Articles | Volume 20, issue 9
https://doi.org/10.5194/acp-20-5679-2020
https://doi.org/10.5194/acp-20-5679-2020
Research article
 | 
13 May 2020
Research article |  | 13 May 2020

Thermodynamic properties of isoprene- and monoterpene-derived organosulfates estimated with COSMOtherm

Noora Hyttinen, Jonas Elm, Jussi Malila, Silvia M. Calderón, and Nønne L. Prisle

Related authors

Predicting Hygroscopic Growth of Organosulfur Aerosol Particles Using COSMOtherm
Zijun Li, Angela Buchholz, and Noora Hyttinen
EGUsphere, https://doi.org/10.5194/egusphere-2024-1182,https://doi.org/10.5194/egusphere-2024-1182, 2024
Short summary
The effect of atmospherically relevant aminium salts on water uptake
Noora Hyttinen
Atmos. Chem. Phys., 23, 13809–13817, https://doi.org/10.5194/acp-23-13809-2023,https://doi.org/10.5194/acp-23-13809-2023, 2023
Short summary
Towards a mechanistic description of autoxidation chemistry: from precursors to atmospheric implications
Lukas Pichelstorfer, Pontus Roldin, Matti Rissanen, Noora Hyttinen, Olga Garmash, Carlton Xavier, Putian Zhou, Petri Clusius, Benjamin Foreback, Thomas Golin Almeida, Chenjuan Deng, Metin Baykara, Theo Kurten, and Michael Boy
EGUsphere, https://doi.org/10.5194/egusphere-2023-1415,https://doi.org/10.5194/egusphere-2023-1415, 2023
Preprint archived
Short summary
Saturation vapor pressure characterization of selected low-volatility organic compounds using a residence time chamber
Zijun Li, Noora Hyttinen, Miika Vainikka, Olli-Pekka Tikkasalo, Siegfried Schobesberger, and Taina Yli-Juuti
Atmos. Chem. Phys., 23, 6863–6877, https://doi.org/10.5194/acp-23-6863-2023,https://doi.org/10.5194/acp-23-6863-2023, 2023
Short summary
Comparison of saturation vapor pressures of α-pinene + O3 oxidation products derived from COSMO-RS computations and thermal desorption experiments
Noora Hyttinen, Iida Pullinen, Aki Nissinen, Siegfried Schobesberger, Annele Virtanen, and Taina Yli-Juuti
Atmos. Chem. Phys., 22, 1195–1208, https://doi.org/10.5194/acp-22-1195-2022,https://doi.org/10.5194/acp-22-1195-2022, 2022
Short summary

Related subject area

Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Decomposing the effective radiative forcing of anthropogenic aerosols based on CMIP6 Earth system models
Alkiviadis Kalisoras, Aristeidis K. Georgoulias, Dimitris Akritidis, Robert J. Allen, Vaishali Naik, Chaincy Kuo, Sophie Szopa, Pierre Nabat, Dirk Olivié, Twan van Noije, Philippe Le Sager, David Neubauer, Naga Oshima, Jane Mulcahy, Larry W. Horowitz, and Prodromos Zanis
Atmos. Chem. Phys., 24, 7837–7872, https://doi.org/10.5194/acp-24-7837-2024,https://doi.org/10.5194/acp-24-7837-2024, 2024
Short summary
Modeling impacts of dust mineralogy on fast climate response
Qianqian Song, Paul Ginoux, María Gonçalves Ageitos, Ron L. Miller, Vincenzo Obiso, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 24, 7421–7446, https://doi.org/10.5194/acp-24-7421-2024,https://doi.org/10.5194/acp-24-7421-2024, 2024
Short summary
Uncertainties in laboratory-measured shortwave refractive indices of mineral dust aerosols and derived optical properties: a theoretical assessment
Senyi Kong, Zheng Wang, and Lei Bi
Atmos. Chem. Phys., 24, 6911–6935, https://doi.org/10.5194/acp-24-6911-2024,https://doi.org/10.5194/acp-24-6911-2024, 2024
Short summary
Diagnosing uncertainties in global biomass burning emission inventories and their impact on modeled air pollutants
Wenxuan Hua, Sijia Lou, Xin Huang, Lian Xue, Ke Ding, Zilin Wang, and Aijun Ding
Atmos. Chem. Phys., 24, 6787–6807, https://doi.org/10.5194/acp-24-6787-2024,https://doi.org/10.5194/acp-24-6787-2024, 2024
Short summary
Role of atmospheric aerosols in severe winter fog over the Indo-Gangetic Plain of India: a case study
Chandrakala Bharali, Mary Barth, Rajesh Kumar, Sachin D. Ghude, Vinayak Sinha, and Baerbel Sinha
Atmos. Chem. Phys., 24, 6635–6662, https://doi.org/10.5194/acp-24-6635-2024,https://doi.org/10.5194/acp-24-6635-2024, 2024
Short summary

Cited articles

Ayers, G. P., Gillett, R. W., and Gras, J. L.: On the vapor pressure of sulfuric acid, Geophys. Res. Lett., 7, 433–436, https://doi.org/10.1029/GL007i006p00433, 1980. a
Ben-Naim, A.: Solvation Thermodynamics, Plenum Press, New York and London, 1987. a
Bondy, A. L., Bonanno, D., Moffet, R. C., Wang, B., Laskin, A., and Ault, A. P.: The diverse chemical mixing state of aerosol particles in the southeastern United States, Atmos. Chem. Phys., 18, 12595–12612, https://doi.org/10.5194/acp-18-12595-2018, 2018. a
Budisulistiorini, S. H., Li, X., Bairai, S. T., Renfro, J., Liu, Y., Liu, Y., McKinney, K. A., Martin, S. T., McNeill, V. F., Pye, H. O. T., Nenes, A., Neff, M. E., Stone, E. A., Mueller, S., Knote, C., Shaw, S. L., Zhang, Z., Gold, A., and Surratt, J. D.: Examining the effects of anthropogenic emissions on isoprene-derived secondary organic aerosol formation during the 2013 Southern Oxidant and Aerosol Study (SOAS) at the Look Rock, Tennessee ground site, Atmos. Chem. Phys., 15, 8871–8888, https://doi.org/10.5194/acp-15-8871-2015, 2015. a
Chan, M. N., Surratt, J. D., Chan, A. W. H., Schilling, K., Offenberg, J. H., Lewandowski, M., Edney, E. O., Kleindienst, T. E., Jaoui, M., Edgerton, E. S., Tanner, R. L., Shaw, S. L., Zheng, M., Knipping, E. M., and Seinfeld, J. H.: Influence of aerosol acidity on the chemical composition of secondary organic aerosol from β-caryophyllene, Atmos. Chem. Phys., 11, 1735–1751, https://doi.org/10.5194/acp-11-1735-2011, 2011. a
Download
Short summary
Organosulfates have been identified in atmospheric secondary organic aerosol (SOA). The thermodynamic properties of SOA constituents, such as organosulfates, affect the stability and atmospheric impact of the SOA. Here we present estimated solubility, activity, pKa, saturation vapor pressure and Henry's law solubility values for several atmospherically relevant monoterpene- and isoprene-derived organosulfate compounds. These properties can be used, for example, in aerosol process modeling.
Altmetrics
Final-revised paper
Preprint