Articles | Volume 15, issue 9
https://doi.org/10.5194/acp-15-5047-2015
https://doi.org/10.5194/acp-15-5047-2015
Research article
 | 
05 May 2015
Research article |  | 05 May 2015

Molecular characterization of free tropospheric aerosol collected at the Pico Mountain Observatory: a case study with a long-range transported biomass burning plume

K. Dzepina, C. Mazzoleni, P. Fialho, S. China, B. Zhang, R. C. Owen, D. Helmig, J. Hueber, S. Kumar, J. A. Perlinger, L. J. Kramer, M. P. Dziobak, M. T. Ampadu, S. Olsen, D. J. Wuebbles, and L. R. Mazzoleni

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Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
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Cited articles

Adachi, K. and Buseck, P. R.: Atmospheric tar balls from biomass burning in Mexico, J. Geophys. Res., 116, D05204, https://doi.org/10.1029/2010JD015102, 2011.
Altieri, K. E., Turpin, B. J., and Seitzinger, S. P.: Oligomers, organosulfates, and nitrooxy organosulfates in rainwater identified by ultra-high resolution electrospray ionization FT-ICR mass spectrometry, Atmos. Chem. Phys., 9, 2533–2542, https://doi.org/10.5194/acp-9-2533-2009, 2009a.
Altieri, K. E., Turpin, B. J., and Seitzinger, S. P.: Composition of dissolved organic nitrogen in continental precipitation investigated by ultra-high resolution FT-ICR mass spectrometry, Environ. Sci. Technol., 43, 6950–6955, 2009b.
Altieri, K. E., Hastings, M. G., Peters, A. J., and Sigman, D. M.: Molecular characterization of water soluble organic nitrogen in marine rainwater by ultra-high resolution electrospray ionization mass spectrometry, Atmos. Chem. Phys., 12, 3557–3571, https://doi.org/10.5194/acp-12-3557-2012, 2012.
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Aerosol was sampled at the Pico Mountain Observatory located at 2.2km amsl on Pico Island of the North Atlantic Azores archipelago. Two aerosol samples characterized by ultrahigh resolution mass spectrometry had biomass burning and marine emissions origins, as corroborated by collocated gas- and particle-phase measurements, air masses analyses and satellites. The paper presents the first molecular characterization of aged and processed aerosol intercepted at a remote lower free troposphere
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