Articles | Volume 24, issue 22
https://doi.org/10.5194/acp-24-12557-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-12557-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Nov 2024
Research article |
| 14 Nov 2024
| 14 Nov 2024
The impact of dehydration and extremely low HCl values in the Antarctic stratospheric vortex in mid-winter on ozone loss in spring
Yiran Zhang-Liu
CORRESPONDING AUTHOR
Institute of Climate and Energy Systems: Stratosphere (ICE-4), Forschungszentrum Jülich, Jülich, Germany
Institute of Climate and Energy Systems: Stratosphere (ICE-4), Forschungszentrum Jülich, Jülich, Germany
Centre for Advanced Simulation and Analytics (CASA), Forschungszentrum Jülich, Jüich, Germany
Jens-Uwe Grooß
Institute of Climate and Energy Systems: Stratosphere (ICE-4), Forschungszentrum Jülich, Jülich, Germany
Centre for Advanced Simulation and Analytics (CASA), Forschungszentrum Jülich, Jüich, Germany
Sabine Robrecht
Institute of Climate and Energy Systems: Stratosphere (ICE-4), Forschungszentrum Jülich, Jülich, Germany
Klima und Umwelt, Deutscher Wetterdienst, Offenbach, Germany
Bärbel Vogel
Institute of Climate and Energy Systems: Stratosphere (ICE-4), Forschungszentrum Jülich, Jülich, Germany
Centre for Advanced Simulation and Analytics (CASA), Forschungszentrum Jülich, Jüich, Germany
Abdul Mannan Zafar
Institute of Climate and Energy Systems: Stratosphere (ICE-4), Forschungszentrum Jülich, Jülich, Germany
Biotechnology Research Center, Technology Innovation Institute, Masdar City, Abu Dhabi, United Arab Emirates
Ralph Lehmann
Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research, Potsdam, Germany
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Johannes C. Laube, Tanja J. Schuck, Sophie Baartman, Huilin Chen, Markus Geldenhuys, Steven van Heuven, Timo Keber, Maria Elena Popa, Elinor Tuffnell, Florian Voet, Bärbel Vogel, Thomas Wagenhäuser, Alessandro Zanchetta, and Andreas Engel
Atmos. Meas. Tech., 18, 4087–4102, https://doi.org/10.5194/amt-18-4087-2025, https://doi.org/10.5194/amt-18-4087-2025, 2025
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A large balloon was launched in summer 2021 in the Arctic to carry instruments for trace gas measurements up to 32 km, above the reach of aircraft. The main aims were to evaluate different techniques and atmospheric processes. We focus on halogenated greenhouse gases and ozone-depleting substances. For this, air was collected with the AirCore technique and a cryogenic air sampler and measured after the flight. A companion paper reports observations of major greenhouse gases.
Rolf Müller, Lennart Bengtsson, John Birks, John Burrows, Ruprecht Jaenicke, and Richard S. Stolarski
Hist. Geo Space. Sci. Discuss., https://doi.org/10.5194/hgss-2025-2, https://doi.org/10.5194/hgss-2025-2, 2025
Revised manuscript accepted for HGSS
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This paper reports a few anecdotes from the life of Paul Crutzen, which were contributed by friends and colleagues. Taken together these anecdotes should shed some light on the person Paul Crutzen, which is perhaps less visible, when focusing only on his scientific achievements.
Oleh Kachula, Bärbel Vogel, Gebhard Günther, and Rolf Müller
EGUsphere, https://doi.org/10.5194/egusphere-2025-1670, https://doi.org/10.5194/egusphere-2025-1670, 2025
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We propose a novel method to define the boundary of the Asian summer monsoon anticyclone (ASMA) and provide the inter-annual and intra-seasonal analyses based on 44 years (1980–2023) and highlight individual years – 2017, 2022 and 2023 during which aircraft campaigns StratoClim, ACCLIP and PHILEAS took place respectively. Our method shows consistent results with previous studies but also provide new information about possible bimodality of the ASMA and inter-annual decrease of the ASMA area.
Mingzhao Liu, Lars Hoffmann, Jens-Uwe Grooß, Zhongyin Cai, Sabine Grießbach, and Yi Heng
Atmos. Chem. Phys., 25, 4403–4418, https://doi.org/10.5194/acp-25-4403-2025, https://doi.org/10.5194/acp-25-4403-2025, 2025
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We studied the transport and chemical decomposition of volcanic SO2, focusing on the 2019 Raikoke event. By comparing two different chemistry modeling schemes, we found that including complex chemical reactions leads to a more accurate prediction of how long SO2 stays in the atmosphere. This research helps improve our understanding of volcanic pollution and its impact on air quality and climate, providing better tools for scientists to track and predict the movement of these pollutants.
Shubhajyoti Roy, Satheesh P. R. Chandran, Suvarna Fadnavis, Vijay Sagar, Michaela I. Hegglin, and Rolf Müller
EGUsphere, https://doi.org/10.5194/egusphere-2025-1098, https://doi.org/10.5194/egusphere-2025-1098, 2025
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We show stratospheric ozone intrusions associated with sudden stratospheric warming events enhance ozone in the lower troposphere over the South Asia. The ozone enhancement increases ozone radiative forcing by 0.04±0.03 W.m-2 over South Asia. This increase in ozone radiative forcing potentially exacerbates regional climate warming.
Florian Voet, Felix Ploeger, Johannes Laube, Peter Preusse, Paul Konopka, Jens-Uwe Grooß, Jörn Ungermann, Björn-Martin Sinnhuber, Michael Höpfner, Bernd Funke, Gerald Wetzel, Sören Johansson, Gabriele Stiller, Eric Ray, and Michaela I. Hegglin
Atmos. Chem. Phys., 25, 3541–3565, https://doi.org/10.5194/acp-25-3541-2025, https://doi.org/10.5194/acp-25-3541-2025, 2025
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This study refines estimates of the stratospheric “age of air”, a measure of how long air circulates in the stratosphere. By analyzing correlations between trace gases measurable by satellites, the research introduces a method that reduces uncertainties and detects small-scale atmospheric features. This improved understanding of stratospheric circulation is crucial for better climate models and predictions, enhancing our ability to assess the impacts of climate change on the atmosphere.
Prashant Chavan, Suvarna Fadnavis, Anton Laakso, Jean-Paul Vernier, Simone Tilmes, and Rolf Müller
EGUsphere, https://doi.org/10.5194/egusphere-2024-3825, https://doi.org/10.5194/egusphere-2024-3825, 2025
Preprint archived
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Our simulations with volcanoes, when compared without volcanoes, show that volcanic aerosol precursors enter the tropical stratosphere, propagating upward and enhancing sulphate aerosol and heating. This stratospheric heating caused by the volcanoes reduces the amplitude of the QBO and disrupts its phases. Since QBO also modulates tropical convection and weather, we suggest including volcanic emissions and the QBO in the weather prediction model for a better forecast.
Ling Zou, Reinhold Spang, Sabine Griessbach, Lars Hoffmann, Farahnaz Khosrawi, Rolf Müller, and Ines Tritscher
Atmos. Chem. Phys., 24, 11759–11774, https://doi.org/10.5194/acp-24-11759-2024, https://doi.org/10.5194/acp-24-11759-2024, 2024
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This study provided estimates of the occurrence of ice polar stratospheric clouds (PSCs) observed by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) and their connection with temperatures above the frost point (Tice) using a Lagrangian model derived from ERA5. We found that ice PSCs above Tice with temperature fluctuations along the backward trajectory are 33 % in the Arctic and 9 % in the Antarctic. This quantitative assessment enhances our understanding of ice PSCs.
Sandra Graßl, Christoph Ritter, Ines Tritscher, and Bärbel Vogel
Atmos. Chem. Phys., 24, 7535–7557, https://doi.org/10.5194/acp-24-7535-2024, https://doi.org/10.5194/acp-24-7535-2024, 2024
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Arctic lidar data for 1 year are compared with global modeling of aerosol tracers in the stratosphere. A trend in the aerosol backscatter can be found. These observations are further compared with a model study to investigate the aerosol origin of the observed arctic aerosol. We found a correlation with increased backscatter signal during summer and early autumn and pathways from the Southeast Asian monsoon region and remains of the Asian tropopause aerosol layer in the Arctic.
Jayanarayanan Kuttippurath, Gopalakrishna Pillai Gopikrishnan, Rolf Müller, Sophie Godin-Beekmann, and Jerome Brioude
Atmos. Chem. Phys., 24, 6743–6756, https://doi.org/10.5194/acp-24-6743-2024, https://doi.org/10.5194/acp-24-6743-2024, 2024
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The current understanding and observational evidence do not provide any support for the possibility of an ozone hole occurring outside Antarctica today with respect to the present-day stratospheric halogen levels.
Jan Clemens, Lars Hoffmann, Bärbel Vogel, Sabine Grießbach, and Nicole Thomas
Geosci. Model Dev., 17, 4467–4493, https://doi.org/10.5194/gmd-17-4467-2024, https://doi.org/10.5194/gmd-17-4467-2024, 2024
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Lagrangian transport models simulate the transport of air masses in the atmosphere. For example, one model (CLaMS) is well suited to calculating transport as it uses a special coordinate system and special vertical wind. However, it only runs inefficiently on modern supercomputers. Hence, we have implemented the benefits of CLaMS into a new model (MPTRAC), which is already highly efficient on modern supercomputers. Finally, in extensive tests, we showed that CLaMS and MPTRAC agree very well.
Martin Ebert, Ralf Weigel, Stephan Weinbruch, Lisa Schneider, Konrad Kandler, Stefan Lauterbach, Franziska Köllner, Felix Plöger, Gebhard Günther, Bärbel Vogel, and Stephan Borrmann
Atmos. Chem. Phys., 24, 4771–4788, https://doi.org/10.5194/acp-24-4771-2024, https://doi.org/10.5194/acp-24-4771-2024, 2024
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Particles were collected during the flight campaign StratoClim 2017 within the Asian tropopause aerosol layer (ATAL). Refractory particles from seven different flights were characterized by scanning and transmission electron microscopy (SEM, TEM). The most abundant refractory particles are silicates and non-volatile organics. The most important sources are combustion processes at the ground and the agitation of soil material. During one flight, small cinnabar particles (HgS) were also detected.
Felix Ploeger, Thomas Birner, Edward Charlesworth, Paul Konopka, and Rolf Müller
Atmos. Chem. Phys., 24, 2033–2043, https://doi.org/10.5194/acp-24-2033-2024, https://doi.org/10.5194/acp-24-2033-2024, 2024
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We present a novel mechanism of how regional anomalies in water vapour concentrations in the upper troposphere and lower stratosphere impact regional atmospheric circulation systems. These impacts include a displaced upper-level Asian monsoon circulation and strengthened prevailing westerlies in the Pacific region. Current climate models have biases in simulating these regional water vapour anomalies and circulation impacts, but the biases can be avoided by improving the model transport.
Reinhold Spang, Rolf Müller, and Alexandru Rap
Atmos. Chem. Phys., 24, 1213–1230, https://doi.org/10.5194/acp-24-1213-2024, https://doi.org/10.5194/acp-24-1213-2024, 2024
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Cirrus clouds play an important role in the radiation budget of the Earth. Despite recent progress in their observation, the radiative impact of ultra-thin cirrus clouds (UTC) in the tropopause region and in the lowermost stratosphere remains poorly constrained. Sensitivity model simulations with different ice parameters provide an uncertainty range for the radiative effect of UTCs. There is a need for better observed UTCs to enable the simulation of their potentially large effect on climate.
Jan Clemens, Bärbel Vogel, Lars Hoffmann, Sabine Griessbach, Nicole Thomas, Suvarna Fadnavis, Rolf Müller, Thomas Peter, and Felix Ploeger
Atmos. Chem. Phys., 24, 763–787, https://doi.org/10.5194/acp-24-763-2024, https://doi.org/10.5194/acp-24-763-2024, 2024
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The source regions of the Asian tropopause aerosol layer (ATAL) are debated. We use balloon-borne measurements of the layer above Nainital (India) in August 2016 and atmospheric transport models to find ATAL source regions. Most air originated from the Tibetan plateau. However, the measured ATAL was stronger when more air originated from the Indo-Gangetic Plain and weaker when more air originated from the Pacific. Hence, the results indicate important anthropogenic contributions to the ATAL.
Bärbel Vogel, C. Michael Volk, Johannes Wintel, Valentin Lauther, Jan Clemens, Jens-Uwe Grooß, Gebhard Günther, Lars Hoffmann, Johannes C. Laube, Rolf Müller, Felix Ploeger, and Fred Stroh
Atmos. Chem. Phys., 24, 317–343, https://doi.org/10.5194/acp-24-317-2024, https://doi.org/10.5194/acp-24-317-2024, 2024
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Over the Indian subcontinent, polluted air is rapidly uplifted to higher altitudes during the Asian monsoon season. We present an assessment of vertical transport in this region using different wind data provided by the European Centre for Medium-Range Weather Forecasts (ECMWF), as well as high-resolution aircraft measurements. In general, our findings confirm that the newest ECMWF reanalysis product, ERA5, yields a better representation of transport compared to the predecessor, ERA-Interim.
Rolf Müller, Ulrich Pöschl, Thomas Koop, Thomas Peter, and Ken Carslaw
Atmos. Chem. Phys., 23, 15445–15453, https://doi.org/10.5194/acp-23-15445-2023, https://doi.org/10.5194/acp-23-15445-2023, 2023
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Paul J. Crutzen was a pioneer in atmospheric sciences and a kind-hearted, humorous person with empathy for the private lives of his colleagues and students. He made fundamental scientific contributions to a wide range of scientific topics in all parts of the atmosphere. Paul was among the founders of the journal Atmospheric Chemistry and Physics. His work will continue to be a guide for generations of scientists and environmental policymakers to come.
Suvarna Fadnavis, Bernd Heinold, T. P. Sabin, Anne Kubin, Katty Huang, Alexandru Rap, and Rolf Müller
Atmos. Chem. Phys., 23, 10439–10449, https://doi.org/10.5194/acp-23-10439-2023, https://doi.org/10.5194/acp-23-10439-2023, 2023
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The influence of the COVID-19 lockdown on the Himalayas caused increases in snow cover and a decrease in runoff, ultimately leading to an enhanced snow water equivalent. Our findings highlight that, out of the two processes causing a retreat of Himalayan glaciers – (1) slow response to global climate change and (2) fast response to local air pollution – a policy action on the latter is more likely to be within the reach of possible policy action to help billions of people in southern Asia.
Lars Hoffmann, Paul Konopka, Jan Clemens, and Bärbel Vogel
Atmos. Chem. Phys., 23, 7589–7609, https://doi.org/10.5194/acp-23-7589-2023, https://doi.org/10.5194/acp-23-7589-2023, 2023
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Atmospheric convection plays a key role in tracer transport in the troposphere. Global meteorological forecasts and reanalyses typically have a coarse spatiotemporal resolution that does not adequately resolve the dynamics, transport, and mixing of air associated with storm systems or deep convection. We discuss the application of the extreme convection parameterization in a Lagrangian transport model to improve simulations of tracer transport from the boundary layer into the free troposphere.
Reimar Bauer, Jens-Uwe Grooß, Jörn Ungermann, May Bär, Markus Geldenhuys, and Lars Hoffmann
Geosci. Model Dev., 15, 8983–8997, https://doi.org/10.5194/gmd-15-8983-2022, https://doi.org/10.5194/gmd-15-8983-2022, 2022
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The Mission Support System (MSS) is an open source software package that has been used for planning flight tracks of scientific aircraft in multiple measurement campaigns during the last decade. Here, we describe the MSS software and its use during the SouthTRAC measurement campaign in 2019. As an example for how the MSS software is used in conjunction with many datasets, we describe the planning of a single flight probing orographic gravity waves propagating up into the lower mesosphere.
Markus Jesswein, Rafael P. Fernandez, Lucas Berná, Alfonso Saiz-Lopez, Jens-Uwe Grooß, Ryan Hossaini, Eric C. Apel, Rebecca S. Hornbrook, Elliot L. Atlas, Donald R. Blake, Stephen Montzka, Timo Keber, Tanja Schuck, Thomas Wagenhäuser, and Andreas Engel
Atmos. Chem. Phys., 22, 15049–15070, https://doi.org/10.5194/acp-22-15049-2022, https://doi.org/10.5194/acp-22-15049-2022, 2022
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This study presents the global and seasonal distribution of the two major brominated short-lived substances CH2Br2 and CHBr3 in the upper troposphere and lower stratosphere based on observations from several aircraft campaigns. They show similar seasonality for both hemispheres, except in the respective hemispheric autumn lower stratosphere. A comparison with the TOMCAT and CAM-Chem models shows good agreement in the annual mean but larger differences in the seasonal consideration.
Bernard Legras, Clair Duchamp, Pasquale Sellitto, Aurélien Podglajen, Elisa Carboni, Richard Siddans, Jens-Uwe Grooß, Sergey Khaykin, and Felix Ploeger
Atmos. Chem. Phys., 22, 14957–14970, https://doi.org/10.5194/acp-22-14957-2022, https://doi.org/10.5194/acp-22-14957-2022, 2022
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The long-duration atmospheric impact of the Tonga eruption in January 2022 is a plume of water and sulfate aerosols in the stratosphere that persisted for more than 6 months. We study this evolution using several satellite instruments and analyse the unusual behaviour of this plume as sulfates and water first moved down rapidly and then separated into two layers. We also report the self-organization in compact and long-lived patches.
Mohamadou A. Diallo, Felix Ploeger, Michaela I. Hegglin, Manfred Ern, Jens-Uwe Grooß, Sergey Khaykin, and Martin Riese
Atmos. Chem. Phys., 22, 14303–14321, https://doi.org/10.5194/acp-22-14303-2022, https://doi.org/10.5194/acp-22-14303-2022, 2022
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The quasi-biennial oacillation disruption events in both 2016 and 2020 decreased lower-stratospheric water vapour and ozone. Differences in the strength and depth of the anomalous lower-stratospheric circulation and ozone are due to differences in tropical upwelling and cold-point temperature induced by lower-stratospheric planetary and gravity wave breaking. The differences in water vapour are due to higher cold-point temperature in 2020 induced by Australian wildfire.
Oliver Appel, Franziska Köllner, Antonis Dragoneas, Andreas Hünig, Sergej Molleker, Hans Schlager, Christoph Mahnke, Ralf Weigel, Max Port, Christiane Schulz, Frank Drewnick, Bärbel Vogel, Fred Stroh, and Stephan Borrmann
Atmos. Chem. Phys., 22, 13607–13630, https://doi.org/10.5194/acp-22-13607-2022, https://doi.org/10.5194/acp-22-13607-2022, 2022
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This paper clarifies the chemical composition of the Asian tropopause aerosol layer (ATAL) by means of airborne in situ aerosol mass spectrometry (AMS). Ammonium nitrate and organics are found to significantly contribute to the particle layer, while sulfate does not show a layered structure. An analysis of the single-particle mass spectra suggests that secondary particle formation and subsequent growth dominate the particle composition, rather than condensation on pre-existing primary particles.
Ingo Wohltmann, Daniel Kreyling, and Ralph Lehmann
Geosci. Model Dev., 15, 7243–7255, https://doi.org/10.5194/gmd-15-7243-2022, https://doi.org/10.5194/gmd-15-7243-2022, 2022
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The study evaluates the performance of the Data Assimilation Research Testbed (DART), equipped with the recently added forward operator Radiative Transfer for TOVS (RTTOV), in assimilating FY-4A visible images into the Weather Research and Forecasting (WRF) model. The ability of the WRF-DART/RTTOV system to improve the forecasting skills for a tropical storm over East Asia and the Western Pacific is demonstrated in an Observing System Simulation Experiment framework.
Liubov Poshyvailo-Strube, Rolf Müller, Stephan Fueglistaler, Michaela I. Hegglin, Johannes C. Laube, C. Michael Volk, and Felix Ploeger
Atmos. Chem. Phys., 22, 9895–9914, https://doi.org/10.5194/acp-22-9895-2022, https://doi.org/10.5194/acp-22-9895-2022, 2022
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Brewer–Dobson circulation (BDC) controls the composition of the stratosphere, which in turn affects radiation and climate. As the BDC cannot be measured directly, it is necessary to infer its strength and trends indirectly. In this study, we test in the
model worlddifferent methods for estimating the mean age of air trends based on a combination of stratospheric water vapour and methane data. We also provide simple practical advice of a more reliable estimation of the mean age of air trends.
Suvarna Fadnavis, Prashant Chavan, Akash Joshi, Sunil M. Sonbawne, Asutosh Acharya, Panuganti C. S. Devara, Alexandru Rap, Felix Ploeger, and Rolf Müller
Atmos. Chem. Phys., 22, 7179–7191, https://doi.org/10.5194/acp-22-7179-2022, https://doi.org/10.5194/acp-22-7179-2022, 2022
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We show that large amounts of anthropogenic aerosols are transported from South Asia to the northern Indian Ocean. These aerosols are then lifted into the UTLS by the ascending branch of the Hadley circulation. They are further transported to the Southern Hemisphere and downward via westerly ducts over the tropical Atlantic and Pacific. These aerosols increase tropospheric heating, resulting in an increase in water vapor, which is then transported to the UTLS.
Lars Hoffmann, Paul F. Baumeister, Zhongyin Cai, Jan Clemens, Sabine Griessbach, Gebhard Günther, Yi Heng, Mingzhao Liu, Kaveh Haghighi Mood, Olaf Stein, Nicole Thomas, Bärbel Vogel, Xue Wu, and Ling Zou
Geosci. Model Dev., 15, 2731–2762, https://doi.org/10.5194/gmd-15-2731-2022, https://doi.org/10.5194/gmd-15-2731-2022, 2022
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We describe the new version (2.2) of the Lagrangian transport model MPTRAC, which has been ported for application on GPUs. The model was verified by comparing kinematic trajectories and synthetic tracer simulations for the free troposphere and stratosphere from GPUs and CPUs. Benchmarking showed a speed-up of a factor of 16 of GPU-enabled simulations compared to CPU-only runs, indicating the great potential of applying GPUs for Lagrangian transport simulations on upcoming HPC systems.
Helmut Ziereis, Peter Hoor, Jens-Uwe Grooß, Andreas Zahn, Greta Stratmann, Paul Stock, Michael Lichtenstern, Jens Krause, Vera Bense, Armin Afchine, Christian Rolf, Wolfgang Woiwode, Marleen Braun, Jörn Ungermann, Andreas Marsing, Christiane Voigt, Andreas Engel, Björn-Martin Sinnhuber, and Hermann Oelhaf
Atmos. Chem. Phys., 22, 3631–3654, https://doi.org/10.5194/acp-22-3631-2022, https://doi.org/10.5194/acp-22-3631-2022, 2022
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Airborne observations were conducted in the lowermost Arctic stratosphere during the winter of 2015/2016. The observed distribution of reactive nitrogen shows clear indications of nitrification in mid-winter and denitrification in late winter. This was caused by the formation of polar stratospheric cloud particles, which were observed during several flights. The sedimentation and evaporation of these particles and the descent of air masses cause a redistribution of reactive nitrogen.
Valentin Lauther, Bärbel Vogel, Johannes Wintel, Andrea Rau, Peter Hoor, Vera Bense, Rolf Müller, and C. Michael Volk
Atmos. Chem. Phys., 22, 2049–2077, https://doi.org/10.5194/acp-22-2049-2022, https://doi.org/10.5194/acp-22-2049-2022, 2022
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We show airborne in situ measurements of the very short-lived ozone-depleting substances CH2Cl2 and CHCl3, revealing particularly high concentrations of both species in the lower stratosphere. Back-trajectory calculations and 3D model simulations show that the air masses with high concentrations originated in the Asian boundary layer and were transported via the Asian summer monsoon. We also identify a fast transport pathway into the stratosphere via the North American monsoon and by hurricanes.
Dina Khordakova, Christian Rolf, Jens-Uwe Grooß, Rolf Müller, Paul Konopka, Andreas Wieser, Martina Krämer, and Martin Riese
Atmos. Chem. Phys., 22, 1059–1079, https://doi.org/10.5194/acp-22-1059-2022, https://doi.org/10.5194/acp-22-1059-2022, 2022
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Extreme storms transport humidity from the troposphere to the stratosphere. Here it has a strong impact on the climate. With ongoing global warming, we expect more storms and, hence, an enhancement of this effect. A case study was performed in order to measure the impact of the direct injection of water vapor into the lower stratosphere. The measurements displayed a significant transport of water vapor into the lower stratosphere, and this was supported by satellite and reanalysis data.
Manuel Baumgartner, Christian Rolf, Jens-Uwe Grooß, Julia Schneider, Tobias Schorr, Ottmar Möhler, Peter Spichtinger, and Martina Krämer
Atmos. Chem. Phys., 22, 65–91, https://doi.org/10.5194/acp-22-65-2022, https://doi.org/10.5194/acp-22-65-2022, 2022
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An important mechanism for the appearance of ice particles in the upper troposphere at low temperatures is homogeneous nucleation. This process is commonly described by the
Koop line, predicting the humidity at freezing. However, laboratory measurements suggest that the freezing humidities are above the Koop line, motivating the present study to investigate the influence of different physical parameterizations on the homogeneous freezing with the help of a detailed numerical model.
Meike K. Rotermund, Vera Bense, Martyn P. Chipperfield, Andreas Engel, Jens-Uwe Grooß, Peter Hoor, Tilman Hüneke, Timo Keber, Flora Kluge, Benjamin Schreiner, Tanja Schuck, Bärbel Vogel, Andreas Zahn, and Klaus Pfeilsticker
Atmos. Chem. Phys., 21, 15375–15407, https://doi.org/10.5194/acp-21-15375-2021, https://doi.org/10.5194/acp-21-15375-2021, 2021
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Airborne total bromine (Brtot) and tracer measurements suggest Brtot-rich air masses persistently protruded into the lower stratosphere (LS), creating a high Brtot region over the North Atlantic in fall 2017. The main source is via isentropic transport by the Asian monsoon and to a lesser extent transport across the extratropical tropopause as quantified by a Lagrange model. The transport of Brtot via Central American hurricanes is also observed. Lastly, the impact of Brtot on LS O3 is assessed.
Prashant Chavan, Suvarna Fadnavis, Tanusri Chakroborty, Christopher E. Sioris, Sabine Griessbach, and Rolf Müller
Atmos. Chem. Phys., 21, 14371–14384, https://doi.org/10.5194/acp-21-14371-2021, https://doi.org/10.5194/acp-21-14371-2021, 2021
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Biomass burning (BB) over Asia is a strong source of carbonaceous aerosols during spring. Here, we show an outflow of Asian BB carbonaceous aerosols into the UTLS. These aerosols enhance atmospheric heating and produce circulation changes that lead to the enhancement of water vapor in the UTLS over the tropics. In the stratosphere, water vapor is further transported to the South Pole by the Brewer–Dobson circulation. Enhancement of water vapor in the UTLS has implications for climate change.
Jayanarayanan Kuttippurath, Wuhu Feng, Rolf Müller, Pankaj Kumar, Sarath Raj, Gopalakrishna Pillai Gopikrishnan, and Raina Roy
Atmos. Chem. Phys., 21, 14019–14037, https://doi.org/10.5194/acp-21-14019-2021, https://doi.org/10.5194/acp-21-14019-2021, 2021
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The Arctic winter/spring 2020 was one of the coldest with a strong and long-lasting vortex, high chlorine activation, severe denitrification, and unprecedented ozone loss. The loss was even equal to the levels of some of the warm Antarctic winters. Total column ozone values below 220 DU for several weeks and ozone loss saturation were observed during the period. These results show an unusual meteorology and warrant dedicated studies on the impact of climate change on ozone loss.
Ralf Weigel, Christoph Mahnke, Manuel Baumgartner, Antonis Dragoneas, Bärbel Vogel, Felix Ploeger, Silvia Viciani, Francesco D'Amato, Silvia Bucci, Bernard Legras, Beiping Luo, and Stephan Borrmann
Atmos. Chem. Phys., 21, 11689–11722, https://doi.org/10.5194/acp-21-11689-2021, https://doi.org/10.5194/acp-21-11689-2021, 2021
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In July and August 2017, eight StratoClim mission flights of the Geophysica reached up to 20 km in the Asian monsoon anticyclone. New particle formation (NPF) was identified in situ by abundant nucleation-mode aerosols (6–15 nm in diameter) with mixing ratios of up to 50 000 mg−1. NPF occurred most frequently at 12–16 km with fractions of non-volatile residues of down to 15 %. Abundance and productivity of observed NPF indicate its ability to promote the Asian tropopause aerosol layer.
Lukas Krasauskas, Jörn Ungermann, Peter Preusse, Felix Friedl-Vallon, Andreas Zahn, Helmut Ziereis, Christian Rolf, Felix Plöger, Paul Konopka, Bärbel Vogel, and Martin Riese
Atmos. Chem. Phys., 21, 10249–10272, https://doi.org/10.5194/acp-21-10249-2021, https://doi.org/10.5194/acp-21-10249-2021, 2021
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A Rossby wave (RW) breaking event was observed over the North Atlantic during the WISE measurement campaign in October 2017. Infrared limb sounding measurements of trace gases in the lower stratosphere, including high-resolution 3-D tomographic reconstruction, revealed complex spatial structures in stratospheric tracers near the polar jet related to previous RW breaking events. Backward-trajectory analysis and tracer correlations were used to study mixing and stratosphere–troposphere exchange.
Felix Ploeger, Mohamadou Diallo, Edward Charlesworth, Paul Konopka, Bernard Legras, Johannes C. Laube, Jens-Uwe Grooß, Gebhard Günther, Andreas Engel, and Martin Riese
Atmos. Chem. Phys., 21, 8393–8412, https://doi.org/10.5194/acp-21-8393-2021, https://doi.org/10.5194/acp-21-8393-2021, 2021
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We investigate the global stratospheric circulation (Brewer–Dobson circulation) in the new ECMWF ERA5 reanalysis based on age of air simulations, and we compare it to results from the preceding ERA-Interim reanalysis. Our results show a slower stratospheric circulation and higher age for ERA5. The age of air trend in ERA5 over the 1989–2018 period is negative throughout the stratosphere, related to multi-annual variability and a potential contribution from changes in the reanalysis system.
Gerald Wetzel, Felix Friedl-Vallon, Norbert Glatthor, Jens-Uwe Grooß, Thomas Gulde, Michael Höpfner, Sören Johansson, Farahnaz Khosrawi, Oliver Kirner, Anne Kleinert, Erik Kretschmer, Guido Maucher, Hans Nordmeyer, Hermann Oelhaf, Johannes Orphal, Christof Piesch, Björn-Martin Sinnhuber, Jörn Ungermann, and Bärbel Vogel
Atmos. Chem. Phys., 21, 8213–8232, https://doi.org/10.5194/acp-21-8213-2021, https://doi.org/10.5194/acp-21-8213-2021, 2021
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Measurements of the pollutants C2H6, C2H2, HCOOH, and PAN were performed in the North Atlantic UTLS region with the airborne limb imager GLORIA in 2017. Enhanced amounts of these species were detected in the upper troposphere and even in the lowermost stratosphere (PAN). Main sources of these gases are forest fires in North America and anthropogenic pollution in South Asia. Simulations of EMAC and CAMS are qualitatively able to reproduce the measured data but underestimate the absolute amounts.
Sabine Robrecht, Bärbel Vogel, Simone Tilmes, and Rolf Müller
Atmos. Chem. Phys., 21, 2427–2455, https://doi.org/10.5194/acp-21-2427-2021, https://doi.org/10.5194/acp-21-2427-2021, 2021
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Column ozone protects life on Earth from radiation damage. Stratospheric chlorine compounds cause immense ozone loss in polar winter. Whether similar loss processes can occur in the lower stratosphere above North America today or in future is a matter of debate. We show that these ozone loss processes are very unlikely today or in future independently of whether sulfate geoengineering is applied and that less than 0.1 % of column ozone would be destroyed by this process in any future scenario.
Johannes Schneider, Ralf Weigel, Thomas Klimach, Antonis Dragoneas, Oliver Appel, Andreas Hünig, Sergej Molleker, Franziska Köllner, Hans-Christian Clemen, Oliver Eppers, Peter Hoppe, Peter Hoor, Christoph Mahnke, Martina Krämer, Christian Rolf, Jens-Uwe Grooß, Andreas Zahn, Florian Obersteiner, Fabrizio Ravegnani, Alexey Ulanovsky, Hans Schlager, Monika Scheibe, Glenn S. Diskin, Joshua P. DiGangi, John B. Nowak, Martin Zöger, and Stephan Borrmann
Atmos. Chem. Phys., 21, 989–1013, https://doi.org/10.5194/acp-21-989-2021, https://doi.org/10.5194/acp-21-989-2021, 2021
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During five aircraft missions, we detected aerosol particles containing meteoric material in the lower stratosphere. The stratospheric measurements span a latitude range from 15 to 68° N, and we find that at potential temperature levels of more than 40 K above the tropopause; particles containing meteoric material occur at similar abundance fractions across latitudes and seasons. We conclude that meteoric material is efficiently distributed between high and low latitudes by isentropic mixing.
Sreeharsha Hanumanthu, Bärbel Vogel, Rolf Müller, Simone Brunamonti, Suvarna Fadnavis, Dan Li, Peter Ölsner, Manish Naja, Bhupendra Bahadur Singh, Kunchala Ravi Kumar, Sunil Sonbawne, Hannu Jauhiainen, Holger Vömel, Beiping Luo, Teresa Jorge, Frank G. Wienhold, Ruud Dirkson, and Thomas Peter
Atmos. Chem. Phys., 20, 14273–14302, https://doi.org/10.5194/acp-20-14273-2020, https://doi.org/10.5194/acp-20-14273-2020, 2020
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During boreal summer, anthropogenic sources yield the Asian Tropopause Aerosol Layer (ATAL), found in Asia between about 13 and 18 km altitude. Balloon-borne measurements of the ATAL conducted in northern India in 2016 show the strong variability of the ATAL. To explain its observed variability, model simulations are performed to deduce the origin of air masses on the Earth's surface, which is important to develop recommendations for regulations of anthropogenic surface emissions of the ATAL.
Joram J. D. Hooghiem, Maria Elena Popa, Thomas Röckmann, Jens-Uwe Grooß, Ines Tritscher, Rolf Müller, Rigel Kivi, and Huilin Chen
Atmos. Chem. Phys., 20, 13985–14003, https://doi.org/10.5194/acp-20-13985-2020, https://doi.org/10.5194/acp-20-13985-2020, 2020
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Wildfires release a large quantity of pollutants that can reach the stratosphere through pyro-convection events. In September 2017, a stratospheric plume was accidentally sampled during balloon soundings in northern Finland. The source of the plume was identified to be wildfire smoke based on in situ measurements of carbon monoxide (CO) and stable isotope analysis of CO. Furthermore, the age of the plume was estimated using backwards transport modelling to be ~24 d, with its origin in Canada.
Cited articles
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Fleming, E. L., Newman, P. A., Liang, Q., and Oman, L. D.: Stratospheric temperature and ozone impacts of the Hunga Tonga-Hunga Ha'apai water vapor injection, J. Geophys. Res., 129, e2023JD039298, https://doi.org/10.1029/2023JD039298, 2024. a, b, c
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Grooß, J.-U., Pierce, R. B., Crutzen, P. J., Grose, W. L., and Russell III, J. M.: Re-formation of chlorine reservoirs in southern hemisphere polar spring, J. Geophys. Res., 102, 13141–13152, https://doi.org/10.1029/96JD03505, 1997. a, b
Grooß, J.-U., Günther, G., Müller, R., Konopka, P., Bausch, S., Schlager, H., Voigt, C., Volk, C. M., and Toon, G. C.: Simulation of denitrification and ozone loss for the Arctic winter 2002/2003, Atmos. Chem. Phys., 5, 1437–1448, https://doi.org/10.5194/acp-5-1437-2005, 2005. a
Grooß, J.-U., Brautzsch, K., Pommrich, R., Solomon, S., and Müller, R.: Stratospheric ozone chemistry in the Antarctic: what determines the lowest ozone values reached and their recovery?, Atmos. Chem. Phys., 11, 12217–12226, https://doi.org/10.5194/acp-11-12217-2011, 2011. a, b, c, d, e, f, g, h, i, j, k, l, m, n, o, p
Grooß, J.-U., Müller, R., Spang, R., Tritscher, I., Wegner, T., Chipperfield, M. P., Feng, W., Kinnison, D. E., and Madronich, S.: On the discrepancy of HCl processing in the core of the wintertime polar vortices, Atmos. Chem. Phys., 18, 8647–8666, https://doi.org/10.5194/acp-18-8647-2018, 2018. a, b, c, d, e, f, g, h, i, j, k, l, m
Hynes, R. G., Fernandez, M. A., and Cox, R. A.: Uptake of HNO3 on water-ice and coadsorption of HNO3 and HCl in the temperature range 210–235 K, J. Geophys. Res., 107, 4797, https://doi.org/10.1029/2001JD001557, 2002. a
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Johansson, S., Santee, M. L., Grooß, J.-U., Höpfner, M., Braun, M., Friedl-Vallon, F., Khosrawi, F., Kirner, O., Kretschmer, E., Oelhaf, H., Orphal, J., Sinnhuber, B.-M., Tritscher, I., Ungermann, J., Walker, K. A., and Woiwode, W.: Unusual chlorine partitioning in the 2015/16 Arctic winter lowermost stratosphere: observations and simulations, Atmos. Chem. Phys., 19, 8311–8338, https://doi.org/10.5194/acp-19-8311-2019, 2019. a, b
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Müller, R., Grooß, J.-U., Zafar, A. M., Robrecht, S., and Lehmann, R.: The maintenance of elevated active chlorine levels in the Antarctic lower stratosphere through HCl null cycles, Atmos. Chem. Phys., 18, 2985–2997, https://doi.org/10.5194/acp-18-2985-2018, 2018. a, b, c, d, e, f, g, h, i, j, k, l, m, n, o, p, q, r, s, t, u, v, w, x, y, z, aa, ab, ac, ad
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Short summary
HCl null cycles in Antarctica are important for maintaining high values of ozone-destroying chlorine in Antarctic spring. These HCl null cycles are not affected by (1) using the most recent recommendations of chemical kinetics (compared to older recommendations), (2) accounting for dehydration in the Antarctic winter vortex, and (3) considering the observed (but unexplained) depletion of HCl in mid-winter in the Antarctic vortex throughout Antarctic winter.
HCl null cycles in Antarctica are important for maintaining high values of ozone-destroying...
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