, https://doi.org/10.5194/hess-19-601-2015, https://doi.org/10.5194/hess-19-601-2015, 2015
Short summary
Short summary
The global potential for collecting usable water from dew on an
artificial collector sheet was investigated by utilising 34 years of
meteorological reanalysis data as input to a dew formation model. Continental dew formation was found to be frequent and common, but daily yields were
mostly below 0.1mm.
M. Paramonov, P. P. Aalto, A. Asmi, N. Prisle, V.-M. Kerminen, M. Kulmala, and T. Petäjä
Atmos. Chem. Phys., 13, 10285–10301, https://doi.org/10.5194/acp-13-10285-2013, https://doi.org/10.5194/acp-13-10285-2013, 2013
N. L. Prisle, N. Ottosson, G. Öhrwall, J. Söderström, M. Dal Maso, and O. Björneholm
Atmos. Chem. Phys., 12, 12227–12242, https://doi.org/10.5194/acp-12-12227-2012, https://doi.org/10.5194/acp-12-12227-2012, 2012
Related subject area
Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
A global dust emission dataset for estimating dust radiative forcings in climate models
Tropospheric aerosols over the western North Atlantic Ocean during the winter and summer deployments of ACTIVATE 2020: life cycle, transport, and distribution
Spatial and temporal evolution of future atmospheric reactive nitrogen deposition in China under different climate change mitigation strategies
Steady-state mixing state of black carbon aerosols from a particle-resolved model
Distinctive dust weather intensities in North China resulted from two types of atmospheric circulation anomalies
Biomass burning emission analysis based on MODIS aerosol optical depth and AeroCom multi-model simulations: implications for model constraints and emission inventories
Quasi-weekly oscillation of regional PM2.5 transport over China driven by the synoptic-scale disturbance of the East Asian winter monsoon circulation
Solar radiation estimation in West Africa: impact of dust conditions during the 2021 dry season
Gaps in our understanding of ice-nucleating particle sources exposed by global simulation of the UK Earth System Model
The role of interfacial tension in the size-dependent phase separation of atmospheric aerosol particles
Warming effects of reduced sulfur emissions from shipping
The key role of atmospheric absorption in the Asian summer monsoon response to dust emissions in CMIP6 models
Multi-model effective radiative forcing of the 2020 sulfur cap for shipping
Representation of iron aerosol size distributions of anthropogenic emissions is critical in evaluating atmospheric soluble iron input to the ocean
High-resolution air quality maps for Bucharest using Mixed-Effects Modeling Framework
Revealing dominant patterns of aerosol regimes in the lower troposphere and their evolution from preindustrial times to the future in global climate model simulations
Improving estimation of a record-breaking east Asian dust storm emission with lagged aerosol Ångström exponent observations
Impact of biomass burning aerosols (BBA) on the tropical African climate in an ocean–atmosphere–aerosol coupled climate model
Retrieval of refractive index and water content for the coating materials of aged black carbon aerosol based on optical properties: a theoretical analysis
Predicting hygroscopic growth of organosulfur aerosol particles using COSMOtherm
Dust aerosol from the Aralkum Desert influences the radiation budget and atmospheric dynamics of Central Asia
Global modeling of aerosol nucleation with a semi-explicit chemical mechanism for highly oxygenated organic molecules (HOMs)
Synergistic effects of the winter North Atlantic Oscillation (NAO) and El Niño–Southern Oscillation (ENSO) on dust activities in North China during the following spring
Aerosol composition, air quality, and boundary layer dynamics in the urban background of Stuttgart in winter
Measurement report: Source attribution and estimation of black carbon levels in an urban hotspot of the central Po Valley – an integrated approach combining high-resolution dispersion modelling and micro-aethalometers
Construction and Application of a Pollen Emissions Model based on Phenology and Random Forests
Microphysical modelling of aerosol scavenging by different types of clouds: description and validation of the approach
Insights into the sources of ultrafine particle numbers at six European urban sites obtained by investigating COVID-19 lockdowns
In-plume and out-of-plume analysis of aerosol–cloud interactions derived from the 2014–2015 Holuhraun volcanic eruption
Impacts of atmospheric circulation patterns and cloud inhibition on aerosol radiative effect and boundary layer structure during winter air pollution in Sichuan Basin, China
The effectiveness of solar radiation management for marine cloud brightening geoengineering by fine sea spray in worldwide different climatic regions
Accounting for Black Carbon Aging Process in a Two-way Coupled Meteorology – Air Quality Model
Investigating the sign of stratocumulus adjustments to aerosols in the ICON global storm-resolving model
A model study investigating the sensitivity of aerosol forcing to the volatilities of semi-volatile organic compounds
Characterization of Brown Carbon absorption in different European environments through source contribution analysis
The impact of uncertainty in black carbon's refractive index on simulated optical depth and radiative forcing
Decomposing the effective radiative forcing of anthropogenic aerosols based on CMIP6 Earth system models
Modeling impacts of dust mineralogy on fast climate response
Uncertainties in laboratory-measured shortwave refractive indices of mineral dust aerosols and derived optical properties: a theoretical assessment
Diagnosing uncertainties in global biomass burning emission inventories and their impact on modeled air pollutants
Role of atmospheric aerosols in severe winter fog over the Indo-Gangetic Plain of India: a case study
Long-term variability in black carbon emissions constrained by gap-filled absorption aerosol optical depth and associated premature mortality in China
Intercomparison of aerosol optical depths from four reanalyses and their multi-reanalysis consensus
Global aviation contrail climate effects from 2019 to 2021
Rapid iodine oxoacid nucleation enhanced by dimethylamine in broad marine regions
Simulations of the impact of cloud condensation nuclei and ice-nucleating particles perturbations on the microphysics and radar reflectivity factor of stratiform mixed-phase clouds
Aerosols in the central Arctic cryosphere: satellite and model integrated insights during Arctic spring and summer
Observationally constrained regional variations of shortwave absorption by iron oxides emphasize the cooling effect of dust
Droplet collection efficiencies inferred from satellite retrievals constrain effective radiative forcing of aerosol–cloud interactions
Global aerosol-type classification using a new hybrid algorithm and Aerosol Robotic Network data
Danny M. Leung, Jasper F. Kok, Longlei Li, David M. Lawrence, Natalie M. Mahowald, Simone Tilmes, and Erik Kluzek
Atmos. Chem. Phys., 25, 2311–2331, https://doi.org/10.5194/acp-25-2311-2025, https://doi.org/10.5194/acp-25-2311-2025, 2025
Short summary
Short summary
This study derives a gridded dust emission dataset for 1841–2000 by employing a combination of observed dust from core records and reanalyzed global dust cycle constraints. We evaluate the ability of global models to replicate the observed historical dust variability by using the emission dataset to force a historical simulation in an Earth system model. We show that prescribing our emissions forces the model to better match observations than other mechanistic models.
Hongyu Liu, Bo Zhang, Richard H. Moore, Luke D. Ziemba, Richard A. Ferrare, Hyundeok Choi, Armin Sorooshian, David Painemal, Hailong Wang, Michael A. Shook, Amy Jo Scarino, Johnathan W. Hair, Ewan C. Crosbie, Marta A. Fenn, Taylor J. Shingler, Chris A. Hostetler, Gao Chen, Mary M. Kleb, Gan Luo, Fangqun Yu, Mark A. Vaughan, Yongxiang Hu, Glenn S. Diskin, John B. Nowak, Joshua P. DiGangi, Yonghoon Choi, Christoph A. Keller, and Matthew S. Johnson
Atmos. Chem. Phys., 25, 2087–2121, https://doi.org/10.5194/acp-25-2087-2025, https://doi.org/10.5194/acp-25-2087-2025, 2025
Short summary
Short summary
We use the GEOS-Chem model to simulate aerosol distributions and properties over the western North Atlantic Ocean (WNAO) during the winter and summer deployments in 2020 of the NASA ACTIVATE mission. Model results are evaluated against aircraft, ground-based, and satellite observations. The improved understanding of life cycle, composition, transport pathways, and distribution of aerosols has important implications for characterizing aerosol–cloud–meteorology interactions over WNAO.
Mingrui Ma, Jiachen Cao, Dan Tong, Bo Zheng, and Yu Zhao
Atmos. Chem. Phys., 25, 2147–2166, https://doi.org/10.5194/acp-25-2147-2025, https://doi.org/10.5194/acp-25-2147-2025, 2025
Short summary
Short summary
We combined two global climate change pathways and three national emission control scenarios to analyze the future evolution of reactive nitrogen (Nr) deposition till the 2060s in China with air quality modeling. We show China’s clean air and carbon neutrality policies would overcome the adverse effects of climate change and efficiently reduce Nr deposition. The outflow of Nr fluxes from mainland China to the west Pacific would also be clearly reduced from continuous stringent emission controls.
Zhouyang Zhang, Jiandong Wang, Jiaping Wang, Nicole Riemer, Chao Liu, Yuzhi Jin, Zeyuan Tian, Jing Cai, Yueyue Cheng, Ganzhen Chen, Bin Wang, Shuxiao Wang, and Aijun Ding
Atmos. Chem. Phys., 25, 1869–1881, https://doi.org/10.5194/acp-25-1869-2025, https://doi.org/10.5194/acp-25-1869-2025, 2025
Short summary
Short summary
Black carbon (BC) exerts notable warming effects. We use a particle-resolved model to investigate the long-term behavior of the BC mixing state, revealing its compositions, coating thickness distribution, and optical properties all stabilize with a characteristic time of less than 1 d. This study can effectively simplify the description of the BC mixing state, which facilitates the precise assessment of the optical properties of BC aerosols in global and chemical transport models.
Qianyi Huo, Zhicong Yin, Xiaoqing Ma, and Huijun Wang
Atmos. Chem. Phys., 25, 1711–1724, https://doi.org/10.5194/acp-25-1711-2025, https://doi.org/10.5194/acp-25-1711-2025, 2025
Short summary
Short summary
Dust days during the spring seasons of 2015–2023 in North China were classified into Mongolian cyclone and cold high types depending on the presence of the Mongolian cyclone. The Mongolian cyclone type led to more frequent and severe dust weather, indicated by PM10 concentrations. To comprehensively forecast the two types of dust weather, a common predictor was established based on 500 hPa anomalous circulation systems, offering insights for dust weather forecasting and climate prediction.
Mariya Petrenko, Ralph Kahn, Mian Chin, Susanne E. Bauer, Tommi Bergman, Huisheng Bian, Gabriele Curci, Ben Johnson, Johannes W. Kaiser, Zak Kipling, Harri Kokkola, Xiaohong Liu, Keren Mezuman, Tero Mielonen, Gunnar Myhre, Xiaohua Pan, Anna Protonotariou, Samuel Remy, Ragnhild Bieltvedt Skeie, Philip Stier, Toshihiko Takemura, Kostas Tsigaridis, Hailong Wang, Duncan Watson-Parris, and Kai Zhang
Atmos. Chem. Phys., 25, 1545–1567, https://doi.org/10.5194/acp-25-1545-2025, https://doi.org/10.5194/acp-25-1545-2025, 2025
Short summary
Short summary
We compared smoke plume simulations from 11 global models to each other and to satellite smoke amount observations aimed at constraining smoke source strength. In regions where plumes are thick and background aerosol is low, models and satellites compare well. However, the input emission inventory tends to underestimate in many places, and particle property and loss rate assumptions vary enormously among models, causing uncertainties that require systematic in situ measurements to resolve.
Yongqing Bai, Tianliang Zhao, Kai Meng, Yue Zhou, Jie Xiong, Xiaoyun Sun, Lijuan Shen, Yanyu Yue, Yan Zhu, Weiyang Hu, and Jingyan Yao
Atmos. Chem. Phys., 25, 1273–1287, https://doi.org/10.5194/acp-25-1273-2025, https://doi.org/10.5194/acp-25-1273-2025, 2025
Short summary
Short summary
We proposed a composite statistical method to identify the quasi-weekly oscillation (QWO) of regional PM2.5 transport over China in winter from 2015 to 2019. The QWO of regional PM2.5 transport is constrained by synoptic-scale disturbances of the East Asian winter monsoon circulation with the periodic activities of the Siberian high, providing a new insight into the understanding of regional pollutant transport with meteorological drivers in atmospheric environment changes.
Léo Clauzel, Sandrine Anquetin, Christophe Lavaysse, Gilles Bergametti, Christel Bouet, Guillaume Siour, Rémy Lapere, Béatrice Marticorena, and Jennie Thomas
Atmos. Chem. Phys., 25, 997–1021, https://doi.org/10.5194/acp-25-997-2025, https://doi.org/10.5194/acp-25-997-2025, 2025
Short summary
Short summary
Solar energy production in West Africa is set to rise and needs accurate solar radiation estimates which are affected by desert dust. This work analyses a March 2021 dust event using a modelling strategy incorporating desert dust. Results show that considering desert dust cuts errors in solar radiation estimates by 75 % and reduces surface solar radiation by 18 %. This highlights the importance of incorporating dust aerosols into solar forecasting for better accuracy.
Ross J. Herbert, Alberto Sanchez-Marroquin, Daniel P. Grosvenor, Kirsty J. Pringle, Stephen R. Arnold, Benjamin J. Murray, and Kenneth S. Carslaw
Atmos. Chem. Phys., 25, 291–325, https://doi.org/10.5194/acp-25-291-2025, https://doi.org/10.5194/acp-25-291-2025, 2025
Short summary
Short summary
Aerosol particles that help form ice in clouds vary in number and type around the world and with time. However, in many weather and climate models cloud ice is not linked to aerosols that are known to nucleate ice. Here we report the first steps towards representing ice-nucleating particles within the UK Earth System Model. We conclude that in addition to ice nucleation by sea spray and mineral components of soil dust, we also need to represent ice nucleation by the organic components of soils.
Ryan Schmedding and Andreas Zuend
Atmos. Chem. Phys., 25, 327–346, https://doi.org/10.5194/acp-25-327-2025, https://doi.org/10.5194/acp-25-327-2025, 2025
Short summary
Short summary
Four different approaches for computing the interfacial tension between liquid phases in aerosol particles were tested for particles with diameters from 10 nm to more than 5 μm. Antonov's rule led to the strongest reductions in the onset relative humidity of liquid–liquid phase separation and reproduced measured interfacial tensions for highly immiscible systems. A modified form of the Butler equation was able to best reproduce measured interfacial tensions in more miscible systems.
Masaru Yoshioka, Daniel P. Grosvenor, Ben B. B. Booth, Colin P. Morice, and Ken S. Carslaw
Atmos. Chem. Phys., 24, 13681–13692, https://doi.org/10.5194/acp-24-13681-2024, https://doi.org/10.5194/acp-24-13681-2024, 2024
Short summary
Short summary
A 2020 regulation has reduced sulfur emissions from shipping by about 80 %, leading to a decrease in atmospheric aerosols that have a cooling effect primarily by affecting cloud properties and amounts. Our climate model simulations predict a global temperature increase of 0.04 K over the next 3 decades as a result, which could contribute to surpassing the Paris Agreement's 1.5 °C target. Reduced aerosols may have also contributed to the recent temperature spikes.
Alcide Zhao, Laura J. Wilcox, and Claire L. Ryder
Atmos. Chem. Phys., 24, 13385–13402, https://doi.org/10.5194/acp-24-13385-2024, https://doi.org/10.5194/acp-24-13385-2024, 2024
Short summary
Short summary
Climate models include desert dust aerosols, which cause atmospheric heating and can change circulation patterns. We assess the effect of dust on the Indian and east Asian summer monsoons through multi-model experiments isolating the effect of dust in current climate models for the first time. Dust atmospheric heating results in a southward shift of western Pacific equatorial rainfall and an enhanced Indian summer monsoon. This shows the importance of accurate dust representation in models.
Ragnhild Bieltvedt Skeie, Rachael Byrom, Øivind Hodnebrog, Caroline Jouan, and Gunnar Myhre
Atmos. Chem. Phys., 24, 13361–13370, https://doi.org/10.5194/acp-24-13361-2024, https://doi.org/10.5194/acp-24-13361-2024, 2024
Short summary
Short summary
In 2020, new regulations by the International Maritime Organization regarding sulfur emissions came into force, reducing emissions of SO2 from the shipping sector by approximately 80 %. In this study, we use multiple models to calculate how much the Earth energy balance changed due to the emission reduction or the so-called effective radiative forcing. The calculated effective radiative forcing is weak, comparable to the effect of the increase in CO2 over the last 2 to 3 years.
Mingxu Liu, Hitoshi Matsui, Douglas S. Hamilton, Sagar D. Rathod, Kara D. Lamb, and Natalie M. Mahowald
Atmos. Chem. Phys., 24, 13115–13127, https://doi.org/10.5194/acp-24-13115-2024, https://doi.org/10.5194/acp-24-13115-2024, 2024
Short summary
Short summary
Atmospheric aerosol deposition provides bioavailable iron to promote marine primary production, yet the estimates of its fluxes remain highly uncertain. This study, by performing global aerosol simulations, demonstrates that iron-containing particle size upon emission is a critical factor in regulating soluble iron input to open oceans. Further observational constraints on this are needed to reduce modeling uncertainties.
Camelia Talianu, Jeni Vasilescu, Doina Nicolae, Alexandru Ilie, Andrei Dandocsi, Anca Nemuc, and Livio Belegante
EGUsphere, https://doi.org/10.5194/egusphere-2024-2930, https://doi.org/10.5194/egusphere-2024-2930, 2024
Short summary
Short summary
Bucharest, Romania's capital, has successfully used mobile measurements and mixed-effects LUR models to derive seasonal maps of near-surface PM10, NO2, and UFP. The data was collected during two intensive campaigns, covering high-traffic streets, residential, industrial, and commercial districts. The model's performance was evaluated, demonstrating its potential for high-resolution mapping in other cities with well-characterized urban structures and diverse in situ monitoring stations.
Jingmin Li, Mattia Righi, Johannes Hendricks, Christof G. Beer, Ulrike Burkhardt, and Anja Schmidt
Atmos. Chem. Phys., 24, 12727–12747, https://doi.org/10.5194/acp-24-12727-2024, https://doi.org/10.5194/acp-24-12727-2024, 2024
Short summary
Short summary
Aiming to understand underlying patterns and trends in aerosols, we characterize the spatial patterns and long-term evolution of lower tropospheric aerosols by clustering multiple aerosol properties from preindustrial times to the year 2050 under three Shared
Socioeconomic Pathway scenarios. The results provide a clear and condensed picture of the spatial extent and distribution of aerosols for different time periods and emission scenarios.
Socioeconomic Pathway scenarios. The results provide a clear and condensed picture of the spatial extent and distribution of aerosols for different time periods and emission scenarios.
Yueming Cheng, Tie Dai, Junji Cao, Daisuke Goto, Jianbing Jin, Teruyuki Nakajima, and Guangyu Shi
Atmos. Chem. Phys., 24, 12643–12659, https://doi.org/10.5194/acp-24-12643-2024, https://doi.org/10.5194/acp-24-12643-2024, 2024
Short summary
Short summary
In March 2021, east Asia experienced an outbreak of severe dust storms after an absence of 1.5 decades. Here, we innovatively used the time-lagged ground-based aerosol size information with the fixed-lag ensemble Kalman smoother to optimize dust emission and reproduce the dust storm. This work is valuable for not only the quantification of health damage, aviation risks, and profound impacts on the Earth's system but also revealing the climatic driving force and the process of desertification.
Marc Mallet, Aurore Voldoire, Fabien Solmon, Pierre Nabat, Thomas Drugé, and Romain Roehrig
Atmos. Chem. Phys., 24, 12509–12535, https://doi.org/10.5194/acp-24-12509-2024, https://doi.org/10.5194/acp-24-12509-2024, 2024
Short summary
Short summary
This study investigates the interactions between smoke aerosols and climate in tropical Africa using a coupled ocean–atmosphere–aerosol climate model. The work shows that smoke plumes have a significant impact by increasing the low-cloud fraction, decreasing the ocean and continental surface temperature and reducing the precipitation of coastal western Africa. It also highlights the role of the ocean temperature response and its feedbacks for the September–November season.
Jia Liu, Cancan Zhu, Donghui Zhou, and Jinbao Han
Atmos. Chem. Phys., 24, 12341–12354, https://doi.org/10.5194/acp-24-12341-2024, https://doi.org/10.5194/acp-24-12341-2024, 2024
Short summary
Short summary
The hydrophilic coatings of aged black carbon (BC) particles absorb moisture during the hygroscopic growth process, but it is difficult to characterize how much water is absorbed under different relative humidities (RHs). In this study, we propose a method to obtain the water content in the coatings based on the equivalent complex refractive index retrieved from optical properties. This method is verified from a theoretical perspective, and it performs well for thickly coated BC at high RHs.
Zijun Li, Angela Buchholz, and Noora Hyttinen
Atmos. Chem. Phys., 24, 11717–11725, https://doi.org/10.5194/acp-24-11717-2024, https://doi.org/10.5194/acp-24-11717-2024, 2024
Short summary
Short summary
Evaluating organosulfur (OS) hygroscopicity is important for assessing aerosol–cloud climate interactions in the post-fossil-fuel future, when SO2 emissions decrease and OS compounds become increasingly important. Here a state-of-the-art quantum-chemistry-based method was used to predict the hygroscopic growth factors (HGFs) of a group of atmospherically relevant OS compounds and their mixtures with (NH4)2SO4. A good agreement was observed between their model-estimated and experimental HGFs.
Jamie R. Banks, Bernd Heinold, and Kerstin Schepanski
Atmos. Chem. Phys., 24, 11451–11475, https://doi.org/10.5194/acp-24-11451-2024, https://doi.org/10.5194/acp-24-11451-2024, 2024
Short summary
Short summary
The Aralkum is a new desert in Central Asia formed by the desiccation of the Aral Sea. This has created a source of atmospheric dust, with implications for the balance of solar and thermal radiation. Simulating these effects using a dust transport model, we find that Aralkum dust adds radiative cooling effects to the surface and atmosphere on average but also adds heating events. Increases in surface pressure due to Aralkum dust strengthen the Siberian High and weaken the summer Asian heat low.
Xinyue Shao, Minghuai Wang, Xinyi Dong, Yaman Liu, Wenxiang Shen, Stephen R. Arnold, Leighton A. Regayre, Meinrat O. Andreae, Mira L. Pöhlker, Duseong S. Jo, Man Yue, and Ken S. Carslaw
Atmos. Chem. Phys., 24, 11365–11389, https://doi.org/10.5194/acp-24-11365-2024, https://doi.org/10.5194/acp-24-11365-2024, 2024
Short summary
Short summary
Highly oxygenated organic molecules (HOMs) play an important role in atmospheric new particle formation (NPF). By semi-explicitly coupling the chemical mechanism of HOMs and a comprehensive nucleation scheme in a global climate model, the updated model shows better agreement with measurements of nucleation rate, growth rate, and NPF event frequency. Our results reveal that HOM-driven NPF leads to a considerable increase in particle and cloud condensation nuclei burden globally.
Falei Xu, Shuang Wang, Yan Li, and Juan Feng
Atmos. Chem. Phys., 24, 10689–10705, https://doi.org/10.5194/acp-24-10689-2024, https://doi.org/10.5194/acp-24-10689-2024, 2024
Short summary
Short summary
This study examines how the winter North Atlantic Oscillation (NAO) and El Niño–Southern Oscillation (ENSO) affect dust activities in North China during the following spring. The results show that the NAO and ENSO, particularly in their negative phases, greatly influence dust activities. When both are negative, their combined effect on dust activities is even greater. This research highlights the importance of these climate patterns in predicting spring dust activities in North China.
Hengheng Zhang, Wei Huang, Xiaoli Shen, Ramakrishna Ramisetty, Junwei Song, Olga Kiseleva, Christopher Claus Holst, Basit Khan, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 24, 10617–10637, https://doi.org/10.5194/acp-24-10617-2024, https://doi.org/10.5194/acp-24-10617-2024, 2024
Short summary
Short summary
Our study unravels how stagnant winter conditions elevate aerosol levels in Stuttgart. Cloud cover at night plays a pivotal role, impacting morning air quality. Validating a key model, our findings aid accurate air quality predictions, crucial for effective pollution mitigation in urban areas.
Giorgio Veratti, Alessandro Bigi, Michele Stortini, Sergio Teggi, and Grazia Ghermandi
Atmos. Chem. Phys., 24, 10475–10512, https://doi.org/10.5194/acp-24-10475-2024, https://doi.org/10.5194/acp-24-10475-2024, 2024
Short summary
Short summary
In a study of two consecutive winter seasons, we used measurements and modelling tools to identify the levels and sources of black carbon pollution in a medium-sized urban area of the Po Valley, Italy. Our findings show that biomass burning and traffic-related emissions (especially from Euro 4 diesel cars) significantly contribute to BC concentrations. This research offers crucial insights for policymakers and urban planners aiming to improve air quality in cities.
Jiangtao Li, Xingqin An, Zhaobin Sun, Caihua Ye, Qing Hou, Yuxin Zhao, and Zhe Liu
EGUsphere, https://doi.org/10.5194/egusphere-2024-2000, https://doi.org/10.5194/egusphere-2024-2000, 2024
Short summary
Short summary
Climate change and pollution have intensified pollen allergies. We developed a pollen emissions model using phenology and random forests. Key factors affecting annual pollen emissions include temperature, relative humidity, and sunshine hours. Pollen dispersal starts around August 10, peaks around August 30, and ends by September 25, lasting about 45 days. Over time, annual pollen emissions exhibit significant fluctuations and a downward trend.
Pascal Lemaitre, Arnaud Quérel, Alexis Dépée, Alice Guerra Devigne, Marie Monier, Thibault Hiron, Chloé Soto Minguez, Daniel Hardy, and Andrea Flossmann
Atmos. Chem. Phys., 24, 9713–9732, https://doi.org/10.5194/acp-24-9713-2024, https://doi.org/10.5194/acp-24-9713-2024, 2024
Short summary
Short summary
A new in-cloud scavenging scheme is proposed. It is based on a microphysical model of cloud formation and may be applied to long-distance atmospheric transport models (> 100 km) and climatic models. This model is applied to the two most extreme precipitating cloud types in terms of both relative humidity and vertical extension: cumulonimbus and stratus.
Alex Rowell, James Brean, David C. S. Beddows, Tuukka Petäjä, Máté Vörösmarty, Imre Salma, Jarkko V. Niemi, Hanna E. Manninen, Dominik van Pinxteren, Thomas Tuch, Kay Weinhold, Zongbo Shi, and Roy M. Harrison
Atmos. Chem. Phys., 24, 9515–9531, https://doi.org/10.5194/acp-24-9515-2024, https://doi.org/10.5194/acp-24-9515-2024, 2024
Short summary
Short summary
Different sources of airborne particles in the atmospheres of four European cities were distinguished by recognising their particle size distributions using a statistical procedure, positive matrix factorisation. The various sources responded differently to the changes in emissions associated with COVID-19 lockdowns, and the reasons are investigated. While traffic emissions generally decreased, particles formed from reactions of atmospheric gases decreased in some cities but increased in others.
Amy H. Peace, Ying Chen, George Jordan, Daniel G. Partridge, Florent Malavelle, Eliza Duncan, and Jim M. Haywood
Atmos. Chem. Phys., 24, 9533–9553, https://doi.org/10.5194/acp-24-9533-2024, https://doi.org/10.5194/acp-24-9533-2024, 2024
Short summary
Short summary
Natural aerosols from volcanic eruptions can help us understand how anthropogenic aerosols modify climate. We use observations and model simulations of the 2014–2015 Holuhraun eruption plume to examine aerosol–cloud interactions in September 2014. We find a shift to clouds with smaller, more numerous cloud droplets in the first 2 weeks of the eruption. In the third week, the background meteorology and previous conditions experienced by air masses modulate the aerosol perturbation to clouds.
Hua Lu, Min Xie, Bingliang Zhuang, Danyang Ma, Bojun Liu, Yangzhihao Zhan, Tijian Wang, Shu Li, Mengmeng Li, and Kuanguang Zhu
Atmos. Chem. Phys., 24, 8963–8982, https://doi.org/10.5194/acp-24-8963-2024, https://doi.org/10.5194/acp-24-8963-2024, 2024
Short summary
Short summary
To identify cloud, aerosol, and planetary boundary layer (PBL) interactions from an air quality perspective, we summarized two pollution patterns characterized by denser liquid cloud and by obvious cloud radiation interaction (CRI). Numerical simulation experiments showed CRI could cause a 50 % reduction in aerosol radiation interaction (ARI) under a low-trough system. The results emphasized the nonnegligible role of CRI and its inhibition of ARI under wet and cloudy pollution synoptic patterns.
Zhe Song, Ningning Yao, Lang Chen, Yuhai Sun, Boqiong Jiang, Pengfei Li, Daniel Rosenfeld, and Shaocai Yu
EGUsphere, https://doi.org/10.5194/egusphere-2024-2263, https://doi.org/10.5194/egusphere-2024-2263, 2024
Short summary
Short summary
Our results with injected sea-salt aerosols for five open oceans show that the sea-salt aerosols with low injection amounts dominated the shortwave radiation mainly through the indirect effects. As indirect aerosol effects saturated with increasing injection rates, direct effects exceeded indirect effects. This implies that marine cloud brightening was best implemented in areas with extensive cloud cover, while the aerosol direct scattering effects remained dominant when clouds were scarce.
Yuzhi Jin, Jiandong Wang, David C. Wong, Chao Liu, Golam Sarwar, Kathleen M. Fahey, Shang Wu, Jiaping Wang, Jing Cai, Zeyuan Tian, Zhouyang Zhang, Jia Xing, Aijun Ding, and Shuxiao Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2372, https://doi.org/10.5194/egusphere-2024-2372, 2024
Short summary
Short summary
Black carbon (BC) affects climate and the environment, and its aging process alters its properties. Current models, like WRF-CMAQ, lack full account. We developed the WRF-CMAQ-BCG model to better represent BC aging by introducing Bare/Coated BC species and their conversion. Our findings show that BC mixing states have distinct spatiotemporal distribution characteristics, and BC wet deposition is dominated by Coated BC. Accounting for BC aging process improves aerosol optics simulation accuracy.
Emilie Fons, Ann Kristin Naumann, David Neubauer, Theresa Lang, and Ulrike Lohmann
Atmos. Chem. Phys., 24, 8653–8675, https://doi.org/10.5194/acp-24-8653-2024, https://doi.org/10.5194/acp-24-8653-2024, 2024
Short summary
Short summary
Aerosols can modify the liquid water path (LWP) of stratocumulus and, thus, their radiative effect. We compare storm-resolving model and satellite data that disagree on the sign of LWP adjustments and diagnose this discrepancy with causal inference. We find that strong precipitation, the absence of wet scavenging, and cloud deepening under a weak inversion contribute to positive LWP adjustments to aerosols in the model, despite weak negative effects from cloud-top entrainment enhancement.
Muhammed Irfan, Thomas Kühn, Taina Yli-Juuti, Anton Laakso, Eemeli Holopainen, Douglas R. Worsnop, Annele Virtanen, and Harri Kokkola
Atmos. Chem. Phys., 24, 8489–8506, https://doi.org/10.5194/acp-24-8489-2024, https://doi.org/10.5194/acp-24-8489-2024, 2024
Short summary
Short summary
The study examines how the volatility of semi-volatile organic compounds affects secondary organic aerosol (SOA) formation and climate. Our simulations show that uncertainties in these volatilities influence aerosol mass and climate impacts. Accurate representation of these compounds in climate models is crucial for predicting global climate patterns.
Hector Navarro-Barboza, Jordi Rovira, Vincenzo Obiso, Andrea Pozzer, Marta Via, Andres Alastuey, Xavier Querol, Noemi Perez, Marjan Savadkoohi, Gang Chen, Jesus Yus-Díez, Matic Ivancic, Martin Rigler, Konstantinos Eleftheriadis, Stergios Vratolis, Olga Zografou, Maria Gini, Benjamin Chazeau, Nicolas Marchand, Andre Prevot, Kaspar Dallenbach, Mikael Ehn, Krista Luoma, Tuukka Petäjä, Anna Tobler, Jaroslaw Necki, Minna Aurela, Hilkka Timonen, Jarkko Niemi, Olivier Favez, Jean-Eudes Petit, Jean-Philippe Putaud, Christoph Hueglin, Nicolas Pascal, Aurelien Chauvigné, Sebastien Conil, Marco Pandolfi, and Oriol Jorba
EGUsphere, https://doi.org/10.5194/egusphere-2024-2086, https://doi.org/10.5194/egusphere-2024-2086, 2024
Short summary
Short summary
Brown carbon (BrC) absorbs UV and visible light, affecting climate. Our study investigates BrC's imaginary refractive index (k ) using data from 12 European sites. Residential emissions are a major OA source in winter, while secondary organic aerosols (SOA) dominate in summer. We derived source-specific k values, enhancing model accuracy. This research improves understanding of BrC's climate role, emphasizing the need for source-specific constraints in atmospheric models.
Ruth A. R. Digby, Knut von Salzen, Adam H. Monahan, Nathan P. Gillett, and Jiangnan Li
EGUsphere, https://doi.org/10.5194/egusphere-2024-1796, https://doi.org/10.5194/egusphere-2024-1796, 2024
Short summary
Short summary
The refractive index of black carbon (BCRI), which determines how much energy black carbon absorbs and scatters, is difficult to measure and different climate models use different values. We show that varying the BCRI across commonly used values can increase absorbing aerosol optical depth by 42 % and the warming effect from interactions between black carbon and radiation by 47 %, an appreciable fraction of the overall spread between models reported in recent literature assessments.
Alkiviadis Kalisoras, Aristeidis K. Georgoulias, Dimitris Akritidis, Robert J. Allen, Vaishali Naik, Chaincy Kuo, Sophie Szopa, Pierre Nabat, Dirk Olivié, Twan van Noije, Philippe Le Sager, David Neubauer, Naga Oshima, Jane Mulcahy, Larry W. Horowitz, and Prodromos Zanis
Atmos. Chem. Phys., 24, 7837–7872, https://doi.org/10.5194/acp-24-7837-2024, https://doi.org/10.5194/acp-24-7837-2024, 2024
Short summary
Short summary
Effective radiative forcing (ERF) is a metric for estimating how human activities and natural agents change the energy flow into and out of the Earth’s climate system. We investigate the anthropogenic aerosol ERF, and we estimate the contribution of individual processes to the total ERF using simulations from Earth system models within the Coupled Model Intercomparison Project Phase 6 (CMIP6). Our findings highlight that aerosol–cloud interactions drive ERF variability during the last 150 years.
Qianqian Song, Paul Ginoux, María Gonçalves Ageitos, Ron L. Miller, Vincenzo Obiso, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 24, 7421–7446, https://doi.org/10.5194/acp-24-7421-2024, https://doi.org/10.5194/acp-24-7421-2024, 2024
Short summary
Short summary
We implement and simulate the distribution of eight dust minerals in the GFDL AM4.0 model. We found that resolving the eight minerals reduces dust absorption compared to the homogeneous dust used in the standard GFDL AM4.0 model that assumes a globally uniform hematite content of 2.7 % by volume. Resolving dust mineralogy results in significant impacts on radiation, land surface temperature, surface winds, and precipitation over North Africa in summer.
Senyi Kong, Zheng Wang, and Lei Bi
Atmos. Chem. Phys., 24, 6911–6935, https://doi.org/10.5194/acp-24-6911-2024, https://doi.org/10.5194/acp-24-6911-2024, 2024
Short summary
Short summary
The retrieval of refractive indices of dust aerosols from laboratory optical measurements is commonly done assuming spherical particles. This paper aims to investigate the uncertainties in the shortwave refractive indices and corresponding optical properties by considering non-spherical and inhomogeneous models for dust samples. The study emphasizes the significance of using non-spherical models for simulating dust aerosols.
Wenxuan Hua, Sijia Lou, Xin Huang, Lian Xue, Ke Ding, Zilin Wang, and Aijun Ding
Atmos. Chem. Phys., 24, 6787–6807, https://doi.org/10.5194/acp-24-6787-2024, https://doi.org/10.5194/acp-24-6787-2024, 2024
Short summary
Short summary
In this study, we diagnose uncertainties in carbon monoxide and organic carbon emissions from four inventories for seven major wildfire-prone regions. Uncertainties in vegetation classification methods, fire detection products, and cloud obscuration effects lead to bias in these biomass burning (BB) emission inventories. By comparing simulations with measurements, we provide certain inventory recommendations. Our study has implications for reducing uncertainties in emissions in further studies.
Chandrakala Bharali, Mary Barth, Rajesh Kumar, Sachin D. Ghude, Vinayak Sinha, and Baerbel Sinha
Atmos. Chem. Phys., 24, 6635–6662, https://doi.org/10.5194/acp-24-6635-2024, https://doi.org/10.5194/acp-24-6635-2024, 2024
Short summary
Short summary
This study examines the role of atmospheric aerosols in winter fog over the Indo-Gangetic Plains of India using WRF-Chem. The increase in RH with aerosol–radiation feedback (ARF) is found to be important for fog formation as it promotes the growth of aerosols in the polluted environment. Aqueous-phase chemistry in the fog increases PM2.5 concentration, further affecting ARF. ARF and aqueous-phase chemistry affect the fog intensity and the timing of fog formation by ~1–2 h.
Wenxin Zhao, Yu Zhao, Yu Zheng, Dong Chen, Jinyuan Xin, Kaitao Li, Huizheng Che, Zhengqiang Li, Mingrui Ma, and Yun Hang
Atmos. Chem. Phys., 24, 6593–6612, https://doi.org/10.5194/acp-24-6593-2024, https://doi.org/10.5194/acp-24-6593-2024, 2024
Short summary
Short summary
We evaluate the long-term (2000–2020) variabilities of aerosol absorption optical depth, black carbon emissions, and associated health risks in China with an integrated framework that combines multiple observations and modeling techniques. We demonstrate the remarkable emission abatement resulting from the implementation of national pollution controls and show how human activities affected the emissions with a spatiotemporal heterogeneity, thus supporting differentiated policy-making by region.
Peng Xian, Jeffrey S. Reid, Melanie Ades, Angela Benedetti, Peter R. Colarco, Arlindo da Silva, Tom F. Eck, Johannes Flemming, Edward J. Hyer, Zak Kipling, Samuel Rémy, Tsuyoshi Thomas Sekiyama, Taichu Tanaka, Keiya Yumimoto, and Jianglong Zhang
Atmos. Chem. Phys., 24, 6385–6411, https://doi.org/10.5194/acp-24-6385-2024, https://doi.org/10.5194/acp-24-6385-2024, 2024
Short summary
Short summary
The study compares and evaluates monthly AOD of four reanalyses (RA) and their consensus (i.e., ensemble mean). The basic verification characteristics of these RA versus both AERONET and MODIS retrievals are presented. The study discusses the strength of each RA and identifies regions where divergence and challenges are prominent. The RA consensus usually performs very well on a global scale in terms of how well it matches the observational data, making it a good choice for various applications.
Roger Teoh, Zebediah Engberg, Ulrich Schumann, Christiane Voigt, Marc Shapiro, Susanne Rohs, and Marc E. J. Stettler
Atmos. Chem. Phys., 24, 6071–6093, https://doi.org/10.5194/acp-24-6071-2024, https://doi.org/10.5194/acp-24-6071-2024, 2024
Short summary
Short summary
The radiative forcing (RF) due to aviation contrails is comparable to that caused by CO2. We estimate that global contrail net RF in 2019 was 62.1 mW m−2. This is ~1/2 the previous best estimate for 2018. Contrail RF varies regionally due to differences in conditions required for persistent contrails. COVID-19 reduced contrail RF by 54% in 2020 relative to 2019. Globally, 2 % of all flights account for 80 % of the annual contrail energy forcing, suggesting a opportunity to mitigate contrail RF.
Haotian Zu, Biwu Chu, Yiqun Lu, Ling Liu, and Xiuhui Zhang
Atmos. Chem. Phys., 24, 5823–5835, https://doi.org/10.5194/acp-24-5823-2024, https://doi.org/10.5194/acp-24-5823-2024, 2024
Short summary
Short summary
The nucleation of iodic acid (HIO3) and iodous acid (HIO2) was proven to be critical in marine areas. However, HIO3–HIO2 nucleation cannot effectively derive the rapid nucleation in some polluted coasts. We find a significant enhancement of dimethylamine (DMA) on the HIO3–HIO2 nucleation in marine and polar regions with abundant DMA sources, which may establish reasonable connections between the HIO3–HIO2 nucleation and the rapid formation of new particles in polluted marine and polar regions.
Junghwa Lee, Patric Seifert, Tempei Hashino, Maximilian Maahn, Fabian Senf, and Oswald Knoth
Atmos. Chem. Phys., 24, 5737–5756, https://doi.org/10.5194/acp-24-5737-2024, https://doi.org/10.5194/acp-24-5737-2024, 2024
Short summary
Short summary
Spectral bin model simulations of an idealized supercooled stratiform cloud were performed with the AMPS model for variable CCN and INP concentrations. We performed radar forward simulations with PAMTRA to transfer the simulations into radar observational space. The derived radar reflectivity factors were compared to observational studies of stratiform mixed-phase clouds. These studies report a similar response of the radar reflectivity factor to aerosol perturbations as we found in our study.
Basudev Swain, Marco Vountas, Aishwarya Singh, Nidhi L. Anchan, Adrien Deroubaix, Luca Lelli, Yanick Ziegler, Sachin S. Gunthe, Hartmut Bösch, and John P. Burrows
Atmos. Chem. Phys., 24, 5671–5693, https://doi.org/10.5194/acp-24-5671-2024, https://doi.org/10.5194/acp-24-5671-2024, 2024
Short summary
Short summary
Arctic amplification (AA) accelerates the warming of the central Arctic cryosphere and affects aerosol dynamics. Limited observations hinder a comprehensive analysis. This study uses AEROSNOW aerosol optical density (AOD) data and GEOS-Chem simulations to assess AOD variability. Discrepancies highlight the need for improved observational integration into models to refine our understanding of aerosol effects on cloud microphysics, ice nucleation, and radiative forcing under evolving AA.
Vincenzo Obiso, María Gonçalves Ageitos, Carlos Pérez García-Pando, Jan P. Perlwitz, Gregory L. Schuster, Susanne E. Bauer, Claudia Di Biagio, Paola Formenti, Kostas Tsigaridis, and Ron L. Miller
Atmos. Chem. Phys., 24, 5337–5367, https://doi.org/10.5194/acp-24-5337-2024, https://doi.org/10.5194/acp-24-5337-2024, 2024
Short summary
Short summary
We calculate the dust direct radiative effect (DRE) in an Earth system model accounting for regionally varying soil mineralogy through a new observationally constrained method. Linking dust absorption at solar wavelengths to the varying amount of specific minerals (i.e., iron oxides) improves the modeled range of dust single scattering albedo compared to observations and increases the global cooling by dust. Our results may contribute to improved estimates of the dust DRE and its climate impact.
Charlotte M. Beall, Po-Lun Ma, Matthew W. Christensen, Johannes Mülmenstädt, Adam Varble, Kentaroh Suzuki, and Takuro Michibata
Atmos. Chem. Phys., 24, 5287–5302, https://doi.org/10.5194/acp-24-5287-2024, https://doi.org/10.5194/acp-24-5287-2024, 2024
Short summary
Short summary
Single-layer warm liquid clouds cover nearly one-third of the Earth's surface, and uncertainties regarding the impact of aerosols on their radiative properties pose a significant challenge to climate prediction. Here, we demonstrate how satellite observations can be used to constrain Earth system model estimates of the radiative forcing from the interactions of aerosols with clouds due to warm rain processes.
Xiaoli Wei, Qian Cui, Leiming Ma, Feng Zhang, Wenwen Li, and Peng Liu
Atmos. Chem. Phys., 24, 5025–5045, https://doi.org/10.5194/acp-24-5025-2024, https://doi.org/10.5194/acp-24-5025-2024, 2024
Short summary
Short summary
A new aerosol-type classification algorithm has been proposed. It includes an optical database built by Mie scattering and a complex refractive index working as a baseline to identify different aerosol types. The new algorithm shows high accuracy and efficiency. Hence, a global map of aerosol types was generated to characterize aerosol types across the five continents. It will help improve the accuracy of aerosol inversion and determine the sources of aerosol pollution.
Cited articles
Ayers, G. P., Gillett, R. W., and Gras, J. L.: On the vapor pressure of
sulfuric acid, Geophys. Res. Lett., 7, 433–436,
https://doi.org/10.1029/GL007i006p00433, 1980. a
Ben-Naim, A.: Solvation Thermodynamics, Plenum Press, New York and London,
1987. a
Bondy, A. L., Bonanno, D., Moffet, R. C., Wang, B., Laskin, A., and Ault,
A. P.: The diverse chemical mixing state of aerosol particles in the
southeastern United States, Atmos. Chem. Phys., 18, 12595–12612,
https://doi.org/10.5194/acp-18-12595-2018, 2018. a
Budisulistiorini, S. H., Li, X., Bairai, S. T., Renfro, J., Liu, Y., Liu, Y.,
McKinney, K. A., Martin, S. T., McNeill, V. F., Pye, H. O. T., Nenes, A.,
Neff, M. E., Stone, E. A., Mueller, S., Knote, C., Shaw, S. L., Zhang, Z.,
Gold, A., and Surratt, J. D.: Examining the effects of anthropogenic
emissions on isoprene-derived secondary organic aerosol formation during the
2013 Southern Oxidant and Aerosol Study (SOAS) at the Look Rock, Tennessee
ground site, Atmos. Chem. Phys., 15, 8871–8888,
https://doi.org/10.5194/acp-15-8871-2015, 2015. a
Chan, M. N., Surratt, J. D., Chan, A. W. H., Schilling, K., Offenberg, J. H.,
Lewandowski, M., Edney, E. O., Kleindienst, T. E., Jaoui, M., Edgerton,
E. S., Tanner, R. L., Shaw, S. L., Zheng, M., Knipping, E. M., and Seinfeld,
J. H.: Influence of aerosol acidity on the chemical composition of secondary
organic aerosol from β-caryophyllene, Atmos. Chem. Phys., 11,
1735–1751, https://doi.org/10.5194/acp-11-1735-2011, 2011. a
Clayden, J., Greeves, N., Warren, S., and Wothers, P.: Organic Chemistry,
Oxford University Press, New York, USA, 2001. a
COSMObase: version 17.01, COSMOlogic GmbH & Co. KG.,
Leverkusen, Germany, 2011. a
COSMOconf: version 4.3, COSMOlogic GmbH & Co. KG.,
Leverkusen, Germany, 2013. a
COSMOtherm: version C3.0, Release 18, COSMOlogic GmbH & Co.
KG., Leverkusen, Germany, 2018. a
COSMOtherm: version C3.0, Release 19, COSMOlogic GmbH & Co.
KG., Leverkusen, Germany, 2019. a
D'Ambro, E. L., Schobesberger, S., Gaston, C. J., Lopez-Hilfiker, F. D., Lee,
B. H., Liu, J., Zelenyuk, A., Bell, D., Cappa, C. D., Helgestad, T., Li, Z.,
Guenther, A., Wang, J., Wise, M., Caylor, R., Surratt, J. D., Riedel, T.,
Hyttinen, N., Salo, V.-T., Hasan, G., Kurtén, T., Shilling, J. E., and
Thornton, J. A.: Chamber-based insights into the factors controlling
epoxydiol (IEPOX) secondary organic aerosol (SOA) yield, composition, and
volatility, Atmos. Chem. Phys., 19, 11253–11265,
https://doi.org/10.5194/acp-19-11253-2019, 2019. a
Darer, A. I., Cole-Filipiak, N. C., O'Connor, A. E., and Elrod, M. J.:
Formation and stability of atmospherically relevant isoprene-derived
organosulfates and organonitrates, Environ. Sci. Technol., 45, 1895–1902,
https://doi.org/10.1021/es103797z, 2011. a, b, c
Eckert, F. and Klamt, A.: Fast solvent screening via quantum chemistry:
COSMO-RS approach, AIChE J., 48, 369–385, https://doi.org/10.1002/aic.690480220, 2002. a
Estillore, A. D., Hettiyadura, A. P. S., Qin, Z., Leckrone, E., Wombacher, B.,
Humphry, T., Stone, E. A., and Grassian, V. H.: Water uptake and hygroscopic
growth of organosulfate aerosol, Environ. Sci. Technol., 50, 4259–4268,
https://doi.org/10.1021/acs.est.5b05014, 2016. a, b
Glasius, M., Bering, M. S., Yee, L. D., de Sá, S. S., Isaacman-VanWertz,
G., Wernis, R. A., Barbosa, H. M. J., Alexander, M. L., Palm, B. B., Hu, W.,
Campuzano-Jost, P., Day, D. A., Jimenez, J. L., Shrivastava, M., Martin,
S. T., and Goldstein, A. H.: Organosulfates in aerosols downwind of an urban
region in central Amazon, Environ. Sci.: Process. Impacts, 20, 1546–1558,
https://doi.org/10.1039/C8EM00413G, 2018a. a, b
Glasius, M., Hansen, A. M. K., Claeys, M., Henzing, J. S., Jedynska, A. D.,
Kasper-Giebl, A., Kistler, M., Kristensen, K., Martinsson, J., Maenhaut, W.,
Nøjgaard, J., Spindler, G., Stenström, K. E., Swietlicki, E., Szidat,
S., Simpson, D., and Yttri, K. E.: Composition and sources of carbonaceous
aerosols in Northern Europe during winter, Atmos. Environ., 173, 127–141,
https://doi.org/10.1016/j.atmosenv.2017.11.005, 2018b. a
Halgren, T. A.: Merck molecular force field. I. Basis, form, scope,
parameterization, and performance of MMFF94, J. Comp. Chem., 17, 490–519,
https://doi.org/10.1002/(SICI)1096-987X(199604)17:5/6<490::AID-JCC1>3.0.CO;2-P, 1996. a
Ham, S., Babar, Z. B., Lee, J. B., Lim, H.-J., and Song, M.: Liquid–liquid
phase separation in secondary organic aerosol particles produced from α-pinene ozonolysis and α-pinene photooxidation with/without ammonia,
Atmos. Chem. Phys., 19, 9321–9331, https://doi.org/10.5194/acp-19-9321-2019, 2019. a, b, c
Hansen, A. M. K., Hong, J., Raatikainen, T., Kristensen, K., Ylisirniö, A.,
Virtanen, A., Petäjä, T., Glasius, M., and Prisle, N. L.: Hygroscopic
properties and cloud condensation nuclei activation of limonene-derived
organosulfates and their mixtures with ammonium sulfate, Atmos. Chem. Phys.,
15, 14071–14089, https://doi.org/10.5194/acp-15-14071-2015, 2015. a, b, c, d, e, f, g
Hettiyadura, A. P. S., Jayarathne, T., Baumann, K., Goldstein, A. H., de Gouw,
J. A., Koss, A., Keutsch, F. N., Skog, K., and Stone, E. A.: Qualitative and
quantitative analysis of atmospheric organosulfates in Centreville, Alabama,
Atmos. Chem. Phys., 17, 1343–1359, https://doi.org/10.5194/acp-17-1343-2017, 2017. a
Hettiyadura, A. P. S., Al-Naiema, I. M., Hughes, D. D., Fang, T., and Stone,
E. A.: Organosulfates in Atlanta, Georgia: anthropogenic influences on
biogenic secondary organic aerosol formation, Atmos. Chem. Phys., 19,
3191–3206, https://doi.org/10.5194/acp-19-3191-2019, 2019. a, b
Huang, R.-J., Cao, J., Chen, Y., Yang, L., Shen, J., You, Q., Wang, K., Lin,
C., Xu, W., Gao, B., Li, Y., Chen, Q., Hoffmann, T., O'Dowd, C. D., Bilde,
M., and Glasius, M.: Organosulfates in atmospheric aerosol: synthesis and
quantitative analysis of PM2.5 from Xi'an, northwestern China, Atmos.
Phys. Chem., 11, 3447–3456, https://doi.org/10.5194/amt-11-3447-2018, 2018. a
Hyttinen, N., Elm, J., Malila, J., Calderón, S. M., and Prisle, N. L.:
Supplementary data for the manuscript “Thermodynamic properties of isoprene
and monoterpene derived organosulfates estimated with COSMOtherm”
[Dataset], Zenodo, https://doi.org/10.5281/zenodo.3552309, 2019. a
Iinuma, Y., Böge, O., Kahnt, A., and Herrmann, H.: Laboratory chamber
studies on the formation of organosulfates from reactive uptake of
monoterpene oxides, Phys. Chem. Chem. Phys., 11, 7985–7997,
https://doi.org/10.1039/B904025K, 2009. a, b, c
Klamt, A.: Conductor-like screening model for real solvents: a new approach to
the quantitative calculation of solvation phenomena, J. Phys. Chem., 99,
2224–2235, https://doi.org/10.1021/j100007a062, 1995. a
Klamt, A., Jonas, V., Bürger, T., and Lohrenz, J. C. W.: Refinement and
parametrization of COSMO-RS, J. Phys. Chem. A, 102, 5074–5085,
https://doi.org/10.1021/jp980017s, 1998. a
Klamt, A., Eckert, F., Reinisch, J., and Wichmann, K.: Prediction of
cyclohexane-water distribution coefficients with COSMO-RS on the SAMPL5 data
set, J. Comput.-Aided Mol. Des., 30, 959–967,
https://doi.org/10.1007/s10822-016-9927-y, 2016. a
Kulmala, M. and Laaksonen, A.: Binary nucleation of water–sulfuric acid
system: Comparison of classical theories with different H2SO4
saturation vapor pressures, J. Chem. Phys., 93, 696–701,
https://doi.org/10.1063/1.459519, 1990. a
Kurtén, T., Tiusanen, K., Roldin, P., Rissanen, M., Luy, J.-N., Boy, M.,
Ehn, M., and Donahue, N.: α-Pinene Autoxidation Products May Not Have
Extremely Low Saturation Vapor Pressures Despite High O:C Ratios, J. Phys.
Chem. A, 120, 2569–2582, https://doi.org/10.1021/acs.jpca.6b02196, 2016. a, b, c, d
Le Breton, M., Wang, Y., Hallquist, Å. M., Pathak, R. K., Zheng, J., Yang,
Y., Shang, D., Glasius, M., Bannan, T. J., Liu, Q., Chan, C. K., Percival,
C. J., Zhu, W., Lou, S., Topping, D., Wang, Y., Yu, J., Lu, K., Guo, S., Hu,
M., and Hallquist, M.: Online gas- and particle-phase measurements of
organosulfates, organosulfonates and nitrooxy organosulfates in Beijing
utilizing a FIGAERO ToF-CIMS, Atmos. Phys. Chem., 10, 10355–10371,
https://doi.org/10.5194/acp-18-10355-2018, 2018. a, b
Liggio, J. and Li, S.-M.: Organosulfate formation during the uptake of
pinonaldehyde on acidic sulfate aerosols, Geophys. Res. Lett., 33, L13808,
https://doi.org/10.1029/2006GL026079, 2006. a
Minerath, E. C. and Elrod, M. J.: Assessing the potential for diol and hydroxy
sulfate ester formation from the reaction of epoxides in tropospheric
aerosols, Environ. Sci. Technol., 43, 1386–1392, https://doi.org/10.1021/es8029076,
2009. a
Nguyen, Q., Christensen, M. K., Cozzi, F., Zare, A., Hansen, A. M. K.,
Kristensen, K., Tulinius, T. E., Madsen, H. H., Christensen, J. H., Brandt,
J., Massling, A., Nøjgaard, J. K., and Glasius, M.: Understanding the
anthropogenic influence on formation of biogenic secondary organic aerosols
in Denmark via analysis of organosulfates and related oxidation products,
Atmos. Chem. Phys., 14, 8961–8981, https://doi.org/10.5194/acp-14-8961-2014,
2014a. a
Nguyen, Q. T., Kristensen, T. B., Hansen, A. M. K., Skov, H., Bossi, R.,
Massling, A., Sørensen, L. L., Bilde, M., Glasius, M., and Nøjgaard,
J. K.: Characterization of humic-like substances in Arctic aerosols, J.
Geophys. Res.-Atmos., 119, 5011–5027, https://doi.org/10.1002/2013JD020144,
2014b. a
Noppel, M., Vehkamäki, H., and Kulmala, M.: An improved model for hydrate
formation in sulfuric acid–water nucleation, J. Chem. Phys., 116, 218–228,
https://doi.org/10.1063/1.1423333, 2002. a
Prigogine, I. and Defay, R.: Chemical Thermodynamics, Longmans Green, London,
1st edn., 1954. a
Prisle, N. L., Engelhart, G. J., Bilde, M., and Donahue, N. M.: Humidity
influence on gas-particle phase partitioning of α-pinene + O3
secondary organic aerosol, Geophys. Res. Lett., 37, L01802,
https://doi.org/10.1029/2009GL041402, 2010. a
Rastak, N., Pajunoja, A., Acosta Navarro, J. C., Ma, J., Song, M., Partridge,
D. G., Kirkevåg, A., Leong, Y., Hu, W., Taylor, N. F., Lambe, A.,
Cerully, K., Bougiatioti, A., Liu, P., Krejci, R., Petäjä, T.,
Percival, C., Davidovits, P., Worsnop, D. R., Ekman, A. M. L., Nenes, A.,
Martin, S., Jimenez, J. L., Collins, D. R., Topping, D. O., Bertram, A. K.,
Zuend, A., Virtanen, A., and Riipinen, I.: Microphysical explanation of the
RH-dependent water affinity of biogenic organic aerosol and its importance
for climate, Geophys. Res. Lett., 44, 5167–5177, https://doi.org/10.1002/2017GL073056,
2017. a, b
Schindelka, J., Iinuma, Y., Hoffmann, D., and Herrmann, H.: Sulfate
radical-initiated formation of isoprene-derived organosulfates in atmospheric
aerosols, Faraday Discuss., 165, 237–259, https://doi.org/10.1039/C3FD00042G, 2013. a
Schröder, B., Fulem, M., and Martins, M. A. R.: Vapor pressure predictions
of multi-functional oxygen-containing organic compounds with COSMO-RS, Atmos.
Environ., 133, 135–144, https://doi.org/10.1016/j.atmosenv.2016.03.036, 2016. a
Shinoda, K., Hiruta, S., and Amaya, K.: The heat of solution and of wetting of
ionic surfactants close to the Krafft points, J. Colloid Interface Sci., 21,
102–106, https://doi.org/10.1016/0095-8522(66)90085-7, 1966. a, b
Song, M., Marcolli, C., Krieger, U. K., Zuend, A., and Peter, T.:
Liquid–liquid phase separation in aerosol particles: Dependence on O:C,
organic functionalities, and compositional complexity, Geophys. Res. Lett.,
39, L19801, https://doi.org/10.1029/2012GL052807, 2012. a, b, c
Song, M., Ham, S., Andrews, R. J., You, Y., and Bertram, A. K.: Liquid–liquid
phase separation in organic particles containing one and two organic species:
importance of the average O : C, Atmos. Chem. Phys., 18, 12075–12084,
https://doi.org/10.5194/acp-18-12075-2018, 2018. a, b, c
Surratt, J. D., Kroll, J. H., Kleindienst, T. E., Edney, E. O., Claeys, M.,
Sorooshian, A., Ng, N. L., Offenberg, J. H., Lewandowski, M., Jaoui, M.,
Flagan, R. C., and Seinfeld, J. H.: Evidence for organosulfates in secondary
organic aerosol, Environ. Sci. Technol., 41, 517–527,
https://doi.org/10.1021/es062081q, 2007. a, b, c, d
Surratt, J. D., Gómez-González, Y., Chan, A. W., Vermeylen, R.,
Shahgholi, M., Kleindienst, T. E., Edney, E. O., Offenberg, J. H.,
Lewandowski, M., Jaoui, M., Maenhaut, W., Claeys, M., Flagan, R. C., and
Seinfeld, J. H.: Organosulfate formation in biogenic secondary organic
aerosol, J. Phys. Chem. A, 112, 8345–8378, https://doi.org/10.1021/jp802310p, 2008. a, b, c
Surratt, J. D., Chan, A. W., Eddingsaas, N. C., Chan, M., Loza, C. L., Kwan,
A. J., Hersey, S. P., Flagan, R. C., Wennberg, P. O., and Seinfeld, J. H.:
Reactive intermediates revealed in secondary organic aerosol formation from
isoprene, P. Natl. Acad. Sci. USA, 107, 6640–6645,
https://doi.org/10.1073/pnas.0911114107, 2010. a, b
Tang, I. N. and Munkelwitz, H. R.: Water activities, densities, and refractive
indices of aqueous sulfates and sodium nitrate droplets of atmospheric
importance, J. Geophys. Res.-Atmos., 99, 18801–18808,
https://doi.org/10.1029/94JD01345, 1994. a, b, c, d
Toivola, M., Prisle, N. L., Elm, J., Waxman, E. M., Volkamer, R., and
Kurtén, T.: Can COSMOTherm Predict a Salting in Effect?, J. Phys. Chem.
A, 121, 6288–6295, https://doi.org/10.1021/acs.jpca.7b04847, 2017. a
Toure, O., Audonnet, F., Lebert, A., and Dussap, C.-G.: COSMO-RS-PDHS: a new
predictive model for aqueous electrolytes solutions, Chem. Eng. Res. Des.,
92, 2873–2883, https://doi.org/10.1016/j.cherd.2014.06.020, 2014. a, b
TURBOMOLE: Version 7.11, a development of University of Karlsruhe and
Forschungszentrum Karlsruhe GmbH, TURBOMOLE GmbH, 2010. a
Wach, P., Spólnik, G., Rudziński, K. J., Skotak, K., Claeys, M.,
Danikiewicz, W., and Szmigielski, R.: Radical oxidation of methyl vinyl
ketone and methacrolein in aqueous droplets: Characterization of
organosulfates and atmospheric implications, Chemosphere, 214, 1–9,
https://doi.org/10.1016/j.chemosphere.2018.09.026, 2019. a
Wang, C., Lei, Y. D., Endo, S., and Wania, F.: Measuring and modeling the
salting-out effect in ammonium sulfate solutions, Environ. Sci. Technol., 48,
13238–13245, https://doi.org/10.1021/es5035602, 2014. a, b, c, d
Wang, C., Lei, Y. D., and Wania, F.: Effect of Sodium Sulfate, Ammonium
Chloride, Ammonium Nitrate, and Salt Mixtures on Aqueous Phase Partitioning
of Organic Compounds, Environ. Sci. Technol., 50, 12742–12749,
https://doi.org/10.1021/acs.est.6b03525, 2016. a
Wavefunction Inc.: Spartan'14, Irvine, CA, 2014. a
Woods III, E., Kim, H. S., Wivagg, C. N., Dotson, S. J., Broekhuizen, K. E.,
and Frohardt, E. F.: Phase transitions and surface morphology of
surfactant-coated aerosol particles, J. Phys. Chem. A, 111, 11013–11020,
https://doi.org/10.1021/jp074848m, 2007. a
Wu, F.-M., Wang, X.-W., Jing, B., Zhang, Y.-H., and Ge, M.-F.: Liquid–liquid
phase separation in internally mixed magnesium sulfate/glutaric acid
particles, Atmos. Environ., 178, 286–292,
https://doi.org/10.1016/j.atmosenv.2018.02.012, 2018. a
Xu, L., Guo, H., Boyd, C. M., Klein, M., Bougiatioti, A., Cerully, K. M., Hite,
J. R., Isaacman-VanWertz, G., Kreisberg, N. M., Knote, C., Olson, K., Koss,
A., Goldstein, A. H., Hering, S. V., de Gouw, J., Baumann, K., Lee, S.-H.,
Nenes, A., Weber, R. J., and Ng, N. L.: Effects of anthropogenic emissions on
aerosol formation from isoprene and monoterpenes in the southeastern United
States, P. Natl. Acad. Sci. USA, 112, 37–42, https://doi.org/10.1073/pnas.1417609112,
2015.
a
Zhang, Y., Chen, Y., Lambe, A. T., Olson, N. E., Lei, Z., Craig, R. L., Zhang,
Z., Gold, A., Onasch, T. B., Jayne, J. T., Worsnop, D. R., Gaston, C. J.,
Thornton, J. A., Vizuete, W., Ault, A. P., and Surratt, J. D.: Effect of the
aerosol-phase state on secondary organic aerosol formation from the reactive
uptake of isoprene-derived epoxydiols (IEPOX), Environ. Sci. Technol. Lett.,
5, 167–174, https://doi.org/10.1021/acs.estlett.8b00044, 2018. a
Short summary
Organosulfates have been identified in atmospheric secondary organic aerosol (SOA). The thermodynamic properties of SOA constituents, such as organosulfates, affect the stability and atmospheric impact of the SOA. Here we present estimated solubility, activity, pKa, saturation vapor pressure and Henry's law solubility values for several atmospherically relevant monoterpene- and isoprene-derived organosulfate compounds. These properties can be used, for example, in aerosol process modeling.
Organosulfates have been identified in atmospheric secondary organic aerosol (SOA). The...
Altmetrics
Final-revised paper
Preprint