Articles | Volume 22, issue 13
https://doi.org/10.5194/acp-22-9175-2022
https://doi.org/10.5194/acp-22-9175-2022
Research article
 | 
15 Jul 2022
Research article |  | 15 Jul 2022

A novel pathway of atmospheric sulfate formation through carbonate radicals

Yangyang Liu, Yue Deng, Jiarong Liu, Xiaozhong Fang, Tao Wang, Kejian Li, Kedong Gong, Aziz U. Bacha, Iqra Nabi, Qiuyue Ge, Xiuhui Zhang, Christian George, and Liwu Zhang

Related authors

Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface
Tao Wang, Yangyang Liu, Hanyun Cheng, Zhenzhen Wang, Hongbo Fu, Jianmin Chen, and Liwu Zhang
Atmos. Chem. Phys., 22, 13467–13493, https://doi.org/10.5194/acp-22-13467-2022,https://doi.org/10.5194/acp-22-13467-2022, 2022
Short summary
Is the photochemistry activity weak during haze events? – A novel exploration on the photoinduced heterogeneous reaction of NO2 on mineral dust
Tao Wang, Yangyang Liu, Yue Deng, Hanyun Cheng, Yang Yang, Yiqing Feng, Muhammad Ali Tahir, Xiaozhong Fang, Xu Dong, Kejian Li, Saira Ajmal, Aziz-Ur-Rahim Bacha, Iqra Nabi, Hongbo Fu, Liwu Zhang, and Jianmin Chen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-315,https://doi.org/10.5194/acp-2019-315, 2019
Revised manuscript not accepted
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Characterization of the particle size distribution, mineralogy, and Fe mode of occurrence of dust-emitting sediments from the Mojave Desert, California, USA
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Patricia Córdoba, Andres Alastuey, Natalia Moreno, Melani Hernández-Chiriboga, Konrad Kandler, Martina Klose, Roger N. Clark, Bethany L. Ehlmann, Rebecca N. Greenberger, Abigail M. Keebler, Phil Brodrick, Robert Green, Paul Ginoux, Xavier Querol, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 24, 9155–9176, https://doi.org/10.5194/acp-24-9155-2024,https://doi.org/10.5194/acp-24-9155-2024, 2024
Short summary
Measurement report: Effects of transition metal ions on the optical properties of humic-like substances (HULIS) reveal a structural preference – a case study of PM2.5 in Beijing, China
Juanjuan Qin, Leiming Zhang, Yuanyuan Qin, Shaoxuan Shi, Jingnan Li, Zhao Shu, Yuwei Gao, Ting Qi, Jihua Tan, and Xinming Wang
Atmos. Chem. Phys., 24, 7575–7589, https://doi.org/10.5194/acp-24-7575-2024,https://doi.org/10.5194/acp-24-7575-2024, 2024
Short summary
The Impact of Aqueous Phase Replacement Reaction on the Phase State of Internally Mixed Organic/ammonium Aerosols
Hui Yang, Fengfeng Dong, Li Xia, Qishen Huang, Shufeng Pang, and Yunhong Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1556,https://doi.org/10.5194/egusphere-2024-1556, 2024
Short summary
Probing Iceland's dust-emitting sediments: particle size distribution, mineralogy, cohesion, Fe mode of occurrence, and reflectance spectra signatures
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Patricia Córdoba, Andres Alastuey, Natalia Moreno, Konrad Kandler, Martina Klose, Roger N. Clark, Bethany L. Ehlmann, Rebecca N. Greenberger, Abigail M. Keebler, Phil Brodrick, Robert O. Green, Xavier Querol, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 24, 6883–6910, https://doi.org/10.5194/acp-24-6883-2024,https://doi.org/10.5194/acp-24-6883-2024, 2024
Short summary
Photoenhanced sulfate formation by the heterogeneous uptake of SO2 on non-photoactive mineral dust
Wangjin Yang, Jiawei Ma, Hongxing Yang, Fu Li, and Chong Han
Atmos. Chem. Phys., 24, 6757–6768, https://doi.org/10.5194/acp-24-6757-2024,https://doi.org/10.5194/acp-24-6757-2024, 2024
Short summary

Cited articles

Abou-Ghanem, M., Oliynyk, A. O., Chen, Z. H., Matchett, L. C., McGrath, D. T., Katz, M. J., Locock, A. J., and Styler, S. A.: Significant Variability in the Photocatalytic Activity of Natural Titanium-Containing Minerals: Implications for Understanding and Predicting Atmospheric Mineral Dust Photochemistry, Environ. Sci. Technol., 54, 13509–13516, https://doi.org/10.1021/acs.est.0c05861, 2020. 
Agustine, I., Yulinawati, H., Gunawan, D., and Suswantoro, E.: Potential impact of particulate matter less than 10 micron (PM10) to ambient air quality of Jakarta and Palembang, Iop C Ser. Earth Env., 106, 012057, https://doi.org/10.1088/1755-1315/106/1/012057, 2018. 
Al-Hosney, H. A. and Grassian, V. H.: Water, sulfur dioxide and nitric acid adsorption on calcium carbonate: A transmission and ATR-FTIR study, Phys. Chem. Chem. Phys., 7, 1266–1276, https://doi.org/10.1039/b417872f, 2005. 
Al-Salihi, A. M. and Mohammed, T. H.: The effect of dust storms on some meteorological elements over Baghdad, Iraq: Study Cases, IOSR Journal of Applied Physics, 7, Ver. II PP 01-07​​​​​​​, https://iosrjournals.org/iosr-jap/papers/Vol7-issue2/Version-2/A07220107.pdf (last access: 12 July 2022)​​​​​​​​​​​​​​, 2015. 
Balachandran, U. and Eror, N. G.: Raman-Spectra Of Titanium-Dioxide, J. Sol. State Chem., 42, 276–282, https://doi.org/10.1016/0022-4596(82)90006-8, 1982. 
Download
Short summary
Both CO2 and carbonate salt work as the precursor of carbonate radicals, which largely promotes sulfate formation during the daytime. This study provides the first indication that the carbonate radical not only plays a role as an intermediate in tropospheric anion chemistry but also as a strong oxidant for the surface processing of trace gas in the atmosphere. CO2, carbponate radicals, and sulfate receive attention from those looking at the environment, atmosphere, aerosol, and photochemistry.
Altmetrics
Final-revised paper
Preprint