Articles | Volume 22, issue 13
https://doi.org/10.5194/acp-22-9175-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-9175-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 Jul 2022
Research article |
| 15 Jul 2022
| 15 Jul 2022
A novel pathway of atmospheric sulfate formation through carbonate radicals
Yangyang Liu
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, Peoples' Republic of China
Yue Deng
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, Peoples' Republic of China
Jiarong Liu
Key Laboratory of Cluster Science, Ministry of Education of China,
School of Chemistry and Chemical Engineering, Beijing Institute of
Technology, Beijing 100081, P.R. China
Xiaozhong Fang
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Tao Wang
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Kejian Li
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Kedong Gong
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Aziz U. Bacha
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Iqra Nabi
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Qiuyue Ge
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Xiuhui Zhang
Key Laboratory of Cluster Science, Ministry of Education of China,
School of Chemistry and Chemical Engineering, Beijing Institute of
Technology, Beijing 100081, P.R. China
Christian George
Univ. Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON,
69626 Villeurbanne, France
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, P.R. China
Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, Peoples' Republic of China
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Cited
10 citations as recorded by crossref.
- Atmospheric Hydroxyl Radical Route Revealed: Interface-Mediated Effects of Mineral-Bearing Microdroplet Aerosol L. Yang et al. 10.1021/jacs.4c14149
- Efficient V-Shaped Substrate for Surface and Volume Enhanced Raman Spectroscopic Analysis of Bioaerosol: Prevention from Potential Health Risk J. Liu et al. 10.1021/envhealth.3c00178
- Potential of Copper-doped nanotubes as catalysts for SO2 oxidation H. Sharif et al. 10.1016/j.mseb.2022.116192
- Carbonate radical ion as a key driver of rapid atmospheric sulfate formation Y. Liu et al. 10.1038/s41612-025-00905-4
- Unveiling the Role of Carbonate Radical Anions in Dust‐Driven SO2 Oxidation Y. Liu et al. 10.1029/2023JD040017
- Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface T. Wang et al. 10.5194/acp-22-13467-2022
- Investigating the impact of pretreatment strategies on photocatalyst for accurate CO2RR productivity quantification: A machine learning approach Y. Liu et al. 10.1016/j.cej.2023.145255
- Impact of flow velocity on the heterogeneous reaction of SO2 over Fe2O3 Y. Liu et al. 10.1016/j.atmosenv.2022.119491
- Photoenhanced sulfate formation by the heterogeneous uptake of SO2 on non-photoactive mineral dust W. Yang et al. 10.5194/acp-24-6757-2024
- Unveiling the Overlooked Inhibitory Effects of Carbon Dioxide on Photochemical Nitrate Decomposition over Photoactive Mineral Dust X. Zhang et al. 10.1021/acs.est.4c11591
10 citations as recorded by crossref.
- Atmospheric Hydroxyl Radical Route Revealed: Interface-Mediated Effects of Mineral-Bearing Microdroplet Aerosol L. Yang et al. 10.1021/jacs.4c14149
- Efficient V-Shaped Substrate for Surface and Volume Enhanced Raman Spectroscopic Analysis of Bioaerosol: Prevention from Potential Health Risk J. Liu et al. 10.1021/envhealth.3c00178
- Potential of Copper-doped nanotubes as catalysts for SO2 oxidation H. Sharif et al. 10.1016/j.mseb.2022.116192
- Carbonate radical ion as a key driver of rapid atmospheric sulfate formation Y. Liu et al. 10.1038/s41612-025-00905-4
- Unveiling the Role of Carbonate Radical Anions in Dust‐Driven SO2 Oxidation Y. Liu et al. 10.1029/2023JD040017
- Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface T. Wang et al. 10.5194/acp-22-13467-2022
- Investigating the impact of pretreatment strategies on photocatalyst for accurate CO2RR productivity quantification: A machine learning approach Y. Liu et al. 10.1016/j.cej.2023.145255
- Impact of flow velocity on the heterogeneous reaction of SO2 over Fe2O3 Y. Liu et al. 10.1016/j.atmosenv.2022.119491
- Photoenhanced sulfate formation by the heterogeneous uptake of SO2 on non-photoactive mineral dust W. Yang et al. 10.5194/acp-24-6757-2024
- Unveiling the Overlooked Inhibitory Effects of Carbon Dioxide on Photochemical Nitrate Decomposition over Photoactive Mineral Dust X. Zhang et al. 10.1021/acs.est.4c11591
Latest update: 30 Mar 2025
Short summary
Both CO2 and carbonate salt work as the precursor of carbonate radicals, which largely promotes sulfate formation during the daytime. This study provides the first indication that the carbonate radical not only plays a role as an intermediate in tropospheric anion chemistry but also as a strong oxidant for the surface processing of trace gas in the atmosphere. CO2, carbponate radicals, and sulfate receive attention from those looking at the environment, atmosphere, aerosol, and photochemistry.
Both CO2 and carbonate salt work as the precursor of carbonate radicals, which largely promotes...
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