Articles | Volume 16, issue 12
Atmos. Chem. Phys., 16, 7969–7979, 2016
https://doi.org/10.5194/acp-16-7969-2016
Atmos. Chem. Phys., 16, 7969–7979, 2016
https://doi.org/10.5194/acp-16-7969-2016

Research article 01 Jul 2016

Research article | 01 Jul 2016

Observations and implications of liquid–liquid phase separation at high relative humidities in secondary organic material produced by α-pinene ozonolysis without inorganic salts

Lindsay Renbaum-Wolff et al.

Related authors

Measurement and modeling of the multiwavelength optical properties of uncoated flame-generated soot
Sara D. Forestieri, Taylor M. Helgestad, Andrew T. Lambe, Lindsay Renbaum-Wolff, Daniel A. Lack, Paola Massoli, Eben S. Cross, Manvendra K. Dubey, Claudio Mazzoleni, Jason S. Olfert, Arthur J. Sedlacek III, Andrew Freedman, Paul Davidovits, Timothy B. Onasch, and Christopher D. Cappa
Atmos. Chem. Phys., 18, 12141–12159, https://doi.org/10.5194/acp-18-12141-2018,https://doi.org/10.5194/acp-18-12141-2018, 2018
Short summary
Diffusion coefficients of organic molecules in sucrose–water solutions and comparison with Stokes–Einstein predictions
Yuri Chenyakin, Dagny A. Ullmann, Erin Evoy, Lindsay Renbaum-Wolff, Saeid Kamal, and Allan K. Bertram
Atmos. Chem. Phys., 17, 2423–2435, https://doi.org/10.5194/acp-17-2423-2017,https://doi.org/10.5194/acp-17-2423-2017, 2017
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds
Andreas Tilgner, Thomas Schaefer, Becky Alexander, Mary Barth, Jeffrey L. Collett Jr., Kathleen M. Fahey, Athanasios Nenes, Havala O. T. Pye, Hartmut Herrmann, and V. Faye McNeill
Atmos. Chem. Phys., 21, 13483–13536, https://doi.org/10.5194/acp-21-13483-2021,https://doi.org/10.5194/acp-21-13483-2021, 2021
Short summary
Chemical composition, optical properties, and oxidative potential of water- and methanol-soluble organic compounds emitted from the combustion of biomass materials and coal
Tao Cao, Meiju Li, Chunlin Zou, Xingjun Fan, Jianzhong Song, Wanglu Jia, Chiling Yu, Zhiqiang Yu, and Ping'an Peng
Atmos. Chem. Phys., 21, 13187–13205, https://doi.org/10.5194/acp-21-13187-2021,https://doi.org/10.5194/acp-21-13187-2021, 2021
Short summary
Photodegradation of atmospheric chromophores: changes in oxidation state and photochemical reactivity
Zhen Mu, Qingcai Chen, Lixin Zhang, Dongjie Guan, and Hao Li
Atmos. Chem. Phys., 21, 11581–11591, https://doi.org/10.5194/acp-21-11581-2021,https://doi.org/10.5194/acp-21-11581-2021, 2021
Short summary
Temperature and volatile organic compound concentrations as controlling factors for chemical composition of α-pinene-derived secondary organic aerosol
Louise N. Jensen, Manjula R. Canagaratna, Kasper Kristensen, Lauriane L. J. Quéléver, Bernadette Rosati, Ricky Teiwes, Marianne Glasius, Henrik B. Pedersen, Mikael Ehn, and Merete Bilde
Atmos. Chem. Phys., 21, 11545–11562, https://doi.org/10.5194/acp-21-11545-2021,https://doi.org/10.5194/acp-21-11545-2021, 2021
Short summary
Tracer-based source apportioning of atmospheric organic carbon and the influence of anthropogenic emissions on secondary organic aerosol formation in Hong Kong
Yubo Cheng, Yiqiu Ma, and Di Hu
Atmos. Chem. Phys., 21, 10589–10608, https://doi.org/10.5194/acp-21-10589-2021,https://doi.org/10.5194/acp-21-10589-2021, 2021
Short summary

Cited articles

Bertram, A. K., Martin, S. T., Hanna, S. J., Smith, M. L., Bodsworth, A., Chen, Q., Kuwata, M., Liu, A., You, Y., and Zorn, S. R.: Predicting the relative humidities of liquid-liquid phase separation, efflorescence, and deliquescence of mixed particles of ammonium sulfate, organic material, and water using the organic-to-sulfate mass ratio of the particle and the oxygen-to-carbon elemental ratio of the organic component, Atmos. Chem. Phys., 11, 10995–11006, https://doi.org/10.5194/acp-11-10995-2011, 2011.
Bilde, M. and Svenningsson, B.: CCN activation of slightly soluble organics: the importance of small amounts of inorganic salt and particle phase, Tellus B, 56, 128–134, https://doi.org/10.1111/j.1600-0889.2004.00090.x, 2004.
Cavalli, F., Facchini, M. C., Decesari, S., Emblico, L., Mircea, M., Jensen, N. R., and Fuzzi, S.: Size-segregated aerosol chemical composition at a boreal site in southern Finland, during the QUEST project, Atmos. Chem. Phys., 6, 993–1002, https://doi.org/10.5194/acp-6-993-2006, 2006.
Chhabra, P. S., Ng, N. L., Canagaratna, M. R., Corrigan, A. L., Russell, L. M., Worsnop, D. R., Flagan, R. C., and Seinfeld, J. H.: Elemental composition and oxidation of chamber organic aerosol, Atmos. Chem. Phys., 11, 8827–8845, https://doi.org/10.5194/acp-11-8827-2011, 2011.
Ciobanu, V. G., Marcolli, C., Krieger, U. K., Weers, U., and Peter, T.: Liquid-liquid phase separation in Mixed Organic/Inorganic Aerosol Particles, J. Phys. Chem. A, 113, 10966–10978, https://doi.org/10.1021/Jp905054d, 2009.
Download
Altmetrics
Final-revised paper
Preprint